JP5032092B2 - Cosmetic pencil lead and method for producing the same - Google Patents

Cosmetic pencil lead and method for producing the same Download PDF

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JP5032092B2
JP5032092B2 JP2006279582A JP2006279582A JP5032092B2 JP 5032092 B2 JP5032092 B2 JP 5032092B2 JP 2006279582 A JP2006279582 A JP 2006279582A JP 2006279582 A JP2006279582 A JP 2006279582A JP 5032092 B2 JP5032092 B2 JP 5032092B2
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pencil lead
cosmetic pencil
sericite
average particle
weight
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聡 坂西
知子 長谷川
清和 桜井
清 河田
紀 桜井
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Mitsubishi Pencil Co Ltd
Shiseido Co Ltd
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Shiseido Co Ltd
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本発明は、主として化粧品用に使用する、木軸用、樹脂軸用、紙巻用又はホルダー用の化粧用鉛筆芯及びその製造方法に関し、更に詳しくは、十分な発色性、描線濃度を持ちながら、塗布感を硬くも軟らかくも自由に設定でき、機械的強度(曲げ強度、引張強度、衝撃強度等)にも優れた化粧用鉛筆芯及びその製造方法に関する。   The present invention relates to a cosmetic pencil lead mainly used for cosmetics, for wooden shafts, resin shafts, cigarettes or holders, and a method for producing the same, and more specifically, while having sufficient color developability and line density, The present invention relates to a cosmetic pencil lead that can be freely set to be hard or soft and has excellent mechanical strength (bending strength, tensile strength, impact strength, etc.) and a method for producing the same.

化粧用鉛筆芯において、一般に要求される重要特性としては、塗布感が良好で多色化でき描線の発色性が良く、機械的強度が強いことである。   In the pencil lead for cosmetics, important characteristics generally required are that the coating feeling is good, the color can be increased, the color of the drawn line is good, and the mechanical strength is strong.

これらの特性を満たす化粧用鉛筆芯として、例えば、シリコーン油、脂肪酸および脂肪族アルコールからなる分子内分岐構造を有する凝固点0℃以下のエステル油、メチルハイドロジェンポリシロキサン処理顔料ならびに固形油脂を必須成分として配合した化粧用鉛筆芯が知られている(例えば、特許文献1参照)。   As a cosmetic pencil lead satisfying these characteristics, for example, an ester oil having an intramolecular branched structure composed of silicone oil, a fatty acid and an aliphatic alcohol having a freezing point of 0 ° C. or lower, a methyl hydrogen polysiloxane-treated pigment, and a solid fat are essential components. A cosmetic pencil lead formulated as is known (for example, see Patent Document 1).

しかしながら、上記特許文献1に記載の化粧用鉛筆芯においては、油脂やシリコーン油といった、油成分を含有しており、これらの材料が強度に強く影響するためにパウダリー(粉体を固めたような塗布感)で軟らかい良好な塗布感にすると、強度が低下してしまうという点に課題がある。   However, the cosmetic pencil lead described in Patent Document 1 contains oil components such as oils and fats and silicone oil, and since these materials strongly influence the strength, powdery (like powdered hardened powder) There is a problem in that the strength decreases when the coating feeling is soft and the coating feeling is soft.

一方、ワックス類を使用せず、パウダリーな塗布感を目指した化粧用鉛筆芯が研究されている。このような化粧用鉛筆芯としては、例えば、結合材にCMC(カルボキシメチルセルロース)等の水溶性の糊料を使用したもの(例えば、特許文献2参照)や、石膏を使用したもの(例えば、特許文献3参照)が知られている。   On the other hand, a pencil lead for makeup aiming at a powdery coating feeling without using waxes has been studied. As such a cosmetic pencil lead, for example, a binder using a water-soluble paste such as CMC (carboxymethyl cellulose) (for example, see Patent Document 2) or a plaster (for example, patent) Document 3) is known.

しかしながら、上記特許文献2及び3におけるCMCや石膏などの結合材を使用した化粧用鉛筆芯では、結合材が極度に硬化してしまうため、肌への塗布感が非常に硬く、またアイブローやアイライナーなどの細いものにすると非常に脆く、十分な機械的強度を得るために結合剤の量を増加させると肌に全く塗布できないものとなる。すなわち、パウダリーな使用感を得るためにワックス類の代わりにCMC等の水溶性の糊料や石膏を結合材に使用した化粧用鉛筆芯では十分な機械的強度と良好な塗布感を同時に満たすことは困難である点に課題がある。   However, in the cosmetic pencil lead using a binding material such as CMC and gypsum in Patent Documents 2 and 3, the binding material is extremely hardened, so that the feeling of application to the skin is very hard, and eyebrow and eye If it is made thin, such as a liner, it is very fragile, and if the amount of the binder is increased to obtain sufficient mechanical strength, it cannot be applied to the skin at all. That is, a cosmetic pencil lead using a water-soluble paste such as CMC or gypsum instead of waxes as a binder to obtain a powdery feeling of use satisfies both sufficient mechanical strength and good coating feeling at the same time. There is a problem in that it is difficult.

更に、ワックス類を使用せず、十分な機械的強度と良好な塗布感を同時に満たす化粧用鉛筆芯も研究されており、例えば、結合剤に粘土を使用し、粘土を焼結させたもの(例えば、特許文献4参照)、気孔形成材を使用し、より多孔質な焼結体にしたもの(例えば、特許文献5参照)が知られている。   Furthermore, a pencil lead for makeup that satisfies both sufficient mechanical strength and good coating feeling without using waxes has been studied. For example, clay is used as a binder and the clay is sintered ( For example, the patent document 4) and the thing which made the pore formation material into the more porous sintered compact (for example, refer patent document 5) are known.

しかしながら、上記特許文献4に記載された化粧用鉛筆芯では、焼結処理を施すことにより多孔質の骨格を形成する粘土の焼結体中に、粉末状に分散含有された無機顔料を含有させた化粧用鉛筆芯であり、その多孔質とは、「気孔率は大きいほど使用時のタッチや塗布性が良くなる傾向にあり、また、気孔率が小さく緻密化すればするほど強度が大きくなる傾向にある。」と記載されており、結局上記特許文献4が開示しているのは気孔率が50%〜90%程度の焼結体である。すなわち、粘土の焼結体では十分な機械的強度は得られるものの硬く、肌に塗布することは困難であるが、多孔質の焼結体にすることにより、十分な機械的強度と良好な塗布感を同時に満たす化粧用鉛筆芯が得られるということである。   However, in the cosmetic pencil lead described in Patent Document 4, an inorganic pigment dispersed and contained in a powder form is contained in a clay sintered body that forms a porous skeleton by sintering. A porous pencil lead for cosmetics, which means that “the higher the porosity, the better the touch and applicability during use, and the smaller the porosity, the higher the strength. In the end, Patent Document 4 discloses a sintered body having a porosity of about 50% to 90%. In other words, a clay sintered body can provide sufficient mechanical strength, but it is hard and difficult to apply to the skin. By making a porous sintered body, sufficient mechanical strength and good application can be obtained. This means that a cosmetic pencil lead satisfying the feeling can be obtained at the same time.

