JP5582568B2 - Emulsion composition for hairdressing - Google Patents
Emulsion composition for hairdressing Download PDFInfo
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- JP5582568B2 JP5582568B2 JP2010193737A JP2010193737A JP5582568B2 JP 5582568 B2 JP5582568 B2 JP 5582568B2 JP 2010193737 A JP2010193737 A JP 2010193737A JP 2010193737 A JP2010193737 A JP 2010193737A JP 5582568 B2 JP5582568 B2 JP 5582568B2
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- 239000000203 mixture Substances 0.000 title claims description 42
- 239000000839 emulsion Substances 0.000 title 1
- 229920001296 polysiloxane Polymers 0.000 claims description 29
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 19
- 229920002545 silicone oil Polymers 0.000 claims description 16
- 229920001577 copolymer Polymers 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 5
- 235000012239 silicon dioxide Nutrition 0.000 claims description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 4
- 230000001804 emulsifying effect Effects 0.000 claims description 4
- 125000006353 oxyethylene group Chemical group 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 238000011156 evaluation Methods 0.000 description 22
- 230000003750 conditioning effect Effects 0.000 description 17
- 239000003795 chemical substances by application Substances 0.000 description 13
- -1 polysaccharide compound Chemical class 0.000 description 13
- 230000000694 effects Effects 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 230000014759 maintenance of location Effects 0.000 description 8
- 239000002537 cosmetic Substances 0.000 description 7
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- 239000010696 ester oil Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 229910002012 Aerosil® Inorganic materials 0.000 description 3
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 3
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- 238000009472 formulation Methods 0.000 description 3
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 230000001953 sensory effect Effects 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- IUMSDRXLFWAGNT-UHFFFAOYSA-N Dodecamethylcyclohexasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 IUMSDRXLFWAGNT-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
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- 238000004945 emulsification Methods 0.000 description 2
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- 239000012530 fluid Substances 0.000 description 2
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
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- 229940015975 1,2-hexanediol Drugs 0.000 description 1
- 229940031723 1,2-octanediol Drugs 0.000 description 1
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- ZPQAUEDTKNBRNG-UHFFFAOYSA-N 2-methylprop-2-enoylsilicon Chemical compound CC(=C)C([Si])=O ZPQAUEDTKNBRNG-UHFFFAOYSA-N 0.000 description 1
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- 208000001840 Dandruff Diseases 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- ADANNTOYRVPQLJ-UHFFFAOYSA-N [dimethyl(trimethylsilyloxy)silyl]oxy-[[dimethyl(trimethylsilyloxy)silyl]oxy-dimethylsilyl]oxy-dimethylsilane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C ADANNTOYRVPQLJ-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 229940121363 anti-inflammatory agent Drugs 0.000 description 1
- 239000002260 anti-inflammatory agent Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 238000011074 autoclave method Methods 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- BMRWNKZVCUKKSR-UHFFFAOYSA-N butane-1,2-diol Chemical compound CCC(O)CO BMRWNKZVCUKKSR-UHFFFAOYSA-N 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- YSRSBDQINUMTIF-UHFFFAOYSA-N decane-1,2-diol Chemical compound CCCCCCCCC(O)CO YSRSBDQINUMTIF-UHFFFAOYSA-N 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000003676 hair preparation Substances 0.000 description 1
- FHKSXSQHXQEMOK-UHFFFAOYSA-N hexane-1,2-diol Chemical compound CCCCC(O)CO FHKSXSQHXQEMOK-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 238000007561 laser diffraction method Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- WCVRQHFDJLLWFE-UHFFFAOYSA-N pentane-1,2-diol Chemical compound CCCC(O)CO WCVRQHFDJLLWFE-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 239000005053 propyltrichlorosilane Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000790 scattering method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229940008424 tetradecamethylhexasiloxane Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- ZOYFEXPFPVDYIS-UHFFFAOYSA-N trichloro(ethyl)silane Chemical compound CC[Si](Cl)(Cl)Cl ZOYFEXPFPVDYIS-UHFFFAOYSA-N 0.000 description 1
- LFXJGGDONSCPOF-UHFFFAOYSA-N trichloro(hexyl)silane Chemical compound CCCCCC[Si](Cl)(Cl)Cl LFXJGGDONSCPOF-UHFFFAOYSA-N 0.000 description 1
- DOEHJNBEOVLHGL-UHFFFAOYSA-N trichloro(propyl)silane Chemical compound CCC[Si](Cl)(Cl)Cl DOEHJNBEOVLHGL-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
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- Cosmetics (AREA)
Description
本発明は、塗布時の延展性が良く、コンディショニング効果と整髪効果を発揮する整髪用乳化組成物に関する。 The present invention relates to an emulsifying composition for styling that has good spreadability at the time of application and exhibits a conditioning effect and a hair styling effect.
