JP5412050B2 - 改変eu−1ゼオライトおよび芳香族c8化合物の異性化におけるその使用 - Google Patents

改変eu−1ゼオライトおよび芳香族c8化合物の異性化におけるその使用 Download PDF

Info

Publication number
JP5412050B2
JP5412050B2 JP2008112062A JP2008112062A JP5412050B2 JP 5412050 B2 JP5412050 B2 JP 5412050B2 JP 2008112062 A JP2008112062 A JP 2008112062A JP 2008112062 A JP2008112062 A JP 2008112062A JP 5412050 B2 JP5412050 B2 JP 5412050B2
Authority
JP
Japan
Prior art keywords
zeolite
modified
catalyst
aluminum atoms
present
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2008112062A
Other languages
English (en)
Japanese (ja)
Other versions
JP2008279440A5 (enExample
JP2008279440A (ja
Inventor
ギュイヨン エマニュエル
サンチェス エリック
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of JP2008279440A publication Critical patent/JP2008279440A/ja
Publication of JP2008279440A5 publication Critical patent/JP2008279440A5/ja
Application granted granted Critical
Publication of JP5412050B2 publication Critical patent/JP5412050B2/ja
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/7246EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74Noble metals
    • B01J29/7446EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C07C5/27Rearrangement of carbon atoms in the hydrocarbon skeleton
    • C07C5/2767Changing the number of side-chains
    • C07C5/277Catalytic processes
    • C07C5/2775Catalytic processes with crystalline alumino-silicates, e.g. molecular sieves
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/14After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/16After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/20After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/22After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/36Steaming
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2008112062A 2007-04-23 2008-04-23 改変eu−1ゼオライトおよび芳香族c8化合物の異性化におけるその使用 Expired - Fee Related JP5412050B2 (ja)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0702943A FR2915113B1 (fr) 2007-04-23 2007-04-23 Zeolithe eu-1 modifiee et son utilisation en isomerisation des composes c8 aromatiques.
FR0702943 2007-04-23

Publications (3)

Publication Number Publication Date
JP2008279440A JP2008279440A (ja) 2008-11-20
JP2008279440A5 JP2008279440A5 (enExample) 2011-06-16
JP5412050B2 true JP5412050B2 (ja) 2014-02-12

Family

ID=38670532

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2008112062A Expired - Fee Related JP5412050B2 (ja) 2007-04-23 2008-04-23 改変eu−1ゼオライトおよび芳香族c8化合物の異性化におけるその使用

Country Status (7)

Country Link
US (1) US7838456B2 (enExample)
EP (1) EP1985363B1 (enExample)
JP (1) JP5412050B2 (enExample)
CN (1) CN101293211B (enExample)
DE (1) DE602008002352D1 (enExample)
FR (1) FR2915113B1 (enExample)
ZA (1) ZA200802629B (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9309170B2 (en) * 2011-11-14 2016-04-12 Uop Llc Aromatics isomerization using a dual-catalyst system
CN104888848A (zh) * 2015-05-05 2015-09-09 陕西延长石油(集团)有限责任公司炼化公司 一种c8芳烃异构化催化剂及合成方法和应用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0013617B1 (en) 1979-01-10 1984-07-04 Beecham Group Plc Penicillin derivatives, process for their preparation and pharmaceutical compositions containing certain of these compounds
FR2477903A1 (fr) 1980-03-13 1981-09-18 Inst Francais Du Petrole Nouveau catalyseur zeolithique d'isomerisation des hydrocarbures alkylaromatiques
DE3165380D1 (en) 1980-06-12 1984-09-13 Ici Plc Zeolite eu-1
DE3169731D1 (en) * 1980-11-04 1985-05-09 Teijin Petrochem Ind A catalyst composition containing as catalytically active components alumina and a cristalline aluminosilicate zeolite, a process for isomerizing xylenes and ethylbenzene, and use of this catalyst composition
US4482773A (en) 1982-02-25 1984-11-13 Mobil Oil Corporation Catalyst for xylene isomerization
US4467129A (en) 1982-11-24 1984-08-21 Toray Industries, Inc. Conversion of xylenes containing ethylbenzene
US4723051A (en) 1986-02-06 1988-02-02 Cosden Technology, Inc. Xylene isomerization process
US4665258A (en) 1986-02-06 1987-05-12 Cosden Technology, Inc. Toluene disproportionation process
GB9116499D0 (en) * 1991-07-31 1991-09-11 British Petroleum Co Plc Treatment method for zeolites
FR2765209B1 (fr) * 1997-06-25 1999-10-22 Inst Francais Du Petrole Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
FR2765206B1 (fr) * 1997-06-25 1999-08-06 Inst Francais Du Petrole Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines
EP0923987A1 (fr) * 1997-12-22 1999-06-23 Institut Français du Pétrole Catalyseur contenant une zéolithe EUO et son utilisation en isomérisation des composés C8 aromatiques
FR2808519B1 (fr) * 2000-05-05 2002-08-02 Inst Francais Du Petrole Zeolithe de type structural euo de faible rapport si/al et son utilisation en tant que catalyseur d'isomerisation des coupes c8 aromatiques
US20040054199A1 (en) * 2002-09-17 2004-03-18 Basf Aktiengesellschaft Process for epoxidation and catalyst to be used therein
EP1699556A2 (en) 2003-12-30 2006-09-13 Uop Llc Process and catalyst for c8 alkylaromatic isomerization
FR2887246B1 (fr) * 2005-06-16 2007-08-31 Inst Francais Du Petrole Zeolithe de type structural euo contenant le cation n,n-dimethyl-n,n-di(3,3-dimethylbutyl)ammonium et son procede de preparation

