JP5230914B2 - Seasoning composition for food and food containing the same - Google Patents

Seasoning composition for food and food containing the same Download PDF

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JP5230914B2
JP5230914B2 JP2006190619A JP2006190619A JP5230914B2 JP 5230914 B2 JP5230914 B2 JP 5230914B2 JP 2006190619 A JP2006190619 A JP 2006190619A JP 2006190619 A JP2006190619 A JP 2006190619A JP 5230914 B2 JP5230914 B2 JP 5230914B2
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浩一 大村
健太郎 古部
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エーザイフード・ケミカル株式会社
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本発明は、ソーセージ等の食肉加工食品に好適な食品用調味料組成物、及びこれを含む食品に関する。   The present invention relates to a seasoning composition for food suitable for processed meat foods such as sausages, and a food containing the same.

近年、食生活の多様化が進み、調理済食品や半調理済食品の需要が大きくなってきている。一般に、これらの食品は、食品工場で調理された後に加工食品として、スーパーマーケットやコンビニエンスストア、小売店等の店内で陳列されて販売され、また、レストランや持ち帰り加工食品チェーン等の外食産業において2次加工されたりして販売されている。これらの加工食品は、製造後直ちに食されるのではなく、製品出荷、陳列、持ち帰り等の流通過程を経て一定時間後に初めて食されることが多いため、保存性に優れていることが求められ、従来より、この保存性を確保するための食品日持向上剤が研究されてきた。
一方、加工食品は、前記保存性のみならず、風味、食感等にも優れていることが求められている。これらの風味、食感等とは、外観(色調、色、艶等)、温度等と共に、食品の所謂「おいしさ」を構成する、味、香り、硬さ、弾力等を意味し、これらを向上するために、味質改善剤や弾力増強剤を始めとする種々の風味向上剤や食感改良剤も研究されてきている。
In recent years, the diversification of eating habits has led to an increasing demand for cooked and semi-cooked foods. In general, these foods are cooked at food factories and then processed and sold as processed foods in supermarkets, convenience stores, retail stores, etc., and in the food service industry such as restaurants and take-out processed food chains. It is sold after being processed. These processed foods are not eaten immediately after production, but are often eaten for the first time after a certain period of time through distribution processes such as product shipment, display, take-out, etc. In the past, food longevity improvers have been studied to ensure this preservability.
On the other hand, processed foods are required to be excellent not only in the above-described storage stability but also in flavor, texture and the like. These flavors, textures, etc. mean the appearance (color tone, color, gloss, etc.), temperature, etc., together with the taste, aroma, hardness, elasticity, etc. that make up the so-called “deliciousness” of food. In order to improve, various flavor improvers and texture improvers including a taste improver and elasticity enhancer have been studied.

前記日持向上剤としては、例えば、アジピン酸、クエン酸、酒石酸、フマル酸等の有機酸、リゾチーム、エタノール及びグリセリン脂肪酸エステルを有効成分とするものが提案されている(特許文献1参照)。また、リゾチーム、アミノ酸、有機酸及び酢酸塩を含有するものも提案されている(特許文献2参照)。
前記味質改善剤としては、例えば、コハク酸又はコハク酸ナトリウム、グルタミン酸ナトリウム、グリシン、フマル酸ナトリウム、及び酢酸塩を含有するものが提案されている(特許文献3参照)。また、前記弾力増強剤としては、例えば、グリシン及びシスチンを含有するものが提案されている(特許文献4参照)。
As the shelf life improver, for example, an organic acid such as adipic acid, citric acid, tartaric acid and fumaric acid, lysozyme, ethanol and glycerin fatty acid ester have been proposed (see Patent Document 1). Moreover, what contains a lysozyme, an amino acid, an organic acid, and acetate is also proposed (refer patent document 2).
As the taste improving agent, for example, one containing succinic acid or sodium succinate, sodium glutamate, glycine, sodium fumarate, and acetate has been proposed (see Patent Document 3). Moreover, as said elasticity enhancer, what contains glycine and cystine, for example is proposed (refer patent document 4).

しかしながら、これらの場合、添加した加工食品の日持ちと、風味、食感等を同時に満足することができないという問題があり、更に、食味を変化させてしまったり、酸味又は酸臭の増加を生じたりするという問題があった。   However, in these cases, there is a problem that the longevity of the added processed food, flavor, texture, etc. cannot be satisfied at the same time, and furthermore, the taste may be changed or the acidity or acid smell may increase. There was a problem to do.

したがって、前記加工食品の静菌効果、並びに風味及び食感を共に向上可能な食品用調味料組成物は未だ得られておらず、その速やかな提供が望まれているのが現状である。前記加工食品の中でも、特に、ハム、ソーセージ等の食肉加工食品については、これらの食品用調味料の提供が切に望まれていた。   Therefore, a seasoning composition for foods that can improve both the bacteriostatic effect, flavor and texture of the processed food has not yet been obtained, and its immediate provision is desired. Among the processed foods, particularly for meat processed foods such as ham and sausage, provision of these food seasonings has been strongly desired.

