JP5307691B2 - Method of forming lacquer coating film, lacquer sheet and lacquer coating film formed body using this lacquer sheet - Google Patents

Method of forming lacquer coating film, lacquer sheet and lacquer coating film formed body using this lacquer sheet Download PDF

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JP5307691B2
JP5307691B2 JP2009253000A JP2009253000A JP5307691B2 JP 5307691 B2 JP5307691 B2 JP 5307691B2 JP 2009253000 A JP2009253000 A JP 2009253000A JP 2009253000 A JP2009253000 A JP 2009253000A JP 5307691 B2 JP5307691 B2 JP 5307691B2
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猛 辻田
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有限会社辻田漆店
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Description

本発明は、対象物に柔軟性を有する天然漆のシートを貼り付けることで、簡単に天然漆の塗膜を対象物に形成することのできる漆塗膜の形成方法及び漆シート並びにこの漆シートを用いた漆塗膜形成体に関する。   The present invention provides a method for forming a lacquer coating film, a lacquer sheet, and a lacquer sheet that can easily form a natural lacquer coating film on an object by attaching a flexible natural lacquer sheet to the object. The present invention relates to a lacquer coating film formed body.

天然漆の塗膜を形成した製品は、独特の色調や高級感から、従来より家具や食器などに使用されている。しかし、これら対象物への天然漆塗膜の形成は、例えば特許文献1,2の「従来の技術」の欄に記載されているように、高度な熟練を必要とし、均一品質の維持が困難であることから、大量生産と大面積の加工には不向きで価格も高く、そのため年々市場規模が縮小してきているという問題がある。   Products with natural lacquer coatings have traditionally been used for furniture and tableware because of their unique color and luxury. However, the formation of natural lacquer coatings on these objects requires advanced skills and is difficult to maintain uniform quality, as described in, for example, “Prior Art” in Patent Documents 1 and 2. Therefore, it is unsuitable for mass production and processing of large areas, and the price is high. Therefore, there is a problem that the market scale is decreasing year by year.

このような問題に鑑みて、特許文献1では、紙状体の一面に漆転写層を形成し、この漆転写層の表面に接着材を塗布して対象物に貼り付けた後、紙状体を剥がす漆転写材が提案されている。
しかしながら、特許文献1に記載の漆転写紙は、特許文献2の「発明が解決しようとする課題」の欄に記載されているように、切断や貼り合わせの際に漆転写層に割れが発生しやすく、特に、対象物が金属である場合に、曲げ加工を行うと貼り合わせた漆層に割れが発生するという問題がある。
そこで、特許文献2では、金属箔に漆層を強固に接着させ、金属箔とともに漆層を対象物に貼り付ける技術を提案している。
In view of such a problem, in Patent Document 1, a lacquer transfer layer is formed on one surface of a paper-like body, an adhesive is applied to the surface of the lacquer transfer layer, and is attached to an object. A lacquer transfer material has been proposed to peel off.
However, the lacquer transfer paper described in Patent Document 1 is cracked in the lacquer transfer layer during cutting and pasting as described in the column “Problems to be Solved by the Invention” in Patent Document 2. In particular, when the object is a metal, there is a problem that cracking occurs in the bonded lacquer layer when bending is performed.
Therefore, Patent Document 2 proposes a technique in which a lacquer layer is firmly bonded to a metal foil, and the lacquer layer is attached to an object together with the metal foil.

