JP5310370B2 - Method for producing deinked pulp - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing deinked pulp from printed used paper, which efficiently reduces dirt and improves quality of deinked pulp when printed used paper is deinked and recycled. <P>SOLUTION: The method for producing deinked pulp includes, in a used paper pulp production step composed of a combination of a disintegrating step, a dust removal step, decarbonation step, dehydration step, bleaching step, dispersion step and washing step of printed used paper, adding a polymeric flocculant in the dehydration step before the bleaching step, adjusting the raw material concentration after the dehydration step to 25-40%, performing bleaching and carrying out a high-temperature dispersion treatment at 90-130&deg;C in the following dispersion step. <P>COPYRIGHT: (C)2011,JPO&amp;INPIT

Description

The present invention relates to a method for reducing dust (dirt) of deinked pulp made of printed waste paper, and more specifically, when deinking and recycling printed waste paper mainly composed of newspaper waste paper and magazine waste paper, and reducing darts efficiently, and The present invention relates to a deinked pulp manufacturing method for improving the whiteness of a finished pulp.

Conventionally, deinking and recycling of used printed paper is a method that consists of the steps of disaggregation (pulper), dust removal (cleaner / screen), bleaching / dispersion (kneading / dispersion), deinking (flotation), washing, and dehydration. Has been manufacturing. In order to reduce the dirt of deinked pulp, it is necessary to improve the performance of alkali, deinking agent, or foaming agent used in the pulper process and flotation process. On the surface, we have conducted detailed research in each field, such as improving the efficiency of dust removers such as screens and cleaners, improving kneading in the dispersion process, and strengthening in the flotation process.

On the other hand, a deinked pulp having a quality equivalent to or equivalent to that of BKP has been further desired in the market. Recently, there is a lot of ash in the printed waste paper, and neutral newspaper waste paper that has been treated with a surface treatment agent and is extremely poor in deinking properties, and waste paper that is relatively inferior compared to the past is collected. As a result, it has become difficult to produce deinked pulp that can meet these demands from used printed paper, mainly used newspapers and magazines.

In conventional deinked pulp manufacturing methods, it has been difficult to sufficiently remove the dirt mainly composed of ink, and at the same time, it has been difficult to maintain the target whiteness, and the bleachability has deteriorated.

Conventionally, in order to reduce dirt and improve whiteness in the deinked pulp manufacturing process, alkaline agents such as caustic soda, sodium silicate and sodium carbonate, bleaching agents such as hydrogen peroxide and hypochlorite, EDTA Chemicals such as various deinking agents have been used together with metal chelating agents such as DTPA. Deinking agents include those having a high effect of peeling and finely dispersing ink from pulp fibers, and those having a high effect of agglomerating ink and enhancing ink collecting properties in the flotation process.

Conventional deinking agents and deinking aids include, for example, higher alcohol sulfates, polyoxyalkylene higher alcohol sulfates, fatty acids or fatty acid salts, alkylbenzene sulfonates, higher alcohols and alkylphenol alkylene oxide adducts, polyvalent Alcohol ester alkylene oxide adducts, homopolymers or copolymers of styrene sulfonate, and the like are used. Further, higher fatty acid alkylene oxide adducts or ether compounds or ester compounds thereof have been proposed as more effective deinking agents (Patent Literature 1, Patent Literature 2, Patent Literature 3, Patent Literature 4, Patent Literature 5). ).

However, even with these deinking agents and deinking aids described in these patent documents, deinking is not possible with recent printed wastepaper with a high ash content or with neutral newspaper wastepaper that is extremely poorly deinked by the surface treatment agent. Ink effect is low, and in order to reduce dirt or to obtain high whiteness, high addition is required and a large cost is required.

  In addition, a method has been proposed in which an aggregating agent is added in a form to supplement a deinking agent, and an adhesive substance is removed by a flotation process (Patent Document 6). However, the sticky substance and the flocculant cannot be completely removed as floss in the flotation process, and if it is not removed and sent to the subsequent stage together with the pulp slurry, the sticky substance present in the colloidal state will be revealed on the contrary. It had a disadvantage that led to

  On the other hand, as a conventional technique for reducing dirt, a feed blade and a return blade are arranged on a uniaxial rotor collecting surface such as a mica processor, and there is a sufficient gap between the stator blade and each blade. There exists a thing (patent document 7) characterized by using the mixer which was made. Further, the kneading in the dispersion process is composed of three stages, and at least one or more stages are subjected to high-temperature treatment with a disk-type disperser, and the three-stage kneading treatment is followed by flotation treatment (Patent Document) 8) etc. are proposed.