従来より、毛髪に優れたコンディショニング効果を付与するために、シリコーン油、エステル油などの油剤を配合する試みがなされている。例えば、特定のカチオン性界面活性剤と、エステル油と、シリコーン類とを含有するヘアコンディショニング組成物(特許文献1を参照)、特定の変性シリコーンと、多価アルコールと、高分子量シリコーンと、カチオン性界面活性剤とを含有するヘアコンディショニング組成物(特許文献2を参照)などが提案されている。 Conventionally, attempts have been made to blend oil agents such as silicone oil and ester oil in order to impart an excellent conditioning effect to the hair. For example, a hair conditioning composition (see Patent Document 1) containing a specific cationic surfactant, an ester oil, and silicones, a specific modified silicone, a polyhydric alcohol, a high molecular weight silicone, and a cation A hair conditioning composition containing an ionic surfactant (see Patent Document 2) has been proposed.
しかしながら、整髪剤において、コンディショニング効果を付与するために、シリコーン油、エステル油などの油剤を配合すると、べたつき感が増すだけでなく、整髪機能自体を損なってしまうといった問題がある。また、セット保持力が低下するだけでなく、再整髪時に望むヘアスタイルにセットできない(再整髪性に劣る)といった問題もある。このように、整髪剤に十分なコンディショニング効果を付与することは困難とされてきた。 However, when an oil agent such as silicone oil or ester oil is added to the hair styling agent to give a conditioning effect, not only the stickiness is increased, but also the hair styling function itself is impaired. Moreover, there is a problem that not only the set holding power is lowered, but also the hairstyle desired at the time of re-styling cannot be set (it is inferior in re-styling properties). Thus, it has been difficult to impart a sufficient conditioning effect to the hairdressing agent.
そこで、整髪機能を損なうことなく、コンディショニング効果を付与する手段として、乳化系の整髪剤とする試みがなされている。 Therefore, attempts have been made to use an emulsifying hair styling agent as a means for imparting a conditioning effect without impairing the hair styling function.
例えば、シリコーン化多糖化合物と、ポリエーテル変性シリコーンと、液状油分とを含む整髪化粧料(特許文献3を参照)、水溶性高分子と、室温で固形状の油剤と、室温で液状のエステル油と、室温で液状の環状シリコーン油とを含有する毛髪化粧料(特許文献4を参照)、部分架橋型オルガノポリシロキサン重合物と、シリコーン油と、水と、粉体とを含有する油中水型毛髪化粧料(特許文献5を参照)などが提案されている。 For example, hairdressing cosmetics (see Patent Document 3) containing a silicone-modified polysaccharide compound, a polyether-modified silicone, and a liquid oil, a water-soluble polymer, a solid oil at room temperature, and an ester oil that is liquid at room temperature And a water-in-oil containing a hair cosmetic containing a cyclic silicone oil that is liquid at room temperature (see Patent Document 4), a partially crosslinked organopolysiloxane polymer, a silicone oil, water, and a powder. Type hair cosmetics (see Patent Document 5) have been proposed.
しかしながら、これら試みに拠ってある程度の整髪機能を付与することはできるものの、従来の整髪剤と同等の整髪機能を発揮させるには至っていない。また、整髪機能を発揮させることに重きを置くと、十分なコンディショニング効果を付与することができないといった問題もある。 However, although some hair styling functions can be imparted based on these attempts, the hair styling functions equivalent to those of conventional hair styling agents have not been achieved. In addition, if the emphasis is placed on exerting the hair-styling function, there is a problem that a sufficient conditioning effect cannot be imparted.
従って、本発明の課題は、優れた延展性と、優れたコンディショニング性と優れた整髪性の三者を満足させることができる整髪用乳化組成物を提供することである。 Therefore, the subject of this invention is providing the emulsification composition for hairdressing which can satisfy the three of the outstanding spreadability, the outstanding conditioning property, and the outstanding hairdressing property.
本発明者が検討を重ねた結果、化粧品分野では製剤の安定化剤として用いられてきた疎水化無水ケイ酸を乳化組成物に配合することにより、意外にも、整髪保持力及び再整髪性といった優れた整髪効果が発揮されることを見出し、本発明を完成させた。 As a result of repeated studies by the inventor, surprisingly, by incorporating hydrophobized silicic anhydride that has been used as a formulation stabilizer in the cosmetics field into an emulsified composition, the hair styling retention and re-styling properties are unexpectedly achieved. The present inventors have found that an excellent hair styling effect is exhibited and completed the present invention.
即ち、本発明の要旨は、
(A)揮発性シリコーン油、(B)不揮発性シリコーン油、(C)ポリエーテル変性シリコーン、(D)疎水化無水ケイ酸及び(E)水を含有してなる整髪用乳化組成物に関するものである。
That is, the gist of the present invention is as follows.
(A) Volatile silicone oil, (B) Non-volatile silicone oil, (C) Polyether-modified silicone, (D) Hydrophobic silicic acid anhydride and (E) Water-emulsifying composition is there.
本発明の整髪用乳化組成物は、塗布時の延展性が良く、べたつき感のない優れたコンディショニング効果、所謂、滑らかさや潤い感を奏するとともに、整髪保持力及び再整髪性に優れた効果を奏する。 The emulsified composition for hair styling of the present invention has good spreading properties at the time of application and has an excellent conditioning effect without stickiness, so-called smoothness and moisturizing feeling, and also has an effect of excellent hair styling holding power and re-styling properties. .
