JP5279844B2 - Oil adsorbing structure and cooking utensil using the same - Google Patents
Oil adsorbing structure and cooking utensil using the same Download PDFInfo
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- 238000010411 cooking Methods 0.000 title claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
- 239000011148 porous material Substances 0.000 claims description 23
- 239000008213 purified water Substances 0.000 claims description 10
- 239000010802 sludge Substances 0.000 claims description 7
- 239000003463 adsorbent Substances 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 238000004056 waste incineration Methods 0.000 claims description 3
- 239000002699 waste material Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims 1
- 239000003610 charcoal Substances 0.000 description 40
- 238000005259 measurement Methods 0.000 description 36
- 238000002485 combustion reaction Methods 0.000 description 30
- 238000004904 shortening Methods 0.000 description 26
- 238000002474 experimental method Methods 0.000 description 21
- 229910010272 inorganic material Inorganic materials 0.000 description 21
- 239000011147 inorganic material Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 20
- 239000007789 gas Substances 0.000 description 14
- 235000013372 meat Nutrition 0.000 description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 235000021168 barbecue Nutrition 0.000 description 12
- 230000009467 reduction Effects 0.000 description 12
- 229910021536 Zeolite Inorganic materials 0.000 description 10
- 239000002956 ash Substances 0.000 description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 10
- 239000010457 zeolite Substances 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 9
- 235000014102 seafood Nutrition 0.000 description 9
- 239000000446 fuel Substances 0.000 description 8
- 238000009529 body temperature measurement Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 239000002893 slag Substances 0.000 description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 230000001788 irregular Effects 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 241000251468 Actinopterygii Species 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 235000008429 bread Nutrition 0.000 description 4
- 235000013339 cereals Nutrition 0.000 description 4
- 235000013305 food Nutrition 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000004449 solid propellant Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000011888 foil Substances 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
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- 230000008859 change Effects 0.000 description 2
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- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- -1 firewood Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
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- 239000011435 rock Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000010801 sewage sludge Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 238000012795 verification Methods 0.000 description 2
- 210000001835 viscera Anatomy 0.000 description 2
- 241000473391 Archosargus rhomboidalis Species 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 239000004484 Briquette Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- 206010034203 Pectus Carinatum Diseases 0.000 description 1
- 230000005678 Seebeck effect Effects 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- PDMMFKSKQVNJMI-BLQWBTBKSA-N Testosterone propionate Chemical compound C1CC2=CC(=O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H](OC(=O)CC)[C@@]1(C)CC2 PDMMFKSKQVNJMI-BLQWBTBKSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000012615 aggregate Substances 0.000 description 1
- 235000015173 baked goods and baking mixes Nutrition 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
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- 230000000052 comparative effect Effects 0.000 description 1
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- 230000007423 decrease Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- 210000003238 esophagus Anatomy 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000011451 fired brick Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 210000003437 trachea Anatomy 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24C—DOMESTIC STOVES OR RANGES ; DETAILS OF DOMESTIC STOVES OR RANGES, OF GENERAL APPLICATION
- F24C15/00—Details
- F24C15/14—Spillage trays or grooves
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J36/00—Parts, details or accessories of cooking-vessels
- A47J36/02—Selection of specific materials, e.g. heavy bottoms with copper inlay or with insulating inlay
- A47J36/022—Cooking- or baking-vessels or supports thereof for using only once
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47J—KITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
- A47J37/00—Baking; Roasting; Grilling; Frying
- A47J37/01—Vessels uniquely adapted for baking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/2803—Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28057—Surface area, e.g. B.E.T specific surface area
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28078—Pore diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3007—Moulding, shaping or extruding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/30—Processes for preparing, regenerating, or reactivating
- B01J20/3042—Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Baking, Grill, Roasting (AREA)
Description
本発明は、魚介類や肉、パンなどの食材を調理する際に、滲み出る焼き汁を吸着保持する油吸着構造物及びそれを用いた調理器具に関し、調理器具内の油の飛び散りを予防するとともに、熱効率向上にともない焼き時間の短縮や燃料の削減ができ、調理器具および食材を好適な環境で調理できる油吸着構造物及びそれを用いた調理器具に関する。 The present invention relates to an oil adsorbing structure that adsorbs and holds a squeezed broth when cooking ingredients such as seafood, meat, and bread , and a cooking utensil using the same, and prevents oil from splashing in the cooking utensil. In addition, the present invention relates to an oil-absorbing structure that can shorten the baking time and reduce fuel as the thermal efficiency is improved, and can cook cooking utensils and ingredients in a suitable environment, and a cooking utensil using the same .
魚介類や魚を網等で焼いて調理する際に、それらの調理食材から滲み出る焼き汁が調理器具を汚したり、焼き汁が発火して調理器具の損傷や食材が焦げることが原因となって調理に不具合を生じていた。さらに、焼き汁の焦げるニオイが発生して室内にニオイがつく、焼き汁が調理器具にこびりつき、清掃が面倒などから、家庭用調理器具を使う際は特に焼き物調理を毛嫌う調理者が多い。 When cooking seafood and fish on a net, etc., the cooking liquid that exudes from the cooking ingredients may contaminate the cooking utensils, or the burning of the broth may ignite the cooking utensils or burn the cooking ingredients. Had trouble cooking. In addition, there are many cooks who do not like cooking pottery, especially when using home cooking utensils, because the burning odor will cause odors in the room, the roasting will stick to the utensils, and the cleaning will be cumbersome.
このような問題を防止するものとして、家庭用調理器具の魚焼きグリルの焼き汁受け皿の底に敷いて用いるための天然ゼオライトやシリカを原料とする油吸着剤が市販されている。この油吸着剤は1〜5mm程度の粒径で、破砕された角張った形状が主流である。 In order to prevent such a problem, an oil adsorbent made of natural zeolite or silica as a raw material for use on the bottom of a grill saucer of a grilled fish grill of a household cooking appliance is commercially available. This oil adsorbent has a particle size of about 1 to 5 mm, and a crushed square shape is the mainstream.
天然ゼオライトやシリカを原料とする油吸着剤はÅ単位の0.3〜0.6nm細孔径を持ち、細孔容積30〜1000m2/gの比表面積を持つことを特徴とするが、細孔が小さすぎるため、内部の細孔から空気が抜けにくく、標準状態の気圧では水や油が内部まで浸透するまで時間がかかる。An oil adsorbent made from natural zeolite or silica has a pore size of 0.3 to 0.6 nm and a specific surface area of a pore volume of 30 to 1000 m 2 / g. Is too small, it is difficult for air to escape from the internal pores, and it takes time for water and oil to penetrate into the interior at standard atmospheric pressure.
また、天然ゼオライトやシリカに苛性ソーダなどの薬剤や2次加工品による技術も考案されている。 In addition, chemicals such as caustic soda and secondary processed products have been devised.
