JP5329397B2 - ガスから重金属を除去する方法 - Google Patents
ガスから重金属を除去する方法 Download PDFInfo
- Publication number
- JP5329397B2 JP5329397B2 JP2009513773A JP2009513773A JP5329397B2 JP 5329397 B2 JP5329397 B2 JP 5329397B2 JP 2009513773 A JP2009513773 A JP 2009513773A JP 2009513773 A JP2009513773 A JP 2009513773A JP 5329397 B2 JP5329397 B2 JP 5329397B2
- Authority
- JP
- Japan
- Prior art keywords
- palladium
- mercury
- gas
- absorbent
- absorbent material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 18
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract description 76
- 229910052763 palladium Inorganic materials 0.000 claims abstract description 33
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910052753 mercury Inorganic materials 0.000 claims abstract description 28
- 239000002250 absorbent Substances 0.000 claims description 48
- 230000002745 absorbent Effects 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 7
- 238000011068 loading method Methods 0.000 claims description 7
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003575 carbonaceous material Substances 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052711 selenium Inorganic materials 0.000 claims description 2
- 239000011669 selenium Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 abstract description 11
- 238000010521 absorption reaction Methods 0.000 abstract description 8
- 239000003245 coal Substances 0.000 abstract description 6
- 239000012530 fluid Substances 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 41
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000002737 fuel gas Substances 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 238000005987 sulfurization reaction Methods 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000005486 sulfidation Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 230000018199 S phase Effects 0.000 description 4
- 239000000567 combustion gas Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000011143 downstream manufacturing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- -1 mercury and arsenic Chemical class 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000010587 phase diagram Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000012696 Pd precursors Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005267 amalgamation Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000013101 initial test Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- ORLVBBQARMEANN-UHFFFAOYSA-N mercury palladium Chemical group [Pd].[Hg] ORLVBBQARMEANN-UHFFFAOYSA-N 0.000 description 1
- 229940008718 metallic mercury Drugs 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QXKXDIKCIPXUPL-UHFFFAOYSA-N sulfanylidenemercury Chemical compound [Hg]=S QXKXDIKCIPXUPL-UHFFFAOYSA-N 0.000 description 1
- NRUVOKMCGYWODZ-UHFFFAOYSA-N sulfanylidenepalladium Chemical compound [Pd]=S NRUVOKMCGYWODZ-UHFFFAOYSA-N 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/64—Heavy metals or compounds thereof, e.g. mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
- B01J20/0285—Sulfides of compounds other than those provided for in B01J20/045
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
- B01J20/3204—Inorganic carriers, supports or substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
- B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
- B01J20/3234—Inorganic material layers
- B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/60—Heavy metals or heavy metal compounds
- B01D2257/602—Mercury or mercury compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Catalysts (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0611316.1A GB0611316D0 (en) | 2006-06-09 | 2006-06-09 | Improvements in the removal of metals from fluid streams |
| GB0611316.1 | 2006-06-09 | ||
| PCT/GB2007/050321 WO2007141577A1 (en) | 2006-06-09 | 2007-06-06 | Method for removing heavy metals from gases |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2009539580A JP2009539580A (ja) | 2009-11-19 |
