JP5562816B2 - Stick-like emulsified composition - Google Patents

Description

The present invention relates to a stick-like emulsified composition having a whitening effect and excellent in storage stability and use feeling. More specifically, the present invention relates to a stick-like emulsified composition having good stability that does not change in quality such as discoloration, odor change, and separation even when stored for a long period of time and is excellent in usability.

Ascorbic acid glucoside is a well-known ingredient in cosmetics and external preparations for the purpose of suppressing melanin production and preventing or treating skin spots and freckles, and is the most stable among many ascorbic acid derivatives One of the things. However, even in cosmetics and external preparations containing these components, there is a problem that discoloration, odor change, separation, etc. due to heat and light often occur during long-term storage, so sufficient stability control Several proposals have been made for the purpose (see Patent Documents 1 to 3).

However, the cosmetics disclosed in these patent documents are mainly in the form of lotion, gel, cream, etc., and are simple (can be applied directly and do not require the use of fingers) No sticky emulsified composition having high portability is disclosed. In order to obtain such a stick shape, in addition to the stabilization of the above-mentioned ascorbic acid glucoside, moldability at the time of manufacture is required.

JP 2002-265344 A JP 2003-012498 A JP 2006-188461 A

The present invention has been made to solve the above-mentioned problems, and has an object of providing a stick-shaped cosmetic composition having a whitening effect, excellent in storage stability and use feeling. It is.

The present invention relates to ascorbic acid glucoside (a), titanium oxide (b), pentylene glycol and / or sorbitol (c), hydrocarbon wax (d), sorbitan fatty acid ester of HLB7 or less and / or polyglycerin fatty acid ester (e ), Liquid oil (f) and water (g), and the hydrocarbon wax (d) is added in a total amount of 5.0 to 30.0% by mass based on the total amount of the stick-like emulsified composition. There is a stick-like emulsified composition characterized in that part or all is polyethylene wax.

The stick-like emulsified composition preferably further contains tribehenine (h).
Tribehenine (h) is preferably contained in a total amount of 0.1 to 3.0% by mass based on the total amount of the stick-like emulsified composition.
The titanium oxide (b) is preferably titanium oxide surface-treated with silica and / or alumina.
The sorbitan fatty acid ester and / or polyglycerol fatty acid ester (e) having an HLB of 7 or less is preferably sorbitan isostearate and / or diglyceryl isostearate.

According to the present invention, a stick-shaped emulsion composition having excellent storage stability and usability, and excellent moldability when formed into a stick shape can be obtained.

Hereinafter, the present invention will be described in detail.
The present invention contains an ascorbic acid glucoside known as a whitening ingredient, and does not cause alteration such as discoloration, odor change and separation due to light and heat in long-term storage, and has excellent storage stability and moldability. To obtain an emulsion composition. By blending titanium oxide (b), alteration such as discoloration, odor change and separation due to light and heat can be prevented. Furthermore, by adding pentylene glycol and / or sorbitol (c) in addition to the above titanium oxide (b), the dispersibility of the titanium oxide particles can be improved, and the feeling and feeling of use can be maintained. it can. And as a component which obtains the form as a stick-like emulsified composition, by using the above-mentioned (d) to (g), it is possible to maintain excellent properties in moldability, feeling of use and stability. is there.

Component (a) in the present invention is ascorbic acid glucoside. The ascorbic acid glucoside is a known compound and can be obtained, for example, by the method described in JP-A-3-139288 or JP-A-3-135992.

As the ascorbic acid glucoside used in the present invention, L-ascorbic acid-2-glucoside can be suitably used. The blending amount is preferably 0.01 to 7.0% by mass, more preferably 0.1 to 5.0% by mass based on the total amount of the stick-like emulsion composition. If the blending amount is less than 0.01% by mass, the whitening effect may not be obtained. If the blending amount exceeds 7.0% by mass, the sticky feeling may become prominent, a good usability may not be obtained, and alterations such as discoloration, odor change and separation may occur.

It does not specifically limit as a titanium oxide of the said component (b), The thing produced by taking any manufacturing method of a baking method or a wet method may be used. Moreover, the shape is not particularly limited. The titanium oxide preferably has an average particle size of 0.1 μm or less. In addition, the said average particle diameter is an average particle diameter measured by the laser diffraction scattering method.

When the average particle diameter exceeds 0.1 μm, the feeling of use may be deteriorated because the degree of coloring at the time of application is too strong and a squeaky feeling is likely to occur. Although the minimum of the said average particle diameter is not specifically limited, It is preferable that it is 0.01 micrometer.

