JP5076898B2 - Water-in-oil emulsion composition for roll-in - Google Patents

Water-in-oil emulsion composition for roll-in Download PDF

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JP5076898B2
JP5076898B2 JP2007533131A JP2007533131A JP5076898B2 JP 5076898 B2 JP5076898 B2 JP 5076898B2 JP 2007533131 A JP2007533131 A JP 2007533131A JP 2007533131 A JP2007533131 A JP 2007533131A JP 5076898 B2 JP5076898 B2 JP 5076898B2
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emulsion composition
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oil emulsion
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智明 熊谷
暁之 石渡
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Fuji Oil Co Ltd
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23DEDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
    • A23D7/00Edible oil or fat compositions containing an aqueous phase, e.g. margarines
    • A23D7/003Compositions other than spreads
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/80Pastry not otherwise provided for elsewhere, e.g. cakes, biscuits or cookies

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Polymers & Plastics (AREA)
  • Edible Oils And Fats (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)

Description

本発明は、ロールイン用油中水型乳化組成物に関し、更に詳しくは、パイ、デニッシュペストリーなどの層状膨化小麦粉食品を製造するに適したロールイン用油中水型乳化組成物及びそれを使用してなる層状膨化小麦粉食品に関する。   The present invention relates to a water-in-oil emulsion composition for roll-in, and more particularly, to a roll-in water-in-oil emulsion composition suitable for producing layered puffed flour foods such as pies and Danish pastries, and the use thereof The present invention relates to a layered puffed flour food.

近年、オープンフレッシュベーカリー、所謂焼き立てのパンを販売する町のパン屋さんなどではクロワッサン、パイ、デニッシュペストリーなどの層状膨化小麦粉食品が人気を集めており、店の顔とも言うべき存在になっている。焼き立てのジューシーな口当たり、さっくりと歯切れの良い食感が消費者に好まれていると言える。一方で、コンビニエンスストア、量販店などにおいてもクロワッサン、パイ、デニッシュペストリーが販売されているが、配送に時間がかかるなどの問題により焼き立てを販売することは困難で、ジューシーな口当たり、さっくり歯切れの良い食感を長時間にわたり維持できる技術が強く望まれている。   In recent years, croissants, pies, Danish pastries and other layered puffed flour foods are gaining popularity at open fresh bakery, bakery in town that sells so-called freshly baked bread, and it has become the face of the store . It can be said that consumers like the freshly baked succulent taste and the crisp and crisp texture. On the other hand, croissants, pies, and Danish pastries are also sold at convenience stores and mass retailers, but it is difficult to sell freshly baked bread due to problems such as time-consuming delivery, juicy taste, crispy A technology that can maintain a good texture over a long period of time is strongly desired.

通常クロワッサン、パイ、デニッシュペストリーなどの層状膨化小麦粉食品を製造する際ロールイン用油中水型乳化組成物が使用されるが、使用する油中水型乳化組成物により層状膨化小麦粉食品の形状、風味が決まってしまうという位、重要な役割を担っている。オープンフレッシュベーカリーでは手作業にて製造されることが多く、生地を捏ね上げ、ロールイン用油中水型乳化組成物を折り込み、ホイロで発酵させ、オーブンで焼き上げる。手作業が主体となる為、使用する油中水型乳化組成物の物性に合わせて適切な温度調節を施して折り込み作業を行なったり、ホイロにおける発酵の時間、温度管理など適宜調節することができる。例えばバターなど温度による硬さの変化の大きい油中水型乳化組成物を使用した場合でも折り込み作業を適切に行うことができ、またホイロにおいてもバターの融解しない30℃付近で長時間発酵させることもでき、油中水型乳化組成物の品質に制限される場面が少ないといえる。   Usually, a water-in-oil emulsion composition for roll-in is used when producing a layered expanded flour food such as croissant, pie, and Danish pastry, but the shape of the layered expanded flour food by the water-in-oil emulsion composition used, It plays an important role as the flavor is determined. In an open fresh bakery, it is often produced by hand. The dough is kneaded, the water-in-oil emulsion composition for roll-in is folded, fermented in a proofer, and baked in an oven. Because it is mainly manual work, it is possible to adjust the temperature appropriately by adjusting the temperature by adjusting the temperature appropriately according to the physical properties of the water-in-oil emulsion composition to be used. . For example, even when using a water-in-oil emulsified composition having a large change in hardness due to temperature, such as butter, the folding operation can be appropriately performed, and even in the proofer, fermentation is performed for a long time at around 30 ° C. where the butter does not melt. It can be said that there are few scenes limited by the quality of the water-in-oil emulsion composition.

それに対し、コンビニエンスストア、量販店などで販売される場合は当然の事ながら大量生産となり、その為連続ラインなどの設備により生産されている。折り込み作業は自動で行なわれ、ホイロでは効率を上げるため36〜40℃程度で発酵が行なわれているのが現状である。その為、ロールイン用油中水型乳化組成物は幅広い温度帯で硬さの変化が少なく伸展性に優れ、ホイロで融け出さない品質が望ましいとされており、バターのような作業温度域が狭い油中水型乳化組成物は実質的に使用することは難しい。   On the other hand, when it is sold at a convenience store, a mass retailer, etc., it is natural that it is mass-produced, and is therefore produced by equipment such as a continuous line. The folding operation is performed automatically, and in the current state, fermentation is performed at about 36 to 40 ° C. in order to increase the efficiency. Therefore, water-in-oil emulsified compositions for roll-in are considered to have excellent extensibility with little change in hardness over a wide temperature range, and a quality that does not melt with a proofer. Narrow water-in-oil emulsion compositions are substantially difficult to use.

このような問題を克服する為、ロールイン用油中水型乳化組成物の油相に高融点脂を配合し、幅広い温度帯で硬さの変化が少なく展延性に優れ、且つホイロで融け出さないようにする方法が一般的に知られているが、これらを使用して得られるクロワッサン、パイ、デニッシュペストリーはジューシー感に乏しくなってしまう問題がある。オープンフレッシュベーカリーで販売されているような焼き立てのものは焼成工程により融解した油脂がほとんど固化していない状態で販売されている為、口の中に液状の油脂が広がりジューシーに感じる。一方、コンビニエンスストア、量販店では配送などに時間がかかるため油脂が固化し易く、上記のとおり高融点脂を配合することにより更に固化が早まってしまいジューシー感が得難くなっている。   In order to overcome such problems, high melting point fat is blended in the oil phase of the water-in-oil emulsion composition for roll-in, there is little change in hardness in a wide temperature range, and excellent extensibility, and melted out with a proofer. Although the method of preventing it is generally known, croissants, pies and Danish pastries obtained by using these have a problem that the juicy feeling is poor. Freshly baked products such as those sold in open fresh bakery are sold in a state where the fats and oils melted by the baking process are hardly solidified, so the liquid fat spreads in the mouth and feels juicy. On the other hand, at convenience stores and mass retailers, it takes time for delivery and the like, so that the oils and fats are easily solidified, and by adding the high melting point fat as described above, the solidification is further accelerated and it is difficult to obtain a juicy feeling.

