JP5435364B2 - Processing method and processing system for harmful substances generated in casting line - Google Patents

Processing method and processing system for harmful substances generated in casting line Download PDF

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JP5435364B2
JP5435364B2 JP2010167793A JP2010167793A JP5435364B2 JP 5435364 B2 JP5435364 B2 JP 5435364B2 JP 2010167793 A JP2010167793 A JP 2010167793A JP 2010167793 A JP2010167793 A JP 2010167793A JP 5435364 B2 JP5435364 B2 JP 5435364B2
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mold
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kneading
casting line
harmful substances
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JP2012024826A (en
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真希 鈴木
寛之 天野
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Sintokogio Ltd
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Priority to CN2011800317730A priority patent/CN102958627A/en
Priority to PCT/JP2011/003836 priority patent/WO2012014383A1/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C5/00Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
    • B22C5/10Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by dust separating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C25/00Foundry moulding plants

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Description

本発明は、鋳造ラインで発生する有害物質の処理方法および処理システムに関するものであり、特に鋳造ラインの集塵ダスト中に含まれる重金属やハロゲンなどの有害物質を不溶化処理する処理方法および処理システムに関するものである。   The present invention relates to a processing method and a processing system for harmful substances generated in a casting line, and more particularly, to a processing method and a processing system for insolubilizing harmful substances such as heavy metals and halogens contained in dust collection dust in a casting line. Is.

従来、鋳物工場で用いられる鋳型砂は所定の処理工程を経て鋳型原料として再利用されており、集塵ダストを含む廃棄砂はセメント原料および路盤材原料として再利用されてきた。しかしながら、近年の土壌を含めた環境浄化の規制強化により、環境省告示46号に示される重金属・ハロゲンなどの有害物質が土壌環境基準の溶出基準値を超えないようにする不溶化処理を実施する必要が生じてきた。   Conventionally, mold sand used in foundries has been reused as a mold raw material through a predetermined treatment process, and waste sand containing dust collection dust has been reused as a cement raw material and a roadbed material raw material. However, due to the recent tightening of environmental cleanup regulations including soil, it is necessary to implement insolubilization treatment to prevent hazardous substances such as heavy metals and halogens from the Ministry of the Environment Notification No. 46 from exceeding the elution standard value of the soil environment standard. Has arisen.

このような有害物質の不溶化処理として、例えば特許文献1には、フッ素汚染土に酸化マグネシウム等を主成分とする添加剤を添加し、混合処理することにより不溶化処理を行う技術が開示されている。   For example, Patent Document 1 discloses a technique for performing an insolubilization process by adding an additive containing magnesium oxide or the like as a main component to fluorine-contaminated soil and performing a mixing process. .

特開2005−324083号公報JP 2005-324083 A

しかし、上述の処理方法を鋳造ラインに適用して集塵ダスト中に含まれる重金属・ハロゲンなどの有害物質の不溶化処理を行うためには、図2に示すように別に不溶化処理設備1を設ける必要があり、設備コストが増大するとともに、処理設備の設置場所を新たに用意しなければならないという問題があった。   However, in order to apply the above-mentioned processing method to a casting line to insolubilize harmful substances such as heavy metals and halogens contained in dust collection dust, it is necessary to provide an insolubilization treatment facility 1 as shown in FIG. As a result, the equipment cost increases, and there is a problem that a new installation site for the processing equipment has to be prepared.

そこで本発明は、鋳造ライン外に別途不溶化処理設備を必要とせず、鋳造ライン内にわずかな設備を付加するだけで、集塵ダスト中に含まれる重金属・ハロゲンなどの有害物質の不溶化処理を行うことができ、設備コストを小さくでき、設備設置のための平面スペースも小さくできる鋳造ラインで発生する有害物質の処理方法および処理システムを実現することを目的とする。   Therefore, the present invention does not require a separate insolubilization processing facility outside the casting line, and performs the insolubilization processing of harmful substances such as heavy metals and halogens contained in the dust collection dust by adding only a few facilities in the casting line. An object of the present invention is to realize a method and a system for treating harmful substances generated in a casting line that can reduce equipment costs, reduce the plane space for equipment installation.

