JP5297792B2 - Base material for lid - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing a base material for a lid, in which strength between layers, processing suitability, and printing suitability are improved and suppression of curling is excellent. <P>SOLUTION: The base material for the lid has a coating layer on one side of base paper, the coating layer having a pigment and adhesive as its principal component. The base paper uses broad-leaf craft pulp as its principal component. Paper is made in the presence of paper strength reinforcement agent containing acrylic amide as its base agent. Pulp in which the base material for the lid is macerated based on JIS P 8220 is from 350 to 500 cc in freeness based on JIS P 8121. The weight average fiber length of the pulp after the maceration is from 0.5 to 1.0 mm. In addition, 90 wt.% or more of the pulp after the maceration is formed from fibers that have a fiber length of 1.5 mm or shorter. The average value of internal bond based on J. TAPPI No.18-2 in the widthwise and flowing directions of the base material for the lid is 200 mJ or greater. <P>COPYRIGHT: (C)2010,JPO&amp;INPIT

Description

  The present invention relates to a base material for a lid material having interlayer strength, suitability for punching, dimensional stability, and dot reproducibility for a lid material.

  As one of the required qualities required for the lid material, easy peel properties that indicate the ease of opening (in the operation of peeling and opening the lid material from the container after the lid material is attached to the container by an adhesive means such as an adhesive) Easy opening).

  Conventionally, the composition of the adhesive is mainly made of polyethylene or polypropylene, so that the easy peelability is adjusted, and when opening the lid, the peelability between the adhesive and the container during the opening operation is lowered. Measures have been taken to improve easy peel.

  However, in recent years, in order to save resources, maintain the quality of contents, and prevent inadvertent opening, quality improvements have progressed in the direction of firmly bonding containers and lids with a small amount of adhesive.

  The strong adhesion between the container and the lid material increases the physical force (peeling strength between layers) applied to the Z-axis of the base material for the lid material when the lid material is peeled from the container and opened. There is a problem that breaks.

  As measures to increase the interlaminar strength, there are methods such as freeness down of raw pulp composing the base material for lid material (advancing beating), addition of paper strength enhancer into the base material, etc. , By increasing the fine fiber and promoting fibrillation, the specific surface area of the fiber increases and the dimensional stability deteriorates, paper dust is easily generated, the tension increases, the cushioning property decreases, and the lid material There arises a problem that processability is lowered.

  In addition, measures to increase the interlayer strength by adding a paper strength enhancer, as well as freeness reduction, the base material becomes harder, cushioning properties are reduced, tightness is increased, and workability as a lid material is reduced. Problems arise.

  In addition, the display surface of the base material for the lid material is subjected to high-definition printing for the purpose of improving the appearance of display at convenience stores, etc., and promoting purchase motivation. In the measure for improving the interlaminar strength by adding the paper strength enhancer, the increase in tightness, that is, the cushioning property is lowered, and the adhesiveness with the printing plate is lowered.

  In particular, the base material for the lid material is generally subjected to purchase-oriented high-definition gravure printing, and in gravure printing, cushioning is an important factor for printability. The decrease is a fatal problem for printability.

  On the other hand, for the conventional base material for lid materials, a measure is taken to bond an aluminum film or a resin film on the side to be bonded to the container for the purpose of improving hermeticity.

  In recent years, the bonding of aluminum films and resin films has become thinner and less aluminum with the trend of responding to the environment. Furthermore, as a recent trend, foods processed with microwave ovens have become more popular. Development of a base material for lids corresponding to the above has been demanded.

  In the conventional base material for lid materials, since an aluminum film or a resin film is bonded to the back surface of the base material for lid materials, no major problem has occurred with respect to curling behavior. Along with the trend, aluminum films and resin films have become thinner or less, and as a trend in recent years, foods processed by microwave ovens have become more popular, and there are many opportunities for the inside of containers to become hot. There is a problem of curling to the exit side.

  Therefore, recent base materials for lid materials are required to improve the interlaminar strength and processability, as well as to improve printability and curl suppression.

  In Cited Document 1, in the coated paper for aluminum foil bonding, which is used for aluminum foil bonding, various irregularities, both large and small, that occur during aluminum foil bonding due to the entanglement and texture of cellulose fibers derived from the base paper, The technique solved by giving a surface sizing agent to the foil bonding surface is disclosed.

  Although the technique disclosed in the cited document 1 discloses a technique for controlling irregularities generated on a bonding surface by an aqueous adhesive used at the time of aluminum foil bonding, the recent improvement in interlayer strength and workability is disclosed. At the same time, there is no description or suggestion about improvement measures corresponding to improvement of printability and curling suppression.

  Cited document 2 is a coated paper for bonding aluminum foil for the purpose of bonding aluminum foil, as in cited document 1, and is produced at the time of bonding aluminum foil due to the entanglement and texture of cellulose fibers derived from the base paper. Various large and small irregularities can be solved by applying an aqueous coating liquid mainly composed of pigment and adhesive to the aluminum foil bonding surface and then applying a surface sizing agent onto the aqueous coating liquid. Technology is disclosed.

  Although the technique disclosed in the cited document 2 discloses a method for further improving the unevenness generated on the bonding surface, it has improved the interlaminar strength and processing aptitude in recent years, and has improved printing aptitude and curl suppression. There is no description or suggestion about improvement measures.

  In Cited Document 3, as in Cited Document 1 and Cited Document 2, it is a coated paper for laminating aluminum foil for the purpose of laminating aluminum foil. In order to improve the extremely fine unevenness in the large and small unevenness generated at the time of foil bonding, the surface sizing agent is applied to the aluminum foil bonding surface and the surface roughness SRa of the surface sizing agent applying surface is within a predetermined range. It is a technology characterized by doing.

  Although the technique disclosed in the cited document 3 discloses a measure for further improving the unevenness generated on the bonding surface, as in the cited document 1 to the cited document 2, with the recent improvement in interlayer strength and workability. There is no description or suggestion about improvement measures corresponding to improvement of printability and curling suppression.

In any of the above documents, there is no technical description or suggestion that can improve the printability and curl as well as the improvement in interlayer strength and processability, which are problems of the base material for lid materials in recent years. There is a demand for a technique for manufacturing a base material for materials.
JP 5-44195A JP 5-44196 JP-A-7-173895

  SUMMARY OF THE INVENTION The main problem to be solved by the present invention is to provide a method for producing a base material for a lid material, which is excellent in improvement in printability and curl suppression, as well as improvement in interlayer strength and processability.

  Means for solving the problems in the present invention are as follows.

A base material for a lid material having a coating layer mainly composed of a pigment and an adhesive on one side of a base paper,
The base paper is made in the presence of a paper strength enhancer based on acrylamide, using hardwood kraft pulp as the main component,
The freeness according to JIS P 8121 of the pulp after disaggregation which disaggregated the said base material for lid | covers based on JISP8220 is 350cc-500cc,
The weight average fiber length of the pulp after disaggregation is 0.5 mm to 1.0 mm,
90% by weight or more of the pulp after disaggregation is occupied by fibers having a fiber length of 1.5 mm or less,
In the width direction and the flow direction of the lid base material, TAPPI No. The average value of the internal bond based on 18-2 is 200 mJ or more, The base material for lid | cover materials characterized by the above-mentioned.