特開昭61−10497号公報Japanese Patent Laid-Open No. 61-10497 特公平5−12148号公報Japanese Patent Publication No. 5-12148

しかし、特許文献2に記載の技術は、金属箔を必須の要素とし、金属製の対象物には好適ではあるものの、その用途が限られ、対象物によっては使用できないという問題がある。また、天然漆本来の色、光沢、肌触りを得ることができないという問題もある。
本発明は上記の問題点にかんがみてなされたもので、特許文献1,2の問題点を同時に解決して、広範な対象物に簡単に天然漆の漆塗膜を形成することのでき、天然漆の塗膜を形成した漆製品の市場拡大を図ることのできる漆塗膜の形成方法及び漆シート並びにこの漆シートを用いた漆塗膜形成体の提供を目的とする。
However, although the technique described in Patent Document 2 has a metal foil as an essential element and is suitable for a metal object, its use is limited and there is a problem that it cannot be used depending on the object. In addition, there is a problem that the natural color, gloss and touch of natural lacquer cannot be obtained.
The present invention has been made in view of the above problems, and can simultaneously solve the problems of Patent Documents 1 and 2, and can easily form a natural lacquer coating film on a wide range of objects. The purpose of the present invention is to provide a method for forming a lacquer coating film and a lacquer sheet capable of expanding the market of lacquer products formed with a lacquer coating film, and a lacquer coating film formed body using the lacquer sheet.

上記課題を解決するために、請求項1に記載の発明は、対象物の表面に天然漆の漆塗膜を形成する方法において、天然漆にエポキシ化大豆油を主成分とする可塑剤を5重量%〜20重量%加え、基材に塗布できる粘性まで溶媒で希釈し原液を準備する工程と、
この原液を前記基材上に均一に塗布した後、乾燥,硬化させて前記基材上に天然漆層を形成する工程と、この天然漆層を前記基材から剥離して漆シートを得る工程と、この漆シートの一面又は対象物の表面に接着材を塗布し、前記漆シートを前記対象物の表面に貼り付ける工程とを有する方法である。
この場合、請求項2に記載するように、漆又はその他の塗料を前記対象物の表面に塗布し、前記漆又はその他の塗料を接着材として漆シートを貼り付けるようにしてもよい。また、請求項3に記載するように、前記原液を基材上に均一に塗布した後に、前記原液の上に金粉,金箔又は貝殻片を配置することで、漆塗膜に装飾性を付与することもできる。
In order to solve the above-mentioned problem, the invention according to claim 1 is a method of forming a natural lacquer coating film on the surface of an object, wherein the natural lacquer contains 5 plasticizers mainly composed of epoxidized soybean oil. Adding a weight percent to 20 weight percent and preparing a stock solution diluted with a solvent to a viscosity that can be applied to a substrate ;
After uniformly coating the stock solution on the substrate, dried to give a step of forming a natural lacquer layer on the substrate is cured, lacquer sheet the natural lacquer layer was peeled from the substrate step And a step of applying an adhesive to one surface of the lacquer sheet or the surface of the object and attaching the lacquer sheet to the surface of the object.
In this case, as described in claim 2, lacquer or other paint may be applied to the surface of the object, and a lacquer sheet may be attached using the lacquer or other paint as an adhesive. In addition, as described in claim 3, after the stock solution is uniformly applied on a substrate, gold powder, a gold foil, or a shell piece is disposed on the stock solution, thereby imparting decorativeness to the lacquer coating film. You can also.

本発明の漆シートは、請求項4に記載するように、対象物の表面に天然漆の漆塗膜を形成するための漆シートであって、天然漆にエポキシ化大豆油を主成分とする可塑剤を5重量%〜20重量%加え、塗布できる粘性まで溶媒で希釈した原液を基材上に均一に塗布し、乾燥,硬化させて形成された前記基材上の漆層を前記基材から剥離して形成される構成としてある。請求項5に記載するように、前記漆シートの一面に接着層を形成し、保護シートを貼り付けるようにしてもよい。また、請求項に記載するように、前記原液を基材上に均一に塗布した後に、前記原液の上に金粉,金箔又は貝殻片を配置することで、装飾性の高い漆シートを得ることも可能である。 The lacquer sheet of the present invention is a lacquer sheet for forming a natural lacquer coating film on the surface of an object, as described in claim 4, and epoxidized soybean oil is the main component of natural lacquer. A lacquer layer on the substrate formed by uniformly applying on the substrate a stock solution diluted with a solvent to a viscosity capable of being applied , 5% to 20% by weight of a plasticizer, and drying and curing the substrate. It is set as the structure formed by peeling off . As described in claim 5 , an adhesive layer may be formed on one surface of the lacquer sheet, and a protective sheet may be attached. Moreover, after applying the said undiluted solution uniformly on a base material as described in claim 6 , a highly decorative lacquer sheet is obtained by arranging gold powder, gold foil or shell pieces on the undiluted solution. Is also possible.

