JP5148287B2 - Valves, in particular compressor valves - Google Patents

Valves, in particular compressor valves Download PDF

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JP5148287B2
JP5148287B2 JP2007547422A JP2007547422A JP5148287B2 JP 5148287 B2 JP5148287 B2 JP 5148287B2 JP 2007547422 A JP2007547422 A JP 2007547422A JP 2007547422 A JP2007547422 A JP 2007547422A JP 5148287 B2 JP5148287 B2 JP 5148287B2
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spring
obturator
valve
turns
valve seat
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JP2008524510A (en
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シアボーン,マッシモ
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DottIng Mario Cozzani Srl
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DottIng Mario Cozzani Srl
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/10Adaptations or arrangements of distribution members
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/10Adaptations or arrangements of distribution members
    • F04B39/102Adaptations or arrangements of distribution members the members being disc valves
    • F04B39/1033Adaptations or arrangements of distribution members the members being disc valves annular disc valves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/10Adaptations or arrangements of distribution members
    • F04B39/102Adaptations or arrangements of distribution members the members being disc valves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B39/00Component parts, details, or accessories, of pumps or pumping systems specially adapted for elastic fluids, not otherwise provided for in, or of interest apart from, groups F04B25/00 - F04B37/00
    • F04B39/10Adaptations or arrangements of distribution members
    • F04B39/1066Valve plates
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T137/00Fluid handling
    • Y10T137/7722Line condition change responsive valves
    • Y10T137/7837Direct response valves [i.e., check valve type]
    • Y10T137/7904Reciprocating valves
    • Y10T137/7922Spring biased

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Compressor (AREA)
  • Check Valves (AREA)
  • Lift Valve (AREA)
  • Springs (AREA)
  • Sliding Valves (AREA)

Abstract

Valve, in particular for compressors, comprising a seat (1) provided with at least one flow way (111), an obturator member (4) able to obstruct said flow way (111) and movable with respect to said seat in a given direction, and means (5) for resiliently stressing said obturator (4), which are able to force said obturator (4) into a given position and are active in the direction of movement thereof; said resilient stressing means (5) comprise at least one cylindrical helical compression spring (5), characterized by the presence, between all the turns and along the entire working length of the spring (5), of inter-turn apertures.

Description

本発明は、バルブに関し、詳細には往復型の往復圧縮機用バルブに関する。   The present invention relates to a valve, and more particularly to a reciprocating reciprocating compressor valve.

上記の圧縮機において現在使用されている型のバルブは、内部に形成されていて同心状であっても非同心状であってもよい複数の軸流路を有するプレートから成っている、弁座と呼ばれる弁胴を含む、通常は自動弁である。上記の流路の開放及び閉塞は、複数の要素から成っていても単一の要素から成っていてもよい部材である、閉塞具によって実行される。総ての場合に、この閉塞具は、弾性押圧手段、一般的には金属製の円筒つる巻圧縮ばねの作用を受ける。このばねは、内部に貫流路が形成されているプレートから成っている(『対向弁座』と呼ばれる)弁胴内に収容されている。上述のばね筐体は、熱可塑性材料で作られていることが好ましい、ばねの表面と、例えば、対向弁座かまたは閉塞具自体に形成されている筐体の壁の様な外部金属部品との間の金属接触を排除する機能を有する、ばね保護要素をも含んでいてよい。   A valve of the type currently used in the above compressor is a valve seat comprising a plate having a plurality of axial channels formed therein that may be concentric or non-concentric. It is usually an automatic valve, including a valve body called. The opening and closing of the flow path is performed by an obturator that is a member that may be composed of a plurality of elements or a single element. In all cases, the obturator is subjected to the action of an elastic pressing means, typically a metal cylindrical helical compression spring. This spring is housed in a valve body (called an “opposite valve seat”) consisting of a plate having a through-flow passage formed therein. The spring housing described above is preferably made of a thermoplastic material and the surface of the spring and external metal parts such as the wall of the housing formed on the counter valve seat or the obturator itself, for example. A spring protection element may also be included that functions to eliminate metal contact between the two.

上記のばねの大部分は、円筒つる巻線かまたは円錐つる巻線を有する圧縮型である。鋼線で作られている上記のばねは、有効巻回と非有効巻回との合計に等しい総巻回数で形成されている。非有効巻回は隣接巻回と接触しており、更に、上記のばねの良好な軸方向安定性を確保するために上記の巻回は両端において適切に研削されている。   Most of the above springs are of the compression type with cylindrical or conical windings. The springs made of steel wire are formed with a total number of turns equal to the sum of the effective and non-effective turns. The non-effective turns are in contact with adjacent turns, and the turns are properly ground at both ends to ensure good axial stability of the spring.

このばねはバルブの最も危ない部品の一つを構成しており、実際、高い開放/閉塞周波数は、それ自体及びそれと接触している部品に、種々の性質及び種々の程度の摩耗を生じさせる。最新の技術水準によると、ばねの運動によって引き起こされる上記の摩耗の大部分が、分析及び定義されており、以下の通りに分類されてよい。
A)ばねの外表面と筐体空洞の表面との間の摩耗であって、この摩耗はばねと筐体との間に挿入される可塑性要素の導入によって排除される。
B)ばねの基端部と筐体空洞支持表面との間の摩耗であって、この摩耗は可塑性要素の導入によって排除される。
C)ばねの先端部と閉塞具に対する接点の表面との間の摩耗であって、この摩耗は可塑性要素の導入によってかまたは可塑性閉塞具の導入によって排除される。
This spring constitutes one of the most dangerous parts of the valve, and in fact the high open / close frequency causes various properties and varying degrees of wear on itself and the parts in contact therewith. According to the state of the art, most of the above wear caused by spring movement has been analyzed and defined and may be classified as follows.
A) Wear between the outer surface of the spring and the surface of the housing cavity, this wear being eliminated by the introduction of a plastic element inserted between the spring and the housing.
B) Wear between the proximal end of the spring and the housing cavity support surface, this wear being eliminated by the introduction of plastic elements.
C) Wear between the tip of the spring and the surface of the contact to the obturator, which wear is eliminated by the introduction of a plastic element or by the introduction of a plastic obturator.

これらの改善にも拘らず、ばねはバルブの最も危ない部品の一つで且つ故障の原因であり続けている。ますます速い圧縮機の開発と圧縮ガス中の油を排除するための絶えざる努力とが、上述の構成部分の信頼性における問題を増加させた。   Despite these improvements, the spring continues to be one of the most dangerous parts of the valve and the cause of failure. Increasingly faster compressor development and constant efforts to eliminate oil in the compressed gas have increased the reliability problems of the above components.

従って、本発明の目的は、最新の技術水準で知られている圧縮機用バルブと比較してばねの摩耗特性が最適化されていて、圧縮機のもっと長い作動寿命を確保する、圧縮機用バルブを提供することである。   Therefore, the object of the present invention is for compressors, which have optimized spring wear characteristics compared to compressor valves known in the state of the art, ensuring a longer operating life of the compressor. It is to provide a valve.

従って、本発明は、少なくとも一つの流路を備える弁座と、前記流路を閉塞することができ且つ前記弁座に対して所定方向へ動くことができる閉塞具部材と、この閉塞具を弾性的に押圧する手段であってこの閉塞具を所定位置へ押しやることができ且つこの閉塞具の運動の方向へ作動する手段とを具備し、この弾性押圧手段が少なくとも一つの円筒つる巻圧縮ばねを含んでいるバルブ、詳細には圧縮機用バルブであって、前記ばねの総ての巻回同士の間の且つ全作動長に沿う巻回間隙間の存在を特徴とするバルブに関する。   Accordingly, the present invention provides a valve seat having at least one flow path, an obturator member capable of closing the flow path and moving in a predetermined direction with respect to the valve seat, and elastically disposing the obturator. And a means for pushing the obturator to a predetermined position and operating in a direction of movement of the obturator, the elastic pushing means comprising at least one cylindrical helical compression spring. In particular, it relates to a valve for a compressor, characterized by the presence of a winding gap between all turns of the spring and along the entire working length.

本発明によるバルブの更なる特徴によると、前記円筒つる巻圧縮ばねは総ての巻回同士の間で且つ全作動長に亙って巻回間隙間を備えており、開放円錐終端巻回であることが好ましい末端巻回とすぐに隣接している巻回との直径の差が、前記ばねを形成している金属線の断面の少なくとも約1.5倍であり2倍であることが好ましい。前記ばねのピッチは可変であることができる。 According to a further feature of the valve according to the invention, the cylindrical helical compression spring has a winding gap between all turns and over the entire working length, Preferably, the difference in diameter between the end turns and the immediately adjacent turns is at least about 1.5 times and twice the cross section of the metal wire forming the spring. . The pitch of the springs can be variable.

好ましい実施形態では、両方の末端巻回の寸法が、すぐに隣接している巻回の寸法よりも小さい。本発明によるバルブは、可塑性材料で作られていることが好ましく且つばねの摩耗を更に保護するためにこのばねを収容している筐体内に配置されている、保護部材を備えていることが好都合である。   In a preferred embodiment, the dimensions of both end turns are smaller than the dimensions of the immediately adjacent turns. The valve according to the invention preferably comprises a protective member, preferably made of a plastic material and arranged in a housing containing the spring to further protect the spring from wear. It is.

本発明による装置の更なる利点及び独特の特徴は、非限定的例としてのみ提供されているこの装置の実施形態の下記の記載と添付図面の参照とから明らかになる。   Further advantages and unique features of the device according to the invention will become apparent from the following description of an embodiment of this device which is provided only as a non-limiting example and with reference to the accompanying drawings.

図1は本発明によるバルブの実施形態を示しており、流体の流路として機能する軸方向であり偏心している複数の通り穴111を備えており且つボルト6のねじ山付き端部306が係合している中央の軸方向のねじ山付きの通り穴201を有するプレート101を含む、上記のバルブの弁座を、1が示している。プレート101には、通り穴111と連通している溝121も形成されている。ボルト6の中央部は、そこに取り付けられている、ブッシュ406と、中央の軸方向の通り穴302を備える対向弁座2とをも有しており、弁座1、ブッシュ406及び対向弁座2は、ボルト6のねじ山付き端部206にねじ止めされているナット106によって互いに固定されている。軸方向の通りダクト102が対向弁座2に形成されている。   FIG. 1 shows an embodiment of a valve according to the invention, comprising a plurality of axially and eccentric through holes 111 functioning as a fluid flow path and engaging a threaded end 306 of a bolt 6. 1 designates the valve seat of the above valve, which includes a plate 101 having a mating central axial threaded through hole 201. A groove 121 communicating with the through hole 111 is also formed in the plate 101. The central part of the bolt 6 also has a bush 406 attached to it and a counter valve seat 2 with a central axial passage hole 302, the valve seat 1, the bush 406 and the counter valve seat. 2 are secured together by a nut 106 which is screwed to the threaded end 206 of the bolt 6. A duct 102 is formed in the counter valve seat 2 in the axial direction.

閉塞具4は、弁座1と対向弁座2との間に配置されており、ブッシュ406と同軸且つ同心であり、閉塞具の中央軸穴304によってブッシュ406に沿って軸方向へ摺動可能である。閉塞具には、弁座1のプレート101の軸穴111に対して軸方向へずれている偏心開口104が形成されているが、これらの偏心開口は対向弁座2に形成されているダクト102と整列している。プレート101に形成されている止まり穴301内へ挿入されており閉塞具4の穴204を貫通して対向弁座の止まり穴202内へ入り込んでいるピン401によって、弁座1と対向弁座2とが更に互いに結合されている。   The obturator 4 is disposed between the valve seat 1 and the counter valve seat 2, is coaxial and concentric with the bush 406, and can slide in the axial direction along the bush 406 by the central shaft hole 304 of the obturator. It is. The obturator is formed with eccentric openings 104 that are offset in the axial direction with respect to the shaft hole 111 of the plate 101 of the valve seat 1. These eccentric openings are formed in the duct 102 formed in the counter valve seat 2. Are aligned with. The valve seat 1 and the counter valve seat 2 are inserted into the blind hole 301 formed in the plate 101 and penetrate the hole 204 of the obturator 4 and enter the stop hole 202 of the counter valve seat. Are further coupled to each other.

対向弁座2は内部に円筒つる巻圧縮ばね5が配置されている円筒筐体402をも備えており、末端巻回105の直径はそれらにすぐに隣接している巻回205の直径よりも小さい。インサート412、422が筐体402内に配置されており、これらのインサートは熱可塑性材料等で作られていることが好ましくばね5と関連筐体402との金属接触を排除する機能を有している。弁座1のプレート101の穴111を貫流する流体流の作用の結果として図中では開放状態に示されている閉塞具4の表面を、インサート412の端壁がばね5の作用のために押す。この図中のばね5は筐体402内で圧縮状態に示されている。   The counter valve seat 2 also includes a cylindrical housing 402 having a cylindrical helical compression spring 5 disposed therein, and the diameter of the end turn 105 is greater than the diameter of the turn 205 immediately adjacent thereto. small. The inserts 412 and 422 are disposed in the housing 402, and these inserts are preferably made of a thermoplastic material or the like, and have a function of eliminating metal contact between the spring 5 and the related housing 402. Yes. As a result of the action of the fluid flow through the hole 111 of the plate 101 of the valve seat 1, the end wall of the insert 412 pushes against the surface of the obturator 4, which is shown open in the figure, due to the action of the spring 5. . The spring 5 in this figure is shown in a compressed state within the housing 402.