また、グリルなどの焼き調理器具やバーベキュー調理器は、下部の鉄板から熱が逃げ、熱を外部に放熱しているため、熱効率の良い省エネ構造ではなっていない。
しかし、従来技術の天然ゼオライトは様々な問題点があり、引火事故などを発生させ、一部発売停止となった。天然ゼオライトが引火事故を発生させた原因としては、天然ゼオライト内部に独立した気孔が存在するため水分が抜けにくい、孔の形状が細孔容積0.05〜2.0ml/gに対して比表面積30〜1000m2/gで細孔径0.3〜0.6nmと、孔の形状が細かすぎてしまい吸着物を吸収する速度が遅く、表面に油の皮膜を作り、その油に引火する、といったことが考えられる。However, the natural zeolite of the prior art has various problems, causing a flammable accident and the like, and a part of it has been suspended. The cause of the flammable accident caused by natural zeolite is that moisture is difficult to escape due to the presence of independent pores inside the natural zeolite, and the pore shape has a specific surface area with respect to a pore volume of 0.05 to 2.0 ml / g. The pore diameter is 0.3-0.6 nm at 30-1000 m 2 / g, the pore shape is too fine and the adsorbate is absorbed slowly, an oil film is formed on the surface, and the oil ignites. It is possible.
さらにこの引火のもう一つの原因として、吸水率が乾燥重量比4〜20%ほどと低いことも上げられる。吸水率が低いと少ない使用回数(3〜5回)で油を吸着できなくなり(油が飽和状態)、引火する。使用する際には使用回数を十分気をつける必要がある。ところが、家庭の主婦(調理者)は経済観念から使用回数を規定以上に多く使用するのが一般的であるため、天然ゼオライトの使用は掃除が楽になる代わり、調理器具を危険にする原因となるのである。 Furthermore, another cause of this ignition is that the water absorption is as low as 4 to 20% by dry weight. If the water absorption rate is low, oil cannot be adsorbed (oil is saturated) with a small number of uses (3 to 5 times) and ignites. When using it, it is necessary to be careful about the number of times it is used. However, because housewives (cookers) at home use more times than prescribed from the economic point of view, the use of natural zeolite makes cleaning easier and makes cooking utensils dangerous. It is.
さらに、天然ゼオライトの形状が1〜5ミリの尖った形状であるため、粒の小ささから、調理器具、特にガス機器の吸気孔を塞ぐ原因となり、不完全燃焼を起こしかねない危険な状態となりやすい。尖った形状は刺さると取れにくく、万が一飲み込んでしまった場合、気管や食道、胃を傷つける原因となる。 Furthermore, since the shape of natural zeolite is pointed to 1-5 mm, it becomes a dangerous condition that can cause incomplete combustion due to the small size of the grains, which can cause the intake of cooking utensils, especially gas appliances, to be blocked. Cheap. A sharp shape is difficult to remove when stabbed, and if it is swallowed, it can cause damage to the trachea, esophagus, and stomach.
さらに、薬剤の混合物や天然ゼオライトの2次加工品は、混入の薬剤が一般の消費者にとって危険であり、価格も高価となるため、実際に市場に市販されていない。 Furthermore, the mixture of drugs and the secondary processed product of natural zeolite are not actually marketed because the mixed drugs are dangerous for general consumers and the price is high.
また一方、地球温暖化対策は必至の環境状況となり、調理器具等も熱効率を上げることにより、ガスまたは電気の消費量を削減し、二酸化炭素の排出量を削減する対策がとられている。近年の調理器具は50%近い二酸化炭素排出量削減に成功しているが、調理器具は10年以上使用することから、このような二酸化炭素排出削減タイプの調理器具は全ての家庭及び調理現場に普及していないのが現状である。 On the other hand, global warming countermeasures are inevitable, and measures are taken to reduce gas or electricity consumption and reduce carbon dioxide emissions by increasing the thermal efficiency of cooking utensils and the like. Although cooking utensils in recent years have succeeded in reducing carbon dioxide emissions by nearly 50%, cooking utensils have been used for more than 10 years. The current situation is not widespread.
さらに、自然に親しむことが目的のアウトドアで行うバーベキューでは炭や薪、固形燃料などの燃料を多く使用しているが、バーベキューコンロの多くは金属でできており、燃料の熱が金属から放熱され、熱効率が悪い状態のまま使用されており、燃料の節約は積極的に行われておらず、その対策方法も考案されていない。 In addition, barbecues performed outdoors for the purpose of getting close to nature use a lot of fuel such as charcoal, firewood, and solid fuel, but many of the barbecue stoves are made of metal, and the heat of the fuel is dissipated from the metal. However, it is used in a state of poor thermal efficiency, fuel is not actively saved, and no countermeasures have been devised.
本発明はこのような従来技術上の問題点を解決するためになされたもので、従来の天然ゼオライトよりも粗い細孔を持ち、早い油吸着が可能な無機材を使い、油を素早く内部に吸着させ、表面に浮き上がらせることを防止し、それに伴い安全性を向上させ、使用回数を増やすことにより、引火の危険性がなくなる油吸着構造物及びそれを用いた調理器具を提供することを目的とする。本発明の別の目的は、これによって、従来技術以上の利便性と安全利用が確保でき、さらに熱効率向上により焼き時間も短縮でき、それに伴いガスの費用量も削減できて二酸化炭素排出量の削減に貢献できる油吸着構造物及びそれを用いた調理器具を提供することにある。 The present invention has been made to solve such problems in the prior art, using an inorganic material having coarser pores than conventional natural zeolite and capable of fast oil adsorption, and quickly bringing oil into the interior. adsorbed, prevents to float to the surface, to improve safety along with it, by increasing the number of uses, aims to provide a cooking utensil using oil adsorption structures risk of ignition is eliminated and it And Another object of the present invention is to ensure more convenient and safer use than the prior art, and also to improve the thermal efficiency, shorten the baking time, and accordingly reduce the cost of gas and reduce carbon dioxide emissions. It is to provide an oil adsorbing structure that can contribute to cooking and a cooking utensil using the same .
本発明は、上記の目的を達成するために、連続した多孔質構造を形成した無機材をグリルなどの焼き調理器具内の焼き汁受け皿に敷き詰め、連続した多孔質構造を形成した無機材が魚介類や肉、パンなどの食材を調理する際に、滲み出る焼き汁を油吸着する。滲み出る焼き汁を吸収し、多孔質の空気層による断熱構造で焼き時間や燃料使用量を削減する。 In order to achieve the above-described object, the present invention provides an inorganic material having a continuous porous structure spread on a saucer in a grilled cooking utensil such as a grill, and the inorganic material having a continuous porous structure is a seafood. When cooking foods such as meat, meat, bread, etc., oil adsorbs the exuding broth. Absorbs the soaking broth and reduces the baking time and fuel consumption with a heat insulating structure with a porous air layer.