  In the present invention, the lid material is a member that seals the opening of a container for storing contents such as toiletries such as detergents for clothes, softeners, shampoos, rinses, cosmetics, beverages, and foodstuffs. It is a member for sealing the container by heat sealing the material with the flange of the container body. The lid is made of a laminate with a base material, a metal film such as an aluminum foil, a heat sealing layer, etc., and the upper surface of the lid (the surface outside the container when the container is sealed) can be beautifully printed. This is a surface, and has a metal film such as an aluminum foil, a heat-sealing layer, or the like on the lower surface of the lid (the surface inside the container when the container is sealed). The base material for lid | cover materials means the base material for laminating | stacking the metal films and heat sealable layers, such as the said aluminum. The base material for the lid material is formed by forming a metal film such as aluminum or a heat-sealing layer on the lower surface to form a laminate, and further performing artistic printing etc. on the upper surface, and punching processing etc. along the shape of various containers By doing so, it is processed into a lid material.

  ADVANTAGE OF THE INVENTION According to this invention, interlayer strength, workability, and printability improve, and the base material for lid | cover materials by which generation | occurrence | production of curl was suppressed can be obtained.

  Embodiments of the present invention will be described below.

  -It has a coating layer mainly composed of pigment and adhesive on one side of the base paper.

  The pigment that can be suitably used in the present invention has a volume average particle diameter of 0.10 to 0.40 μm, a fine kaolin (A) having an aspect ratio of 7 to 13, and a volume average particle diameter of 0.20 to 0.60 μm. Of heavy calcium carbonate (B) is contained at a weight ratio of (A) :( B) = 30: 70 to 70:30.

  The pigment for the base material for the lid material is a fine kaolin (A) having a volume average particle diameter of 0.10 to 0.40 μm, an aspect ratio of 7 to 13 and a heavy carbonic acid having a volume average particle diameter of 0.20 to 0.60 μm. The calcium (B) is used in a weight ratio of (A) :( B) = 30: 70 to 70:30, more preferably 40:60 to 60:40.

  As a pigment contained in the coating layer, a volume average particle diameter of 0.10 to 0.40 μm, more preferably 0.20 to 0.35 μm, an aspect ratio of 7 to 13, and more preferably 8 to 12 fine particles It is preferable to use kaolin (A) and heavy calcium carbonate (B) having a volume average particle size of 0.20 to 0.60 μm, more preferably 0.30 to 0.50 μm.

  If the volume average particle size of fine kaolin is less than 0.10 μm, the particles are too fine and a considerable amount of binder is required, and binder migration occurs, so the ink acceptability in the coating layer becomes poor during gravure printing, resulting in poor drying. The operability during gravure printing deteriorates. When it exceeds 0.40 μm, the particle diameter is too large, the fluidity of the paint is deteriorated, and the coating suitability is deteriorated. That is, streaks occur, and it is necessary to lower the paint concentration, resulting in a decrease in productivity. The thickness is preferably 0.20 to 0.30 μm.

  Fine powder kaolin having an aspect ratio of less than 7 cannot provide high halftone dot reproducibility because the voids in the pigment become large. On the other hand, if it exceeds 13, the fluidity of the coating is deteriorated and the coating suitability is deteriorated. That is, streaks occur, and it is necessary to lower the paint concentration, resulting in a decrease in productivity.

  If the volume average particle size of the heavy calcium carbonate is less than 0.20 μm, the particles are too fine and a considerable amount of binder is required, and binder migration occurs, so that the ink acceptability in the coating layer becomes poor during gravure printing, resulting in poor drying. Occurs and operability during gravure printing deteriorates. When it exceeds 0.60 μm, the particle diameter is too large, the fluidity of the paint is deteriorated, and the coating suitability is deteriorated. That is, streaks occur, and it is necessary to lower the paint concentration, resulting in a decrease in productivity. Preferably it is 0.30-0.50 micrometer.

  As a pigment to be contained in the coating layer, it is preferable to contain fine kaolin (A): heavy calcium carbonate (B) in a weight ratio of 30:70 to 70:30. When the weight ratio of the fine kaolin is less than 30, the ratio of heavy calcium carbonate is too large, so that the voids in the pigment increase and high halftone dot reproducibility cannot be obtained. If it exceeds 70, the fluidity of the paint will deteriorate and the coating suitability will deteriorate. That is, streaks occur, and it is necessary to lower the paint concentration, resulting in a decrease in productivity.

  Adhesives preferably used in the present invention include styrene / butadiene copolymer (SBR), acrylonitrile / butadiene copolymer (NBR), acrylic acid ester or methacrylic acid ester polymer or copolymer, ethylene / acetic acid Mention may be made of various latexes of vinyl copolymers. In particular, among SBR latexes, those having a styrene content of 50 wt% to 80 wt% that are rich in styrene are preferable because they have no effect of blocking the paper surface with soft butadiene and have an effect of improving smoothness.

The coating layer in the present invention is provided at 8 to ²⁰ g / m ² , preferably 12 to 16 g / m ² . If the coating layer is less than 8 g / m ² , the coating property is insufficient, and if it exceeds 20 g / m ² , cracking of the coating layer or paper dust may occur at the time of peeling and opening the lid from the container, which is not preferable.

  As the coating method, for example, various known coating methods such as a two-roll size press, a transfer roll coater, a rod metering size press coater, a blade coater, an air knife coater, a bar coater, and a gravure coater can be used. It is preferable to use a blade coater in order to easily apply to a glossy surface (one surface) and to enable high-definition gravure printing.

  -Hardwood kraft pulp is used as the main component of the pulp constituting the base paper.

  The hardwood kraft pulp in the present invention may be hardwood unbleached kraft pulp (that is, LUKP), hardwood bleached kraft pulp (that is, LBKP), or a mixture of both.

  In the present invention, the content of hardwood kraft pulp is 50% by weight or more, preferably 100% by weight of the total amount of pulp, combined with freeness of pulp after disaggregation and Runkel ratio, Thus, a lid base material having high dimensional stability, no generation of paper dust, and cushioning properties can be obtained.

  As pulp other than hardwood kraft pulp, softwood kraft pulp, waste paper pulp and the like may be blended.

  The paper is made in the presence of a paper strength enhancer based on acrylamide.

  Examples of paper strength enhancers based on acrylamide include polyacrylamides such as anionic polyacrylamide, cationic polyacrylamide, and amphoteric polyacrylamide. Examples of the anionic polyacrylamide include a copolymer of acrylamide and an anionic monomer such as acrylic acid or methacrylic acid, and a partial hydrolyzate of polyacrylamide. Cationic polyacrylamides include Mannich modified products of polyacrylamide, Hoffman degradation products, or acrylamide and dimethylaminoethyl methacrylate, diallyldimethylammonium chloride, diallyldiethylammonium chloride, methacryloyloxyethyltrimethylammonium methylsulfate, methacryloyloxyethyltrimethyl. Examples thereof include copolymers with cationic monomers such as ammonium methyl chloride and methacrylamidopropyltrimethylammonium chloride. Examples of the amphoteric polyacrylamide include a copolymer of acrylamide and an anionic monomer and a cationic monomer, a Mannich modified product of a copolymer of acrylamide and the anionic monomer, and a Hoffmann degradation product. Of these, amphoteric polyacrylamide is preferred. These polyacrylamide polymer compounds may be used alone or in combination of two or more.

