JP4993568B2 - Water treatment method and apparatus for stopping / starting a power plant - Google Patents

Water treatment method and apparatus for stopping / starting a power plant Download PDF

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JP4993568B2
JP4993568B2 JP2006256704A JP2006256704A JP4993568B2 JP 4993568 B2 JP4993568 B2 JP 4993568B2 JP 2006256704 A JP2006256704 A JP 2006256704A JP 2006256704 A JP2006256704 A JP 2006256704A JP 4993568 B2 JP4993568 B2 JP 4993568B2
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賢一 高原
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Chugoku Electric Power Co Inc
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Description

本発明は、発電プラントの停止・起動時の水処理方法及びその装置に関する。   The present invention relates to a water treatment method and apparatus for stopping and starting a power plant.

発電プラントは、ボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水質を維持するために、アンモニアやヒドラジン等の薬品を給水に注入して水質を維持する水処理手段を備えている。この水処理手段は、給水の電気伝導率、溶存酸素濃度、pH、ヒドラジン濃度、鉄イオン濃度等の測定指標を監視しながら水処理を行っている。また、給水の酸化還元電位とボイラ水管構成材料の腐食電位とを検出して、給水の水質を一元的且つ直接に表して監視する水質監視方法も知られている(例えば、特許文献1参照)。   The power plant supplies water to the boiler, and maintains water quality by injecting chemicals such as ammonia and hydrazine into the feed water to maintain the quality of the feed water that is circulated and used in the boiler, steam-driven turbine and condenser. Means. This water treatment means performs water treatment while monitoring measurement indexes such as the electric conductivity, dissolved oxygen concentration, pH, hydrazine concentration, and iron ion concentration of the feed water. There is also known a water quality monitoring method for detecting the oxidation-reduction potential of the feed water and the corrosion potential of the boiler water pipe constituent material and monitoring the feed water quality in a unified and direct manner (see, for example, Patent Document 1). .

特開2003−254503号公報JP 2003-254503 A

点検や運転調整により発電プラントを停止させるときには、系統内に給水が長時間滞って水質が悪化しやすいために、停止工程においてアンモニアやヒドラジン等の薬品を給水に注入して停止期間中の水質を維持している。しかし、従来の水処理方法においては、停止時の薬品注入量の監視ができないために、給水への薬品の注入量が少ないと停止期間中の給水の水質を維持することができない。一方、給水への薬品の注入量が多いと、発電プラント起動時に薬品の濃度が高いために給水のブロー時間が長くなるという問題があった。   When shutting down a power plant by inspection or operation adjustment, the water quality is likely to deteriorate because the water supply is stagnant for a long time in the system. Is maintained. However, in the conventional water treatment method, since the amount of chemical injection at the time of stoppage cannot be monitored, the quality of the water supply during the stop period cannot be maintained if the amount of chemical injection into the water supply is small. On the other hand, if the amount of chemicals injected into the water supply is large, the concentration of the chemicals is high when the power plant is started up, resulting in a problem that the blow time of the water supply becomes long.

また、従来の水処理方法は、発電プラント起動時に系統内の給水をサンプリングし、水質を実測しながら水処理を行っていたために、起動時の水処理の各工程に時間を要するという課題があった。
そこで、本発明は、発電プラントの停止時及び起動時の水処理において、起動時の水処理工程を短縮することができる発電プラントの停止・起動時の水処理方法及びその装置を提供するものである。
Also, the conventional water treatment method has a problem that it takes time for each process of the water treatment at the start-up because the water supply in the system is sampled at the start-up of the power plant and the water treatment is performed while actually measuring the water quality. It was.
Therefore, the present invention provides a water treatment method and apparatus for stopping and starting a power plant that can shorten the water treatment process at the time of starting and stopping the water treatment at the time of stopping and starting the power plant. is there.

