JP5537854B2 - Method for producing phosphorus fertilizer and phosphorus fertilizer obtained by the method - Google Patents

Method for producing phosphorus fertilizer and phosphorus fertilizer obtained by the method Download PDF

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JP5537854B2
JP5537854B2 JP2009164668A JP2009164668A JP5537854B2 JP 5537854 B2 JP5537854 B2 JP 5537854B2 JP 2009164668 A JP2009164668 A JP 2009164668A JP 2009164668 A JP2009164668 A JP 2009164668A JP 5537854 B2 JP5537854 B2 JP 5537854B2
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長治 森村
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株式会社森村運輸
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本発明は肥料の製造方法、及びこの方法により得られる肥料に関し、さらに詳細には、天然物である梅の種子を原料とし、これを昨今の環境破壊などの問題を生じることなく、簡便な方法で経済性良く高濃度のリン肥料とすることができるリン肥料の製造方法、及びこの方法で得られる天然物由来のリン肥料に関する。   The present invention relates to a method for producing fertilizer, and a fertilizer obtained by this method. More specifically, the method uses a natural product plum seed as a raw material, and this is a simple method without causing problems such as recent environmental destruction. It is related with the manufacturing method of the phosphorus fertilizer which can be made into a high concentration phosphorus fertilizer with economical efficiency, and the phosphorus fertilizer derived from the natural product obtained by this method.

従来、窒素、カリウムとともに農産物の生育に必須のリン成分を供給するリン肥料は、リン鉱石などの鉱物由来のものや、生物(海鳥の排泄物、微生物など)由来のものの他に、活性汚泥や下水汚泥の焼却灰、あるいは海や湖の深層水を逆浸透膜で処理してリン化合物を高濃度にした水等が知られている。   Conventionally, phosphorus fertilizers that supply phosphorus components essential for the growth of agricultural products together with nitrogen and potassium are derived from minerals such as phosphorus ore, and from living organisms (seabird excrement, microorganisms, etc.), activated sludge and Incinerated ash from sewage sludge, or water in which deep water from the sea or lake is treated with a reverse osmosis membrane to increase the concentration of phosphorus compounds is known.

しかし、近年来の世界的なリンの枯渇が懸念されており、また、日本では原料のリン鉱石は輸入に頼らざるを得なかったり、上記した従来の各種リン肥料の製造には多大の工程や製造設備を要するため製造コストが膨大になるばかりか、設備設置箇所の確保や設備の保守管理を余儀なくされ、製造コストの一層の高騰を招くなどの種々の問題があるところから、市場では製造に要する工程が少なく、低コストで安定したリン肥料の供給が急務とされている。   However, there is a concern about the global depletion of phosphorus in recent years, and in Japan, it is necessary to rely on imports of the raw material ore. Since the manufacturing equipment is required, not only the manufacturing cost becomes enormous, but also there are various problems such as securing the installation location of the equipment and maintenance management of the equipment, leading to further increase in the manufacturing cost. There is an urgent need to supply low-cost and stable phosphorus fertilizers with fewer processes.

特開平 8−119778号公報JP-A-8-119778 特開2002−29871号公報JP 2002-29871 A 特開平 5−301791号公報JP-A-5-301791

本発明は上記状況に鑑みてなされたものであり、原料の入手が容易で、しかも大がかりな設備を要さずして安価に、かつ、簡便に製造することのできるリン肥料の製造方法、並びにリン肥料の提供を課題とする。   The present invention has been made in view of the above situation, and it is easy to obtain raw materials, and does not require large-scale equipment, and can be produced inexpensively and simply. The issue is to provide phosphorus fertilizer.