上記問題にあたり、これまで数々の発明がなされてきている。特許文献1では、バター脂を分別したステアリン画分を用いたマーガリンが開示されている。特許文献2では、沃素価が10以下であり、全構成脂肪酸のうち炭素数18以上の構成脂肪酸が80重量%以上である脂肪Aと、沃素価20以下であり、全構成脂肪酸のうち炭素数14以下の構成脂肪酸が60重量%以上である脂肪Bとを、脂肪A/脂肪B=10/90〜90/10の重量比率で混合後、ランダムエステル交換したエステル交換油脂C、及び乳脂肪を含有することを特徴とするロールイン用油脂組成物が開示されている。特許文献3では、乳脂、乳脂の分別油の中から選ばれた1種又は2種以上の油脂(A)を油相中に5〜90重量%、2位の構成脂肪酸がH(炭素数16以上の飽和脂肪酸)であるトリグリセリドを20重量%以上含有する油脂(B)を油相中に5重量%以上含有し、該油脂(A)と該油脂(B)の重量比率が油脂(B)/油脂(A)≧0.2であることを特徴とする可塑性油脂組成物が開示されている。しかしながらこれらの発明は風味や口どけがよい焼成品が得られるとしているが焼き立てのジューシー感は得られがたかった。   Numerous inventions have been made for the above problems. Patent Document 1 discloses margarine using a stearin fraction obtained by fractionating butterfat. In Patent Document 2, an iodine value of 10 or less and a fatty acid A in which a constituent fatty acid having 18 or more carbon atoms out of all the constituent fatty acids is 80% by weight or more and a iodine number of 20 or less and a carbon number in the total constituent fatty acids. Fat B, whose constituent fatty acid of 14 or less is 60% by weight or more, is mixed at a weight ratio of Fat A / Fat B = 10/90 to 90/10, and then transesterified oil C and milk fat subjected to random transesterification. An oil and fat composition for roll-in characterized by containing is disclosed. According to Patent Document 3, one or two or more kinds of fats and oils (A) selected from milk fat and milk oil fractionation oil are 5 to 90% by weight in the oil phase, and the constituent fatty acid at the 2nd position is H (16 carbon atoms). The oil and fat (B) containing at least 20% by weight of triglyceride, which is the above saturated fatty acid), is contained in the oil phase in an amount of 5% by weight or more, and the weight ratio between the oil and fat (A) and the oil and fat (B) is fat and oil (B). / Plastic oil composition characterized in that oil / fat (A) ≧ 0.2 is disclosed. However, although these inventions say that a baked product with good flavor and mouthfeel can be obtained, it is difficult to obtain a freshly succulent feeling.

特許文献4では油相中のSXXで表されるトリグリセリド(SXX)とSXSで表されるトリグリセリド(SXS)との合計量が6〜60重量%であり、該油相中のSXX/(SXX+SXS)が0.5以上であることを特徴とするロールイン用油脂組成物〔但し、S:炭素数16以上の飽和脂肪酸、X:炭素数16以上のトランス型の不飽和脂肪酸〕が開示されており焼成品の口どけが良いとしているが焼き立てのジューシー感は得られがたかった。   In Patent Document 4, the total amount of triglyceride (SXX) represented by SXX in the oil phase and triglyceride (SXS) represented by SXS is 6 to 60% by weight, and SXX / (SXX + SXS) in the oil phase. Is disclosed in which an oil-and-fat composition for roll-in [wherein S is a saturated fatty acid having 16 or more carbon atoms and X is a trans-type unsaturated fatty acid having 16 or more carbon atoms] is disclosed. Although the mouth of the baked product is said to be good, it was difficult to obtain a freshly juicy feeling.

作業性を改善し、ホイロ耐性を向上させる発明として特許文献5、特許文献6、特許文献7など水相の工夫に基づく発明もなされているが焼き立てのジューシー感が得られるかについては言及されていない。   As inventions that improve workability and improve proof resistance, Patent Literature 5, Patent Literature 6, Patent Literature 7 and other inventions have been made based on the idea of the aqueous phase, but mention has been made as to whether a succulent juicy feeling can be obtained. Absent.

油中水型乳化組成物にシュガーエステル又は/及びポリグリセリン脂肪酸エステルを使用する発明として特許文献8、特許文献9など多々開示されているが、焼き立てのジューシー感が得られるかについては言及されていない。   Patent Document 8 and Patent Document 9 disclose various inventions that use sugar esters or / and polyglycerin fatty acid esters in water-in-oil emulsion compositions, but mention is made of whether a freshly succulent feeling can be obtained. Absent.

特開2000−166469号公報JP 2000-166469 A 特開2002−253117号公報JP 2002-253117 A 特開2003−3194号公報JP 2003-3194 A 特開2002−371296号公報JP 2002-371296 A 特開昭59−11141号公報JP 59-111141 A 特開2002−262772号公報Japanese Patent Application Laid-Open No. 2002-262772 特開平9−87657号公報JP-A-9-87657 特開2004−350580号公報JP 2004-350580 A 特開2000−116322号公報JP 2000-116322 A

本発明の目的は、パイ、デニッシュペストリーなどの層状膨化小麦粉食品を製造する際に用いられるロールイン用油中水型乳化組成物であって、作業性に優れ、発酵の温度を低くするなど製造効率を減ずることなく美しい内層の焼成品が得られ、且つ、口当たりの良いジューシー感を呈することができるロールイン用油中水型乳化組成物を提供することにある。   The object of the present invention is a water-in-oil emulsion composition for roll-in used for producing layered expanded flour foods such as pies and Danish pastries, which is excellent in workability and manufactured at a low fermentation temperature. An object of the present invention is to provide a water-in-oil emulsion composition for roll-in which can obtain a beautiful baked product with an inner layer without reducing the efficiency, and can provide a palatable juicy feeling.

本発明者らは、ロールイン用油中水型乳化組成物中の油脂の結晶析出に着眼し、数多くの試行錯誤を繰り返しある特定の結晶調整剤が有効であるという知見を得、本発明を完成するに至った。   The present inventors have focused on the precipitation of oil and fat in the water-in-oil emulsion composition for roll-in and obtained the knowledge that a specific crystal modifier is effective by repeating many trials and errors. It came to be completed.

即ち本発明の第1は、油中水型乳化組成物を構成する油相の融点が33〜40℃の範囲であり、油相の油脂原料が菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油の植物性油脂並びに乳脂、牛脂、ラード、魚油、鯨油の動物性油脂の混合油或いはそれらの硬化、分別、エステル交換を施した加工油脂であり、且つ油相の油脂原料のSFCが10℃で30〜70、20℃で10〜45、30℃で2〜25であり、当該油脂原料を60℃で60分置いた後、25℃に移し60分後のSFCを(A)、シュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルからなる群より選ばれた1種以上であり、構成する全脂肪酸の25重量%以上がラウリン酸、エルカ酸から選ばれる1種又は2種を含有し、且つ平均エステル化度が30%以上である結晶調整剤を含有させた油脂原料を60℃で60分置いた後、25℃に移し60分後のSFCを(B)とした場合、(A)≧5、且つ(B)/(A)≦0.75となる結晶調整剤を含有するロールイン用油中水型乳化組成物である。第2は、油中水型乳化組成物の油分が70〜99重量%である、第1記載のロールイン用油中水型乳化組成物である。第3は、結晶調整剤がシュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルからなる群より選ばれた1種以上であり、構成する全脂肪酸の35重量%以上がラウリン酸、エルカ酸から選ばれる1種又は2種を含有し、且つ平均エステル化度が30%以上である、第1記載のロールイン用油中水型乳化組成物である。第4は、油中水型乳化組成物全体に対して結晶調整剤を0.07〜3.5重量%含有する、第1記載のロールイン用油中水型乳化組成物である。第5は、油相を構成するトリグリセライド中、3個の構成脂肪酸のうち2個以上がオレイン酸、リノール酸、リノレン酸から選ばれる1種又は2種よりなるトリグリセライドを16〜50重量%含有する、第1乃至第の何れか1に記載のロールイン用油中水型乳化組成物である。第6は、油中水型乳化組成物を構成する原料油脂中乳由来の脂肪が60重量%以下である、第1乃至第の何れか1に記載のロールイン用油中水型乳化組成物である。第7は、第1乃至第の何れか1に記載のロールイン用油中水型乳化組成物を使用してなる、層状膨化小麦粉食品である。 That is, the first aspect of the present invention is that the oil phase constituting the water-in-oil emulsion composition has a melting point in the range of 33 to 40 ° C., and the oily raw material for the oil phase is rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut Oil, rice bran oil, corn oil, safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, shea fat, monkey fat, cocoa butter, coconut oil, vegetable oil of palm kernel oil and milk fat, beef tallow, lard , Mixed oil of animal oils and fats of fish oil and whale oil or processed oils and oils obtained by curing, fractionation and transesterification thereof, and SFC of the oil phase fats and oils is 30 to 70 at 10 ° C. and 10 to 45 at 20 ° C. The oil and fat raw material is placed at 60 ° C. for 60 minutes and then moved to 25 ° C., and the SFC after 60 minutes is composed of (A), a sugar ester, a polyglycerin fatty acid ester and a sorbitan fatty acid ester. Than group And a barre was 1 or more, configured to 25% by weight or more lauric acid of the total fatty acids, containing one or two elements selected from erucic acid, and an average degree of esterification is 30% or more crystallization modifiers When the contained oil and fat raw material is placed at 60 ° C. for 60 minutes and then transferred to 25 ° C. and the SFC after 60 minutes is (B), (A) ≧ 5 and (B) / (A) ≦ 0.75 It is a water-in-oil emulsion composition for roll-in containing a crystal modifier. The second is the water- in- oil emulsion composition for roll-in according to the first aspect, wherein the oil-in-water emulsion composition has an oil content of 70 to 99% by weight . Third, the crystal modifier is one or more selected from the group consisting of sugar esters, polyglycerol fatty acid esters and sorbitan fatty acid esters, and 35% by weight or more of the total fatty acids are selected from lauric acid and erucic acid. The water-in-oil emulsified composition for roll-in according to the first aspect , which contains one or two kinds and has an average degree of esterification of 30% or more . 4th is a water-in-oil emulsion composition for roll-ins of 1 which contains 0.07 to 3.5 weight% of crystal regulators with respect to the whole water-in-oil emulsion composition. 5thly, the triglyceride which comprises an oil phase contains 16 to 50weight% of the triglyceride which 2 or more of three structural fatty acids consist of 1 type or 2 types chosen from oleic acid, linoleic acid, and linolenic acid. The water-in-oil emulsion composition for roll-in according to any one of 1st to 4th . Sixth, the water-in-oil emulsified composition for roll-in according to any one of the first to fifth , wherein the fat derived from the raw oil-and-fat milk constituting the water-in-oil emulsion composition is 60% by weight or less. It is a thing. The seventh is a layered puffed flour food product using the water-in-oil emulsion composition for roll-in according to any one of the first to sixth .

