JP5041682B2 - Agglomeration method of roll grinding powder - Google Patents
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Description
本発明は、鋼材の熱間圧延用ロールや冷間圧延用ロールなどの金属加工用ロールの研削時に発生するロール研削粉の塊成化方法に関するものである。 The present invention relates to a method for agglomerating roll grinding powder generated during grinding of a metal working roll such as a hot rolling roll or a cold rolling roll of steel.
上記のような金属加工用ロールは、表面状態を良好に維持するために定期的に研削を行う。このときに発生するロール研削粉はクロム、タングステン、バナジウム等を含有する有価物であるが、粒径が500μm以下と細かいために金属屑としての取り扱いが容易でなく、有効に利用されていないのが実情である。 The metal working roll as described above is periodically ground to maintain a good surface state. The roll grinding powder generated at this time is a valuable material containing chromium, tungsten, vanadium, etc., but because the particle size is as fine as 500 μm or less, it is not easy to handle as metal scrap and is not effectively used. Is the actual situation.
特許文献1には、粒状または綿状の金属加工屑の再利用を図るため、金属加工屑を乾燥・養生したのち、廃プラスティックをバインダーとして添加し、ロール成形機やスクリュー押出機で塊成化する方法が開示されている。しかしこの方法は製鉄工場では入手しにくい廃プラスティックが必要であるために、原料準備が容易でないという問題がある。また塊成化された成形品が崩壊して粉化し、自己発熱による火災発生の可能性があるため、粉分除去のための篩い分けや強制冷却が必要であることが同一出願人の特許文献2で指摘されており、多額の設備費用を要するという問題がある。 In Patent Document 1, in order to recycle granular or cotton-like metal processing waste, after drying and curing the metal processing waste, waste plastic is added as a binder and agglomerated by a roll molding machine or a screw extruder. A method is disclosed. However, this method has a problem that raw material preparation is not easy because it requires waste plastic, which is difficult to obtain at an iron factory. In addition, patent documents of the same applicant that sieving and forced cooling are necessary to remove the powder because the agglomerated molded product collapses and pulverizes, and there is a possibility of fire due to self-heating. It is pointed out in 2 and there is a problem that a large amount of equipment costs are required.
更に、金属加工屑には大量の水分や油分が含まれているが、廃プラスティックをバインダーとして使用する場合には水分が5%以下でないとバインダー効果が得られないこと、また油分が多い場合には成形品の強度が低下して粉化し易くなるため、事前の脱水・脱油プロセスが必要となることが、同一出願人の特許文献3で指摘されている。
Furthermore, metal processing waste contains a large amount of moisture and oil, but when using waste plastic as a binder, if the moisture content is less than 5%, the binder effect cannot be obtained, and if there is a lot of oil. It is pointed out in
さらに特許文献4には、アルミニウム等の研摩スラッジに同一金属材料の切削屑を混合し、圧縮してブリケット化することが記載されている。しかし金属加工用ロールの場合にはユーザーにおいてそれと同一材料の切削屑を入手することは困難であり、特許文献4の技術を採用することはできない。このように、ロール研削粉のような微細な金属屑を利用し易い塊状の成形品にするためには、様々な問題が残されていた。
従って本発明の目的は、金属加工用ロールの研削時に発生するロール研削粉を廃プラスティックのようなバインダーを使用せず、また煩雑な工程や多額の設備費用を必要とせずに、安定的に塊成化することができる技術を提供することである。 Accordingly, an object of the present invention is to stably collect lump powder generated during grinding of a metal processing roll without using a binder such as waste plastic, and without requiring complicated processes and large equipment costs. It is to provide a technology that can be formed.