In the present invention, the component (b) titanium oxide is preferably titanium oxide surface-treated with silica and / or alumina because the reactivity (photocatalytic activity and ion elution) of titanium oxide can be suppressed. The surface treatment amount of silica and / or alumina is particularly preferably such that the composition ratio of titanium oxide and silica and / or alumina is in the range of mass ratio 98: 2 to 60:40. Further, titanium oxide whose surface has been hydrophobized with silicone oil or the like can also be used.

Commercially available titanium oxides include, for example, Taipei CR-50, TTO series (Ishihara Sangyo), MT series (Taika), Maxlite TS series (Showa Denko), Pulsol TX (DSM Nutrition). For example).

The amount of the titanium oxide is preferably 0.1 to 7.0% by mass, and more preferably 0.5 to 5.0% by mass based on the total amount of the stick-like emulsion composition. If it is less than 0.1% by mass, it may be difficult to suppress alterations such as discoloration, odor change, and separation caused by heat and light of ascorbic acid glucoside. When it exceeds 7.0% by mass, the feeling of blotting becomes remarkable, and it may be difficult to obtain a good feeling of use.

The pentylene glycol is not particularly limited, and those widely used as cosmetic raw materials can be used. By blending the pentylene glycol, the emulsion stability is improved, and a smooth feel and a good feeling of use are easily obtained.

As said pentylene glycol, a commercially available thing can also be used. Examples of commercially available products include Diol PD (manufactured by Higher Alcohol Industry), HYDROLITE-5 (manufactured by Simrise), and the like.

It does not specifically limit as said sorbitol, Well-known raw materials, such as sorbitol Kao (made by Kao Corporation; pure part 69.5-70.5%), sorbitol D-70 (made by Towa Kasei Kogyo Co., Ltd., concentration 70%), etc. are used. Can be used. By blending the sorbitol, the emulsion stability is improved, and a smooth feel and a good feeling of use are easily obtained.

The blending amount of the component (c) is preferably 0.5 to 20.0% by mass and more preferably 1.0 to 10.0% by mass with respect to the total amount of the stick-like emulsion composition. . If the blending amount is less than 0.5% by mass, it may be difficult to obtain an emulsion stability, a smooth feel, and a good feeling of use. If the blending amount exceeds 7.0% by mass, the sticky feeling becomes remarkable, and a good usability may not be obtained. In addition, the compounding quantity of a component (c) is taken as the total amount of both, when using pentylene glycol and sorbitol together.

The said component (d) is a hydrocarbon wax, and makes polyethylene wax a part or all. That is, it is a hydrocarbon wax in which polyethylene wax is essential and other hydrocarbon waxes may be used in combination. The polyethylene wax is preferably used as a consistency adjusting agent because it is easy to obtain a smooth feel and a good feeling of use. In particular, those having an average molecular weight of 300 to 1000 are preferably used. Further, by using polyethylene wax as an essential component, excellent effects can be obtained with respect to the feeling of use and storage stability.

As the above polyethylene wax, Performalene
PL Polyethylene, Performanceene 400 Polyethylene, Performanceene 655 Polyethylene (New)
Commercial products such as Phase Technologies) and Sun Wax 151-P (Sanyo Chemicals) can be suitably used.

Many waxes derived from plants and animals are commercially available as cosmetic raw materials, but many of them contain impurities, which may cause alteration such as discoloration, odor change and separation. Therefore, in the present invention, it is preferable not to use any wax other than the hydrocarbon wax.

The hydrocarbon wax other than the polyethylene wax is not particularly limited as long as it has a hydrocarbon structure, but is selected from the group consisting of synthetic waxes such as paraffin wax, microcrystalline wax, ceresin, ozokerite and Fischer-Tropsch wax. It is preferable that it is at least one kind. Examples of commercially available hydrocarbon waxes include paraffin waxes 155, 150, 140, HNP-9, HNP-10, microcrystalline wax Hi-Mic series, and Fischer-Tropsch wax FT series (manufactured by Nippon Seiwa Co., Ltd.). it can. Further, as the Sasolwax series (manufactured by SASOL), synthetic waxes such as paraffin wax, microcrystalline wax, ceresin, ozokerite and Fischer-Tropsch wax are commercially available.

The compounding quantity of the said component (d) is 5.0-30.0 mass% with respect to the stick-shaped emulsion composition total amount by a total amount. If the blending amount is less than 5.0% by mass, the moldability of the resulting stick-like emulsion composition is deteriorated. In addition, the stick-like emulsion composition tends to collapse during use. If the blending amount exceeds 30.0% by mass, it is too hard, and it becomes difficult to obtain a smooth feel and good usability.