  -The freeness based on JISP8121 of the pulp after the disaggregation which disaggregated the said base material for lid | covers based on JISP8220 is 350cc-500cc.

  When the freeness is less than 350 cc, fibrillation of the fiber is promoted too much, and the specific surface area of the fiber increases, resulting in deterioration of dimensional stability. If the freeness exceeds 500 cc, fiber fibrillation does not progress and the bonding between layers weakens, so that paper peeling occurs when the lid is opened, and the paper itself becomes rigid, resulting in poor processability and paper dust.

  The means for adjusting the freeness according to JIS P 8121 of the pulp after disaggregation according to JIS P 8220 to 350 cc to 500 cc is adjusted by a conventionally known method by the degree of beating to raw pulp, physical classification means, etc. Is possible.

  The freeness according to JIS P 8121 of the pulp after disaggregation according to JIS P 8220, which is used as an index in the present invention, is different from the freeness at the raw pulp adjustment stage, and the fine fibers in the raw pulp during papermaking are white water. In addition, the paper strength enhancer based on acrylamide is the freeness in the paper layer formation as a result of the aggregation and bonding of the raw material pulp constituting the base material for the lid material between the fibers by the paper strength enhancer. It can be suitably used as an index reflecting the effect of.

  -The weight average fiber length of the pulp after said disaggregation is 0.5 mm-1.0 mm.

  If a pulp with a weight average fiber length exceeding 1.0 mm is used, the binding of the pulp fibers will occur and the formation will deteriorate, so the coating amount will not increase in order to satisfy high-definition gravure printing suitability In addition, since air permeability is increased, bubbling occurs when an aluminum film or a resin film is bonded. On the other hand, when a pulp having a weight average fiber length of less than 0.5 mm is used, the formation is good, but the tension is increased too much, so that the cushioning property is lowered, and the suitability for punching as a cover material is lowered. To do.

  -Fibers having a fiber length of 1.5 mm or less occupy 90% by weight or more of the pulp after disaggregation.

  By using a pulp containing 90% by weight or more of fibers having a fiber length of 1.5 mm or less in the pulp after disaggregation as the raw material pulp constituting the base paper, the paper layer becomes uniform and the lid has excellent surface smoothness. A base material for materials can be obtained.

  The base material for the lid material is a pulp raw material constituting the base paper, and the weight average fiber length of the pulp after disaggregation is 0.5 mm to 1.0 mm, and the fibers having a fiber length of 1.5 mm or less are 90% by weight or more, A pulp containing 93 to 97% by weight is preferably used. More preferably, the weight average fiber length is adjusted to 0.6 to 0.9 mm, and more preferably 0.65 to 0.85 mm.

  The adjustment of the fiber length is performed by a beating process and a screening process.

  As a means of ensuring cushioning properties, attempts to blend mechanical pulp into raw pulp can be considered. However, when mechanical pulp is blended, it is possible to improve the cushioning properties and punching suitability of the base material for lids. Because of the appearance of fibers on the surface of coated paper for gravure printing, the appearance of the printed matter tends to deteriorate from the halftone part, which is particularly affected by the surface property of the white paper, to the highlight part. It is preferable to use hardwood kraft pulp of 50% by weight or more, preferably 100% by weight of hardwood kraft pulp as a main component.

  Furthermore, if a pulp having a weight average fiber length exceeding 1.0 mm is used, the binding of the pulp fibers is generated and the formation is deteriorated. Therefore, the coating amount is increased in order to satisfy high-definition gravure printing suitability. It is necessary to reduce the cushioning properties of the paper as the coating amount increases. On the other hand, when a pulp having a weight average fiber length of less than 0.5 mm is used, the formation is good, but since the tension is too high, the cushioning property is lowered and the gravure printing suitability is lowered.

The freeness according to JIS P 8121 of the pulp after disaggregation which disaggregated the said base material for lid | covers based on JISP8220 is 350cc-500cc,
The weight average fiber length of the pulp after disaggregation is 0.5 mm to 1.0 mm,
90% by weight or more of the pulp after the disaggregation is occupied by fibers having a fiber length of 1.5 mm or less, and synergistically improves the interlaminar strength, cushioning and dimensional stability by improving the texture of the base paper, and further increases the paper strength. The combination with the agent can suppress the generation of paper dust and improve punchability.

-J. in the width direction and the flow direction of the said base material for lid | cover materials. TAPPI No. The average value of the internal bond based on 18-2 is 200 mJ or more. Coating by measurement with an internal bond tester (manufactured by Kumagaya Riki Kogyo Co., Ltd.) based on "Paper and paperboard-Internal bond strength test method-Part 2: Internal bond tester method" specified in 18-2 With respect to the internal bond (internal bond strength) from the surface of the work layer, the average value of N = 10 measured 5 times each in the flow direction and the width direction is 200 mJ or more, preferably 220 mJ or more. When the internal bond strength is less than 200 mJ, there is a problem of peeling between layers when used as a lid material, for example. When the internal bond is too large, the glossy paper itself becomes rigid, for example, when the lid material is processed, the adhesiveness with the container is inferior, and at the time of opening, there are cracks or fractured cracks at the bent part. The internal bond strength is preferably 500 mJ or less because there is a risk that it may occur.

  The internal bond can be adjusted by selecting the type of pulp to be used and adjusting the jet wire ratio, but the internal bond (internal bond strength) from the coating layer surface in the present invention is 200 mJ or more. In addition, it is preferable that a paper strength enhancer based on acrylamide is contained in the substrate as a means suitable for setting to 220 mJ or more.

  According to a preferred embodiment of the present invention, the paper strength enhancer based on acrylamide is an amphoteric polyacrylamide, and the content thereof is 1.0 to 3.0 weight as solid content per pulp solid content. And the Runkel ratio when the lid base material is disaggregated in accordance with JIS P 8220 is 0.9 or less.

  -Amphoteric polyacrylamide is used as the paper strength enhancer.

  In the present invention, the paper strength enhancer based on acrylamide can be suitably used by improving the interlayer strength, suppressing the generation of paper dust and also having a curl suppressing effect while maintaining cushioning properties. However, it is more preferable to use amphoteric polyacrylamide.

  Examples of the amphoteric polyacrylamide include a copolymer of acrylamide and an anionic monomer and a cationic monomer, a Mannich modified product of a copolymer of acrylamide and the anionic monomer, and a Hoffmann degradation product. These polyacrylamide polymer compounds may be used alone or in combination of two or more.

  Since the amphoteric polyacrylamide-based paper strength enhancer that can be suitably used in the present invention has a self-fixing action, by incorporating this into the base paper, the effect on conventional printing paper and the like can be obtained. It is possible to improve not only the tensile strength (or tearing length) and stiffness, but also the Z-axis strength. Furthermore, the dimensional stability is a characteristic of the base material for lids, and there is no generation of paper dust. In addition, the cushioning property can be maintained and the printability can be improved.

  -The amphoteric polyacrylamide is contained in an amount of 1.0 to 3.0% by weight as a solid content per pulp solid content.