一般に、良好な塗布感と十分な機械的強度とを同時に満たすためには、上記特許文献4及び5に記載されるように、気孔率の調整が不可欠であるが、気孔率の調整は、上記特許文献4に記載されるように、焼結処理時の温度や粘土と粉末状の顔料の使用割合を変更することだけでは、好ましい50〜90%程度の気孔率の焼結体を得ることは非常に困難であり、また、上記特許文献5に記載されるように、気孔形成材を使用することだけでは、好ましい範囲となる気孔率の焼結体を得ることは非常に困難であるのが現状である。   Generally, in order to satisfy a good coating feeling and a sufficient mechanical strength at the same time, as described in Patent Documents 4 and 5, it is essential to adjust the porosity. As described in Patent Document 4, it is possible to obtain a sintered body having a preferable porosity of about 50 to 90% only by changing the temperature at the time of sintering treatment or the use ratio of clay and powdered pigment. It is very difficult, and as described in Patent Document 5, it is very difficult to obtain a sintered body having a porosity within a preferable range only by using a pore forming material. Currently.

更に、良好な塗布感と十分な機械的強度とを同時に満たすために、例えば、ベントナイト、スメクタイト、モンモリロナイト、ビーデライト、ノントライト、ヘクトライト及びサポナイトからなる群より選ばれた少なくとも1種を1〜10重量%と無機の体質顔料及び無機の着色顔料を必須成分とし、これらを300℃〜1,000℃の温度範囲で焼結して得た炭化物を全く残さない無機粉体及び水よりなる成形組成物を乾燥後300〜1,000℃で熱処理を施してなる化粧用鉛筆芯(例えば、特許文献6参照)が知られている。   Furthermore, in order to satisfy a good coating feeling and a sufficient mechanical strength at the same time, for example, 1 to 10 weights of at least one selected from the group consisting of bentonite, smectite, montmorillonite, beidellite, nontrite, hectorite and saponite. %, An inorganic extender pigment and an inorganic coloring pigment as essential components, and a molding composition comprising inorganic powder and water obtained by sintering these in a temperature range of 300 ° C. to 1,000 ° C. A cosmetic pencil lead (see, for example, Patent Document 6) is known which is heat-treated at 300 to 1,000 ° C. after drying.

しかしながら、上記と同様に、粘土を焼結させて結合材としているため、軟らかい塗布感に配合した場合には強度が弱くなってしまう点に課題がある。
また、このように粘土を焼成して結合材とする場合、有機顔料や染料は変色してしまうため無機顔料等の耐熱性の高い顔料しか使用することができないため、十分な多色化と発色性を得ることは困難である。
However, similar to the above, since clay is sintered to form a binder, there is a problem in that the strength is weakened when blended into a soft coating feeling.
Also, when clay is baked in this way to form a binder, organic pigments and dyes change color, so only highly heat-resistant pigments such as inorganic pigments can be used. It is difficult to get sex.

他方、ポリシロキサンを用いる色鉛筆芯の製造方法を用いることにより、酸化ケイ素骨格を低温で合成できる色鉛筆芯(本願出願人による、例えば、特許文献7参照)が知られているが、本願発明とは、その技術思想(目的、構成及び作用効果)が異なるものである。
特公昭62−169714号公報(特許請求の範囲、実施例等) 特開昭59−44305号公報(特許請求の範囲、実施例等) 特開昭59−93014号公報(特許請求の範囲、実施例等) 特開昭61−176513号公報(特許請求の範囲、実施例等) 特開昭61−197507号公報(特許請求の範囲、実施例等) 特開平8−188518号公報(特許請求の範囲、実施例等) 特開2003−261812号公報(特許請求の範囲、実施例等)
On the other hand, a colored pencil lead that can synthesize a silicon oxide skeleton at a low temperature by using a method for producing a colored pencil lead using polysiloxane is known (for example, see Patent Document 7 by the applicant of the present application). The technical idea (purpose, configuration and operational effect) is different.
Japanese Patent Publication No. 62-169714 (claims, examples, etc.) JP 59-44305 A (Claims, Examples, etc.) JP 59-93014 A (Claims, Examples, etc.) JP 61-176513 (Claims, Examples, etc.) Japanese Patent Laid-Open No. 61-197507 (Claims, Examples, etc.) JP-A-8-188518 (Claims, Examples, etc.) JP2003-261812 (Claims, Examples, etc.)

本発明は、上記従来技術の課題に鑑み、上記発明者らの先行技術を更に改良することであり、塗布感が軟らかく良好であり、かつ、機械的強度を維持し、鮮やかな発色性と濃度を有する多色化可能な化粧用鉛筆芯を提供することを目的とする。   The present invention is to further improve the prior art of the inventors in view of the problems of the prior art described above, the coating feeling is soft and good, and the mechanical strength is maintained, vivid color developability and density An object of the present invention is to provide a multi-color cosmetic pencil lead having

本発明者らは、上記従来の課題等を解決するために、鋭意研究を行った結果、少なくとも、芯体を構成する粉体の表面や界面に、酸化ケイ素の多孔質体を骨格として形成し、平均粒径が特定範囲に調整されているセリサイトを体質材として含有することにより解決し得ることを見い出し、本発明を完成するに至ったのである。   As a result of intensive studies to solve the above-described conventional problems, the present inventors have formed a porous body of silicon oxide as a skeleton at least on the surface and interface of the powder constituting the core body. The present inventors have found that the problem can be solved by containing sericite whose average particle diameter is adjusted to a specific range as an extender, and has completed the present invention.