In this invention, a component (e) is sorbitan fatty acid ester and / or polyglycerol fatty acid ester of HLB7 or less. A stable emulsion composition can be obtained by using a sorbitan fatty acid ester and / or a polyglycerin fatty acid ester having an HLB of 7 or less. The HLB means an HLB value based on the Griffin method. Regarding the sorbitan fatty acid ester and / or polyglycerin fatty acid ester, the lower limit of the HLB is not particularly limited, but is preferably 2.

As said sorbitan fatty acid ester and / or polyglycerin fatty acid ester, since the stick-shaped emulsion composition excellent in storage stability and usability | use_condition can be obtained, a liquid thing is preferable at normal temperature. Of these, sorbitan isostearate and / or diglyceryl isostearate, in which the fatty acid is isostearic acid, is preferably used. The blending amount of the sorbitan fatty acid ester and / or polyglycerin fatty acid ester is preferably 0.1 to 5.0% by mass, and 0.5 to 3.0% by mass with respect to the total amount of the stick-like emulsion composition. It is more preferable. If the blending amount is less than 0.1% by mass, emulsification becomes difficult, and if it exceeds 5.0% by mass, a sticky feeling becomes prominent and a good usability may be difficult to obtain. The component (e) may be used in combination of two or more.

In the present invention, component (f) is a liquid oil. By blending liquid oil, it is preferable because a good feeling of use can be obtained. The liquid oil is not particularly limited. What is widely used as a cosmetic raw material can be used. Of these, silicone oil, hydrocarbon oil, ester oil and the like are preferable. More specifically, for example, cyclomethicone, dimethicone, methyltrimethicone, caprylmethicone; isododecane, isohexadecane, didecene, hydrogenated polydecene, olefin oligomer, liquid paraffin and the like are preferable. The liquid oil (f) may be used in combination of two or more liquid oils.

The blending amount of the component (f) is preferably 10 to 80% by mass, and more preferably 20 to 60% by mass with respect to the total amount of the stick-like emulsion composition. If the blending amount is less than 10% by mass, there may be a problem that a smooth feel cannot be obtained, and if it exceeds 80% by mass, there may be a problem that it becomes a sticky feel.

The present invention is an emulsified composition containing water (g). Water (g) is preferably 1 to 40% by mass, and more preferably 3 to 30% by mass, based on the total amount of the stick-like emulsion composition. If the blending amount is less than 1% by mass, there may be a problem that it becomes a sticky feel, and if it exceeds 40% by mass, the storage stability may be lowered.

Furthermore, it is preferable to contain 0.1-3.0 mass% of tribehenine (h) with respect to the stick-like emulsion composition total amount. By blending the above tribehenine (h), it is preferable in terms of improving the moldability of the resulting stick-like emulsion composition. Moreover, it becomes difficult for the said stick-like emulsion composition to disintegrate at the time of use.

In addition to the above-mentioned components, the stick-like emulsion composition of the present invention generally contains medicinal ingredients, flavoring agents, cooling agents, ultraviolet absorbers, ultraviolet scattering agents, suspending agents, stabilizers, wetting agents, Antioxidants, pH adjusters, viscosity adjusters, colorants, preservatives, and the like can be blended.

The stick-like emulsion composition of the present invention is obtained by molding an emulsion composition obtained by emulsifying each of the above components into a stick shape. The emulsification method is not particularly limited, and can be carried out by a usual method.

The stick-like emulsified composition of the present invention has a high whitening effect and a feeling of use, and is a basic cosmetic such as an eye cream; a base makeup cosmetic such as a makeup base, concealer or foundation; a UV protective cosmetic Etc. can be suitably used.

EXAMPLES Next, although an Example and a comparative example are given and this invention is demonstrated in more detail, this invention is not limited to these Examples. In addition, all compounding quantities are the mass%.

Examples 1 to 7 and Comparative Examples 1 to 4: Whitening Stick Cream Whitening stick cream having the composition shown in Table 1 was prepared by the following production method. The obtained whitening stick cream was evaluated for (1) whitening effect, (2) feeling of use (drinking and sticking), (3) moldability of the stick, and (4) storage stability by the following methods, together with the results. It is shown in Table 1.

Production Method (1) After components 1-18 are uniformly dissolved at about 85 ° C., components 19-24 are added and dispersed uniformly.
(2) The component 31 is dissolved in advance using a part of the component 33, and the component 32 is further added to adjust the pH to 6.0 to 7.5.
(3) The components 25 to 30 and the remainder of the component 33 are uniformly dissolved at about 80 ° C.
(3) was added to (1) with stirring and emulsified, then (2) was added, poured into an airtight stick-like container, cooled and molded to obtain a whitening stick cream.

[Whitening effect: Test method / Evaluation method]
The whitening effect after each sample was applied to the forearm twice a day (morning and evening) for one month was evaluated by three cosmetic evaluation panels for each sample according to the following criteria in three stages, and further judged from the average score. .