  Increasing the content of the polyacrylamide paper strength enhancer generates flocs in the pulp slurry. Therefore, in order to maintain a good level of operability and product formation, There are restrictions on the amount.

  According to the knowledge of the present inventors, the dimensional stability is high, there is no generation of paper dust, and the addition amount for maintaining cushioning properties is 1.0 to 3.0% by weight as the solid content per pulp solid content. It has been found that it is preferable to contain.

  If the solid content per pulp solid content is less than 1.0% by weight, the tensile strength (or breaking length) and stiffness, and the characteristics of the base material for lid materials, such as improvement of Z-axis strength, dimensional stability, paper The effect which contributes to improvement of powder generation is not seen.

  When the content exceeds 3.0% by weight as the solid content per pulp solid content, flocs are generated in the pulp slurry, and it is difficult to maintain the operability and the product formation at a good level. At the same time, paper dust is generated.

  -Runkel ratio when the said base material for lid | cover materials is disaggregated based on JISP8220 is 0.9 or less.

  If the Runkel ratio exceeds 0.9, cushioning properties necessary for punching cannot be obtained.

If fibers with a small Runkel ratio (thin fiber walls) are used, for example, when an adhesive or the like is provided on the back surface of the base material for the lid, there may be a problem that the permeability of the adhesive into the fibers becomes excessive. In addition, the wet press cannot be sufficiently applied to maintain the cushioning property, and the flatness of the glossy surface is likely to be uneven, which is not preferable. Moreover, since a fiber with a small Runkel ratio (thin fiber wall) is inferior in rigidity, problems such as deterioration in dimensional stability and underwater elongation occur. Therefore, it is preferable that the Runkel ratio exceeds 0.6.
The pulp fiber has a lumen (lumen), which collapses itself and leads to a cushion function as a whole paper. Therefore, the ratio between the lumen and the thickness of the outer ring (cell wall) is important for cushioning. . Therefore, there is a Runkel ratio as an index for evaluating the cushioning properties of pulp fibers.

  The Runkel ratio (R) is a value obtained from the width (diameter) (L) of the lumen of the fiber and the thickness (t) of the cell wall, and is represented by R = 2 · t / L. The measurement of the Runkel ratio described in the examples was performed using Fiber Lab. It is calculated from the fiber width and cell wall thickness measured by (kajaani). It can be said that the fiber having a larger Runkel ratio is a rigid fiber, and when such a fiber is used, paper having a low density can be easily made. Moreover, the lower the numerical value, the thinner the fiber wall with respect to the same diameter, and the fiber is more flexible. When paper is made using pulp fibers having a large Runkel ratio of pulp that has been disaggregated according to JIS P 8220, it becomes a porous paper with a small bonding area between the fibers, and cushioning properties are improved, but if the Runkel ratio is too large, Since the bonding area between the fibers becomes very small, not only the strength and stiffness are lowered, but also the surface property is lowered, so that the gravure printing suitability is also lowered.

  According to the knowledge of the present inventors, if the Runkel ratio of the pulp after disaggregation is 0.9 or less, more preferably 0.6 to 0.9, cushioning properties suitable for gravure printing can be obtained. In order to obtain pulp fibers with a Runkel ratio of 0.9 or less, it is preferable to use planted trees and thinned wood that have been cut at a relatively young stage as wood used as a raw material for pulp. If fibers with a small Runkel ratio (thin fiber walls) are used, for example, when an adhesive or the like is provided on the back surface of the base material for the lid, the problem of excessive penetration of the adhesive into the fibers tends to occur. In addition to problems, it is not preferable that the wet press is not sufficiently applied to maintain the cushioning property, and the flatness of the glossy surface is likely to be uneven. Moreover, since a fiber with a small Runkel ratio (thin fiber wall) is inferior in rigidity, there arises a problem that the dimensional stability (elongation in water) deteriorates. Therefore, the Runkel ratio is preferably more than 0.6.

According to a preferred aspect of the present invention, the base paper has a glossy surface that has been dried by a Yankee dryer,
The glossy surface is provided with the coating layer,
According to JIS P 8119, the coating layer surface has a Beck smoothness of 500 seconds to 2000 seconds,
The average value of the delamination strength in the width direction and the flow direction of the base material for lids is 200 to 250 N / m.

  -The base paper has a glossy surface dried by a Yankee dryer.

  As a use application of the base material for a lid material obtained in the present invention, a gravure printing is performed on a glossy surface having a coating layer of the base material for a lid material as a configuration, although the lid material is mainly a food packaging material. An adhesive layer is provided on the surface, and a process of bonding with an aluminum film or a resin film is performed. The gravure printing surface requires high smoothness, while the bonding surface is smooth to increase the specific surface area between the adhesive, the base paper, the aluminum film, and the resin film in order to increase the bonding strength and increase the degree of adhesion. Since a low degree is required, it is preferable to use Yankee paper as the base paper in the present invention because a smoothness difference can be provided.

  Yankee paper is good for dimensional stability due to tension drying and curling during reabsorption.

  When the base paper is dried with a Yankee dryer, the Yankee dryer contact surface (glossy surface) of the base paper copies the Yankee dryer mirror surface, so that the surface smoothness is excellent and a smoother coating layer can be provided.

  In addition, drying with a Yankee dryer has less cushioning during drying, so it dries with cushioning properties, so high-definition gravure printing is possible during gravure printing, and misregistration does not occur, and halftone dot reproducibility is also good. It is.

The basis weight of the base paper of the base material for a lid material in the present invention is preferably 40 to 80 g / m ² , more preferably 40 to 60 g / m ² . If it is less than 40 g / m ² , it is difficult to secure paper strength, and sufficient cushioning properties for high-definition gravure printing may not be provided, so that halftone dot reproducibility during gravure printing does not appear.

On the other hand, if it exceeds 80 g / m ² , the bulk strength increases and the interlayer strength decreases. Therefore, it is conceivable to further reduce the freeness, but it is not possible to provide cushioning for performing high-quality gravure printing.

  The coating layer is provided on the glossy surface.

  In order to produce the base paper for the base material for a lid material of the present invention, at least a wet paper forming process, a pressing process, and a drying process using a Yankee dryer are performed. In this drying step, the coating liquid is applied to one side (glossy surface) of the glossy paper on the side that comes into contact with the Yankee dryer.

  Conventionally known coating means can be appropriately used as the coating means. For example, a blade coater, an air knife coater, a bar coater, a rod blade coater, a roll coater, a gravure coater may be used in order to obtain a coated surface corresponding to the gravure printing suitability. It is formed by a method of applying and drying to a substrate by various known coating methods such as a curtain coater.

  In the coating of the present invention, a coating means using a blade coater is preferably used in accordance with gravure printing suitability.

  In the coating of the present invention, the means for coating the coating liquid on one side of the glossy paper on the side in contact with the Yankee dryer in the drying process between the wet paper forming process and the drying process is also simple. It can also be used as a coating means.

  -The Beck smoothness of the said coating layer surface based on JISP8119 is 500 second to 2000 second.