本発明者は上記課題達成のため、リン肥料の主原料としてリン鉱石や化学工業での副産物等のリンを含む無機物質に代えて、リン肥料の原料となる物質としてリンの含有量が多い天然物由来の有機物質に着目し、天然物由来の有機物質を使用して、原料が含有するリン成分を簡便な手法で植物が吸収し易い形態のリンの化合物に分解、抽出してリン肥料を得ることのできる手法を見出すべく鋭意検討を重ねた。
その結果、種々の有機物質について検討する中で、我が国において季節を問わず比較的大量に消費され、したがって大量に発生し廃棄される梅の種子、特に種子の内部のいわゆる“仁”の部分には、比較的高濃度のリンが含まれており、また、梅の種子には青酸に由来する窒素も含まれているとの知見を得た。
In order to achieve the above object, the present inventor replaces an inorganic substance containing phosphorus as a main raw material of phosphorus fertilizer, such as phosphorus ore and by-products in the chemical industry. Focusing on organic substances derived from substances, using organic substances derived from natural products, the phosphorus component contained in the raw material is decomposed and extracted into phosphorus compounds in a form that is easily absorbed by plants using a simple technique. We intensively studied to find a method that can be obtained.
As a result, in the study of various organic substances, in Japan, plum seeds that are consumed in relatively large quantities regardless of the season, and are therefore generated and discarded in large quantities, especially in the so-called “ren” part of the seeds. Has a relatively high concentration of phosphorus, and it has been found that plum seeds also contain nitrogen derived from hydrocyanic acid.

梅の種子は土壌中にそのまま放置、又は埋設しておいても特に弊害はなく、リン肥料や窒素肥料を必要とする作物が栽培される土壌中にそのまま鋤きこんでもよいが、単に土壌中に放置しておいただけでは種子の外側の殻の自然分解には長時間を要するところから即効性に乏しく、土壌の性質や季節に合わせた施肥量の制御も難しい。   Plum seeds can be left undisturbed or buried in the soil with no particular adverse effects, and may be planted directly in the soil where crops that require phosphorus fertilizer or nitrogen fertilizer are cultivated. If left alone, the natural decomposition of the outer shell of the seed takes a long time, so it is not immediately effective, and it is difficult to control the amount of fertilization according to the nature of the soil and the season.

本発明者は、種子を含む梅の果実に発酵菌を添加して空気中において発酵処理することにより、該種子中のリン成分を植物が土壌中において吸収可能なリン酸イオンとなり易い形態のリンの化合物として簡単に抽出され、リン肥料とすることができることを見いだし本発明に到った。   The present inventor added a fermentative bacterium to a plum fruit containing seeds and fermented it in the air, whereby the phosphorus component in the seeds was easily converted into phosphate ions that can be absorbed by the plant in the soil. As a result, the present inventors have found that it can be easily extracted as a compound and can be used as a phosphorus fertilizer.

従来、原料を発酵処理することによって肥料を製造する方法としては、例えば畜産廃棄物や汚泥などを用いて発酵槽等で発酵処理する発酵肥料の製造方法(特許文献1、2等)や農産物廃棄物等の植物由来の堆肥原料に微生物による発酵生成物を添加して堆積、発酵、熟成させる堆肥の製造方法(特許文献3等)を始めとしていくつも提案されているが、梅の果実を原料とし発酵菌を用いればその発酵処理が容易に進行することや、梅の果実を原料として発酵処理によりこれをリン肥料とする方法については従来知られていない。   Conventionally, as a method for producing fertilizer by fermenting raw materials, for example, a fermented fertilizer production method (eg, Patent Documents 1 and 2) for fermenting in a fermenter or the like using livestock waste or sludge, or agricultural product disposal Several methods have been proposed, including a method for producing compost (such as Patent Document 3) in which fermented products from microorganisms are added to plant-derived compost raw materials such as foods to deposit, ferment, and mature. It is not known in the past that the fermenting process can easily proceed if fermenting bacteria are used, and that a method of using a plum fruit as a raw material to make it a phosphorus fertilizer by a fermentation process.