Evaluation criteria 3 points: 2 points where whitening effect was recognized: 1 point where whitening effect was slightly recognized: Criteria where whitening effect was not recognized ○: 2.5-3.0
Δ: Less than 1.5 to 2.5 x: Less than 1.5

[Usability: Test method / Evaluation method]
Using 10 panelists specializing in cosmetics, the feeling of use (spreading and sticking) when applied to the face was evaluated in five levels according to the following criteria, and further judged from the average score.

5 points: Good 4 points: Slightly good 3 points: Normal 2 points: Slightly bad 1 point: Defect criteria C: Average point 4.0 or higher Δ: Average point 3.0 or higher and lower than 4.0 ×: Average point 3. Less than 0

[Moldability of stick: Test method / Evaluation method]
The whitening stick cream poured into an airtight stick-like container, cooled, and molded was repeatedly raised and lowered several times, and the bulk state was visually observed.
Judgment criteria ○: Smooth and glossy △: Slight moisture leakage or fusion with the container and / or cracks ×: Significant moisture leakage, fusion with the container and / Or cracks are seen

[Storage stability test]
Each sample was set in a constant temperature bath at 40 ° C., and after standing for 6 months, the state change of each sample was observed and evaluated according to the following criteria.
○: No alteration such as discoloration, odor, separation, etc. △: Some alteration, such as discoloration, odor, separation, etc. is observed ×: Significant discoloration, odor, separation, etc. are observed

As is apparent from the results in Table 1, Examples 1 to 7 according to the present invention were whitening stick creams having a whitening effect and excellent storage stability and usability compared to the comparative examples. On the other hand, in Comparative Examples 1-4, although the whitening effect was equivalent, it was unsatisfactory about a feeling of use, the moldability of a stick, and storage stability.

Example 8 Whitening Stick Sunscreen A whitening stick sunscreen having the composition shown in Table 2 was prepared by the following production method.

Production Method (1) After components 1-14 are uniformly dissolved at about 85 ° C., components 15-17 are added and dispersed uniformly.
(2) Component 23 is dissolved in advance using part of component 25, and component 24 is added to adjust the pH to 6.0 to 7.5.
(3) The components 18 to 22 and the remainder of the component 25 are uniformly dissolved at about 80 ° C.
(3) was added to (1) with stirring and emulsified, then (2) was added, poured into an airtight stick-like container, cooled and molded to obtain a whitening stick sunscreen. When the obtained whitening stick sunscreen was evaluated in the same manner, it was found that it had a whitening effect and was excellent in storage stability and usability.

Example 9 Whitening Stick Eye Cream A whitening stick eye cream having the composition shown in Table 3 was prepared by the following production method.

Production Method (1) After components 1-12 are uniformly dissolved at about 85 ° C., components 13-15 are added and dispersed uniformly.
(2) The component 20 is dissolved in advance using a part of the component 22, and the component 21 is further added to adjust the pH to 6.0 to 7.5.
(3) The components 16 to 19 and the remainder of the component 22 are uniformly dissolved at about 80 ° C.
After (3) was added to (1) with stirring and emulsified, (2) was added, poured into an airtight stick-like container, cooled and molded to obtain a whitening stick eye cream. About the obtained whitening stick eye cream, when the same evaluation was performed, it turned out that it has a whitening effect and is excellent in storage stability and usability.

The stick-like emulsified composition of the present invention has a whitening effect, is excellent in storage stability and use feeling, and is a basic cosmetic such as an eye cream; a base makeup cosmetic such as a makeup base, a concealer, and a foundation; It can be suitably used as a UV protective cosmetic.

Claims (5)

Ascorbic acid glucoside (a), titanium oxide (b), pentylene glycol and / or sorbitol (c), hydrocarbon wax (d), HLB7 or lower sorbitan fatty acid ester and / or polyglycerin fatty acid ester (e), liquid oil (F) as well as water (g), and the hydrocarbon wax (d) has a total blending amount of 5.0 to 30.0% by mass with respect to the total amount of the stick-like emulsified composition. A stick-like emulsified composition characterized in that or is entirely polyethylene wax. Furthermore, the stick-shaped emulsion composition of Claim 1 containing a tribehenine (h). 3. The stick-like emulsion composition according to claim 2, wherein tribehenine (h) is contained in a total amount of 0.1 to 3.0% by mass relative to the total amount of the stick-like emulsion composition. The stick-like emulsified composition according to claim 1, wherein the titanium oxide (b) is titanium oxide surface-treated with silica and / or alumina. 5. The stick-like emulsion composition according to claim 1, wherein the HLB7 or lower sorbitan fatty acid ester and / or polyglycerin fatty acid ester (e) is sorbitan isostearate and / or diglyceryl isostearate.