The smoothness of the surface of the coating layer provided on the glossy surface of the glossy paper used in the present invention is 500 to 2000 seconds, more preferably 1000 to 1500 seconds. If it is less than 500 seconds, the bonding property of the aluminum film or the resin film to the base material for the lid material is not sufficient, and further, the coating property of the water-soluble resin applied to the back surface is inferior, and the curl improvement property is inferior. . In addition, the higher the smoothness, the better the adhesiveness of the aluminum film or resin film, and the less glue used for the bonding, which is more economical. In order to exceed 2000 seconds, it is necessary to reduce the freeness, improve the press pressure in the papermaking press process, etc., and the cushioning property is lowered. Further, as an index of flatness, the smoothness (regular reflection smoothness) of the surface of the lid base material of the present invention is measured using a microtopograph manufactured by Toyo Seiki Seisakusho at a pressure of 24.4 kg / cm ^2. It was crimped to one surface and evaluated by the Rp value when measured using light having a wavelength of 0.5 μm.

  As a means for adjusting the Beck smoothness of the coating layer surface from 500 seconds to 2000 seconds, a flattening treatment by a conventionally known calendar method is possible, but preferably the coating layer while suppressing the amount of change in density. It is preferable to use a soft calender composed of a combination of a metal roll and an elastic roll capable of flattening the surface. Flattening with a single stack process in which the metal surface of the soft calender is applied to the coating layer side has less change in density and improves the interlaminar strength and workability, which are the problems of the present invention, as well as the printability. It is suitable for obtaining a base material for a lid material excellent in curling suppression.

The nip pressure under gravure printing is usually 10 to 20 kgf / cm ² , and the passing time of the nip is said to be around 1 millisecond, and the smoothness of the paper under a very short pressurization, that is, the paper and the gravure It can be seen that the contact rate with the printing plate is important. Conventionally, a specular reflection smoothness meter (a microtopograph manufactured by Toyo Seiki Seisakusho Co., Ltd.) is known as an apparatus for measuring the optical contact rate between a glass surface and paper under pressure. In the microtopograph, it is impossible to read the contact rate around 1 millisecond after the start of pressurization, but it is possible to read the optical contact rate between the glass surface and paper 10 ms after the start of pressurization at the shortest. Yes, Rp value (proportional to the average depth of the recesses), which is an index of smoothness calculated from the contact ratio between the glossy surface (coating layer) and the glass surface of the base material for lid materials using Yankee paper as the base paper (Physical quantity: unit μm) and the occurrence rate of missing dots, the Rp value 10 milliseconds after the start of pressurization with the setting of pressurization pressure of 24.4 kgf / cm ² of the microtopograph is the highest occurrence rate of missing dots. It was found that the correlation was high.

In other words, unlike coated paper using conventional high-quality paper, Yankee paper has a rough back surface and a glossy surface with a coating layer. The Rp value 10 milliseconds after the start of pressurization at a set pressure 24.4 kgf / cm ² of a microtopograph with a high nip pressure under gravure printing is set to 2.0 μm or less, preferably 1.8 μm or less. By providing the base paper made of Yankee paper and the coating layer as described above, it is possible to obtain good gravure printing aptitude.

  As a method of obtaining the Rp value desired by the present invention, as a pulp main raw material constituting the base paper, in addition to using hardwood kraft pulp having a Runkel ratio of 0.9 or less, a weight average as a pulp raw material constituting the base paper A pulp having a fiber length of 0.5 mm to 1.0 mm and containing 90% or more of a fiber having a fiber length of 1.5 mm or less is used. The pigment used in the coating layer has a volume average particle size of 0.10 to 0.40 μm. The weight ratio of fine kaolin (A) having an aspect ratio of 7 to 13 and heavy calcium carbonate (B) having a volume average particle diameter of 0.20 to 0.60 μm is (A) :( B) = 30: 70. It is mentioned as a suitable means to contain by -70: 30.

  Although the lower limit of the Rp value is not particularly limited, the lower limit value of the Rp value is 0.5 μm in consideration of the appearance characteristics of the matte coated paper. Incidentally, if the thickness is less than 0.5 μm, the applicability of high-definition gravure printing may be lowered. If it exceeds 2 μm, the halftone dot reproducibility necessary for high-definition gravure printing cannot be obtained.

The average value of the delamination strength in the width direction and the flow direction of the base material for the lid material is 200 to 250 N / m. The delamination strength referred to in the present invention is a delamination tester (model number: SP). -2000, manufactured by IMASS).

  A sample having a thickness of 200 mm in the peel strength measurement direction and a width of 15 mm is prepared, and the sample is rubbed on a double-sided adhesive tape (model number: 4970 manufactured by TESA) 10 times on a desk using a wooden board attached to both sides of the paper sample.

  At the same time, quickly pull the tape affixed to both sides of the paper so that it tears between the paper layers.

  Remove the adhesive tape on one side of the paper, stick it to the iron plate, and set the iron plate on the peel tester.

  One end of the paper not bonded to the iron plate is fixed with a load measuring clip of a peel tester so that an angle of 90 degrees can be formed.

  The iron plate is moved at a speed of 756 cm / min (300 inches / min), with peeling. At that time, the load applied to the clip is measured, and the average value during movement is calculated as the delamination strength (N / m). The average value of N number = 6, measured three times for each of the flow direction and the width direction of the base material for lids, was taken as the measurement value.

  The delamination strength is suitably used as an index indicating the continuous peeling force at the time of opening when the base material for a lid material of the present invention is used as a lid material, unlike the impact peeling force by an internal bond tester. Unlike the instantaneous peel strength improvement effect by a paper strength enhancer or the like, the fiber length, Runkel ratio, freeness, etc. suitably used in the present invention are preferably used as an index in a configuration that exhibits the effect. The inventors of the present invention, most preferably, have an impact peeling force by an internal bond tester, and also have an effect of a predetermined strength or higher in the delamination strength, and satisfy both effects. Heading.

According to a preferred embodiment of the present invention, a water-soluble resin is applied in a solid content of 0.1 to 3.0 g / m ² on the back surface of the base paper,
The water-soluble resin contains, as main components, oxidized starch (A) and a polyamide water-resistant agent (B),
The blending ratio of the oxidized starch (A) and the polyamide water-resistant agent (B) is (A) :( B) = 95: 5 to 85:15 in terms of solid content weight ratio.

  As the water-proofing agent on the back surface of the base paper, known water-proofing agents can be used, and those obtained by cationically modifying a polyamide resin or an epoxy resin with a secondary, tertiary amino group or quaternary ammonium base are preferable. Used in more than one type. Among them, a polyamide resin modified with a secondary amino group is preferably used because of its high compatibility with oxidized starch and cost effectiveness in curling suppression.

In a preferred configuration of the present invention, a water-soluble resin is applied to the back surface (the surface opposite to the surface on which the coating layer is provided) of the base material for lid material made of Yankee paper. The water-soluble resin is prepared by applying 0.1 to 8.0 g / m ² of a mixed aqueous coating solution of starch and a water-proofing agent by a coating means such as a bar coater or a roll coater, and then further drying the surface. By performing a smoothing process at a linear pressure of about 60 kN / m using a calendar made of a metal roll having a temperature of 180 ° C., the anti-curling agent for the lid base material according to the present invention and the adhesive on the adhesive coating surface The quality related to the surface properties of the base material for lid materials, such as coating properties, can be improved.

-On the back surface of the base paper, 0.1 to 8.0 g / m ^{2 of} water-soluble resin is applied in solid content.