特開平5−72号公報Japanese Patent Laid-Open No. 5-72 特開平8−196252号公報JP-A-8-196252 特開2001−17893号公報Japanese Patent Laid-Open No. 2001-17893 特開2003−70430号公報JP 2003-70430 A

本発明は、従来における前記問題を解決し、以下の目的を達成することを課題とする。即ち、本発明は、食品、特に食肉加工食品に好適であり、その静菌効果、風味及び食感を向上可能であり、食品の日持ちを向上可能である食品用調味料組成物、及びこれを含む食品を提供することを目的とする。   An object of the present invention is to solve the conventional problems and achieve the following objects. That is, the present invention is suitable for foods, particularly processed meat foods, can improve its bacteriostatic effect, flavor and texture, and can improve the shelf life of foods, and a food seasoning composition therefor The purpose is to provide food containing.

前記課題を解決するための手段は以下の通りである。即ち、
<1> グルタミン酸塩、グリシン、アラニン、フマル酸塩、及び酢酸塩を含有することを特徴とする食品用調味料組成物である。
<2> グルタミン酸塩がグルタミン酸ナトリウムであり、フマル酸塩がフマル酸ナトリウムであり、酢酸塩が酢酸ナトリウムである前記<1>に記載の食品用調味料組成物である。
<3> 風味向上作用、食感改良作用及び日持向上作用の少なくともいずれかを示す前記<1>から<2>のいずれかに記載の食品用調味料組成物である。
<4> グルタミン酸塩を0.1〜1質量%含み、グリシンを5〜30質量%含み、アラニンを5〜30質量%含み、フマル酸塩を3〜15質量%含み、酢酸塩を45〜70質量%含む前記<1>から<3>のいずれかに記載の食品用調味料組成物である。
<5> グリシン及びアラニンを合計で15〜45質量%含む前記<4>に記載の食品用調味料組成物である。
<6> 前記<1>から<5>のいずれかに記載の食品用調味料組成物を含むことを特徴とする食品である。
<7> 食品が食肉加工食品である前記<6>に記載の食品である。
Means for solving the above-mentioned problems are as follows. That is,
<1> A food seasoning composition comprising glutamate, glycine, alanine, fumarate, and acetate.
<2> The food seasoning composition according to <1>, wherein the glutamate is sodium glutamate, the fumarate is sodium fumarate, and the acetate is sodium acetate.
<3> The food seasoning composition according to any one of <1> to <2>, wherein the seasoning composition exhibits at least one of a flavor improving action, a texture improving action, and a shelf life improving action.
<4> 0.1 to 1% by mass of glutamate, 5 to 30% by mass of glycine, 5 to 30% by mass of alanine, 3 to 15% by mass of fumarate, 45 to 70% of acetate It is a seasoning composition for foodstuffs in any one of said <1> to <3> containing mass%.
<5> The seasoning composition for food according to <4>, wherein the total amount of glycine and alanine is 15 to 45% by mass.
<6> A food comprising the seasoning composition for food according to any one of <1> to <5>.
<7> The food according to <6>, wherein the food is a processed meat food.

本発明によると、従来における前記問題を解決し、食品、特に食肉加工食品に好適であり、その静菌効果、風味及び食感を向上可能であり、食品の日持ちを向上可能である食品用調味料組成物、及びこれを含む食品を提供することができる。   According to the present invention, the above-mentioned problems in the prior art are solved, and it is suitable for foods, particularly processed meat foods, can improve its bacteriostatic effect, flavor and texture, and can improve the shelf life of foods. The food composition and the food containing the same can be provided.

(食品用調味料組成物)
本発明の食品用調味料組成物は、グルタミン酸塩、グリシン、アラニン、フマル酸塩、及び酢酸塩を含有してなり、更に必要に応じて、その他の成分を含有してなる。
(Food seasoning composition)
The food seasoning composition of the present invention contains glutamate, glycine, alanine, fumarate, and acetate, and further contains other components as necessary.

−グルタミン酸塩−
前記グルタミン酸塩は、酸性アミノ酸の一種であるグルタミン酸の塩類であり、旨み成分として公知であり、化学調味料として広く利用されている。
前記グルタミン酸塩としては、通常食品素材として利用されているグルタミン酸塩であれば特に制限はなく、例えば、ナトリウム塩、カリウム塩等のアルカリ金属塩、カルシウム塩、マグネシウム塩等のアルカリ土類金属塩等が挙げられ、これらの中でも特にナトリウム塩が好ましい。グルタミン酸ナトリウムは、昆布だしの旨みの主体となるもので、業務用はもとより、家庭用の調味料としても広く普及している。
-Glutamate-
The glutamate is a salt of glutamic acid, which is a kind of acidic amino acid, is known as an umami component, and is widely used as a chemical seasoning.
The glutamate is not particularly limited as long as it is a glutamate normally used as a food material. For example, alkali metal salts such as sodium salt and potassium salt, alkaline earth metal salts such as calcium salt and magnesium salt, etc. Among these, sodium salts are particularly preferable. Sodium glutamate is the main flavor of kombu soup and is widely used as a seasoning for home use as well as for business use.