  Moreover, it is characterized by using alkali wash wastewater of kraft pulp as the disaggregation dilution water of the pulper, and treating at pH 8 to 13 and temperature of 20 to 70 ° C., focusing on the temperature, pH and dilution water in the disaggregation process. The thing (patent document 9) etc. are proposed. All the proposals are excellent and have a certain effect, but are not sufficient, and are not focused on the importance of maintaining and managing the pulp concentration in the bleaching process and the dehydration process affecting the high-temperature dispersion process.

JP 58-109696 A JP-A-62-276093 Japanese Patent Laid-Open No. 5-25790 JP 2004-19023 A JP 2000-282382 A JP-A-6-257082 JP-A-4-050391 JP 2008-169507 A JP 2009-35843 A

The object of the present invention is to solve the above-mentioned problems and greatly reduce the deinking pulp dirt produced from used printed paper including neutral newspapers with poor deinking properties. A method that can be manufactured is provided.

The inventors of the present invention have completed the present invention by paying attention to the importance of maintaining and managing the pulp concentration in the bleaching step and the dehydration step affecting the dispersion step.
The present invention includes the following inventions.
(1) In a deinking pulp manufacturing process comprising a combination of a disaggregation process, a dust removal process, a deinking process, a dewatering process, a bleaching process, a dispersion process, and a washing process, the printed waste paper is polymerized in the dehydrating process before the bleaching process. A method for producing deinked pulp in which a flocculant is added so that the raw material concentration in the dehydration step is 25% to 40%, bleaching is performed, and the subsequent dispersion step is performed at 90 to 130 ° C.

(2) The method for producing deinked pulp according to (1), wherein the polymer flocculant has a decomposition temperature of 90 ° C. or lower.

(3) The method for producing deinked pulp according to any one of (1) and (2), wherein the polymer flocculant is a polymer flocculant mainly composed of a cationic polyacrylate.

(4) The pulp sheet produced by JIS P 8222 from the deinked pulp produced by the method described in the above (1) to (3) has a dart number of 0.004 to 5.0 mm ² in size. A method for producing deinked pulp, which is in a range of 000 to 50,000 pieces / m ² .

  According to the present invention, the dirt of deinked pulp is reduced regardless of the quality of the raw paper, and the quality is improved, so that it is possible to enhance the incorporation of deinked pulp into paper products that are cheaper than kraft pulp, mechanical pulp, etc. It becomes possible, and the range of use of waste paper is expanded.

Examples of used printing paper as a raw material include neutral newspaper, acidic newspaper waste, fine coated paper, high ash coated paper, non-coated paper, and the like containing 7% to 35% ash. The present invention is particularly effective for waste printed paper including neutral newspaper waste paper having poor deinking property due to a large amount of surface treatment agent.

  Although there is no restriction | limiting in particular about the disaggregation process in this invention, Diluted water is put so that it may become solid content concentration 12-18% as a preferable process. Further, 0.6 to 3.5% by mass, preferably 1.0 to 2.5% by mass of sodium hydroxide is added to the pulp. In the case of adding a deinking agent, those having strong permeability to pulp fibers and strong ink peelability are preferable, and the deinking agent is 0.01 to 0.5% by mass, preferably 0.03% by weight of the pulp. Add ~ 0.3 mass%. The disaggregation time is 10 to 30 minutes, preferably 10 to 25 minutes, more preferably 10 to 18 minutes, and the disaggregation temperature is 10 to 50 ° C, preferably 30 to 50 ° C.