上記の課題を解決するためになされた本発明は、製鉄工場の圧延ロールを研削する際に発生したロール研削粉に、金属切削屑を10%以上加えた混合物を、事前の脱水プロセスを経ることなく、10MPa以上の圧縮力で圧縮成形するロール研削粉の塊成化方法であって、該金属切削屑が、鋳片表面を切削した際に生じた金属切削屑を、事前に30〜80mm長に切断されたものであることを特徴とするものである。
なお、ロール研削粉は鋼材の圧延用ロールの研削時に発生する500μm以下の粒度のものであり、切断された金属切削屑が、(実長−最大長径)/実長で表わされるカール度が0.4以下のものであることが好ましい。また、ロール研削粉に、金属切削屑を40%以上混合することがより好ましい。
This invention made in order to solve said subject passes the prior spin-drying | dehydration process the mixture which added 10% or more of metal cutting waste to the roll grinding powder generated when grinding the rolling roll of an iron mill. And a method of agglomerating roll grinding powder that is compression-molded with a compressive force of 10 MPa or more, and the metal cutting waste is 30 to 80 mm long in advance when the metal cutting waste generated when the slab surface is cut It is what was cut | disconnected by this.
The roll grinding powder has a particle size of 500 μm or less that is generated when grinding a roll for rolling steel material, and the cut metal scrap has a curl degree represented by (actual length−maximum major axis) / actual length is 0. It is preferable that it is below 0.4. Moreover, it is more preferable to mix 40% or more of metal cutting waste with the roll grinding powder.
本発明によれば、ロール研削粉に事前に30〜80mm長に切断された金属切削屑を10%以上混合し、10MPa以上の圧縮力を加えて固めることによって、バインダーを使用せずに塊成化することができる。しかもこの高圧により、ロール研削粉に付着している水分は5%以下にまで脱水され、事前の脱水工程を必要としない。なお、切断された金属切削屑として、(実長−最大長径)/実長で表わされるカール度が0.4以下のものを用いれば、金属切削屑がブリッジング効果を発揮し、強度のある圧縮成形品が得られる。 According to the present invention, 10% or more of metal cutting scraps cut into a length of 30 to 80 mm in advance is mixed with roll grinding powder, and agglomeration is performed without using a binder by applying a compressive force of 10 MPa or more and solidifying. Can be Moreover, due to this high pressure, the moisture adhering to the roll grinding powder is dehydrated to 5% or less, and no prior dehydration step is required. In addition, when the curl degree represented by (actual length−maximum major axis) / actual length is 0.4 or less as the cut metal scrap, the metal scrap exhibits a bridging effect and is strong. A compression molded product is obtained.
また本発明では金属切削屑とともに10MPa以上の高圧で塊成化を行うため、強度が大きく粉化のおそれのない圧縮成形品を得ることができる。このため自己発熱による火災のおそれもないので篩い分けや強制冷却は不要である。そして圧縮成形品を高炉、転炉、溶銑予備処理炉、電気炉、キュポラ等にリサイクルする場合にもコンベヤの乗り継ぎ箇所等で粉化することもなく、効率のよいリサイクルが可能である。 Further, in the present invention, the agglomeration is performed at a high pressure of 10 MPa or more together with the metal cutting waste, so that it is possible to obtain a compression molded product having a high strength and no risk of powdering. For this reason, since there is no risk of fire due to self-heating, sieving and forced cooling are unnecessary. Even when the compression molded product is recycled to a blast furnace, a converter, a hot metal pretreatment furnace, an electric furnace, a cupola, etc., it can be efficiently recycled without being pulverized at a connecting point of the conveyor.
以下に図1を参照しつつ、本発明の好ましい実施形態を示す。
本発明においては、金属加工用ロールの研削時に発生するロール研削粉を鉄源としてリサイクルするために回収する。ここで金属加工用ロールとしては、鋼材の熱間圧延用ロールや冷間圧延用ロールなどが代表的なもので、その材質は工具鋼が普通である。これらは定期的に研削されるため、大量のロール研削粉が発生する。その粒径は500μm以下であり、そのままでは取り扱いにくいことは前述の通りである。
Hereinafter, a preferred embodiment of the present invention will be described with reference to FIG.
In the present invention, roll grinding powder generated during grinding of a metal working roll is collected for recycling as an iron source. Here, as a roll for metal processing, a roll for hot rolling of steel, a roll for cold rolling, etc. are typical, and the material is usually tool steel. Since these are periodically ground, a large amount of roll grinding powder is generated. As described above, the particle size is 500 μm or less and is difficult to handle as it is.
