JP5094518B2 - Transparent liquid cosmetic - Google Patents

Description

  The present invention relates to a transparent liquid cosmetic excellent in fragrance standing and scent sustainability. Furthermore, it is a transparent liquid cosmetic having excellent appearance characteristics and excellent storage stability even at low temperatures.

  Conventionally, as a commercial value as a cosmetic, fragrance standing and scent persistence are one of important factors. Further, in order to further increase the commercial value, the cosmetic itself is colored and filled into a transparent or translucent container to give a vivid color tone to the appearance. However, there are drawbacks such as deterioration of scent and persistence of the scent due to change with time and light irradiation, and phenomena such as discoloration and fading.

  Therefore, there is a method to use a light-shielding container to prevent deterioration, discoloration, and fading of fragrance and scent persistence, but the remaining amount of the contents is difficult to understand and the color tone of the contents cannot be confirmed. Appearance characteristics cannot be obtained. For this reason, in order to use a transparent or translucent container, a container subjected to UV cut processing has been used. A UV-cut container means, for example, that a glass container is immersed in an acidic solution such as hydrofluoric acid to corrode the container surface, causing irregular reflection of light on the surface of the container and light transmittance. Or a container in which a UV absorber is coated on the surface of the container, or kneaded into the container itself and molded.

  As described in Patent Document 1, these UV-cut containers have been shown to prevent fragrance, fragrance persistence, and pigment fading by combining with aldehyde-based fragrances. As for sustainability, satisfactory characteristics have not been sufficiently obtained, and the container itself is dulled by UV-cut processing, so that the vivid color tone as expected cannot be obtained. When it is applied to cosmetics, it is not preferable as a commercial value because it deteriorates due to its own aging or light irradiation and becomes more dull.

  Further, as disclosed in Patent Documents 2 and 3, it is shown that discoloration and deterioration can be prevented without using a UV cut processing container by blending a cosmetic material with an ultraviolet absorber. However, in these methods, even though they are excellent in storage stability due to aging and light irradiation, it is completely recognized that fragrance standing and scent sustaining, which are one of the important elements as cosmetics, are improved. Not.

Furthermore, depending on the type of ultraviolet absorber, it may precipitate at a low temperature such as −10 ° C., resulting in poor storage stability.
JP 2007-16161 A JP-A-9-235216 JP 2006-169144 A

  All of the above prior arts have been improved as cosmetics and aqueous compositions, but the fragrance and scent persistence, which are important elements for cosmetics, have not been fully demonstrated. As for the characteristics, satisfactory characteristics are not sufficiently obtained.

As a result of intensive studies to achieve the above-mentioned purpose, it is possible to provide a transparent liquid cosmetic excellent in fragrance standing and scent sustainability by containing a specific ultraviolet absorber and a specific antioxidant in combination. I found it. Furthermore, the present inventors have found that it is possible to provide a transparent liquid cosmetic that is excellent in appearance characteristics such as light resistance and excellent in storage stability even at low temperatures.

  That is, claim 1 of the present invention includes (A) an ultraviolet absorber that absorbs UV-A, (B) an ultraviolet absorber that absorbs UV-B, (C) an antioxidant, and (D) 25 to 65 masses. A transparent liquid cosmetic comprising 1% ethanol and having a viscosity at 25 ° C. of 100 mmPa · s or less.

  Further, claim 2 of the present invention provides (E) an aldehyde fragrance composition, (F) a lactone fragrance composition, (G) a natural fragrance composition, and (H) a ketone fragrance composition as the fragrance composition. The transparent liquid cosmetic according to claim 1, comprising one or more fragrance compositions selected from the group consisting of: A third aspect of the present invention is the transparent liquid cosmetic according to any one of the first and second aspects, which comprises (I) a tar pigment. A fourth aspect of the present invention is the transparent liquid cosmetic according to any one of the first to third aspects, which contains all the components (A) to (I). The fifth aspect of the present invention is the transparent liquid cosmetic according to any one of the first to fourth aspects, wherein (C) the antioxidant contains dehydrodicreole. Claim 6 of the present invention is the transparent liquid cosmetic according to any one of claims 1 to 5 filled in a transparent or translucent container not subjected to UV cut processing. The seventh aspect of the present invention is the transparent liquid cosmetic according to any one of the first to sixth aspects, which does not contain a surfactant.

  The present invention can provide a transparent liquid cosmetic excellent in fragrance standing and scent sustainability, and also has excellent appearance characteristics such as light resistance and excellent storage stability even at low temperatures. Fees can be provided.

Hereinafter, the configuration of the present invention will be described in detail.
The ultraviolet absorber that absorbs (A) UV-A used in the present invention is 2- [4- (diethylamino) -2-hydroxybenzoyl] benzoic acid hexyl ester (Ubinal Plus (manufactured by BASF)), dimethoxybenzylidene diene Examples include 2-ethylhexyl oxoimidazolidine propionate, 4-tert-butyl-4'-methoxydibenzoylmethane (parasol 1789 (Roche)), and there is no odor and dimethoxybenzylidene dioxo soluble in ethanol. Imidazolidinepropionate 2-ethylhexyl is preferred.

  Dimethoxybenzylidene dioxoimidazolidine 2-ethylhexyl propionate is available as a commercial product, and soft shade A (manufactured by Ajinomoto Co., Inc.) is preferably exemplified.

  Content of the said (A) component is 0.0001-1.0 mass% with respect to the whole composition from the surface that it is excellent in fragrance formation and persistence of fragrance, and has the stability which was excellent also at low temperature. It is preferable that the content is 0.001 to 0.1% by mass.

The ultraviolet absorber which absorbs (B) UV-B used in the present invention is amyl paradimethylbenzoate, 2-ethylhexyl paradimethylaminobenzoate (Escalol 507 (manufactured by ISP)), 4- [N, N -Di (2-hydroxypropyl) amino] ethyl benzoate, 2-ethylhexyl salicylate (Escarol 587 (manufactured by ISP)), 2-ethoxyethyl paramethoxycinnamate, 2-ethylhexyl paramethoxycinnamate, dipara Glyceryl mono-2-ethylhexanoate methoxycinnamate (NOMCOAT X (Nisshin Oilio)), hydroxymethoxybenzophenone (Ubinal M40 (BASF)), hydroxymethoxybenzophenone sulfonic acid (Ubinal MS40 (BASF)) ), Dihydroxybenzophenone, 2,4,6-tria Reno-p- (carbo-2'-ethylhexyl-1'-oxy) -1,3,5-triazine (Ubinal T150 (manufactured by BASF)) and the like are mentioned. 2-ethylhexyl methoxycinnamate is preferred.

  Paramethoxycinnamate 2-ethylhexyl is commercially available, and preferable examples include Parasol MCX and Parasol MCX XR (manufactured by Givaudan), Ubinal MC80 (manufactured by BASF), and Escalol 557 (manufactured by ISP). .

  The content of the above components is in the range of 0.0001 to 1.0% by mass with respect to the total composition from the standpoint of excellent fragrance and scent sustainability and excellent stability even at low temperatures. Preferably, 0.001 to 0.1% by mass is further contained.

  Examples of the (C) antioxidant used in the present invention include dibutylhydroxytoluene, dehydrodicreole, and the like. Among them, dehydrodicreole that has no odor and is soluble in ethanol is preferable.

  The content of the above components is in the range of 0.0001 to 1.0% by mass with respect to the total composition from the standpoint of excellent fragrance and scent sustainability and excellent stability even at low temperatures. Preferably, 0.001 to 0.1% by mass is further contained.

  The content of (D) ethanol used in the present invention is 25 to 65 masses based on the total composition from the viewpoint of having good storage stability at low temperatures and good scenting and scent sustainability. %, Preferably 30 to 60% by mass.

  Examples of the fragrance composition used in the present invention include (E) an aldehyde fragrance composition, (F) a lactone fragrance composition, (G) a natural fragrance composition, and (H) a ketone fragrance composition.

The following can be illustrated as (E) aldehyde fragrance | flavor used for this invention.
Citronellal, citral, 3,7-dimethyl-1-octanal, hydroxycitronellal, methoxycitronellal, perilaldehyde, myrtenal, caryophyllenaldehyde, n-hexal, 2-methylbutanal, isovaleraldehyde, n-valeraldehyde , Acetaldehyde, n-heptanal, n-octanal, n-nonanal, 2-methyloctanal, 3,5,5-trimethylhexanal, 1-decanal, undecanal, dodecanal, 2-methyldecanal, 2-methylundecanal , Tridecanal, tetradecanal, 2-pentenal, cis-3-hexenal, trans-2-hexenal, trans-2-heptenal, 4-heptenal, trans-2-octenal, t ans-2-nonenal, cis-6-nonenal, meronal (2,6-dimethyl-5-heptenal), trans-4-decenal, cis-4-decenal, trans-2-decenal, grinal (2, 5, 6 -Trimethyl-4-heptenal), 10-undecenal, trans-2-undecenal, trans-2-dodecenal, mandarinaldehyde (3-dodecenal), trans-2-tridecenal, adoxal (2,6,10-trimethyl-9- Undecen-1-al), 2,4-hexadienal, 2,4-heptadienal, 2,4-octadienal, 2,4-nonadienal, 2,6-nonadienal, 2,4-decadienal, 2,4 -Undecadienal, 2,4-dodecadienal Geraldaldehyde (5,9-dimethyl-4,8-decadienal), trimenal (3,7,9-trimethyl-2,6-decadien-1-al), oncidar (2,6,10-trimethyl-5,9-) Undecadienal), bergamar (α-methylenecitronellal), camphorene aldehyde, cyclocitral, isocyclocitral, safranal (2,6,6-trimethyl-1,3-cyclohexadiene-1-carboxaldehyde) , Mugealdehyde (6,10-dimethyl-3-oxa-9-undecenal), geranyloxyacetaldehyde, tripral (dimethyltetrahydrobenzaldehyde), chrysantal (3-propylbicyclo [2,2,1] -5-heptene-2- Carboxaldehyde), centenal Methoxydicyclopentadienecarboxaldehyde), dupical (4-tricyclodecylidenebutanal), 4- (4-methyl-3-cyclohexenylidene-1) pentanal, mylacaldehyde (4 (3)-(4-methyl) -3-penten-1-yl) -3-cyclohexene-1-carboxaldehyde), setneral (trimethylcyclohexene methylbutanal), inonal (2-methyl-4- (2,6,6-trimethyl-1 (2)) -Cyclohexenyl) -butenal), telestral (4-cyclooctene-1-carboxaldehyde), benzaldehyde, p-tolylaldehyde, phenylacetaldehyde, trifernal (3-phenylbutanal), cuminaldehyde, p-methylphenylacetate Ardehi , P-isopropylphenylacetaldehyde, hydratropaldehyde, p-methylhydratropaldehyde, p-isopropylhydratropaldehyde, phenylpropionaldehyde, β-methylhydrocinnamic aldehyde, jasmorandi (2-methyl-3- (4 -Methylphenyl) -propanal), burgeonal (p-tert-butylhydrocinnamic aldehyde), cyclamenaldehyde (2-methyl-3- (p-isopropylphenyl) -propionaldehyde), florarozone (p-ethyl-α) , Α-dimethylhydrocinnamic aldehyde), suzalal (p-isobutyl-α-methylhydrocinnamic aldehyde), synamic aldehyde, salicylaldehyde, anisaldehyde, o-methoxyben Aldehydes, o- methoxy cinnamic aldehyde, Kantokisaru (2-methyl-3-(p-methoxyphenyl) - propanal), vanillin, ethyl vanillin, methyl vanillin (3,4-dimethoxybenzaldehyde).

  Furthermore, heliotropin, helional (α-methyl-3,4-methylenedioxyhydrocinnamic aldehyde), phenoxyacetaldehyde, p-methylphenoxyacetaldehyde, furfural, 5-methylfurfural, 5-hydroxymethyl-2-furfural, furyl Acrolein, rilal (4 (3)-(4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde), Bernaldehyde (1-methyl-4- (4-methylpentyl) -3-cyclohexenecarboxy Aldehyde), homomylacaldehyde (1-methyl-4 (4-methyl-3-pentenyl) -3-cyclohexenecarboxaldehyde), junipal (4 (5) -formyl-7,7,9-trimethylbicyclo [4 3.0 -Nonene), vertoral (octahydro-4,7-methanoindene carboxaldehyde), lyial (p-tert-butyl-α-methylhydrocinnamic aldehyde), mefranal (3-methyl-5-phenylvaleraldehyde), egrantal (4-methyl-2-phenyl-2-pentenal), cocarl (5-methyl-2-phenyl-2-hexenal), α-methyl cinnamic aldehyde, α-butyl cinnamic aldehyde, α-amyl cinnamic aldehyde, α-hexylcinnamic aldehyde, formylethyltetramethyltetralin (6-ethyl-7-formyl-1,1,4,4-tetramethyl-1,2,3,4-tetrahydronaphthalene) and the like can be mentioned. Good fragrance standing and sustainability Et al., Toripuraru, cumin aldehyde and ocean propanal is preferable.

The following can be illustrated as (F) lactone-type fragrance | flavor.
Pentalide (cyclopentadecanolide), habanolide (oxacyclohexadecen-2-one), ambletide, cyclohexadecanolide, 10-oxahexadecanolide, 11-oxahexadecanolide, 12-oxahexalide Decanolide, ethylenedodecandioate, γ-butyrolactone, γ-valerolactone, angelica lactone, γ-hexalactone, γ-heptalactone, γ-octalactone, γ-nonalactone, whiskey lactone (3-methyl-4-octanolide ), [Gamma] -decalactone, [gamma] -undecalactone, [gamma] -dodecalactone, [gamma] -jasmolactone, jasmine lactone, cis jasmon lactone, lacto jasmon (4-methyl-4-decanolide), jasmolactone (tetrahydro-6-) (3-pentenyl) -2H Pyran-2-one), mentalactone (3,6-dimethyl-5,6,7,7a-tetrahydro-2 (4H) -benzofuranone), n-butylphthalide, propylidenephthalide, butylidenephthalide, δ-hexa Lactone, δ-octalactone, trivalon (4,6,6 (4,4,6) -trimethyltetrahydropyran-2-one), δ-nonalactone, δ-decalactone, δ-2-decenolactone, δ-undecalactone , Δ-dodecalactone, δ-tridecalactone, δ-tetradecalactone, lactoskatone (decahydro-4, α-hydroxy-2,8,8-trimethylnaphthalene-2-carboxyacid-δ-lactone), coumarin, dihydro Coumarin, cyclohexyl lactone, 6-methylcoumarin, ε-decalactone, ε-dodecalact Etc.. Among them, γ-undecalactone, jasmine lactone, and coumarin are preferable from the viewpoint of good fragrance formation and fragrance persistence.

(G) As a natural fragrance | flavor, the following can be illustrated.
Asafetida Resinoid, Ajowan Oil, Star Anise Oil, Abies Oil, Amiris Oil, Ambret Seed Oil, Ambergris Tincture, Ylang Ylang Oil, Ylang Ylang Absolute, Iris Resinoid, Iris Absolute, Iris Oil, Winter Green Oil, Elemiole Ole Gin, Elemi Resinoid Absolute, Elemi Tinch, Oak Mos Concrete, Oak Mos Absolute, Oak Mos Resin, Oak Moth Resinoid, Ocotia Oil, Ottoman Sus Absolute, Otto Man Sus Concrete, Opopanax Resinoid, Opopanax Absolute, Opopanax Oil, Olivian Resinoid, Olivenum absolute, olivenum oil, allspice oil, orange Gano oil, oregano oleoresin, orange oil, orange flower absolute, orange flower concrete, cananga oil, garjun balsam, garjun balsam oil, cascari bark oil, castrium absolute, cassy absolute, cassy flower oil, cassia oil, gardenia absolute , Carnation Absolute, Cabruba Oil, Camomil Oil, Cardamom Oil, Galvanam Oil, Galvanam Resin, Galvanam Resinoid, Caraway Seed Oil, Carrot Seed Oil, Guayac Wood Oil, Guayac Resin, Guayac Concrete, Kusunoki Oil, Kubaba Oil, Cumin oil, cumin absolute, cumin oleoresin, clari Oil, grapefruit oil, clove oil, costa oil, copaiba balsam, copaiba balsam oil, copaiba balsam resin, coriander oil, sassafras oil, sandalwood oil, june absolute, perilla oil, citronella oil, jasmine absolute, jasmine concrete, juniper berry oil , Civet absolute, Civet tincture, Jonquil absolute, Agarwood oil, Ginger oil, Cinnamon oil, Cinnamon bark oil, Cinnamon leaf oil, Cedar oil, Stylax oil, Stylax resinoid, Spearmint oil, Savory oil, Sage oil, Cedar oil, Cedar leaf oil, geranium oil, celery seed oil , Thyme oil, tagget oil, tarragon oil, tuberose absolute, dill oil, tea tree oil, turmos absolute, trubal sum, nutmeg oil, narcissus absolute, neroli oil, violet leaf absolute, pine oil, basil oil, parsley leaf oil, Parsley seed oil, parsley herb oil, patchouli oil, mint oil, vanilla absolute, honeysuckle absolute, palmarosa oil, valerian oil, bitter orange oil, hyssop oil, hiba oil, hyacinth absolute, fennel oil, fig absolute, petit glen oil, butu oil, Vetiver oil, penny royal oil, pepper oil, peppermint Il, Bergamot oil, Peruvian balsam, benzoin tincture, benzoin resinoid, bored rose oil, pepper oil, hop oil, hop concrete, hop absolute, marjoram oil, mandarin oil, orange oil, mimosa concrete, mimosa absolute, mimosa oil, mill Resinoid, Mill Absolute, Mill Oil, Musk Absolute, Mustinki, Eucalyptus Oil, Yuzu Oil, Artemisia Oil, Lime Oil, Labdanum Oil, Labdanum Resinoid, Lavender Oil, Lavender Absolute, Lavandin Oil, Lavandin Absolute, Linaroe Oil, Lemon Oil, Lemongrass Oil, rose oil, rose absolute, rose concrete, low Marie oil, Robejioiru, Laurel oil, laurel leaf oil, wormwood oil, musk, Reinekoko, dragon Zen incense, Castoreum, musk-Chibata like. Among them, ylang ylang oil, ylang ylang absolute, oak moss absolute and lemon oil are preferable from the viewpoint of good scent formation and scent sustainability.

Examples of (H) ketone-based fragrances include the following.
Acetyl caryophyllene, carvone, pregon, piperithenone, piperiton, menthone, show brain, oxocedrane, isolongifolanone, nootkatone, 2-heptanone, 2-pentanone, 3-hexanone, 3-heptanone, 4-heptanone, 2-octanone, 3 -Octanone, 2-nonanone, 3-nonanone, 2-undecanone, 2-tridecanone, methyl isopropyl ketone, ethyl isoamyl ketone, mesityl oxide, butylideneacetone, methylheptadienone, methylheptenone, dimethyloctenone, coavone (4- Methylene-3,5,6,6-tetramethyl-2-heptanone), geranyl acetone, farnesyl acetone, acetoin, butyroin (5-hydroxy-4-octanone), methyl lavender ketone (3- Droxymethyl-2-nonane), diacetyl, 2,3-pentadione, 2,3-hexadione, 3,4-hexadione, 2,3-heptadione, acetylisovaleryl, amylcyclopentanone, amylcyclopentenone, 2- Cyclopentylcyclopentanone, hexylcyclopentanone, fluuramon (2-n-heptylcyclopentanone), cis-jasmon, dihydrojasmon, isojasmon, trimethylpentylcyclopentanone, sedamon (2-butylidene-3,5,5 ( 3,3,5) -trimethylcyclopentanone), sandex (3-methyl-5- (2,2,3-trimethyl-3-cyclopentenyl) -3-penten-2-one), cycloten, coronol ( 3,5-dimethyl-1,2-cyclopentadione), Tylcholylone (3,4-dimethyl 1,2-cyclopentadione), Verdon (2-tert-butylcyclohexanone), p-tert-butylcyclohexanone, Hellbach (3,3-dimethylcyclohexylmethylketone), frescomente (2- sec-butylcyclohexanone), Artemon (1-acetyl-3,3-dimethyl-1-cyclohexene), celly ketone (3-methyl-5-propyl-2-cyclohexenone), krypton (4-isopropyl-2-cyclohexanone) , Ribbon (p-tert-pentylcyclohexanone), methylcyclocitron (2,3,5-trimethyl-4-cyclohexenyl-1-methylketone), neron (1- (p-menten-6-yl) -1-propane ), Vetival (4-cyclohe Xyl-4-methyl-2-pentanone), havanol (2- (1-cyclohexen-1-yl) -cyclohexanone), maltol, ethyl maltol, oxide ketone (cis-2-acetonyl-4-methyl-tetrahydropyran), Emoxiflon (5-ethyl-3-hydroxy-4-methyl-2 [5H] -furanone), homofurol (2-ethyl-4-hydroxy-5-methyl-3 [2H] -furanone and 5-ethyl-4-hydroxy- 2-methyl-3 [2H] -furanone), sotron (3-hydroxy-4,5-dimethyl-2 [5H] -furanone), furaneol (2,5-dimethyl-4-hydroxy-3 [2H] -furanone) ), Acetyldimethylfuran, furfural acetone, 2-acetyl-5-methylfuran, 2-acetyl. Rufuran, methyltetrahydrofuranone, dibenzyl ketone, benzophenone, methyl naphthyl ketone, 4-damascol (5-phenyl-5-methyl-3-hexanone).

  Furthermore, bethicon (4-methyl-4-phenyl-2-pentanone), α-methylanisalacetone, heliotropylacetone, anisylideneacetone, anisylacetone, p-methoxyphenylacetone, raspberry ketone (4- (p- Hydroxyphenyl) -2-butanone), labandone (3-methyl-4-phenyl-3-buten-2-one), benzylideneacetone, p-methoxyacetophenone, p-methylacetophenone, propiophenone, acetophenone, damasenone, damascone , Isodamascon, α-dynascon (1- (5,5-dimethylcyclohexen-1-yl) -4-penten-1-one), iriton (4- (2,4,6-trimethyl-3-cyclohexene-1-) Yl) -3-buten-2-one and 4-3,5 6-trimethyl-3-cyclohexen-1-yl) -3-buten-2-one), ionone, pseudoionone, methylyonone, methyliriton (3-methyl-4- (2,4,6-trimethyl-3-cyclohexenyl) -3-buten-2-one), cyclowood (2,4-di-tert-butylcyclohexanone), iron, allyl ionone, 2,6,6-trimethyl-2-cyclohexene-1,4-dione, kamek DH ( 2-acetyl-3,3-dimethylnorbornane), Florex (6-ethylideneoctahydro-5,8-methano-2H-1-benzopyran-2-one), pricatone (4-methyltricyclo [6.2. 1.02.7] undecan-5-one), oxocedrane, belt fix (9-acetyl-2,6,6,8-tetramethyl) Lutricyclo [5.3.3.11.7.01.5] -8-undecene), berbenone (4,6,6-trimethyl- (1R) -bicyclohept-3-en-2-one), Fencon, Caron (7 -Methyl-3,5-dihydro-2H-benzodioxepin-3-one), trimofix O (2,6,10-trimethyl-1-acetyl-2,5,9-cyclododecatriene), bitalide ( Acetyldimethyltetrahydrobenzindane), epiton (7 (8) -acetyl-5-isopropyl-2-methylbicyclo [2.2.2] oct-2-ene), atrinone (4 (5) -acetyl-7,7 , 9 (7,7,9) -trimethylbicyclo [4.3.0] -1-nonene), cachemelan (6,7-dihydro-1,1,2,3,3-pentamethyl-4 ( H) -Indanone), Muscon (3-methylcyclopentadecanone-1), Cybeton (cycloheptadec-9-en-1-one), Exalton (cyclopentadecanone), Musk TM-II (Cyclohexadecenone) ), Fantolide (5-acetyl-1,1,2,3,3,6-hexamethylindane), celestrido (4-acetyl-6-tert-butyl-1,1-dimethylindane), traceolide (5-acetyl) -3-Isopropyl-1,1,2,6-tetramethylindane), tonalide (6-acetyl-1,1,2,4,4,7-hexamethyltetrahydronaphthalene), bitalide (acetyldimethyltetrahydrobenzindane) , Iso-e super (7-acetyl-1,2,3,4,5,6,7,8-octahydro- 1,1,6,7-tetramethylnaphthalene), dihydrocarbon, diosphenol, gingerone and the like. Among them, cis-jasmon, maltol and yonon are preferred from the viewpoint of good fragrance formation and fragrance persistence.

  The content of (E) aldehyde-based fragrance composition, (F) lactone-based fragrance composition, (G) natural fragrance composition, (H) ketone-based fragrance composition is excellent in fragrance and scent sustainability, From the standpoint of having excellent stability even at low temperatures, it is preferably in the range of 0.000001 to 0.5% by weight, particularly 0.000001 to 0.4% by weight, based on the total composition. preferable. The fragrance compositions (E) to (H) may be used alone, or two or more kinds may be mixed. It is preferable to contain all of (E) to (H) in terms of fragrance.

  In this invention, fragrance | flavor compositions other than the said fragrance | flavor composition can also be contained. Examples of other fragrance compositions include hydrocarbon-based fragrance compositions, alcohol-based fragrance compositions, ether-based fragrance compositions, ester-based fragrance compositions, nitrogen-containing fragrance compositions, and the like.

  The hydrocarbon-based fragrances are α-pinene, β-pinene, camphene, myrcene, limonene, terpineol, terpinolene, osimene, γ-terpinene, α-ferrandylene, p-cymene, β-caryophyllene, β-farnesene, 1,3. , 5-undecatriene, diphenylmethane and the like.

  Alcohol-based fragrances are trans-2-hexenol, cis-3-hexenol, 3-octanol, 1-octen-3-ol, 2,6-dimethyl-2-heptanol, 9-decenol, 4-methyl-3-decene -5-ol, 10-undecenol, trans-2-cis-6-nonadienol, linalool, geraniol, nerol, citronellol, rosinol, myrsenol, lavandulol, tetrahydrogeraniol, tetrahydrolinalol, hydroxycitronellol, dihydromyrcenol, allo Osimenol, terpineol, turpinen-4-ol, l-menthol, borneol, isopulegol, nopol, farnesol, nerolidol, bisabolol, cedrol, patchoulialcohol, tiveverol, 2 4-dimethyl-3-cyclohexene-1-methanol, 4-isopropylcyclohexanol, 4-isopropylcyclohexanemethanol 1- (4-isopropylcyclohexyl) -ethanol, 2,2-dimethyl-3- (3-methylphenyl) -propanol , Pt-butylcyclohexanol, ot-butylcyclohexanol, ambrinol, benzyl alcohol, phenylethyl alcohol, phenoxyethanol, styryl alcohol, anise alcohol, cinnamic alcohol, phenylpropyl alcohol, dimethylbenzylcarbinol, phenyl Ethylmethylethyl carbinol, 3-methyl-5-phenylpentanol, thymol, carvacrol, orcinol monomethyl ether, eugenol, i Eugenol, santalol, isobornyl cyclohexanol, Sandaroa, Bagudanoru, sandal Mai Sol core, Buramanoru, Ebanoru, poly San tall, 2-ethoxy-4-methoxymethyl phenol and the like.

  Ether-based fragrances are nerol oxide, miloxide, 1,8-cineol, rose oxide, limethol, mentfuran, linalool oxide, butyldimethyldihydropyran, acetoxyamyltetrahydropyran, cedolmethyl ether, methoxycyclododecane, 1-methyl -1-methoxycyclododecane, ethoxymethylcyclododecyl ether, tricyclodecenyl methyl ether, rubofix, cedroxide, ambroxan, glycalva, voiris, anisole, dimethylhydroquinone, paracresyl methyl ether, acetanisole, anethole, dihydro Anethole, estragole, diphenyl oxide, methyl eugenol, methyl isoeugenol, benzyl isoeugenol, phenyl Tyl isoamyl ether, β-naphthyl methyl ether, β-naphthyl ethyl ether, β-naphthyl isobutyl ether, 2,4-dimethyl-4-phenyltetrahydrofuran, galaxide, 2,2,5,5-tetramethyl-4-isopropyl- 1,3-dioxane and the like can be mentioned.

  Ester flavors include ethyl formate, cis-3-hexenyl formate, linalyl formate, citronellyl formate, geranyl formate, benzyl formate, phenyl ethyl formate, ethyl acetate, butyl acetate, isoamyl acetate, methyl cyclopentylidene acetate, hexyl acetate, acetic acid Cis-3-hexenyl, trans-2-hexenyl acetate, isononyl acetate, citronellyl acetate, lavandulyl acetate, geranyl acetate, linalyl acetate, myrcenyl acetate, terpinyl acetate, menthyl acetate, menthanyl acetate, nopyru acetate, n-bornyl acetate, isobornyl acetate P-t-butylcyclohexyl acetate, o-t-butylcyclohexyl acetate, tricyclodecenyl acetate, 2,4-dimethyl-3-cyclohexene-1-methanyl acetate, benzyl acetate, phenylethyl acetate, styraryl acetate, Cinnamyl acid, anisyl acetate, paracresyl acetate, heliotropyl acetate, acetyl eugenol, acetyl isoeugenol, guayl acetate, cedolyl acetate, ethyl bethioberyl acetate, isoamyl propionate, citronellyl propionate, geranyl propionate, linalyl propionate, propionic acid Tarpinyl, benzyl propionate, cinnamyl propionate, allyl cyclohexylpropionate, tricyclodecenyl propionate, ethyl butyrate, 2-methylbutyrate, butyl butyrate, isoamyl butyrate, hexyl butyrate, linalyl butyrate, geranyl butyrate, citronellyl butyrate, Benzyl butyrate, cis-3-hexenyl isobutyrate, citronellyl isobutyrate, geranyl isobutyrate, linalyl isobutyrate, benzyl isobutyrate, phenybutyrate Ethyl, tricyclodecenyl isobutyrate, ethyl isovalerate, propyl valerate, citronellyl isovalerate, geranyl isovalerate, benzyl isovalerate, cinnamyl isovalerate, phenylethyl isovalerate, ethyl caproate, capron Allyl acid, ethyl enanthate, allyl enanthate, ethyl caprate, citronellyl tiglate, methyl benzoate, ethyl benzoate, isobutyl benzoate, isoamyl benzoate, geranyl benzoate, linalyl benzoate, benzyl benzoate, phenyl benzoate Ethyl, methyl phenylacetate, ethyl phenylacetate, isobutyl phenylacetate, isoamyl phenylacetate, geranyl phenylacetate, benzyl phenylacetate, phenylethyl phenylacetate, p-cresyl phenylacetate, methyl cinnamate, ethyl cinnamate, cinnamic acid Benzyl, cinnamyl cinnamate, phenylethyl cinnamate, methyl salicylate, ethyl salicylate, isobutyl salicylate, amyl salicylate, hexyl salicylate, cis-3-hexenyl salicylate, benzyl salicylate, phenylethyl salicylate, methyl jasmonate, methyl dihydrojasmonate, flutate Allyl 2-pentyloxyglycolate, ethyl 3-methyl-3-phenylglycidate, ethyl 2-pentanoate, 4-acetoxy-3-amyltetrahydropyran, cyclohexylsalicylate, ethyl 2-cyclohexylpropionate, ethyltri And cyclo [5.2.1.02,6] decane-2-carboxylate, 2-methylpentyl 2-methylpentylate and the like.

  Examples of the nitrogen-containing fragrance include 6-sec-butylquinoline, 5-methyl-3-heptanone oxime, and citronellyl nitrile.

  Moreover, as a result of measuring the transparent liquid cosmetics of this invention using the B-type viscosity meter rotor No. 1, it is preferable that it is 100 mmPa * s or less in 25 degreeC.

  The (I) tar dye used in the present invention can be selected from those described in the Legal Dye Handbook Revised Edition (edited by the Japan Cosmetic Industry Association, issued on September 21, 2004).

  For example, Red No. 2, Red No. 3, Red No. 102, Red No. 104 (1), Red No. 105 (1), Red No. 106, Yellow No. 4, Yellow No. 5, Green No. 3, Blue No. 1, Blue No. 2, Red No. 213, Red No. 227, Red No. 203 (1), Red No. 203 (2), Red No. 231, Red No. 232, Daigo Color No. 205, Dai No Color No. 207, Yellow No. 202 (1), yellow 202 (2), yellow 203, green 201, green 204, green 205, blue 205, blue 202, blue 203, blue 205, brown 201, red 401, red 502 No., Red 503, Red 504, Red 506, Orange 402, Yellow 402, Yellow 403 (1), Yellow 406, Yellow 407, Green 401, Green 402, Purple 401 , Black 401 etc. That.

  These may be used singly or as a mixture of two or more, but from the viewpoint of having excellent appearance characteristics, it is preferable to contain two or more (I) tar dyes, It is preferable to contain 0.00005-0.005 mass%.

  The container used in the present invention is a transparent or semi-transparent container that has not been subjected to UV-cut processing from the viewpoint of having excellent appearance characteristics, and may be any arbitrary resin such as a transparent glass bottle or a synthetic resin bottle such as transparent PET. The thing of a raw material can be used and it does not specifically limit.

  If the transparent liquid cosmetic composition of the present invention contains a surfactant, it is solubilized by the surface active ability, so that the fragrance standing and the scent sustainability are not good. In addition, the contents are foamed when used, which is not preferable as a commercial value in terms of appearance characteristics.

  Examples of the surfactant include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants.

  The transparent liquid cosmetic composition of the present invention can contain, in addition to the above essential components, optional components that are usually used as long as the effects of the present invention are not impaired. These components include higher alcohols, higher fatty acids, hydrocarbons, waxes, ester oils, vegetable oils, UV absorbers, preservatives, humectants, polyhydric alcohols, anionic polymers, cationic polymers, amphoteric polymers, Nonionic polymers, polymers, amino acid derivatives, sugar derivatives, animal and plant derivatives, animal and plant extracts, thickeners, vitamins, UV absorbers, colorants, sequestering agents, antioxidants, cell activators, etc. It is done.

  Applications of the transparent liquid cosmetic composition of the present invention include hair styling agents, hair growth agents, hair nourishing agents, hair tonics, skin lotions and the like.

EXAMPLES Next, although this invention is demonstrated in detail based on an Example, it is not limited to this. A compounding amount is a mass percentage (%) unless otherwise specified. Examples 2, 5, 9, and 13 to 15 are reference examples.

<Preparation of transparent liquid cosmetics>
Transparent liquid cosmetics shown in “Table 1” were prepared and evaluated for fragrance standing, scent sustainability, light resistance, and storage stability at low temperatures.

<Evaluation method for fragrance standing and scent sustainability>
The fragrance is the intensity of the scent that is felt immediately after application, and the persistence of the scent means whether or not the intensity of the scent drifting in the space is sufficient after a certain period of time has elapsed after application.
(1) Thirty seconds after applying the cosmetic, the intensity of fragrance (fragrance standing) was evaluated according to the following criteria.
◎: Scent is very good ○: Scent is good △: Scent is a little bad ×: Scent is not good (2) After 30 minutes, the scent strength (scent of scent) is as follows. Evaluated by criteria.
◎: Sustainability of fragrance is very good ○: Sustainability of scent is good △: Sustainability of scent is slightly bad ×: Sustainability of scent is poor

<Evaluation method for light resistance>
(3) Each sample was filled in a colorless and transparent glass container and a PET container, and exposed to sunlight for one month. On the other hand, as a control, the same packing was stored (5 ° C.) in a cool dark place for 1 month.
One month later, the difference in color was visually observed in comparison with the control product, and evaluated according to the following criteria.
◎: Neither change from the initial stage ○: Slightly different from any initial color △: Slightly different from any initial stage ×: Colors completely different from any initial stage

<Evaluation method for storage stability at low temperatures>
(4) Each sample was filled in a colorless and transparent glass container and a PET container, and stored for one month in a cool and dark place (−20 ° C., −10 ° C.).
On the other hand, as a control, the same packing was stored (5 ° C.) in a cool dark place for 1 month.
One month later, the crystal precipitation and the like were visually observed in comparison with the control product, and evaluated according to the following criteria.
◎: No change from initial stage ○: Slightly different from either initial stage △: Any sample becomes cloudy ×: Any crystal precipitation is confirmed

Examples 1-10, Comparative Examples 1-9 (hairdressing)

  From the results in Table 1, (A) UV absorber that absorbs UV-A, (B) UV absorber that absorbs UV-B, (C) antioxidant, and (D) 25 to 65 mass% ethanol. It has been found that a transparent liquid cosmetic with excellent scenting and scent sustainability and excellent storage stability even at low temperatures can be obtained. Moreover, it turns out that those effects stand out more by containing a fragrance | flavor composition and (I) tar pigment | dye.

Consciousness survey was conducted by 10 panelists about “motivation to purchase”, and a questionnaire was conducted using the following three types of containers. In addition, the transparent liquid cosmetics of Example 8 were used for the contents.
(1) Container whose contents cannot be seen (light-shielding container)
(2) Slightly dull container (container with UV cut)
(3) Transparent container (container that is not UV cut)
(Evaluation) Each individual performed the following evaluations on each item, and determined by the total score.
I want to buy: 2 points I don't want to buy: 0 points I can't say either: 1 point Total score of 15 points or more: ◎
10 points or more and less than 15 points: ○
5 points or more and less than 10 points: △
Less than 5 points: ×

  From the results in Table 2, it was found that cosmetics contained in a transparent container (a container not subjected to UV cut processing) is an effective means for increasing consumers' willingness to purchase.

Hereinafter, other formulation examples of the transparent liquid cosmetic of the present invention will be given as examples. In addition, the transparent liquid cosmetics of these examples were also good because they had excellent properties such as fragrance and scent sustainability, appearance characteristics, and storage stability at low temperatures.

Example 11 (hair growth agent)
Dimethoxybenzylidenedioxoimidazolidine
2-ethylhexyl propionate (A) 0.02
2-Ethylhexyl paramethoxycinnamate (B) 0.03
Dehydrodicreole (C) 0.01
Ethanol (D) 55.0
Fragrance 1.0
(Fragrance breakdown)
(Cuminaldehyde (E) 0.025)
(Coumarin (F) 0.025)
(Ylang Ylang Oil (G) 0.025)
(Maltor (H) 0.025)
(Other perfume composition 0.9)
Green No. 201 (I) 0.0001 Yellow No. 4 (I) 0.004
Red No. 227 (I) 0.0001 D-pantothenyl alcohol 0.2
Isopropylmethylphenol 0.1
Purified water residue

Example 12 (hairdressing) Mass%
Dimethoxybenzylidenedioxoimidazolidine
2-ethylhexyl propionate (A) 0.02
2-Ethylhexyl paramethoxycinnamate (B) 0.03
Dehydrodicreole (C) 0.01
Ethanol (D) 55.0
Fragrance 0.1
(Fragrance breakdown)
(Helionar (E) 0.025)
(Cyclopentadecanolide (F) 0.025)
(Ylang Ylang Absolute (G) 0.025)
(Menton (H) 0.025)
(Other perfume composition 0.9)
Green 205 (I) 0.0001 Yellow 203 (I) 0.004
Red No. 231 (I) 0.0001 (methacryloyloxyethylcarboxybetaine)
/ Alkyl methacrylate) copolymer 0.2
Purified water residue

Example 13 (hair tonic)% by mass
Dimethoxybenzylidenedioxoimidazolidine
2-ethylhexyl propionate (A) 0.02
2-Ethylhexyl paramethoxycinnamate (B) 0.03
Dehydrodicreole (C) 0.01
Ethanol (D) 55.0
Fragrance 1.0
(Fragrance breakdown)
(Szaral (E) 0.025)
(Lact Jasmon (F) 0.025)
(Orange oil (G) 0.025)
(Other perfume composition 0.925)
Green No. 3 (I) 0.08
Polyoxyethylene hydrogenated castor oil (60 EO) 0.3
Benzalkonium chloride 0.05
Pepper tincture 1.0
D-pantothenyl alcohol 0.2
L-Menthol 0.2
Rosemary extract (trade name: Mannenrou extract, manufactured by Koei Kogyo Co., Ltd.) 0.1
Purified water residue

Example 14 (hairdressing) Mass%
Dimethoxybenzylidenedioxoimidazolidine
2-ethylhexyl propionate (A) 0.02
2-Ethylhexyl paramethoxycinnamate (B) 0.03
Dehydrodicreole (C) 0.01
Ethanol (D) 30.0
Fragrance 1.0
(Fragrance breakdown)
(Citral (E) 0.025)
(Angelica lactone (F) 0.025)
(Iris oil (G) 0.025)
(Other perfume composition 0.925)
Green 401 (I) 0.08
Polyoxyethylene hydrogenated castor oil (40E.O.) 0.3
Benzalkonium chloride 0.05
Polyoxyethylene (17) Polyoxypropylene (17)
Butyl ether 0.5
Glycerin 3.0
D-pantothenyl alcohol 0.2
L-Menthol 0.2
Rosemary extract (trade name: Mannenrou extract, manufactured by Koei Kogyo Co., Ltd.) 0.1
Purified water residue

Example 15 (hair tonic refreshing type)
Dimethoxybenzylidenedioxoimidazolidine
2-ethylhexyl propionate (A) 0.02
2-Ethylhexyl paramethoxycinnamate (B) 0.03
Dehydrodicreole (C) 0.01
Ethanol (D) 60.0
Fragrance 1.0
(Fragrance breakdown)
(Whisky lactone (F) 0.025)
(Garjung Balsam (G) 0.025)
(Oxocedrane (H) 0.025)
(Other perfume composition 0.925)
Green No. 3 (I) 0.08
Polyoxyethylene hydrogenated castor oil (60 EO) 0.3
Benzalkonium chloride 0.05
Pepper tincture 1.0
D-pantothenyl alcohol 0.2
L-Menthol 0.2
L-threonine 0.1
L-serine 0.1
Biwa leaf extract (Brand name: Biwa leaf extract CA, manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.1
Assembly extract (trade name: assembly extract, manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.1
Ages extract (trade name: Agetsu extract, manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.1
Dibutylhydroxytoluene 0.01
Purified water residue

Example 16 (hair tonic moist type)
Dimethoxybenzylidenedioxoimidazolidine
2-ethylhexyl propionate (A) 0.02
2-Ethylhexyl paramethoxycinnamate (B) 0.03
Dibutylhydroxytoluene (C) 0.01
Ethanol (D) 30.0
Fragrance 1.0
(Fragrance breakdown)
(Junipal (E) 0.025)
(Linaroe oil (G) 0.025)
(3-Hexanone (H) 0.025)
(Other perfume composition 0.925)
Green No. 402 (I) 0.08
Pepper tincture 1.0
D-pantothenyl alcohol 0.2
L-Menthol 0.2
Benzalkonium chloride 0.05
Ginger root extract (trade name: ginger tincture, manufactured by Koei Kogyo Co., Ltd.) 0.1
Panax ginseng extract (trade name: carrot extract, manufactured by Koei Kogyo Co., Ltd.) 0.1
Macombu extract (trade name: seaweed extract K, manufactured by Koei Kogyo Co., Ltd.) 0.1
Roman chamomile flower extract (trade name: Roman chamomile extract BG-50, manufactured by Koei Kogyo Co., Ltd.) 0.1
Cordyceps extract (trade name: Cordyceps extract, manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.1
Peppermint extract (trade name: peppermint extract BG, manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.1
Eucalyptus extract (trade name: Eucalyptus extract, manufactured by Maruzen Pharmaceutical Co., Ltd.) 0.1
Purified water residue

  The present invention can provide a transparent liquid cosmetic excellent in fragrance standing and scent sustainability, and also has excellent appearance characteristics such as light resistance, and is excellent in storage stability even at low temperatures. It is possible to supply transparent liquid cosmetics with excellent fragrance, scent sustainability and appearance characteristics.

Claims (5)

(A) an ultraviolet absorber which absorbs UV-A, (B) an ultraviolet absorber which absorbs UV-B, antioxidant selected from (C) dibutylhydroxytoluene and dehydro Logistics creosol: 0.001 features and 0.1 wt%, and (D) 25 to 65 wt% ethanol, containing a perfume composition, Ri viscosity 100mmPa · s der less at 25 ° C., that it does not contain a surfactant Transparent liquid cosmetics. Perfume composition, (E) aldehyde perfume composition, (F) lactone fragrance composition, (G) a natural fragrance composition and (H) 1, two or more selected from ketone perfume composition The transparent liquid cosmetic composition according to claim 1, which is a fragrance composition. The transparent liquid cosmetic according to claim 1 or 2, further comprising (I) a tar pigment. Ingredients (A) ~ (I) a transparent liquid cosmetic according to claim 3, characterized in that it contains everything. Furthermore, the transparent liquid cosmetics in any one of Claims 1-4 filled with the transparent or semi-transparent container which has not performed UV cut process.