  As a deinking agent having a strong ink peeling property used at the time of disaggregation, there are higher alcohol deinking agents, for example, DI-7020, DI-7300, DI-767, DI-7282, manufactured by Kao Corporation. DIA-Z-100, DIA-Z-5000 manufactured by Shin Chemical Laboratory Co., Ltd., Neoscore FW-780, Neoscore FW-790, Neoscore FW-795, FT-467, FT manufactured by Toho Chemical Co., Ltd. -470, FT-487, FT-511, FT-515, FT-517, FT-519, BB agent, Daihope 940, Daihope 960, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., manufactured by Nikka Corporation Lipobrite DP-810 and the like are not limited thereto.

  Moreover, there is no restriction | limiting in particular as a dust removal process. Although it is sufficient that foreign substances in the raw material can be removed with a screen cleaner, it is preferable to use a slit screen (first stage 0.15 mm slit or less, second stage 0.15 mm slit or less). Any cleaner may be used as long as it can efficiently remove heavy foreign matter.

The target concentration of the pulp obtained by the treatment in the dehydration step is preferably 25% to 40%, more preferably 25% to 35%, still more preferably in order to obtain a sufficient effect in the subsequent bleaching step and dispersion step. 25% to 30%. If the pulp concentration is less than 25%, the energy required for increasing the temperature becomes enormous, the mechanical load is difficult to be applied, and the dispersibility of ink peeling and dirt is not suitable. It is difficult to squeeze the water to a high concentration exceeding the treatment concentration of 40%, and it is easy to cause spots, and the power intensity becomes high and the pulp strength is remarkably lowered.

Although there is no restriction | limiting in particular as an apparatus which concentrates the pulp slurry in a spin-drying | dehydration process, Generally, pressure dehydrators, such as a screw press, are used. Examples of the uniaxial screw press include V45LM-H type manufactured by Aikawa Tekko, Metso Paper, and Optimum Screw Press manufactured by AFT. Examples of twin press and twin wire dehydrators include Ishigaki's twin screw press and Maruishi Seisakusho's twin wire press. In the case of deinked pulp, it is usually difficult to concentrate to the target pulp concentration instantaneously with only one stage of a pressure dehydrator. Therefore, it is preferable to devise such as using a pressure dehydrator in combination with a suction dehydrator. .

  By adding a polymer flocculant in the present invention, a low-concentration pulp that cannot be sufficiently squeezed by mechanical force alone can be raised relatively quickly to the target pulp concentration by an existing pressure dehydrator. Further, it is possible to finely adjust the pulp concentration, which is difficult to finely adjust mechanically, by adjusting the addition rate of the polymer flocculant. In addition, when the process temperature is high in summer or the like and the dehydration efficiency is improved even by mechanical force, it can be freely adjusted by reducing the amount of addition.

In the present invention, the step of adding the polymer flocculant is preferably before the dehydration step or the dehydration step. At least, the pulp in the dehydration process needs to be sufficiently immersed in the polymer flocculant. In order to improve the processing efficiency in the bleaching step and the dispersion step after the dehydration step, it is important that the pulp concentration is high. The addition rate of the polymer flocculant is preferably 0.005 to 0.05% by mass, more preferably 0.01 to 0.04% by mass with respect to the pulp, although it depends on the pulp concentration and equipment. is there. When the addition rate is low, a sufficient effect does not appear. When the addition rate is high, the target pulp concentration is exceeded and costs are high, which is not practical. The concentration of the polymer flocculant added is not particularly limited, but is preferably 0.1 to 0.3%.

  The polymer flocculant has no problem in the bleaching step after achieving an increase in pulp concentration in the dehydration step, but may cause a decrease in foaming in the deinking step (flotation step). In addition, when remaining in the finished pulp, there is a possibility that the size of the sheet after papermaking may be affected. Therefore, it is preferably decomposed and removed by a high-temperature treatment exceeding 90 ° C. in the high-temperature dispersion treatment after the dehydration step. .

The polymer flocculant added in the present invention is not particularly limited as long as the pulp concentration can be raised to the target concentration in the dehydration step, but the acrylic ester cationic polymer flocculant can raise the pulp concentration most efficiently. Therefore, it is preferable. Examples of the cationic polyacrylate ester include C-525M and C-500N manufactured by MT Aqua Polymer Co., Ltd., High Holder 725 manufactured by Kurita Kogyo, and High Form K162.