本発明の漆塗膜形成体は、請求項に記載するように、請求項4〜のいずれかに記載の漆シートを対象物の表面に貼り付けたものである。この場合、請求項に記載するように、前記対象物の表面に漆又はその他の塗料を塗布し、前記漆又は前記塗料を接着材として前記漆シートを貼り付けてもよいし、請求項に記載するように、前記漆シートを所定の形状に切断して前記対象物に貼り付けてもよい。
As described in claim 7 , the lacquer coating film formed body of the present invention is obtained by attaching the lacquer sheet according to any one of claims 4 to 6 to the surface of an object. In this case, as described in claim 8, wherein the lacquer or other coating material is applied to the surface of the object, wherein the lacquer or to the coating material may be adhered to the lacquer sheet as an adhesive, claim 9 As described in, the lacquer sheet may be cut into a predetermined shape and attached to the object.

本発明によれば、漆シートは高い柔軟性を有するため、特許文献1のように切断や貼り合わせの際にも漆シートが割れたり破れたりすることがない。また、対象物に貼り付ける際に特許文献2のような補強のための金属箔も必要としない。
そのため、パソコンや携帯電話、浴槽、屋内外の壁面、自動車や鉄道等の車両,船舶,航空機等の内装などのあらゆる対象物に、天然漆本来の色、光沢、肌触りを有する漆塗膜を簡単に形成することができ、漆製品の市場拡大を図ることができる。
According to the present invention, since the lacquer sheet has high flexibility, the lacquer sheet is not broken or torn even during cutting and bonding as in Patent Document 1. Moreover, the metal foil for reinforcement like patent document 2 is not required when affixing on a target object.
Therefore, lacquer coating film with natural lacquer color, luster and texture can be easily applied to all objects such as personal computers, mobile phones, bathtubs, indoor and outdoor walls, vehicles such as automobiles and railways, interiors of ships and aircraft. The market for lacquer products can be expanded.

以下、本発明の好適な一実施形態を詳細に説明する。
本発明の漆シートは、以下の手順で形成することができる。
[原液]
精製した天然漆に可塑剤を添加し、溶媒を加えて適当な粘性を与える。
可塑剤としては種々のものを用いることができるが、植物由来の可塑剤が好ましく、例えばエポキシ化大豆油を主成分とするものを使用することができる。可塑剤の一例としては、DIC株式会社のエポサイザー(登録商標)W-100ELを挙げることができる。
溶媒としては、例えばトルエンを主成分とするものを用いることができる。溶媒による希釈の目安は、例えば塗装用として市販されているスプレーガンを用いる場合は、後述の基材の表面にスプレーガンで吹き付け塗装ができる程度である。
天然漆に対する可塑剤の割合の一例としては、天然漆100重量%に対して、5重量%〜20重量%の間を挙げることができ、10重量%程度が好ましい。5重量%より少なくなると漆シートに十分な柔軟性が得られず、20重量%を越えると漆シートや漆塗膜の品質が低下する。
Hereinafter, a preferred embodiment of the present invention will be described in detail.
The lacquer sheet of the present invention can be formed by the following procedure.
[Undiluted solution]
Add plasticizer to purified natural lacquer and add solvent to give proper viscosity.
Various plasticizers can be used, but plant-derived plasticizers are preferable. For example, those based on epoxidized soybean oil can be used. An example of a plasticizer is Eposizer (registered trademark) W-100EL manufactured by DIC Corporation.
As the solvent, for example, a solvent mainly containing toluene can be used. The standard of dilution with a solvent is such that, for example, when a spray gun commercially available for coating is used, the surface of the base material described later can be sprayed with the spray gun.
As an example of the ratio of the plasticizer with respect to natural lacquer, it can mention between 5 weight%-20 weight% with respect to 100 weight% of natural lacquer, and about 10 weight% is preferable. When the amount is less than 5% by weight, the lacquer sheet cannot have sufficient flexibility, and when it exceeds 20% by weight, the quality of the lacquer sheet and the lacquer coating film is deteriorated.