すなわち、本発明は、次の(1)〜(6)に存する。
(1) 酸化ケイ素からなる多孔質体骨格と、少なくとも平均粒径が3.5〜10μmに調整されているセリサイト体質材とを含有し、これらが結合したものを含むことを特徴とする化粧用鉛筆芯。
(2) 前記セリサイトに対し、窒化ホウ素を1:0.28〜4.0の重量比で更に含有し、結合したものを含むこと特徴とする上記(1)に記載の化粧用鉛筆芯。
(3) 前記窒化ホウ素の平均粒径が4.5〜7.5μmであることを特徴とする上記(2)に記載の化粧用鉛筆芯。
(4) 前記窒化ホウ素と前記セリサイトの合計含有量が、化粧用鉛筆芯の全体量に対して、15〜25重量%含有されていることを特徴とする上記(2)又は(3)に記載の化粧用鉛筆芯。
(5) 前記酸化ケイ素からなる多孔質体の孔が直径2〜1000nmの範囲であることを特徴とする上記(1)〜(4)の何れか一つに記載の化粧用鉛筆芯。
(6) 酸化ケイ素多孔質体を骨格として合成するため、下記一般式(I)で表される構造単位を有するポリシロキサンを平均粒径が3.5〜10μmに調整されているセリサイトの体質材及び着色材を少なくとも含有する配合組成物中に存在させ、マイクロ波による加熱処理を施すことにより、酸化ケイ素からなる多孔質体を骨格とし、少なくとも平均粒径が3.5〜10μmに調整されているセリサイトの体質材とを含有し、これらが結合したものを含む化粧用鉛筆芯を低温で製造することを特徴とする化粧用鉛筆芯の製造方法。

Figure 0005032092
That is, the present invention resides in the following (1) to (6).
(1) and the skeleton of the porous body made of silicon oxide, and characterized by including those in which at least an average particle diameter contains a constitutional material of sericite which has been adjusted to 3.5~10Myuemu, it is attached Make up pencil lead for makeup.
(2) The cosmetic pencil lead according to the above (1), which further contains boron nitride in a weight ratio of 1: 0.28 to 4.0 and is bonded to the sericite.
(3) The cosmetic pencil lead as described in (2) above, wherein the boron nitride has an average particle size of 4.5 to 7.5 μm.
(4) total content of the boron nitride and the sericite, based on the total amount of the cosmetic pencil lead, the above (2) or (3), characterized in that it is contained 15 to 25 wt% The pencil lead for makeup as described .
(5) the cosmetic pencil lead according to any one of the pores of the porous body made of silicon oxide is characterized by a range of diameter 2 to 1000 nm (1) ~ (4).
(6) Structure of sericite in which polysiloxane having a structural unit represented by the following general formula (I) is adjusted to an average particle size of 3.5 to 10 μm in order to synthesize a silicon oxide porous body as a skeleton It is made to exist in the compounding composition containing at least a material and a coloring material, and is subjected to a heat treatment by microwaves, so that a porous body made of silicon oxide is used as a skeleton, and at least an average particle size is adjusted to 3.5 to 10 μm. A method for producing a cosmetic pencil lead, comprising: a sericite extender, and a cosmetic pencil lead comprising these bonded materials at a low temperature.
Figure 0005032092

本発明によれば、酸化ケイ素からなる多孔質体骨格と、少なくとも平均粒径が3.5〜10μmに調整されているセリサイト体質材とを含有し、これらが結合したものを含むことにより、十分な発色性、描線濃度を持ちながら、塗布感が良好で、機械的強度(曲げ強度、引張強度、衝撃強度等)にも優れた化粧用鉛筆芯が提供される。
また、酸化ケイ素からなる多孔質体を骨格として用いると共に、少なくとも平均粒径が3.5〜10μmに調整されているセリサイトの体質材を用いているため、パウダリーで良好な塗布感が得られると共に、マイクロ波を用いて製造することにより、低温で作製することが可能になるため、様々な顔料を熱処理による劣化を発生させずに使用することができ、発色が損なわれることも少なくなる化粧用鉛筆芯が得られる。
According to the present invention, comprise a skeleton of the porous body made of silicon oxide, those at least an average particle diameter contains a constitutional material of sericite which has been adjusted to 3.5~10Myuemu, it is attached Thus, a cosmetic pencil lead is provided which has a sufficient color developability and a drawn line density, a good coating feeling and excellent mechanical strength (bending strength, tensile strength, impact strength, etc.).
Further, Rutotomoni a porous body made of silicon oxide as a skeleton, since at least the average particle diameter is used extender material sericite being adjusted to 3.5~10Myuemu, good coating feeling powdery give In addition, since it can be produced at a low temperature by manufacturing using microwaves, various pigments can be used without causing deterioration due to heat treatment, and color development is less likely to be impaired. A cosmetic pencil lead is obtained.

以下、本発明の実施形態について説明するが、本発明は以下の実施の形態に限定されるものではない。   Hereinafter, although embodiment of this invention is described, this invention is not limited to the following embodiment.

本発明の化粧用鉛筆芯は、酸化ケイ素からなる多孔質体(以下、単に「酸化ケイ素多孔体」という)の骨格と、少なくとも平均粒径が3.5〜10μmに調整されているセリサイト体質材とを含有し、これらが結合したものを含むことを特徴とするものであり、また、本発明の化粧用鉛筆芯の製造方法としては、例えば、酸化ケイ素多孔質体を骨格として合成するため、下記一般式(I)で表される構造単位を有するポリシロキサンを平均粒径が3.5〜10μmに調整されているセリサイトの体質材及び着色材を少なくとも含有する配合組成物中に存在させ、マイクロ波による加熱処理を施すことにより、酸化ケイ素からなる多孔質体骨格と、少なくとも平均粒径が3.5〜10μmに調整されているセリサイトの体質材とを含有し、これらが結合したものを含む化粧用鉛筆芯を低温で製造することを特徴とするものである。

Figure 0005032092
Cosmetic pencil lead of the present invention, a porous body made of silicon oxide (hereinafter, simply "oxide porous silicon" hereinafter) and skeleton of at least an average particle diameter of sericite which is adjusted to 3.5~10μm And a combination of these , and as a method for producing a cosmetic pencil lead of the present invention, for example, a silicon oxide porous body is synthesized as a skeleton. Therefore, a polysiloxane having a structural unit represented by the following general formula (I) is contained in a composition containing at least a sericite extender and a colorant whose average particle size is adjusted to 3.5 to 10 μm. is present, by performing heat treatment by microwaves, contains a skeleton of a porous body made of silicon oxide, and a constitution material of sericite at least average particle diameter is adjusted to 3.5~10Myuemu, this Ru der which is characterized in that to produce a cosmetic pencil lead including those et bound at low temperatures.
Figure 0005032092

本発明の化粧用鉛筆芯は、上述の如く、酸化ケイ素多孔質体を骨格(結合材)とし、平均粒径を3.5〜10μmに調整されているセリサイトを体質材として含有するものであり、酸化ケイ素多孔質体を骨格として構成するため、例えば、上記一般式(I)で表される構造単位を有するポリシロキサンを体質材及び着色材を少なくとも含有する配合組成物中に存在させ、マイクロ波加熱処理などの加熱処理を施すことにより形成することができる。   As described above, the cosmetic pencil lead of the present invention contains sericite having a porous structure of silicon oxide as a skeleton (binding material) and an average particle size of 3.5 to 10 μm as a constitutional material. In order to constitute the silicon oxide porous body as a skeleton, for example, a polysiloxane having a structural unit represented by the above general formula (I) is present in a blend composition containing at least a body material and a colorant, It can be formed by performing heat treatment such as microwave heat treatment.