本発明により、パイ、デニッシュペストリーなどの層状膨化小麦粉食品を製造する際に作業性に優れ、発酵の温度を低くするなど製造効率を減ずることなく美しい内層の焼成品が得られ、且つ、口当たりの良いジューシー感を表現することが可能になった。   According to the present invention, it is excellent in workability when producing layered puffed flour foods such as pies and Danish pastries, and a beautiful inner layer baked product can be obtained without reducing the production efficiency such as lowering the temperature of fermentation. It became possible to express a good juicy feeling.

本発明のロールイン用油中水型乳化組成物に使用する油脂原料としては例えば、菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油等の植物性油脂並びに乳脂、牛脂、ラード、魚油、鯨油等の動物性油脂が例示でき、上記油脂類の単独又は混合油或いはそれらの硬化、分別、エステル交換等を施した加工油脂が適する。   Examples of oils and fats used in the water-in-oil emulsion composition for roll-in of the present invention include rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, safflower oil, olive oil, and kapok oil. And vegetable oils such as sesame oil, evening primrose oil, palm oil, shea fat, monkey fat, cacao fat, coconut oil, palm kernel oil, and animal fats such as milk fat, beef fat, lard, fish oil, whale oil, etc. Of these, single or mixed oils or processed oils and fats that have been cured, fractionated, transesterified or the like are suitable.

本発明のロールイン用油中水型乳化組成物を構成する油脂原料は、10℃におけるSFCが30〜70、20℃におけるSFCが10〜45、30℃におけるSFCが2〜25であるのが好ましい。
このSFCは油脂の固体脂指数を表わすものであって測定方法としては、AOCS Official Method第5版Cd16−81に準じて、60℃に60分置いた後、0℃に移し60分置いた後、各測定温度に移し30分後に測定したものである。下限未満ではロールイン用油中水型乳化組成物が軟らかくなりすぎ、ロールイン作業時に生地が縮んでしまい焼成品の内層が不均一になったり、油中水型乳化組成物が生地に練り込まれてしまい焼成品の内層が詰まってしまったりして好ましくない。上限を超える場合はロールイン用油中水型乳化組成物が硬くなりすぎてしまい場合によっては可塑性を失ってしまい、ロールイン作業時に油中水型乳化組成物が割れてしまい、焼成品の内層が不均一になってしまい好ましくない。
The oil and fat raw material constituting the water-in-oil emulsion composition for roll-in of the present invention has an SFC of 30 to 70 at 10 ° C, an SFC of 10 to 45 at 20 ° C, and an SFC of 2 to 25 at 30 ° C. preferable.
This SFC represents the solid fat index of fats and oils, and as a measuring method, according to AOCS Official Method 5th edition Cd16-81, after 60 minutes at 60 ° C., after moving to 0 ° C. and 60 minutes Measured 30 minutes after moving to each measurement temperature. Below the lower limit, the water-in-oil emulsion composition for roll-in becomes too soft, the dough shrinks during the roll-in operation, the inner layer of the baked product becomes uneven, or the water-in-oil emulsion composition is kneaded into the dough. It is not preferable because the inner layer of the fired product is clogged. When the upper limit is exceeded, the water-in-oil emulsion composition for roll-in becomes too hard, and in some cases, the plasticity is lost, the water-in-oil emulsion composition breaks during the roll-in operation, and the inner layer of the baked product Becomes ununiform.

本発明のロールイン用油中水型乳化組成物は結晶調整剤を含有させる必要がある。本発明でいう結晶調整剤とは、原料油脂に添加することにより原料油脂の固化状態に影響を及ぼすもののことを指し、乳化剤として一般的に油中水型乳化組成物に使用されるものも含まれる場合がある。結晶調整剤としては結晶析出を遅延させるものが好適で、油脂原料を60℃で60分置いた後、25℃に移し60分後のSFCを(A)、結晶調整剤を含有させた油脂原料を60℃で60分置いた後、25℃に移し60分後のSFCを(B)とした場合、(A)≧5、好ましくは(A)≧7、更に好ましくは(A)≧10、且つ(B)/(A)≦0.75、好ましくは(B)/(A)≦0.50、更に好ましくは(B)/(A)≦0.30、最も好ましくは(B)/(A)≦0.10となる結晶調整剤を含有させたロールイン用油中水型乳化組成物である。当該乳化組成物を用いた焼成品において目的とする口当たりの良いジューシー感を得ることができる。
(A)、(B)については上記温度処理を行い25℃で測定したものである。温度処理以外はAOCS Official Method第5版Cd16−81に準じて測定することにより得ることができる。
The water-in-oil emulsion composition for roll-in of the present invention must contain a crystal modifier. The term "crystal modifier" as used in the present invention refers to those that affect the solidified state of raw oils and fats when added to raw oils and fats, and include those that are generally used in water-in-oil emulsion compositions as emulsifiers. May be. As the crystal modifier, those that delay the precipitation of crystals are suitable. After putting the fat and oil raw material at 60 ° C. for 60 minutes, the SFC after 60 minutes is transferred to 25 ° C. (A), and the fat and oil raw material containing the crystal modifier Is placed at 60 ° C. for 60 minutes, then moved to 25 ° C. and SFC after 60 minutes is defined as (B), (A) ≧ 5, preferably (A) ≧ 7, more preferably (A) ≧ 10, And (B) / (A) ≦ 0.75, preferably (B) / (A) ≦ 0.50, more preferably (B) / (A) ≦ 0.30, most preferably (B) / ( A) A water-in-oil emulsified composition for roll-in containing a crystal modifier satisfying ≦ 0.10. In the baked product using the emulsified composition, a desired juicy feeling can be obtained.
(A) and (B) were measured at 25 ° C. after the above temperature treatment. Except temperature treatment, it can be obtained by measuring according to AOCS Official Method 5th edition Cd16-81.