本発明者は以下の構成を採用することによって前記課題を解決することができた。すなわち、本発明は下記(1)〜(5)の構成からなる。
(1)本発明のリン肥料の製造方法は、梅の種子、又は種子を含んだ梅の果実に発酵菌を添加して好気条件下で発酵処理することを特徴とする。
(2)前記(1)に記載の本発明のリン肥料の製造方法においては、前記種子が梅干又は/及び梅酒に加工した後の果実から採取された種子であることが梅の利用効率を高める上でより好ましい。
(3)また、前記(1)又は(2)に記載の本発明のリン肥料の製造方法は、前記発酵菌が高温菌であることが発酵効率を高める点でより好ましい。
(4)さらにまた、前記(1)〜(3)のいずれかに記載の本発明のリン肥料の製造方法は、前記発酵処理する温度が25℃以上であることが好ましい。
(5)また、本発明のリン肥料は前記(1)〜(4)のいずれかに記載の製造方法により製造されることを特徴とする。
The present inventor was able to solve the above problems by adopting the following configuration. That is, this invention consists of the structure of following (1)-(5).
(1) The method for producing a phosphorus fertilizer according to the present invention is characterized in that a fermenting bacterium is added to a plum seed or a plum fruit containing a seed and subjected to a fermentation treatment under aerobic conditions.
(2) In the method for producing a phosphorus fertilizer according to the present invention described in (1), the use efficiency of plums is enhanced when the seeds are seeds collected from fruits after being processed into plum dried or / and plum wine. More preferred above.
(3) Moreover, the manufacturing method of the phosphorus fertilizer of this invention as described in said (1) or (2) is more preferable at the point which raises fermentation efficiency that the said fermentation bacteria are thermophilic bacteria.
(4) Furthermore, in the method for producing a phosphorus fertilizer according to any one of (1) to (3), the temperature for the fermentation treatment is preferably 25 ° C. or higher.
(5) Moreover, the phosphorus fertilizer of this invention is manufactured by the manufacturing method in any one of said (1)-(4).

本発明のリン肥料の製造方法によれば、枯渇が懸念されているリン鉱石やリン酸カルシウム等、化学工業での副産物などリン成分を含む無機物質を使用せず、天然物由来の有機物質であり、しかも季節を問わず常時大量に消費され、廃棄される梅の種子を原料としているため、原料が容易、かつ安価に入手することができる。
さらに、原料である梅の種子に発酵菌を添加して発酵処理するだけなので、特別の生産設備や広大な場所は要さず、また、製造のプロセスも簡便なため、経済性良く植物に対して吸収が早い高濃度のリン肥料を製造することができる。
According to the method for producing phosphorus fertilizer of the present invention, it is an organic substance derived from a natural product without using an inorganic substance containing a phosphorus component such as a by-product in the chemical industry, such as phosphate ore and calcium phosphate, which are feared to be depleted, Moreover, since the ume seeds, which are always consumed in large quantities regardless of the season and are discarded, are used as raw materials, the raw materials can be obtained easily and inexpensively.
Furthermore, because fermented bacteria are simply added to the ume seeds, which are the raw material, and fermented, no special production facilities or large space is required, and the manufacturing process is simple, so it is economically efficient. High concentration phosphorus fertilizer that can be absorbed quickly.

以下、本発明をさらに詳細に説明する。
本発明のリン肥料の製造方法は、梅の種子や種子が取り除かれていない梅の果実を原料とし、これを発酵菌の作用により発酵処理することによって、梅の種子のままでは植物に吸収され難い形態で該種子中に存在するリン成分を、水分を含む土壌中において植物が吸収し易いリン酸イオンとして解離し得る形態のリン化合物に分解するものである。
Hereinafter, the present invention will be described in more detail.
The method for producing phosphorus fertilizer according to the present invention uses ume seeds and ume fruits from which seeds have not been removed as raw materials, and is fermented by the action of fermenting bacteria so that the ume seeds can be absorbed by plants. The phosphorus component present in the seed in a difficult form is decomposed into a phosphorus compound in a form that can be dissociated as phosphate ions that are easily absorbed by plants in soil containing water.

すなわち、本発明のリン肥料は概略、下記のプロセスにより製造される。
出発原料として梅の種子、又は種子を含んだ梅の果実(以下、梅の種子、及び種子を含んだ梅の果実を単に梅の種子という)が用いられる。梅は梅の樹木からもぎ取られた生の果実をそのまま使用しても、また、梅干として加工し食された後に廃棄された種子や、梅酒等に加工した後の果実から採取された種子を用いてもよいが、梅干としたものや梅酒等に加工した後の果実から採取された種子を用いれば、梅の利用効率を高める上でより好ましい。
That is, the phosphorus fertilizer of the present invention is generally manufactured by the following process.
Plum seeds or plum fruits containing seeds (hereinafter referred to as plum seeds and plum fruits containing seeds are simply referred to as plum seeds) are used as starting materials. Plums can be used as they are, with raw fruits picked from plum trees, as well as seeds that have been processed and dried as plums, and seeds collected from fruits that have been processed into plum wine, etc. However, it is more preferable to increase the utilization efficiency of plums by using seeds collected from fruits that have been processed into umeboshi or umeshu.