しかもロール研削粉には水分や油分が付着しており、バインダーを使用せずに圧縮しても強度のある圧縮成形品を得ることができず粉化のおそれがある。そこで本発明では、ロール研削粉に金属切削屑を質量比で10%以上混合する。この金属切削屑は圧縮成形品の骨格となり得る線状またはリボン状のものが好ましく、この実施形態ではスラブ等の鋳片の表面を切削した際に発生するリボン状の金属切削屑を用いる。このような金属切削屑は100〜200mm程度の長さを持つが通常はカールしているために非常に嵩張り、そのままでは圧縮成形機に供給しにくい。 In addition, moisture and oil are attached to the roll grinding powder, and even if it is compressed without using a binder, a strong compression molded product cannot be obtained, and there is a risk of powdering. Therefore, in the present invention, metal cutting waste is mixed with the roll grinding powder at a mass ratio of 10% or more. This metal cutting scrap is preferably a linear or ribbon-like one that can be a skeleton of a compression molded product. In this embodiment, a ribbon-shaped metal cutting scrap generated when the surface of a cast piece such as a slab is cut is used. Such metal cutting waste has a length of about 100 to 200 mm, but is usually curled because it is curled, and is difficult to supply to a compression molding machine as it is.
そこで本発明では、金属切削屑をロータリーハンマークラッシャ−等の破砕機にかけて30〜80mmに切断する。図2は金属切削屑の平均長と圧縮成形品の強度との関係を示すグラフであり、縦軸は圧縮成形品を3mの高さからコンクリート床上に落下させ、最大固形物の重量/初期重量の式により求めた固形物残存重量率である。金属切削屑の平均長が30mm未満になると圧縮成形品の強度は急激に低下する。これはブリッジング効果が低下するためである。逆に80mmを越えるとロール研削粉との混合性が悪化し、やはり圧縮成形品の強度は低下する。 So, in this invention, metal cutting waste is cut | disconnected to 30-80 mm with crushing machines, such as a rotary hammer mark lasher. FIG. 2 is a graph showing the relationship between the average length of metal cutting waste and the strength of the compression molded product, and the vertical axis represents the weight of the maximum solid matter / initial weight by dropping the compression molded product onto the concrete floor from a height of 3 m. It is the solid substance residual weight rate calculated | required by the type | formula. When the average length of the metal cutting waste is less than 30 mm, the strength of the compression molded product is rapidly reduced. This is because the bridging effect is reduced. On the other hand, when it exceeds 80 mm, the mixing property with the roll grinding powder deteriorates, and the strength of the compression molded product also decreases.
また、金属切削屑は図3に示すように強くカールしていることが多く、延ばした場合の長さ(実長)が30〜80mmの範囲にあってもそのままでは好ましいブリッジング効果が得られない傾向にある。そこで切断の際にカールを引き延ばし、(実長−最大長径)/実長で表わされるカール度が0.4以下としたものを用いることが好ましい。このような引き延ばしはロータリーハンマークラッシャ−等の破砕機により、切断と同時に行わせることができる。カール度が0.4より小さい金属切削屑はそれ自体で小さくまとまっており、ロール研削粉の骨格材として機能しにくい。 Further, metal cutting scraps are often strongly curled as shown in FIG. 3, and a preferable bridging effect can be obtained as it is even if the length (actual length) when extended is in the range of 30 to 80 mm. There is no tendency. Therefore, it is preferable that the curl is extended at the time of cutting so that the curl degree expressed by (actual length−maximum major axis) / actual length is 0.4 or less. Such stretching can be performed simultaneously with cutting by a crusher such as a rotary hammer mark lasher. The metal cutting waste having a curl degree of less than 0.4 is small in itself and hardly functions as a skeleton material for the roll grinding powder.