本発明のロールイン用油中水型乳化組成物は、該ロールイン用油中水型乳化組成物を構成する油相の融点が33℃〜40℃の範囲であるのが好ましく、34℃〜40℃の範囲が更に好ましく、35℃〜40℃の範囲が最も好ましい。本発明でいう油相はロールイン用油中水型乳化組成物を融解させ水及び水溶性成分を取り除くなどにより得ることができる、油脂原料を主体とし乳化剤、着色料、香料、結晶調整剤など油溶性添加剤を含有する成分のことを言う。下限未満ではホイロ工程において発酵槽の温度が高い場合、油中水型乳化組成物が融解し流れ出してしまい得られた焼成品の風味が低下してしまったり、ボリュームが劣ってしまい好ましくない。発酵槽の温度を下げることにより上記問題は克服できるが発酵に時間がかかり効率が悪くなるので好ましくない。ホイロ耐性を考慮した場合、融点は40℃未満で充分である。40℃を超える場合は口どけが悪くなるなどの問題が生じ好ましくない。   In the water-in-oil emulsion composition for roll-in of the present invention, the melting point of the oil phase constituting the water-in-oil emulsion composition for roll-in is preferably in the range of 33 ° C to 40 ° C. A range of 40 ° C. is more preferable, and a range of 35 ° C. to 40 ° C. is most preferable. The oil phase referred to in the present invention can be obtained by melting a water-in-oil emulsion composition for roll-in and removing water and water-soluble components. The emulsifier, colorant, fragrance, crystal modifier, etc. It refers to a component containing an oil-soluble additive. Below the lower limit, if the temperature of the fermenter is high in the proofing process, the water-in-oil emulsified composition melts and flows out, and the flavor of the baked product obtained is lowered or the volume is inferior. The above problem can be overcome by lowering the temperature of the fermenter, but this is not preferable because it takes time for fermentation and the efficiency is lowered. In consideration of proof resistance, a melting point of less than 40 ° C is sufficient. If it exceeds 40 ° C., problems such as poor mouthfeel occur, which is not preferable.

本発明のロールイン用油中水型乳化組成物に含有する結晶調整剤としてはシュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルからなる群より選ばれた1種以上が好ましく、中でもシュガーエステルが好ましい。シュガーエステルはアセチル化処理されたものでも同等若しくはそれ以上の効果が期待できる。シュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルを構成する脂肪酸としてはカプリン酸、カプリル酸、ラウリン酸、ミリスチン酸、オレイン酸、リノール酸、リノレン酸、エルカ酸から選ばれる1種類以上を含有することが好ましく、ラウリン酸、オレイン酸、リノール酸、リノレン酸、エルカ酸から選ばれる1種類以上を含有することが更に好ましく、ラウリン酸、エルカ酸から選ばれる1種又は2種を含有することが最も好ましく、該ロールイン用油中水型乳化組成物を使用して得られた層状小麦膨化食品において目的とする口当たりの良いジューシー感が得られる。   The crystal modifier contained in the water-in-oil emulsion composition for roll-in of the present invention is preferably at least one selected from the group consisting of sugar esters, polyglycerol fatty acid esters and sorbitan fatty acid esters, and sugar esters are particularly preferable. . Even if sugar ester is acetylated, the same or higher effect can be expected. The fatty acid constituting sugar ester, polyglycerin fatty acid ester and sorbitan fatty acid ester contains at least one selected from capric acid, caprylic acid, lauric acid, myristic acid, oleic acid, linoleic acid, linolenic acid and erucic acid It is more preferable that it contains one or more selected from lauric acid, oleic acid, linoleic acid, linolenic acid, and erucic acid, and most preferably contains one or two selected from lauric acid and erucic acid. Preferably, the desired palatable juicy feeling is obtained in the layered wheat puffed food obtained by using the water-in-oil emulsion composition for roll-in.

更に上記脂肪酸は該シュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルを構成する全脂肪酸量の25重量%以上であることが好ましく、35重量%以上であることが更に好ましく、50重量%以上であることが最も好ましい。下限未満の場合、該ロールイン用油中水型乳化組成物を使用して得られた層状小麦膨化食品において目的とする口当たりの良いジューシー感が得られ難くなる。   Furthermore, the fatty acid is preferably 25% by weight or more of the total amount of fatty acids constituting the sugar ester, polyglycerin fatty acid ester and sorbitan fatty acid ester, more preferably 35% by weight or more, and 50% by weight or more. Most preferred. When it is less than the lower limit, it becomes difficult to obtain a desired mouth-feeling juicy feeling in the layered wheat puffed food obtained by using the water-in-oil emulsion composition for roll-in.

本発明のロールイン用油中水型乳化組成物は、油中水型乳化組成物全体に対して結晶調整剤を0.07〜3.5重量%含有することが好ましく、0.08〜2.5重量%含有することが更に好ましく、0.1〜1.5重量%含有することが最も好ましい。下限未満では該ロールイン用油中水型乳化組成物を使用して得られた層状小麦膨化食品において目的とする口当たりの良いジューシー感が得られ難くなる。上限を超える場合はホイロ耐性が劣ってしまう為ボリュームが出にくくなったり、風味成分が溶け出してしまう場合があり好ましくない。   The water-in-oil emulsion composition for roll-in of the present invention preferably contains 0.07 to 3.5% by weight of a crystal modifier based on the entire water-in-oil emulsion composition, and 0.08 to 2 More preferably, the content is 5% by weight, and most preferably 0.1 to 1.5% by weight. If it is less than the lower limit, it is difficult to obtain a desired mouth-feeling juicy feeling in the layered wheat expanded food obtained using the water-in-oil emulsion composition for roll-in. If the upper limit is exceeded, the proof resistance is inferior, so that it is difficult to produce a volume or the flavor component may be dissolved out, which is not preferable.

本発明のロールイン用油中水型乳化組成物に含有させるシュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルの脂肪酸の平均エステル化度が30%以上であることが好ましく、50%以上であることが更に好ましい。下限未満の場合、該ロールイン用油中水型乳化組成物を使用して得られた層状小麦膨化食品において目的とする口当たりの良いジューシー感が得られ難くなる。   The average esterification degree of the fatty acid of the sugar ester, polyglycerin fatty acid ester and sorbitan fatty acid ester contained in the water-in-oil emulsion composition for roll-in of the present invention is preferably 30% or more, and 50% or more. Is more preferable. When it is less than the lower limit, it becomes difficult to obtain a desired mouth-feeling juicy feeling in the layered wheat puffed food obtained by using the water-in-oil emulsion composition for roll-in.

本発明のロールイン用油中水型乳化組成物は油相を構成するトリグリセライド中、3個の構成脂肪酸のうち2個以上がオレイン酸、リノール酸、リノレン酸から選ばれる1種又は2種よりなるトリグリセライドを16〜50重量%含有することが好ましく、20〜40重量%であることが更に好ましい。下限未満の場合は、該ロールイン用油中水型乳化組成物を使用して得られた層状小麦膨化食品において目的とする口当たりの良いジューシー感が得られ難くなる。上限を超える場合は該ロールイン用油中水型乳化組成物のコシが弱くなり、生地へのロールイン時に生地に練り込まれてしまったり、生地が縮んでしまったりして得られる焼成品の内層が詰まってしまったり、不均一になり好ましくない。   The water-in-oil emulsified composition for roll-in of the present invention comprises one or two selected from oleic acid, linoleic acid, and linolenic acid in the triglyceride constituting the oil phase, wherein two or more of the three constituent fatty acids are selected from oleic acid, linoleic acid, and linolenic acid. It is preferable to contain the triglyceride which becomes 16 to 50 weight%, and it is still more preferable that it is 20 to 40 weight%. When it is less than the lower limit, it becomes difficult to obtain a desired mouth-feeling juicy feeling in the layered wheat puffed food obtained using the water-in-oil emulsion composition for roll-in. When the upper limit is exceeded, the stiffness of the water-in-oil emulsion composition for roll-in becomes weak, and the baked product obtained by kneading into the dough at the time of roll-in to the dough or shrinking the dough The inner layer is clogged or uneven, which is not preferable.

本発明のロールイン用油中水型乳化組成物は該油中水型乳化組成物を構成する油脂中乳由来の脂肪が60重量%以下、好ましくは45重量%以下、更に好ましくは35重量%以下であることが好ましい。 上限を超える場合は乳由来の脂肪特有の低温で硬い物性となってしまい該ロールイン用油中水型乳化組成物を生地へロールインするときに割れてしまい、得られた焼成品の内層が不均一になったり、ボリュームにばらつきが出てしまうなど作業適性を著しく失ってしまい好ましくない。下限は特に限定しないが、乳由来の脂肪を含有させることにより風味が良好となる為、該油中水型乳化組成物を構成する油脂中2重量%以上含有させるのが好ましい。   The water-in-oil emulsion composition for roll-in of the present invention contains 60% by weight or less, preferably 45% by weight or less, and more preferably 35% by weight of fat derived from fats and oils constituting the water-in-oil emulsion composition. The following is preferable. If it exceeds the upper limit, it becomes hard at a low temperature peculiar to fat derived from milk and cracks when the water-in-oil emulsion composition for roll-in is rolled into the dough, and the inner layer of the obtained baked product is It is not preferable because workability is remarkably lost such as non-uniformity and variation in volume. Although a minimum is not specifically limited, Since flavor will become favorable by containing the fat derived from milk, it is preferable to make it contain 2weight% or more in the fats and oils which comprise this water-in-oil emulsion composition.

本発明のロールイン用油中水型乳化組成物の油分は70〜99重量%が好ましく、80〜98重量%が更に好ましく、85〜98重量%が最も好ましい。該ロールイン用油中水型乳化組成物を使用して得られた層状小麦膨化食品において目的とする口当たりの良いジューシー感が得られ難くなる。上限を超える場合は水相に含有させる風味成分が制限される為好ましくない。   The oil content of the water-in-oil emulsion composition for roll-in of the present invention is preferably 70 to 99% by weight, more preferably 80 to 98% by weight, and most preferably 85 to 98% by weight. In the layered wheat puffed food obtained by using the water-in-oil emulsion composition for roll-in, it is difficult to obtain a desired pleasant and juicy feeling. When exceeding an upper limit, since the flavor component contained in a water phase is restrict | limited, it is unpreferable.

本発明の油中水型乳化組成物は必要に応じて乳化剤を添加しても良い。乳化剤としてはレシチン、グリセリン脂肪酸エステル、ポリグリセリン縮合リシノレイン酸エステル、シュガーエステル、ポリグリセリン脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、プロピレングリコール脂肪酸エステルおよび酢酸モノグリセリド、酒石酸モノグリセリド、酢酸酒石酸混合モノグリセリド、クエン酸モノグリセリド、ジアセチル酒石酸モノグリセリド、乳酸モノグリセリド、コハク酸モノグリセリド、リンゴ酸モノグリセリド等各種有機酸モノグリセリド、ステアロイル乳酸カルシウム、ステアロイル乳酸ナトリウムなどが挙げられる。   An emulsifier may be added to the water-in-oil emulsion composition of the present invention as necessary. As emulsifiers, lecithin, glycerin fatty acid ester, polyglycerin condensed ricinoleic acid ester, sugar ester, polyglycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, propylene glycol fatty acid ester and acetic acid monoglyceride, tartaric acid monoglyceride, mixed tartaric acid monoglyceride Citric acid monoglyceride, diacetyltartaric acid monoglyceride, lactic acid monoglyceride, succinic acid monoglyceride, various organic acid monoglycerides such as malic acid monoglyceride, stearoyl calcium lactate, and stearoyl sodium lactate.

本発明において、上記の原料、添加物の他に、所望により、色素、抗酸化剤、香料などの油溶性成分、食塩、糖類、粉乳、発酵乳などの水溶性成分を使用することができる。   In the present invention, in addition to the above-mentioned raw materials and additives, oil-soluble components such as pigments, antioxidants, and fragrances, and water-soluble components such as salt, saccharides, milk powder, and fermented milk can be used as desired.

本発明のロールイン用油中水型乳化組成物の製造法については特に限定されないが、常法通り油相と水相とを予備乳化した後、パーフェクター、ボテーター、コンビネーターなどで急冷捏和することにより製造することができる。油相は、融解した油脂に必要に応じて色素、抗酸化剤、香料等の油溶性成分を添加、溶解/分散させ調製することができる。水相は水又は温水に水溶性の乳成分、必要に応じて食塩、糖類、無機塩類等を添加、溶解/分散させ調製することができる。   The method for producing the water-in-oil emulsion composition for roll-in of the present invention is not particularly limited. Can be manufactured. The oil phase can be prepared by adding and dissolving / dispersing oil-soluble components such as pigments, antioxidants, and fragrances as necessary to the melted fats and oils. The aqueous phase can be prepared by adding and dissolving / dispersing a water-soluble milk component in water or warm water, and if necessary, sodium chloride, saccharides, inorganic salts and the like.

本発明の層状膨化小麦粉食品は、生地を薄く延ばし、これにロールイン用油中水型乳化組成物をのせて折りたたみ、再び薄く延ばすことを繰り返し生地を作り、焼成することにより得ることが出来る。このようにして得られた層状膨化小麦粉食品の具体例としてはデニッシュペストリー、クロワッサン、パイ等が例示できる。   The layered puffed flour food of the present invention can be obtained by thinly extending the dough, placing the water-in-oil emulsion composition for roll-in on it, folding it, and extending it thinly again to make a dough and baking it. Specific examples of the layered expanded flour food thus obtained include Danish pastries, croissants, and pies.

以下に本発明の実施例を示し本発明をより詳細に説明するが、本発明の精神は以下の実施例に限定されるものではない。なお、例中、%及び部は、いずれも重量基準を意味する。   EXAMPLES The present invention will be described in more detail with reference to the following examples, but the spirit of the present invention is not limited to the following examples. In the examples, “%” and “part” mean weight basis.

実験例1
バター20部、大豆硬化油(上昇融点50℃)10部、パーム分別硬化油(上昇融点38℃)20部、菜種硬化油(上昇融点35℃)10部、大豆油30部、飽和モノグリセリド(『エマルジーMS』理研ビタミン株式会社製)0.5部、大豆レシチン(『SLPペースト』辻製油株式会社製)0.3部、ラウリン酸シュガーエステル(『リョートーシュガーエステルL−195』三菱化学フーズ株式会社製)0.5部を60℃で混合し、油相を得た、60℃の水9部に食塩1部を溶解させ水相を得た。油相と水相とを60℃で混合攪拌し予備乳化させ、コンビネーターにより急冷捏和し、実験例1の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表1に纏めた。実験例1の油中水型乳化組成物について、(A)=13.7、(B)/(A)=0.03であった。
Experimental example 1
20 parts butter, 10 parts soybean hardened oil (increased melting point 50 ° C.), 20 parts palm fractionated cured oil (increased melting point 38 ° C.), 10 parts rapeseed oil hardened (increased melting point 35 ° C.), 30 parts soybean oil, saturated monoglyceride (“ Emulsy MS (Riken Vitamin Co., Ltd.) 0.5 parts, soy lecithin (SLP Paste Sakai Oil Co., Ltd.) 0.3 parts, lauric sugar ester (Ryoto Sugar Ester L-195) Mitsubishi Chemical Foods Co., Ltd. 0.5 parts (made by company) was mixed at 60 ° C. to obtain an oil phase. 1 part of sodium chloride was dissolved in 9 parts of water at 60 ° C. to obtain an aqueous phase. The oil phase and the aqueous phase were mixed and stirred at 60 ° C., preliminarily emulsified, and rapidly cooled and kneaded with a combinator to obtain a water-in-oil emulsion composition for roll-in with good structure in Experimental Example 1. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 1. Regarding the water-in-oil emulsion composition of Experimental Example 1, (A) = 13.7 and (B) / (A) = 0.03.

実験例2
実験例1において、ラウリン酸シュガーエステル0.5部をエルカ酸シュガーエステル(『リョートーシュガーエステルER190』三菱化学フーズ株式会社製)0.5部に代えた以外は実験例1に準じて実施し実験例2の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表1に纏めた。実験例2の油中水型乳化組成物について、(A)=13.7、(B)/(A)=0.05であった。
Experimental example 2
In Experimental Example 1, the same procedure as in Experimental Example 1 was performed except that 0.5 part of lauric acid sugar ester was replaced with 0.5 part of erucic acid sugar ester ("Ryoto Sugar Ester ER190" manufactured by Mitsubishi Chemical Foods Co., Ltd.). The water-in-oil emulsion composition for roll-in having a good structure of Experimental Example 2 was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 1. Regarding the water-in-oil emulsion composition of Experimental Example 2, (A) = 13.7 and (B) / (A) = 0.05.

実験例3
実験例1において、ラウリン酸シュガーエステル0.5部をエルカ酸オクタグリセリンエステル(『SYグリスターOE−750』阪本薬品工業株式会社製)1.0部に代えた以外は実験例1に準じて実施し実験例3の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表1に纏めた。実験例3の油中水型乳化組成物について、(A)=13.7、(B)/(A)=0.52であった。
Experimental example 3
The same procedure as in Experimental Example 1 was performed except that 0.5 part of lauric acid sugar ester was replaced with 1.0 part of erucic acid octaglycerin ester (“SY Glyster OE-750” manufactured by Sakamoto Pharmaceutical Co., Ltd.) in Experimental Example 1. Thus, a water-in-oil emulsion composition for roll-in having a good structure of Experimental Example 3 was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 1. Regarding the water-in-oil emulsion composition of Experimental Example 3, (A) = 13.7 and (B) / (A) = 0.52.

実験例4
実験例1において、バター20部を30部に、大豆硬化油10部を15部に、大豆油30部を25部に、ラウリン酸シュガーエステル0.5部を1.0部に代え、菜種硬化油10部を省いた以外は実験例1に準じて実施し実験例4の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表1に纏めた。実験例4の油中水型乳化組成物について、(A)=17.2、(B)/(A)=0.05であった。
Experimental Example 4
In Experimental Example 1, 20 parts of butter was changed to 30 parts, 10 parts of soybean hardened oil to 15 parts, 30 parts of soybean oil to 25 parts, 0.5 parts of lauric sugar ester to 1.0 part, Except that 10 parts of oil was omitted, the same procedure as in Experimental Example 1 was carried out to obtain a water-in-oil emulsion composition for roll-in of Experimental Example 4 with good structure. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 1. Regarding the water-in-oil emulsion composition of Experimental Example 4, (A) = 17.2 and (B) / (A) = 0.05.

実験例5
実験例1において、バター20部を30部に大豆硬化油10部を8部に、大豆油30部を22部に代えた以外は実験例1に準じて実施し実験例5の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表1に纏めた。実験例5の油中水型乳化組成物について、(A)=10.5、(B)/(A)=0.01であった。
Experimental Example 5
In Example 1, the roll with good structure of Example 5 was carried out according to Example 1 except that 20 parts of butter, 10 parts of soybean hardened oil were changed to 8 parts, and 30 parts of soybean oil were changed to 22 parts. A water-in-oil emulsion composition for in was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 1. Regarding the water-in-oil emulsion composition of Experimental Example 5, (A) = 10.5 and (B) / (A) = 0.01.

実験例6
実験例1において、大豆硬化油10部を8部に、パーム分別硬化油20部を30部に、菜種硬化油10部を25部に、大豆油30部を27部に代え、バター20部を除いた以外は実験例1に準じて実施し実験例6の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表1に纏めた。実験例6の油中水型乳化組成物について、(A)=18.1、(B)/(A)=0.06であった。
Experimental Example 6
In Experimental Example 1, 10 parts of soybean hardened oil is replaced with 8 parts, 20 parts of palm fractionated hardened oil is replaced with 30 parts, 10 parts of rapeseed cured oil is replaced with 25 parts, 30 parts of soybean oil is replaced with 27 parts, and 20 parts of butter is replaced with 20 parts of butter. Except for the removal, the same procedure as in Experimental Example 1 was carried out to obtain a water-in-oil emulsion composition for roll-in of Experimental Example 6 with good structure. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 1. Regarding the water-in-oil emulsion composition of Experimental Example 6, (A) = 18.1 and (B) / (A) = 0.06.

実験例7
実験例1において、バター20部を30部に、大豆硬化油10部を5部に、菜種硬化油10部を22部に、大豆油30部を13部に代えた以外は実験例1に準じて実施し実験例7の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表2に纏めた。実験例7の油中水型乳化組成物について、(A)=17.2、(B)/(A)=0.02であった。
Experimental Example 7
In Experimental Example 1, according to Experimental Example 1, except that 20 parts of butter was changed to 30 parts, 10 parts of soybean hardened oil to 5 parts, 10 parts of rapeseed oil was changed to 22 parts, and 30 parts of soybean oil was changed to 13 parts. The water-in-oil emulsified composition for roll-in of Experimental Example 7 having a good structure was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Experimental Example 7, (A) = 17.2 and (B) / (A) = 0.02.

表1に実験例1〜実験例7の配合と結果を纏めた。

Figure 0005076898
Table 1 summarizes the formulations and results of Experimental Examples 1 to 7.
Figure 0005076898

比較実験例1
実験例1において、飽和モノグリセリド0.5部、大豆レシチン0.3部、ラウリン酸シュガーエステル0.5部の3種類を除いた以外は実験例1に準じて実施し比較実験例1の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表2に纏めた。比較実験例1の油中水型乳化組成物について、(A)=13.7であった。
Comparative Experiment Example 1
In Example 1, except for three types of saturated monoglyceride 0.5 part, soy lecithin 0.3 part, and lauric acid sugar ester 0.5 part, the experiment was conducted according to Example 1 and the structure of Comparative Example 1 was good. A water-in-oil emulsion composition for roll-in was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Comparative Experimental Example 1, (A) = 13.7.

比較実験例2
実験例1において、ラウリン酸シュガーエステル0.5部のみを除いた以外は実験例1に準じて実施し比較実験例2の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表2に纏めた。比較実験例2の油中水型乳化組成物について、(A)=13.7、(B)/(A)=1.03であった。
Comparative Experiment Example 2
In Experimental example 1, it carried out according to Experimental example 1 except having removed only 0.5 parts of lauric acid sugar ester, and the water-in-oil type emulsion composition for roll-in of comparative experimental example 2 with good structure was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Comparative Experimental Example 2, (A) = 13.7 and (B) / (A) = 1.03.

比較実験例3
実験例1において、大豆硬化油(上昇融点50℃)10部及び菜種硬化油(上昇融点35℃)10部を除き、原料油脂をバター20部を30部に、パーム分別硬化油20部を34部に、大豆油30部を26部に代え、ラウリン酸シュガーエステル0.5部を除いた以外は実験例1に準じて実施し比較実験例3の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は31℃であった。これらを表2に纏めた。比較実験例3の油中水型乳化組成物について、(A)=0であった。
Comparative Experiment Example 3
In Experimental Example 1, except 10 parts of soybean hardened oil (increased melting point 50 ° C.) and 10 parts of rapeseed oil (increased melting point 35 ° C.), the raw material fats and oils were 20 parts butter 30 parts and palm fractionated oil 20 parts 34 parts. In this example, 30 parts of soybean oil was replaced with 26 parts, and except that 0.5 part of lauric sugar ester was removed, the same procedure as in Experimental Example 1 was performed, and the water-in-oil emulsification for roll-in in Comparative Experimental Example 3 was good. A composition was obtained. The rising melting point of the oil phase of the obtained water-in-oil emulsion composition was 31 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Comparative Experimental Example 3, (A) = 0.

比較実験例4
実験例1において、ラウリン酸シュガーエステル0.5部をステアリン酸シュガーエステル(『リョートーシュガーエステルS170』三菱化学フーズ株式会社製)0.5部に代えた以外は実験例1に準じて実施し比較実験例4の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表2に纏めた。比較実験例4の油中水型乳化組成物について、(A)=13.7、(B)/(A)=1.07であった。
Comparative Experiment Example 4
Experiment 1 was carried out in the same manner as in Experiment 1 except that 0.5 part of lauric acid sugar ester was replaced with 0.5 part of stearic acid sugar ester ("Ryoto Sugar Ester S170" manufactured by Mitsubishi Chemical Foods Co., Ltd.). A water-in-oil emulsified composition for roll-in with a good structure of Comparative Experimental Example 4 was obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Comparative Experimental Example 4, (A) = 13.7 and (B) / (A) = 1.07.

比較実験例5
実験例1において、ラウリン酸シュガーエステル0.5部を0.03部に代えた以外は実験例1に準じて実施し比較実験例5の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表2に纏めた。比較実験例5の油中水型乳化組成物について、(A)=13.7、(B)/(A)=0.77であった。
Comparative Experiment Example 5
In Experimental Example 1, except that 0.5 part of lauric acid sugar ester was replaced with 0.03 part, the water-in-oil emulsion composition for roll-in with a good structure of Comparative Experimental Example 5 was carried out according to Experimental Example 1. Obtained. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Comparative Experimental Example 5, (A) = 13.7 and (B) / (A) = 0.77.

比較実験例6
実験例1において、バター20部を70部に、大豆硬化油10部を15部に、菜種硬化油10部を5部に代え、パーム分別硬化油20部、大豆油20部を除いた以外は実験例1に準じて実施し比較実験例6の組織良好なロールイン用油中水型乳化組成物を得た。得られた油中水型乳化組成物の油相の上昇融点は36℃であった。これらを表2に纏めた。比較実験例6の油中水型乳化組成物について、(A)=14.8、(B)/(A)=0.95であった。
Comparative Experiment Example 6
In Experimental Example 1, except that 20 parts of butter was changed to 70 parts, 10 parts of soybean hardened oil to 15 parts, 10 parts of rapeseed oil was replaced with 5 parts, and 20 parts of palm fractionated oil and 20 parts of soybean oil were removed. It carried out according to Experimental Example 1 and obtained the water-in-oil emulsion composition for roll-in of Comparative Experimental Example 6 with good structure. The ascending melting point of the oil phase of the obtained water-in-oil emulsion composition was 36 ° C. These are summarized in Table 2. Regarding the water-in-oil emulsion composition of Comparative Experimental Example 6, (A) = 14.8 and (B) / (A) = 0.95.

表2に比較実験例1〜比較実験例6の配合と結果を纏めた。

Figure 0005076898
Table 2 summarizes the formulations and results of Comparative Experimental Example 1 to Comparative Experimental Example 6.
Figure 0005076898

次にロールイン用油中水型乳化組成物を使用し、表3の配合、表4の製造条件でクロワッサンを焼成し、ロールイン時の作業性、ホイロでの油の染み出し、焼成品の内層、ボリューム、風味、ジューシー感の評価を行った。

Figure 0005076898
Figure 0005076898
Next, using a water-in-oil emulsified composition for roll-in, the croissant was fired under the composition shown in Table 3 and the production conditions shown in Table 4, workability during roll-in, oil exudation in the proofer, The inner layer, volume, flavor, and juiciness were evaluated.
Figure 0005076898
Figure 0005076898

実施例1
表3の実施例1の配合において、実験例1のロールイン用油中水型乳化組成物以外の原料を練り上げ、28℃、湿度75%の庫内にて60分間発酵させた後、−18℃のフリーザーで60分間リタードをとった。実験例1のロールイン用油中水型乳化組成物を折り込み、リバースシーターで3つ折りを2回行った後、−7℃のフリーザーで60分間リタードをとり、リバースシーターで3つ折りを1回行った後、−7℃のフリーザーで45分間リタードをとった。そして、リバースシーターで生地厚4mmまで延ばし、55gを成形し、36℃、湿度75%の庫内で60分間発酵させた後、庫内温度210℃のオーブンで17分間焼成し実施例1のクロワッサンを得た。評価としてはロールイン時の作業性は良好で、ホイロでの油の染み出し無く良好であり、良好な内層、ボリュームの焼成品であった。この結果を表5に纏めた。
Example 1
In the composition of Example 1 in Table 3, raw materials other than the water-in-oil emulsion composition for roll-in of Experimental Example 1 were kneaded and fermented in a chamber at 28 ° C. and 75% humidity for 60 minutes, and then −18 Retard was taken for 60 minutes in a freezer at 0 ° C. The water-in-oil emulsion composition for roll-in of Experimental Example 1 was folded, and then folded in three with a reverse sheeter, then retarded for 60 minutes with a freezer at -7 ° C, and then folded in three with a reverse sheeter. And then retarded for 45 minutes in a freezer at -7 ° C. Then, the dough thickness was extended to 4 mm using a reverse sheeter, 55 g was formed, fermented in a chamber at 36 ° C. and 75% humidity for 60 minutes, and then baked in an oven at 210 ° C. for 17 minutes. Got. As the evaluation, the workability at the time of roll-in was good, the oil did not ooze out in the proofer, and it was a fired product with a good inner layer and volume. The results are summarized in Table 5.

実施例2〜実施例7及び比較例1〜比較例6
表3の実施例2〜実施例6及び比較例1〜比較例6の配合において、実施例1と同様な処理を行なった。評価としては実施例2〜実施例7及び比較例1、比較例2、比較例4、比較例5はロールイン時の作業性は良好で、ホイロでの油の染み出し無く良好であり、良好な内層、ボリュームの焼成品であったが、比較例3ではホイロで油の染み出しが見られ、焼成品のボリュームが劣り不良であった。比較例6においてはロールイン時に割れが見られ、焼成品の内層が不均一でボリュームにばらつきがあり不良であった。これらの結果を表5に纏めた。

Figure 0005076898
Examples 2 to 7 and Comparative Examples 1 to 6
In the formulations of Examples 2 to 6 and Comparative Examples 1 to 6 in Table 3, the same treatment as in Example 1 was performed. For evaluation, Examples 2 to 7 and Comparative Example 1, Comparative Example 2, Comparative Example 4, and Comparative Example 5 have good workability at the time of roll-in, good without oil exudation at the proofer, and good. Although the inner layer was a fired product with a volume, in Comparative Example 3, the oil exuded with a proofer and the volume of the fired product was inferior and poor. In Comparative Example 6, cracks were observed at the time of roll-in, and the inner layer of the fired product was non-uniform and the volume was uneven, which was poor. These results are summarized in Table 5.
Figure 0005076898

実施例1〜7、比較例1、比較例2、比較例4、比較例5のクロワッサンについて焼成1日後に試食し、風味、ジューシー感について評価した結果を表6に示した。実施例1、実施例2は良好な風味と非常に良好なジューシー感が得られ、実施例3では良好な風味とまあまあ良好なジューシー感が得られ、実施例4、実施例5では非常に良好な風味、ジューシー感が得られ、実施例6はまあまあ良好な風味と非常に良好なジューシー感が得られ、実施例7では非常に良好な風味と良好なジューシー感が得られた。総じて実施例1〜7はジューシー感に優れていた。それに対し比較例1、比較例2、比較例4、比較例5では風味は良好なもののジューシー感に乏しく不良であった。