(A)成分の揮発性シリコーン油としては、化粧品分野で公知のものを制限無く使用することができる。揮発性シリコーン油の具体例としては、オクタメチルシクロテトラシロキサン、デカメチルシクロペンタシロキサン、ドデカメチルシクロヘキサシロキサン、メチルシクロポリシロキサン等の環状シリコーン;オクタメチルトリシロキサン、テトラデカメチルヘキサシロキサン、25℃における粘度が例えば1mPa・s以上10mPa・s未満のメチルポリシロキサン等の鎖状シリコーン等が挙げられる。 As the volatile silicone oil of component (A), those known in the cosmetics field can be used without limitation. Specific examples of volatile silicone oils include cyclic silicones such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, methylcyclopolysiloxane; octamethyltrisiloxane, tetradecamethylhexasiloxane, 25 ° C. Examples thereof include chain silicones such as methylpolysiloxane having a viscosity of 1 mPa · s or more and less than 10 mPa · s.
(A)成分としては、これらの化合物を単独で用いてもよく、あるいは複数の化合物を併用してもよい。 As the component (A), these compounds may be used alone or a plurality of compounds may be used in combination.
組成物中の(A)成分の含有量としては、1〜50質量%が好ましく、5〜45質量%がより好ましく、10〜40質量%がさらに好ましい。使用感の観点から、該含有量は1質量%以上が好ましく、50質量%以下が好ましい。 As content of (A) component in a composition, 1-50 mass% is preferable, 5-45 mass% is more preferable, and 10-40 mass% is further more preferable. From the viewpoint of usability, the content is preferably 1% by mass or more, and more preferably 50% by mass or less.
(B)成分の不揮発性シリコーン油としては、化粧品分野で公知のものを制限無く使用することができる。不揮発性シリコーン油としては、25℃における粘度が例えば10mPa・s以上15,000,000mPa・s以下の鎖状シリコーン;アミノ変性シリコーン、カルボキシ変性シリコーン、脂肪酸変性シリコーン、アルコール変性シリコーン、脂肪族アルコール変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、アルキル変性シリコーン等の変性シリコーン(ただし、後述する(C)成分を除く)等が挙げられる。好適な(B)成分としては、優れたコンディショニング効果を付与する観点から、鎖状シリコーン、アミノ変性シリコーンが挙げられる。 As the nonvolatile silicone oil of component (B), those known in the cosmetics field can be used without limitation. As the non-volatile silicone oil, a chain silicone having a viscosity at 25 ° C. of, for example, 10 mPa · s to 15,000,000 mPa · s; amino-modified silicone, carboxy-modified silicone, fatty acid-modified silicone, alcohol-modified silicone, aliphatic alcohol-modified Examples include silicones, epoxy-modified silicones, fluorine-modified silicones, alkyl-modified silicones and other modified silicones (excluding the component (C) described later). Suitable components (B) include chain silicones and amino-modified silicones from the viewpoint of imparting an excellent conditioning effect.
鎖状シリコーンの具体例としては、25℃における粘度が例えば10mPa・s以上6,000mPa・s未満のメチルポリシロキサン、25℃における粘度が例えば6,000mPa・s以上15,000,000mPa・s以下の高重合メチルポリシロキサン、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、ジメチコノール等が挙げられる。アミノ変性シリコーンの具体例としては、アミノプロピルメチルシロキサン・ジメチルシロキサン共重合体、アミノエチルアミノプロピルシロキサン・ジメチルシロキサン共重合体、アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体等が挙げられる。 Specific examples of the chain silicone include methylpolysiloxane having a viscosity at 25 ° C. of, for example, 10 mPa · s to less than 6,000 mPa · s, and a viscosity at 25 ° C. of, for example, 6,000 mPa · s to 15,000,000 mPa · s. And highly polymerized methylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, and dimethiconol. Specific examples of the amino-modified silicone include aminopropylmethylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylsiloxane / dimethylsiloxane copolymer, aminoethylaminopropylmethylsiloxane / dimethylsiloxane copolymer, and the like.
(B)成分としては、これらの化合物を単独で用いてもよく、あるいは複数の化合物を併用してもよい。 As the component (B), these compounds may be used alone or a plurality of compounds may be used in combination.
組成物中の(B)成分の含有量としては、0.5〜50質量%が好ましく、1〜40質量%がより好ましく、2〜30質量%がさらに好ましい。十分なコンディショニング効果を付与する観点から、該含有量は0.5質量%以上が好ましく、整髪効果を十分に発揮させる観点から、該含有量は50質量%以下が好ましい。 As content of (B) component in a composition, 0.5-50 mass% is preferable, 1-40 mass% is more preferable, 2-30 mass% is further more preferable. From the viewpoint of imparting a sufficient conditioning effect, the content is preferably 0.5% by mass or more, and from the viewpoint of sufficiently exhibiting the hair-styling effect, the content is preferably 50% by mass or less.