連続した多孔質構造を形成した無機材は焼き汁を素早く吸着するとともに、調理器具内の油の飛び散りを予防し、熱効率を向上させて焼き時間も短縮でき、調理器具および食材を好適な環境で調理できる。このとき、水を使用するグリルについては、水を使用しない。水を入れることで、連続した多孔質構造を形成した無機材の吸着力が低下し、焼成過程で水蒸気が発生するために、食材の味や質を損なうことになる。 The inorganic material that forms a continuous porous structure quickly adsorbs the broth, prevents splashing of oil in the cooking utensils, improves thermal efficiency and shortens the baking time. I can cook. At this time, water is not used for grills that use water. By adding water, the adsorptive power of the inorganic material having a continuous porous structure is reduced, and water vapor is generated during the baking process, which impairs the taste and quality of the food material.
本発明はIH調理機器やガス調理機器、炭火などの固形燃料を使用するバーベキュー機器など熱源を問わず使用でき、水なしグリルタイプや水ありグリルタイプ、両面焼きグリルタイプ、片面焼きグリル、バーベキュー機器、七輪など違うグリルの形状やタイプ、器具でも使用できる。 The present invention can be used regardless of heat source such as IH cooking equipment, gas cooking equipment, barbecue equipment using solid fuel such as charcoal fire, waterless grill type, water-containing grill type, double-sided grilled type, single-sided grilled grill, barbecue equipment Can be used with different grill shapes, types and utensils.
また、焼き調理器具内の焼き汁受け皿の上にアルミホイルを敷き詰めて連続した多孔質構造を形成した無機材を敷き詰めると、交換時に汚れた連続した多孔質構造を形成した無機材をアルミホイルで包んで廃棄でき、手が汚れず廃棄や清掃が簡単となる。 In addition, if an inorganic material that forms a continuous porous structure is spread by spreading aluminum foil on a saucer in a grilled cooking utensil, the inorganic material that forms a continuous porous structure that is soiled at the time of replacement is covered with aluminum foil. It can be wrapped and discarded, and it is easy to dispose and clean without getting your hands dirty.
本発明は、連続した多孔質構造を形成した無機材は吸水率(乾燥重量比)30〜300%であり、調理器具に敷き詰め使用することを特徴とする。高い吸水率を持つことで、従来品では5回程度の使用回数を約10〜30回に増やすことができる。内部の細孔の形状を粗く大きくすることで、従来技術にくらべてすばやく油が吸着することが可能となり、繰り返し使用することによる表面の油皮膜の発生を抑え、引火の危険性を防止できる。細孔の形状は細孔容積0.2〜3.5ml/g、細孔径の平均が10nm以上、比表面積は0.2〜20m2/gが好ましい。The present invention is characterized in that the inorganic material having a continuous porous structure has a water absorption rate (dry weight ratio) of 30 to 300% and is spread on a cooking utensil. By having a high water absorption rate, it is possible to increase the number of uses of about 5 times to about 10 to 30 times in the conventional product. By roughly increasing the shape of the internal pores, oil can be adsorbed more quickly than in the prior art, and the occurrence of an oil film on the surface due to repeated use can be suppressed, and the risk of ignition can be prevented. The pore shape is preferably a pore volume of 0.2 to 3.5 ml / g, an average pore diameter of 10 nm or more, and a specific surface area of 0.2 to 20 m 2 / g.
また、本発明は粒径を3〜20ミリとすることで、ガス調理機器の吸気孔に詰まり、不完全燃焼を防止できる。粒の形状は角の無い球形、不定形球形及び異形球形、タドン型、楕円形、円柱形などが好ましく、適している。この形状は誤って飲み込んだ場合でも内臓を傷つけず危険性を解消できる。 Moreover, the present invention can prevent the incomplete combustion by clogging the intake holes of the gas cooking appliance by setting the particle diameter to 3 to 20 mm. The shape of the grain is preferably a sphere without a corner, an irregular sphere, a deformed sphere, a tadon type, an ellipse, or a cylinder, and is suitable. This shape can eliminate the danger without damaging the internal organs even if swallowed by mistake.
本発明は網焼きなどが行える調理器具に備え付けてある焼き汁受け皿に、多孔質構造の無機質材を敷き詰め、その上に網を置き、通常の調理作業を行える。使用中に発生する魚介類や肉から滲み出る焼き汁を焼き汁受け皿の中で吸着し、調理器具内の汚れを減らすことで掃除が簡単になる。多孔質構造の無機材は微細な多孔質構造を形成し、吸水率20〜300%と高い性能を持つため、約10〜30回使用しても表面に油が付着する状態に至らないため、焼き汁に含まれる油により引火することが無い。 In the present invention, an inorganic material having a porous structure is laid on a saucer provided in a cooking utensil capable of grilling and the like, and a net is placed thereon to perform a normal cooking operation. Cleaning is easy by adsorbing the broth that exudes from seafood and meat that occurs during use in the broth pan and reducing dirt in the cooking utensils. Since the inorganic material having a porous structure forms a fine porous structure and has a high water absorption rate of 20 to 300%, the oil does not adhere to the surface even when used about 10 to 30 times. There is no ignition by oil contained in the broth.
そこで、本発明と従来品とで使用回数の比較を行った。同機種(リンナイ ガステーブル 水ありグリル)の魚焼きグリルに従来品と発明品を使用し、表面の色が変色するまで繰り返し魚焼きを行い、実験の終了は焼き汁を吸収して色が黒くなった時点とした。色の評価は目視で行った。
また、本発明は連続した多孔質構造を形成した無機材であり、細孔の形状が孔容積0.2〜3.5ml/g、細孔径の平均が10nm以上、比表面積が0.2〜20m2/gの特徴を持ちながら、一軸圧縮強度1.0MN/m2以上の強度を持つ油吸着構造をもつ。その空気層が断熱と蓄熱となり、上部からの熱が表面に蓄熱され、グリルなどの焼き調理器具では焼き時間を約10〜30%短縮し、炭や練炭、薪などを燃料とするバーベキューなどの焼き調理器具では炭の温度が200度以下となるのに約1.5〜5倍の焼き時間を可能とする。Further, the present invention is an inorganic material having a continuous porous structure, the pore shape is a pore volume of 0.2 to 3.5 ml / g, the average pore diameter is 10 nm or more, and the specific surface area is 0.2 to It has an oil adsorbing structure having a uniaxial compressive strength of 1.0 MN / m 2 or more while having a characteristic of 20 m 2 / g. The air layer becomes heat insulation and heat storage, heat from the upper part is stored on the surface, and grilling utensils such as grills shorten baking time by about 10-30%, such as barbecue using charcoal, briquettes, firewood, etc. as fuel With a baked cooking appliance, the baking time of about 1.5 to 5 times is possible even when the temperature of the charcoal is 200 degrees or less.