図2は図1によるバルブの断面細部を示しており、同じ部分は同じ符号で示されている。このバルブは、この図2では、流体が流れる穴111と図1で明らかな様に連通しているプレート101の溝121に接触している閉塞具4による閉塞状態で示されている。ばね5は、この図2では、図1中に示されている状態に比べて拡大されている平衡状態で示されている。   FIG. 2 shows a cross-sectional detail of the valve according to FIG. In FIG. 2, this valve is shown in the closed state by the obturator 4 in contact with the groove 111 of the plate 101 communicating with the hole 111 through which the fluid flows as apparent in FIG. The spring 5 is shown in this FIG. 2 in an equilibrium state which is enlarged compared to the state shown in FIG.

図3はバルブの閉塞具4に作用するばね5の平面図を示しており、明らかな様に、図中に見える末端巻回105の直径はそれに隣接している巻回205の直径よりも小さい。一方、図4A、4Bは、巻回間隙間の存在が、開放円錐末端巻回105とすぐに隣接している巻回205との直径の相違と相まって、有効作動区間に亙って総ての巻回の非干渉を生じさせる、という事実を強調している。   FIG. 3 shows a plan view of the spring 5 acting on the valve obturator 4 and, as can be seen, the diameter of the end turn 105 visible in the figure is smaller than the diameter of the adjacent turn 205. . On the other hand, FIGS. 4A and 4B show that the presence of the winding gap is coupled with the difference in diameter between the open conical end winding 105 and the immediately adjacent winding 205, all over the effective operating section. Emphasizes the fact that winding causes non-interference.

本発明によるバルブの作動原理は下記の説明で明らかになる。図1に示されている型のバルブは、通常は圧縮機中で使用されて、断然高い開放及び閉塞周波数で作動する。その結果、閉塞具4に作用する弾性押圧手段はかなり摩耗し、このことは対処できないほどにバルブの適切な作動に悪影響を及ぼす。通常の円筒つる巻ばねよりもかなり少ない程度にまでしか破損しないことを確実にするための特徴が、ばね5にある。問題になっているばねの摩耗の主要な原因の一つは、上記の末端巻回が、互いに平行でばねの軸に垂直であるがつる巻線の広がる平面つまりばねのその他の巻回が存在する平面に対して傾斜している平面内に存在するという事実と関連している。この異なる傾斜は、実際、ばねの負荷の不十分な分布を生じさせてばねを摩耗し易くさせる。   The principle of operation of the valve according to the invention will become apparent from the following description. A valve of the type shown in FIG. 1 is typically used in a compressor and operates at a significantly higher open and closed frequency. As a result, the elastic pressing means acting on the obturator 4 are considerably worn, which adversely affects the proper operation of the valve, which cannot be dealt with. The feature of the spring 5 is to ensure that it breaks to a much lesser extent than a normal cylindrical helical spring. One of the main causes of spring wear in question is that the above end turns are parallel to each other and perpendicular to the axis of the spring, but there are spreading planes of the windings, ie other turns of the spring Associated with the fact that it lies in a plane that is inclined with respect to the plane to be This different slope actually creates an inadequate distribution of the spring load and makes the spring susceptible to wear.

この場合、この摩耗効果は、巻回間隙間の存在と、上記の末端巻回105のすぐに隣接している巻回と比較した直径の減少とのために、非常に減じられて殆ど完全に排除されさえする。図4A、4Bから分かる様に、このばねの特徴、つまり、巻回間隙間の存在と、上記の末端巻回同士の間における直径の相違とが、上記のばねの圧縮中に、全有効作動区間に亙って総ての巻回同士の間に干渉が存在しないことを確実にし(図4B参照)、その結果、このばねの巻回は摩耗し難く、このばねは初期形態に最も近い様子で機能し易く、その作動寿命は著しく改善される。   In this case, this wear effect is greatly reduced and almost completely due to the presence between the winding gaps and the reduced diameter compared to the immediately adjacent winding of the end winding 105 described above. Even excluded. As can be seen from FIGS. 4A and 4B, the characteristics of this spring, namely the presence between the winding gaps and the difference in diameter between the end turns, are fully effective during compression of the spring. Ensure that there is no interference between all turns over the section (see FIG. 4B), so that the windings of this spring are less likely to wear and this spring is closest to the initial configuration And its operating life is significantly improved.

熱可塑性インサート412、422を筐体402内へ挿入することによって、ばね5と対向弁座2の壁及び/または閉塞具4との金属接触が更に排除されることが好都合である。   Advantageously, by inserting the thermoplastic inserts 412, 422 into the housing 402, metal contact between the spring 5 and the wall of the counter valve seat 2 and / or the obturator 4 is further eliminated.