(A)成分と(B)成分の組成物中の総含有量としては、20〜60質量%が好ましく、20〜30質量%がより好ましい。コンディショニング効果を与える観点から、上記総含有量は20質量%以上が好ましく、整髪効果を十分に発揮させる観点から、上記総含有量は60質量%以下が好ましい。 As total content in the composition of (A) component and (B) component, 20-60 mass% is preferable and 20-30 mass% is more preferable. The total content is preferably 20% by mass or more from the viewpoint of providing a conditioning effect, and the total content is preferably 60% by mass or less from the viewpoint of sufficiently exhibiting the hair-styling effect.
さらに、(A)成分と(B)成分との組成物中の質量比は特に制限されないが、使用感の観点から、(A)/(B)=100/1〜20/1の範囲が好ましい。 Furthermore, the mass ratio in the composition of the component (A) and the component (B) is not particularly limited, but from the viewpoint of usability, a range of (A) / (B) = 100/1 to 20/1 is preferable. .
(C)成分のポリエーテル変性シリコーンは乳化作用を有するので、本発明において乳化剤として用いられる。(C)成分の具体例としては、例えば、ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体、ポリオキシエチレンメチルポリシロキサン共重合体等が挙げられる。(C)成分のHLB値は、乳化させることができるのであれば特に限定されないが、例えば1〜8の範囲のものを用いることが好ましく、1〜6がより好ましく、1〜4がさらに好ましい。 Since the polyether-modified silicone as component (C) has an emulsifying action, it is used as an emulsifier in the present invention. Specific examples of the component (C) include poly (oxyethylene / oxypropylene) methyl polysiloxane copolymer, polyoxyethylene methyl polysiloxane copolymer, and the like. Although the HLB value of (C) component will not be specifically limited if it can be emulsified, For example, it is preferable to use the thing of the range of 1-8, 1-6 are more preferable, and 1-4 are more preferable.
なお、(C)成分は、市販品を用いることもできる。ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体の市販品としては、例えば、BY22−008M(HLB:2)、BY11−030(HLB:3)、FZ−2233(HLB:3)(商品名、何れも東レ・ダウコーニング社製)等が挙げられる。また、ポリオキシエチレンメチルポリシロキサン共重合体の市販品としては、例えば、ES−5612 Formulation Aid(HLB:4)(商品名、東レ・ダウコーニング社製)、KF6015(HLB:4.5)KF6017(HLB:4.5)(商品名、何れも信越化学工業社製)等が挙げられる。 In addition, a commercial item can also be used for (C) component. Examples of commercially available poly (oxyethylene / oxypropylene) methylpolysiloxane copolymers include BY22-008M (HLB: 2), BY11-030 (HLB: 3), and FZ-2233 (HLB: 3) (product). Name, all manufactured by Toray Dow Corning). Moreover, as a commercial item of a polyoxyethylene methyl polysiloxane copolymer, ES-5612 Formulation Aid (HLB: 4) (brand name, the Toray Dow Corning company make), KF6015 (HLB: 4.5) KF6017, for example. (HLB: 4.5) (trade name, all manufactured by Shin-Etsu Chemical Co., Ltd.) and the like.
(C)成分としては、これらの化合物を単独で用いてもよく、あるいは複数の化合物を併用してもよい。 As the component (C), these compounds may be used alone or a plurality of compounds may be used in combination.
(C)成分の組成物中の含有量としては、0.01〜15質量%が好ましく、0.05〜10質量%がより好ましく、0.1〜5質量%がさらに好ましい。乳化組成物を得る観点から、上記含有量は0.01質量%以上が好ましく、適度な油性感とする観点から、上記含有量は15質量%以下が好ましい。 As content in the composition of (C) component, 0.01-15 mass% is preferable, 0.05-10 mass% is more preferable, 0.1-5 mass% is further more preferable. From the viewpoint of obtaining an emulsified composition, the content is preferably 0.01% by mass or more, and from the viewpoint of achieving an appropriate oily feeling, the content is preferably 15% by mass or less.
組成物に整髪効果を付与する観点から、本発明では(D)成分として疎水化無水ケイ酸を用いる。疎水化無水ケイ酸は、後述する処理剤で無水ケイ酸に疎水化処理が施された粉体である。 In the present invention, hydrophobized silicic anhydride is used as the component (D) from the viewpoint of imparting a hair styling effect to the composition. Hydrophobic silicic anhydride is a powder obtained by subjecting silicic anhydride to a hydrophobization treatment with a treatment agent described later.
