JP5010127B2 - High refractive index polysilane - Google Patents

Description

  The present invention relates to a polysilane having a very high refractive index and excellent solvent solubility and film-forming properties, and a method for producing the same.

  Polysilanes are attracting attention as ceramic precursors, optoelectronic materials (for example, photoelectrophotographic materials such as photoresists and organic photoreceptors, optical transmission materials such as optical waveguides, optical recording materials such as optical memories, and materials for electroluminescent elements). ing. In such applications, polysilane is usually used in the form of a thin film. However, methylphenyl polysilane and diphenyl polysilane, which are the most common polysilanes, have low solubility in solvents, and the thin films of these polysilanes are hard and brittle, and have low mechanical strength. . Moreover, although the refractive index of polysilane is high as an organic compound, most is 1.75 or less, and polysilane with a higher refractive index tends to have lower solubility in solvents and crack resistance.

As a method for producing polysilane, WO 98/29476 pamphlet (Patent Document 1) includes lithium salts (LiCl, LiNO ₃ , Li ₂ CO ₃ , LiClO _4, etc.) and metal halides (aprotic solvent) (Patent Document 1). A method of forming polysilane by allowing magnesium or a magnesium alloy to act on dihalosilane in the presence of FeCl ₂ , FeCl _3, etc. is disclosed. However, in this method, three components of a lithium salt, a metal halide, and a magnesium component are essential, and the resulting polysilane has insufficient solubility in a solvent, affinity for a resin, and film formability.

Japanese Patent Laying-Open No. 2005-36139 (Patent Document 2) discloses a copolysilane composed of a diarylsilane unit and other halosilane units (mono to tetrahalosilane units, etc.). And in the Example of the said patent document 2, the copolysilane obtained by using diphenyldichlorosilane and phenyltrichlorosilane by 400/100 (molar ratio) is disclosed. However, in such a copolysilane, in addition to solvent solubility and film formability, the refractive index can be improved to a certain extent of 1.70 to 1.73, but a higher refractive index (for example, a refractive index of 1.75 or more). It is not applicable to the required use.
WO 98/29476 pamphlet (Claim 1) Japanese Patent Laying-Open No. 2005-36139 (Claims 1 and 2 and Example 4)

  Accordingly, an object of the present invention is to provide a polysilane having a very high refractive index, excellent solubility in a solvent and film formability, and usable as a thin film, and a method for producing the same.

  Another object of the present invention is to provide a method for producing polysilane capable of controlling the physical properties of polysilane by a simple method.

  As a result of intensive studies to achieve the above-mentioned problems, the inventors of the present invention reacted with an aryltrihalosilane compound, a monohalosilane compound, and / or a dihalosilane compound, resulting in a high refractive index and improved solubility in a solvent and film formability. The inventors have found that excellent polysilane can be easily obtained, and completed the present invention.

  That is, the polysilane of the present invention is a polysilane composed of an aryltrihalosilane unit and at least one other halosilane unit selected from a monohalosilane unit and a dihalosilane unit. The polysilane is prepared in an aprotic solvent in the presence of (i) a catalyst composed of a metal magnesium component alone, or (ii) a catalyst system combining a metal magnesium component and lithium halide or a halide of a polyvalent metal. And an aryl trihalosilane compound and at least one other halosilane compound selected from a monohalosilane compound and a dihalosilane compound.

  In the polysilane, the ratio (molar ratio) between the aryltrihalosilane unit and the other halosilane unit may be about the former / the latter = 60/40 to 99/1.

  The aryltrihalosilane unit has the following formula (1)

(In the formula, X ^{1 to} X ³ are the same or different and each represents a halogen atom, R ¹ represents an organic group or a silyl group, R ¹ may be different depending on n, and n is an integer of 0 to 5. )
The monohalosilane unit may be a halosilane unit corresponding to the aryltrihalosilane compound represented by the following formula (2):

(Wherein X ⁴ represents a halogen atom, and R ^{2 to} R ⁴ are the same or different and represent a hydrogen atom, an organic group or a silyl group)
The dihalosilane unit may be a halosilane unit corresponding to the monohalosilane compound represented by the following formula (3):

(In the formula, X ⁵ and X ⁶ are the same or different and represent a halogen atom, and R ⁵ and R ⁶ are the same or different and represent a hydrogen atom, an organic group or a silyl group)
The halosilane unit corresponding to the dihalosilane compound represented by these may be sufficient. In the formulas (1) to (3), the organic group represented by R ^{1 to} R ⁶ may be a hydrocarbon group, an alkoxy group, an amino group, or an N-substituted amino group. The polysilane includes a unit corresponding to a C _6-10 aryltrihalosilane compound and a silane unit corresponding to at least one other halosilane compound selected from trialkylhalosilane, alkylaryldihalosilane, and diaryldihalosilane. You may have.