The pulp concentration in the bleaching step following the dehydration step is also preferably 20 to 40%, and more preferably 25 to 35%. A high concentration of pulp in the bleaching step is preferred because a high concentration allows aging time to be obtained and bleaching chemicals are not diluted by excess water.

Hydrogen peroxide, hydrosulfide, thiourea dioxide, hypo, etc. are used as bleaching chemicals in the bleaching process. In the practice of the present invention, alkaline hydrogen peroxide bleaching was performed, but the bleaching method is not limited as long as the target whiteness of the deinked pulp to be produced is reached, but hydrogen peroxide increases whiteness due to the bleaching effect. In addition, since it is aged under alkaline conditions, the pulp swells during aging, the adhesion with the ink relaxes, and the effect of enhancing the ink peeling effect in the disperser is also obtained, which is preferable because high whiteness is obtained, It is preferable to add 0.5 to 5.0 mass% with respect to pulp. Even if the amount added is further increased, the increase in whiteness tends to saturate. On the other hand, the pH at the time of bleaching is preferably 10.5 to 12.0. If the pH is out of this range, the bleaching property of hydrogen peroxide deteriorates. It is effective to carry out the bleaching temperature at 50 to 120 ° C.
Moreover, caustic soda is added to 1.5 to 3.0% by mass of pulp, and sodium silicate is added to 0.5 to 1.0% by mass (as NaOH) of pulp, and the bleaching time is 10 minutes to 5 hours, preferably Perform in 1.5-3 hours. If the bleaching time is too short, hydrogen peroxide does not react sufficiently, which is not preferable. Even longer than 5 hours, the consumption of hydrogen peroxide progresses, and the yellowing of the pulp occurs from the point in time when the remaining hydrogen peroxide is used up.

  The dispersion process (including the mixer process) is performed between the dehydration process and the bleaching process, and the bleaching chemical added to the bleaching process is mixed into the pulp, so that the chemical is effectively kneaded into the pulp. It is effective. At the same time, in the dispersing step, it is efficient to raise the temperature with steam to a temperature sufficient for the bleaching step because the temperature can be raised relatively instantaneously.

  The treatment concentration in the dispersion step performed after the bleaching step of the present invention is preferably 25% to 40%, more preferably 25% to 35%. By performing the dispersion treatment within this concentration range, a mechanical load is moderately applied and the ink attached to the pulp fiber can be efficiently peeled off. If the treatment concentration is less than 25%, it is difficult to apply a mechanical load, ink dispersibility / dirt dispersibility is lowered, and energy required for temperature increase is enormous, which is not suitable. Further, the dispersion treatment in a state where the treatment concentration exceeds 40% in the dispersion step is not preferable because a mechanical load is excessively applied to the pulp fiber due to an increase in frictional force and a decrease in pulp strength occurs.

The dispersion step performed after the bleaching step of the present invention is preferably high temperature dispersion at a processing temperature of 90 to 130 ° C. By performing the treatment within this range, it is possible to carry out the dispersion process at a high concentration by carrying out the dispersion treatment at a higher temperature than the normal temperature, and the physical properties such as the ink and the polymer flocculant at the high temperature. Since the softening or decomposition occurs, they can be easily peeled off from the pulp fibers. When the treatment is performed at a temperature lower than 90 ° C., a sufficient dart reducing effect cannot be obtained, and the polymer flocculant cannot be decomposed and removed. On the other hand, if the temperature exceeds 130 ° C., yellowing of the pulp occurs, which is not suitable.

  Further, by performing the bleaching step after the dehydration step of the present invention and the high-temperature dispersion treatment after the bleaching step, the high concentration conditions (25% to 40%) of the dehydration step performed before the bleaching step can be continuously used. I can do it. Moreover, since the high temperature conditions (50 to 120 ° C.) in the bleaching step can be continuously used, the temperature can be increased to a temperature sufficient for high-temperature dispersion treatment (90 to 130 ° C.) with a slight temperature increase. . For this reason, it is possible to save energy compared to installing each separately.