ロール研削粉と金属切削屑との混合比率は、圧縮成形品の強度に大きく影響する。図4はその結果を示すグラフであり、金属切削屑の混合比率が10%を超えると強度が急激に上昇し、40%を越えると更に上昇することが示されている。従って金属切削屑の混合比率(金属切削屑重量/圧縮成形品重量)は10%以上が必要であり、40%以上とすれば更に好ましい。 The mixing ratio of the roll grinding powder and the metal cutting waste greatly affects the strength of the compression molded product. FIG. 4 is a graph showing the results. It is shown that the strength sharply increases when the mixing ratio of the metal cutting scraps exceeds 10% and further increases when the mixing ratio exceeds 40%. Accordingly, the mixing ratio of metal cutting scraps (metal cutting scrap weight / compression molded product weight) needs to be 10% or more, and more preferably 40% or more.
次にロール研削粉と金属切削屑との混合物は、圧縮成形機によって10MPa以上の圧縮力を加えて固められ、圧縮成形品となる。この圧縮成形品は単にロール研削粉のみを圧縮成形したものではなく、内部に骨格となる金属切削屑が含まれているので、取り扱い上十分な強度を備えたものとなる。この圧縮成形品は粉化のおそれがないので、従来のような篩い分けや強制冷却は不要であり、多額の設備コストは不要である。 Next, the mixture of roll grinding powder and metal cutting waste is hardened by applying a compressive force of 10 MPa or more by a compression molding machine to form a compression molded product. This compression-molded product is not simply compression-molded of roll grinding powder, but contains metal cutting scraps that become a skeleton inside, and therefore has sufficient strength for handling. Since this compression molded product has no fear of pulverization, conventional sieving and forced cooling are unnecessary, and a large equipment cost is unnecessary.
しかもこのような高圧を加えると、ロール研削粉や金属切削屑に付着していた水分は押し出されて5%以下のレベルにまで低下し、従来のような予備的な脱水処理を行わなくても、強度の大きい圧縮成形品を得ることができる。このため設備費用をさらに削減することが可能である。しかし圧力が10MPa未満であると、圧縮成形品中に残存する水分量が増加し、強度が低下するとともに圧縮成形品の保管上の問題が生じやすくなる。 Moreover, when such a high pressure is applied, the moisture adhering to the roll grinding powder and the metal cutting waste is pushed out and drops to a level of 5% or less. A compression molded product with high strength can be obtained. For this reason, it is possible to further reduce equipment costs. However, when the pressure is less than 10 MPa, the amount of water remaining in the compression molded product increases, the strength decreases, and a problem in storage of the compression molded product is likely to occur.
なお、圧縮成形機としてはシリンダ内に供給された材料を油圧駆動式のピストンにより圧縮成形する形式のものを用いることが好ましい。前記したように金属切削屑を予めロータリーハンマークラッシャー等の破砕機で破砕したうえでロール研削粉と混合すれば、シリンダ内への供給が行い易くなる。 As the compression molding machine, it is preferable to use a type in which the material supplied into the cylinder is compression molded by a hydraulically driven piston. As described above, if the metal cutting waste is crushed in advance by a crusher such as a rotary hammer crusher and then mixed with the roll grinding powder, the supply into the cylinder is facilitated.
得られた圧縮成形品は、高炉、転炉、溶銑予備処理炉、電気炉、キュポラ等に鉄源として投入されリサイクルされる。従来はロール研削粉は利用されていなかったため、本発明によりコストダウンを図ることができ、もちろん、鉄源として外販することも可能である。なお、圧縮成形品は十分な強度を有するので、搬送工程における振動によって破壊されたり粉化することはない。 The obtained compression molded product is thrown into the blast furnace, converter, hot metal pretreatment furnace, electric furnace, cupola, etc. as an iron source and recycled. Conventionally, since roll grinding powder has not been used, the present invention can reduce the cost and, of course, can be sold as an iron source. In addition, since the compression molded product has sufficient strength, it is not broken or pulverized by vibration in the conveying process.