前記グルタミン酸塩は、1種単独で用いてもよいし、2種以上を併用してもよい。
前記グルタミン酸塩の含有量としては、特に制限はなく、他の成分の含有量に応じて適宜選択することができるが、他の成分のもたらす静菌効果や味、臭い、食感等の官能的な効果を損なわない範囲で含有することが好ましく、本発明の食品用調味料組成物全質量に対し、0.1〜1質量%が好ましく、0.3〜0.7質量%がより好ましい。
The said glutamate may be used individually by 1 type, and may use 2 or more types together.
The content of the glutamate is not particularly limited and may be appropriately selected depending on the content of other components. However, the bacteriostatic effect and taste, smell, texture, etc. brought about by other components It is preferable to contain in the range which does not impair the effect, 0.1-1 mass% is preferable with respect to the seasoning composition for foodstuffs of this invention, and 0.3-0.7 mass% is more preferable.

−グリシン−
前記グリシンは、天然アミノ酸の1つであり、グリココール又はアミノ酢酸とも称され、ほぼすべての動物蛋白質中に存在するが、植物性蛋白質にはほとんど含まれていない。前記グリシンは、砂糖の約60%程度の甘みを持ち、また、微生物に対する静菌効果を持つために、甘みとコクを与える調味料や、日持向上剤として多くの食品に添加されている。
-Glycine-
The glycine is one of natural amino acids and is also called glycochol or aminoacetic acid and is present in almost all animal proteins, but is hardly contained in plant proteins. The glycine has a sweetness of about 60% of that of sugar and has a bacteriostatic effect on microorganisms. Therefore, the glycine is added to many foods as a seasoning that provides sweetness and richness, and as a shelf life improving agent.

前記グリシンの含有量としては、特に制限はなく、他の成分の含有量に応じて適宜選択することができるが、本発明の食品用調味料組成物全質量に対し、5〜30質量%が好ましく、8〜25質量%がより好ましく、10〜20質量%が特に好ましい。   There is no restriction | limiting in particular as content of the said glycine, Although it can select suitably according to content of another component, 5-30 mass% is with respect to the seasoning composition for foodstuffs of this invention. Preferably, 8 to 25% by mass is more preferable, and 10 to 20% by mass is particularly preferable.

−アラニン−
前記アラニンは、イカや貝類などの水産食品に特有の旨みを構成するアミノ酸であり、グリシンと同様に甘みを持ち、特に非天然型のD−体は、強い甘みを持つことが知られている。本発明の食品用調味料組成物に用いるアラニンとしては、特に制限はなく、D−体、L−体、及びDL−体のいずれも使用することができる。
-Alanine-
The alanine is an amino acid that constitutes umami unique to marine foods such as squid and shellfish, and has a sweetness similar to that of glycine. In particular, a non-natural D-form is known to have a strong sweetness. . There is no restriction | limiting in particular as alanine used for the seasoning composition for foodstuffs of this invention, Any of D-form, L-form, and DL-form can be used.

前記アラニンの含有量としては、特に制限はなく、他の成分の含有量に応じて適宜選択することができるが、本発明の食品用調味料組成物全質量に対し、5〜30質量%が好ましく、8〜25質量%がより好ましく、10〜20質量%が特に好ましい。   There is no restriction | limiting in particular as content of the said alanine, Although it can select suitably according to content of another component, 5-30 mass% is with respect to the seasoning composition for foodstuffs of this invention. Preferably, 8 to 25% by mass is more preferable, and 10 to 20% by mass is particularly preferable.

前記グリシン及びアラニンは、併用することで、これらを単独で使用した場合よりも高い静菌効果を付与することができる。前記グリシン及びアラニンの含有量の合計として、本発明の食品用調味料組成物全体に対し、15〜45質量%が好ましく、20〜40質量%がより好ましく、25〜35質量%が特に好ましい。   The glycine and alanine can be used together to give a higher bacteriostatic effect than when they are used alone. The total content of glycine and alanine is preferably 15 to 45% by mass, more preferably 20 to 40% by mass, and particularly preferably 25 to 35% by mass with respect to the entire food seasoning composition of the present invention.

−フマル酸塩−
前記フマル酸塩は、特有の酸味を持つ有機酸塩であり、主に酸味料やpH調整剤として食品に使用されている。
前記フマル酸塩としては、通常の食品素材として利用されているフマル酸塩であれば特に制限はなく、例えば、ナトリウム塩、カリウム塩等のアルカリ金属塩、カルシウム塩、マグネシウム塩等のアルカリ土類金属塩等が挙げられ、これらの中でも、特にナトリウム塩が好ましい。
-Fumarate-
The fumarate is an organic acid salt having a specific acidity, and is mainly used in foods as an acidulant and a pH adjuster.
The fumarate is not particularly limited as long as it is a fumarate used as a normal food material. For example, alkali metal salts such as sodium salt and potassium salt, alkaline earth such as calcium salt and magnesium salt Examples thereof include metal salts, and among these, sodium salts are particularly preferable.

前記フマル酸塩は、1種単独で用いてもよいし、2種以上を併用してもよい。
前記フマル酸塩の含有量としては、特に制限はなく、他の成分の含有量に応じて適宜選択することができるが、本発明の食品用調味料組成物全質量に対し、3〜15質量%が好ましく、7.5〜12質量%がより好ましく、9〜11質量%が特に好ましい。
The fumarate may be used alone or in combination of two or more.
There is no restriction | limiting in particular as content of the said fumarate, Although it can select suitably according to content of another component, 3-15 mass with respect to the food seasoning composition total mass of this invention. % Is preferable, 7.5 to 12% by mass is more preferable, and 9 to 11% by mass is particularly preferable.

−酢酸塩−
前記酢酸塩は、有機酸の中でも強い抗菌作用を持つ酢酸の酸性塩であり、水和物結晶、無水結晶等が存在し、塩にすることで酢酸特有の刺激臭や酸味が抑えられており、酸味料やpH調整剤として使用されている。
前記酢酸塩としては、通常食品素材として利用されている酢酸塩であれば特に制限はないが、特に無水酢酸ナトリウム塩が好ましい。
-Acetate-
The acetate is an acid salt of acetic acid that has strong antibacterial action among organic acids, and there are hydrate crystals, anhydrous crystals, etc., and the salt suppresses the irritating odor and acidity peculiar to acetic acid. It is used as a sour agent and a pH adjuster.
The acetate is not particularly limited as long as it is an acetate generally used as a food material, but anhydrous sodium acetate is particularly preferable.

前記酢酸塩は、1種単独で用いてもよいし、2種以上を併用してもよい。
前記酢酸塩の含有量としては、特に制限はなく、他の成分の含有量に応じて適宜選択することができるが、本発明の食品用調味料組成物全質量に対し、45〜70質量%が好ましく、48〜65質量%がより好ましく、55〜60質量%が特に好ましい。
The said acetate may be used individually by 1 type, and may use 2 or more types together.
There is no restriction | limiting in particular as content of the said acetate, Although it can select suitably according to content of another component, It is 45-70 mass% with respect to the seasoning composition for foodstuffs of this invention. Is preferable, 48-65 mass% is more preferable, 55-60 mass% is especially preferable.

−その他の成分−
本発明の食品用調味料組成物は、前記の各成分に加えて、対象とする食品に応じて、更に必要に応じて、通常使用される、リンゴ酸、クエン酸等の有機酸またはその塩、アミノ酸、リン酸塩、アルコール等を含有することができる。
-Other ingredients-
The seasoning composition for food according to the present invention is an organic acid such as malic acid or citric acid or a salt thereof, which is usually used in addition to the above components, depending on the target food, and if necessary. , Amino acids, phosphates, alcohols and the like.

前記食品用調味料組成物の製造方法としては、特に制限は無く、目的に応じて適宜選択することができるが、通常用いられるミキサー、乳鉢、すり鉢等を使用して、各成分を適切な割合で混合し製造すればよい。なお、前記食品用調味料組成物の形態としては特に制限はなく、各成分の粉体混合物のままでもよいが、デキストリン、シクロデキストリン等の薬学的に許容され得るキャリアーや、その他任意の助剤と混合して製剤化し、粉末状、顆粒状、錠剤状等の任意の剤形にしてもよく、また、液状、ペースト状等にしてもよい。   The method for producing the food seasoning composition is not particularly limited and may be appropriately selected depending on the intended purpose. However, using a commonly used mixer, mortar, mortar, etc., each component is contained in an appropriate ratio. Can be mixed and manufactured. The form of the food seasoning composition is not particularly limited and may be a powder mixture of each component, but may be a pharmaceutically acceptable carrier such as dextrin or cyclodextrin, or any other auxiliary agent. And may be formulated into any dosage form such as powder, granule, tablet, etc., or it may be liquid, paste or the like.

以上のようにして得られる食品用調味料組成物は、静菌効果、風味及び食感の向上効果に優れ、食品の日持ちの向上に優れていると共に、安全性にも優れているため、ソーセージなどの食肉加工食品に添加するのに好適である。   The seasoning composition for foods obtained as described above is excellent in bacteriostatic effect, flavor and texture improving effect, is excellent in improving the shelf life of food, and is excellent in safety. It is suitable for adding to processed meat foods such as.

(食品)
本発明の食品は、前記食品用調味料組成物を含有してなり、更に必要に応じて適宜選択したその他の成分を含有してなる。
(Food)
The food of the present invention contains the above-mentioned seasoning composition for food, and further contains other components appropriately selected as necessary.

前記食品としては、前記食品用調味料組成物を含有している限り、経口摂取可能な組成物であれば、特に制限はなく、目的に応じて適宜選択することができるが、例えば、ハム、ソーセージ、ウインナー、フランクフルト、ハンバーグ、メンチカツ、チキンナゲット、ミートボール、つみれ、竹輪、薩摩揚、蒲鉾等の食肉加工食品が好ましい。   As long as the said foodstuff contains the said seasoning composition for foods, if it is a composition which can be taken orally, there will be no restriction | limiting in particular, According to the objective, it can select suitably, for example, ham, Meat processed foods such as sausage, Wiener, Frankfurt, hamburger, pork cutlet, chicken nuggets, meatballs, tsumire, bamboo rings, Satsuma fried foods, and salmon are preferred.

前記食品への本発明の食品用調味料組成物の添加方法としては、特に制限はなく、目的に応じて適宜選択することができるが、通常は調理又は調製中に、溶解、混和、練りこみ、吹きつけ、ふりかけ、まぶす等を行なう方法が挙げられる。
前記食品用調味料組成物の含有量としては、特に制限はなく、目的に応じて適宜選択することができるが、前記食品の全質量に対し、0.3〜1.5質量%が好ましく、0.5〜1.0質量%がより好ましい。
The method for adding the food seasoning composition of the present invention to the food is not particularly limited and may be appropriately selected depending on the intended purpose. Usually, it is dissolved, mixed, and kneaded during cooking or preparation. , Spraying, sprinkling, and spraying.
The content of the seasoning composition for food is not particularly limited and may be appropriately selected depending on the purpose. It is preferably 0.3 to 1.5% by mass with respect to the total mass of the food, 0.5-1.0 mass% is more preferable.

−その他の成分−
本発明の食品は、前記の各成分に加えて、その食品の種類に応じて、本発明の効果を損なわない範囲であれば、更に必要に応じて、通常使用される、乳糖、デキストリン、食塩、リン酸塩等の各種食品素材や、食品添加物を含有することができる。
-Other ingredients-
The food of the present invention, in addition to the above-mentioned components, depending on the type of the food, as long as it does not impair the effects of the present invention, is further commonly used, lactose, dextrin, salt Various food materials such as phosphates and food additives can be contained.

以下、本発明の実施例を説明するが、本発明は、これらの実施例に何ら限定されるものではない。なお、本実施例において、特に断りのない限り、表中の数値は全て質量%を表すものとする。   Examples of the present invention will be described below, but the present invention is not limited to these examples. In this example, all numerical values in the table represent mass% unless otherwise specified.

(実施例1〜5、7及び8、参考例6、並びに比較例1〜5)
−食品用調味料組成物の調製−
下記表1及び表2に記載の組成で、合計50gとなるように各組成物を秤取し、ミキサー(「Wonder Blender WB−1」;大阪ケミカル株式会社製)を用いて2分間混合し、実施例1〜5、7及び8、参考例6、並びに比較例1〜5の食品用調味料組成物を得た。
(Examples 1-5 , 7, and 8, Reference Example 6, and Comparative Examples 1-5)
-Preparation of a seasoning composition for food-
Each composition was weighed so as to be 50 g in total with the composition described in Table 1 and Table 2 below, and mixed for 2 minutes using a mixer (“Wonder Blender WB-1”; manufactured by Osaka Chemical Co., Ltd.) The seasoning composition for foodstuffs of Examples 1-5 , 7, and 8, Reference Example 6, and Comparative Examples 1-5 was obtained.

−ソーセージの製造−
下記処方に従って、実施例1〜5、7及び8、参考例6、並びに比較例1〜5から得られた食品用調味料組成物をそれぞれ含有するソーセージを製造した。
豚背脂肪をフードカッター(「DLC−6PRO」;クイジナートサンエイ株式会社製)にて30秒間粉砕し、残りの材料を添加し、2分間混合した。次いで前記実施例又は比較例から得られた食品用調味料 1.8g(原材料合計の0.6質量%)を添加し、3分間混合した後、得られた生地をケーシング(直径40mmの円形)に充填し、90℃の温水で30分間加熱してソーセージを得た。また、食品用調味料を添加しないもの(無添加サンプル)も製造した。
<ソーセージの処方>
豚赤身挽肉 141.0g
豚背脂肪 67.5g
でん粉 11.1g
食塩 6.0g
砂糖 4.5g
コショウ 2.4g
氷 67.5g
合計 300.0g
-Manufacture of sausages-
According to the following prescription, the sausage which contains the seasoning composition for foods obtained from Examples 1-5 , 7, and 8, Reference Example 6, and Comparative Examples 1-5, respectively was manufactured.
The pork back fat was pulverized for 30 seconds with a food cutter (“DLC-6PRO”; manufactured by Kuisinato Sanei Co., Ltd.), and the remaining ingredients were added and mixed for 2 minutes. Next, 1.8 g (0.6% by mass of the total raw materials) of food seasonings obtained from the examples or comparative examples were added and mixed for 3 minutes, and then the obtained dough was casing (circular with a diameter of 40 mm). And heated with 90 ° C. hot water for 30 minutes to obtain a sausage. Moreover, the thing which does not add the seasoning for foodstuffs (an additive-free sample) was also manufactured.
<Sausage prescription>
141.0g minced pork
Pork back fat 67.5g
Starch 11.1g
6.0g of salt
4.5g sugar
Pepper 2.4g
67.5g ice
Total 300.0g

[評価]
前記ソーセージについて、以下の方法により、静菌効果を測定し、更に風味を官能評価した。結果を表1及び表2に示す。
[Evaluation]
About the said sausage, the bacteriostatic effect was measured with the following method, and also the flavor was sensory-evaluated. The results are shown in Tables 1 and 2.

(1)バイオサーモアナライザー(BTA)試験
前記ソーセージ5gを検査瓶(「PS−3K」;第一硝子社製)に入れ、蓋を閉めた後、バイオサーモアナライザー(「H−201」;日本医科器械製作所製)の高温槽内セルに設置した。また、対照セルには無添加サンプルを入れた。バイオサーモアナライザーの設定条件は、高温槽温度30℃、微小電圧計レンジ500μV、測定間隔15分とした。得られた各サンプルの細菌増殖ピーク時間に基づき、以下の評価基準に従って、静菌効果を評価した。
バイオサーモアナライザー(BTA)試験における細菌増殖ピークは、細菌の増殖のしやすさのパラメーターであり、ピーク発現時間が遅いほど、静菌効果が優れていることを意味するものである。本試験では、食品用調味料組成物を添加したサンプルのピーク時間が、無添加サンプルのピーク時間に対して1.9倍以上のものを静菌効果が良好であると評価した。
−評価基準−
○:無添加サンプルのピーク時間に対する添加サンプルのピーク時間の比が2.1以上
△:無添加サンプルのピーク時間に対する添加サンプルのピーク時間の比が1.9以上2.1未満
×:無添加サンプルのピーク時間に対する添加サンプルのピーク時間の比が1.9未満
(1) Biothermoanalyzer (BTA) test 5 g of the sausage was placed in an inspection bottle (“PS-3K”; manufactured by Daiichi Glass Co., Ltd.), the lid was closed, and then a biothermoanalyzer (“H-201”; Japanese Medical Department) It was installed in a cell in a high-temperature tank of Instrument Manufacturing). In addition, an additive-free sample was placed in the control cell. The biothermoanalyzer was set at a high temperature bath temperature of 30 ° C., a microvoltmeter range of 500 μV, and a measurement interval of 15 minutes. Based on the bacterial growth peak time of each sample obtained, the bacteriostatic effect was evaluated according to the following evaluation criteria.
The bacterial growth peak in the biothermoanalyzer (BTA) test is a parameter for the ease of bacterial growth, and the slower the peak expression time, the better the bacteriostatic effect. In this test, a sample having a food seasoning composition added with a peak time of 1.9 times or more of the peak time of an additive-free sample was evaluated as having a good bacteriostatic effect.
-Evaluation criteria-
○: The ratio of the peak time of the added sample to the peak time of the additive-free sample is 2.1 or more. Δ: The ratio of the peak time of the added sample to the peak time of the additive-free sample is 1.9 or more and less than 2.1. Ratio of peak time of added sample to peak time of sample is less than 1.9

(2)官能評価
前記ソーセージを、5名のパネラーに試食してもらい、それぞれの風味(味、臭い)及び食感について無添加サンプルと比較して、以下の評価基準に従って、評価した。
−評価基準−
○:無添加サンプルと比べて優れている状態
△:無添加サンプルとの差がない状態
×:無添加サンプルと比べて劣っている状態
(2) Sensory evaluation The sausage was sampled by five panelists, and each flavor (taste, smell) and texture were evaluated according to the following evaluation criteria in comparison with the additive-free sample.
-Evaluation criteria-
○: Excellent state compared to the additive-free sample △: No difference from the additive-free sample ×: State inferior to the additive-free sample