次に、採取された梅の果実をライカイ機、ロールミル、乳鉢などの粉砕手段によりほぼ1〜5mm程度の大きさに機械的に粗砕してリン肥料の原料を調製する。
次いで、得られたリン肥料の原料を土壌の露出した地面やコンクリート床等の上に野積み状態で堆積させ、この堆積体(機械的に粗砕し堆積された梅の種子を、以下「原料種子堆積体」ということにする)の全体に散水して該堆積体の水分含有率がほぼ30〜50%となるように水分調整を行い、該堆積体の内部の1ヶ所、又は数カ所に発酵菌を含有する菌床を埋設、配置する。
なお、発酵菌は原料種子堆積体の内部の1ヶ所、又は数カ所に埋設、配置するのではなく、最初に粗砕された梅の種子と混合しておいてから地面やコンクリート床等の上に野積み状態で堆積させて原料種子堆積体としてもよいことはいうまでもない。
Next, the raw material of phosphorus fertilizer is prepared by mechanically crushing the collected plum fruits to a size of about 1 to 5 mm by a pulverizing means such as a laika machine, a roll mill, or a mortar.
Next, the raw material of the obtained phosphorus fertilizer is deposited in a piled state on the ground, concrete floor, etc. where the soil is exposed, and this sediment (mechanically crushed and deposited plum seeds is hereinafter referred to as “raw material”. Water is adjusted so that the moisture content of the sediment is approximately 30 to 50%, and fermentation is performed at one or several locations inside the sediment. A fungus bed containing bacteria is buried and placed.
The fermenter is not buried or placed in one or several places inside the seed deposit, but it is first mixed with the coarsely ground ume seeds and then placed on the ground or concrete floor. Needless to say, the raw material seed deposits may be deposited in a piled state.

次に、原料種子堆積体中に0.5〜1重量%程度の蔗糖、果糖等を添加することによって原料種子堆積体中に糖分等の栄養分を供給し、保温のために塩ビシートなどのプラスチク製シート、ムシロ、稲藁等で原料種子堆積体全体を覆って、周囲の温度が23〜25℃以上の温度下で一定期間放置する。   Next, by adding about 0.5 to 1% by weight of sucrose, fructose, etc. into the raw material seed deposit, nutrients such as sugar are supplied into the raw material seed deposit, and plastic sheets such as PVC sheets are used for heat insulation. The entire raw material seed deposit is covered with a sheet, mushiro, rice straw, etc., and left for a certain period of time at an ambient temperature of 23 to 25 ° C. or higher.

菌床を加え、水分調整するとともに、栄養分を与えてシート等で覆った状態で一定温度のもとで放置しておくことによって、原料種子堆積体が発酵しはじめ、そのため内部温度が発酵熱によって徐々に上昇する。
原料種子堆積体を放置している間、発酵菌の増殖をより活発にするため、およそ1週間に1回程度の頻度で覆われているシートを取り除いて空気を吹き込みながら切り返し(攪拌、混合)を行うことが発酵を促進し、均一に発酵させる上でより好ましい。
なお、本明細書中において発酵とは梅の種子が微生物により分解されてゆく現象をいう。
By adding the fungus bed, adjusting the moisture, leaving it under a certain temperature with nutrients and covering with a sheet etc., the raw material seed deposits start to ferment, so the internal temperature is caused by the heat of fermentation. Rise gradually.
While leaving the seed seed deposit, the fermented bacteria grow more actively, removing the covered sheet about once a week and turning it back while blowing air (stirring, mixing) It is more preferable to promote the fermentation and make the fermentation uniform.
In this specification, fermentation refers to a phenomenon in which ume seeds are decomposed by microorganisms.