まず、本発明において、用いる酸化ケイ素多孔質体は、粉体同士を結合させる結合材として用いるものであれば、その構造は特に限定されるものではなく、例えば、非晶質、結晶質などの結晶構造や種々のセル構造のものが使用できる。通常、これらは単独で用いることとなるが、2種類以上を混合して用いることも可能であり、目的とする化粧用鉛筆芯の性状や強度によって適宜選択される。   First, in the present invention, the structure of the porous silicon oxide to be used is not particularly limited as long as it is used as a binder for bonding powders together. Crystal structures and various cell structures can be used. Usually, these are used alone, but two or more kinds can be mixed and used, and are appropriately selected depending on the properties and strength of the target cosmetic pencil lead.

本発明に用いるセリサイトは、良好な塗布感と機械的強度を付与するために、体質材として含有するものであり、その構造は特に限定されるものではなく、例えば、天然品、合成品などの製造方法の違いや産出地の違いによって微妙に構成成分が異なっているもの、または種々のポリタイプのものが使用できる。通常、これらは単独で用いることとなるが、2種類以上を混合して用いることも可能であり、目的とする化粧用鉛筆芯の性状や強度によって適宜選択される。   The sericite used in the present invention is contained as an extender in order to impart a good coating feeling and mechanical strength, and its structure is not particularly limited. For example, natural products, synthetic products, etc. Depending on the production method and the production area, those having slightly different constituents or those of various polytypes can be used. Usually, these are used alone, but two or more kinds can be mixed and used, and are appropriately selected depending on the properties and strength of the target cosmetic pencil lead.

用いるセリサイトは、酸化ケイ素多孔質体骨格との構造的バランスの関係から、平均粒径が3.5〜10μmとなるものを用いることが必要であり、好ましくは、6.5〜8.5μmとなるものを用いることが望ましい。
このセリサイトの平均粒径が3.5μm未満であると、パウダリーな塗布感が失われ硬くなり、一方、10μmを超えると、機械的強度が失われることとなり、好ましくない。なお、上記範囲となる平均粒径のセリサイトは、粉砕処理することなどにより好適に調整することができる。
The sericite to be used needs to have an average particle size of 3.5 to 10 μm, preferably 6.5 to 8.5 μm, in view of the structural balance with the silicon oxide porous skeleton. It is desirable to use
When the average particle size of the sericite is less than 3.5 μm, the powdery coating feeling is lost and hardened, while when it exceeds 10 μm, the mechanical strength is lost, which is not preferable. In addition, the sericite of the average particle diameter which becomes the said range can be adjusted suitably by grind | pulverizing.

本発明において、用いる酸化ケイ素多孔質体としては、好ましくは、上記一般式(I)で表されるポリシロキサンに特定の加熱硬化処理を施すことにより骨格として形成することが望ましい。
本発明で用いられる上記一般式(I)で表されるポリシロキサンは、珪素の有機化合物や珪素の無機化合物を出発原料として、ゾルゲル法等の一般的な重合方法に適した形で決定され、中でもテトラエトキシシランが安価で取り扱いも容易なことから特に好ましい。
また、本発明で用いられるポリシロキサンの重合度は、2以上であれば十分であり、特にその重合度の上限はなく、重合反応とポリシロキサンの取り扱いの容易さから適時決定される。
更に、上記一般式(I)で表されるポリシロキサンは、体質材などと充分になじませ、混練時及び成形時の特性向上の目的で、エタノール等で希釈し、希塩酸液等で調整したポリシロキサン溶液の形態で用いることが好ましい。
In the present invention, the porous silicon oxide used is preferably formed as a skeleton by subjecting the polysiloxane represented by the general formula (I) to a specific heat curing treatment.
The polysiloxane represented by the general formula (I) used in the present invention is determined in a form suitable for a general polymerization method such as a sol-gel method using a silicon organic compound or a silicon inorganic compound as a starting material, Of these, tetraethoxysilane is particularly preferable because it is inexpensive and easy to handle.
Further, the degree of polymerization of the polysiloxane used in the present invention is sufficient if it is 2 or more, and there is no particular upper limit of the degree of polymerization, and it is determined in a timely manner from the ease of the polymerization reaction and the handling of the polysiloxane.
Furthermore, the polysiloxane represented by the above general formula (I) is sufficiently blended with an extender and the like, diluted with ethanol or the like for the purpose of improving characteristics at the time of kneading and molding, and adjusted with a diluted hydrochloric acid solution or the like. It is preferably used in the form of a siloxane solution.

このポリシロキサンの配合量は、配合組成物全量に対して、好ましくは、2〜50重量%、更に好ましくは、3〜30重量%とすることが好ましい。このポリシロキサンの配合量が2重量%未満であると、強度不足で弱い芯となり、一方、50重量%を超えると、着色力が低く、塗布感の硬い芯となり、好ましくない。   The blending amount of this polysiloxane is preferably 2 to 50% by weight, more preferably 3 to 30% by weight, based on the total amount of the blending composition. When the blending amount of the polysiloxane is less than 2% by weight, the core becomes weak due to insufficient strength. On the other hand, when it exceeds 50% by weight, the coloring power is low and the core having a hard coating feeling is not preferable.

本発明においては、セリサイト以外の体質材も用いることができ、他の体質材としては、従来化粧用鉛筆芯に使用されているものであれば特に限定されるものではなく、いずれも使用可能である。セリサイトの他、窒化ホウ素、カオリン(カオリナイト)、タルク、マイカ、炭酸カルシウム等の白色系体質材や、化粧用鉛筆芯の色相によっては、有色系の体質材も使用することができ、当然これら数種類の混合物も使用できる。好ましくは、その物性、形状から窒化ホウ素、カオリンが挙げられる。
用いるセリサイトの含有量は、良好な塗布感と機械的強度を付与するために、配合組成物全量に対して、3〜20重量%とすることが好ましい。なお、セリサイトを含む体質材の合計含有量は、配合組成物全量に対して、15〜85重量%とすることが好ましい。
In the present invention, a constitution material other than sericite can also be used, and the other constitution material is not particularly limited as long as it is conventionally used for a cosmetic pencil lead, and any constitution material can be used. It is. In addition to sericite, white based materials such as boron nitride, kaolin (kaolinite), talc, mica, calcium carbonate, and other colored materials can be used depending on the hue of the pencil lead for makeup. Several of these mixtures can also be used. Preferably, boron nitride and kaolin are mentioned from the physical property and shape.
The content of sericite to be used is preferably 3 to 20% by weight with respect to the total amount of the blended composition in order to impart a good coating feeling and mechanical strength. In addition, it is preferable that the total content of the extender containing sericite is 15 to 85% by weight with respect to the total amount of the blended composition.

