JP5131579B2 - Textile product storage formulation and textile product storage method - Google Patents

Description

The present invention relates to a textile product storage formulation and a textile product storage method, and more particularly to a clothing storage formulation and a clothing storage method using the same.
More specifically, for textile products storage agents such as insecticides and bactericides, which are arranged when storing and storing textile products such as clothes, clothes, drawers, closets, clothes stored in plastic clothes cases, etc. The present invention relates to a textile product storage formulation using a textile product discoloration preventing agent for preventing discoloration of textile products such as clothing, and a textile product storage method using the same.

Textile products typified by clothes are stored in clothes chests, drawers, closets, plastic clothes cases and the like after being worn or washed, and are stored and stored for a long period of time to be replaced every season.
During storage and storage, the surface may change color.

The cause of such discoloration is oxidation due to corrosive gas due to dirt or the like that could not be removed by washing, reaction of an antioxidant contained in the storage container attached to the textile product, and the corrosive gas .
In particular, it is recognized that the color is remarkably changed at a part that is in good contact with the skin such as a heel and a sleeve and a part that is in good contact with the storage container.
With regard to such discoloration, particularly discoloration of clothes stored or stored in clothes chests, drawers, closets, plastic clothes cases, etc., countermeasures are strongly demanded as the standard of living has improved in recent years. It is coming.

On the other hand, methods for preventing discoloration of metal parts such as buttons, metal rings and zippers as textile products and their accessories have been studied.
For example, JP-A-10-273878 (Patent Document 1) represents 2,6-di-t-butyl-P-cresol (hereinafter abbreviated as BHT) contained in a packaging material or the like. It has been shown that packaged textiles turn yellow due to phenolic antioxidants and vanillin present in cardboard.

The cause is that BHT in the packaging material sublimes over time and adheres to the fiber product, and this BHT is denatured by nitration with nitric oxide gas (NO _x ), etc., causing the fiber product to turn yellow. As a countermeasure, it has been shown that a textile product is treated with a non-volatile acid such as malic acid or citric acid or an ammonium salt thereof.

Furthermore, the terms are metal parts, JP at 2004-91918 (Patent Document 2), for example, silver, copper, nickel, metal ornaments such as chromium, sulfur oxides present in the atmosphere In order to prevent discoloration by sulfur-containing gas such as (SO _X ), mercaptan, hydrogen sulfide, etc., it contains a fiber having a crosslinked structure and a carboxyl group in the molecule, and at least a part of the carboxyl group is an alkali A metal discoloration-preventing material that is present as a salt of a metal, an alkaline earth metal, or ammonia, and in which fine particles of a metal and / or metal compound that are hardly soluble are dispersed in water having reactivity with a sulfur-containing compound. Proposed.

  Apart from these, textile product storage formulations such as insect repellents, insecticides, fragrances, antibacterial agents, antifungal agents, repellents or disinfectants are used depending on the purpose when storing and preserving textile products such as clothing. JP-A-11-332449 (Patent Document 3) proposes a combination of an insect repellent and a deodorizing and deodorizing agent as follows.

That is, in the invention described in Patent Document 3, a sheet-like base material is loaded with a deodorizing and deodorizing agent composed of one or more selected from activated carbon, silica gel, activated alumina, zeolite, and ceramic, and a pyrethroid insecticide. This is an insect repellent deodorizing sheet.
JP-A-10-273878 (claims, paragraphs 0002 to 0004) JP 2004-91918 A (claims, paragraphs 0002 to 0003) JP-A-11-332449 (Claims, paragraph 0020)

  The inventors have been widely used in the past especially for preventing discoloration of textile products, in particular, preventing discoloration of textile products stored or stored in clothes chests, drawers, closets, plastic clothes cases, etc. The study was carried out with the objective of preventing the discoloration of the textile product by giving the textile product storage product an anti-discoloration effect.

  At that time, after the textile product is worn or washed, it is stored inside a clothes chiffon, drawer, closet, plastic clothes case, etc., and the textile product is discolored during storage and storage after changing every season. We focused on the fact that it was.

That is, such discoloration of textile products is oxidized by contact of sebum dirt and sweat secretions that could not be removed by washing with nitrogen gas, sulfur oxide, hydrogen sulfide, etc., which are corrosive gases. It happens that the textile product changes color during storage.
In addition, plastic clothing cases and packaging materials may contain a phenolic antioxidant as a stabilizer during production. If textile products are stored in the clothing case, the phenolic antioxidant will be removed. Sublimation fills the clothing case, adheres to the textile, contacts with corrosive gases contained in the air, and discolors the textile.

The nitrogen oxides are present not only in factory exhaust gases and automobile exhaust gases, but also in rooms where clothes dances, drawers, closets, plastic costume cases, etc. are arranged.
Indoors, nitrogen oxides are generated by the use of oil stoves, oil fan heaters, gas water heaters, etc., whereas the environmental standard concentration of NO ₂ is 0.04 to 0.06 ppm or less on an annual average value, In the room in which the oil stove is being used, the investigation was conducted by paying attention to the fact that the concentration of NO ₂ is said to be 0.7 to 2.3 ppm.

As a result, the inventors have found that corrosion caused by nitrogen oxides, sulfur oxides, hydrogen sulfide gas, etc. existing in textile product storage spaces such as clothes dances, drawers, closets, plastic clothing cases, etc. due to discoloration of textile products. The present inventors have completed a fiber product storage preparation and a method for preventing discoloration of a fiber product, which can effectively prevent discoloration of the fiber product by using a chemical that removes or decomposes the property gas in combination with a fabric product storage agent.

That is, the invention according to claim 1 of the present invention is
Insect repellent or insecticide, fragrance, antimicrobial agents, antifungal, repellents, and the fiber product storage agent made of one or more selected from the disinfectant, copper ions, iron ions, zinc ions, One or more metal ions selected from nickel ions are introduced by ion exchange, and a textile product discoloration prevention agent comprising zeolite having a pore size in the range of 3 to 10 angstroms ,
A textile product storage product characterized by being divided and held in one container .

The invention according to claim 2 of the present invention is
In the textile product storage formulation according to claim 1,
The container is
The textile product storage chemical is held inside, and the textile product discoloration prevention medicine is carried outside by printing or coating .

The invention according to claim 3 of the present invention is
In the textile product storage formulation according to claim 2 ,
The printing is
This is characterized by PAD printing.

The invention according to claim 4 of the present invention is
In the textile product storage formulation according to claim 1,
The textile product storage agent is:
It is a room temperature volatile chemical.

The invention according to claim 5 of the present invention is
In the textile product storage formulation according to claim 4 ,
The room temperature volatile chemical is:
It is a pyrethroid type insect repellent.

Furthermore, the invention according to claim 6 of the present invention is
A textile product storage method, wherein the textile product storage formulation according to any one of claims 1 to 5 is used in a textile product storage space.

The textile product storage formulation of the present invention is a specific textile product storage agent, and one or more metal ions selected from copper ions, iron ions, zinc ions, nickel ions are introduced by ion exchange, Adsorbing ability or resolution and adsorbing ability of corrosive gas by using together with a chemical for preventing discoloration of textile products made of zeolite whose pore size is in the range of 3 to 10 angstroms and separating them into one container Therefore, it effectively prevents discoloration during textiles such as clothing, especially during storage.

In particular, since zeolite having a pore size of 3 to 10 angstroms is used as a chemical for preventing discoloration of textile products, the molecular sieve that can selectively adsorb molecules smaller than the pore size possessed by the zeolite, A corrosive gas having a small molecular weight can be selectively adsorbed.

Furthermore , textile product storage chemicals such as volatile chemicals with a large molecular weight are not adsorbed on metal ion exchange zeolite, and metal ion exchange zeolite contains corrosive gases such as nitrogen oxides, sulfur oxides, and hydrogen sulfide. It can be selectively adsorbed.

As a result , the chemicals for storing textile products can be efficiently volatilized, and since there is no adsorption of chemicals for storing textile products, including during the distribution of pharmaceutical products, these losses can be eliminated, and the discoloration of textile products can be eliminated. The combination of the preventive agent and the textile product storage agent is made efficient, and a highly practical textile product storage formulation can be prepared.

Furthermore , the textile product discoloration prevention agent and the textile product storage agent are separated and held in a single container, so that corrosive gas can be removed from the textile product storage space and at the same time prevent discoloration of clothing. In addition, the function as a textile storage agent is sufficiently exhibited.

Furthermore, where the fiber product storage formulation of the present invention, metal components are accessories textile products, for example, discoloration, such as buttons or zippers also effectively prevented, which may be present in the phenolic antioxidant In this case, the effect is exhibited.

Textile discoloration preventing agent comprising a specific zeolite in the present invention, nitrogen oxides, corrosive gases such as sulfur oxides or hydrogen sulfide gas, intended to have a selective adsorption or degrade the ability of the garment Discoloration can be prevented.

Zeolite is a compound mainly composed of hydrous aluminosilicate and includes natural zeolite and synthetic zeolite.
All of them have ion exchange ability, and the crystal structure does not change even when dehydrated. After dehydration, molecular-sized pores are obtained, and they have a large adsorption ability.
The general formula is as follows.

(Chemical formula 1)
_{(L 2, M) O ·} Al 2 O 3 · xSiO 2 · yH 2 O

In the above formula, L represents an alkali metal, M represents an alkaline earth metal, x represents a number of 2 or more, and y is a number determined by the type and state of the zeolite.

The basic structure of the zeolite crystal is a tetrahedron of SiO ₄ and its substituted AlO ₄ , which share an apex oxygen atom with each other to form a crystal structure developed in a three-dimensional direction.
Zeolites used in this invention, rather good either natural or synthetic, if I have pores capable of adsorbing corrosive gases, can be used with any structure zeolite.

As natural zeolite, for example, clinoptilolite type, mordenite type, chabazite type and the like are generally known.
As artificially synthesized synthetic zeolite, A type, faujasite type (X type, Y type), L type, mordenite type, ZSM-5 type and the like are industrially produced.

In the synthetic zeolites, it exists a metal ion exchanged zeolite and the metal-loaded zeolite.
Certain metal ion exchange zeolite can selectively adsorb corrosive gases such as nitrogen oxides, sulfur oxides, hydrogen sulfide, etc. It can be selectively adsorbed and used in the present invention.

  Furthermore, as a metal ion exchange zeolite, in order to efficiently adsorb corrosive gases such as nitrogen oxides, sulfur oxides, hydrogen sulfide, etc., and not to absorb textile storage chemicals, Those having a pore diameter in the range of 3 to 10 angstroms are essential.

The metal ion exchange zeolite used in the present invention is prepared by ion exchange of metal ions selected from copper ions, iron ions, zinc ions and nickel ions among various metal ions.
These metal ions may be used alone or in combination of two or more metal ions and a plurality of metal ions exchanged zeolite or a mixture.

Among the synthetic zeolites, there is a so-called high silica zeolite.
This high silica zeolite is chemically a crystal of an aluminosilicate metal salt, like ordinary zeolite.

However, the ratio of silica and alumina in the crystal is different from that of ordinary zeolite, and the ratio of silica is larger than that of alumina.
Furthermore, since oxygen atoms in the silica structure have almost no basicity and do not participate in the formation of hydrogen bonds, (Si—O—Si) bonds present on the zeolite surface exhibit water repellency and do not adsorb water molecules.
Therefore, as the ratio of silica to alumina increases, the water repellency increases, so in high humidity environments, high silica zeolite can be used to reduce corrosive gases such as nitrogen oxides, sulfur oxides, and hydrogen sulfide. It becomes possible to adsorb more selectively.

A commonly used method can be used for the metal ion exchange of zeolite.
For example, a method of immersing zeolite in a metal compound solution can be used.

The textile product storage formulation of the present invention is used by being stored or supported in a container.
Such a container is not particularly limited, and plastic molded containers, paper containers, wooden tools, ceramics, bag-like objects, plate-like objects, and the like can be used.

As a method for holding the textile product discoloration preventing agent in a container, it is possible to disperse or liquefy in combination with various solvents and binders.
Furthermore, it is possible to arbitrarily combine methods such as printing, coating, bonding, spreading, hot pressing, sandwiching, kneading into a container , and materials such as solvent-based adhesives and emulsion-based adhesives.
At that time, printing using a binder, in particular, it is possible to print not only on flat surfaces but also on secondary and tertiary curved surfaces, and because it is possible to print detailed designs, it is necessary to hold on the container surface by PAD printing. preferable.

The textile product storage agent is widely used, for example, one or more agents selected from insecticides or insecticides, fragrances, deodorants, antibacterial agents, antifungal agents, and repellents. Is used.

Examples of the repellent or insecticide, for example, may be selected from a variety of pest control agent vaporize at normal temperature include, components, etc. that can control pests by components or contacts to volatilize at heating can be used.

As such a pest control agent, any of various drugs conventionally used for the purpose of insecticide, repellent, insect control and the like can be used.
Examples include organophosphorus, carbamate, pyrethroid, and amide-type insecticides, insect growth regulators, and the like, which can be used alone or in combination of two or more.
Specific examples of the pest control agents that can be used are shown below with general names or trade names.

As the pyrethroid insecticide, for example,
Metofluthrin, transfluthrin, profluthrin, allethrin, dl · d-T80-alleslin, d · d-T80-alleslin, bioareslin, phthalthrin, resmethrin, d-T80-flamethrin, permethrin, phenothrin, fenvalerate, esfenvalerate, d · d-T80-praretrin, tefluthrin, cypermethrin, ciphenothrin, fenpropatorin, fenfluthrin, empentrin, terrareslin, neopinamine forte, etofenprox, imiprotorin, etc.
Is mentioned.

  Among these, metofluthrin, transfluthrin, profluthrin, and empentrin are preferable because they have an excellent insecticidal effect, low contamination, excellent medicinal durability, and excellent safety.

The resmethrin, permethrin, phenothrin, etc. can be used as a component that can control the contact.

Examples of the organophosphorus insecticides, for example, common name DDVP, diazinon, Sumithion include Vitex like.
Further, examples of the carbamate insecticide include propoxer and carbaryl.

  Various additives such as a commonly used efficacy enhancer, volatilization rate improver, and container migration inhibitor can be arbitrarily added to these pest control agents.

As the enhancer, for example, it can be exemplified piperonyl butoxide, N- propyl Lee transchromosomic, MGK-264, Sainepirin 222, the Sainepirin 500, Risen 384, IBTA, S421 and the like.

As the volatilization rate improver, for example, can be cited Hue phenethyl isothiocyanate, a Haimitsukusu dimethyl like.

Examples of the container migration inhibitor include triethyl citrate, triethyl phosphate, triisobutyl phosphate, dimethyl phthalate, diethyl phthalate, and triethyl citrate.

  Other pest control agents include plant essential oils, terpenes, sublimable naphthalene, camphor or paradichlorobenzene.

As the fragrance, for example,
Jacha, Ryunobu, Abies oil, Almond oil, Pagele oil, Perch oil, Kayabuchi oil, Citronella oil, Eucalyptus oil, Fennel oil, Garlic oil, Ginger oil, Grapefruit oil, Lemon oil, Lemongrass oil, Nutmeg oil, Natural fragrances such as peppermint oil, orange oil, turpentine oil, sage oil, pinene, limonene, linalool, geraniol, citronellal, borneol, benzyl alcohol, anise alcohol, anethole, eugenol, aldehyde, citral, citronellal, vanillin, carvone, ketone, Menton, acetophenone, coumarin, cineol, ethyl acetate, octyl acetate, butyl propionate, isopropyl isobutyrate, allyl caproate, ethyl benzoate, methyl cinnamate, methyl salicylate, etc. The postal and the like.

As the deodorant, for example,
Lauryl methacrylate, geranyl crotonate, acetophenone myristate, paramethylacetophenone benzaldehyde, benzyl acetate, benzyl propionate, amylcinnamic aldehyde, anisic aldehyde, diphenyl oxide, methyl benzoate, ethyl benzoate, methyl phenylacetate, ethyl phenylacetate , Neoline, safrole, citronella oil, lemongrass oil and the like.

As the antibacterial and antifungal agents, for example,
Irgasan DP300, dawsyl S-13, benzalkonium chloride, benzethonium chloride, hinokitiol, preventol A5, preventol A4, preventol A3, thiabendazole (TBZ), dioxin, O-phenylphenol, isopropylmethylphenol, 2-chloro- 4-phenylphenol, thymol, phenoxyethanol and the like can be mentioned.

As a specific example of the repellent,
N, N-diethyl-m-toluamide (diet), dimethyl phthalate, dibutyl phthalate, 2-ethyl-1,3-hexanediol, di-n-propylisocincomeronate, p-dichlorobenzene, di-n-butyl Examples include succinate, caran-3,4-diol, 1-methylpropyl-2- (2-hydroxyethyl) -1-piperidinecarboxylate and the like.

  These textile storage chemicals may be used alone or in combination, and the amount (concentration) used is appropriately determined in consideration of the type and volatility of the chemical so as to achieve a desired effect. That's fine.

In addition, before Symbol drug agents, for example,
3,5-di-t-butyl-4-hydroxytoluene, 3-t-butyl-4-hydroxyanisole, mercaptobenzimidazole, dilauryl-thio-di-propionate, 2,2′-methylene-bis- (6- t-butyl-4-methylphenol), 4,4′-methylene-bis- (2,6-di-t-butylphenol), 4,4′-thio-bis- (6-t-butyl-3-methyl) Phenol), phenyl-β-naphthylamine, 2-t-butyl-4-methoxyphenol, stearyl-β- (3,5-di-t-butyl-4-hydroxyphenyl) propionate, α-tocopherol, ascorbic acid, erythorbine You may mix | blend stabilizers, such as an acid, suitably.

As a solvent for preparing the drug in a solution form, for example,
Hydrocarbons such as water, naphthene, white kerosene, paraffin, alcohols such as glycerin, propylene glycol, methanol, isopropanol, 1-octanol and 1-dodecanol, ketones such as acetone and acetophenone, dihexyl ether, diethylene glycol diethyl ether, etc. Ethers, esters such as dioctyl adipate, diethyl malonate and diethyl phthalate, xylene, chlorocene, chloroform, silicone oil and the like.

The medicine for preventing discoloration of textile products and the medicine for storing textile products according to the present invention are stored separately in different storage portions of one container 1 shown in FIGS. 1 and 2 in order to avoid contact or adsorption and decomposition of the medicine . Is done .

Specifically, the nonwoven fabric 3 carrying the textile storage agent is stored and held between the upper and lower sheets constituting the container 1, and the textile discoloration prevention medicine is placed on the surface of the upper sheet 1. By carrying the non-woven fabric 2 carrying the color, the effect of preventing discoloration and the effect of the drug can be sufficiently exhibited.
As the pre-Symbol containers, plastic molded containers, paper containers, bag-like objects and the like.

  Regarding the method for supporting the textile product discoloration prevention agent on the surface, particularly on the surface thereof, the medicine may be used as it is, but it can be arbitrarily combined with various resins, binders, solvents, etc., and printing using various plates , Impregnation, dipping, spray coating, dripping, kneading into a container material and the like, but there is no particular limitation.

  For example, in the case of impregnation or immersion, the drug may be used as it is, or dissolved in an appropriate solvent and applied to the surface of the container, etc., and held on the surface of the container, or impregnated inside the carrier and dried. .

Printing with the binder, in particular, the plane of course, secondary, that can also be printed on the tertiary curved surface, and since it is possible that the detailed pattern is printed, it is preferable to be held on the vessel surface by PAD printing.

Further, the substrate for holding the textile product storage agent is not particularly limited.
For example, paper, non-woven fabric, woven fabric, wood, pulp, inorganic polymer material, inorganic porous material (silicate, silica, etc.), organic polymer material (cellulose, polyethylene, polypropylene, polyvinyl alcohol, etc.), gelled material (Agar, carrageenan, gelatin, etc.), resins and the like can be mentioned, and these can be used alone or in combination.

The form of the substrate is not particularly limited, and any form can be selected.
Examples include porous particles, woven fabrics, non-woven fabrics, sheets, mats and the like having spherical, square, and flat shapes.

  The textile product storage formulation of the present invention can be applied to a place for storing clothes such as clothes dance, drawers, closets, plastic costume cases, organizing dances, and discolors clothes by adsorbing or decomposing corrosive gas. It can be protected from.

In the present invention, the textile product is intended to cover all textile products stored in clothes dances, drawers, closets, plastic costume cases, organizing dances, etc., such as clothes and socks, clothes, handkerchiefs, towels, etc. it can.

Next, the textile product storage formulation and the textile product storage method of the present invention will be described in more detail based on Examples , but the present invention is not limited to these Examples.
As shown in FIGS. 1 and 2, a plastic container 1 in which various nonwoven fabric storage agents are impregnated in a nonwoven fabric 3, and the textile product discoloration prevention agent 2 is supported on the container surface with a binder by the PAD printing method. Covered with.
As shown in Table 1, preparations of Examples 1 to 8 were prepared by various combinations of the textile product discoloration prevention medicine and the textile product storage medicine.
Similarly, preparations of Comparative Examples 1 to 17 were also prepared.

<Test Example 1>
1) Discoloration prevention test About Examples 1-8 and Comparative Examples 1-7, it confirmed that the discoloration of clothes was prevented by the following method about the chemical | medical agent for textile product discoloration adsorption | suction or decomposition | disassembly removal of corrosive gas. did.
Each preparation and fabric (size: 3 cm × 3 cm) were placed in a Tedlar bag (1 L) and sealed. Cupra and silk were used as the fabric.
Next, nitrogen monoxide gas diluted with nitrogen gas and adjusted to 100 ppm was put into the Tedlar bag, and stored at a temperature of 25 ° C. for 2 weeks.
Two weeks later, the fabric was taken out from the tedlar bag, and the discoloration of the fabric was confirmed visually.

2) Visual evaluation criteria for coloration <Score discoloration>
◎: No discoloration ○: Slightly discolored △: Slightly discolored ×: Very discolored ××: Remarkably discolored

In the discoloration prevention test shown in Table 2, it can be seen that in the discoloration prevention tests of Examples 1 to 8 and Comparative Examples 8 and 9 using activated carbon, discoloration of cupra and silk was completely prevented.
On the other hand, except for the case where activated carbon was used in combination, discoloration of more or less was confirmed in Comparative Examples 1 to 17 in which no discoloration inhibitor was used.
From this, it can be seen that the textile product discoloration preventing agent of this invention is excellent in the effect of preventing discoloration of clothing.

<Test Example 2>
1) Drug transfer test For Examples 1 to 8 and Comparative Examples 8 to 17, the amount of transfer of various textile product storage chemicals to the textile product discoloration prevention agent was measured.
Each of the preparations of Examples and Comparative Examples was sealed with a gas barrier bag and stored in a thermostatic bath at a temperature of 40 ° C. for 1 month.
Extract each pharmaceutical preparation from various nonwoven fabrics with acetone and subtract it from the original amount by gas chromatography (internal standard method) to transfer and absorb various textile storage chemicals to textile product discoloration prevention agents. The amount was measured.

In the chemical | medical agent transfer test of Examples 1-8 and Comparative Examples 10 and 11, it turned out that the chemical | medical agent for various textiles storage has not transferred to the textiles discoloration prevention chemical | medical agent.
On the other hand, in the preparations of Comparative Examples 8, 9, 12, and 13, it was found that various textile product storage chemicals were transferred to textile product discoloration prevention chemicals.
Moreover, in Comparative Examples 15 and 16 using metal-supported zeolite, since a strange odor was produced after opening, the amount of drug transfer is considered to be due to decomposition of various drugs.

<Test Example 3>
1) Insect repellent effect test About Examples 1-9 and Comparative Examples 1-4, 8-10 and 14,15, the chemical | medical agent for textiles storage was volatilized, and the insect repellent effect was confirmed.
A metal insect cage (size: φ3.5 cm) containing a plain weave wool muslin cloth (size: 3 cm × 3 cm) and 10 moth larvae was placed on the bottom of a 1.8 liter wide-mouth bottle.
Moreover, each formulation was affixed on the back side of the lid used for the same wide-mouth bottle.
Next, an insecticidal effect test was performed under the condition of a temperature of 25 ° C.
The wide-mouth bottle was sealed with a lid.
After standing for 7 days, the mass of the wool muslin cloth in the wide-mouth bottle was measured.
Moreover, the food damage rate was computed by following formula (1) with the mass before and behind a test.
Furthermore, the number of deaths of the carp after the test was measured, and the mortality was calculated from the following formula (2).
These values are shown in Table 4 below.

Corrosion rate = {(mass before test−mass after test) ÷ mass before test} × 100 (1)
Mortality rate = (Number of dead insects / Number of input insects) x 100 (2)

From Table 4, in the insect repellent effect test of Examples 1-4, it turned out that a feeding damage rate and a dead insect rate have no difference from the case of Comparative Examples 2-4.
From this, it was found that the textile product discoloration preventing agent exhibits a sufficient insecticidal effect without adsorbing or decomposing various textile product storage agents.

<Test Example 4>
1) Aroma performance test The preparations of Examples 5 to 8 and Comparative Examples 5 to 9, 11, 13, 16, and 17 were set in the aroma evaluation box and allowed to stand at a temperature of 25 ° C. for 7 days. About three panelists, sensory evaluation was performed on the following evaluation criteria. The results are shown as average values.

2) Evaluation criteria 5: Strongly scented 4: Slightly scented 3: Scented moderately 2: Slightly scented 1: Not scented

From Table 5, in the aroma performance test of Examples 5-8, it turned out that it smells strongly similarly to Comparative Examples 5-7 which does not use a discoloration prevention agent.
On the other hand, in Comparative Examples 9 and 13, the scent was felt weak because the various textile storage agents were adsorbed on activated carbon or silica gel.

The fiber product storage formulation and the fiber product storage method of the present invention have a possibility of being widely used not only in homes but also in the industry that handles fiber products because of the excellent discoloration preventing property of the fiber product.
In addition, it may be widely used in the industry for preparing textile product storage chemicals such as insect repellents.

It is a top view of the textile product storage formulation of this invention. It is a disassembled perspective view of the textile product storage formulation of this invention.

1 container 2 non-woven fabric holding chemicals for preventing discoloration of textile products 3 non-woven fabric holding chemicals for storing textile products

Claims (6)

Insect repellent or insecticide, fragrance, antimicrobial agents, antifungal, repellents, and the fiber product storage agent made of one or more selected from the disinfectant, copper ions, iron ions, zinc ions, One or more metal ions selected from nickel ions are introduced by ion exchange, and a textile product discoloration prevention agent comprising zeolite having a pore size in the range of 3 to 10 angstroms ,
A textile product storage preparation characterized by being divided and held in one container . The container is
The textile product according to claim 1 , wherein the textile product storage chemical is held inside and the textile product discoloration preventing chemical is carried outside by printing or coating. Storage formulation. The printing is
3. The textile product storage formulation according to claim 2 , wherein the textile product storage formulation is PAD printing. The textile product storage agent is:
The fiber product storage formulation according to claim 1, which is a room temperature volatile chemical. The room temperature volatile chemical is:
The fiber product storage formulation according to claim 4 , which is a pyrethroid insect repellent. A textile product storage method, wherein the textile product storage formulation according to any one of claims 1 to 5 is used in a textile product storage space.