疎水化処理に用いられる処理剤としては、化粧品分野で公知のものを制限無く使用することができる。処理剤の具体例としては、メチルトリクロロシラン、ジメチルジクロロシラン、トリメチルクロロシラン、ヘキサメチルジシラザン、メチルトリアルコキシシラン、ジメチルジアルコキシシラン、トリメチルアルコキシシラン、エチルトリクロロシラン、プロピルトリクロロシラン、ヘキシルトリクロロシラン、長鎖アルキルトリクロロシラン、エチルトリアルコキシシラン、プロピルトリアルコキシシラン、ヘキシルトリアルコキシシラン、長鎖アルキルトリアルコキシシラン、メタクリルシラン、フルオロアルキルシラン、ペルフルオロアルキルシラン等の有機シリル化合物;ジメチルポリシロキサン(シリコーンオイル)、メチルフェニルポリシロキサン、メチルハイドロジェンポリシロキサン、アミノ変性シリコーン等のシリコーン化合物等が挙げられる。 As the treating agent used for the hydrophobizing treatment, those known in the cosmetics field can be used without limitation. Specific examples of the treating agent include methyltrichlorosilane, dimethyldichlorosilane, trimethylchlorosilane, hexamethyldisilazane, methyltrialkoxysilane, dimethyldialkoxysilane, trimethylalkoxysilane, ethyltrichlorosilane, propyltrichlorosilane, hexyltrichlorosilane, Organosilyl compounds such as long-chain alkyltrichlorosilane, ethyltrialkoxysilane, propyltrialkoxysilane, hexyltrialkoxysilane, long-chain alkyltrialkoxysilane, methacrylsilane, fluoroalkylsilane, perfluoroalkylsilane; dimethylpolysiloxane (silicone oil) ), Silicones such as methylphenylpolysiloxane, methylhydrogenpolysiloxane, amino-modified silicone Compounds, and the like.
疎水化処理方法としては、疎水化無水ケイ酸の疎水化処理を実施することができる方法であれば、特に限定されること無く公知の方法を採用することができるが、例えば、液相法、気相法、オートクレーブ法等を例示することができる。 As the hydrophobizing treatment method, any known method can be adopted without particular limitation as long as the hydrophobizing treatment of hydrophobized silicic acid can be carried out. For example, a liquid phase method, A gas phase method, an autoclave method, etc. can be illustrated.
疎水化無水ケイ酸の具体例としては、ジメチルシロキシル化無水ケイ酸、トリメチルシロキシル化無水ケイ酸、シリコーンオイル処理無水ケイ酸、メタクリルシロキシル化無水ケイ酸及びオクチルシロキシル化無水ケイ酸等が挙げられる。疎水化無水ケイ酸としては、これらの化合物を一種で用いても良く、あるいは二種以上を併用しても良い。 Specific examples of hydrophobized silicic anhydride include dimethylsiloxylated silicic anhydride, trimethylsiloxylated silicic anhydride, silicone oil-treated silicic anhydride, methacrylsiloxylated silicic anhydride, octylsiloxylated silicic anhydride, etc. Is mentioned. As the hydrophobized silicic anhydride, these compounds may be used alone or in combination of two or more.
疎水化無水ケイ酸の大きさは特に限定されないが、例えば、平均一次粒径として、5〜45nmのものが好ましく、5〜15nmのものがより好ましい。ここで、平均一次粒径は、レーザー回析型粒度分布計を用い、レーザー回折・散乱法に基づいて求められる値である。 The size of the hydrophobized silicic anhydride is not particularly limited. For example, the average primary particle size is preferably 5 to 45 nm, more preferably 5 to 15 nm. Here, the average primary particle size is a value obtained based on a laser diffraction / scattering method using a laser diffraction type particle size distribution meter.
(D)成分の組成物中の含有量としては、0.1〜15質量%が好ましく、0.5〜10質量%がより好ましく、1〜5質量%がさらに好ましい。組成物に整髪効果を与える観点から、上記含有量は0.1質量%以上が好ましく、コンディショニング効果の低減を抑える観点から、上記含有量は15質量%以下が好ましい。 (D) As content in the composition of a component, 0.1-15 mass% is preferable, 0.5-10 mass% is more preferable, 1-5 mass% is further more preferable. The content is preferably 0.1% by mass or more from the viewpoint of giving a hair-styling effect to the composition, and the content is preferably 15% by mass or less from the viewpoint of suppressing the reduction of the conditioning effect.
さらに、整髪効果とコンディショニング効果の両方を兼ね備える観点から、(A)成分、(B)成分及び(D)成分が下記の関係を示すことが望ましい。具体的には、質量比として、((A)+(B))/(D)=4/1〜200/1が好ましく、10/1〜100/1がより好ましく、20/1〜50/1がさらに好ましい。 Furthermore, it is desirable that the component (A), the component (B), and the component (D) show the following relationship from the viewpoint of combining both the hair styling effect and the conditioning effect. Specifically, the mass ratio is preferably ((A) + (B)) / (D) = 4/1 to 200/1, more preferably 10/1 to 100/1, and 20/1 to 50 /. 1 is more preferable.
本発明においては、(E)成分としての水が用いられる。水の組成物中の含有量としては、20〜80質量%が好ましく、30〜80質量%がより好ましく、40〜80質量%がさらに好ましい。 In the present invention, water as the component (E) is used. As content in the composition of water, 20-80 mass% is preferable, 30-80 mass% is more preferable, 40-80 mass% is further more preferable.
