JP5575660B2 - ブローモールド成形チューブからステントを製作する方法 - Google Patents
ブローモールド成形チューブからステントを製作する方法 Download PDFInfo
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- JP5575660B2 JP5575660B2 JP2010538092A JP2010538092A JP5575660B2 JP 5575660 B2 JP5575660 B2 JP 5575660B2 JP 2010538092 A JP2010538092 A JP 2010538092A JP 2010538092 A JP2010538092 A JP 2010538092A JP 5575660 B2 JP5575660 B2 JP 5575660B2
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2/00—Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
- A61F2/82—Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
- A61F2/86—Stents in a form characterised by the wire-like elements; Stents in the form characterised by a net-like or mesh-like structure
- A61F2/90—Stents in a form characterised by the wire-like elements; Stents in the form characterised by a net-like or mesh-like structure characterised by a net-like or mesh-like structure
- A61F2/91—Stents in a form characterised by the wire-like elements; Stents in the form characterised by a net-like or mesh-like structure characterised by a net-like or mesh-like structure made from perforated sheet material or tubes, e.g. perforated by laser cuts or etched holes
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- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6409—Thermal conditioning of preforms
- B29C49/6436—Thermal conditioning of preforms characterised by temperature differential
- B29C49/6445—Thermal conditioning of preforms characterised by temperature differential through the preform length
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- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C49/783—Measuring, controlling or regulating blowing pressure
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/78—Measuring, controlling or regulating
- B29C49/786—Temperature
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2230/00—Geometry of prostheses classified in groups A61F2/00 - A61F2/26 or A61F2/82 or A61F9/00 or A61F11/00 or subgroups thereof
- A61F2230/0002—Two-dimensional shapes, e.g. cross-sections
- A61F2230/0028—Shapes in the form of latin or greek characters
- A61F2230/0054—V-shaped
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/46—Component parts, details or accessories; Auxiliary operations characterised by using particular environment or blow fluids other than air
- B29C2049/4602—Blowing fluids
- B29C2049/4605—Blowing fluids containing an inert gas, e.g. helium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/46—Component parts, details or accessories; Auxiliary operations characterised by using particular environment or blow fluids other than air
- B29C2049/4602—Blowing fluids
- B29C2049/4605—Blowing fluids containing an inert gas, e.g. helium
- B29C2049/4608—Nitrogen
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
- B29C2049/4838—Moulds with incorporated heating or cooling means for heating moulds or mould parts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
- B29C2049/4838—Moulds with incorporated heating or cooling means for heating moulds or mould parts
- B29C2049/4846—Moulds with incorporated heating or cooling means for heating moulds or mould parts in different areas of the mould at different temperatures, e.g. neck, shoulder or bottom
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C49/4823—Moulds with incorporated heating or cooling means
- B29C2049/4854—Heating or cooling from the inside of the cavity, e.g. using flames or other means
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/48—Moulds
- B29C2049/4879—Moulds characterised by mould configurations
- B29C2049/4894—With at least a part of the mould cavity formed by a cylindrical mould
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/079—Auxiliary parts or inserts
- B29C2949/08—Preforms made of several individual parts, e.g. by welding or gluing parts together
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/04—Extrusion blow-moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
- B29C49/06—Injection blow-moulding
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6604—Thermal conditioning of the blown article
- B29C49/6605—Heating the article, e.g. for hot fill
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/42—Component parts, details or accessories; Auxiliary operations
- B29C49/64—Heating or cooling preforms, parisons or blown articles
- B29C49/6604—Thermal conditioning of the blown article
- B29C49/6605—Heating the article, e.g. for hot fill
- B29C49/66055—Heating the article, e.g. for hot fill using special pressurizing during the heating, e.g. in order to control the shrinking
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/258—Tubular
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/004—Semi-crystalline
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0037—Other properties
- B29K2995/0059—Degradable