本発明において、塗布感が更に良好で、更なる機械的強度の向上の点から、セリサイト以外の体質材として、窒化ホウ素を含有せしめることが特に好ましく、窒化ホウ素を併用する場合の含有量は、前記セリサイト1に対し、窒化ホウ素を0.28〜4.0の重量比で含有することが望ましい。
用いる窒化ホウ素の平均粒径は、酸化ケイ素多孔質体骨格、セリサイトとの構造的バランスの関係から、好ましくは、4.5〜7.5μmとなるものが望ましい。
また、用いる窒化ホウ素とセリサイトの合計含有量は、更に良好な塗布感と機械的強度の更なる向上の点から、配合組成物全量に対して、15〜25重量%で配合することが望ましい。
In the present invention, the feeling of application is better, and from the viewpoint of further improving mechanical strength, it is particularly preferable to contain boron nitride as a constitution material other than sericite, and the content when boron nitride is used in combination is It is desirable to contain boron nitride in a weight ratio of 0.28 to 4.0 with respect to the sericite 1.
The average particle diameter of boron nitride to be used is preferably 4.5 to 7.5 μm in view of the structural balance with the silicon oxide porous body skeleton and sericite.
Further, the total content of boron nitride and sericite to be used is desirably 15 to 25% by weight based on the total amount of the blended composition from the viewpoint of further improving the coating feeling and mechanical strength. .

本発明で用いられる着色材としては、従来の化粧用鉛筆芯に使用されている公知の各種染料、無機顔料、有機顔料等をいずれも使用することができ、当然これら数種類の混合物も使用できる。特に好ましくは、その物性、形状から酸化鉄(黒、赤、黄)、紺青、酸化チタンが挙げられる。
これらの着色材の配合量は、配合組成物全量に対して、好ましくは、10〜75重量%、更に好ましくは、30〜55重量%とすることが望ましい。
As the coloring material used in the present invention, any of various known dyes, inorganic pigments, organic pigments and the like used in conventional cosmetic pencil cores can be used, and naturally these several kinds of mixtures can also be used. Particularly preferred are iron oxides (black, red, yellow), bitumen, and titanium oxide because of their physical properties and shape.
The blending amount of these colorants is preferably 10 to 75% by weight, more preferably 30 to 55% by weight, based on the total amount of the blending composition.

本発明の化粧用鉛筆芯の製造方法としては、例えば、酸化ケイ素多孔質体を骨格として合成するため、上記一般式(I)で表される構造単位を有するポリシロキサンを体質材及び着色材を少なくとも含有する配合組成物中に存在させ、この配合組成物を混練し、この混練物を押出機にて細線状に押出成形し、乾燥後、マイクロ波による加熱処理などの加熱処理を施すことにより、酸化ケイ素多孔質体を骨格とする化粧用鉛筆芯を低温で製造することができる。
マイクロ波による加熱処理の条件(周波数、照射時間等)は、化粧用鉛筆芯の用途、形状、原料種等により変動するが、直径4mm程度の化粧用鉛筆芯であれば、900〜3000MHz、100g程度のサンプルの場合、100Wで1〜60分間程度である。
また、マイクロ波による加熱処理以外の処理方法としては、窒素ガスなどの不活性ガス雰囲気中で、450〜700℃の温度で1〜48時間加熱処理することもできる。
As a method for producing a cosmetic pencil lead of the present invention, for example, in order to synthesize a silicon oxide porous body as a skeleton, a polysiloxane having a structural unit represented by the above general formula (I) is used as a constitution material and a coloring material. By presenting at least in the compounding composition to be contained, kneading the compounding composition, extruding the kneaded material into a thin line with an extruder, drying, and then subjecting to heat treatment such as heat treatment using microwaves. A cosmetic pencil lead having a silicon oxide porous body as a skeleton can be produced at a low temperature.
The conditions (frequency, irradiation time, etc.) of the heat treatment with microwaves vary depending on the use, shape, raw material type, etc. of the cosmetic pencil lead, but if it is a cosmetic pencil lead having a diameter of about 4 mm, 900 to 3000 MHz, 100 g. In the case of about a sample, it is about 1 to 60 minutes at 100 W.
As a treatment method other than the heat treatment by microwave, heat treatment can be performed at 450 to 700 ° C. for 1 to 48 hours in an inert gas atmosphere such as nitrogen gas.

本発明では、上述の如く、酸化ケイ素多孔質体からなるセラミックを骨格とし、セリサイトを体質材として用いているため、パウダリーで良好な塗布感が得られると共に、特に、マイクロ波加熱処理を用いて製造することにより、化粧用鉛筆芯を低温(100℃以下)での合成により製造することができるため、耐熱性の低い顔料を含む様々な顔料を熱処理による劣化を発生させずに、使用することができ、発色が損なわれることも少ない十分な多色化と鮮やかな発色性を有する化粧用鉛筆芯が製造されることとなる。
得られる化粧用鉛筆芯の酸化ケイ素多孔質体(骨格)の孔は、塗布感が軟らかく良好であり、機械的強度を維持しつつ、鮮やかな発色性と濃度を有する化粧用鉛筆芯を得る点から、直径が2nm〜1000nmの範囲、好ましくは、10〜200nmとなるものが望ましい。なお、上記酸化ケイ素多孔質体(骨格)の孔径の調整は、用いる原料(セリサイト、窒化ホウ素等)の平均粒径の選択、過熱処理条件などを好適に組み合わせることにより調整でき、また、その孔の測定(後述する実施例を含む)は、水銀圧入式の細孔分布測定装置(ユアサアイオニック社製)により測定することができる。
In the present invention, as described above, a ceramic made of a silicon oxide porous body is used as a skeleton, and sericite is used as a build material, so that a good coating feeling can be obtained in a powdery manner, and in particular, a microwave heat treatment is used. As a result, it is possible to produce a cosmetic pencil lead by synthesis at a low temperature (100 ° C. or less), so various pigments including pigments with low heat resistance are used without causing deterioration due to heat treatment. Thus, a cosmetic pencil lead having a sufficient number of colors and vivid color developability that is less likely to impair color development is produced.
The pores of the silicon oxide porous body (skeleton) of the resulting cosmetic pencil lead are soft and good in coating feeling, and obtain a cosmetic pencil lead having vivid color developability and concentration while maintaining mechanical strength. Therefore, it is desirable that the diameter is in the range of 2 nm to 1000 nm, preferably 10 to 200 nm. The pore size of the silicon oxide porous body (skeleton) can be adjusted by suitably combining the selection of the average particle size of the raw materials to be used (sericite, boron nitride, etc.) and the conditions of the heat treatment. The measurement of the pores (including examples described later) can be performed with a mercury intrusion type pore distribution measuring device (manufactured by Yuasa Ionic Co., Ltd.).