[添加剤]
原液の湿潤性、増粘性、保存性、粘度安定性、充填性、保持性などの向上を目的として市販の添加剤を加えてもよい。また、天然漆の艶出しのために添加剤を加えてもよい。この場合は、例えば亜麻仁油45%とロジンエステル55%を加熱合わせしたものを用いることができ、天然漆90重量%に対して10重量%程度の割合で添加剤を加えての添加剤の含有量10%程度の精製漆を得る。また、着色のために顔料を添加してもよい。
[Additive]
Commercially available additives may be added for the purpose of improving the wettability, thickening, storage stability, viscosity stability, fillability, retention, etc. of the stock solution. Moreover, you may add an additive for glossing of natural lacquer. In this case, for example, a mixture of 45% linseed oil and 55% rosin ester can be used, and the additive is contained in an amount of about 10% by weight with respect to 90% by weight of natural lacquer. Obtain approximately 10% purified lacquer. A pigment may be added for coloring.

[基材]
基材は、上記の原液をスプレーガンで吹き付けて漆塗膜を形成し、乾燥硬化後に容易に剥がすことができるのであれば、その材質や形態、形状は問わない。
材質としては樹脂やガラス板、金属板,陶板等であってもよい。樹脂の一例としては、ポリプロピレンを挙げることができる。また、金属板や陶板を用いる場合は、必要に応じて剥離剤を塗布するとよい。
形態としては、シート状,フィルム状又は板状のものを用いることができる。形状としては、円形状、楕円状、三角状、多角状、不定形状などあらゆる形状のものを選択することができ、漆塗膜を形成しようとする対象物の形状に一致させた形状とすることも可能である。また、平面状に限らず立体状のものも選択することができ、前記対象物が曲面や球面を有する場合には、これらに一致した曲面状又は球面状の表面を有するものであってもよい。
[Base material]
The base material is not limited in its material, form, and shape as long as the above-mentioned stock solution is sprayed with a spray gun to form a lacquer coating film and can be easily peeled off after drying and curing.
The material may be a resin, a glass plate, a metal plate, a ceramic plate, or the like. An example of the resin is polypropylene. Moreover, when using a metal plate or a ceramic plate, a release agent may be applied as necessary.
As a form, a sheet form, a film form, or a plate form can be used. As the shape, any shape such as circular, elliptical, triangular, polygonal, and indefinite shape can be selected, and the shape should match the shape of the object on which the lacquer coating film is to be formed. Is also possible. Further, not only a planar shape but also a solid shape can be selected, and when the object has a curved surface or a spherical surface, it may have a curved surface or a spherical surface that matches these. .