本発明は、上記課題を解決するために、発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水処理方法において、発電プラント停止時に停止期間を予測し、この予測した停止期間に対応して予め定めた薬品量を前記給水に注入するようにした発電プラントの停止・起動時の水処理方法を提供するものである。   In order to solve the above problems, the present invention predicts a stop period when a power plant is stopped in a method for treating water supplied to a boiler of a power plant and circulated and used in a boiler, a steam-driven turbine, and a condenser. The present invention provides a water treatment method at the time of stopping / starting a power plant that injects a predetermined amount of chemicals corresponding to the predicted stop period into the feed water.

また、本発明は、発電プラントの停止期間に対応して発電プラント起動時の水処理手順を予め定めてあり、発電プラント起動時に該水処理手順に基づいて前記給水の水処理を行うようにした請求項1に記載の発電プラントの停止・起動時の水処理方法を提供するものである。   Further, according to the present invention, a water treatment procedure at the time of starting the power plant is determined in advance corresponding to a stop period of the power plant, and the water treatment of the feed water is performed based on the water treatment procedure at the time of starting the power plant. The water treatment method at the time of stop and start of the power plant according to claim 1 is provided.

また、本発明は、発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水処理装置において、発電プラント停止時に前記給水に注入する薬品量を発電プラントの停止期間に対応して記憶した記憶手段と、発電プラントの予測停止期間を入力する停止期間入力手段と、発電プラント停止時に入力された停止期間に対応した薬品量を前記給水に注入する薬品注入手段とからなる発電プラントの停止・起動時の水処理装置を提供するものである。   Further, the present invention provides a water treatment apparatus for feed water that is fed to a boiler of a power plant and is circulated and used in a boiler, a steam driven turbine, and a condenser. Storage means stored corresponding to the stop period, stop period input means for inputting the predicted stop period of the power plant, and chemical injection means for injecting a chemical amount corresponding to the stop period input when the power plant is stopped into the feed water The water treatment apparatus at the time of the stop and starting of the power plant which consists of is provided.

また、本発明は、前記記憶手段が発電プラントの停止期間に対応した発電プラント起動時の水処理手順を記憶してあり、発電プラント起動時に該水処理手順に基づいて前記給水の水処理を行う水処理手段を備えた請求項3に記載の発電プラントの停止・起動時の水処理装置を提供するものである。   Further, according to the present invention, the storage means stores a water treatment procedure at the time of starting the power plant corresponding to the stop period of the power plant, and performs the water treatment of the feed water based on the water treatment procedure at the time of starting the power plant. The water treatment apparatus at the time of the stop and starting of the power plant according to claim 3 provided with water treatment means is provided.

本発明に係る発電プラントの停止・起動時の水処理方法によれば、発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水処理方法において、発電プラント停止時に停止期間を予測し、この予測した停止期間に対応して予め定めた薬品量を前記給水に注入するようにした構成を有することにより、発電プラント停止時に停止期間に対応した適切な薬品量を給水に注入することができ、停止期間中の給水の水質を確実に維持することができると共に、発電プラント起動時のブロー時間を短縮して起動時間を短縮することができる効果がある。   According to the water treatment method at the time of stopping and starting a power plant according to the present invention, in the water treatment method for feed water supplied to the boiler of the power plant and circulated and used in the boiler, the steam driven turbine and the condenser, the power plant An appropriate amount of chemicals corresponding to the stop period when the power plant is stopped by having a configuration in which a stop period is predicted at the time of stoppage and a predetermined amount of chemical is injected into the water supply corresponding to the predicted stop period. Can be injected into the feed water, and the quality of the feed water during the stop period can be reliably maintained, and the blow time at the start of the power plant can be shortened to shorten the start-up time.

また、本発明は、発電プラントの停止期間に対応して発電プラント起動時の水処理手順を予め定めてあり、発電プラント起動時に該水処理手順に基づいて前記給水の水処理を行うようにした請求項1に記載の構成を有することにより、発電プラント起動時に給水系統内の水をサンプリングして水質を測定することなく、停止期間に対応した水処理手順によって給水の水質を維持して発電プラントを起動することができ、更に起動時間を短縮することができる効果がある。   Further, according to the present invention, a water treatment procedure at the time of starting the power plant is determined in advance corresponding to a stop period of the power plant, and the water treatment of the feed water is performed based on the water treatment procedure when the power plant is started. By having the configuration according to claim 1, the power plant can maintain the quality of the feed water by the water treatment procedure corresponding to the stop period without sampling the water in the feed water system and measuring the water quality when starting the power plant. Can be activated and the activation time can be further shortened.