さらに本発明の組成物には、化粧品分野で汎用されている種々の成分、例えば、エチレングリコール、ジエチレングリコール、トリエチレングリコール、ポリエチレングリコール、プロピレングリコール、ジプロピレングリコール、イソプレングリコール、1,3−ブチレングリコール、1,2−ブタンジオール、1,2−ペンタンジオール、1,2−ヘキサンジオール、1,2−オクタンジオール、1,2−デカンジオールなどの多価アルコール;球状ポリエチレン、結晶セルロースなど上記(D)成分以外の粉体;デキストリン脂肪酸エステル、増粘性高分子などの増粘性成分;固形ロウ類、油脂、高級脂肪酸などの油性成分;陰イオン性界面活性剤、陽イオン性界面活性剤、両性界面活性などの界面活性剤;無機顔料、有機顔料、パール顔料などの粉体;動植物由来抽出物、紫外線吸収剤、金属封鎖剤、ビタミン類、酸化防止剤、防腐・殺菌剤、抗炎症剤、抗フケ剤、着色剤、増粘剤、清涼剤、皮膜形成剤、pH調整剤、香料等を含有していていも構わない。かかる成分の組成物中の含有量は、例えば0.01〜50質量%が好ましい。 Further, the composition of the present invention includes various components widely used in the cosmetic field, such as ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, isoprene glycol, 1,3-butylene glycol. , 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol and other polyhydric alcohols; spherical polyethylene, crystalline cellulose and the like (D ) Powders other than ingredients; Thickening ingredients such as dextrin fatty acid esters and thickening polymers; Oily ingredients such as solid waxes, fats and oils, higher fatty acids; Anionic surfactants, cationic surfactants, amphoteric interfaces Surfactant such as activity; inorganic pigment, organic pigment, par Powders such as pigments; extracts from animals and plants, UV absorbers, metal sequestering agents, vitamins, antioxidants, antiseptics / bactericides, anti-inflammatory agents, anti-dandruff agents, coloring agents, thickeners, refreshing agents, films It may contain a forming agent, a pH adjuster, a fragrance and the like. The content of such components in the composition is preferably 0.01 to 50% by mass, for example.
本発明の組成物の調製方法は特に限定されるものではなく、各原料を公知の混合装置で混合することにより、本発明の組成物を調製することができる。また、本発明の乳化組成物は、所望の効果が十分に発揮されるのであれば、乳化のタイプは油中水型(W/O型)であっても、水中油型(O/W型)であっても特に限定されないが、使用感の観点から、油中水型(W/O型)の形態とすることがより好ましい。 The preparation method of the composition of this invention is not specifically limited, The composition of this invention can be prepared by mixing each raw material with a well-known mixing apparatus. In addition, the emulsified composition of the present invention has an oil-in-water type (O / W type) even if the type of emulsification is a water-in-oil type (W / O type) as long as the desired effect is sufficiently exhibited ) Is not particularly limited, but is preferably a water-in-oil type (W / O type) from the viewpoint of usability.
(試料の調製1)
表1及び表2に記した組成に従い、実施例1〜5及び比較例1〜4の各試料を調製し、下記評価に供した。結果をそれぞれ表1及び表2に併記する。尚、評価はすべて、23℃、湿度60%の恒温恒湿の一定条件下で実施した。表中の組成の値はいずれも質量%である。((A)+(B))/(D)の数値に関して、表中では分母の記載(/1)を省略した。
(Sample preparation 1)
Each sample of Examples 1-5 and Comparative Examples 1-4 was prepared according to the composition described in Table 1 and Table 2, and it used for the following evaluation. The results are shown in Table 1 and Table 2, respectively. In addition, all evaluation was implemented on the constant conditions of constant temperature and humidity of 23 degreeC and 60% of humidity. All values of composition in the table are mass%. Regarding the numerical value of ((A) + (B)) / (D), the denominator (/ 1) is omitted in the table.
(試験例1:「延展性」の評価)
評価パネル20名により、23℃、湿度60%の恒温恒湿下で一晩放置した毛束(長さ10cm、幅0.8cm、重量1g)に各実施例及び各比較例で得られた試料を0.4g塗布した後、指先でのばして毛束の厚みを均一にした。次いで、各試料の塗布時の「延展性」について、下記の評価基準に従って官能評価した。
(Test Example 1: Evaluation of “spreadability”)
Samples obtained in each example and comparative example on a hair bundle (length 10 cm, width 0.8 cm, weight 1 g) left overnight under constant temperature and humidity of 23 ° C. and humidity 60% by 20 evaluation panels After applying 0.4 g of the hair, it was extended with a fingertip to make the thickness of the hair bundle uniform. Next, sensory evaluation was performed according to the following evaluation criteria with respect to “spreadability” at the time of application of each sample.