  In the present invention, (i) a catalyst composed of a metal magnesium component alone, or (ii) a catalyst system in which a metal magnesium component and a lithium halide or a halide of a polyvalent metal are combined, in an aprotic solvent. A polysilane is produced by reacting an aryltrihalosilane compound with at least one other halosilane compound selected from a monohalosilane compound and a dihalosilane compound.

  The present invention also includes a method for improving the film forming property and / or the solubility in a solvent and the refractive index using the polysilane.

  In the present invention, since the polysilane is composed of the aryltrihalosilane unit and the specific silane unit (monohalosilane unit and / or dihalosilane unit), a polysilane having a very high refractive index can be easily produced. Further, it is excellent in solubility in a solvent, compatibility with a resin, and film formability, and a polysilane usable as a thin film can be easily produced. Moreover, since the aryltrihalosilane unit and the specific silane unit are combined, polysilane can be produced in a high yield by a simple method without using any special apparatus or method, and the physical properties of the polysilane can be easily obtained. Can be controlled.

[Polysilane]
The polysilane of the present invention is a copolysilane composed of an aryltrihalosilane unit and at least one other halosilane unit selected from a monohalosilane unit and a dihalosilane unit. The polysilane is obtained by reacting an aryltrihalosilane compound corresponding to the aryltrihalosilane unit with at least one other halosilane compound selected from a monohalosilane compound and a dihalosilane compound corresponding to the monohalosilane unit and the dihalosilane unit, respectively. .

  The aryltrihalosilane compound, monohalosilane compound, and dihalosilane compound may be an aryltrihalosilane compound, a monohalosilane compound, and a dihalosilane compound represented by the formulas (1), (2), and (3), respectively.

In the above formulas (1), (2) and (3), the organic group represented by R ^{1 to} R ⁶ is an alkyl group [straight chain such as methyl, ethyl, propyl, isopropyl, butyl and t-butyl groups. Or a branched C _1-10 alkyl group (preferably a C _1-6 alkyl group, particularly a C _1-4 alkyl group, etc.), a cycloalkyl group (C _5-8 cycloalkyl group such as a cyclohexyl group, in particular C _5-6 cycloalkyl group and the like), aryl groups (C _6-10 aryl groups such as phenyl and naphthyl groups), aralkyl groups [C _6-10 aryl-C _1-6 alkyl groups such as benzyl and phenethyl groups ( C _6-10 aryl-C _1-4 alkyl group etc.), etc.], as well as alkoxy groups [C _1-10 alkoxy groups such as methoxy, ethoxy, propoxy, isopropoxy, butoxy and t-butoxy groups] (Preferably C _1-6 alkoxy groups, especially C _1-4 alkoxy group), etc.], an amino group, and N- substituted amino group (said alkyl group, a cycloalkyl group, an aryl group, an aralkyl group, N substituted with an acyl group -Mono- or di-substituted amino group, etc.).

The aryl group constituting the alkyl group, cycloalkyl group, aryl group, or aralkyl group may have a substituent. Examples of such a substituent include the above-exemplified alkyl groups (particularly, C _1-6 alkyl groups and the like), the above-exemplified alkoxy groups and the like. The number of substituents is not particularly limited, and may be one or plural (for example, 2 to 4). Examples of the organic group having such a substituent include C _1-6 alkyl C _6-10 aryl groups such as tolyl, xylenyl, ethylphenyl, and methylnaphthyl groups (preferably mono to tri C _1-4 alkyl C _{6 -10} aryl groups, especially mono or di C _1-4 alkylphenyl groups); C _1-10 alkoxy C _6-10 aryl groups such as methoxyphenyl, ethoxyphenyl, _{methoxynaphthyl} groups (preferably C _1-6 alkoxy C) _6-10 aryl group, especially C _1-4 alkoxyphenyl group, etc.).

The silyl group represented by R ^{1 to} R ⁶ may be a substituted silyl group substituted with the alkyl group, cycloalkyl group, aryl group, aralkyl group, alkoxy group or the like.

