JP5435364B2 - Processing method and processing system for harmful substances generated in casting line - Google Patents
Processing method and processing system for harmful substances generated in casting line Download PDFInfo
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- JP5435364B2 JP5435364B2 JP2010167793A JP2010167793A JP5435364B2 JP 5435364 B2 JP5435364 B2 JP 5435364B2 JP 2010167793 A JP2010167793 A JP 2010167793A JP 2010167793 A JP2010167793 A JP 2010167793A JP 5435364 B2 JP5435364 B2 JP 5435364B2
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- 238000005266 casting Methods 0.000 title claims description 36
- 239000000126 substance Substances 0.000 title claims description 23
- 238000003672 processing method Methods 0.000 title description 4
- 239000004576 sand Substances 0.000 claims description 61
- 239000000428 dust Substances 0.000 claims description 54
- 238000000034 method Methods 0.000 claims description 50
- 238000004898 kneading Methods 0.000 claims description 27
- 239000003795 chemical substances by application Substances 0.000 claims description 16
- 238000000465 moulding Methods 0.000 claims description 12
- 239000000383 hazardous chemical Substances 0.000 claims description 9
- 238000000926 separation method Methods 0.000 claims description 8
- 230000008929 regeneration Effects 0.000 claims description 7
- 238000011069 regeneration method Methods 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 5
- 238000004064 recycling Methods 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 229910052731 fluorine Inorganic materials 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 3
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 claims description 3
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 3
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 claims description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052753 mercury Inorganic materials 0.000 claims description 3
- 229910052711 selenium Inorganic materials 0.000 claims description 3
- 239000011669 selenium Substances 0.000 claims description 3
- 238000003900 soil pollution Methods 0.000 claims description 2
- 230000001172 regenerating effect Effects 0.000 claims 1
- 231100000167 toxic agent Toxicity 0.000 claims 1
- 239000003440 toxic substance Substances 0.000 claims 1
- 229910052736 halogen Inorganic materials 0.000 description 7
- 150000002367 halogens Chemical class 0.000 description 7
- 229910001385 heavy metal Inorganic materials 0.000 description 7
- 239000002994 raw material Substances 0.000 description 7
- 239000002689 soil Substances 0.000 description 7
- 239000000395 magnesium oxide Substances 0.000 description 5
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 5
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000004568 cement Substances 0.000 description 3
- 238000010828 elution Methods 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000007730 finishing process Methods 0.000 description 2
- 238000007689 inspection Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/10—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by dust separating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C25/00—Foundry moulding plants
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Molds, Cores, And Manufacturing Methods Thereof (AREA)
Description
本発明は、鋳造ラインで発生する有害物質の処理方法および処理システムに関するものであり、特に鋳造ラインの集塵ダスト中に含まれる重金属やハロゲンなどの有害物質を不溶化処理する処理方法および処理システムに関するものである。 The present invention relates to a processing method and a processing system for harmful substances generated in a casting line, and more particularly, to a processing method and a processing system for insolubilizing harmful substances such as heavy metals and halogens contained in dust collection dust in a casting line. Is.
従来、鋳物工場で用いられる鋳型砂は所定の処理工程を経て鋳型原料として再利用されており、集塵ダストを含む廃棄砂はセメント原料および路盤材原料として再利用されてきた。しかしながら、近年の土壌を含めた環境浄化の規制強化により、環境省告示46号に示される重金属・ハロゲンなどの有害物質が土壌環境基準の溶出基準値を超えないようにする不溶化処理を実施する必要が生じてきた。 Conventionally, mold sand used in foundries has been reused as a mold raw material through a predetermined treatment process, and waste sand containing dust collection dust has been reused as a cement raw material and a roadbed material raw material. However, due to the recent tightening of environmental cleanup regulations including soil, it is necessary to implement insolubilization treatment to prevent hazardous substances such as heavy metals and halogens from the Ministry of the Environment Notification No. 46 from exceeding the elution standard value of the soil environment standard. Has arisen.