上記目的を達成するためになされた本発明の鋳造ラインで発生する有害物質の処理方法は、鋳造ラインで発生する集塵ダスト中の有害物質を不溶化処理するための有害物質の処理方法であって、前記鋳造ラインは、鋳型への注湯後に鋳型ばらしを行う鋳型ばらし工程と、鋳型ばらし工程から排出される鋳型砂の再生処理を行う砂再生工程と、砂再生工程で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練工程と、を含む鋳型砂を再利用する再利用工程を備え、各工程および各工程を行う設備間の搬送工程、鋳型ばらし工程および砂再生工程の少なくとも1工程から発生した集塵ダストを前記混練工程に送り、不溶化剤とともに鋳物砂中に混練して不溶化処理を行うことを特徴とするものである。 The method for treating harmful substances generated in the casting line of the present invention to achieve the above object is a method for treating harmful substances for insolubilizing harmful substances in dust collection dust generated in the casting line. The casting line includes a mold breaking process for casting a mold after pouring into the mold, a sand recycling process for reclaiming the mold sand discharged from the mold breaking process, and a mold sand regenerated in the sand recycling process. A recycle process for reusing the mold sand, including a kneading process for kneading with unused foundry sand, additives, etc., and supplying it to a molding machine as a kneaded product used for mold molding. transport step between equipment performing a feature that sends a collected dust generated from at least one step of the mold shakeout process and sand reclamation process to the kneading step, the insolubilized by kneading the casting sand along with the insolubilizing agent Is shall.

なお、前記混練工程では鋳型砂の調整および不溶化処理を行うことができる。また前記有害物質は、カドミウム、六価クロム、水銀、セレン、鉛、砒素、ふっ素、ほう素等、土壌汚染対策法において土壌環境基準が規定される第二種特定有害物質のうちのすくなくとも1つである。 Incidentally, it is possible to adjust and insolubilization of the mold sand in the kneading step. In addition, the hazardous substance is at least one of cadmium, hexavalent chromium, mercury, selenium, lead, arsenic, fluorine, boron, etc., and at least one of the second class specified hazardous substances regulated by the soil pollution control law. It is.

また上記目的を達成するためになされた本発明の鋳造ラインで発生する有害物質の処理システムは、鋳物を製造する鋳造ラインから発生する集塵ダスト中の有害物質を不溶化処理するための有害物質の処理システムであって、前記鋳造ラインは、鋳型への注湯後に鋳型ばらしを行う鋳型ばらし設備と、鋳型ばらし設備で生じたばらし砂の再生処理を行う砂再生設備と、砂再生設備で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練設備と、集塵ダストを混練工程に送る設備とを備え、前記混練設備は、不溶化剤を集塵ダストとともに鋳型砂に添加する不溶化剤添加設備を備えることを特徴とするものである。   In addition, a system for treating harmful substances generated in the casting line of the present invention, which has been made to achieve the above-mentioned object, provides a harmful substance for insolubilizing harmful substances in dust collection dust generated from a casting line for producing castings. In the processing system, the casting line is regenerated by a mold separation facility that performs mold separation after pouring into the mold, a sand regeneration facility that regenerates loose sand generated in the mold separation facility, and a sand regeneration facility. A kneading facility for kneading the cast sand with unused foundry sand, additives, etc., and supplying it to a molding machine as a kneaded product used for mold molding, and a facility for sending dust collection dust to the kneading process, Is characterized by comprising an insolubilizing agent addition facility for adding the insolubilizing agent together with dust collecting dust to the mold sand.

本発明によれば、鋳造ラインから発生する集塵ダストを混練工程に送り、不溶化剤とともに鋳物砂中に混練して不溶化処理を行う。このため、集塵ダスト中に含まれる重金属・ハロゲンなどの有害物質の不溶化処理を行うための専用設備を必要としない。このため、設備コストを小さくでき、設備設置のための平面スペースも小さくすることができる。また本発明により処理された鋳物砂をセメント原料や路盤材原料などとして再利用する場合にも、有害物質が溶出することがなく、土壌環境基準の溶出基準値を超えるおそれがない。   According to the present invention, the dust collection dust generated from the casting line is sent to the kneading step, and kneaded in the foundry sand together with the insolubilizing agent to perform insolubilization treatment. For this reason, a dedicated facility for insolubilizing hazardous substances such as heavy metals and halogens contained in the dust collection dust is not required. For this reason, equipment cost can be made small and the plane space for equipment installation can also be made small. Further, when the foundry sand treated according to the present invention is reused as a cement raw material or a roadbed material raw material, no harmful substances are eluted and there is no possibility of exceeding the elution standard value of the soil environment standard.