この様に設計されているバルブは、一方では高周波数でも正確な作動と、他方では弾性押圧手段従ってバルブ自体の平均寿命がかなり延長されることとを、確実にすることができる。   A valve designed in this way can ensure correct operation on the one hand even at high frequencies and, on the other hand, that the elastic pressing means and thus the average life of the valve itself is considerably extended.

本発明によるバルブの実施形態の断面図である。1 is a cross-sectional view of an embodiment of a valve according to the present invention. 別の作動形態にある図1によるバルブの断面細部である。2 shows a cross-sectional detail of the valve according to FIG. 1 in another operating configuration. 本発明によるバルブ中で使用されているばねの平面図である。FIG. 2 is a plan view of a spring used in a valve according to the present invention. 休止状態にあるばねの断面図である。It is sectional drawing of the spring in a resting state. 圧縮状態にあるばねの断面図である。It is sectional drawing of the spring in a compression state.

Claims (3)

少なくとも一つの流路(111)を備える弁座(1)と、前記流路(111)を閉塞することができ且つ前記弁座に対して所定方向へ動くことができる閉塞具部材(4)と、この閉塞具(4)を弾性的に押圧する手段(5)であってこの閉塞具(4)を所定位置へ押しやることができ且つこの閉塞具の運動の方向へ作動する手段とを具備し、この弾性押圧手段(5)が少なくとも一つのつる巻圧縮ばね(5)を含んでいる往復圧縮機用バルブにおいて、
休止状態と圧縮状態との両方において、前記ばね(5)の総ての巻回同士の間の、且つ、前記ばねの伸縮方向とは垂直な方向から前記ばねを見たときに前記ばねの全作動長に沿って見える巻回間隙間の存在を特徴とし、
前記ばね(5)の両方の末端巻回(105)が、これらの末端巻回にすぐ隣接している巻回(205)の直径よりも小さいことを更に特徴とし、
前記ばね(5)の両方の末端巻回(105)とすぐに隣接している巻回(205)との直径の差が、前記ばねを形成している金属線の断面の少なくとも1.5倍であるという前記両方の末端巻回のテーパ比変化を更に特徴とする、バルブ。
A valve seat (1) comprising at least one flow path (111), and an obturator member (4) capable of closing the flow path (111) and moving in a predetermined direction relative to the valve seat; Means (5) for elastically pressing the obturator (4), which can push the obturator (4) to a predetermined position and operate in the direction of movement of the obturator. In the reciprocating compressor valve, the elastic pressing means (5) includes at least one helical compression spring (5).
In both the resting state and the compressed state, when the spring is viewed from the direction between all the turns of the spring (5) and perpendicular to the direction of expansion and contraction of the spring, Characterized by the presence of winding gaps visible along the working length,
Further characterized in that both end turns (105) of the spring (5) are smaller than the diameter of the turns (205) immediately adjacent to these end turns;
The difference in diameter between both end turns (105) of the spring (5) and the immediately adjacent turn (205) is at least 1.5 times the cross section of the metal wire forming the spring. A valve further characterized by a taper ratio change of both said end turns to be.
前記末端巻回(105)とこれらにすぐに隣接している前記巻回(205)との直径の差が、前記ばねを形成している金属線の断面の2倍である、請求項1に記載のバルブ。  The diameter difference between the end turns (105) and the turns (205) immediately adjacent thereto is twice the cross section of the metal wire forming the spring. The valve described. 円錐状に形成されている前記末端巻回が研削されている、請求項1または2に記載のバルブ。  The valve according to claim 1 or 2, wherein the end winding formed in a conical shape is ground.
JP2007547422A 2004-12-22 2005-11-18 Valves, in particular compressor valves Active JP5148287B2 (en)

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ITGE20040116 ITGE20040116A1 (en) 2004-12-22 2004-12-22 VALVE, IN PARTICULAR FOR COMPRESSORS.
PCT/EP2005/056083 WO2006067011A1 (en) 2004-12-22 2005-11-18 Valve, in particular for compressors

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KR20070085826A (en) 2007-08-27
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DE602005020186D1 (en) 2010-05-06
ATE462080T1 (en) 2010-04-15
CN101084375A (en) 2007-12-05
US20090126807A1 (en) 2009-05-21
EP1831564A1 (en) 2007-09-12
BRPI0519219B1 (en) 2019-08-06
WO2006067011A1 (en) 2006-06-29
KR101258303B1 (en) 2013-04-25
BRPI0519219A2 (en) 2009-01-06
ES2342547T3 (en) 2010-07-08
JP2008524510A (en) 2008-07-10

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