When a coating layer is provided on one side of the base paper, curling is likely to occur due to the difference in hygroscopicity / stretchability between the base paper layer and the coating layer. Therefore, when a coating layer is formed on one side, it is preferable to coat a water-soluble resin for the purpose of dimensional stabilization on the opposite side.
The coating amount is 0.1 to 8.0 g / m ² and preferably 0.5 to 2.5 g / m ² . If it is less than 0.1 g / m ² , the effect as a water-soluble resin for dimensional stabilization is not exhibited, and curling is not suppressed. When it exceeds 8.0 g / m ² , punching suitability due to a decrease in cushioning properties is deteriorated.

  -The said water-soluble resin contains an oxidized starch (A) and a polyamide-type water-resistant agent (B) as a main component.

  What coated the water-soluble resin which consists of oxidized starch and a polyamide-type water-resistant agent for the purpose of curling prevention on the back surface of the base material of the base material for lid | cover materials is good. Other methods are possible, such as applying a paint consisting of a pigment and an adhesive, or adding water to prevent curling, but pigment coating avoids curling due to moisture absorption, but it reduces air permeability. Heat does not escape from the paper layer when bonded to an aluminum film or a resin film, and processing problems such as bubbling occur. Even in the configuration in which water is applied, there is a problem that curling occurs again on the glossy side of the base paper by drying at the time of bonding the aluminum film or the resin film.

  On the other hand, the combination of oxidized starch and water-resistant agent Starch is an inexpensive product and has the property of increasing the viscosity under the heating conditions when bonding aluminum film or resin film. Water absorption is prevented and the lid material has the most excellent dimensional stability after bonding. Further, since oxidized starch is a viscoelastic fluid, it can retain cushioning properties during printing.

  In the present invention, among the oxidized starches, oxidized starches that have undergone aldehyde modification can be suitably used. By using oxidized starch modified with low viscosity aldehyde which has aldehyde group as a generated functional group, it enhances inter-fiber bonding by enhancing permeability into paper and improves internal bond strength. It has been found to improve the air permeability by reducing the ring.

  As a result, compared with the case where self-modified starch is used, an interlayer strength equal to or higher than that can be secured, the amount of addition of the acrylamide-based paper strength enhancer can be reduced, and the degree of beating also conforms to JIS P 8220. It is easy to adjust the freeness according to JIS P 8121 from 350cc to 500cc after the disaggregation of the pulp for the base material for the lid material, so that the beating is rough within a range that does not affect the drainage and texture. Accordingly, it is possible to obtain a base material for a lid material that suppresses an increase in tightness and improves interlaminar strength and processability, as well as improved printability and curl suppression.

  -The compounding ratio of oxidized starch (A) and a polyamide-type water-resistant agent (B) is (A) :( B) = 95: 5-85: 15 by solid content weight ratio.

  If the weight ratio of the water-proofing agent (B) is less than 5, the effect of the water-proofing agent is reduced, so that the occurrence of curling due to water absorption cannot be sufficiently prevented and the dimensional stability is not improved. If the weight ratio of the water-resistant agent (B) exceeds 15, the adhesive used at the time of laminating the back surface aluminum film of the lid material is water-based, so that the penetration of the adhesive into the paper substrate is weakened by increasing the water repellency too much. Therefore, in addition to the decrease in the adhesive strength during bonding, bubbling occurs during the bonding of the aluminum film due to the increase in film properties.

(Preferred embodiment of the present invention)
It is preferable to include a wet paper strength enhancer in the coating layer on the surface of the base paper. The wet paper strength enhancer contained in the coating layer is not particularly limited. For example, urea resin, melamine resin, urea-formaldehyde resin, melamine-formaldehyde resin, polyamide-polyurea-formaldehyde resin, polyamide resin, Polyamide-epichlorohydrin resin, polyamide-polyamine-epichlorohydrin resin, epoxidized polyamide resin, polyethyleneimine resin, aldehyde starch, ketone aldehyde resin and the like can be mentioned, and two or more kinds can be used together as necessary. Of these, polyamide epichlorohydrin resin is preferably used.

  If the content of the wet paper strength enhancer is too small, it is difficult to obtain sufficient water resistance and elongation in water, and if it is too much, poor operability in paint adjustment and inadvertent coagulation are likely to occur. It is desirable to contain 0.3 to 1.0% by weight per pigment. By containing in this range in this invention, the target water resistance and elongation in water can be obtained efficiently, without impairing operativity. More preferably, it is 0.3 to 0.5% by weight.

  When the solid content is less than 0.3% by weight per pigment, it is difficult to obtain sufficient water resistance and elongation in water, and when the content exceeds 1.0% by weight, a coating layer that originally exhibits anionic properties is formed. However, the problem of gelation of coating liquid and generation of aggregates is likely to occur, resulting in problems in operability.

  The lid base material preferably has a Gurley permeability (JIS P 8117) of 1000 seconds or more and an underwater elongation of 2.5% or less (paper width direction).

  In the present invention, by setting the Gurley air permeability to 1000 seconds or more, in the case of gravure printing, while maintaining dimensional stability against heating at the time of drying after printing, the adhesive particularly when used in label applications It is possible to suppress the excessive permeability of the resin and to reduce the disposal property after use and the amount of adhesive used.

  In order to suppress the air permeability of the lid material, in addition to increasing the air permeability of the base material for the lid material, the air permeability of the coating layer is suppressed. In the present invention, as a pulp main raw material constituting the base paper, in addition to containing hardwood kraft pulp having a Runkel ratio of 0.9 or less, a weight average fiber length of 0.5 mm to 1 as a pulp raw material constituting the base paper A method of using a pulp containing 90% or more of fibers having a fiber length of 1.5 mm or less at 0.0 mm is preferable, and in forming the coating layer, a volume average particle size of 0.10 is used for the pigment used in the coating layer. A fine kaolin (A) having an aspect ratio of 7 to 13 and a heavy calcium carbonate (B) having a volume average particle diameter of 0.20 to 0.60 μm in a weight ratio of (A) :( B) It is used as a suitable means to make it contain by = 30: 70-70: 30.

  In addition, attempts to increase the tightness of the paper layer, such as increasing the press line pressure during papermaking, can be considered, but excessive measures have the problem of lowering cushioning properties, and mainly the composition of the raw material pulp and coating layer It is preferable to adjust.

  Further, if the air permeability is less than 1000 seconds, the ink easily penetrates into the paper, the ink sealing property on the coated surface is deteriorated, and the halftone dot reproducibility does not appear. 1000 seconds to 3500 seconds are preferable. If it exceeds 3500 seconds, heat does not escape from the paper layer during bonding with aluminum or a film, which causes processing problems such as bubbling.

  The base material for a lid material of the present invention has a J.I. TAPPI No. The elongation in water after 20 minutes based on No. 27 is preferably 2.5% or less, more preferably 2.2% or less.

  The underwater elongation is 2.5% or less. In high-definition gravure printing applications, high halftone dot reproducibility is required, but if it exceeds 2.5%, misregistration at the time of printing occurs due to shrinkage of the paper in the drying process during gravure printing.