そこで、1〜3回目の製造品で地盤工学会基準 岩石の点載荷試験(JGS 3421-2005)による強度試験を行った。試験体の形状は不定形な球状である。 Therefore, the first to third manufactured products were subjected to a strength test by the Geotechnical Society standard rock point loading test (JGS 3421-2005). The shape of the test body is an irregular spherical shape.
計算式を次に示す。
また、多孔質構造の無機質材の高い吸水率は、油が飽和状態まで吸着されない限り空洞を保ち、この空洞が断熱効果を持ち、焼成体(魚介類や肉など)の内部温度が早く上がり、焼き時間を短縮できる。この焼き時間の短縮はガスの消費量を削減することとなり、したがって二酸化炭素の排出量を削減できることとなる。また、連続した多孔質構造を形成した無機材は粒径を3〜20ミリとすることで、グリルなどの調理器具内の吸気孔における詰まり、不完全燃焼の防止と、バーベキュー等の調理器具の吸気孔を塞ぐ設置をしても空気の流入を阻害せずに鎮火防止可能となる。 In addition, the high water absorption rate of the porous inorganic material keeps the cavity as long as the oil is not adsorbed to saturation, this cavity has a heat insulating effect, the internal temperature of the fired body (such as seafood and meat) rises quickly, The baking time can be shortened. This shortening of the baking time reduces the consumption of gas, and therefore the emission of carbon dioxide can be reduced. In addition, the inorganic material forming a continuous porous structure has a particle size of 3 to 20 mm, which prevents clogging and incomplete combustion in the intake holes in cooking utensils such as grills, and prevents cooking utensils such as barbecues. Even if the air intake hole is closed, the fire can be prevented without inhibiting the inflow of air.
また、焼き汁受け皿の上にアルミホイルを敷き詰めると、捨てるときに包んで捨てられ、焼き汁受け皿も汚れなく、掃除が簡易となる。 Also, if an aluminum foil is spread on the saucer, it will be wrapped and thrown away when it is discarded, and the saucer will not be soiled and cleaning will be easier.
本発明の連続した多孔質構造の無機質材は、連続した多孔質構造を持つ油吸着機能を持ち、吸水率20〜300%の特徴のセラミックス質が好ましい。連続した多孔質構造の無機質材は、火山岩、人工ゼオライト、軽量骨材、パーライト、珪藻土、吸水性セラミックス、低温焼成のレンガ、発泡ガラス、発砲スラグ、水砕スラグ、セルベン、シャモット、耐火レンガなどでも良く、製紙産業廃棄物及び製紙産業廃棄物焼却灰、下水スラッジ及び下水スラッジ焼却灰、浄水発生土(浄水スラッジ)及び浄水発生土焼却灰(浄水スラッジ焼却灰)、フライアッシュ、コークス灰、高炉スラグ、スラグ、溶融スラグ、電気溶融スラグ、発砲スラグ、発砲ガラス、珪藻土、粘土、シャモット、セルベン、頁岩、モンモリナイト、カオリナイト、ベントナイト、クロボク、シロボク、セメント、石灰などを原料とし、この中の1種類で構成されても良く、数種類を混合して得られるものでも良い。この原料を使用しても、粘性が得られず成型が困難な場合はバインダーを混入してもより。バインダーは限定するものではないが、澱粉のり、コーンスターチ、小麦粉、水ガラス(珪酸ソーダ)、アクリルエマルジョン、ポパール、エポキシ樹脂、シリコン樹脂、ウレタン樹脂、ふのりなどでも良い。最も好ましい連続した多孔質構造の無機質材は、製紙産業廃棄物及び製紙産業廃棄物焼却灰や浄水発生土(浄水スラッジ)及び浄水発生土焼却灰(浄水スラッジ焼却灰)、ベントナイトを1種類もしくは2種類以上を混合し、焼成して得られるものであり、原料の価格が安価なことと加工性の良さ、重金属等の溶出の危険性が少ないことにある。 The inorganic material having a continuous porous structure according to the present invention is preferably a ceramic material having an oil adsorption function having a continuous porous structure and a water absorption rate of 20 to 300%. Inorganic materials with continuous porous structure include volcanic rocks, artificial zeolite, lightweight aggregates, perlite, diatomaceous earth, water-absorbing ceramics, low-temperature fired bricks, foamed glass, foamed slag, granulated slag, cerven, chamotte, refractory bricks, etc. Well, paper industry waste and paper industry waste incineration ash, sewage sludge and sewage sludge incineration ash, purified water generation soil (purified water sludge) and purified water generation soil incineration ash (purified water sludge incineration ash), fly ash, coke ash, blast furnace slag Slag, molten slag, electric molten slag, foamed slag, foamed glass, diatomaceous earth, clay, chamotte, selben, shale, montmorillonite, kaolinite, bentonite, kuroboku, shiroboku, cement, lime, etc., one of these Or may be obtained by mixing several types. Even if this raw material is used, if viscosity is not obtained and molding is difficult, it is better to mix a binder. The binder is not limited, but may be starch paste, corn starch, wheat flour, water glass (sodium silicate), acrylic emulsion, popal, epoxy resin, silicone resin, urethane resin, furan or the like. The most preferable inorganic material having a continuous porous structure is one or two kinds of paper industry waste and paper industry waste incineration ash, purified water generation soil (purified water sludge), purified water generation soil incineration ash (purified water sludge incineration ash), bentonite It is obtained by mixing and firing more than one kind, and is that the price of the raw material is low, the workability is good, and the risk of elution of heavy metals is low.
粒の形状は角の無い球形、不定形球形及び異形球形、タドン型、楕円形、円柱形状などが適しており、その形状を得るためにはペレットや押し出し成型、プレス成型、ブリケット成型、ロールプレス成型、パンペレット成型などで得られ、加工手間やコストから適当な成型方法を用いるのが好適である。 The shape of the grains is suitable for spheres without corners, irregular spheres, irregular spheres, tadons, ovals, and cylinders. To obtain these shapes, pellets, extrusion molding, press molding, briquette molding, roll press It can be obtained by molding, bread pellet molding, or the like, and it is preferable to use an appropriate molding method from processing effort and cost.
本発明に係る油吸着構造はさらに、グリルなど焼き調理器具や炭などの燃料を使用するバーベキューなどの調理器具内の焼き汁受け皿や炭置きに設置し、魚介類や肉、パンなどの食材を調理する際に染み出る焼き汁や熱の効率を上げる構造が、連続した多孔質構造を形成した無機材によって構成される。 The oil adsorbing structure according to the present invention is further installed in a grill saucer or charcoal holder in a cooking appliance such as a barbecue or the like using a fuel such as a grill or a grill, etc., and a food such as seafood, meat, bread, etc. The broth that exudes when cooking and the structure that increases the efficiency of heat are composed of an inorganic material that forms a continuous porous structure.