このように構成される本発明では、素材を成形させた後に、結合材となる酸化ケイ素多孔質体が骨格とし、特定範囲となる平均粒径のセリサイトが体質材として含有されることとなるので、十分な発色性、描線濃度を持ちながら、塗布感を酸化ケイ素多孔質体の孔の大きさや分布、若しくは材料種及びセリサイトの平均粒径の選択によって硬くも軟らかくも自由に設定でき、機械的強度(曲げ強度、引張強度、衝撃強度等)にも優れると共に、多色化を可能とした化粧用鉛筆芯及びその製造方法が得られるものとなる。
得られる化粧用鉛筆芯は、軸体として繰り出し容器、木軸、紙巻、樹脂軸、ホルダーを用いて化粧用鉛筆に好適に適用することができる。
In the present invention configured as described above, after forming the raw material, the porous silicon oxide body serving as a binder is used as a skeleton, and sericite having an average particle diameter within a specific range is contained as the extender. Therefore, while having sufficient color developability and drawing density, the coating feeling can be freely set to be hard or soft by selecting the size and distribution of pores of the silicon oxide porous body, or the material type and the average particle size of sericite, A cosmetic pencil lead that is excellent in mechanical strength (bending strength, tensile strength, impact strength, etc.) and can be multicolored and a method for producing the same are obtained.
The resulting cosmetic pencil lead can be suitably applied to a cosmetic pencil using a feeding container, a wooden shaft, a paper roll, a resin shaft, and a holder as a shaft.

このように構成される本発明の化粧用鉛筆芯は、上記実施形態に限定されるものではなく、本発明の技術思想の範囲内で、種々変更して実施することができる。   The makeup pencil lead of the present invention configured as described above is not limited to the above embodiment, and can be implemented with various modifications within the scope of the technical idea of the present invention.

次に、実施例及び比較例により、本発明をさらに具体的に説明するが、本発明は下記実施例に何等限定されるものではない。   EXAMPLES Next, although an Example and a comparative example demonstrate this invention further more concretely, this invention is not limited to the following Example at all.

(実施例1)
テトラエトキシシラン50gをエタノール50gで希釈し、1時間混合後、0.01N−HCl水溶液を100g滴下して6時間混合し、溶液Aを得た。
配合組成物:
溶液A 30.0重量%
黒酸化鉄 20.0重量%
弁柄 17.5重量%
セリサイト(平均粒径6.5μm) 27.5重量%
カオリナイト(平均粒径4.8μm) 15.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、空気中80℃で24時間乾燥後、芯をIPA(イソプロピルアルコール)で洗浄し、マイクロ波加熱(2.45GHz・700W)を3分間行い、直径4.0mmの茶色化粧用鉛筆芯を得た。
Example 1
After diluting 50 g of tetraethoxysilane with 50 g of ethanol and mixing for 1 hour, 100 g of 0.01N-HCl aqueous solution was added dropwise and mixed for 6 hours to obtain Solution A.
Formulation composition:
Solution A 30.0% by weight
Black iron oxide 20.0% by weight
17.5% by weight
Sericite (average particle size 6.5 μm) 27.5% by weight
Kaolinite (average particle size 4.8 μm) 15.0% by weight
The above blended composition is kneaded, extruded into a thin line with an extruder, dried in air at 80 ° C. for 24 hours, washed with IPA (isopropyl alcohol), and heated with microwave (2.45 GHz, 700 W). Was performed for 3 minutes to obtain a brown cosmetic pencil lead having a diameter of 4.0 mm.

(実施例2)
テトラエトキシシラン50gをエタノール50gで希釈し、1時間混合後、0.01N−HCl水溶液を80g滴下して6時間混合し、溶液Bを得た。
配合組成物:
溶液B 30.0重量%
黒酸化鉄 20.0重量%
弁柄 10.0重量%
セリサイト(平均粒径6.5μm) 10.0重量%
窒化ホウ素(平均粒径4.5μm) 6.0重量%
カオリナイト(平均粒径4.8μm) 24.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、空気中80℃で24時間乾燥後、芯をIPAで洗浄し、マイクロ波加熱(2.45GHz・700W)を3分間行い、直径4.0mmの茶色化粧用鉛筆芯を得た。
(Example 2)
After diluting 50 g of tetraethoxysilane with 50 g of ethanol and mixing for 1 hour, 80 g of 0.01N-HCl aqueous solution was dropped and mixed for 6 hours to obtain Solution B.
Formulation composition:
Solution B 30.0% by weight
Black iron oxide 20.0% by weight
Petal 10.0% by weight
Sericite (average particle size 6.5 μm) 10.0% by weight
Boron nitride (average particle size 4.5 μm) 6.0% by weight
Kaolinite (average particle size 4.8 μm) 24.0% by weight
The above blended composition is kneaded, extruded into a thin line with an extruder, dried in air at 80 ° C. for 24 hours, the core washed with IPA, and microwave heating (2.45 GHz · 700 W) performed for 3 minutes. A brown cosmetic pencil lead with a diameter of 4.0 mm was obtained.

(実施例3)
エチルポリシエリケートとテトラエトキシシランの混合物(エチルシリケート40:コルコート株式会社製)50gをエタノール50gで希釈し、0.01N−クエン酸水溶液を100g滴下して6時間混合し、溶液Cを得る
配合組成物:
黒酸化鉄 20.0重量%
弁柄 9.5重量%
セリサイト(平均粒径6.5μm) 10.5重量%
窒化ホウ素(平均粒径4.5μm) 5.0重量%
カオリナイト(平均粒径4.8μm) 35.0重量%
溶液C 20.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、窒素中700℃で24時間乾燥後、溶液Cを含浸し、マイクロ波加熱(2.45GHz・700W)を3分間行い、直径4.0mmの茶色化粧用鉛筆芯を得た。
(Example 3)
50 g of a mixture of ethyl polysilicate and tetraethoxysilane (ethyl silicate 40: manufactured by Colcoat Co., Ltd.) is diluted with 50 g of ethanol, and 100 g of 0.01N-citric acid aqueous solution is added dropwise and mixed for 6 hours to obtain solution C. Composition:
Black iron oxide 20.0% by weight
9.5% by weight
Sericite (average particle size 6.5 μm) 10.5% by weight
Boron nitride (average particle size 4.5 μm) 5.0% by weight
Kaolinite (average particle size 4.8 μm) 35.0% by weight
Solution C 20.0% by weight
The above blended composition was kneaded, extruded into a thin line with an extruder, dried at 700 ° C. in nitrogen for 24 hours, impregnated with solution C, and subjected to microwave heating (2.45 GHz · 700 W) for 3 minutes. A brown cosmetic pencil lead with a diameter of 4.0 mm was obtained.