  Of these groups, hydrogen atoms or hydrocarbon groups, particularly hydrocarbon groups (alkyl groups, aryl groups, aralkyl groups, etc.) are preferred.

In the above formulas (1) to (3), the halogen atoms represented by X ^{1 to} X ⁶ include F, Cl, Br, and I atoms. Of these halogen atoms, Cl and Br (especially Cl) atoms are particularly preferred.

(1) Aryltrihalosilane compound In the aryltrihalosilane compound represented by the formula (1), n may be an integer of 0 to 5, preferably an integer of 0 to 3, more preferably an integer of 0 to 2. Good. The group R ¹ may be different depending on n.

As the aryl trihalosilane compound, in the formula (1), a phenyl trihalosilane compound that does not have the group R ¹ , that is, n = 0, or the group R ¹ is an alkyl group (for example, a methyl group, an ethyl group, or the like). A substituted phenyltrihalosilane compound (for example, n is an integer of 1 to 3) such as a C _1-6 alkyl group) and / or the above alkoxy group (C _1-6 alkoxy group such as methoxy group, ethoxy group, etc.). Compound) is preferred.

Specific examples of the aryltrihalosilane compound include phenyltrihalosilanes such as phenyltrichlorosilane, phenyltribromosilane, and phenylbromodichlorosilane; substituted phenyltrihalosilanes corresponding to the phenyltrihalosilane (tolyltrichlorosilane and xylyltrichlorosilane). C _6-10 aryl trihalosilanes such as mono to tri C _1-4 alkyl-phenyl trihalosilanes such as methoxytolyltrichlorosilane; mono to tri C _1-4 alkoxy-phenyl trihalosilanes such as methoxyphenyl trichlorosilane Is mentioned.

  Aryl trihalosilane compounds can be used alone or in combination of two or more.

(2) Monohalosilane Compound In the monohalosilane compound of the above formula (2), the groups R ^{2 to} R ⁴ are preferably hydrocarbon groups such as alkyl groups and aryl groups.

Specific examples of the monohalosilane compound include, for example, trialkylhalosilanes (such as tri-C _1-6 alkylhalosilanes such as trimethylchlorosilane) and dialkylarylhalosilanes (di-C _1-6 alkyl C _6-10 such as dimethylphenylchlorosilane). arylhalosilanes etc.), a C _1-6 alkyl di C _6-10 aryl halosilanes, such as an alkyl diaryl halo silane (methyl diphenyl chlorosilane), triaryl halo silane (tri C _6-10 aryl halosilane such as triphenyl chlorosilane, etc. And the like.

  These monohalosilane compounds can be used alone or in combination of two or more.

(3) Dihalosilane Compound In the dihalosilane compound of the above formula (3), the groups R ⁵ and R ⁶ are preferably hydrocarbon groups such as alkyl groups and aryl groups.

Specific examples of the dihalosilane compound include, for example, dialkyldihalosilane (diC _1-4 alkyldihalosilane such as dimethyldichlorosilane) and alkylaryldihalosilane (C _1-4 alkylC such as methylphenyldichlorosilane). _6-10 an aryl dihalo silane), and di-C _6-10 aryl dihalo silane such as diaryl dihalo silane (diphenyl dichlorosilane) and the like.

  These dihalosilane compounds can be used alone or in combination of two or more.

Of the other halosilane compounds, trialkylhalosilane, alkylaryldihalosilane, diaryldihalosilane and the like are particularly preferable. That is, among polysilanes, polysilanes having silane units corresponding to these other halosilane compounds and aryltrihalosilane units (such as C _6-10 aryltrihalosilane) are preferred.

  The polymerization form of polysilane is not particularly limited, and may be a random or block copolymer. The block copolymer can be obtained, for example, by using an oligomer or polymer of the dihalosilane compound (3) (particularly an oligomer or polymer having a large number of repeating dihalosilane units). A random copolymer can be obtained by using the halosilane compound (2) or (3) as a monomer or an oligomer having a small number of repeating halosilane units.

  In the polysilane, the ratio (molar ratio) of the aryl trihalosilane compound (aryltrihalosilane unit) and the other trihalosilane compound (other trihalosilane unit) is not particularly limited, and the former / the latter = 10/90 to 99 / 1 can be selected from a wide range, for example, 10/90 to 95/5, preferably 20/80 to 90/10, and more preferably about 30/70 to 80/20. In addition, when another halosilane unit contains a diaryldihalosilane unit, the ratio of the aryltrihalosilane unit to 1 mol of the diaryldihalosilane unit is preferably more than 0.25 mol. The polysilane of the present invention usually contains an aryl trihalosilane unit as a main constituent unit, and the ratio of the aryl trihalosilane compound to the other trihalosilane compound is, for example, 55/45 to 99/1, preferably 60. / 40 to 95/5, more preferably about 65/35 to 90/10.

  The ratio of the aryltrihalosilane unit to the entire halosilane unit (that is, the ratio of the aryltrihalosilane compound to the entire halosilane compound) is, for example, 50 mol% or more (for example, about 50 to 98 mol%), preferably 55 to 97 mol%. (For example, 60 to 97 mol%), more preferably about 65 to 95 mol% (for example, 70 to 95 mol%).

  In polysilane, when the proportion of the trihalosilane compound is increased, the refractive index is improved, but the solubility in a solvent tends to be reduced. Further, when the proportion of the trihalosilane compound is reduced, the solubility in a solvent and the film formability are improved, but the refractive index tends to gradually decrease.

  The weight average molecular weight of polysilane is, for example, about 500 to 5,000, preferably about 800 to 4,000, and more preferably about 1,000 to 3,000 (for example, 1,200 to 2,500).

  The thin film refractive index of polysilane (the refractive index of the thin film formed of polysilane (refractive index for light having a wavelength of 589.4 nm)) is 1.75 or more (for example, 1.75 to 1) when the thickness of the thin film is 1 μm. .85), preferably 1.755 to 1.85, more preferably about 1.76 to 1.85.

  The solution transmittance of polysilane (transmittance for visible light having a wavelength of 600 nm) is 60% or more (for example, about 65 to 100%), preferably 70 to 100%, with respect to a toluene solution containing polysilane at a concentration of 50% by weight. More preferably, it is about 80 to 100% (for example, 90 to 100%). The solution permeability is 70% or more (for example, 70 to 100%), preferably 80 for a propylene glycol-1-monoethyl ether-2-acetate (PGMEA) solution containing polysilane at a concentration of 10% by weight. It is about -100% (for example, 90-100%), More preferably, it is about 90-100%. In the polysilane, at least one of the toluene solution and the PGMEA solution may have a solution permeability in such a range. Usually, both solutions have a solution permeability in the above range. There are many.

[Production method of polysilane]
The polysilane can be produced by reacting an aryltrihalosilane compound with at least one other halosilane compound selected from a monohalosilane compound and a dihalosilane compound. The reaction between the aryltrihalosilane compound and another halosilane compound may be usually carried out in an aprotic solvent in the presence of (i) a magnesium metal component or (ii) a magnesium metal component and a metal halide.

(Catalyst or catalyst system)
In the reaction, (i) magnesium metal component, and (ii) magnesium metal component and metal halide constitute a catalyst or a catalyst system, respectively. In the production method of the present invention, the metal halide is not essential, and it is possible to produce a polysilane having a high refractive index and a high solubility in a solvent even with a magnesium metal component alone. In particular, conventionally used catalyst systems, for example, there is no need to use a combination of three components of a magnesium metal component, a lithium halide or lithium salt, and another metal halide (metal halide other than lithium). In addition, the refractive index can be greatly improved (improved to 1.75 or more).

(a) Magnesium metal component The magnesium metal component only needs to contain at least magnesium, and may be a magnesium metal alone or a magnesium-based alloy, or a mixture containing the magnesium metal or alloy. The magnesium alloy is not particularly limited, and examples thereof include conventional magnesium alloys such as magnesium alloys containing components such as aluminum, zinc, rare earth elements (scandium, yttrium, etc.). These magnesium metal components can be used alone or in combination of two or more.

  The shape of the magnesium metal component is not particularly limited as long as it does not impair the reactivity of the halosilane compound, but it is a powdered granule (powder, granule, etc.), ribbon, cut piece, lump, rod, flat plate, etc. In particular, a shape having a large surface area (powder, granule, ribbon, cut piece, etc.) is preferable. When the magnesium metal component is granular, the average particle size is, for example, 1 to 10,000 μm, preferably 10 to 5,000 μm, and more preferably about 20 to 1,000 μm.

  Depending on the storage status of the magnesium metal component, a film (such as an oxide film) may be formed on the metal surface. Since this coating may adversely affect the reaction, it may be removed by cutting or the like, if necessary.

  The usage-amount of a magnesium metal component is 1-10 equivalent normally in conversion of magnesium with respect to the halogen of a halosilane compound, Preferably it is 1-5 equivalent, More preferably, it is about 1-3 equivalent. Moreover, the usage-amount of a magnesium metal component is 1-10 times as a magnesium normally with respect to a halosilane compound as magnesium, More preferably, it is 1.2-5 times, Most preferably, it is 1.5-3 times Degree.

  The magnesium metal component reduces the halosilane compounds of the above formulas (1) to (3) to form a polysilane copolymer, and magnesium itself is oxidized to form a halide.

(b) Metal halide When a metal halide is used in combination with a magnesium metal component, the reactivity of the halosilane compound can be increased, and the solubility of the product in a solvent and the film formability can also be improved. Also, the physical properties (refractive index, molecular weight, etc.) of the product polysilane can be controlled. However, the catalyst system does not include a combination of a magnesium metal component, a lithium halide or lithium salt, and a metal halide other than lithium.

  Examples of such metal halides include lithium halides (such as lithium chloride LiCl, lithium bromide LiBr, and lithium iodide LiI), and halides of polyvalent metals. Examples of the multivalent metal halide include transition metals (for example, periodic table group 3A elements such as samarium; periodic table group 4A elements such as titanium; periodic table group 5A elements such as vanadium; iron, cobalt, palladium, etc. Periodic table group 8 element; periodic table 2B group element such as zinc), periodic table group 3B metal (such as aluminum), periodic table group 4B metal (such as tin) halides (chloride, bromide, iodide, etc.) Etc.

Specific examples of the metal halide include, for example, chloride [LiCl; SmCl ₂ , TiCl ₄ , VCl ₂ , iron chloride (FeCl ₂ , FeCl ₃ etc.), CoCl ₂ , PdCl ₂ , ZnCl ₂ , AlCl ₃ , SnCl _2. And the like], bromides (LiBr; iron bromides such as FeBr ₂ and FeBr ₃ ), iodides (SmI _{2 and the} like), and the like. Of these metal halides, chlorides (lithium chloride, iron chloride, zinc chloride, etc.) and bromides are preferred. A metal halide can be used individually or in combination of 2 or more types.

  The catalyst may be (i) a metal magnesium component alone or (ii) a combination of a metal magnesium component and a lithium halide or a halide of a polyvalent metal (that is, a magnesium metal component, a lithium halide, a polyvalent The combination with a metal halide is not included.

  The concentration of the metal halide in the solvent (or reaction solution) is, for example, about 0.001 to 3 mol / l, preferably about 0.005 to 1 mol / l, more preferably about 0.01 to 0.5 mol / l. . If the concentration of the metal halide in the reaction solution is too high, the solubility of the resulting polysilane tends to be high, but it is difficult to obtain a polysilane having a high refractive index (for example, a refractive index of 1.75 or more). There is a risk of becoming.

(Aprotic solvent)
As the reaction solvent, aprotic solvents can be widely used. For example, ethers (1,4-dioxane, tetrahydrofuran, tetrahydropyran, diethyl ether, diisopropyl ether, 1,2-dimethoxyethane, bis (2-methoxyethyl) Cyclic or linear C _4-6 ether such as ether), carbonates (such as propylene carbonate), nitriles (such as acetonitrile and benzonitrile), amides (such as dimethylformamide and dimethylacetamide), sulfoxides (such as dimethyl sulfoxide) , Halogen-containing compounds (halogenated hydrocarbons such as methylene chloride, chloroform, bromoform, chlorobenzene and bromobenzene), aromatic hydrocarbons (benzene, toluene, xylene, etc.), aliphatic hydrocarbons (eg For example, chain or cyclic hydrocarbons such as hexane, cyclohexane, octane, and cyclooctane). These aprotic solvents can be used alone or in combination of two or more as a mixed solvent. Of these solvents, polar solvents alone (tetrahydrofuran, 1,2-dimethoxyethane, etc.), a mixture of two or more polar solvents, a mixture of polar solvents and nonpolar solvents, and the like are preferable. When a mixture of a polar solvent and a nonpolar solvent is used, the ratio between the two may be the former / the latter (weight ratio) = 1 / 0.01 to 1/20.

  In addition, when the density | concentration of the halosilane compound in a solvent (or reaction liquid) is too low, there exists a possibility that superposition | polymerization may not be performed efficiently, and when too high, there exists a possibility that the metal halide used for reaction may not melt | dissolve. Therefore, the concentration of the halosilane compound in the solvent (or reaction solution) is usually 0.05 to 20 mol / l, preferably 0.2 to 15 mol / l, particularly about 0.3 to 13 mol / l. It is preferable to appropriately adjust the ratio.

  In the production method of the present invention, for example, an aryltrihalosilane compound (1), another halosilane compound (monohalosilane compound (2) and / or dihalosilane compound (3)), and the catalyst or catalyst system are sealed in a sealable reaction vessel. May be accommodated together with the reaction solvent, and the reaction may be carried out with mechanical or magnetic stirring as necessary. The starting halosilane compound may be used in advance as a mixture of an aryltrihalosilane compound and another halosilane compound, or each halosilane compound may be added to the reaction system separately. For example, an aryl trihalosilane compound and another halosilane compound may be added to the reaction system in parallel. After one halosilane compound is added and the reaction proceeds to some extent, the other halosilane compound is added. Also good. In addition, a method in which an aryltrihalosilane compound and another halosilane compound are mixed in advance is useful for obtaining a random copolymer, and a method of adding the other halosilane compound during the reaction of one halosilane compound is as follows. Useful for obtaining block copolymers.

  In the reaction, the halosilane compound as the substrate is preferably as highly pure as possible. For example, liquid halosilane compounds are preferably dried using a desiccant such as calcium hydride and distilled, and solid halosilane compounds are preferably purified and used by recrystallization. preferable.

  As long as the reaction vessel can be sealed, there is no particular limitation on the shape and structure. The reaction vessel may have a dry atmosphere, but a dry inert gas (for example, helium, nitrogen, argon gas) atmosphere, particularly a deoxygenated and dried argon gas atmosphere is preferable.

  The reaction time varies depending on the type and amount of the halosilane compound, the amount of the magnesium metal component, the presence or absence of a metal halide, etc., but is usually 5 minutes or longer, preferably about 30 minutes to 100 hours. The molecular weight of the polysilane may be controlled by adjusting the reaction time.

  The reaction temperature is usually in the temperature range from −20 ° C. to the boiling point of the solvent used, preferably 0 to 70 ° C., more preferably about 15 to 70 ° C. Further, the higher the reaction temperature is, the higher the refractive index polysilane can be obtained, but the solubility in the solvent may decrease.

  In addition, although the homopolymer which uses phenyltrichlorosilane as a raw material has a high refractive index of 1.75 or more depending on manufacturing conditions, its solubility with respect to most organic solvents is low. In addition, a homopolymer using methylphenyldichlorosilane, diphenyldichlorosilane, or the like as a raw material has a refractive index of 1.75 or less, is liable to crack during film formation, and has low mechanical strength.

  In contrast, in the present invention, polysilane is produced by combining an aryltrihalosilane compound, which is a raw material of a high refractive index polysilane, with another halosilane compound (monochlorohalosilane compound and / or dihalosilane compound). In addition to improving the refractive index (for example, to a refractive index of 1.75 or more), solubility in a solvent (such as an organic solvent), film formability, and compatibility with a resin (such as an organic polymer) can be improved. Therefore, the present invention provides a method for improving the solubility of polysilane in a solvent, compatibility (or affinity) with a resin, and / or refractive index by reacting the aryltrihalosilane compound with the other halosilane compound. Is also included.

  In the present invention, the polysilane can be produced in a high yield by a simple method using a general-purpose apparatus without using any special apparatus or complicated means. In addition, various physical properties such as the structure, refractive index, molecular weight, and solubility of polysilane can be controlled by appropriately adjusting the combination of halosilane compounds, reaction temperature, reaction time, ratio of catalyst or catalyst system, and the like.

  In addition, you may use the polysilane of this invention as a resin composition in combination with resin. In such a resin composition, the polysilane (copolysilane or polysilane mixture) is usually added as an additive. The kind of resin is not specifically limited, Any of a thermoplastic resin and a thermosetting resin may be sufficient.

  Examples of the thermoplastic resin include olefin resins [polyethylene, polypropylene, polymethylpentene, amorphous polyolefin, etc.], halogen-containing resins [polyvinyl chloride, fluororesins, etc.], styrene resins [polystyrene, acrylonitrile-styrene. Resin], acrylic resin [polymethyl methacrylate, etc.], polycarbonate resin [bisphenol A type polycarbonate resin, etc.], polyester resin [polyethylene terephthalate, polybutylene terephthalate, polycyclohexanedimethylene terephthalate, polyethylene naphthalate, polyarylate , Liquid crystal polyester, etc.], polyacetal resin, polyamide resin [nylon 6, nylon 66, nylon 46, nylon 6T, nylon MXD, etc.], poly Nylene ether resin [modified polyphenylene ether, etc.], polysulfone resin [polysulfone, polyethersulfone, etc.], polyimide resin [polyetherimide, polyamideimide, etc.], maleimide resin [polyamino bismaleimide, bismaleimide triazine resin, etc.] Examples thereof include thermoplastic elastomers.

  Thermosetting resins include phenolic resin, furan resin, amino resin [urea resin, melamine resin, etc.], unsaturated polyester resin, diallyl phthalate resin, epoxy resin, vinyl ester resin, polyurethane resin, silicone resin, polyimide resin, etc. It can be illustrated. The thermosetting resin may be an initial condensate.

  These resins can be used alone or in combination of two or more. When using a plurality of resins, a polymer alloy may be formed.

  The amount of polysilane added varies depending on the type of resin and polysilane, the application, and the like, but is generally 0.01 to 50 parts by weight (for example, 0.5 to 50 parts by weight), preferably 0. It may be about 1 to 30 parts by weight. If the addition amount is small, the resin cannot be imparted with characteristics such as flame retardancy and water repellency, and if it is too much, the resin characteristics may be impaired.

  In addition, the resin composition has various additives, for example, a solvent, a filler, a reinforcing agent, a plasticizer, a curing agent, a polymerization initiator, a catalyst, a stabilizer (an antioxidant, an ultraviolet absorber, etc.). ), Release agents, antistatic agents, colorants, vulcanizing agents, antifoaming agents, leveling agents, dispersing agents, flow control agents, and the like.

  The method of adding and mixing polysilane to the resin is not particularly limited, and usually, resin pellets, polysilane, and if necessary, additives are often melt-mixed. For example, after premixing resin pellets and components such as a stabilizer, polysilane may be melt-mixed in a kneading apparatus together with additives such as reinforcing agents and fillers as necessary. The melt-mixed resin composition is usually pelletized and subjected to molding. There are two types of kneaders: a batch type and a continuous type. Examples of the batch-type kneader include a mixing roll, a kneader, and an intensive mixer. Examples of the continuous kneader include a single screw extruder, a meshing twin screw extruder, and a non-meshing twin screw extruder.

  In a thermosetting resin, generally, a curable composition is prepared by mixing polysilane and a resin initial condensate together with various resin additives such as a curing agent. The polysilane and the resin initial condensate are mixed or mixed in a dissolution tank, and if necessary, kneaded with an additive such as a reinforcing agent to prepare a curable composition, and this curable composition is used as a base material. It may be impregnated or coated, dried and cured.

  The molding method of the resin composition varies depending on the type and use of the resin, but in the case of a thermoplastic resin, extrusion molding, injection molding, blow molding, stretched film molding, compression molding, calendar molding, RIM molding (reaction injection molding) ) And the like. In the case of a thermosetting resin, methods such as compression molding, transfer molding, laminate molding, cast molding, and RIM molding can be exemplified.

  The present invention can improve solvent solubility and affinity for resins while maintaining the characteristics of arylpolysilane. Therefore, the characteristics of the aryl polysilane, such as characteristics such as flame retardancy, water repellency, releasability, and slipperiness, can be effectively imparted to the resin and the substrate. Therefore, various uses, for example, ceramic precursors, optoelectronic materials (for example, photoelectrophotographic materials such as photoresists and organic photoreceptors, optical transmission materials such as optical waveguides, optical recording materials such as optical memories, electroluminescent element materials, etc. ), Flame retardants, water repellents, release agents and the like.

  Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited to these examples.

Example 1
A round flask with an internal volume of 1000 ml equipped with a three-way cock was charged with 25 g of granular (particle size 20 to 1000 μm) magnesium and heated at 50 ° C. under reduced pressure of 1 mmHg (= 133 kPa) to dry the inside of the reactor. . Next, dry argon gas was introduced into the reactor, 500 ml of tetrahydrofuran (THF) previously dried with sodium-benzophenone ketyl was added, and the mixture was stirred at 50 ° C. for about 30 minutes. To this reaction mixture, 105.8 g (0.5 mol) of phenyltrichlorosilane (PhSiCl ₃ ) purified in advance by distillation and 10.9 g (0.1 mol) of trimethylchlorosilane (Me ₃ SiCl) were added using a syringe. Stir at about 24 hours. After completion of the reaction, 250 ml of 1N (= 1 mol / L) hydrochloric acid was added to the reaction mixture, followed by extraction with 500 ml of toluene. The toluene phase was washed 5 times with 200 ml of pure water, the toluene phase was dried over anhydrous magnesium sulfate, and then toluene was distilled off to obtain a phenyltrichlorosilane-trimethylchlorosilane copolymer (weight average molecular weight 1900, yield). Rate 95%).

Example 2
The reaction was conducted in the same manner as in Example 1 except that the amount of trimethylchlorosilane was changed to 21.7 g (0.2 mol) to obtain a phenyltrichlorosilane-trimethylchlorosilane copolymer (weight average molecular weight 1600, yield 95%). ).

Reference example 1
The reaction was carried out in the same manner as in Example 1 except that 19.1 g (0.1 mol) of methylphenyldichlorosilane (MePhSiCl ₂ ) was used instead of 10.9 g (0.1 mol) of trimethylchlorosilane, and phenyltrichlorosilane- A methylphenyldichlorosilane copolymer was obtained (weight average molecular weight 1700, yield 94%).

Reference example 2
Instead of 10.9 g (0.1 mol) of trimethylchlorosilane, the reaction was carried out in the same manner as in Example 1 except that 25.3 g (0.1 mol) of diphenyldichlorosilane (Ph ₂ SiCl ₂ ) was used. A diphenyldichlorosilane copolymer was obtained (weight average molecular weight 1500, yield 90%).

Comparative Example 1
A reaction was carried out in the same manner as in Example 1 except that phenyltrichlorosilane was used alone without using trimethylchlorosilane to obtain polyphenylsilin (weight average molecular weight 2500, yield 89%).

Comparative Example 2
In accordance with the method described in the pamphlet of WO 98/29476, polymethylphenylsilane was obtained using methylphenyldichlorosilane as a raw material.

Comparative Example 3
In accordance with the method described in the pamphlet of WO98 / 29476, polydiphenylsilane was obtained using diphenyldichlorosilane as a raw material.

[Evaluation of characteristics]
(1) Solution permeability The polysilane obtained in Examples and Comparative Examples is mixed with toluene or propylene glycol-1-monoethyl ether-2-acetate (PGMEA), and mixed with 50 wt% toluene or 10 wt% PGMEA. A mixed solution was prepared, and the transmittance of visible light (600 nm) was measured.

(2) Thin film refractive index The polysilane obtained by the Example and the comparative example was mixed with PGMEA, and the 10 weight% PGMEA liquid mixture was prepared. Using this mixed solution, a coating film was formed on the substrate so as to have a thickness after drying of 1 μm by spin coating, and the refractive index of the obtained thin film with respect to light having a wavelength of 589.4 nm was measured.

As is apparent from Table 1, when Me ₃ SiCl, MePhSiCl ₂ and Ph ₂ SiCl ₂ are copolymerized using PhSiCl ₃ as the main raw material, a polysilane having a refractive index of 1.75 or more and having solubility in a solvent is obtained. It was.

Claims (2)

( i) a catalyst composed of a metal magnesium component alone, or (ii) phenyltrihalosilane in an aprotic solvent in the presence of a catalyst system in which the metal magnesium component is combined with a lithium halide or a halide of a polyvalent metal. and a trimethyl monohaloalkyl silane, the former / the latter = 65 / 35-5 / 1 molar weight can be obtained by reacting with a ratio of average molecular weight 500 to 5,000 polysilanes. In the presence of a catalyst system composed of (i) a magnesium metal component alone or (ii) a combination of a metal magnesium component and a lithium halide or a halide of a polyvalent metal in an aprotic solvent, phenyltrihalo A method of producing polysilane having a weight average molecular weight of 500 to 5000 by reacting silane and trimethylmonohalosilane using the former / the latter = 65/35 to 5/1 in a molar ratio .