本発明によれば、本発明の効果は、連続した多孔質構造を形成した無機材は焼き汁を素早く吸着するとともに、調理器具内の油の飛び散りを予防し、熱効率を向上させて焼き時間も短縮でき、調理器具および食材を好適な環境で調理できる。使用中に発生する魚介類や肉から滲み出る焼き汁を焼き汁受け皿の中で吸着し、調理器具内の汚れを減らすことで掃除が簡単になる。多孔質構造の無機材は微細な多孔質構造を形成し、吸水率20〜300%と高い性能を持つため、約10〜30回使用しても表面に油が付着する状態に至らなく、細孔も従来技術よりも粗く大きいことから焼き汁と素早く内部に吸収できるため、焼き汁に含まれる油により引火することが無い。 According to the present invention, the effect of the present invention is that the inorganic material having a continuous porous structure quickly adsorbs the broth, prevents the oil from splashing in the cooking utensil, improves the thermal efficiency, and shortens the baking time. The cooking utensils and ingredients can be cooked in a suitable environment. Cleaning is easy by adsorbing the broth that exudes from seafood and meat that occurs during use in the broth pan and reducing dirt in the cooking utensils. A porous inorganic material forms a fine porous structure and has a high water absorption rate of 20 to 300%. Therefore, even if it is used about 10 to 30 times, it does not reach the state where oil adheres to the surface. Since the hole is coarser and larger than the prior art, it can be quickly absorbed into the broth and therefore is not ignited by the oil contained in the broth.
本発明の多孔質構造の無機質材の高い細孔容積が、油が飽和状態まで吸着されない限り空洞を保ち、この空洞が断熱効果を持ち、焼成体(魚介類や肉など)の内部温度が早く上がり、焼き時間の短縮や炭など固形燃料の削減ができる。この焼き時間の短縮はガスの消費量を削減することとなり、したがって二酸化炭素の排出量を削減できる効果がある。炭などの固形燃料の使用量の削減は、森林などの天然資源の枯渇防止に貢献する。 The high pore volume of the porous inorganic material of the present invention keeps the cavity unless the oil is adsorbed to saturation, this cavity has a heat insulating effect, and the internal temperature of the fired body (such as seafood and meat) is fast. It can reduce the burning time and solid fuel such as charcoal. This shortening of the baking time reduces the amount of gas consumption, and therefore has the effect of reducing the amount of carbon dioxide emissions. Reduction of the use of solid fuel such as charcoal will contribute to prevention of depletion of natural resources such as forests.
また、本発明は粒径を3〜20ミリとすることで、ガス調理機器の吸気孔に詰まり、不完全燃焼を防止できる。粒の形状は角の無い球形、不定形球形及び異形球形、タドン型、楕円形などが好ましく、適している。この形状は誤って飲み込んだ場合でも内臓を傷つけず危険性を解消できる。
また、本発明は細孔容積が高く連続した多孔質構造を持つと強度が低くなるが、一軸圧縮強度1.0MN/m2以上の強度を持ち、輸送可能な強度を保つ。Moreover, the present invention can prevent the incomplete combustion by clogging the intake holes of the gas cooking appliance by setting the particle diameter to 3 to 20 mm. The shape of the grain is preferably a spherical shape with no corners, an irregular sphere shape, an irregular sphere shape, a tadon shape, an oval shape, or the like. This shape can eliminate the danger without damaging the internal organs even if swallowed by mistake.
In addition, the present invention has a continuous pore structure with a high pore volume, but the strength decreases. However, the uniaxial compressive strength is 1.0 MN / m 2 or more, and the transportable strength is maintained.
以下により、焼き時間の短縮率を検証した。これはひとつの評価方法であり、評価はこれに限定されるものではない。 The shortening rate of baking time was verified by the following. This is one evaluation method, and the evaluation is not limited to this.
(実験例 1)
1.グリルの使用の効果検証
グリルの中に試作した保水性セラミックスを入れ、熱効率がどのぐらい向上するか検証試験を行った。(Experiment 1)
1. Effect verification of the use of the grill The prototype water-retaining ceramic was put in the grill and a verification test was conducted to see how much the thermal efficiency was improved.
2.実験概要
(1)供試体
本実験では、グリル内で市販のかまぼこを焼きその内部の温度を計測する。かまぼこを採用したのは、中身がほぼ均一であり、また適度な硬さがあるので温度計測のためのセンサーを内部に設置しやすいことによる。本実験で利用したかまぼこについて下記に示す。2. Outline of Experiment (1) Specimen In this experiment, a commercially available kamaboko is baked in the grill and the temperature inside it is measured. Kamaboko was adopted because the contents are almost uniform and the hardness is appropriate, so it is easy to install a sensor for temperature measurement inside. The kamaboko used in this experiment is shown below.
(2)実験装置
本実験で用いた装置について図3に示す。(2) Experimental apparatus The apparatus used in this experiment is shown in FIG.
図3は、実験装置を示す写真図である。図中の番号は以下を指標する。
1ガスコンロ
2熱伝対(T−H−0.65,東京測器研究所)
温度を計測する熱伝対は2種の異なる金属線を接続し、その両方の接点に温度差を与えると熱起電力が生じる原理(ゼーベック効果)を利用した温度計である。
3データロガー(TDS‐303,東京測器研究所)
熱伝対からの信号を記録。
4パソコン
データを保存
5 熱伝対固定治具
かまぼこ内部の温度を計測する際、常に同じ箇所で計測する必要がある。そこで図4A、B(熱伝対固定治具の様子、熱伝対固定治具図)のような治具を作成し、計測点である熱伝対の先端がかまぼこ内で常に同じ位置に来るようにした。FIG. 3 is a photograph showing the experimental apparatus. The numbers in the figure indicate the following:
1
A thermocouple that measures temperature is a thermometer that uses the principle (Seebeck effect) that thermoelectric power is generated when two different metal wires are connected and a temperature difference is applied to both of the contact points.
3 data logger (TDS-303, Tokyo Sokki Kenkyujo)
Records signals from thermocouples.
4 Save
図4A及びBに示すようにφ5mmのアルミパイプを3本等間隔となるように固定する。アルミパイプ内に熱伝対を通し、先端部でパイプ穴を閉塞して熱伝対を固定する。このパイプ群をかまぼこの中心の位置で、真横から所定の位置まで(先端より25
mm)挿入させる(図5:熱伝対の設置)。このようにして毎回熱伝対が同じ位置にくるよう、設置した。As shown in FIGS. 4A and 4B, three φ5 mm aluminum pipes are fixed at equal intervals. Pass the thermocouple through the aluminum pipe and close the pipe hole at the tip to fix the thermocouple. This pipe group is located at the center of the kamaboko from right side to a predetermined position (25 from the tip).
mm) is inserted (FIG. 5: installation of a thermocouple). Thus, it installed so that a thermocouple might be in the same position every time.