- B29K2995/006—Bio-degradable, e.g. bioabsorbable, bioresorbable or bioerodible
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/753—Medical equipment; Accessories therefor
- B29L2031/7532—Artificial members, protheses
- B29L2031/7534—Cardiovascular protheses
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Physics & Mathematics (AREA)
- Heart & Thoracic Surgery (AREA)
- Animal Behavior & Ethology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Transplantation (AREA)
- Optics & Photonics (AREA)
- Vascular Medicine (AREA)
- Life Sciences & Earth Sciences (AREA)
- Cardiology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Thermal Sciences (AREA)
- Materials For Medical Uses (AREA)
- Media Introduction/Drainage Providing Device (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Description
110 ストラット(ステント)
120 ストラット(直線状部分)(ステント)
130 ストラット(屈曲要素)(ステント)
140 ストラット(屈曲要素)(ステント)
150 ストラット(屈曲要素)(ステント)
160 軸(ステント)
200 チューブ
205 外径(チューブ)
210 内径(チューブ)
215 外側表面(チューブ)
220 円筒軸(チューブ)
300 ブローモールド成形システム
301 ポリマーチューブ
305 変形前の外径(ポリマーチューブ)
310 モールド型
315 内径(モールド型)
320 遠位端部(ポリマーチューブ)
321 近位端部(ポリマーチューブ)
325 矢印(流体の送り方向)
330 ノズル
335 矢印(加熱した流体の流れ方向/ノズル)
340 矢印(加熱した流体の流れ方向/ノズル)
355 矢印(加熱した流体の流れ方向/ノズル)
360 構造部材(ノズル)
365 矢印(平行移動方向/ノズル)
367 矢印(平行移動方向/ノズル)
370 変形したセクション(ポリマーチューブ)
372 変形中のセクション(ポリマーチューブ)
380 矢印(半径方向の変形)
382 矢印(軸方向の変形)
Claims (7)
- ポリマーチューブが周囲よりも高い内部圧力を有し、前記ポリマーチューブが前記ポリマーチューブの軸に沿って加熱されるにつれて前記ポリマーチューブの半径方向の変形が前記軸に沿って伝播するように、前記変形したポリマーチューブからステントを製作する際に使用される前記ポリマーチューブを半径方向に変形させるステップと;
前記ポリマーチューブから製作されるステントの選択された破壊耐性を提供するために、前記ポリマーチューブの温度を制御するステップであって、前記選択された破壊耐性を提供する前記ポリマーチューブのモルフォロジーを提供するように前記温度を制御し、前記温度は前記ポリマーの結晶核形成速度が前記ポリマーの結晶成長速度よりも大きい範囲内となるように、前記ポリマーチューブの温度を制御するステップと;
前記変形したポリマーチューブからステントを製作するステップとを備え;
更に、前記ポリマーチューブが前記半径方向に拡張するように加熱するために前記ポリマーチューブの軸に沿って熱源を移動させるステップであって、前記ポリマーチューブの加熱および前記内部圧力の増大が前記ポリマーチューブの半径方向の拡張を可能とする、前記ポリマーチューブの軸に沿って熱源を移動させるステップと;
前記選択された破壊耐性を提供するために、前記内部圧力および前記熱源の移動速度を更に制御するステップとを備え;
前記ポリマーチューブはポリ(L−ラクチド)チューブであり、
前記内部圧力は827kPa乃至896kPaの範囲にまで増大され、
前記熱源の移動速度は、0.5mm/s乃至0.7mm/sの範囲であり、
前記ポリ(L−ラクチド)チューブは摂氏82度乃至摂氏104度の範囲にまで加熱され、
前記内部圧力は半径方向の変形速度をもたらし、前記熱源の移動速度は軸方向の変形速度をもたらし、前記変形速度が、内部応力を減少させて配向した分子構造の発達を促進する、
ステントを製作する方法。 - 前記温度を制御して、分散させた結晶領域を有する非晶性マトリックスにより構成された前記変形したポリマーチューブのモルフォロジーを提供する、
請求項1に記載の方法。 - 前記結晶領域は、10マイクロメートル未満の結晶サイズにより構成された、
請求項2に記載の方法。 - 前記温度を制御して、40%未満の結晶化度により構成された前記変形したポリマーチューブのモルフォロジーを提供する、
請求項1乃至請求項3のいずれか一項に記載の方法。 - 前記ステントの選択された破壊耐性は、前記半径方向に拡張された場合の前記ステントの破壊耐性を含む、
請求項1乃至請求項4のいずれか一項に記載の方法。 - 前記温度を制御して、50%の結晶化度により構成された前記変形したポリマーチューブのモルフォロジーを提供する、
請求項1乃至請求項3のいずれか一項に記載の方法。 - 前記温度を制御して、分散させた結晶領域を有する非晶性マトリックスにより構成された前記変形したポリマーチューブのモルフォロジーを提供し、前記結晶領域は、15マイクロメートル未満の結晶サイズにより構成された、
請求項1に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/001,777 | 2007-12-11 | ||
US12/001,777 US8268228B2 (en) | 2007-12-11 | 2007-12-11 | Method of fabricating stents from blow molded tubing |
US26748108A | 2008-11-07 | 2008-11-07 | |
US12/267,481 | 2008-11-07 | ||
PCT/US2008/086054 WO2009076350A1 (en) | 2007-12-11 | 2008-12-09 | Method of fabricating a stent from blow molded tubing |
Publications (3)
Publication Number | Publication Date |
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JP2011505982A JP2011505982A (ja) | 2011-03-03 |
JP2011505982A5 JP2011505982A5 (ja) | 2012-01-26 |
JP5575660B2 true JP5575660B2 (ja) | 2014-08-20 |
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ID=40418921
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Application Number | Title | Priority Date | Filing Date |
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JP2010538092A Expired - Fee Related JP5575660B2 (ja) | 2007-12-11 | 2008-12-09 | ブローモールド成形チューブからステントを製作する方法 |
Country Status (6)
Country | Link |
---|---|
EP (3) | EP2397306B1 (ja) |
JP (1) | JP5575660B2 (ja) |
AT (1) | ATE523317T1 (ja) |
ES (1) | ES2585254T3 (ja) |
HK (1) | HK1190363A1 (ja) |
WO (1) | WO2009076350A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8012402B2 (en) | 2008-08-04 | 2011-09-06 | Abbott Cardiovascular Systems Inc. | Tube expansion process for semicrystalline polymers to maximize fracture toughness |
EP1885281B1 (en) | 2005-05-24 | 2019-02-13 | Inspire M.D Ltd. | Stent apparatuses for treatment via body lumens |
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JP2007160102A (ja) * | 2005-12-13 | 2007-06-28 | Cordis Corp | 可撓性コネクターの選択された領域の中に修飾された分子構造を有するポリマーステント |
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2008
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EP2234788A1 (en) | 2010-10-06 |
EP2397306B1 (en) | 2014-09-24 |
ATE523317T1 (de) | 2011-09-15 |
EP2647484B1 (en) | 2016-06-01 |
HK1190363A1 (zh) | 2014-07-04 |
EP2397306A2 (en) | 2011-12-21 |
JP2011505982A (ja) | 2011-03-03 |
WO2009076350A1 (en) | 2009-06-18 |
EP2234788B1 (en) | 2011-09-07 |
EP2397306A3 (en) | 2013-03-27 |
EP2647484A1 (en) | 2013-10-09 |
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