また、本発明に係る発電プラントの停止・起動時の水処理装置によれば、発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水処理装置において、発電プラント停止時に前記給水に注入する薬品量を発電プラントの停止期間に対応して記憶した記憶手段と、発電プラントの予測停止期間を入力する停止期間入力手段と、発電プラント停止時に入力された停止期間に対応した薬品量を前記給水に注入する薬品注入手段とからなる構成を有することにより、発電プラント停止時に停止期間に対応した適切な薬品量を給水に注入することができ、停止期間中の給水の水質を確実に維持することができると共に、発電プラント起動時のブロー時間を短縮して起動時間を短縮することができる効果がある。   Further, according to the water treatment device at the time of stopping and starting the power plant according to the present invention, in the water treatment device for feed water supplied to the boiler of the power plant and circulated and used in the boiler, the steam driven turbine and the condenser, Storage means for storing the amount of chemical injected into the water supply when the power plant is stopped corresponding to the power plant stop period, stop period input means for inputting the predicted power plant stop period, and the stop input when the power plant is stopped By comprising a chemical injection means for injecting a chemical amount corresponding to the period into the feed water, an appropriate chemical amount corresponding to the stop period can be injected into the feed water when the power plant is stopped. The water quality of the feed water can be reliably maintained, and the blow time at the start-up of the power plant can be shortened to shorten the start-up time.

また、本発明は、前記記憶手段が発電プラントの停止期間に対応した発電プラント起動時の水処理手順を記憶してあり、発電プラント起動時に該水処理手順に基づいて前記給水の水処理を行う水処理手段を備えた請求項3に記載の構成を有することにより、発電プラント起動時に給水系統内の水をサンプリングして水質を測定することなく、停止期間に対応した水処理手順によって給水の水質を維持して発電プラントを起動することができ、更に起動時間を短縮することができる効果がある。   Further, according to the present invention, the storage means stores a water treatment procedure at the time of starting the power plant corresponding to the stop period of the power plant, and performs the water treatment of the feed water based on the water treatment procedure at the time of starting the power plant. By having the structure of Claim 3 provided with the water treatment means, the water quality of the feed water by the water treatment procedure corresponding to the stop period without sampling the water in the feed water system at the time of starting the power plant and measuring the water quality It is possible to start the power plant while maintaining the above, and to further shorten the startup time.

本発明の実施の形態を図示する実施例に基づいて説明する。
本発明に係る発電プラントの停止・起動時の水処理装置は、発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水を水処理することができるようにしてあり、発電プラント停止時に前記給水に注入する薬品量を発電プラントの停止期間に対応して記憶した記憶手段1と、発電プラントの予測停止期間を入力する停止期間入力手段2と、発電プラント停止時に入力された停止期間に対応した薬品量を前記給水に注入する薬品注入手段3とから構成してある。
Embodiments of the present invention will be described based on examples shown in the drawings.
The water treatment device at the time of stopping / starting a power plant according to the present invention is configured so that water supplied to a boiler of a power plant can be treated with water used for circulation in a boiler, a steam driven turbine, and a condenser. Yes, storage means 1 that stores the amount of chemical injected into the water supply when the power plant is stopped corresponding to the power plant stop period, stop period input means 2 that inputs a predicted power plant stop period, and when the power plant stops It is comprised from the chemical | medical agent injection | pouring means 3 which inject | pours the chemical | medical agent quantity corresponding to the input stop period into the said water supply.