<延展性の評価基準>
◎:20名中17名以上が延展性に優れると回答
○:20名中13〜16名が延展性に優れると回答
△:20名中9〜12名が延展性に優れると回答
×:20名中8名以下が延展性に優れると回答
<Evaluation criteria for spreadability>
A: Reply if 17 or more out of 20 people are excellent in spreadability ○: Reply if 13-16 out of 20 people are excellent in spreadability Δ: Reply if 9-12 out of 20 people are excellent in spreadability ×: 20 8 or less of the respondents say they are excellent in spreadability
(試験例2:「べたつき感」、「滑らかさ」及び「潤い感」の評価)
同評価パネル20名により、試験例1の評価30分後の毛束の「べたつき感」、「滑らかさ」及び「潤い感」について、下記の評価基準に従って官能評価した。
(Test Example 2: Evaluation of “feel of stickiness”, “smoothness” and “feel of moisture”)
By the 20 evaluation panels, the “stickiness”, “smoothness” and “moistness” of the hair bundle 30 minutes after the evaluation of Test Example 1 were subjected to sensory evaluation according to the following evaluation criteria.
<べたつき感の評価基準>
◎:20名中17名以上がべたつき感はないと回答
○:20名中13〜16名がべたつき感はないと回答
△:20名中9〜12名がべたつき感はないと回答
×:20名中8名以下がべたつき感はないと回答
<Evaluation criteria for stickiness>
◎: 17 or more of 20 people answered that there was no stickiness ○: 13-16 of 20 people answered that there was no stickiness △: 9-12 of 20 people answered that they did not feel sticky ×: 20 8 or less of the names responded that there was no stickiness
<滑らかさの評価基準>
◎:20名中17名以上が滑らかさがあると回答
○:20名中13〜16名が滑らかさがあると回答
△:20名中9〜12名が滑らかさがあると回答
×:20名中8名以下が滑らかさがあると回答
<Evaluation criteria for smoothness>
A: When 17 or more out of 20 people are smooth, ○: When 13-16 of 20 people are smooth, Δ: When 9-12 out of 20 people are smooth, ×: 20 8 or less of the respondents say they are smooth
<潤い感の評価基準>
◎:20名中17名以上が潤い感に優れると回答
○:20名中13〜16名が潤い感に優れると回答
△:20名中9〜12名が潤い感に優れると回答
×:20名中8名以下が潤い感に優れると回答
<Evaluation criteria for moisture>
◎: Reply if 17 or more out of 20 people are excellent in moist feeling ○: Reply if 13 to 16 out of 20 people are excellent in moist feeling △: Reply if 9 to 12 out of 20 people are excellent in moist feeling ×: 20 8 or less of the names responded that they were excellent in moisture
(試験例3:「整髪保持力」及び「再整髪性」の評価)
同評価パネル20名により、各実施例及び各比較例で得られた試料をウィッグ(レッスンマネキン:ユーカリジャパン社製)を用いて使用してもらい、「整髪保持力」及び「再整髪性」を下記の評価基準に従って官能評価した。
(Test Example 3: Evaluation of “hair-styling retention” and “re-hair-styling”)
By using 20 evaluation panels, the samples obtained in each example and each comparative example were used using a wig (Lesson Mannequin: manufactured by Eucalyptus Japan Co., Ltd.). Sensory evaluation was performed according to the following evaluation criteria.
尚、整髪保持力の評価は、毛髪を毛先の方からにぎる操作を10回行い、形成されたスタイルに、にぎった形がくっきりと保持されているものを整髪保持力が良いとして評価を行った。また、再整髪性の評価は、整髪保持力の評価後、毛髪を10回コームで梳いた後、再度、同様の評価を行った。 The hair styling retention strength is evaluated by performing the operation of squeezing the hair from the tip of the hair 10 times, and if the squeezed shape is clearly held in the formed style, the hair styling retention strength is good. It was. Moreover, the evaluation of the re-styling property was carried out again after evaluating the hair holding power, after combing the hair 10 times with a comb.
<整髪保持力の評価基準>
◎:20名中17名以上が整髪保持力に優れると回答
○:20名中13〜16名が整髪保持力に優れると回答
△:20名中9〜12名が整髪保持力に優れると回答
×:20名中8名以下が整髪保持力に優れると回答
<Evaluation criteria for hair styling retention power>
◎: 17 or more out of 20 responded that they have excellent hair styling retention ability ○: 13 to 16 out of 20 responded that they had excellent hair styling retention ability △: 9 to 12 out of 20 responded that they had excellent hair styling retention ability ×: 8 or less out of 20 responded that they have excellent hair holding ability
<再整髪性の評価基準>
◎:20名中17名以上が再整髪性に優れると回答
○:20名中13〜16名が再整髪性に優れると回答
△:20名中9〜12名が再整髪性に優れると回答
×:20名中8名以下が再整髪性に優れると回答
<Evaluation criteria for re-styling>
A: Reply that 17 or more of 20 people are excellent in re-styling ○: Reply that 13 to 16 in 20 people are excellent in re-styling Δ: Responding that 9 to 12 in 20 people are excellent in re-styling ×: 8 or less out of 20 responded that they have excellent hair styling
表中の各原料の詳細は次の通りである。
・デカメチルシクロペンタシロキサン(信越化学社製、商品名:KF−995)
・ドデカメチルシクロヘキサシロキサン(東レ・ダウコーニング社製、商品名:DC246 Fluid)
・メチルポリシロキサン(20cs)(東レ・ダウコーニング社製、商品名:SH200C−20cs)
・アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体(東レ・ダウコーニング社製、商品名:SF 8452 C)
・ジメチコノール(東レ・ダウコーニング社製、商品名:1501 Fluid)
・ポリ(オキシエチレン・オキシプロピレン)メチルポリシロキサン共重合体(東レ・ダウコーニング社製、商品名:BY22−008M、HLB:2))
・ポリオキシエチレンメチルポリシロキサン共重合体(東レ・ダウコーニング社製、商品名:ES−5612 Formulation Aid(HLB:4))
・トリメチルシロキシル化無水ケイ酸(EVONIK社製、商品名:AEROSIL RX300、平均粒径:7nm)
・シリコーンオイル処理無水ケイ酸(EVONIK社製、商品名:AEROSIL R202、平均粒径:14nm)
・オクチルシロキシル化無水ケイ酸(EVONIK社製、商品名:AEROSIL R−805、平均粒径:12nm)
Details of each raw material in the table are as follows.