Also Published As

Publication number Publication date
ZA200802629B (en) 2008-12-31
CN101293211B (zh) 2012-11-07
DE602008002352D1 (de) 2010-10-14
US20080281138A1 (en) 2008-11-13
CN101293211A (zh) 2008-10-29
JP2008279440A (ja) 2008-11-20
FR2915113A1 (fr) 2008-10-24
EP1985363B1 (fr) 2010-09-01
FR2915113B1 (fr) 2009-06-26
US7838456B2 (en) 2010-11-23
EP1985363A1 (fr) 2008-10-29

Similar Documents

Publication Publication Date Title
JP6379196B2 (ja) Euo型のゼオライトの改変、および芳香族c8化合物の異性化におけるその使用
US5506182A (en) Modified zeolite Y catalyst composition
KR100565134B1 (ko) 제올라이트euo를함유하는촉매,및분자당8개의탄소원자를함유한방향족화합물의이성화반응에이촉매를사용하는방법
CN101987298B (zh) 金属改性的含euo结构的共晶沸石催化剂及制备方法和应用
JPH062578B2 (ja) ゼオライトおよびその製法
JP5379995B2 (ja) 脱アルミニウム化euoゼオライトをベースとする触媒の存在下での芳香族c8留分の異性化方法
CN112138715A (zh) 贵金属杂化分子筛的制备方法、制备的分子筛及其应用
CN107774301B (zh) 用于C8芳族馏分的异构化的包含具有最优化Si/Al摩尔比的IZM-2沸石的催化剂
CN101722020A (zh) 一种含euo结构的共晶沸石催化剂及其制备和应用
JP5291924B2 (ja) 改質euoゼオライトを含む触媒の存在下で芳香族c8化合物を異性化する方法
JP5412050B2 (ja) 改変eu−1ゼオライトおよび芳香族c8化合物の異性化におけるその使用
JP4016164B2 (ja) ゼオライトim−5をベースとする触媒を用いるパラフィン仕込原料の流動点の改良方法
US9505681B2 (en) Process for isomerizing an aromatic C8 cut in the presence of a catalyst based on an euo zeolite and a particular sodium content
JP2001504079A (ja) 脱アルミニウムゼオライトnu―86および炭化水素の転換におけるその使用法
JP2821603B2 (ja) モルデナイトおよびチタンから成るn−パラフィンの異性化触媒
US10494581B2 (en) Process for producing LPG from a heavy hydrocarbon feed
JP4928678B2 (ja) 低いSi/Al比を有するEUO構造型ゼオライトおよびC8−芳香族留分の異性化用触媒としてのその使用
US9828311B2 (en) Method for isomerizing an aromatic C8 fraction in the presence of a catalyst containing an EUO zeolite and a specific binder
US4874504A (en) pH control by bulky organic bases during noble-metal exchange of zeolite catalysts
JP2023506849A (ja) 低含有率のアルカリ金属を有するizm-2ゼオライトをベースとする触媒、および芳香族c8留分の異性化のためのその使用

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110421

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20110421

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20121206

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20130122

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20130417

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20131015

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20131111

R150 Certificate of patent or registration of utility model

Ref document number: 5412050

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees