JP5164371B2 - Liquid detergent composition for hard surfaces - Google Patents
Liquid detergent composition for hard surfaces Download PDFInfo
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- JP5164371B2 JP5164371B2 JP2006337199A JP2006337199A JP5164371B2 JP 5164371 B2 JP5164371 B2 JP 5164371B2 JP 2006337199 A JP2006337199 A JP 2006337199A JP 2006337199 A JP2006337199 A JP 2006337199A JP 5164371 B2 JP5164371 B2 JP 5164371B2
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Description
本発明は硬質表面用液体洗浄剤組成物に関する。 The present invention relates to a liquid cleaning composition for hard surfaces.
食器や調理器具等の硬質表面の手洗い洗浄に用いられる洗浄剤組成物は、利便性から液体であることが好ましい。このような洗浄剤組成物には、皿、茶碗、湯呑み等の食器、包丁、鍋、フライパン等の調理器具、換気扇や台所周辺の壁、ガラス、冷蔵庫等に付着した強固な油汚れを簡単に除去する高い洗浄力と、豊かな泡立ち（起泡性）が求められる。そのため、通常の界面活性剤だけでは満足する洗浄力を得ることができず、従来、直鎖アルキルベンゼンスルホン酸塩等の陰イオン界面活性剤とアミンオキシド型界面活性剤等とを組み合わせることにより、良好な洗浄力や起泡性を有する液体洗浄剤組成物が開発されている。 The cleaning composition used for hand-washing hard surfaces such as tableware and cooking utensils is preferably a liquid for convenience. Such cleaning compositions can easily remove strong oil stains attached to dishes such as dishes, teacups, and cups, kitchen utensils, cooking utensils such as pans and pans, ventilation fans and kitchen peripheral walls, glass and refrigerators. High detergency to remove and rich foaming (foaming property) are required. For this reason, satisfactory detergency cannot be obtained only with ordinary surfactants. Conventionally, a combination of an anionic surfactant such as a linear alkylbenzene sulfonate and an amine oxide surfactant is favorable. Liquid detergent compositions having excellent detergency and foaming properties have been developed.
特許文献１には、陰イオン界面活性剤、アミンオキシド型界面活性剤、及びアルキルグリセリルエーテルを含有する、洗浄効果に優れる食器洗い用洗浄剤が開示されている。また、特許文献２には、陰イオン界面活性剤、両性界面活性剤、非イオン界面活性剤、及び分子内に複数の水酸基を有する化合物を含有する、洗浄力、泡立ち、泡質、低温安定性に優れた液体洗浄剤組成物が開示されている。しかしながら、これらの液体洗浄剤組成物は、洗浄力、起泡性の点で十分ではなく、これらの性能をさらに向上させた液体洗浄剤組成物の開発が望まれている。 Patent Document 1 discloses a dishwashing detergent containing an anionic surfactant, an amine oxide surfactant, and an alkyl glyceryl ether, which has an excellent cleaning effect. Patent Document 2 discloses an anionic surfactant, an amphoteric surfactant, a nonionic surfactant, and a compound having a plurality of hydroxyl groups in the molecule, detergency, foaming, foam quality, and low temperature stability. An excellent liquid detergent composition is disclosed. However, these liquid detergent compositions are not sufficient in terms of detergency and foamability, and development of liquid detergent compositions that further improve these performances is desired.
本発明は、洗浄力と起泡性に優れた硬質表面用液体洗浄剤組成物であって、特に食器用として好適な硬質表面用液体洗浄剤組成物を提供することを課題とする。 It is an object of the present invention to provide a hard surface liquid detergent composition excellent in detergency and foamability, and particularly suitable for tableware.
本発明者らは、特定のアミンオキシド型界面活性剤、及び特定の陰イオン界面活性剤を含有する液体洗浄剤組成物が、上記課題を解決しうることを見出した。
すなわち、本発明は次の液体洗浄剤組成物を提供する。
１．（ａ）下記一般式（Ｉ）のアミンオキシド型界面活性剤、（ｂ）下記一般式（ＩＩ）のアミンオキシド型界面活性剤、及び（ｃ）下記一般式（ＩＩＩ）の陰イオン界面活性剤を含有する硬質表面用液体洗浄剤組成物。
２．（ａ）／（ｂ）の質量比が６０／４０〜９９．５／０．５であり、（ａ）と（ｂ）との合計含有量が１〜４０質量％である上記１に記載の硬質表面用液体洗浄剤組成物。
３．（ｃ）の含有量が５〜５０質量％である上記１又は２に記載の硬質表面用液体洗浄剤組成物。
４．食器用の液体洗浄剤に用いられる上記１〜３のいずれかに記載の硬質表面用液体洗浄剤組成物。
The present inventors have found that a liquid detergent composition containing a specific amine oxide type surfactant and a specific anionic surfactant can solve the above problems.
That is, the present invention provides the following liquid detergent composition.
1. (A) an amine oxide surfactant of the following general formula (I), (b) an amine oxide surfactant of the following general formula (II), and (c) an anionic surfactant of the following general formula (III) A liquid detergent composition for hard surfaces containing
2. 2. The mass ratio of (a) / (b) is 60/40 to 99.5 / 0.5, and the total content of (a) and (b) is 1 to 40% by mass. Liquid detergent composition for hard surfaces.
3. The liquid detergent composition for hard surfaces according to 1 or 2 above, wherein the content of (c) is 5 to 50% by mass.
4). The liquid detergent composition for hard surfaces according to any one of the above 1 to 3, which is used for a liquid detergent for tableware.
本発明によれば、洗浄力と起泡性に優れた硬質表面用液体洗浄剤組成物であって、特に食器用として好適な硬質表面用液体洗浄剤組成物を得ることができる。 ADVANTAGE OF THE INVENTION According to this invention, it is a liquid detergent composition for hard surfaces excellent in detergency and foamability, Comprising: The liquid detergent composition for hard surfaces suitable especially for tableware can be obtained.
［（ａ）成分：第３級アミンオキシド］
本発明にかかる（ａ）成分は、下記一般式（Ｉ）で表される第３級アミンオキシドである。
[(A) component: tertiary amine oxide]
The component (a) according to the present invention is a tertiary amine oxide represented by the following general formula (I).
式中、Ｒ1は、炭素数６〜２４のアルキル基又はアルケニル基であり、洗浄力及び起泡性の向上の観点より、炭素数８〜２０が好ましく、炭素数８〜１８がより好ましく、直鎖でも分岐鎖であってもよい。Ｒ2及びＲ3は、各々独立に炭素数１〜４のアルキル基又はヒドロキシアルキル基であり、洗浄力及び起泡性の向上の観点より、炭素数１〜３が好ましく、より好ましくは炭素数１又は２のアルキル基であり、直鎖でも分岐鎖であってもよい。 In the formula, R 1 is an alkyl group or alkenyl group having 6 to 24 carbon atoms, preferably 8 to 20 carbon atoms, more preferably 8 to 18 carbon atoms from the viewpoint of improving detergency and foamability. It may be linear or branched. R 2 and R 3 are each independently an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group, and from the viewpoint of improving detergency and foaming properties, preferably 1 to 3 carbon atoms, more preferably carbon number. 1 or 2 alkyl groups, which may be linear or branched.
［（ｂ）成分：第３級アミンオキシド］
本発明にかかる（ｂ）成分は、下記一般式（ＩＩ）で表される第３級アミンオキシドである。
[(B) component: tertiary amine oxide]
The component (b) according to the present invention is a tertiary amine oxide represented by the following general formula (II).
式中、Ｒ4及びＲ5は、各々独立に、炭素数６〜２４のアルキル基又はアルケニル基であり、洗浄力及び起泡性の向上の観点より、炭素数６〜２０が好ましく、炭素数８〜１８がより好ましく、直鎖でも分岐鎖であってもよい。また、Ｒ6は、炭素数１〜４のアルキル基又はヒドロキシアルキル基であり、洗浄力及び起泡性の向上の観点より、炭素数１〜３が好ましく、炭素数１又は２のアルキル基がより好ましく、直鎖でも分岐鎖であってもよい。 In the formula, R 4 and R 5 are each independently an alkyl group or an alkenyl group having 6 to 24 carbon atoms, and preferably 6 to 20 carbon atoms from the viewpoint of improving detergency and foamability. 8-18 are more preferable and may be linear or branched. R 6 is an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group, and from the viewpoint of improving detergency and foaming properties, preferably 1 to 3 carbon atoms, and an alkyl group having 1 or 2 carbon atoms. More preferably, it may be linear or branched.
本発明にかかる（ａ）成分及び（ｂ）成分の第三級アミンオキシドは、公知の方法で合成することができる。例えば、アルキルアミンを過酸化水素水等の酸化剤を用いて酸化して得られる。（ａ）成分及び（ｂ）成分の第三級アミンオキシドは、単独で合成して得られたものを混合して用いてもよいし、また、モノアルキル及びジアルキルアミンの混合物を原料として合成されたものを（ａ）成分及び（ｂ）成分の混合物として用いてもよい。 The tertiary amine oxide of component (a) and component (b) according to the present invention can be synthesized by a known method. For example, it can be obtained by oxidizing alkylamine using an oxidizing agent such as hydrogen peroxide. The tertiary amine oxides of the component (a) and the component (b) may be used by mixing those obtained by synthesis alone, or synthesized from a mixture of monoalkyl and dialkylamine as raw materials. May be used as a mixture of component (a) and component (b).
［（ｃ）成分：陰イオン界面活性剤］
本発明にかかる（ｃ）成分は、下記一般式（ＩＩＩ）で表される陰イオン界面活性剤である。
[(C) component: anionic surfactant]
The component (c) according to the present invention is an anionic surfactant represented by the following general formula (III).
式中、Ｒ7は炭素数６〜２４のアルキル基又はアルケニル基であり、優れた泡立ちを得る観点から、炭素数６〜２０が好ましく、炭素数８〜１８がより好ましく、また、直鎖でも分岐鎖であってもよい。Ｒ8は炭素数１〜３のアルカンジイル基であり、炭素数２又は３が好ましく、特に炭素数２のエチレン基が好ましい。ｎは平均付加モル数であり、０．５〜１０．０を示し、洗浄力の向上の点から１〜５がより好ましい。また、Ｍはアルカリ金属、アルカリ土類金属、又はアンモニウム基であり、粘度の点からナトリウム、カリウム、アンモニウム基が好ましい。 In the formula, R 7 is an alkyl group or an alkenyl group having 6 to 24 carbon atoms, and from the viewpoint of obtaining excellent foaming, 6 to 20 carbon atoms are preferable, 8 to 18 carbon atoms are more preferable, It may be a branched chain. R 8 is an alkanediyl group having 1 to 3 carbon atoms, preferably 2 or 3 carbon atoms, particularly preferably an ethylene group having 2 carbon atoms. n is an average added mole number, shows 0.5-10.0, and 1-5 is more preferable from the point of the improvement of a detergency. M is an alkali metal, alkaline earth metal, or ammonium group, and a sodium, potassium, or ammonium group is preferred from the viewpoint of viscosity.
［その他の成分］
本発明の液体洗浄剤組成物においては、洗浄力を強化する目的から（ａ）成分、（ｂ）成分、及び（ｃ）成分以外の界面活性剤（以下、（ｄ）成分ということがある。）を含有させることが好ましく、中でも、非イオン界面活性剤及び／又は両性界面活性剤を用いることが好ましい。非イオン界面活性剤としては、例えば、ポリオキシアルキレンアルキル又はアルケニルエーテル、アルキルポリグルコシド、グルコースアミド等が挙げられ、両性界面活性剤としては、アルキルベタイン、アルキルスルホベタイン、アルキルヒドロキシスルホベタイン、アルキルアミドベタイン、カルボベタイン等を挙げることができる。
[Other ingredients]
In the liquid detergent composition of the present invention, a surfactant other than the component (a), the component (b), and the component (c) (hereinafter referred to as the component (d) may be referred to for the purpose of enhancing the detergency. ) Is preferable, and among them, it is preferable to use a nonionic surfactant and / or an amphoteric surfactant. Examples of the nonionic surfactant include polyoxyalkylene alkyl or alkenyl ether, alkyl polyglucoside, glucose amide and the like. Examples of the amphoteric surfactant include alkyl betaine, alkyl sulfobetaine, alkylhydroxysulfobetaine, alkylamide. Examples include betaine and carbobetaine.
また、本発明の液体洗浄剤組成物は、本発明の効果を損なわない範囲において、上記の非イオン界面活性剤、両性界面活性剤以外にも、一般に洗浄剤に配合される成分を配合することができる。例えば、高級脂肪酸アルカノールアミド、脂肪酸モノグリセリド等の脂肪酸と多価アルコールとのエステル；可溶化剤としてｐ−トルエンスルホン酸塩、ｍ−キシレンスルホン酸塩等の芳香族スルホン酸塩類；グリセリン、エチレングリコール、プロピレングリコール、ソルビトール、１，３−ブチレングリコール等の多価アルコール；エタノール、プロパノール等の低級アルコールや、ポリエチレングリコール、プロピレングリコール、グリセリン等の粘度調節剤；貯蔵安定性を向上させる目的で、低級アリールスルホン酸及びこれらのナトリウム、カリウム又はマグネシウム塩等のハイドロトロープ剤；クエン酸、エチレンジアミン四酢酸誘導体、ニトリロトリ酢酸三ナトリウム等のキレート剤；安息香酸ナトリウム、パラオキシ安息香酸エステル等の防腐剤；防カビ剤；増粘剤；色素；香料等を配合することができる。 In addition, the liquid detergent composition of the present invention is formulated with components generally blended in detergents other than the above-mentioned nonionic surfactants and amphoteric surfactants as long as the effects of the present invention are not impaired. Can do. For example, esters of fatty acids such as higher fatty acid alkanolamides and fatty acid monoglycerides and polyhydric alcohols; aromatic sulfonates such as p-toluenesulfonate and m-xylenesulfonate as solubilizers; glycerin, ethylene glycol, Polyhydric alcohols such as propylene glycol, sorbitol and 1,3-butylene glycol; lower alcohols such as ethanol and propanol; viscosity modifiers such as polyethylene glycol, propylene glycol and glycerin; lower aryls for the purpose of improving storage stability Hydrotropes such as sulfonic acids and their sodium, potassium or magnesium salts; chelating agents such as citric acid, ethylenediaminetetraacetic acid derivatives, nitrilotriacetic acid trisodium; sodium benzoate, paraoxybenzoate Fungicides; preservatives such as esters thickener; can be blended perfumes; dyes.
［硬質表面用液体洗浄剤組成物］
本発明の硬質表面用液体洗浄剤組成物における各成分の含有は、以下の通りである。
本発明の硬質表面用液体洗浄剤組成物における（ａ）成分と（ｂ）成分との合計は、１〜４０質量％が好ましく、より好ましくは１〜３０質量％、さらに好ましくは１〜２０質量％、最も好ましくは１〜１５質量％である。（ａ）／（ｂ）の質量比は、洗浄力、泡立ち性、及び水への分散性の観点から、６０／４０〜９９．５／０．５が好ましく、より好ましくは７０／３０〜９９．５／０．５、さらに好ましくは９０／１０〜９９／１である。
本発明の硬質表面用液体洗浄剤組成物における（ｃ）成分の含有量は、洗浄力の観点から、５〜５０質量％が好ましく、より好ましくは１０〜４５質量％、さらに好ましくは１０〜４０質量％である。
[Liquid detergent composition for hard surface]
The content of each component in the hard surface liquid detergent composition of the present invention is as follows.
1-40 mass% is preferable, as for the sum total of (a) component and (b) component in the liquid detergent composition for hard surfaces of this invention, More preferably, it is 1-30 mass%, More preferably, it is 1-20 mass. %, Most preferably 1 to 15% by mass. The mass ratio of (a) / (b) is preferably 60/40 to 99.5 / 0.5, more preferably 70/30 to 99, from the viewpoints of detergency, foamability, and dispersibility in water. 0.5 / 0.5, more preferably 90/10 to 99/1.
From the viewpoint of detergency, the content of the component (c) in the hard surface liquid detergent composition of the present invention is preferably 5 to 50% by mass, more preferably 10 to 45% by mass, and still more preferably 10 to 40%. % By mass.
本発明の硬質表面用液体洗浄剤組成物は、上記の成分を溶解した水溶液の形態が使い勝手、及び貯蔵安定性の点から好ましく、水の含有量は、粘度の点から５０〜９９質量％が好ましく、５５〜９０質量％がより好ましく、５５〜８５質量％がさらに好ましい。また、該組成物の２０℃におけるｐＨは７〜１２が好ましく、８〜１１とすることが洗浄力の点から好ましい。ｐＨ調整剤としては、塩酸や硫酸等の無機酸や、クエン酸、コハク酸、リンゴ酸、フマル酸、酒石酸、マロン酸、マレイン酸等の有機酸等の酸剤や、水酸化ナトリウムや水酸化カリウム等のアルカリ剤を好ましく挙げることができる。
このようにして得られた本発明の硬質表面用液体洗浄剤組成物は、食器、各種調理器具の洗浄等の台所用、台所周辺の洗浄等の硬質表面の洗浄に好適に用いることができ、特に食器用の洗浄に好適に用いることができる。
The liquid detergent composition for hard surfaces of the present invention is preferably in the form of an aqueous solution in which the above components are dissolved from the viewpoint of ease of use and storage stability, and the water content is from 50 to 99 mass% from the viewpoint of viscosity. Preferably, 55 to 90 mass% is more preferable, and 55 to 85 mass% is more preferable. Moreover, 7-12 are preferable and, as for pH at 20 degreeC of this composition, it is preferable from the point of a detergency that it is 8-11. Examples of pH adjusters include inorganic acids such as hydrochloric acid and sulfuric acid, acid agents such as citric acid, succinic acid, malic acid, fumaric acid, tartaric acid, malonic acid, and maleic acid, and sodium hydroxide and hydroxide. Preferable examples include alkaline agents such as potassium.
The hard surface liquid detergent composition of the present invention thus obtained can be suitably used for washing hard surfaces such as dishes, kitchens such as washing various cooking utensils, and washing around kitchens, In particular, it can be suitably used for cleaning dishes.
各実施例及び比較例で調整した硬質表面用液体洗浄剤組成物を、以下の方法に従って評価した。ここで、牛脂となたね油とを１／１（質量比）で均一に混ぜ込んだモデル油汚れ１ｇを白色陶器皿（φ２３．５ｃｍ）に均一に塗り広げたものをモデル汚染食器とした。
１．洗浄力の評価
市販の新品スポンジ（素材：ポリウレタンフォーム、商品名：キクロン）を水道水でもみ洗いし、水道水の含有量が１５ｇになるまで絞ったあと、各実施例及び比較例の硬質表面用液体洗浄剤組成物１ｇと水道水２０ｇをしみこませる。モデル汚染食器上で上記スポンジを２〜３回手でもみ泡立たせた後、モデル汚染食器を擦り洗いし、洗浄（食器に付着した色が消えることにより確認）できた皿の枚数を求めた。
２．起泡性の評価
各実施例及び比較例の硬質表面用液体洗浄剤組成物０．４ｇ及びイオン交換水３．６ｇを試験管に仕込んだ。該試験管に、モデル油汚れを０．２ｍｌ添加し（工程Ａ）、次に３０秒振とう（５０回）した後の泡量を目視した（工程Ｂ）。工程Ａ及び工程Ｂを繰り返し、泡が消えた時のモデル油汚れの添加量を測定した。
The liquid detergent composition for hard surfaces prepared in each example and comparative example was evaluated according to the following method. Here, 1 g of model oil stain in which beef tallow oil was uniformly mixed at 1/1 (mass ratio) was uniformly spread on a white ceramic dish (φ23.5 cm) to obtain a model-contaminated tableware.
1. Evaluation of detergency After washing a commercially available new sponge (material: polyurethane foam, trade name: Kikuron) with tap water and squeezing until the tap water content is 15 g, the hard surface of each example and comparative example Soak 1 g of liquid detergent composition and 20 g of tap water. After the sponge was bubbled with the hand 2-3 times on the model-contaminated tableware, the model-contaminated tableware was rubbed and the number of dishes that could be washed (confirmed by the disappearance of the color attached to the tableware) was determined.
2. Evaluation of foamability 0.4 g of liquid detergent compositions for hard surfaces and 3.6 g of ion-exchanged water in each example and comparative example were charged into a test tube. 0.2 ml of model oil stain was added to the test tube (step A), and then the amount of foam after shaking for 30 seconds (50 times) was visually observed (step B). Step A and Step B were repeated, and the amount of model oil stain added when the bubbles disappeared was measured.
合成例１（ＡＯ−１：ラウリルジメチルアミンオキシドの合成）
温度計、攪拌器、冷却管、滴下ロートを備えた１リットルの４つ口フラスコにラウリルジメチルアミン２５８．８ｇとイオン交換水４３９．８ｇとを仕込み、８０℃まで昇温した。その後、４５質量％の過酸化水素水溶液９１．９ｇを１時間かけて滴下した後、９０℃で８時間熟成を行い、３４．６質量％のラウリルジメチルアミンオキシド（（ａ）成分）を得た。
Synthesis Example 1 (AO-1: Synthesis of lauryldimethylamine oxide)
258.8 g of lauryl dimethylamine and 439.8 g of ion-exchanged water were charged into a 1-liter four-necked flask equipped with a thermometer, a stirrer, a condenser, and a dropping funnel, and the temperature was raised to 80 ° C. Thereafter, 91.9 g of a 45% by mass aqueous hydrogen peroxide solution was added dropwise over 1 hour, followed by aging at 90 ° C. for 8 hours to obtain 34.6% by mass lauryldimethylamine oxide (component (a)). .
合成例２（ＡＯ−２：ジラウリルジメチルアミンオキシドの合成）
合成例１と同様の装置に、ジラウリルメチルアミン１７８．８ｇとイオン交換水１７７．１ｇを仕込み８０℃まで昇温した。その後、４５質量％の過酸化水素水溶液４０．３ｇを１．５時間かけて滴下した後に、９０℃で断続的に２７時間熟成を行った。その後、８０℃で４５質量％の過酸化水素水溶液３３．０ｇを０．５時間かけて滴下し、６時間熟成を行った。次いで、上層を分取し、７４．７質量％のジラウリルメチルアミンオキシド（（ｂ）成分）を得た。
Synthesis Example 2 (AO-2: Synthesis of dilauryldimethylamine oxide)
In the same apparatus as in Synthesis Example 1, 178.8 g of dilaurylmethylamine and 177.1 g of ion-exchanged water were charged and heated to 80 ° C. Thereafter, 40.3 g of a 45% by mass aqueous hydrogen peroxide solution was dropped over 1.5 hours, and then aging was performed at 90 ° C. for 27 hours intermittently. Thereafter, 33.0 g of a 45% by mass aqueous hydrogen peroxide solution was added dropwise at 80 ° C. over 0.5 hours, followed by aging for 6 hours. Subsequently, the upper layer was separated to obtain 74.7% by mass of dilaurylmethylamine oxide (component (b)).
合成例３（ＡＯ−３：ラウリルジメチルアミンオキシド及びジラウリルジメチルアミンオキシドの混合物の合成）
合成例１と同様の装置に、ジラウリルメチルアミン５．６質量％を含有したラウリルジメチルアミン２６２．２ｇとイオン交換水４３５．１ｇを仕込み８０℃まで昇温した。その後、４５質量％の過酸化水素水溶液９０．９ｇを５時間かけて滴下した後に、９０℃で１０時間熟成を行い、３２．６質量％のラウリルジメチルアミンオキシド（（ａ）成分）及び２．０質量％のジラウリルメチルアミンオキシド（（ｂ）成分）の混合物を得た。
Synthesis Example 3 (AO-3: Synthesis of a mixture of lauryl dimethylamine oxide and dilauryl dimethylamine oxide)
The same apparatus as in Synthesis Example 1 was charged with 262.2 g of lauryldimethylamine containing 5.6% by mass of dilaurylmethylamine and 435.1 g of ion-exchanged water, and the temperature was raised to 80 ° C. Thereafter, 90.9 g of a 45% by mass aqueous hydrogen peroxide solution was added dropwise over 5 hours, followed by aging at 90 ° C. for 10 hours to obtain 32.6% by mass lauryldimethylamine oxide (component (a)) and 2. A mixture of 0% by mass of dilaurylmethylamine oxide (component (b)) was obtained.
実施例１〜５、比較例１及び２
第１表に示す配合比で調整し、各成分の含有量が第１表に示される通りの硬質表面用液体洗浄剤組成物を得た。該組成物の洗浄力、起泡性についての評価を上記の方法に従い行い、その評価を第１表に示す。
Examples 1-5, Comparative Examples 1 and 2
It adjusted with the compounding ratio shown in Table 1, and obtained the liquid detergent composition for hard surfaces as content of each component was shown by Table 1. The detergency and foamability of the composition were evaluated according to the above methods, and the evaluation is shown in Table 1.
実施例１〜５の硬質表面用液体洗浄剤組成物は、比較例１及び２の組成物と比較して、より多くのモデル油汚れが加えられるまで泡が消えることなく、良好な起泡性を発現した。このことから、本発明の硬質表面用液体洗浄剤組成物は、より多くの汚れを乳化することが可能であり、優れた洗浄性能を有することが示された。 The liquid detergent compositions for hard surfaces of Examples 1 to 5 have good foaming properties as compared with the compositions of Comparative Examples 1 and 2, without foam disappearing until more model oil stains are added. Expressed. From this, it was shown that the liquid detergent composition for hard surfaces of the present invention can emulsify more dirt and has excellent cleaning performance.
実施例６
合成例１で得られた化合物１３．０ｇと、合成例２で得られた化合物０．７ｇとを混合し、（ａ）成分４．５ｇ、（ｂ）成分０．５２ｇ、及び水を含有する混合物を得た。さらに、該混合物に第２表に示される含有量となるように各成分を加えて調整し、硬質表面用液体洗浄剤組成物を得た。該組成物の洗浄力についての評価を上記の方法に従い行い、その評価を第２表に示す。
Example 6
13.0 g of the compound obtained in Synthesis Example 1 and 0.7 g of the compound obtained in Synthesis Example 2 are mixed to contain (a) component 4.5 g, (b) component 0.52 g, and water. A mixture was obtained. Furthermore, each component was added and adjusted so that it might become content shown to Table 2 to this mixture, and the liquid cleaning composition for hard surfaces was obtained. The detergency of the composition was evaluated according to the above method, and the evaluation is shown in Table 2.
比較例３
合成例１で得られた化合物１４．５ｇ（（ａ）成分５．０ｇ）に、第２表に示される含有量となるように各成分を加えて調整し、硬質表面用液体洗浄剤組成物を得た。該組成物の洗浄力についての評価を上記の方法に従い行い、その評価を第２表に示す。
Comparative Example 3
The liquid detergent composition for hard surfaces was prepared by adding each component to 14.5 g of the compound obtained in Synthesis Example 1 (component (a) 5.0 g) so as to have the content shown in Table 2. Got. The detergency of the composition was evaluated according to the above method, and the evaluation is shown in Table 2.
実施例６の硬質表面用液体洗浄剤組成物は、比較例３と比較して、より多くの皿を洗浄することができ、優れた洗浄力を有することが示された。 It was shown that the liquid detergent composition for hard surface of Example 6 can wash more dishes and has excellent detergency compared to Comparative Example 3.
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