(2)測定項目
測定項目はかまぼこ内温度、グリル内気中温度、燃焼開始からの経過時間である。なお、10秒ごとに計測を行う。
*かまぼこ内温度測定箇所
図6A、Bに示すように、供試体中の1、2、3の3箇所の温度変化を測定する。
*グリル内気中温度
図7:気中温度測定位置に示すように、グリル内気中の温度を計測する。
トーストなど、内部に空気を含むものの外側をパリッ、内側をふわっと仕上げるには、ガスの強火でサクサクッと焼く方法が合っている
(http://www.nikkeibp.co.jp/ecomom/column/ep_067.html
参照)。(2) Measurement items The measurement items are the temperature inside the kamaboko, the temperature inside the grill, and the elapsed time from the start of combustion. Measurement is performed every 10 seconds.
* Kamaboko internal temperature measurement location As shown in FIGS. 6A and 6B, the temperature change at three
* Grill air temperature As shown in Fig. 7: Air temperature measurement position, the temperature in the air inside the grill is measured.
To finish the inside of a toast or other item that contains air inside with a crisp outer side, the method of baking with a strong gas fire is suitable (http://www.nikkeibp.co.jp/ecomom/column/ep_067) .html
reference).
これは,グリル内の気中温度と関連することから、かまぼこ燃焼実験中のグリル内の温度についても検討を行う。なお、図7に示すように、ここでの計測位置はグリルの端部になっている。そこで、別途Case−3実験にて、グリル内中心位置での気中温度について検討を行う。 Since this is related to the air temperature in the grill, the temperature in the grill during the kamaboko combustion experiment is also examined. As shown in FIG. 7, the measurement position here is the end of the grill. Therefore, the air temperature at the center position in the grill is examined separately in Case-3 experiment.
(4)実験手順
本実験の手順を以下に示す。
(4−1)グリルの受け皿に水(400g)、もしくは本発明品(400g)を敷き詰める(図8)。
(4−2)かまぼこに温度計測装置を設置し、グリルの網の中心部に来るよう設置する(図9、10)。
(4−3)供試体の測定位置(4−2)の温度が15
℃になったら,火を着け,計測を始める(計測時間20 分)。(4) Experimental procedure The procedure of this experiment is shown below.
(4-1) Water (400 g) or the product of the present invention (400 g) is spread on the saucer of the grill (FIG. 8).
(4-2) Install a temperature measuring device on the kamaboko so that it comes to the center of the grill net (FIGS. 9 and 10).
(4-3) The temperature at the measurement position (4-2) of the specimen is 15
When it reaches ℃, set fire and start measurement (
かまぼこは実験直前まで冷蔵庫中に保管しており内部の温度は10℃以下であるが、取り出して計測準備完了までの間にいくらか温度が上昇する。そこで燃焼開始時の温度を常に一定にするため,測定位置(4−2)の温度が15℃になるのを確認して加熱しはじめる。 Kamaboko is stored in the refrigerator until immediately before the experiment, and the internal temperature is 10 ° C. or lower, but the temperature rises somewhat until it is taken out and ready for measurement. Therefore, in order to keep the temperature at the start of combustion always constant, heating is started after confirming that the temperature at the measurement position (4-2) is 15 ° C.
また火力は、常に調整レバーの右端の位置で固定し弱火とした(図11)。 The heating power was always fixed at the right end position of the adjustment lever to reduce the heat (FIG. 11).
3. Case−1実験の結果と考察
Case−1実験での温度計測箇所はかまぼこ内3箇所と、グリル内の気中1箇所の計4箇所である。各箇所での燃焼時間と温度変化の様子を、本発明品を使用したときと、水の場合で比較検討する。3. Results and Discussion of Case-1 Experiment Temperature measurement locations in Case-1 experiment are 4 locations in total, 3 locations in kamaboko and 1 location in the air in the grill. The combustion time and temperature changes at each location will be compared when using the product of the present invention and when using water.
(1)計測箇所1の結果
a) 温度時間関係
図12(温度時間関係(計測箇所1))に計測箇所1の温度と燃焼時間の関係を示す。実験は2回ずつ実施しており、全ての結果を示している。図12より2回ともほぼ同じ挙動を示しており、再現性が確認される。また、本発明品を使用したときは、水を使用した時に比べて、温度の上昇が早い。(1) Result of
a) Temperature time relationship FIG. 12 (temperature time relationship (measurement location 1)) shows the relationship between the temperature of
次に40、 50、60、70、 80、90 ℃に達する時間を、本発明品使用時と水使用時の両者で比較する(表3)。水使用時には燃焼時間20分以内に90
℃には達しなかった。各ケースに対して2回ずつ実験を行っているので、その両方のデータ(データ1,データ2)を示す。なお、以下、表及び図において、「グリル革命」と称されるものは本発明の一態様を実現した品である。Next, the time to reach 40, 50, 60, 70, 80, and 90 ° C. is compared both when using the product of the present invention and when using water (Table 3). 90 minutes within 20 minutes when using water
It did not reach ℃. Since the experiment is performed twice for each case, both data (
b) 燃焼時間短縮率
表3より本発明品を使用したときには水の場合よりも、ある温度への到達時間が短縮されることがわかった。そこで、各温度で数式(1)のように燃焼時間短縮率を算出し、本発明品の効果を定量的に評価する。b) Combustion time shortening rate From Table 3, it was found that when the product of the present invention was used, the time to reach a certain temperature was shortened compared to the case of water. Therefore, the burning time reduction rate is calculated at each temperature as shown in Formula (1), and the effect of the product of the present invention is quantitatively evaluated.
なお、表3中で、水使用時に得られた2つのデータのうち、各温度への到達時間が早い方のデータ1と、本発明品使用時に得られた2つのデータのうち、各温度への到達時間が遅い方のデータ2とで、短縮率を算出する。つまり、本発明品にとって最も不利なデータの組合せで検討する。
In Table 3, among the two data obtained at the time of using the water, the
このようにして算出された燃焼時間短縮率を表4に示す。また図13(本発明品による燃焼時間短縮率(計測箇所1))では短縮率を縦軸に、比較温度を横軸にとり表示する。 Table 4 shows the combustion time reduction rate calculated in this way. In FIG. 13 (combustion time reduction rate (measurement location 1) according to the present invention), the reduction rate is displayed on the vertical axis and the comparative temperature is displayed on the horizontal axis.
図13から、温度が高いほど、燃焼時間短縮率が大きくなり本発明品による効果が高いことがわかる。 From FIG. 13, it can be seen that the higher the temperature, the greater the combustion time reduction rate and the higher the effect of the product of the present invention.