Figure 0005076898
Table 6 shows the results of tasting the croissants of Examples 1 to 7, Comparative Example 1, Comparative Example 2, Comparative Example 4, and Comparative Example 5 one day after baking and evaluating the flavor and juicy feeling. In Examples 1 and 2, a good flavor and a very good juicy feeling were obtained. In Example 3, a good flavor and a fairly good juicy feeling were obtained. In Examples 4 and 5, the taste was very good. Good flavor and juicy feeling were obtained. Example 6 gave a fairly good flavor and a very good juicy feeling, and Example 7 gave a very good flavor and a good juicy feeling. In general, Examples 1 to 7 were excellent in a juicy feeling. On the other hand, in Comparative Example 1, Comparative Example 2, Comparative Example 4, and Comparative Example 5, although the flavor was good, the juicy feeling was poor and poor.
Figure 0005076898

本発明は、ロールイン用油中水型乳化組成物に関し、更に詳しくは、パイ、デニッシュペストリーなどの層状膨化小麦粉食品を製造するに適したロールイン用油中水型乳化組成物及びそれを使用してなる層状膨化小麦粉食品に関するものである。   The present invention relates to a water-in-oil emulsion composition for roll-in, and more particularly, to a roll-in water-in-oil emulsion composition suitable for producing layered puffed flour foods such as pies and Danish pastries, and the use thereof The present invention relates to a layered puffed flour food.

Claims (7)

油中水型乳化組成物を構成する油相の融点が33〜40℃の範囲であり、油相の油脂原料が菜種油、大豆油、ヒマワリ種子油、綿実油、落花生油、米糠油、コーン油、サフラワー油、オリーブ油、カポック油、ゴマ油、月見草油、パーム油、シア脂、サル脂、カカオ脂、ヤシ油、パーム核油の植物性油脂並びに乳脂、牛脂、ラード、魚油、鯨油の動物性油脂の混合油或いはそれらの硬化、分別、エステル交換を施した加工油脂であり、且つ油相の油脂原料のSFCが10℃で30〜70、20℃で10〜45、30℃で2〜25であり、当該油脂原料を60℃で60分置いた後、25℃に移し60分後のSFCを(A)、シュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルからなる群より選ばれた1種以上であり、構成する全脂肪酸の25重量%以上がラウリン酸、エルカ酸から選ばれる1種又は2種を含有し、且つ平均エステル化度が30%以上である結晶調整剤を含有させた油脂原料を60℃で60分置いた後、25℃に移し60分後のSFCを(B)とした場合、(A)≧5、且つ(B)/(A)≦0.75となる結晶調整剤を含有するロールイン用油中水型乳化組成物。 The melting point of the oil phase constituting the water-in-oil emulsion composition is in the range of 33 to 40 ° C., and the oil and fat raw material of the oil phase is rapeseed oil, soybean oil, sunflower seed oil, cottonseed oil, peanut oil, rice bran oil, corn oil, Vegetable oils such as safflower oil, olive oil, kapok oil, sesame oil, evening primrose oil, palm oil, shea fat, monkey fat, cocoa butter, palm oil, palm kernel oil and animal fats such as milk fat, beef fat, lard, fish oil, whale oil Of mixed oils or processed oils and fats obtained by curing, fractionation and transesterification thereof, and SFC of oily raw materials in oil phase is 30 to 70 at 10 ° C, 10 to 45 at 20 ° C, and 2 to 25 at 30 ° C. Yes, after putting the fat / oil raw material at 60 ° C. for 60 minutes, the SFC after moving to 25 ° C. and 60 minutes later is selected from the group consisting of (A), sugar ester, polyglycerin fatty acid ester and sorbitan fatty acid ester In , 25 wt% or more lauric acid of the total fatty acids constituting, one or containing, and an average degree of esterification was contained crystal modifier is 30% or more fat material selected from erucic acid 60 After placing at 60 ° C. for 60 minutes, when it is transferred to 25 ° C. and SFC after 60 minutes is (B), it contains a crystal modifier that satisfies (A) ≧ 5 and (B) / (A) ≦ 0.75 A water-in-oil emulsion composition for roll-in. 油中水型乳化組成物の油分が70〜99重量%である、請求項1記載のロールイン用油中水型乳化組成物。 The water-in-oil emulsion composition for roll-in of Claim 1 whose oil content of a water-in-oil emulsion composition is 70 to 99 weight% . 結晶調整剤がシュガーエステル、ポリグリセリン脂肪酸エステル及びソルビタン脂肪酸エステルからなる群より選ばれた1種以上であり、構成する全脂肪酸の35重量%以上がラウリン酸、エルカ酸から選ばれる1種又は2種を含有し、且つ平均エステル化度が30%以上である、請求項1記載のロールイン用油中水型乳化組成物。 The crystal modifier is one or more selected from the group consisting of sugar ester, polyglycerin fatty acid ester and sorbitan fatty acid ester, and 35% by weight or more of the total fatty acid constituting one or two selected from lauric acid and erucic acid The water-in-oil emulsion composition for roll-in according to claim 1 , comprising seeds and having an average degree of esterification of 30% or more . 油中水型乳化組成物全体に対して結晶調整剤を0.07〜3.5重量%含有する、請求項1記載のロールイン用油中水型乳化組成物。The water-in-oil emulsion composition for roll-in according to claim 1, comprising 0.07 to 3.5% by weight of a crystal modifier based on the whole water-in-oil emulsion composition. 油相を構成するトリグリセライド中、3個の構成脂肪酸のうち2個以上がオレイン酸、リノール酸、リノレン酸から選ばれる1種又は2種よりなるトリグリセライドを16〜50重量%含有する、請求項1乃至請求項の何れか1項に記載のロールイン用油中水型乳化組成物。2. The triglyceride constituting the oil phase contains 16 to 50% by weight of triglyceride consisting of one or two selected from oleic acid, linoleic acid, and linolenic acid among two of the three constituent fatty acids. The water-in-oil type emulsion composition for roll-ins of any one of thru | or 4 . 油中水型乳化組成物を構成する原料油脂中乳由来の脂肪が60重量%以下である、請求項1乃至請求項の何れか1項に記載のロールイン用油中水型乳化組成物。The water-in-oil emulsion composition for roll-in according to any one of claims 1 to 5 , wherein the fat derived from the raw oil-and-fat milk constituting the water-in-oil emulsion composition is 60% by weight or less. . 請求項1乃至請求項の何れか1項に記載のロールイン用油中水型乳化組成物を使用してなる、層状膨化小麦粉食品。A layered puffed flour food product comprising the water-in-oil emulsion composition for roll-in according to any one of claims 1 to 6 .
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0423940A (en) * 1990-05-17 1992-01-28 Nippon Oil & Fats Co Ltd Emulsified oil and fat composition for making bread and bread making
JPH06209704A (en) * 1993-01-14 1994-08-02 Snow Brand Milk Prod Co Ltd Oil-in-water type emulsified fat and oil composition
JP2002078448A (en) * 2000-06-27 2002-03-19 Asahi Denka Kogyo Kk Plasticated oil and fat composition and bakery product using the same
JP2002262772A (en) * 2001-03-09 2002-09-17 Asahi Denka Kogyo Kk Plastic fat composition
JP2003038097A (en) * 2001-07-30 2003-02-12 Asahi Denka Kogyo Kk Oil and fat composition for roll-in

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0423940A (en) * 1990-05-17 1992-01-28 Nippon Oil & Fats Co Ltd Emulsified oil and fat composition for making bread and bread making
JPH06209704A (en) * 1993-01-14 1994-08-02 Snow Brand Milk Prod Co Ltd Oil-in-water type emulsified fat and oil composition
JP2002078448A (en) * 2000-06-27 2002-03-19 Asahi Denka Kogyo Kk Plasticated oil and fat composition and bakery product using the same
JP2002262772A (en) * 2001-03-09 2002-09-17 Asahi Denka Kogyo Kk Plastic fat composition
JP2003038097A (en) * 2001-07-30 2003-02-12 Asahi Denka Kogyo Kk Oil and fat composition for roll-in

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