本発明の実施形態を示すフロー図である。It is a flowchart which shows embodiment of this invention. 従来例を示すフロー図である。It is a flowchart which shows a prior art example.

以下に図1を参照しつつ、本発明の実施形態を説明する。
図1に示す鋳造ラインにおいて、10は混練設備を備えた混練工程であり、砂再生工程11から搬送された鋳型砂と、未使用の鋳物砂及び副資材を混練して鋳型造型に使用する混練物とする。副資材は粘土、樹脂等の結合剤であり、所定量の水とともに混練調整を行い、混練された鋳型砂は造型工程12に送られる。造型工程12ではこの鋳型砂を用いて鋳型を造型し、次に注湯工程13においてこの鋳型中に金属溶湯が注湯され、鋳造が行われる。
Hereinafter, an embodiment of the present invention will be described with reference to FIG.
In the casting line shown in FIG. 1, reference numeral 10 denotes a kneading process equipped with a kneading facility, and kneading the mold sand conveyed from the sand regeneration process 11 and unused casting sand and auxiliary materials to be used for mold molding. It is a thing. The auxiliary material is a binder such as clay and resin, and kneading adjustment is performed with a predetermined amount of water, and the kneaded mold sand is sent to the molding step 12. In the molding process 12, a mold is molded using the mold sand, and then in the pouring process 13, a molten metal is poured into the mold to perform casting.

注湯工程13の後に冷却された鋳型は鋳型ばらし設備を備えた鋳型ばらし工程14に送られ、鋳造品と鋳型砂とが分離される。分離された鋳型砂は砂再生設備を備えた砂再生工程11に送られ、磁選機による鉄片等の分離、砂表面からの結合剤の剥離、微粉の篩い分け、サンドクーラによる冷却などを行って鋳型砂を再生する。このように鋳型ばらし工程14と、砂再生工程11と、混練工程10とにより、鋳型砂を再利用する再利用工程が構成されている。   The mold cooled after the pouring process 13 is sent to a mold spreading process 14 equipped with a mold spreading facility, and the cast product and the mold sand are separated. The separated mold sand is sent to a sand regeneration process 11 equipped with a sand regeneration facility, and the separation of iron pieces and the like by a magnetic separator, separation of the binder from the sand surface, sieving of fine powder, and cooling by a sand cooler are performed. Recycle the mold sand. As described above, the mold separation step 14, the sand regeneration step 11, and the kneading step 10 constitute a reuse step for reusing the mold sand.

なお、鋳型ばらし工程14で分離された鋳造品の表面に付着している鋳物砂は、砂付き鋳物清掃工程15において分離され、砂再生工程11に送られる。一方、砂付き鋳物清掃工程15において砂が取り除かれた鋳造品は、仕上げ工程16、検査工程17などを経て出荷される。   In addition, the foundry sand adhering to the surface of the cast product separated in the mold separating process 14 is separated in the cast-with-sand cleaning process 15 and sent to the sand recycling process 11. On the other hand, the cast product from which sand has been removed in the casting casting process with sand 15 is shipped through a finishing process 16, an inspection process 17, and the like.

前述したように、上記した鋳造ラインにおいては重金属やハロゲンなどの有害物質を含むダストが発生するため、集塵装置20による集塵が行われる。ダストの発生部位は、各工程および各工程を行う設備間の搬送工程であるが、特に鋳型ばらし工程14および砂再生工程11では多量のダストが発生するので、少なくともこれらのうちの1工程において集塵が行われる。   As described above, dust containing harmful substances such as heavy metals and halogens is generated in the above-described casting line, so that dust collection by the dust collector 20 is performed. The dust generation site is each process and the transfer process between the facilities that perform each process. However, a large amount of dust is generated particularly in the mold separation process 14 and the sand recycling process 11, so at least one of these processes collects dust. Dust is done.