  For the high-temperature dispersion treatment performed at 90 to 130 ° C. in the present invention, a low-speed / high-concentration shaft type disperser or a disk-type disperser is suitable. As the low-speed and high-concentration shaft type disperser, a uniaxial or biaxial kneader type disperser is preferable. It has a rotary blade attached to an axial rotor and a fixed blade attached to the casing, and performs processing at a low speed of 50 to 300 rpm. In the shaft type disperser, the frictional action between the fibers is the main, and the ink peeling and dirt dispersion occur. If the treatment concentration is less than 20%, it is difficult to apply a mechanical load, and ink dispersibility / dirt dispersibility is lowered, and energy required for temperature increase is enormous, which is not suitable. In general, Nieding Disperser KD (trade name: manufactured by IH IFOIT Paper Technology), Disperser (trade name: manufactured by Aikawa Tekko Co., Ltd.), Disperser (trade name: product name: uniaxial kneader) ASEC), Disperser (trade name: Sanei Regulator Co., Ltd.), CCE type ruding machine (trade name: Niihama Pump Seisakusho Co., Ltd.), kneader (trade name: Yamamoto Hyakuma Seisakusho Co., Ltd.) Moreover, as a biaxial kneader, those manufactured by Niihama Pump Manufacturing Co., Ltd., Yamamoto Hyakuma Manufacturing Co., Ltd. are used.

Further, the disk type disperser is not particularly limited as long as it is a disk type disperser or a conical type disperser. Structurally similar to a disc refiner, but the disc plate has a different structure. Further, the conical type disperser has a rotating blade in a conical shape. Processing is performed at a rotational speed of 300 rpm to 2500 rpm and a processing concentration of 20% or more.
The difference from the shaft type disperser is that the ink and the dirt are dispersed mainly by the collision action of the fiber and the blade. Generally, as a disk-type disperser, a disperser HTD (trade name: manufactured by IH / IFOIT Paper Technology), a KRIMA hot dispersion facility (trade name: manufactured by Cellwood), etc. are used. As conical type dispersers, conical discs (trade name: manufactured by Aikawa Tekko Co., Ltd.), conical dispersion systems / HI pre-heaters / Optifiner dispersers (product name: manufactured by Metso SHI), etc. are used. It is not limited. Low-speed / high-density shaft type kneaders or disc-type dispersers are suitable, but disc-type dispersers are more suitable.

In addition to hydrogen peroxide and thiourea dioxide, an alkaline chemical may be added to the high temperature dispersion treatment performed at 90 to 130 ° C. in the present invention. As the alkaline chemical, sodium hydroxide is preferable. The amount of hydrogen peroxide added is 0.05 to 3% by mass with respect to the mass of the absolutely dry pulp, and the amount of thiourea dioxide added is 0.1 to 2% by mass with respect to the mass of the absolutely dry pulp, particularly preferably 0. .2 to 1.0% by mass.

  The flotation process in the deinking process is not limited in the form of the flotator, but the treatment concentration is 0.7 to 1.5%, the flotator treatment temperature is 10 to 55 ° C, preferably 30 to 50 ° C. It is good. In addition, there is no particular limitation on the flotation process in either one stage or two stages, but it is more effective for ink removal to perform the flotation process after the high temperature dispersion process.

If the flotation deinking agent can be uniformly mixed with the pulp, a deinking agent may be added to the bleaching step. Deinking agents with strong ink cohesion include fatty acid or fatty acid derivative-based deinking agents. For example, in the case of fatty acids, DI-254 (oleic acid), DI-268, manufactured by Kao Corporation. K-1400-D manufactured by Daiichi Kogyo Seiyaku Co., Ltd. In the case of a fatty acid derivative, DI-1120 and DI-1050 manufactured by Kao Corporation, DIY-23543 manufactured by Nisshin Chemical Laboratory Co., Ltd., and Paper Aid manufactured by Daiichi Kogyo Seiyaku Co., Ltd. W, Daihope 1000, etc. are not limited.

The washing step after the flotation treatment is a step of dewatering and washing fine ink that could not be removed by the flotator. After diluting 0.6-1.5% pulp slurry with fresh water or white water of a paper machine, 10 It is preferable to dehydrate and wash to ~ 30%.