このような有害物質の不溶化処理として、例えば特許文献1には、フッ素汚染土に酸化マグネシウム等を主成分とする添加剤を添加し、混合処理することにより不溶化処理を行う技術が開示されている。
For example,
しかし、上述の処理方法を鋳造ラインに適用して集塵ダスト中に含まれる重金属・ハロゲンなどの有害物質の不溶化処理を行うためには、図2に示すように別に不溶化処理設備1を設ける必要があり、設備コストが増大するとともに、処理設備の設置場所を新たに用意しなければならないという問題があった。
However, in order to apply the above-mentioned processing method to a casting line to insolubilize harmful substances such as heavy metals and halogens contained in dust collection dust, it is necessary to provide an
そこで本発明は、鋳造ライン外に別途不溶化処理設備を必要とせず、鋳造ライン内にわずかな設備を付加するだけで、集塵ダスト中に含まれる重金属・ハロゲンなどの有害物質の不溶化処理を行うことができ、設備コストを小さくでき、設備設置のための平面スペースも小さくできる鋳造ラインで発生する有害物質の処理方法および処理システムを実現することを目的とする。 Therefore, the present invention does not require a separate insolubilization processing facility outside the casting line, and performs the insolubilization processing of harmful substances such as heavy metals and halogens contained in the dust collection dust by adding only a few facilities in the casting line. An object of the present invention is to realize a method and a system for treating harmful substances generated in a casting line that can reduce equipment costs, reduce the plane space for equipment installation.
上記目的を達成するためになされた本発明の鋳造ラインで発生する有害物質の処理方法は、鋳造ラインで発生する集塵ダスト中の有害物質を不溶化処理するための有害物質の処理方法であって、前記鋳造ラインは、鋳型への注湯後に鋳型ばらしを行う鋳型ばらし工程と、鋳型ばらし工程から排出される鋳型砂の再生処理を行う砂再生工程と、砂再生工程で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練工程と、を含む鋳型砂を再利用する再利用工程を備え、各工程および各工程を行う設備間の搬送工程、鋳型ばらし工程および砂再生工程の少なくとも1工程から発生した集塵ダストを前記混練工程に送り、不溶化剤とともに鋳物砂中に混練して不溶化処理を行うことを特徴とするものである。 The method for treating harmful substances generated in the casting line of the present invention to achieve the above object is a method for treating harmful substances for insolubilizing harmful substances in dust collection dust generated in the casting line. The casting line includes a mold breaking process for casting a mold after pouring into the mold, a sand recycling process for reclaiming the mold sand discharged from the mold breaking process, and a mold sand regenerated in the sand recycling process. A recycle process for reusing the mold sand, including a kneading process for kneading with unused foundry sand, additives, etc., and supplying it to a molding machine as a kneaded product used for mold molding. transport step between equipment performing a feature that sends a collected dust generated from at least one step of the mold shakeout process and sand reclamation process to the kneading step, the insolubilized by kneading the casting sand along with the insolubilizing agent Is shall.
なお、前記混練工程では鋳型砂の調整および不溶化処理を行うことができる。また前記有害物質は、カドミウム、六価クロム、水銀、セレン、鉛、砒素、ふっ素、ほう素等、土壌汚染対策法において土壌環境基準が規定される第二種特定有害物質のうちのすくなくとも1つである。 Incidentally, it is possible to adjust and insolubilization of the mold sand in the kneading step. In addition, the hazardous substance is at least one of cadmium, hexavalent chromium, mercury, selenium, lead, arsenic, fluorine, boron, etc., and at least one of the second class specified hazardous substances regulated by the soil pollution control law. It is.
また上記目的を達成するためになされた本発明の鋳造ラインで発生する有害物質の処理システムは、鋳物を製造する鋳造ラインから発生する集塵ダスト中の有害物質を不溶化処理するための有害物質の処理システムであって、前記鋳造ラインは、鋳型への注湯後に鋳型ばらしを行う鋳型ばらし設備と、鋳型ばらし設備で生じたばらし砂の再生処理を行う砂再生設備と、砂再生設備で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練設備と、集塵ダストを混練工程に送る設備とを備え、前記混練設備は、不溶化剤を集塵ダストとともに鋳型砂に添加する不溶化剤添加設備を備えることを特徴とするものである。 In addition, a system for treating harmful substances generated in the casting line of the present invention, which has been made to achieve the above-mentioned object, provides a harmful substance for insolubilizing harmful substances in dust collection dust generated from a casting line for producing castings. In the processing system, the casting line is regenerated by a mold separation facility that performs mold separation after pouring into the mold, a sand regeneration facility that regenerates loose sand generated in the mold separation facility, and a sand regeneration facility. A kneading facility for kneading the cast sand with unused foundry sand, additives, etc., and supplying it to a molding machine as a kneaded product used for mold molding, and a facility for sending dust collection dust to the kneading process, Is characterized by comprising an insolubilizing agent addition facility for adding the insolubilizing agent together with dust collecting dust to the mold sand.