ここで、「動物性の食品は内部温度が75 ℃から80 ℃止まりになるときが焼き上がった状態である(http://yakitori.co.jp/knowledge/tec/yaki/index.html
参照)ことから、70 ℃、80 ℃に到達する時間の短縮率に着目する。図13より、動物性のもの(焼鳥や魚など)を焼くとき、時間を約15 %短縮できることが分かる。Here, “animal food is in a state of being baked when the internal temperature stops at 75 ° C. to 80 ° C. (http://yakitori.co.jp/knowledge/tec/yaki/index.html
Therefore, attention is paid to the shortening rate of the time to reach 70 ° C. and 80 ° C. From FIG. 13, it can be seen that the time can be reduced by about 15% when animal things (yakitori, fish, etc.) are baked.
(2)計測箇所2の結果
a) 温度時間関係
計測箇所1と同様に、計測箇所2での実験結果を整理する。図14に計測箇所2における、温度と燃焼時間の関係を示し、表5では40、50、60、70、80、90
℃に到達する時間を、本発明品使用時と水使用時の両者で比較する。図14、表5から、本発明品を使用時は、水の場合に比べて、温度の上昇が早いことが分かる。(2) Result of
a) Organize the experimental results at
The time to reach ° C. is compared both when using the product of the present invention and when using water. From FIG. 14 and Table 5, it can be seen that when the product of the present invention is used, the temperature rises faster than in the case of water.
計測箇所1での時と同様に、燃焼時間短縮率を算出する。表5中、水使用時のデータ1と本発明品使用時のデータ2により算出した。短縮率を表6、図15(本発明品による燃焼時間短縮率(計測箇所2))に示す。
℃での短縮率から約15 %短縮できるといえる。
It can be said that the shortening rate at ℃ can be reduced by about 15%.
(3)計測箇所3の結果
a) 温度時間関係
計測箇所1、2と同様に図16(温度時間関係(計測箇所3))に計測箇所3における、温度と燃焼時間の関係を示し、表7では40、50、60、70、80、90 ℃に達する時間を、本発明品使用時と水使用時の両者で比較する。図16、表7から、本発明品を使用時は、水の場合に比べて、温度の上昇が早いことが分かる。(3) Result of
a) Similar to the
計測箇所1,2での時と同様に、本発明品の効果を定量的に把握するため、燃焼時間短縮率を算出する。表7中、水使用時のデータ1と本発明品使用時のデータ2により算出した。短縮率を表8、図17(本発明品による燃焼時間短縮率(計測箇所3))に示す。
℃、80 ℃での短縮率から約20 %短縮できるといえる。
It can be said that it can be shortened by about 20% from the shortening rate at 80 ° C.
(4)気中温度の計測結果
a) 温度時間関係
図18(温度時間関係(気中))にグリル内気中における、温度と燃焼時間の関係を示す。気中においては、急激に約60
℃まで温度上昇し、本発明品使用時と水の場合で両者に大きな差は見られなかった。そこで表9では80、90、100、110、120、130 ℃に達する時間を、本発明品使用時と水使用時の両者で比較する。図18、表9から、本発明品を使用時は、水の場合に比べて、温度の上昇が早いことが分かる。(4) Air temperature measurement results
a) Temperature time relationship FIG. 18 (temperature time relationship (in air)) shows the relationship between temperature and combustion time in the air in the grill. In the air, about 60
The temperature rose to 0 ° C., and no significant difference was observed between the use of the product of the present invention and the case of water. Therefore, in Table 9, the time to reach 80, 90, 100, 110, 120, and 130 ° C. is compared both when using the product of the present invention and when using water. From FIG. 18 and Table 9, it can be seen that when the product of the present invention is used, the temperature rises faster than in the case of water.
本発明品の効果を定量的に把握するため、燃焼時間短縮率を算出する。表9中、水使用時のデータ1と本発明品使用時のデータ2により算出した。短縮率を表10、図19(本発明品による燃焼時間短縮率(気中))に示す。
1.1.1.1計測箇所と本発明品の効果
かまぼこ内3箇所の燃焼時間短縮率を表11、図20(本発明品による燃焼時間短縮率(かまぼこ内))にまとめる。1.1.1.1 Effect of measurement location and effect of the product of the present invention Combustion time shortening rates at three locations in the kamaboko are summarized in Table 11 and FIG. 20 (burning time shortening rate by the product of the present invention (kamaboko)).
1.1.1.2Case−1実験の結果のまとめ
以上からかまぼこ内3箇所、グリル内気中1箇所の温度は、本発明品を使用することにより、ある温度の到達する時間を水使用時に比べて大幅に短縮できることが分かる。このことから、実際に調理時に本発明品を使用することによって、ガスを利用する調理時間が短縮されガス消費量を削減することができると考えられる。1.1.1.2 Summary of Case-1 Experiment Results From the above, the temperature at three locations in the kamaboko and one location in the air inside the grill is compared to the time it takes to reach a certain temperature by using the product of the present invention. It can be seen that it can be greatly shortened. From this fact, it is considered that cooking time using gas can be shortened and gas consumption can be reduced by actually using the product of the present invention during cooking.
尚、本発明は上述した実施形態に限定されるものではなく、本発明の主旨を逸脱しない範囲内で種々変更して実施することが可能である。 Note that the present invention is not limited to the above-described embodiment, and various modifications can be made without departing from the spirit of the present invention.
さらにまた、上述したものは本願に係る技術思想を具現化するための実施形態の一例を示したにすぎないものであり、他の実施形態でも本願に係る技術思想を適用することが可能である。 Furthermore, what has been described above is merely an example of an embodiment for embodying the technical idea of the present application, and the technical idea of the present application can be applied to other embodiments. .
また、本願発明を用いて生産される装置、方法、システムが、その2次的生産品に登載されて商品化された場合であっても、本願発明の価値は何ら減ずるものではない。 Moreover, even if the apparatus, method, and system produced by using the present invention are listed and commercialized as a secondary product, the value of the present invention is not reduced at all.
アウトドアとして用いられている、炭火を熱源としたバ−ベキューコンロにおいて、本発明を温度保持媒体材として用いる場合と、そうでない場合とのコンロ内における温度持続時間に関する比較を行った。そして、少ない炭火熱源での熱量の持続により、実際の焼き肉成果と効果を確認する。 In a barbecue stove using charcoal fire as a heat source used outdoors, a comparison was made regarding the temperature duration in the stove when the present invention was used as a temperature maintaining medium material and when it was not. And the actual roasted meat results and effects are confirmed by sustaining the amount of heat in a small charcoal heat source.
市販の加工備長炭を熱源として使用するバーベキューコンロを2つ用意し、一方には一般的に使用法と同様に炭のみをコンロ本体内部に配置し、他方にはコンロ本体内部に熱源である炭及び温度保持媒体として本発明品を配置する。
ここで使用する加工備長炭はおがくずに圧縮加工を施したものであり、角柱状で本体表面に1つまたは複数の穴を有するものである。また、ここで使用する本発明品として、Ps(ペーパースラッジ)焼却灰を加工した造粒焼成物を用いる。Prepare two barbecue stoves that use commercial processed Bincho charcoal as a heat source, and generally place only charcoal inside the stove body in the same way as the usage, and the other is charcoal that is the heat source inside the stove body The product of the present invention is placed as a temperature holding medium.