集塵装置20により捕集された集塵ダスト中には、カドミウム、六価クロム、水銀、セレン、鉛、砒素、ふっ素、ほう素等、土壌汚染対策法において土壌環境基準が規定される第二種特定有害物質のうちの少なくとも1つが含まれている。本発明ではこのような有害物質を含む集塵ダストを、ベルトコンベヤや輸送管などのダスト搬送手段21により、混練工程10に送る。搬送中に集塵ダストが飛散しないように、ダスト搬送手段21は密閉構造であることが好ましい。   The dust collected by the dust collector 20 is cadmium, hexavalent chromium, mercury, selenium, lead, arsenic, fluorine, boron, etc., and the soil environment standards are stipulated in the Soil Contamination Countermeasures Law. Contains at least one of the species-specific hazardous substances. In the present invention, the dust collecting dust containing such harmful substances is sent to the kneading step 10 by the dust conveying means 21 such as a belt conveyor or a transport pipe. The dust transfer means 21 preferably has a sealed structure so that dust collection dust does not scatter during transfer.

混練工程10には、不溶化剤を集塵ダストとともに鋳型砂に添加する不溶化剤添加設備が設けられている。不溶化剤としては、酸化マグネシウム、酸化マグネシウム含有剤と塩化第二鉄、塩化カルシウム、珪酸アルカリ金属塩、酸化カルシウムとカルシウムアルミネート、カルシウムアルミネートと珪酸カルシウムなどを用いることができる。   The kneading step 10 is provided with an insolubilizing agent addition facility for adding the insolubilizing agent to the mold sand together with dust collection dust. As the insolubilizer, magnesium oxide, magnesium oxide-containing agent and ferric chloride, calcium chloride, alkali metal silicate, calcium oxide and calcium aluminate, calcium aluminate and calcium silicate, and the like can be used.

特に環境基準値が厳しいふっ素及びその化合物と、ほう素及びその化合物の不溶化処理には、酸化マグネシウム系の不溶化剤が適している。この実施形態では、酸化マグネシウム系の不溶化剤を粉体の状態で添加した。不溶化剤添加設備は、タンク中から不溶化剤を定量供給することができる構造とすることが好ましい。   Fluorine and its compounds, which have particularly strict environmental standards, and magnesium oxide-based insolubilizers are suitable for insolubilizing boron and its compounds. In this embodiment, a magnesium oxide-based insolubilizing agent is added in a powder state. It is preferable that the insolubilizing agent addition facility has a structure capable of supplying a constant amount of the insolubilizing agent from the tank.

このようにして有害物質を含む集塵ダストを混練工程10に送り、鋳型砂及び不溶化剤とともに混練すれば、不溶化剤と反応した有害物質は鋳型砂に溶出しない状態で固定される。この鋳型砂はそのまま鋳型に使用することができる。また廃棄砂としてセメント原料や路盤材原料として再利用する場合にも、環境省告示46号に示される重金属・ハロゲンなどの有害物質が土壌環境基準の溶出基準値を超えることがない。   In this way, if dust collection dust containing harmful substances is sent to the kneading step 10 and kneaded together with the mold sand and the insolubilizing agent, the harmful substances that have reacted with the insolubilizing agent are fixed in a state where they are not eluted into the mold sand. This mold sand can be used as a mold as it is. In addition, even when reusing as waste sand as cement raw material or roadbed material raw material, hazardous substances such as heavy metals and halogens shown in Ministry of the Environment Notification No. 46 do not exceed the elution standard value of the soil environment standard.

また本発明によれば、集塵機を備えた既存の鋳造ライン中に、集塵ダストを混練工程10に搬送するダスト搬送手段21と不溶化剤添加設備とを増設するだけでよく、不溶化処理設備を別途設ける必要がないので設備コストが安く、処理設備の設置場所を新たに用意する必要もない。   Further, according to the present invention, in the existing casting line equipped with the dust collector, it is only necessary to add the dust transport means 21 for transporting the dust collection dust to the kneading step 10 and the insolubilizing agent addition equipment, and the insolubilization processing equipment is separately provided. Since there is no need to provide the equipment, the equipment cost is low, and there is no need to prepare a new place for installing the treatment equipment.