  Although there is no restriction | limiting in particular as a washing | cleaning apparatus, There exist an extractor, a fall washer (made by Eiko), a double nip thickener (made by Ishikawajima Industrial Machinery), etc. The washing device is preferably a washing machine that preferentially removes fine ink and ash in the raw material and minimizes loss of fiber. Among them, a wire washer is preferable, and the eye hole can be about 20 to 200 mesh, preferably 40 to 100 mesh, and more preferably 50 to 80 mesh.

Pulp obtained by the present invention, it is preferable Dirt number of 0.004～5.0Mm ² is 5,000 to 50,000 pieces / ^{m 2.} When the number of dirt exceeds 50,000, it is extremely inferior to BKP. Further, it is not preferable to make the dart count 5,000 / m ² or less because enormous chemicals and energy are required. Moreover, it is possible to make good paper with less dirt by using 50% by mass or more of the pulp obtained by the present invention.

  According to the present invention, the ISO whiteness of deinked pulp produced from printed waste paper mainly composed of newspaper waste paper can be widely produced from 50% to 85%, all of which can achieve reduced dart quality. Become.

  EXAMPLES Next, although this invention is demonstrated in detail based on an Example, an Example does not limit this invention at all. Percentage (%) means mass% except whiteness, and chemical addition rate is expressed as mass% per dry pulp. The quality of the deinked pulp was evaluated by the number of darts according to the following dart evaluation method. Unless otherwise specified, the raw material concentration is the solid content concentration including ash, and the chemical addition rate is mass%. The practice of the present invention used a finished pulp 120ADT / D deinked pulp production facility.

<Dirt evaluation method>
The deinked pulp is dispensed onto a 150 mesh wire, and the ink released from the fibers is thoroughly washed with about 20 liters of filtered fresh water per gram of pulp, and then a handsheet having a basis weight of 60 g / m ² is removed. Five sheets were produced in accordance with the method for preparing a test handsheet shown in JIS P 8222. The number of darts of 0.004 to 5.0 mm ² size contained in the center 10 cm × 10 cm in 5 handsheets was measured using a Dart Analyzer (DIP-200) manufactured by Oji Scientific Instruments. The measurement result was converted to the number per 1 m ^{2 of} pulp and used as the number of dirt.

<Whiteness measurement method>
After the finished pulp was disaggregated, 20.0% of the dried pulp was added to the pulp slurry, and a sheet having a basis weight of 60 g / m ² was prepared according to Tappi test method T205os-71 (JIS P 8209). The whiteness of the fluorescence intensity cut was measured for the prepared sheet with a spectral whiteness colorimeter (manufactured by Suga Test Instruments).

Example 1
Waste paper (mainly ash content: 13.9%) made from newspapers and leaflets is charged into a pulper, the raw material concentration is 15%, sodium hydroxide is added to 1.0% pulp, and higher alcohol deinking agent (Toho Chemical Co., Ltd.) Manufactured, FT-517) Addition ratio to pulp 0.10%, disaggregation time 15 minutes, disaggregation temperature after disaggregation at 35 ° C. It processed with the rotator (made by Oji Engineering Co., Ltd.). The first stage flotation treatment temperature was 37 ° C.

The pulp slurry after the floatator was washed with an extractor, and thereafter, a cationic polymer flocculant C-525M made of MT Aqua Polymer mainly composed of polyacrylate was added at 0.03% to the pulp. Thereafter, it was dehydrated to a pulp concentration of 28.0% with a disk thickener and a screw press (V45LM-H type manufactured by Aikawa Tekko).

After that, the temperature is raised to 80 ° C. with a heating mixer, and as a shaft type disperser, the first-stage dispersion treatment is performed at a power unit of about 40 kwh / pulp T with a disperser manufactured by Aikawa Tekko, and then bleaching is performed. I did it. The bleaching conditions were as follows: hydrogen peroxide addition rate 2.5% pulp, sodium hydroxide addition rate 2.0% pulp, sodium silicate addition rate 0.6% pulp sodium hydroxide equivalent, pulp concentration about 28.5% The bleaching time was 150 minutes.

Next, after raising the raw material temperature to 110 ° C. with steam, as a second stage disperser, a high temperature dispersion process is performed at a power unit of about 20 kwh / pulp T using a disk type KURIMA hot disperser manufactured by Cellwood. It was.