(実施例4)
エチルポリシエリケートとテトラエトキシシランの混合物(エチルシリケート40:コルコート株式会社製)40gをエタノール60gで希釈し、0.01N−クエン酸水溶液を100g滴下して6時間混合し、溶液Cを得た。
配合組成物:
二酸化チタン被覆マイカ(平均粒径22.5μm) 50.0重量%
セリサイト(平均粒径6.5μm) 10.0重量%
窒化ホウ素(平均粒径4.5μm) 5.0重量%
カオリナイト(平均粒径4.8μm) 15.0重量%
溶液C 20.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、窒素中700℃で24時間乾燥し、直径7.0mmの白色アイシャドー用鉛筆芯を得た。
Example 4
40 g of a mixture of ethyl polysilicate and tetraethoxysilane (ethyl silicate 40: manufactured by Colcoat Co., Ltd.) was diluted with 60 g of ethanol, 100 g of 0.01N-citric acid aqueous solution was added dropwise and mixed for 6 hours to obtain Solution C. .
Formulation composition:
Titanium dioxide-coated mica (average particle size 22.5 μm) 50.0% by weight
Sericite (average particle size 6.5 μm) 10.0% by weight
Boron nitride (average particle size 4.5 μm) 5.0% by weight
Kaolinite (average particle size 4.8 μm) 15.0% by weight
Solution C 20.0% by weight
The above blended composition was kneaded, extruded into a thin line with an extruder, and dried in nitrogen at 700 ° C. for 24 hours to obtain a white eyeshadow pencil lead having a diameter of 7.0 mm.

(比較例1)
配合組成物:
溶液A 30.0重量%
黒酸化鉄 20.0重量%
弁柄 10.0重量%
窒化ホウ素(平均粒径4.5μm) 10.0重量%
カオリナイト(平均粒径4.8μm) 30.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、空気中80℃で24時間乾燥後、芯の不純物をソックスレー抽出し、マイクロ波加熱(2.45GHz・700W)を3分間行い、直径4.0mmの茶色化粧用鉛筆芯を得た。
(Comparative Example 1)
Formulation composition:
Solution A 30.0% by weight
Black iron oxide 20.0% by weight
Petal 10.0% by weight
Boron nitride (average particle size 4.5 μm) 10.0% by weight
Kaolinite (average particle size 4.8 μm) 30.0% by weight
The above blended composition is kneaded, extruded into a thin line with an extruder, dried in air at 80 ° C. for 24 hours, core impurities are Soxhlet extracted, and microwave heating (2.45 GHz · 700 W) is applied for 3 minutes. A brown cosmetic pencil lead having a diameter of 4.0 mm was obtained.

(比較例2)
配合組成物:
溶液B 30.0重量%
黒酸化鉄 20.0重量%
弁柄 10.0重量%
窒化ホウ素(平均粒径4.5μm) 22.0重量%
カオリナイト(平均粒径4.8μm) 18.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、空気中80℃で24時間乾燥後、芯をIPAで洗浄し、マイクロ波加熱(2.45GHz・700W)を3分間行い、直径4.0mmの茶色化粧用鉛筆芯を得た。
(Comparative Example 2)
Formulation composition:
Solution B 30.0% by weight
Black iron oxide 20.0% by weight
Petal 10.0% by weight
Boron nitride (average particle size 4.5 μm) 22.0% by weight
Kaolinite (average particle size 4.8 μm) 18.0% by weight
The above blended composition is kneaded, extruded into a thin line with an extruder, dried in air at 80 ° C. for 24 hours, the core washed with IPA, and microwave heating (2.45 GHz · 700 W) performed for 3 minutes. A brown cosmetic pencil lead with a diameter of 4.0 mm was obtained.

(比較例3)
配合組成物:
黒酸化鉄 20.0重量%
弁柄 5.0重量%
セリサイト(平均粒径6.5μm) 15.0重量%
窒化ホウ素(平均粒径4.5μm) 5.0重量%
カオリナイト(平均粒径4.8μm) 30.0重量%
ベントナイト(平均粒径4.5μm) 5.0重量%
蒸留水 20.0重量%
上記配合組成物を2本ロールで混練し、さらに3本ロールで分散した後、この混練物をスクリュー型押出機にて細線状に押出成形し、窒素雰囲気中で700℃まで昇温して5時間焼成し、直径4.0mmの茶色化粧用鉛筆芯を得た。
(Comparative Example 3)
Formulation composition:
Black iron oxide 20.0% by weight
Petal 5.0% by weight
Sericite (average particle size 6.5 μm) 15.0% by weight
Boron nitride (average particle size 4.5 μm) 5.0% by weight
Kaolinite (average particle size 4.8 μm) 30.0% by weight
Bentonite (average particle size 4.5 μm) 5.0% by weight
Distilled water 20.0% by weight
The above blended composition is kneaded with two rolls and further dispersed with three rolls, and then the kneaded product is extruded into a thin wire shape with a screw type extruder, heated to 700 ° C. in a nitrogen atmosphere and heated to 5 ° C. By baking for a while, a brown cosmetic pencil lead having a diameter of 4.0 mm was obtained.

(比較例4)
配合組成物:
二酸化チタン被覆マイカ(平均粒径22.5μm) 50.0重量%
窒化ホウ素(平均粒径4.5μm) 5.0重量%
カオリナイト(平均粒径4.8μm) 20.0重量%
溶液C 20.0重量%
上記配合組成物を混練し、押出機にて細線状に押出成形し、窒素中700℃で24時間乾燥し、直径7.0mmのアイシャドー用鉛筆芯を得た。
(Comparative Example 4)
Formulation composition:
Titanium dioxide-coated mica (average particle size 22.5 μm) 50.0% by weight
Boron nitride (average particle size 4.5 μm) 5.0% by weight
Kaolinite (average particle size 4.8 μm) 20.0% by weight
Solution C 20.0% by weight
The above blended composition was kneaded, extruded into a thin line with an extruder, and dried in nitrogen at 700 ° C. for 24 hours to obtain an eye shadow pencil lead having a diameter of 7.0 mm.