本発明によれば、鋳造ラインから発生する集塵ダストを混練工程に送り、不溶化剤とともに鋳物砂中に混練して不溶化処理を行う。このため、集塵ダスト中に含まれる重金属・ハロゲンなどの有害物質の不溶化処理を行うための専用設備を必要としない。このため、設備コストを小さくでき、設備設置のための平面スペースも小さくすることができる。また本発明により処理された鋳物砂をセメント原料や路盤材原料などとして再利用する場合にも、有害物質が溶出することがなく、土壌環境基準の溶出基準値を超えるおそれがない。 According to the present invention, the dust collection dust generated from the casting line is sent to the kneading step, and kneaded in the foundry sand together with the insolubilizing agent to perform insolubilization treatment. For this reason, a dedicated facility for insolubilizing hazardous substances such as heavy metals and halogens contained in the dust collection dust is not required. For this reason, equipment cost can be made small and the plane space for equipment installation can also be made small. Further, when the foundry sand treated according to the present invention is reused as a cement raw material or a roadbed material raw material, no harmful substances are eluted and there is no possibility of exceeding the elution standard value of the soil environment standard.
以下に図1を参照しつつ、本発明の実施形態を説明する。
図1に示す鋳造ラインにおいて、10は混練設備を備えた混練工程であり、砂再生工程11から搬送された鋳型砂と、未使用の鋳物砂及び副資材を混練して鋳型造型に使用する混練物とする。副資材は粘土、樹脂等の結合剤であり、所定量の水とともに混練調整を行い、混練された鋳型砂は造型工程12に送られる。造型工程12ではこの鋳型砂を用いて鋳型を造型し、次に注湯工程13においてこの鋳型中に金属溶湯が注湯され、鋳造が行われる。
Hereinafter, an embodiment of the present invention will be described with reference to FIG.
In the casting line shown in FIG. 1,
注湯工程13の後に冷却された鋳型は鋳型ばらし設備を備えた鋳型ばらし工程14に送られ、鋳造品と鋳型砂とが分離される。分離された鋳型砂は砂再生設備を備えた砂再生工程11に送られ、磁選機による鉄片等の分離、砂表面からの結合剤の剥離、微粉の篩い分け、サンドクーラによる冷却などを行って鋳型砂を再生する。このように鋳型ばらし工程14と、砂再生工程11と、混練工程10とにより、鋳型砂を再利用する再利用工程が構成されている。
The mold cooled after the
なお、鋳型ばらし工程14で分離された鋳造品の表面に付着している鋳物砂は、砂付き鋳物清掃工程15において分離され、砂再生工程11に送られる。一方、砂付き鋳物清掃工程15において砂が取り除かれた鋳造品は、仕上げ工程16、検査工程17などを経て出荷される。
In addition, the foundry sand adhering to the surface of the cast product separated in the mold separating process 14 is separated in the cast-with-sand cleaning process 15 and sent to the
前述したように、上記した鋳造ラインにおいては重金属やハロゲンなどの有害物質を含むダストが発生するため、集塵装置20による集塵が行われる。ダストの発生部位は、各工程および各工程を行う設備間の搬送工程であるが、特に鋳型ばらし工程14および砂再生工程11では多量のダストが発生するので、少なくともこれらのうちの1工程において集塵が行われる。
As described above, dust containing harmful substances such as heavy metals and halogens is generated in the above-described casting line, so that dust collection by the
集塵装置20により捕集された集塵ダスト中には、カドミウム、六価クロム、水銀、セレン、鉛、砒素、ふっ素、ほう素等、土壌汚染対策法において土壌環境基準が規定される第二種特定有害物質のうちの少なくとも1つが含まれている。本発明ではこのような有害物質を含む集塵ダストを、ベルトコンベヤや輸送管などのダスト搬送手段21により、混練工程10に送る。搬送中に集塵ダストが飛散しないように、ダスト搬送手段21は密閉構造であることが好ましい。
The dust collected by the
混練工程10には、不溶化剤を集塵ダストとともに鋳型砂に添加する不溶化剤添加設備が設けられている。不溶化剤としては、酸化マグネシウム、酸化マグネシウム含有剤と塩化第二鉄、塩化カルシウム、珪酸アルカリ金属塩、酸化カルシウムとカルシウムアルミネート、カルシウムアルミネートと珪酸カルシウムなどを用いることができる。
The kneading
特に環境基準値が厳しいふっ素及びその化合物と、ほう素及びその化合物の不溶化処理には、酸化マグネシウム系の不溶化剤が適している。この実施形態では、酸化マグネシウム系の不溶化剤を粉体の状態で添加した。不溶化剤添加設備は、タンク中から不溶化剤を定量供給することができる構造とすることが好ましい。 Fluorine and its compounds, which have particularly strict environmental standards, and magnesium oxide-based insolubilizers are suitable for insolubilizing boron and its compounds. In this embodiment, a magnesium oxide-based insolubilizing agent is added in a powder state. It is preferable that the insolubilizing agent addition facility has a structure capable of supplying a constant amount of the insolubilizing agent from the tank.