The processed Bincho charcoal used here is compression-processed sawdust, is a prismatic shape, and has one or more holes on the surface of the main body. Moreover, the granulated baked material which processed Ps (paper sludge) incineration ash is used as this invention product used here.
また、実験計測装置として、温度測定にKタイプの熱電対である温度センサ、及びデータ計測にはデータロガを使用する。 As an experimental measurement device, a temperature sensor that is a K-type thermocouple is used for temperature measurement, and a data logger is used for data measurement.
さらに、加工備長炭からコンロ上部網までの高さを5cmに調整し、加工備長炭の使用数15個を100%として、75%、50%、25%の4種類についてデータ計測を行う。図21、図22共に同一の符号は同一の対象を示す。さらに、図21に示す1は温度センサ、2は加工備長炭、3は灰、4は本発明品を表す。加工備長炭の点火時から火の鎮火、室温に戻るまでを10分毎に温度計測を行う。加工備長炭のみを使用する場合と本発明を温度保持媒体として使用する場合の各炭火燃焼温度持続実験計測の結果を表12、表13に示した。そして、本発明品を利用し、かつ加工備長炭を50%に減じたときのデ−タを表14に示した。
表12、13より、明らかに本発明品を利用した方が燃焼温度の上昇と持続時間が延びる現象が見られ熱持続効果が判明した。炭火下の温度差では約200℃、温度持続時間で200℃下で250分〜1100分と炭のみに比べ約4倍の保温効果があった。 From Tables 12 and 13, it was apparent that the use of the product of the present invention showed an increase in combustion temperature and a prolonged duration, and the heat sustaining effect was found. The temperature difference under the charcoal fire was about 200 ° C., and the temperature duration was 200 ° C. at 250 minutes to 1100 minutes.
表14より、炭量(炭火)を50%に半減させた場合、炭火下の温度200℃の持続は340分、コンロ網面(炭火から約5cm)での200℃時の、炭のみで150分、エコトク利用時(炭火100%)で200分、炭火50%でも110分を記録し約2時間の熱量持続効果が見られた。 From Table 14, when the amount of charcoal (charcoal fire) is halved to 50%, the temperature of 200 ° C under the charcoal fire lasts for 340 minutes, 150% with charcoal only at 200 ° C on the stove mesh surface (about 5 cm from charcoal fire). 200 minutes when using Ecotok (100% charcoal fire) and 110 minutes even when 50% charcoal fire was recorded.
つぎに、本発明(「エコトク」とも指標する。)利用条件で炭量(炭火)を変化とコンロ上部網面の温度を表15に示した。
表15より、従来技術では炭量が多いほど燃焼温度持続時間が長いと考えられるが、コンロ網面温度200℃時点で炭量100%、75%、50%の場合ともに持続時間は220分とほぼ同時間を保持していた。コンロ網面温度100℃時点では炭量100%で700分(約11時間)、炭量75%で560分(約9時間)、炭量50%では320分(約5時間)持続していることが判明した。 From Table 15, it can be considered that the combustion temperature duration is longer as the amount of coal is larger in the conventional technology, but the duration is 220 minutes in the case of the amount of coal of 100%, 75% and 50% at the stove mesh surface temperature of 200 ° C. I kept almost the same time. When the stove mesh surface temperature is 100 ° C, it lasts for 700 minutes (about 11 hours) with 100% carbon, 560 minutes (about 9 hours) with 75%, and 320 minutes (about 5 hours) with 50%. It has been found.
バ−ベキュコンロで本発明品を利用し、炭量(炭火)70%のもとで実際焼肉を焼いて実証実験を行った結果の全体温度状況を表16に、焼き肉時の詳細温度状況について表17に示した。
表17より、炭火70%で開始して焼きもの時間区間を2回行い、その間焼き肉等の焼き物を温度センサ−に差し込み1個ずつ計測した。そして45分後に炭火を2割減(47%)にした後再び先ほどと同様な形式で焼もの時間区間を1回行った。その結果、コンロ上部網面の温度130℃〜180℃間で温度推移している間で、焼き物を焼いた内部温度はカマボコ、焼き鳥胸肉等にかかわらず、約5分〜10分程度で焼き上がることが判明し焼き物内部の温度は75℃〜90℃近くであることも判明した。全体に比較的短時間で焼き物が焼き上がり、香ばしく焼き上がっていた。 From Table 17, the grilling time section was started twice starting at 70% charcoal fire, and during that time, grilled meat such as grilled meat was inserted into the temperature sensor and measured one by one. After 45 minutes, the charcoal fire was reduced by 20% (47%), and then the baking time section was once again performed in the same manner as before. As a result, while the temperature of the upper surface of the stove is changing between 130 ° C and 180 ° C, the internal temperature at which the baked goods were baked was baked in about 5 minutes to 10 minutes regardless of the sea bream, grilled chicken breasts, etc. It was also found that the temperature inside the pottery was 75 ° C to 90 ° C. The pottery was baked in a relatively short time, and baked fragrantly.
炭火70%で開始45分後に炭火をさらに2割減じてもコンロ網面の温度が130℃を維持しており、炭火50%時点で約75分間可能(表16参照)と判明した。したがって、炭火のみでバ−ベキュより本発明品を利用することで、炭量が3割から4割強まで減量でき炭火燃料に対する経済効果が確認できた。 Even if the charcoal fire was reduced by 20% after the start of 70% at the charcoal fire, the temperature of the stove net was maintained at 130 ° C., and it was found that it was possible for approximately 75 min at the 50% charcoal fire (see Table 16). Therefore, by using the product of the present invention from Barbecue only by charcoal, the charcoal amount can be reduced from 30% to over 40%, and the economic effect on the charcoal fuel was confirmed.
本発明によれば、本発明の多孔質構造の無機質材の高い吸水率が、油が飽和状態まで吸着されない限り空洞を保ち、この空洞が断熱効果を持ち、焼成体(魚介類や肉など)の内部温度が早く上がり、焼き時間を短縮できる。この焼き時間の短縮はガスの消費量を削減することとなり、したがって二酸化炭素の排出量を削減できる効果があるから、施設、ホテル、事務所等キッチンを必要とするあらゆる空間・機会に有用性を発揮することとなり、各種産業に非常な有益性をもたらすものである。 According to the present invention, the high water absorption rate of the inorganic material having a porous structure of the present invention maintains a cavity unless the oil is adsorbed to a saturated state, and this cavity has a heat insulating effect, and a fired body (such as seafood and meat) The internal temperature rises quickly and baking time can be shortened. This shortening of the baking time reduces the gas consumption, and therefore has the effect of reducing carbon dioxide emissions. Therefore, it is useful for any space / opportunity that requires kitchens such as facilities, hotels, and offices. It will be demonstrated and will bring great benefits to various industries.
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