| JP2009539580A5 JP2009539580A5 (enExample) | 2010-07-29 |
| JP5329397B2 true JP5329397B2 (ja) | 2013-10-30 |
Family
ID=36745491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009513773A Expired - Fee Related JP5329397B2 (ja) | 2006-06-09 | 2007-06-06 | ガスから重金属を除去する方法 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8366807B2 (enExample) |
| EP (1) | EP2026898B1 (enExample) |
| JP (1) | JP5329397B2 (enExample) |
| KR (1) | KR20090031553A (enExample) |
| CN (1) | CN101466456A (enExample) |
| AU (1) | AU2007255151B2 (enExample) |
| CA (1) | CA2654787C (enExample) |
| GB (1) | GB0611316D0 (enExample) |
| RU (1) | RU2438762C2 (enExample) |
| WO (1) | WO2007141577A1 (enExample) |
| ZA (1) | ZA200810232B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB0616343D0 (en) * | 2006-08-17 | 2006-09-27 | Johnson Matthey Plc | Mercury removal |
| US8741243B2 (en) | 2007-05-14 | 2014-06-03 | Corning Incorporated | Sorbent bodies comprising activated carbon, processes for making them, and their use |
| US7998898B2 (en) | 2007-10-26 | 2011-08-16 | Corning Incorporated | Sorbent comprising activated carbon, process for making same and use thereof |
| US8563092B2 (en) | 2010-09-14 | 2013-10-22 | Jawaharial Nehru Centre For Advanced Scientific Research | Formation of palladium sulfide |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2656803C2 (de) * | 1975-12-18 | 1986-12-18 | Institut Français du Pétrole, Rueil-Malmaison, Hauts-de-Seine | Verfahren zur Entfernung von in einem Gas oder in einer Flüssigkeit vorhandenem Quecksilber |
| US4814152A (en) | 1987-10-13 | 1989-03-21 | Mobil Oil Corporation | Process for removing mercury vapor and chemisorbent composition therefor |
| FR2644472B1 (fr) * | 1989-03-16 | 1991-06-21 | Inst Francais Du Petrole | Procede pour l'elimination du mercure et eventuellement d'arsenic dans les hydrocarbures |
| US5401392A (en) * | 1989-03-16 | 1995-03-28 | Institut Francais Du Petrole | Process for eliminating mercury and possibly arsenic in hydrocarbons |
| US5053380A (en) * | 1989-12-21 | 1991-10-01 | Union Carbide Chemicals And Plastics Technology Corporation | Cu-al catalyst for hydrogenation |
| US5080799A (en) | 1990-05-23 | 1992-01-14 | Mobil Oil Corporation | Hg removal from wastewater by regenerative adsorption |
| GB9022060D0 (en) | 1990-10-10 | 1990-11-21 | Ici Plc | Mercury removal |
| US5281258A (en) * | 1992-12-21 | 1994-01-25 | Uop | Removal of mercury impurity from natural gas |
| FR2701270B1 (fr) * | 1993-02-08 | 1995-04-14 | Inst Francais Du Petrole | Procédé d'élimination du mercure dans les hydrocarbures par passage sur un catalyseur présulfuré. |
| FR2701269B1 (fr) | 1993-02-08 | 1995-04-14 | Inst Francais Du Petrole | Procédé d'élimination d'arsenic dans des hydrocarbures par passage sur une masse de captation présulfurée. |
| RU2035993C1 (ru) * | 1993-09-30 | 1995-05-27 | Александр Ефимович Горенбейн | Способ получения сорбентов для очистки газов от ртути |
| JPH11104432A (ja) * | 1997-09-30 | 1999-04-20 | Kawasaki Heavy Ind Ltd | ガス処理方法及び装置 |
| US7033419B1 (en) * | 2003-09-16 | 2006-04-25 | The United States Of America As Represented By The United States Department Of Energy | Method for high temperature mercury capture from gas streams |
-
2006
- 2006-06-09 GB GBGB0611316.1A patent/GB0611316D0/en not_active Ceased
-
2007
- 2007-06-06 WO PCT/GB2007/050321 patent/WO2007141577A1/en not_active Ceased
- 2007-06-06 JP JP2009513773A patent/JP5329397B2/ja not_active Expired - Fee Related
- 2007-06-06 US US12/304,063 patent/US8366807B2/en not_active Expired - Fee Related
- 2007-06-06 CA CA2654787A patent/CA2654787C/en not_active Expired - Fee Related
- 2007-06-06 RU RU2008152116/05A patent/RU2438762C2/ru not_active IP Right Cessation
- 2007-06-06 EP EP07733742.6A patent/EP2026898B1/en not_active Not-in-force
- 2007-06-06 KR KR1020097000275A patent/KR20090031553A/ko not_active Ceased