粗砕された原料種子は、前記のように地面やコンクリート床上に堆積させて放置しておくのではなく、例えばステンレス、コンクリート、レンガなどからなる貯留槽(発酵槽)を設け、その中に菌床や栄養分とともに収容して放置しておいて貯留槽(発酵槽)の中で発酵させてもよい。
粗砕された原料種子に添加する菌床中に含有させる発酵菌としては、グラム陰性菌、放線菌、乳酸菌など、ほぼ50℃以上で増殖が活発となる高温発酵菌、又は30℃〜40℃で増殖が活発となる中温発酵菌が使用される、特に高温発酵菌を用いるのが発酵処理のための時間を短縮できるのでより好ましい。これらの発酵菌は、例えばペースト状にした厨芥、家畜糞、魚かす、骨粉などと混合して増量したものを使用してもよい。
Roughly crushed raw material seeds are not deposited and left on the ground or concrete floor as described above, but a storage tank (fermenter) made of, for example, stainless steel, concrete, bricks, etc. is provided and fungi are contained therein. You may make it ferment in a storage tank (fermentor), storing and leaving with a floor and nutrients.
As fermentative bacteria to be contained in the fungus bed added to the roughly crushed raw material seeds, gram-negative bacteria, actinomycetes, lactic acid bacteria, etc., high-temperature fermentative bacteria that actively grow at about 50 ° C or higher, or 30 ° C to 40 ° C It is more preferable to use a high-temperature fermenting bacterium, in particular, a high-temperature fermenting bacterium that can be actively grown. These fermenting bacteria may be used, for example, by increasing the amount by mixing with paste-like strawberries, livestock dung, fish meal, bone meal or the like.

このようにして、一定期間放置された原料種子堆積体は発酵処理が進むにしたがってその内部の温度が次第に上昇し、一定の温度に達すると反対に温度低下が始まる。内部の温度がおよそ60℃以上の一定温度に達した後、やがて徐々に低下し始めると原料種子堆積体の発酵はほぼ完了し、梅の種子中のリンの成分が分解されて土壌中の水分によって植物に吸収され易いリン酸イオンを解離し得る形態に変化し、本発明のリン肥料が得られる。
本発明の製造方法により梅の種子の発酵がほぼ完了し、リン肥料が仕上がるまでには、種子原料の仕込み量にもよるがほぼ20〜30日の時間で十分である。
このようにして得られた本発明のリン肥料は、さらに必要に応じて施肥しやすい任意の粒径に粉砕される。
In this way, the temperature of the seed seed deposits left for a certain period of time gradually increases as the fermentation process proceeds, and when the temperature reaches a certain level, the temperature starts to decrease. When the internal temperature reaches a certain temperature of about 60 ° C or higher and then gradually begins to decline, the fermentation of the raw material seed deposits is almost complete, and the phosphorus component in the plum seeds is decomposed and moisture in the soil The phosphate fertilizer of the present invention is obtained by changing to a form capable of dissociating phosphate ions that are easily absorbed by plants.
Depending on the amount of seed material charged, approximately 20 to 30 days are sufficient until fermentation of plum seeds is almost completed by the production method of the present invention and phosphorus fertilizer is finished.
The phosphorus fertilizer of the present invention thus obtained is pulverized to an arbitrary particle size that is easy to fertilize as necessary.

次に実施例により本発明を説明する。
〔実施例1〕
梅干の種子100gを十分に乾燥し、ロールミルで最長部分の長さがおよそ3〜5mm程度の大きさになるように粗砕して原料種子を調製した。
次に、得られた原料種子をコンクリートの床上に堆積して原料種子堆積体とし、原料種子堆積体に対して約2重量%の割合の砂糖を全体に散布し、これに水を添加して原料種子堆積体の水分含有率がおよそ40%となるように調整した。
次いで、原料種子堆積体内部のほぼ中央部分に高温発酵菌を含んだ菌床を埋め込み、堆積した原料種子の外部から内部の温度が確認できる状態で温度計を挿入し、その上をビニールシートで覆って周囲温度25℃の環境下で放置した。
放置した原料種子堆積体は、7日に一度の割合で表面を覆ったビニールシートを取り外し、ファンで空気を送りながら切り返し混合して原料種子堆積体の表面を空気に接触させた。
Next, an example explains the present invention.
[Example 1]
100 g of umeboshi seeds were sufficiently dried and coarsely crushed with a roll mill so that the length of the longest part was about 3 to 5 mm.
Next, the obtained raw material seeds are deposited on a concrete floor to form a raw material seed deposit, and about 2% by weight of sugar is sprayed over the raw material seed deposit, and water is added thereto. The water content of the raw material seed deposit was adjusted to be approximately 40%.
Next, a fungus bed containing high-temperature fermenting bacteria is embedded in the central part of the raw material seed deposit, and a thermometer is inserted in a state in which the internal temperature can be confirmed from the outside of the deposited raw material seed. It was covered and left in an environment with an ambient temperature of 25 ° C.
The raw material seed deposits were removed from the vinyl sheet covering the surface once every seven days, mixed by turning back while sending air with a fan to bring the surface of the raw material seed deposits into contact with air.