上記実施例1〜4及び比較例1〜4で得られた各化粧用鉛筆芯体の成形性、機械的強度、発色性(外観及び描線色)、官能評価による塗布感の各評価を行った。
なお、機械的強度は、支点間20mm、速度5mm/minの条件で三点曲げ強度試験を各芯20本行い、比較例1の折損荷重(7N)を100とした比率で表し、成形性、発色性と塗布感の評価は、木軸に組んだ鉛筆の形状で行った。
これらの結果を下記表1に示す。
Each evaluation of the moldability of each cosmetic pencil core obtained in Examples 1 to 4 and Comparative Examples 1 to 4, mechanical strength, color developability (appearance and line drawing color), and coating feeling by sensory evaluation was performed. .
The mechanical strength is expressed as a ratio with 20 breaks (7N) of Comparative Example 1 taken as 100, with a three-point bending strength test conducted under the conditions of 20 mm between fulcrums and a speed of 5 mm / min. Evaluation of color developability and coating feeling was performed in the form of a pencil assembled on a wooden shaft.
These results are shown in Table 1 below.

Figure 0005032092
Figure 0005032092

(表1の考察)
本発明範囲となる実施例1〜3のアイブロー用に好適な化粧用鉛筆芯、並びに、実施例4のアイシャドー用鉛筆芯は、摩耗し易く、サラサラした塗布感が得られていると同時に極めて発色性が良く機械的強度も強いことが判明した。また、実施例1〜4の化粧用鉛筆芯において、酸化ケイ素多孔質体(骨格)の孔を測定したところ、いずれも、直径が2nm〜1000nmの範囲内のものであった。また、実施例1〜4の化粧用鉛筆芯に油分を含浸しても良好な塗布感が得られるものであった。
一方、本発明範囲外の比較例1は、セリサイトを用いず、替わりに窒化ホウ素を用いることにより、成形性の悪さを補うためにカオリンを多めに配合しているため、カオリンの塗布感が強く出てしまっている。
また、比較例2、4に示したように窒化ホウ素ばかりで構成されていると、ヌルヌルした塗布感が発現し、結果としてサラサラした塗布感は失われてしまった。また、窒化ホウ素が多くなると、機械的強度も弱くなってしまう傾向にある。
更に、比較例3に示したように骨格が酸化ケイ素多孔質体以外の物質であると、強度と塗布感のバランスが悪く、実施例3と比較すると実施例3の優位性は明らかである。
(Consideration of Table 1)
The cosmetic pencil lead suitable for the eyebrow of Examples 1 to 3 and the eye shadow pencil lead of Example 4 that are within the scope of the present invention are easily worn and have a smooth coating feeling and at the same time. It was found that the color development was good and the mechanical strength was strong. Moreover, when the hole of the silicon oxide porous body (skeleton) was measured in the cosmetic pencil lead of Examples 1 to 4, all had a diameter in the range of 2 nm to 1000 nm. Further, even when the cosmetic pencil lead of Examples 1 to 4 was impregnated with oil, a good coating feeling was obtained.
On the other hand, Comparative Example 1 outside the scope of the present invention does not use sericite, but instead uses boron nitride, so that a large amount of kaolin is blended in order to compensate for poor moldability. It has come out strongly.
Moreover, when it was comprised only with boron nitride as shown to the comparative examples 2 and 4, the coating feeling which became null null appeared and as a result, the smooth coating feeling was lost. Moreover, when the amount of boron nitride increases, the mechanical strength tends to be weakened.
Furthermore, as shown in Comparative Example 3, when the skeleton is a substance other than the silicon oxide porous body, the balance between strength and coating feeling is poor, and the superiority of Example 3 is clear when compared with Example 3.

Claims (6)

酸化ケイ素からなる多孔質体骨格と、少なくとも平均粒径が3.5〜10μmに調整されているセリサイト体質材とを含有し、これらが結合したものを含むことを特徴とする化粧用鉛筆芯。 Cosmetic to the skeleton of the porous body made of silicon oxide, characterized in that it includes those in which at least an average particle diameter contains a constitutional material of sericite which has been adjusted to 3.5~10Myuemu, they are attached Pencil lead. 前記セリサイトに対し、窒化ホウ素を1:0.28〜4.0の重量比で更に含有し、結合したものを含むこと特徴とする請求項1に記載の化粧用鉛筆芯。 The cosmetic pencil lead according to claim 1, further comprising boron nitride in a weight ratio of 1: 0.28 to 4.0 and bonded to the sericite. 前記窒化ホウ素の平均粒径が4.5〜7.5μmであることを特徴とする請求項2に記載の化粧用鉛筆芯。 3. The cosmetic pencil lead according to claim 2, wherein the boron nitride has an average particle size of 4.5 to 7.5 [mu] m. 前記窒化ホウ素と前記セリサイトの合計含有量が、化粧用鉛筆芯の全体量に対して、15〜25重量%含有されていることを特徴とする請求項2又は3に記載の化粧用鉛筆芯。 The total content of the sericite and the boron nitride, cosmetic pencil lead according to claim 2 or 3 with respect to the total amount of the cosmetic pencil leads, characterized in that it is contained 15 to 25 wt% . 前記酸化ケイ素からなる多孔質体の孔が直径2〜1000nmの範囲であることを特徴とする請求項1〜4の何れか一つに記載の化粧用鉛筆芯。 Cosmetic pencil lead according to any one of claims 1 to 4 pores of the porous body consisting of the silicon oxide is characterized by a range of diameters 2 to 1000 nm. 酸化ケイ素多孔質体を骨格として合成するため、下記一般式(I)で表される構造単位を有するポリシロキサンを平均粒径が3.5〜10μmに調整されているセリサイトの体質材及び着色材を少なくとも含有する配合組成物中に存在させ、マイクロ波による加熱処理を施すことにより、酸化ケイ素からなる多孔質体を骨格とし、少なくとも平均粒径が3.5〜10μmに調整されているセリサイトの体質材とを含有し、これらが結合したものを含む化粧用鉛筆芯を低温で製造することを特徴とする化粧用鉛筆芯の製造方法。
Figure 0005032092
In order to synthesize a silicon oxide porous body as a skeleton, a polysiloxane having a structural unit represented by the following general formula (I) and a coloring material of sericite whose average particle diameter is adjusted to 3.5 to 10 μm and coloring be present in the blend composition containing at least wood, by applying a heat treatment by microwaves, a porous body made of silicon oxide as a skeleton, at least the average particle size is adjusted to 3.5~10μm A method for producing a cosmetic pencil lead, comprising a sericite extender, and a cosmetic pencil lead comprising those bound together .
Figure 0005032092
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