1 不溶化処理設備
10 混練工程
11 砂再生工程
12 造型工程
13 注湯工程
14 鋳型ばらし工程
15 砂付き鋳物清掃工程
16 仕上げ工程
17 検査工程
20 集塵装置
DESCRIPTION OF SYMBOLS 1 Insolubilization processing equipment 10 Kneading process 11 Sand reproduction process 12 Molding process 13 Pouring process 14 Mold casting process 15 Casting cleaning process with sand 16 Finishing process 17 Inspection process 20 Dust collector

Claims (4)

鋳造ラインで発生する集塵ダスト中の有害物質を不溶化処理するための有害物質の処理方法であって、
前記鋳造ラインは、
鋳型への注湯後に鋳型ばらしを行う鋳型ばらし工程と、
鋳型ばらし工程から排出される鋳型砂の再生処理を行う砂再生工程と、
砂再生工程で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練工程と、を含む鋳型砂を再利用する再利用工程を備え、
各工程および各工程を行う設備間の搬送工程、鋳型ばらし工程および砂再生工程の少なくとも1工程から発生した集塵ダストを前記混練工程に送り、不溶化剤とともに鋳物砂中に混練して不溶化処理を行うことを特徴とする鋳造ラインで発生する有害物質の処理方法。
A method for treating harmful substances for insolubilizing harmful substances in dust collection dust generated in a casting line,
The casting line is
A mold spreading process for casting mold after pouring into mold,
A sand regeneration process for regenerating the mold sand discharged from the mold separation process;
Reusing mold sand, including kneading the mold sand regenerated in the sand reclamation process with unused foundry sand, additives, etc., and supplying it to the molding machine as a kneaded product used for mold molding With a process,
Transport step between equipment performing each step and each process sends a collected dust generated from at least one step of the mold shakeout process and sand reclamation process to the kneading step, the kneading to insolubilized to sand along with the insolubilizing agent A method for treating harmful substances generated in a casting line.
前記混練工程では鋳型砂の調整および不溶化処理を行うことを特徴とする請求項1記載の鋳造ラインで発生する有害物質の処理方法。 The method for treating harmful substances generated in a casting line according to claim 1, wherein in the kneading step, the mold sand is adjusted and insolubilized. 前記有害物質は、カドミウム、六価クロム、水銀、セレン、鉛、砒素、ふっ素、ほう素等、土壌汚染対策法において土壌環境基準が規定される第二種特定有害物質のうちのすくなくとも1つであることを特徴とする請求項1記載の鋳造ラインで発生する有害物質の処理方法。   The hazardous substance is at least one of the Specified Hazardous Substances of the second kind specified in the soil pollution control law, such as cadmium, hexavalent chromium, mercury, selenium, lead, arsenic, fluorine, boron, etc. The method for treating harmful substances generated in a casting line according to claim 1. 鋳物を製造する鋳造ラインから発生する集塵ダスト中の有害物質を不溶化処理するための有害物質の処理システムであって、
前記鋳造ラインは、
鋳型への注湯後に鋳型ばらしを行う鋳型ばらし設備と、
鋳型ばらし設備で生じたばらし砂の再生処理を行う砂再生設備と、
砂再生設備で再生された鋳型砂を未使用の鋳物砂、添加剤等と混練し、鋳型造型に使用する混練物として造型機に供給する混練設備と、
集塵ダストを混練工程に送る設備とを備え、
前記混練設備は、不溶化剤を集塵ダストとともに鋳型砂に添加する不溶化剤添加設備を備えることを特徴とする鋳造ラインで発生する有害物質の処理システム。
A hazardous substance processing system for insolubilizing harmful substances in dust collection dust generated from a casting line for producing castings,
The casting line is
A mold disassembly facility that performs mold disassembly after pouring into the mold,
Sand reclamation equipment for reclaiming loose sand generated in the mold bulk equipment;
A kneading facility for kneading mold sand regenerated in the sand recycling facility with unused foundry sand, additives, etc., and supplying it to a molding machine as a kneaded product used for mold molding;
Equipment to send dust collection dust to the kneading process,
The said kneading | mixing equipment is equipped with the insolubilizing agent addition equipment which adds an insolubilizing agent to mold sand with dust collection dust, The processing system of the harmful | toxic substance generate | occur | produced in the casting line characterized by the above-mentioned.
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BR112012033401A BR112012033401A2 (en) 2010-07-27 2011-07-05 method and system for treating hazardous materials that were generated in a foundry line.
CN2011800317730A CN102958627A (en) 2010-07-27 2011-07-05 Method and system for treating hazardous materials that have been generated in foundry line
PCT/JP2011/003836 WO2012014383A1 (en) 2010-07-27 2011-07-05 A method and a system for treating hazardous materials that have been generated in a foundry line

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CH687858A5 (en) * 1992-07-01 1997-03-14 Fischer Georg Giessereianlagen Means for regenerating foundry sand.
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