[漆シートの形成]
上記の手順で準備した適度な粘性の原液を市販のスプレーガンに充填して、基材の表面にムラなく吹き付ける。必要に応じて金箔片や金粉,貝殻片(螺鈿)等を原液の上に配置又は撒き散らしてもよい。
この基材を、恒温恒湿のムロ内に収容し、一定期間(2〜3日)放置して漆を乾燥・硬化させ、基材上に天然漆層を形成する。この後、基材をムロから取り出し、天然漆層を基材から剥離して漆シートを得る。漆シートはこのまま保管してもよいし、漆シートの一面に接着材を塗布して接着層を形成し、この接着層にフィルムや金属箔等の保護シートを貼り付けて保管してもよい。なお、市販の両面テープの一面を漆シートの一面に貼り付けることで、接着層の形成と保護シートの貼り付けを同時に行うことが可能である。
[Formation of lacquer sheet]
A commercially available spray gun is filled with an appropriately viscous stock solution prepared by the above procedure, and sprayed evenly on the surface of the substrate. If necessary, gold leaf pieces, gold powder, shell pieces (screws) and the like may be arranged or scattered on the stock solution.
This base material is accommodated in a constant temperature and humidity chamber and left for a certain period (2 to 3 days) to dry and cure the lacquer, thereby forming a natural lacquer layer on the base material. Then, a base material is taken out from a mud and a natural lacquer layer is peeled from a base material, and a lacquer sheet is obtained. The lacquer sheet may be stored as it is, or an adhesive may be applied to one surface of the lacquer sheet to form an adhesive layer, and a protective sheet such as a film or metal foil may be attached to the adhesive layer for storage. In addition, it is possible to perform formation of an adhesive layer and affixing a protective sheet simultaneously by affixing one surface of a commercially available double-sided tape to one surface of a lacquer sheet.

[漆シートの貼り付け]
漆塗膜を形成しようとする対象物への漆シートの貼り付けは、前記対象物の表面又は漆シートの一面に接着材を塗布して行う。予め漆シートの一面に接着層を形成してこれに保護シートを貼り付けたものは、前記保護シートを剥がして対象物に貼り付ける。対象物の表面に漆等の塗料を塗布し、これを接着材として漆シートを貼り付けるようにしてもよい。
[Paste of lacquer sheet]
Affixing a lacquer sheet to an object on which a lacquer coating film is to be formed is performed by applying an adhesive to the surface of the object or one surface of the lacquer sheet. In the case where an adhesive layer is previously formed on one surface of a lacquer sheet and a protective sheet is attached thereto, the protective sheet is peeled off and attached to an object. You may make it apply | coat coating materials, such as lacquer, on the surface of a target object, and affix a lacquer sheet | seat on this as an adhesive material.

本発明の好適な実施形態について説明したが、本発明は上記の説明に限定されるものではない。
例えば、基材への原液の塗布はスプレーガンで行うものとして説明したが、エアーブラシを用いた吹付法やゴムロールを用いたロールコーター法、刷毛塗り法等の他の塗布方法も用いることができる。特に、吹付法やロールコーター法を利用することで、天然漆の漆シートの生産を自動化できる。
Although a preferred embodiment of the present invention has been described, the present invention is not limited to the above description.
For example, the application of the undiluted solution to the base material has been described as being performed with a spray gun, but other application methods such as a spray method using an air brush, a roll coater method using a rubber roll, and a brush coating method can also be used. . In particular, the production of natural lacquer sheets can be automated by using the spraying method and the roll coater method.

本発明は、漆シートの貼り付けが可能であれば、パソコンや携帯電話、浴槽、屋内外の壁面、自動車や鉄道等の車両,船舶,航空機等の内装など、あらゆる対象物への天然漆の塗膜形成に適用が可能である。   As long as the lacquer sheet can be pasted, the present invention can be applied to any object such as personal computers, mobile phones, bathtubs, indoor / outdoor walls, vehicles such as cars and railways, interiors of ships, aircraft, etc. Applicable to coating film formation.