このようにして有害物質を含む集塵ダストを混練工程10に送り、鋳型砂及び不溶化剤とともに混練すれば、不溶化剤と反応した有害物質は鋳型砂に溶出しない状態で固定される。この鋳型砂はそのまま鋳型に使用することができる。また廃棄砂としてセメント原料や路盤材原料として再利用する場合にも、環境省告示46号に示される重金属・ハロゲンなどの有害物質が土壌環境基準の溶出基準値を超えることがない。
In this way, if dust collection dust containing harmful substances is sent to the kneading
また本発明によれば、集塵機を備えた既存の鋳造ライン中に、集塵ダストを混練工程10に搬送するダスト搬送手段21と不溶化剤添加設備とを増設するだけでよく、不溶化処理設備を別途設ける必要がないので設備コストが安く、処理設備の設置場所を新たに用意する必要もない。
Further, according to the present invention, in the existing casting line equipped with the dust collector, it is only necessary to add the dust transport means 21 for transporting the dust collection dust to the kneading
1 不溶化処理設備
10 混練工程
11 砂再生工程
12 造型工程
13 注湯工程
14 鋳型ばらし工程
15 砂付き鋳物清掃工程
16 仕上げ工程
17 検査工程
20 集塵装置
DESCRIPTION OF
Claims (4)
前記鋳造ラインは、
鋳型への注湯後に鋳型ばらしを行う鋳型ばらし工程と、
鋳型ばらし工程から排出される鋳型砂の再生処理を行う砂再生工程と、
砂再生工程で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練工程と、を含む鋳型砂を再利用する再利用工程を備え、
各工程および各工程を行う設備間の搬送工程、鋳型ばらし工程および砂再生工程の少なくとも1工程から発生した集塵ダストを前記混練工程に送り、不溶化剤とともに鋳物砂中に混練して不溶化処理を行うことを特徴とする鋳造ラインで発生する有害物質の処理方法。 A method for treating harmful substances for insolubilizing harmful substances in dust collection dust generated in a casting line,
The casting line is
A mold spreading process for casting mold after pouring into mold,
A sand regeneration process for regenerating the mold sand discharged from the mold separation process;
Reusing mold sand, including kneading the mold sand regenerated in the sand reclamation process with unused foundry sand, additives, etc., and supplying it to the molding machine as a kneaded product used for mold molding With a process,
Transport step between equipment performing each step and each process sends a collected dust generated from at least one step of the mold shakeout process and sand reclamation process to the kneading step, the kneading to insolubilized to sand along with the insolubilizing agent A method for treating harmful substances generated in a casting line.
前記鋳造ラインは、
鋳型への注湯後に鋳型ばらしを行う鋳型ばらし設備と、
鋳型ばらし設備で生じたばらし砂の再生処理を行う砂再生設備と、
砂再生設備で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練設備と、
集塵ダストを混練工程に送る設備とを備え、
前記混練設備は、不溶化剤を集塵ダストとともに鋳型砂に添加する不溶化剤添加設備を備えることを特徴とする鋳造ラインで発生する有害物質の処理システム。 A hazardous substance processing system for insolubilizing harmful substances in dust collection dust generated from a casting line for producing castings,
The casting line is
A mold disassembly facility that performs mold disassembly after pouring into the mold,
Sand reclamation equipment for reclaiming loose sand generated in the mold bulk equipment;
A kneading facility for kneading mold sand regenerated in the sand recycling facility with unused foundry sand, additives, etc., and supplying it to a molding machine as a kneaded product used for mold molding;
Equipment to send dust collection dust to the kneading process,
The said kneading | mixing equipment is equipped with the insolubilizing agent addition equipment which adds an insolubilizing agent to mold sand with dust collection dust, The processing system of the harmful | toxic substance generate | occur | produced in the casting line characterized by the above-mentioned.
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JP2010167793A JP5435364B2 (en) | 2010-07-27 | 2010-07-27 | Processing method and processing system for harmful substances generated in casting line |
BR112012033401A BR112012033401A2 (en) | 2010-07-27 | 2011-07-05 | method and system for treating hazardous materials that were generated in a foundry line. |
CN2011800317730A CN102958627A (en) | 2010-07-27 | 2011-07-05 | Method and system for treating hazardous materials that have been generated in foundry line |
PCT/JP2011/003836 WO2012014383A1 (en) | 2010-07-27 | 2011-07-05 | A method and a system for treating hazardous materials that have been generated in a foundry line |
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CN2085687U (en) * | 1990-10-09 | 1991-10-02 | 华中理工大学 | Centrifugal self-circular sand reclaiming machine |
CH687858A5 (en) * | 1992-07-01 | 1997-03-14 | Fischer Georg Giessereianlagen | Means for regenerating foundry sand. |
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