- 2007-06-06 CN CNA2007800213491A patent/CN101466456A/zh active Pending
- 2007-06-06 ZA ZA200810232A patent/ZA200810232B/xx unknown
- 2007-06-06 AU AU2007255151A patent/AU2007255151B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| AU2007255151B2 (en) | 2011-12-08 |
| WO2007141577A1 (en) | 2007-12-13 |
| KR20090031553A (ko) | 2009-03-26 |
| JP2009539580A (ja) | 2009-11-19 |
| AU2007255151A1 (en) | 2007-12-13 |
| RU2008152116A (ru) | 2010-07-20 |
| RU2438762C2 (ru) | 2012-01-10 |
| ZA200810232B (en) | 2010-03-31 |
| EP2026898B1 (en) | 2014-10-01 |
| US20100229722A1 (en) | 2010-09-16 |
| GB0611316D0 (en) | 2006-07-19 |
| US8366807B2 (en) | 2013-02-05 |
| CA2654787A1 (en) | 2007-12-13 |
| EP2026898A1 (en) | 2009-02-25 |
| CA2654787C (en) | 2014-09-16 |
| CN101466456A (zh) | 2009-06-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Chai et al. | Effect of CO2 adsorbents on the Ni‐based dual‐function materials for CO2 capturing and in situ methanation | |
| JP5662162B2 (ja) | ガス流からの汚染物質除去 | |
| Yi et al. | Effects of preparation conditions for active carbon-based catalyst on catalytic hydrolysis of carbon disulfide | |
| CN102357364A (zh) | 用于烟气选择性还原脱硫的活性炭基催化剂的制备 | |
| JP2012508102A (ja) | 汚染物除去用の複数の固定−流動床 | |
| JP2930409B2 (ja) | 硫化物含有ガスの精製法 | |
| JP5329397B2 (ja) | ガスから重金属を除去する方法 | |
| Hao et al. | Constructing and synthesizing optimal Cu-BTC and its application in low-temperature denitration | |
| Wu et al. | Development of iron oxide sorbents for Hg0 removal from coal derived fuel gas: Sulfidation characteristics of iron oxide sorbents and activity for COS formation during Hg0 removal | |
| Tepluchin et al. | Study on the hydrothermal and SO2 stability of Al2O3-supported manganese and iron oxide catalysts for lean CO oxidation | |
| Lincke et al. | Chemoadsorption for separation of hydrogen sulfide from biogas with iron hydroxide and sulfur recovery | |
| CN102316959A (zh) | 从含水的气流除去污染物的方法 | |
| Zhang et al. | Simultaneous removal of elemental mercury and arsine from a reducing atmosphere using chloride and cerium modified activated carbon | |
| Ma et al. | Enhancement of Hg0 oxidation removal in chloride-free flue gas over FeOCl-modified commercial selective catalytic reduction catalyst | |
| US5252528A (en) | Hot gas, regenerative, supported H2 S sorbents | |
| JP2002224570A (ja) | Ｃｏシフト反応用触媒 | |
| JP5278874B2 (ja) | ガスからの硫黄化合物除去方法、及び合成燃料製造方法 | |
| CN118491517A (zh) | 一种抗硫的双金属催化剂及其制备方法和应用 | |
| Lim et al. | Enhancing the effect of CoAl2O4 on the simultaneous removal of H2S and NH3 on Co-and Mo-based catal-sorbents in IGCC | |
| US20130004395A1 (en) | Processes and apparatuses for oxidizing elemental mercury in flue gas using oxychlorination catalysts | |
| Zhang et al. | Syngas mercury removal using LaMeOx/ZSM-5 sorbents: Mechanistic insights and performance tests under industrial conditions | |
| JP7727983B2 (ja) | 触媒への供給方法および供給装置 | |
| RU2840458C2 (ru) | Катализатор, его применение и способ удаления карбонилсульфида из природного газа | |
| JPH0679178A (ja) | 炭酸ガス還元用硫化モリブデン触媒 | |
| Sheng et al. | Enhanced SO2 resistance and broadened operating temperature window of Sn-Mn/TiO2 catalysts for NH3-SCR |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100607 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100607 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110603 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110610 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110912 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120626 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20120924 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20121001 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130625 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130724 |
|
| R150 | Certificate of patent or registration of utility model |
Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| LAPS | Cancellation because of no payment of annual fees |