Figure 0005230914
Figure 0005230914

Figure 0005230914
Figure 0005230914

表1及び表2の結果から、本発明の食品用調味料組成物は良好な静菌効果を示すと共に、添加した食品の風味及び食感の向上作用を示すことが判った。中でも、グリシン及びアラニンの含有量がそれぞれ8〜25質量%である実施例1〜4の食品用調味料組成物は、実施例5、7及び8並びに参考例6の食品用調味料組成物と比べて特に優れた静菌効果を持つことが判った。 From the results of Tables 1 and 2, it was found that the seasoning composition for foods of the present invention exhibits a good bacteriostatic effect and also exhibits an effect of improving the flavor and texture of the added food. Among them, the food seasoning compositions of Examples 1 to 4 in which the contents of glycine and alanine are 8 to 25% by mass are the same as the food seasoning compositions of Examples 5 , 7 and 8 and Reference Example 6 , respectively. It was found to have a particularly excellent bacteriostatic effect.

(実施例9〜12)
下記表3に記載の組成で、前記実施例1〜5、7及び8、参考例6、並びに比較例1〜5と同様にして、実施例9〜12の食品用調味料組成物、及び該食品調味料組成物を含有するソーセージをそれぞれ製造した。
得られた実施例9〜12の食品調味料組成物を含有するソーセージについて、前記実施例1〜5、7及び8、参考例6、並びに比較例1〜5と同様に静菌効果を測定し、更に食感及び風味を官能評価した。結果を表3に示す。
(Examples 9 to 12)
In the composition described in Table 3 below, in the same manner as in Examples 1 to 5, 7 and 8, Reference Example 6 and Comparative Examples 1 to 5, the seasoning compositions for foods of Examples 9 to 12, and Sausages containing the food seasoning composition were each produced.
About the sausage containing the food seasoning composition of Examples 9-12 obtained, the bacteriostatic effect was measured similarly to the said Examples 1-5 , 7 and 8, Reference Example 6, and Comparative Examples 1-5. Furthermore, sensory evaluation was performed on the texture and flavor. The results are shown in Table 3.

Figure 0005230914
Figure 0005230914

表3の結果から、本発明の食品用調味料組成物は添加した食品の風味及び食感の向上作用を示すと共に、良好な静菌効果を持つことが判った。中でも、酢酸ナトリウムの含有量が48〜65質量%の範囲である実施例10〜11の食品用調味料組成物は、実施例9及び12の食品用調味料組成物と比べて静菌効果及び風味に特に優れていることが判った。   From the results of Table 3, it was found that the seasoning composition for food of the present invention has an effect of improving the flavor and texture of the added food and has a good bacteriostatic effect. Among them, the food seasoning composition of Examples 10 to 11 in which the content of sodium acetate is in the range of 48 to 65% by mass is less bacteriostatic than the food seasoning compositions of Examples 9 and 12. It was found to be particularly excellent in flavor.

(実施例13〜17)
下記表4に記載の組成で、前記実施例1〜5、7及び8、参考例6、並びに比較例1〜5と同様にして、実施例13〜17の食品用調味料組成物、及び該食品調味料組成物を含有するソーセージをそれぞれ製造した。
得られた実施例13〜17の食品調味料組成物を含有するソーセージについて、前記実施例1〜5、7及び8、参考例6、並びに比較例1〜5と同様に静菌効果を測定し、更に食感及び風味を官能評価した。結果を表4に示す。
(Examples 13 to 17)
In the composition described in Table 4 below, in the same manner as in Examples 1 to 5, 7, and 8, Reference Example 6, and Comparative Examples 1 to 5, the food seasoning compositions of Examples 13 to 17, and the Sausages containing the food seasoning composition were each produced.
About the sausage containing the food seasoning composition of Examples 13-17 obtained, the bacteriostatic effect was measured similarly to the said Examples 1-5 , 7 and 8, Reference Example 6, and Comparative Examples 1-5. Furthermore, sensory evaluation was performed on the texture and flavor. The results are shown in Table 4.

Figure 0005230914
Figure 0005230914

表4の結果から、本発明の食品用調味料組成物は添加した食品の風味及び食感の向上作用を示すと共に、良好な静菌効果を示すことが判った。中でも、フマル酸ナトリウムの含有量が7.5〜12質量%の範囲である実施例14〜16の食品用調味料組成物は、実施例13及び17の食品用調味料組成物と比べて静菌効果及び食感に特に優れていることが判った。   From the results of Table 4, it was found that the seasoning composition for food of the present invention showed an effect of improving the flavor and texture of the added food and also showed a good bacteriostatic effect. Especially, the seasoning composition for foodstuffs of Examples 14-16 whose content of sodium fumarate is the range of 7.5-12 mass% is quiet compared with the seasoning composition for foodstuffs of Examples 13 and 17. It was found that the fungus effect and texture were particularly excellent.