Thereafter, a second-stage floatator treatment was performed. Flotator deinking conditions were performed at a special fatty acid derivative (Kao Corporation, DI-1120) addition rate of 0.12%, a flowator treatment concentration of 1.1%, and a flowator treatment temperature of 40 ° C. Table 1 shows the number of dirt in the finished pulp (deinked pulp) after dewatering and washing with a disc thickener.

Example 2
A deinked pulp was produced in the same manner as in Example 1 except that the second stage disk type dispersion treatment was performed at 125 ° C. Table 1 shows the number of dirt in the deinked pulp.

Example 3
A deinked pulp was produced in the same manner as in Example 1 except that the dispersion treatment in the second stage was carried out at a high temperature of 95 ° C. Table 1 shows the number of dirt in the deinked pulp.

Example 4
A deinked pulp was produced in the same manner as in Example 1 except that the addition rate of the cationic polymer flocculant was 0.04% with respect to the pulp. Table 1 shows the number of dirt in the deinked pulp.

Example 5
A deinked pulp was produced in the same manner as in Example 1 except that the addition rate of the cationic polymer flocculant was 0.02% to pulp. Table 1 shows the number of dirt in the deinked pulp.

Example 6
A deinked pulp was produced in the same manner as in Example 1 except that the brand of the cationic polymer flocculant was N-100 made of MT aquapolymer mainly composed of polyacrylamide. Table 1 shows the number of dirt in the deinked pulp.

Comparative Example 1
A deinked pulp was produced in the same manner as in Example 1 except that the cationic polymer flocculant was not added. Table 1 shows the number of dirt in the deinked pulp.

Comparative Example 2
A deinked pulp was produced in the same manner as in Example 1 except that the cationic polymer flocculant was not added and the second stage dispersion treatment was dispersed at a high temperature of 135 ° C. Table 1 shows the number of dirt in the deinked pulp.

Comparative Example 3
A deinked pulp was produced in the same manner as in Example 1 except that the cationic polymer flocculant was not added and the second stage dispersion treatment was performed at 85 ° C. Table 1 shows the number of dirt in the deinked pulp.

Comparative Example 4
MT Aqua Polymer Cationic Polymer Flocculant Containing Polyacrylic Acid Ester as Main Component C-525M was not added before the dehydration step added in Example 1, but the second stage at 0.03% to pulp. A deinked pulp was produced in the same manner as in Example 1 except that it was added before the flotator treatment. Table 1 shows the number of dirt in the deinked pulp.

Comparative Example 5
A deinked pulp was produced in the same manner as in Example 1 except that the second stage dispersion treatment was performed at 85 ° C. Table 1 shows the number of dirt in the deinked pulp.

As is clear when Examples 1 to 6 and Comparative Examples 1 to 5 are compared, a cationic polyacrylate is added to the dehydration step before the bleaching step, and the treatment temperature of the dispersion step following the bleaching step is 90 to 130 ° C. It is clear that by optimizing to a minimum of finished pulp dirt.

  In the deinked pulp manufacturing process consisting of a combination of a disaggregation process, a dust removal process, a deinking process, a dewatering process, a bleaching process, a dispersing process, and a washing process, the dewatering process prior to the bleaching process After increasing the concentration of the raw material using a polymer flocculant and setting the raw material concentration in the dehydration step to 25% to 40%, bleaching of the pulp fiber is performed, and in the subsequent dispersion step, high temperature dispersion is performed at 90 to 130 ° C. By performing the treatment, it was possible to produce deinked pulp with a small number of dirt.

Claims (1)

In the pulping process of waste paper, which consists of a combination of a disaggregation process, a dust removal process, a deinking process, a dehydration process, a bleaching process, a dispersion process, and a washing process to disaggregate used waste paper, a dehydration process is performed before the bleaching process and the dispersion process And adding a polymer flocculant mainly composed of a cationic polyacrylate in the dehydration step, setting the raw material concentration in the dehydration step to 25% to 40% , following the dehydration step, bleaching step, dispersion step Then, it does in the range of 25%-40%, without reducing a raw material density | concentration, The process temperature of the dispersion | distribution process following this bleaching process is performed at 90-130 degreeC , The manufacturing method of the deinking pulp characterized by the above-mentioned.