このようにして放置された原料種子堆積体の発熱によって内部温度が室温(25℃)から次第に上昇しはじめ、放置後28日で内部温度がほぼ80℃に達し、やがて80℃よりも低下し始めたので、放置後30日目でビニールシートを除去し、この堆積体をかき集めて攪拌し、篩いにかけて粒径を揃えてリン肥料を得た。   The internal temperature begins to gradually increase from room temperature (25 ° C.) due to the heat generation of the raw material seed deposits left in this way, the internal temperature reaches approximately 80 ° C. within 28 days after being left, and then begins to drop below 80 ° C. Therefore, the vinyl sheet was removed on the 30th day after standing, and this deposit was collected and stirred, and sieved to obtain a phosphorus fertilizer with a uniform particle size.

得られたリン肥料を純水中に懸濁させ、十分に攪拌してからその上澄み液を分取し化学分析したところ、上澄み液からはリン酸イオンが検出された。
一方、このリン肥料の原料である梅干の種子100gを1000ccの純水中に7日間放置し、その上澄み液を同様に化学分析したところ、上澄み液からはリン酸イオンは検出されなかったことから、本発明のリン肥料には、水分を含む土壌中において植物が吸収し易いリン酸イオンを解離する成分が含まれていて、リン肥料として即効性が高いことがわかる。
When the obtained phosphorus fertilizer was suspended in pure water and sufficiently stirred, the supernatant was collected and subjected to chemical analysis. As a result, phosphate ions were detected in the supernatant.
On the other hand, 100 g of umeboshi seeds, which are the raw material for this phosphorus fertilizer, were left in 1000 cc of pure water for 7 days, and the supernatant was chemically analyzed. As a result, phosphate ions were not detected in the supernatant. The phosphorus fertilizer of the present invention contains a component that dissociates phosphate ions that are easily absorbed by plants in water-containing soil, and it is understood that the phosphorus fertilizer has a high immediate effect as a phosphorus fertilizer.

Claims (5)

梅の種子、又は種子を含んだ梅の果実に発酵菌を添加して好気条件下で発酵処理することを特徴とするリン肥料の製造方法。 A method for producing phosphorus fertilizer, comprising adding fermentative bacteria to plum seeds or plum fruits containing seeds and subjecting them to fermentation under aerobic conditions. 前記種子が梅干又は/及び梅酒に加工した後の果実から採取された種子であることを特徴とする請求項1に記載のリン肥料の製造方法。 The method for producing a phosphorus fertilizer according to claim 1, wherein the seed is a seed collected from a fruit after being processed into plum dried or / and plum wine. 前記発酵菌が高温菌であることを特徴とする請求項1又は2に記載のリン肥料の製造方法。 The method for producing a phosphorus fertilizer according to claim 1 or 2, wherein the fermentative bacterium is a thermophilic bacterium. 前記発酵処理の温度が25℃以上であることを特徴とする請求項1〜3のいずれか1項に記載のリン肥料の製造方法。 The temperature of the said fermentation process is 25 degreeC or more, The manufacturing method of the phosphorus fertilizer of any one of Claims 1-3 characterized by the above-mentioned. 請求項1〜4のいずれか1項に記載の製造方法により製造されることを特徴とするリン肥料。 The phosphorus fertilizer manufactured by the manufacturing method of any one of Claims 1-4.
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