製鉄工場の熱間圧延ロールを研削する際に発生したロール研削粉と、普通鋼のスラブ表面を切削した際に生じた金属切削屑とを質量比で50%ずつ混合した。なお、熱間圧延ロールのロール研削粉には30%の水分と8%の油分とが付着していた。金属切削屑はカール状で嵩密度が低くそのままでは取り扱いが容易ではないため、ロータリーハンマークラッシャーにより平均長が50〜60mm、(実長−最大長径)/実長で表わされるカール度が0.01〜0.2となるように破砕したうえ、ロール研削粉と混合した。 Roll grinding powder generated when grinding a hot rolling roll of an iron factory and metal cutting waste generated when cutting a slab surface of ordinary steel were mixed in a mass ratio of 50%. In addition, 30% of water | moisture content and 8% of oil content adhered to the roll grinding powder of the hot rolling roll. Since the metal cutting waste is curled and has a low bulk density and is not easy to handle as it is, the average length is 50 to 60 mm by a rotary hammer crusher, and the curl degree expressed by (actual length−maximum major axis) / actual length is 0.01. The mixture was crushed so as to be 0.2, and mixed with roll grinding powder.
この混合物を油圧式の往復ピストン型圧縮機に供給し、100MPaの圧力で圧縮し、直径90mm、厚さ50mmの圧縮成形品を製造した。この圧縮成形品は高さ3mからコンクリート床上に落下させてもほとんど破壊されず、固形物残存重量率は90%を越えるものである。なお、圧縮成形品中の水分を分析したところ2.8%であり、予備乾燥を行わなくても十分な脱水効果があることが確認できた。ただ油分は6%であり、水分ほどには低減されていなかった。このようにして得られた圧縮成形品は転炉に投入され、鉄源として再利用された。 This mixture was supplied to a hydraulic reciprocating piston compressor and compressed at a pressure of 100 MPa to produce a compression molded product having a diameter of 90 mm and a thickness of 50 mm. This compression-molded product is hardly destroyed even when dropped onto a concrete floor from a height of 3 m, and the residual solid weight ratio exceeds 90%. The moisture content in the compression-molded product was analyzed and found to be 2.8%, and it was confirmed that there was a sufficient dehydrating effect without performing preliminary drying. However, the oil content was 6% and was not reduced as much as the water content. The compression molded product thus obtained was put into a converter and reused as an iron source.
製鉄工場の冷間圧延ロールを研削する際に発生したロール研削粉と、普通鋼のスラブ表面を切削した際に生じた金属切削屑とを、質量比で60%:40%の比率で混合した。ロール研削粉には47%の水分と3%の油分とが付着していた。金属切削屑は実施例1と同様、平均長が50〜60mm、(実長−最大長径)/実長で表わされるカール度が0.01〜0.2となるように破砕し、ロール研削粉と混合した。 Roll grinding powder generated when grinding cold rolling rolls in steel mills and metal cutting waste generated when cutting the slab surface of ordinary steel were mixed at a mass ratio of 60%: 40%. . The roll grinding powder had 47% moisture and 3% oil. As in Example 1, the metal cutting waste was crushed so that the average length was 50 to 60 mm and the curl degree represented by (actual length−maximum major axis) / actual length was 0.01 to 0.2, and the roll grinding powder Mixed with.
この混合物を油圧式の往復ピストン型圧縮機に供給し、100MPaの圧力で圧縮し、直径90mm、厚さ50mmの圧縮成形品を製造した。この圧縮成形品は高さ3mからコンクリート床上に落下させたときの固形物残存重量率は60%であり、取り扱いに支障のない強度を備えていた。なお、圧縮成形品中の水分を分析したところ3.8%であり、予備乾燥を行わなくても十分な脱水効果があることが確認できた。油分は2.5%であり、あまり低減されていなかった。このようにして得られた圧縮成形品は溶銑予備処理炉に投入され、鉄源として再利用された。 This mixture was supplied to a hydraulic reciprocating piston compressor and compressed at a pressure of 100 MPa to produce a compression molded product having a diameter of 90 mm and a thickness of 50 mm. This compression-molded product had a solid residual weight ratio of 60% when dropped onto a concrete floor from a height of 3 m, and had strength that did not hinder handling. The moisture content in the compression-molded product was analyzed and found to be 3.8%, and it was confirmed that there was a sufficient dehydrating effect without performing preliminary drying. The oil content was 2.5% and was not reduced much. The compression molded product thus obtained was put into a hot metal pretreatment furnace and reused as an iron source.
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