−食品用調味料組成物の添加量の異なる食品(ソーセージ)の製造−
実施例3の食品用調味料組成物を、原料の合計質量(300g)に対して下記表5に示す添加量でそれぞれ添加して、食品調味料組成物を含有する各ソーセージを製造した。
得られた各ソーセージについて、前記と同様にして、静菌効果を測定し、更に食感及び風味を官能評価した。結果を表5に示す。
-Manufacture of foods (sausages) with different amounts of food seasonings-
Each sausage containing the food seasoning composition was produced by adding the seasoning composition for food of Example 3 in an amount shown in Table 5 below with respect to the total mass (300 g) of the raw materials.
About each obtained sausage, it carried out similarly to the above, the bacteriostatic effect was measured, and also food texture and flavor were sensory-evaluated. The results are shown in Table 5.

Figure 0005230914
Figure 0005230914

表5に示す結果から、本発明の食品用調味料組成物は、幅広い添加量で食品の風味及び食感の向上作用及び静菌効果を発揮することができることが判った。中でも、食品(ソーセージ)へ0.5〜1.0質量%の範囲内で添加した場合は、静菌効果及び風味に特に優れた効果を発揮することが判った。   From the results shown in Table 5, it was found that the seasoning composition for food according to the present invention can exhibit the effect of improving the flavor and texture of food and the bacteriostatic effect with a wide range of addition amounts. Especially, when it added to the foodstuff (sausage) in the range of 0.5-1.0 mass%, it turned out that the effect especially excellent in the bacteriostatic effect and flavor is exhibited.

本発明の食品用調味料組成物は、各種食品に添加することにより、その静菌効果、風味及び食感を向上可能であり、該食品の日持ちを向上可能であるので、例えば、ハム、ソーセージ、ウインナー、フランクフルト、ハンバーグ、メンチカツ、チキンナゲット、ミートボール、つみれ、竹輪、薩摩揚、蒲鉾等の食肉加工食品の調味料として好適である。
The seasoning composition for food of the present invention can be added to various foods to improve its bacteriostatic effect, flavor and texture, and can improve the shelf life of the food. For example, ham, sausage , Wiener, frankfurt, hamburger, meat cutlet, chicken nuggets, meatballs, tsumire, bamboo rings, satsuma fried foods, and other meat processed foods.

Claims (6)

グルタミン酸塩、グリシン、アラニン、フマル酸塩、及び酢酸塩を含有し、
前記グリシンの含有量が全質量に対し、5質量%〜30質量%であり、
前記アラニンの含有量が全質量に対し、8質量%〜25質量%であり、
前記フマル酸塩の含有量が全質量に対し、7.5質量%〜12質量%であり、
前記酢酸塩の含有量が全質量に対し、48質量%〜65質量%であり、
前記グリシン及び前記アラニンの合計含有量が全質量に対し、15質量%〜45質量%であることを特徴とする食品用調味料組成物。
Contains glutamate, glycine, alanine, fumarate, and acetate;
The content of the glycine with respect to the total mass, Ri 5% to 30% by mass,
The alanine content is 8% by mass to 25% by mass with respect to the total mass,
The content of the fumarate is 7.5% by mass to 12% by mass with respect to the total mass,
The content of the acetate is 48% by mass to 65% by mass with respect to the total mass,
The glycine and the total content of the alanine with respect to the total mass, food seasoning composition characterized der Rukoto 15 wt% to 45 wt%.
グルタミン酸塩がグルタミン酸ナトリウムであり、フマル酸塩がフマル酸ナトリウムであり、酢酸塩が酢酸ナトリウムである請求項1に記載の食品用調味料組成物。   The food seasoning composition according to claim 1, wherein the glutamate is sodium glutamate, the fumarate is sodium fumarate, and the acetate is sodium acetate. 風味向上作用、食感改良作用及び日持向上作用の少なくともいずれかを示す請求項1から2のいずれかに記載の食品用調味料組成物。   The seasoning composition for foodstuffs in any one of Claim 1 to 2 which shows at least any one of a flavor improvement effect | action, a food texture improvement effect | action, and a shelf life improvement effect | action. グルタミン酸塩を全質量に対し、0.1質量%〜1質量%含請求項1から3のいずれかに記載の食品用調味料組成物。 With respect to the total mass of glutamate, food seasoning composition according to any one of 3 to 0.1 wt% to 1 wt% including claim 1. 請求項1からのいずれかに記載の食品用調味料組成物を含むことを特徴とする食品。 A food comprising the seasoning composition for food according to any one of claims 1 to 4 . 食品が食肉加工品である請求項に記載の食品。 The food according to claim 5 , wherein the food is a processed meat product.
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