  In addition, in a label application where the base material for a lid material of the present invention is suitably used, when the underwater elongation exceeds 2.5%, an adhesive provided on the back surface of the base material for the lid material may be applied, If moisture is contained in the coating layer or base paper provided on the glossy surface, dimensional changes will occur in the base material or coating layer, so the workability will deteriorate when sticking to the adherend. Occurs. The underwater elongation is ideally 0%, but the lower limit of the underwater elongation is practically about 0.5%.

Hereinafter, examples according to the present invention will be described in detail with reference to comparative examples. In addition, the addition amount of each chemical | medical agent is solid content. Hereinafter, the number of parts represents parts by weight, and% represents% by weight.
[Example 1]
<Adjustment of base paper>
Using 100% hardwood bleached kraft pulp (LBKP) made mainly from Chilean eucalyptus chips, using a hardwood bleached kraft pulp adjusted to a Runkel ratio of 0.75 by applying a viscous beating at the pulp adjustment stage, 1.5% by weight of a paper strength enhancer based on acrylamide (trade name: DS4366, manufactured by Seiko PMC Co., Ltd., amphoteric polyacrylamide) in the amount shown in Table 1 and sizing agent (trade name: NES555, Harima Kasei) Co., Ltd.) was added in an amount of 0.4% by weight, and the raw materials were adjusted, and then a paper machine having a Yankee dryer was used to make a base paper having a basis weight of 60 g / m ² .

<Adjustment of glossy coating layer coating solution>
Fine pigment kaolin (trade name: Kaofine, manufactured by Seal Co., Ltd., average particle size: 0.25 μm, aspect ratio: 10) as a pigment and heavy calcium carbonate (trade name: Carbital 97, manufactured by Imerizu Minerals Japan, A pigment slurry was prepared by adding 50 parts of an average particle size: 0.4 μm) and 0.1 part of a dispersant (trade name: Aron T-540, manufactured by Toa Gosei Co., Ltd.) and dispersing in water using a Coreless disperser.

To this pigment slurry, as an adhesive, 3.0 parts of phosphate esterified starch (trade name: PN700S, manufactured by Sanwa Starch Co., Ltd.), styrene-butadiene copolymer latex (trade name: R1395, manufactured by Asahi Kasei Chemicals) ) 12 parts, wet paper strength enhancer (Starlight P
MC part number: WS4024 polyamide / epichlorohydrin) 0.4 part was added and stirred, and water was further added to prepare a coating solution having a solid content concentration of 60%.

<Formation of glossy coating layer>
The coating liquid was applied to the glossy surface of the base paper using a blade coater so that the coating amount was 15.0 g / m ^2, and the coated surface was flattened with a calendar.

<Adjustment of non-glossy surface water-soluble resin>
100 parts of oxidized starch (trade name: MS3600 manufactured by Nippon Food Processing Co., Ltd.) and 8 parts of polyamide-based water-resistant agent (trade name: Sumirez Resin 633, manufactured by Sumitomo Chemical Co., Ltd.) are added and stirred as a non-glossy surface water-soluble resin. Further, water was added to prepare a coating solution having a solid concentration of 30%. The coating liquid was applied to the back side of the base paper using a roll coater so that the coating amount was 1.5 g / m ² .

  In Examples and Comparative Examples, Chilean eucalyptus chips are used as hardwood kraft pulp (LBKP), Tasmanian Douglas fir is used in coniferous kraft pulp (NBKP), and used paper statistics by used paper recycling promotion center are used. In the classification, waste paper pulp that was deinked with imitation and color as the main raw paper was subjected to beating, disaggregation, and classification treatment to adjust the Runkel ratio.

  The freeness, the weight average fiber length, and the fiber length distribution in the present invention were adjusted using a beating means using a single disc refiner and using a classifying means in combination.

  For Comparative Example 5, cationic starch (CATO304, manufactured by NSC Japan) was used as a paper strength enhancer.

In Example 7, Reference Example 1, and Examples 9 to 12, dialdehyde-modified oxidized starch (National Starch: Cobond) was used as the oxidized starch.

The inorganic fine particles used in the present invention are as follows.
(1) Fine kaolin Examples 1-7 , Reference Example 1, Examples 9, 15, 16, Comparative Example 7
-Khao Fine (manufactured by Seal) average particle size: 0.25 μm, aspect ratio: 10
Example 10
-The particle size of kaofine was further adjusted with a wet pulverizer.
Average particle diameter: 0.20 μm, aspect ratio: 10
Example 11
-The particle size of Capim CC (manufactured by Rio Capim) was further adjusted with a wet pulverizer.
Average particle size: 0.35 μm, aspect ratio: 10
Example 12
Delaminated clay (manufactured by Engelhard), average particle size: 0.45 μm, aspect ratio: 13
Example 13
-The particle size of kaofine was further adjusted with a wet pulverizer.
Average particle size: 0.25 μm, aspect ratio: 8
Example 14
-The particle size of kaofine was further adjusted with a wet pulverizer.
Average particle diameter: 0.10 μm, aspect ratio: 12

(2) Clay Comparative Examples 1-5
-The particle size of a commercially available first grade clay was further adjusted with a wet pulverizer.
Average particle size: 0.55 μm, aspect ratio: 10
Comparative Example 6
-The particle size of a commercially available first grade clay was further adjusted with a wet pulverizer.
Average particle size: 0.55 μm, aspect ratio: 5

(3) Heavy calcium carbonate Examples 1 to 7, Reference Example 1, Examples 9 to 11, 13, 14 Comparative Examples 1 to 5, 7
Carbital 97 (Imeris Minerals Japan) average particle size: 0.40 μm
Example 12
-The particle size of Carbital 97 was further adjusted with a wet pulverizer. Average particle size: 0.20 μm
Example 15
-The particle size of Carbital 97 was further adjusted with a wet pulverizer. Average particle size: 0.30 μm
Example 16
-Carbital 60 (Imeris Minerals Japan Co., Ltd.) was classified and manufactured by wet pulverization. Average particle size: 0.5 μm
Comparative Example 6
・ Manufactured Chinese heavy calcium carbonate by classification and dry grinding. Average particle size: 1.20 μm
Various conditions of each Example and the comparative example were implemented and evaluated based on Tables 1-2.

<Evaluation means>
[Runkel ratio]
About the base material for lid | cover materials manufactured based on the Example, using the pulp after disaggregation disaggregated based on JISP8220, the width | variety (diameter) L of the fiber of the pulp and the thickness t of a cell wall are set to Kayani After measurement using Fiberlab, it was calculated by the following formula.
Runkel ratio = t (μm) × 2 / L (μm)
[US tsubo (basis weight)]
Measurement was performed according to JIS P 8124.

[Freeness after disaggregation]
The base material for lid materials manufactured based on the Example was measured according to JIS P 8121 using the pulp after disaggregation which was disaggregated according to JIS P 8220.

[Weight average fiber length]
The obtained base material for lids was disaggregated according to JIS P 8220, and based on the obtained disaggregated pulp, JAPAN TAPPI paper pulp test method No. Based on 52 "pulp and paper-fiber length test method-optical automatic measurement method", the weight average fiber length of the pulp after disaggregation was measured using a Kayani fiber length measuring machine FS-100.