Claims (9)

対象物の表面に天然漆の漆塗膜を形成する方法において、
天然漆にエポキシ化大豆油を主成分とする可塑剤を5重量%〜20重量%加え、基材に塗布できる粘性まで溶媒で希釈し原液を準備する工程と、
この原液を前記基材上に均一に塗布した後、乾燥,硬化させて前記基材上に天然漆層を形成する工程と、
この天然漆層を前記基材から剥離して漆シートを得る工程と、
この漆シートの一面又は対象物の表面に接着材を塗布し、前記漆シートを前記対象物の表面に貼り付ける工程と、
を有することを特徴とする漆塗膜の形成方法。
In the method of forming a natural lacquer coating film on the surface of an object,
Adding 5% to 20% by weight of a plasticizer mainly composed of epoxidized soybean oil to natural lacquer, and preparing a stock solution diluted with a solvent to a viscosity that can be applied to a substrate ;
After the stock solution was uniformly applied on the substrate, drying, forming a natural lacquer layer is cured on the substrate,
Peeling the natural lacquer layer from the substrate to obtain a lacquer sheet;
Applying an adhesive to one surface of the lacquer sheet or the surface of the object, and attaching the lacquer sheet to the surface of the object;
A method for forming a lacquer coating film characterized by comprising:
漆又はその他の塗料を前記対象物の表面に塗布し、前記漆又はその他の塗料を接着材として漆シートを貼り付けることを特徴とする請求項1に記載の漆塗膜の形成方法。 The method for forming a lacquer coating film according to claim 1, wherein lacquer or other paint is applied to the surface of the object, and a lacquer sheet is pasted using the lacquer or other paint as an adhesive. 前記原液を基材上に均一に塗布した後に、前記原液の上に金粉,金箔又は貝殻片配置したことを特徴とする請求項1又は2に記載の漆塗膜の形成方法。 3. The method for forming a lacquer coating film according to claim 1, wherein a gold powder, a gold foil, or a shell piece is disposed on the stock solution after the stock solution is uniformly applied on a substrate. 請求項1〜3のいずれかに記載の漆塗膜の形成方法に用いられる漆シートであって、
天然漆にエポキシ化大豆油を主成分とする可塑剤を5重量%〜20重量%加え、塗布できる粘性まで溶媒で希釈した原液を基材上に均一に塗布し、乾燥,硬化させて形成された前記基材上の漆層を前記基材から剥離して形成されることを特徴とする漆シート。
It is the lacquer sheet used for the formation method of the lacquer coating film in any one of Claims 1-3,
It is formed by adding 5% to 20% by weight of a plasticizer based on epoxidized soybean oil to natural lacquer, uniformly applying a stock solution diluted with a solvent to a viscosity that can be applied, and then drying and curing. A lacquer sheet formed by peeling a lacquer layer on the substrate from the substrate.
前記漆シートの一面に接着層を形成し、保護シートを貼り付けたことを特徴とする請求項4に記載の漆シート。 The lacquer sheet according to claim 4, wherein an adhesive layer is formed on one surface of the lacquer sheet and a protective sheet is attached. 前記原液を基材上に均一に塗布した後に、前記原液の上に金粉,金箔又は貝殻片配置したことを特徴とする請求項4又は5に記載の漆シート。 6. The lacquer sheet according to claim 4 or 5 , wherein a gold powder, a gold foil, or a shell piece is disposed on the stock solution after the stock solution is uniformly applied on a substrate. 請求項4〜のいずれかに記載の漆シートを対象物の表面に貼り付けたことを特徴とする漆塗膜形成体。 A lacquer coating film formed body, wherein the lacquer sheet according to any one of claims 4 to 6 is attached to a surface of an object. 前記対象物の表面に漆又はその他の塗料を塗布し、前記漆又は前記塗料を接着材として前記漆シートを貼り付けたことを特徴とする請求項に記載の漆塗膜形成体。 The lacquer coating film forming body according to claim 7 , wherein lacquer or other paint is applied to the surface of the object, and the lacquer sheet is pasted using the lacquer or the paint as an adhesive. 前記漆シートを所定の形状に切断して前記対象物に貼り付けたことを特徴とする請求項7又は8に記載の漆塗膜形成体。 The lacquer coating film forming body according to claim 7 or 8 , wherein the lacquer sheet is cut into a predetermined shape and attached to the object.
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