Decamethylcyclopentasiloxane (manufactured by Shin-Etsu Chemical Co., Ltd., trade name: KF-995)
・ Dodecamethylcyclohexasiloxane (made by Toray Dow Corning Co., Ltd., trade name: DC246 Fluid)
・ Methylpolysiloxane (20cs) (manufactured by Dow Corning Toray, trade name: SH200C-20cs)
・ Aminoethylaminopropylmethylsiloxane ・ dimethylsiloxane copolymer (manufactured by Dow Corning, Toray, trade name: SF8452C)
・ Dimethiconol (made by Toray Dow Corning Co., Ltd., trade name: 1501 Fluid)
・ Poly (oxyethylene / oxypropylene) methylpolysiloxane copolymer (manufactured by Toray Dow Corning, trade name: BY22-008M, HLB: 2))
・ Polyoxyethylene methylpolysiloxane copolymer (manufactured by Dow Corning Toray Co., Ltd., trade name: ES-5612 Formulation Aid (HLB: 4))
Trimethylsiloxylated silicic acid anhydride (manufactured by EVONIK, trade name: AEROSIL RX300, average particle size: 7 nm)
Silicone oil-treated silicic acid anhydride (manufactured by EVONIK, trade name: AEROSIL R202, average particle size: 14 nm)
-Octylsiloxylated silicic anhydride (manufactured by EVONIK, trade name: AEROSIL R-805, average particle size: 12 nm)
上記のように、本発明品は優れたコンディショニング性と優れた整髪性を両立することができるだけでなく、延展性にも優れた組成物であることが分かった。 As described above, it was found that the product of the present invention is a composition that not only has excellent conditioning properties and excellent hair styling properties, but also has excellent spreadability.
一方、各比較例に示されるように、(A)成分を欠く組成ではべたつき感が強く(比較例1)、(B)成分を欠く組成では滑らかさ及び潤い感に劣り(比較例2)、(D)成分を欠く組成では整髪保持力及び再整髪性に劣ることが分かった(比較例4)。さらに、比較例3は(C)成分を含有していないため、水相と油相とが分離してしまい、乳化組成物として得ることができなかった。そのため、比較例3についての評価をすることができなかった。 On the other hand, as shown in each comparative example, the composition lacking the component (A) is strongly sticky (Comparative Example 1), and the composition lacking the component (B) is inferior in smoothness and moisture (Comparative Example 2). It was found that the composition lacking the component (D) was inferior in hair holding ability and re-styling (Comparative Example 4). Furthermore, since Comparative Example 3 did not contain the component (C), the water phase and the oil phase were separated, and could not be obtained as an emulsified composition. Therefore, it was not possible to evaluate Comparative Example 3.
(参考例1、2)
表3に記した組成に従い、参考例1及び2の各試料を調製しようとした。
(Reference Examples 1 and 2)
According to the composition described in Table 3, each sample of Reference Examples 1 and 2 was prepared.
しかしながら、参考例1及び2の混合物は、水相と油相とが分離してしまい、乳化組成物として得ることができなかった。そのため、参考例1及び2についての評価をすることができなかった。 However, the mixture of Reference Examples 1 and 2 could not be obtained as an emulsified composition because the water phase and the oil phase were separated. Therefore, it was not possible to evaluate Reference Examples 1 and 2.
本発明の整髪用乳化組成物は、優れた延展性と、優れたコンディショニング性と優れた整髪性の三者を満足させることができる整髪剤として使用することができる。 The emulsified composition for hair styling of the present invention can be used as a hair styling agent that can satisfy three properties of excellent spreadability, excellent conditioning properties, and excellent hair styling properties.
Claims (3)
質量比として、((A)+(B))/(D)=10/1〜100/1
を満たす、請求項1又は2に記載の組成物。
The (A) component, the (B) component, and the (D) component have the following relationship:
As a mass ratio, ((A) + (B)) / (D) = 10/1 to 100/1
The composition of Claim 1 or 2 satisfy | filling .
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