(Fiber length distribution)
The obtained base material for lids was disaggregated according to JIS P 8220, and based on the obtained disaggregated pulp, JAPAN TAPPI paper pulp test method No. In accordance with 52 “Pulp and Paper—Fiber Length Test Method—Optical Automatic Measurement Method”, the ratio of fibers having a fiber length of 1.5 mm or less was measured using a Kayani fiber length measuring machine FS-100.

〔aspect ratio〕
Using an electron microscope (manufactured by Shimadzu Corporation: S-2150), an arbitrary straight line is drawn on the photograph taken at 200 times, and the major axis and minor axis are measured for 100 particles of fine kaolin applied to the straight line. The average of the aspect ratio (= major axis / minor axis) was determined from the major axis and minor axis.

[Volume average particle diameter]
The methanol dispersion of the pigment contained in the coating composition was measured with a laser particle size distribution measuring device (laser type microtrack particle size analyzer, manufactured by Nikkiso Co., Ltd.).

[Beck smoothness]
It measured based on JISP8119 about the coating layer surface provided in the exposed surface of the base material for lid | cover materials.

[Specular reflection smoothness]
The specular reflection smoothness referred to in the present specification refers to a value measured for a wavelength of 0.5 mm using a microtopograph manufactured by Toyo Seiki Co., Ltd., with a pressure of 24.4 kgf / cm ² and 10 milliseconds after the start of pressurization.

[Delamination strength]
A sample of 200 mm in the peel strength measurement direction and 15 mm in the width direction is prepared, and is rubbed on a double-sided pressure-sensitive adhesive tape (manufactured by TESA) 10 times using a wooden board attached to both sides of the paper sample 10 times.
At the same time, quickly pull the tape affixed to both sides of the paper so that it tears between the paper layers.
Remove the adhesive tape on one side of the paper, stick it to the iron plate, and set the iron plate on the peel tester.
One end of the paper not bonded to the iron plate is fixed with a load measuring clip of a peel tester so that an angle of 90 degrees can be formed.
The iron plate is moved at a speed of 756 cm / min (300 inches / min), and peeling occurs. At that time, the load applied to the clip is measured, and the average value during movement is calculated as the delamination strength (N / m). The average value of N number = 6 measured 3 times each in the flow direction and the width direction of the base material for lids was taken as the measurement value.

[Internal Bond]
It measured according to J * TAPPI-No18-2 method. Using the lid base material according to the present invention, a sample with a long side in the flow direction and a sample in the width direction were prepared, and the average value of N number = 10 was measured by measuring the width direction and the flow direction 5 times each. Value.

[Air permeability]
It measured based on JISP8117 in the state which provided the coating layer in the exposed surface of the base material for lid | cover materials.

[Elongation in water]
It is the value of the width direction of the base material for lid | cover materials based on this invention measured according to J * TAPPI-No27-28A method.

[Punching suitability]
As an evaluation method of punching process suitability, 15 sheets of paper are punched with a 25 mm diameter SC45C carbon steel belt punch (manufactured by 3H), and the fluffing of the cross section, the degree of cutting, and the degree of curling are visually judged, and the following 5 stages of 1-5 It was evaluated with.

(Evaluation criteria)
5: Very good level with no fuzz, cuts, or curls in the cross-section 4: Slight fuzz in the cross-section is seen, but it is a level with no problems with cuts and curls 3: No fuzz, cuts, or curls in the cross-section A small amount is observed, but there is no practical problem.
2: A level where there is a problem in practical use due to a large amount of fluffing, cutting defects, and curling in the cross section.
1: The level of fluffing, cutting failure, and curling in the cross section is observed and there is a problem in practical use.

〔water resistant〕
As an evaluation of water resistance, after checking offset rotary printing (offset rotary printing machine: model number LITHRONE44, manufactured by Komori Corporation, both sides are 4 color solid design and printing speed is 600 rpm), the stain condition of the printing blanket is visually judged. Evaluation was made in the following 5 grades.

(Evaluation criteria)
5: A level in which no dirt is observed on the blanket and it is extremely excellent.
4: Stain is hardly observed on the blanket, and is an excellent level.
3: A small amount of peeling of the coating layer is observed on the blanket, but at a level that is not a problem in practice.
2: A large amount of peeling of the coating layer on the blanket was observed, and there was a problem in practical use.
1: Peeling of the coating layer on the blanket was remarkably observed, and there was a problem in practical use.

[Reproducibility of halftone dots]
Printing by gravure printing was performed on the coating layer of the base material for lid materials, and the degree of ink placement was visually observed and evaluated according to the following criteria 1 to 5.

(Evaluation criteria)
5: There is no white spot.
4: Less white spots.
3: White spots are slightly noticeable.
2: Many white spots are conspicuous.
1: A lot of white spots are noticeable.

〔curl〕
Using the lid base materials of Examples and Comparative Examples that were conditioned for 15 hours in an environment of 23 ° C. and 65% RH, the samples were held in a thermostatic bath at 120 ° C. for about 1 minute. At this time, 10 pieces of each base material for each cover material was continuously measured every 3 minutes in the wrong place, taken out from the thermostatic bath, placed on a flat measurement table, and from the measurement table to the four corners of the recording paper, The linear distance between the recording paper and the surface of the measuring table was measured, and the value with the largest distance was evaluated as the measured value of curl. The evaluation criteria are as follows, and the evaluation was made in 5 stages of 1-5.

(Evaluation criteria)
5: Less than 3 mm 4: 3 mm to less than 6 mm 3: 6 mm to less than 10 mm 2: 10 mm to less than 15 mm 1: 15 mm or more

Claims (4)

A base material for a lid material having a coating layer mainly composed of a pigment and an adhesive on one side of a base paper,
The base paper is made in the presence of a paper strength enhancer based on acrylamide, using hardwood kraft pulp as the main component,
The freeness according to JIS P 8121 of the pulp after disaggregation which disaggregated the said base material for lid | covers based on JISP8220 is 350cc-500cc,
The weight average fiber length of the pulp after disaggregation is 0.5 mm to 1.0 mm,
90% by weight or more of the pulp after disaggregation is occupied by fibers having a fiber length of 1.5 mm or less,
The Runkel ratio of the pulp after disaggregation is 0.9 or less,
In the width direction and the flow direction of the lid base material, TAPPI No. The average value of the internal bond based on 18-2 is 200 mJ or more, The base material for lid | cover materials characterized by the above-mentioned. The acrylamide polyacrylamide paper strength agent to base amphoteric, claims, characterized in that its content is 1.0 to 3.0 wt% as a solid content per solid pulp content The base material for lid | cover materials of 1. The base paper has a glossy surface that has been dried by a Yankee dryer,
The glossy surface is provided with the coating layer,
According to JIS P 8119, the coating layer surface has a Beck smoothness of 500 seconds to 2000 seconds,
The base material for a lid material according to claim 1 or 2, wherein an average value of delamination strength in the width direction and the flow direction of the base material for the lid material is 200 to 250 N / m. On the back surface of the base paper, a water-soluble resin is applied in a solid content of 0.1 to 8.0 g / m ² ,
The water-soluble resin contains, as main components, oxidized starch (A) and a polyamide water-resistant agent (B),
The blending ratio of the oxidized starch (A) and the polyamide-based water-proofing agent (B) is (A) :( B) = 95: 5 to 85:15 in terms of solid content weight ratio. The base material for lid | cover materials in any one of 3.