図2は、給水の水処理系統図を示している。給水は、蒸気を冷却水で冷やして水に戻す復水系統10と、この復水を昇圧してボイラへ給水する給水系統11と、ボイラで発生した蒸気をタービンに供給する蒸気系統12を循環して使用されている。
図2において、13は試料採取点であり、給水を採取してpH値、電気伝導率、ヒドラジン濃度及び鉄イオン濃度等の水質を計測することができるようにしてある。また、14は薬品注入点であり、ヒドラジン等の薬品をボイラ水に注入してボイラ水の水質を維持することができるように構成してある。
FIG. 2 shows a water treatment system diagram of the water supply. The feed water is circulated through a condensate system 10 that cools the steam with cooling water and returns it to the water, a feed water system 11 that boosts the condensate and feeds it to the boiler, and a steam system 12 that feeds steam generated in the boiler to the turbine. Have been used.
In FIG. 2, reference numeral 13 denotes a sampling point, which can collect water supply and measure water quality such as pH value, electrical conductivity, hydrazine concentration, and iron ion concentration. Reference numeral 14 denotes a chemical injection point, which is configured so as to maintain the quality of the boiler water by injecting chemicals such as hydrazine into the boiler water.

図1に示す実施例において、記憶手段1は、中央制御装置5又は中央制御装置5に接続された端末のハードディスク等の記憶装置からなる。記憶手段1は、発電プラント停止時に給水に注入する薬品量を発電プラントの停止期間に対応して記憶する薬品量記憶手段と、発電プラントの停止期間に対応した発電プラント起動時の水処理手順を記憶する水処理手順記憶手段を備えている。   In the embodiment shown in FIG. 1, the storage means 1 comprises a central control device 5 or a storage device such as a hard disk of a terminal connected to the central control device 5. The storage means 1 stores the chemical amount storage means for storing the chemical amount injected into the feed water when the power plant is stopped corresponding to the power plant stop period, and the water treatment procedure at the time of starting the power plant corresponding to the power plant stop period. Water treatment procedure storage means for storing is provided.

薬品量記憶手段は、図2に示すように、DSS(毎日起動停止)、ホットバンキング状態のWSS(週末起動停止)、強制冷却状態のWSS、LSS(長期起動停止)に発電プラントの停止期間を分類してある。薬品量記憶手段は、この停止期間の分類に対応して給水に注入するヒドラジンやアンモニア等の薬品量を記憶してある。また、WSSでは、停止期間が短い間(ホットバンキング状態)はボイラ内の圧力が大気圧より高く、ボイラ内は外気に対してシールされているが、停止期間が長くなるとボイラ内の圧力が低下して酸素が入りやすくなるために、ホットバンキング状態と強制冷却状態に分類を分けて薬品量を管理している。   As shown in FIG. 2, the chemical amount storage means sets the power plant stop period to DSS (daily start / stop), hot banking WSS (weekend start / stop), forced cooling WSS, LSS (long-term start / stop). Classified. The chemical amount storage means stores a chemical amount such as hydrazine or ammonia to be injected into the water supply in accordance with the classification of the stop period. In WSS, while the stop period is short (hot banking state), the pressure in the boiler is higher than the atmospheric pressure, and the boiler is sealed against the outside air, but when the stop period is long, the pressure in the boiler decreases. In order to facilitate the entry of oxygen, the chemical amount is managed by dividing the classification into a hot banking state and a forced cooling state.

水処理手順記憶手段は、図4〜6に示すように、発電プラントの停止期間に対応した発電プラント起動時の水処理手順を記憶してある。図4はDSSから起動時の水処理手順を示し、図5はWSS(ホットバンキング)から起動時の水処理手順を示し、図6はWSS(強制冷却)から起動時の水処理手順を示している。水処理手順記憶手段は、停止期間に対応して、発電プラント起動時の給水へのヒドラジンやアンモニア等の薬品の注入量を記憶してあると共に、給水のブロー時間を記憶してある。   As shown in FIGS. 4 to 6, the water treatment procedure storage means stores a water treatment procedure at the time of starting the power plant corresponding to the stop period of the power plant. 4 shows the water treatment procedure at the time of startup from DSS, FIG. 5 shows the water treatment procedure at the time of startup from WSS (hot banking), and FIG. 6 shows the water treatment procedure at the time of startup from WSS (forced cooling). Yes. The water treatment procedure storage means stores the injection amount of chemicals such as hydrazine and ammonia into the water supply when the power plant is activated, and stores the water supply blow time corresponding to the stop period.

図1に示す実施例において、停止期間入力手段2は、中央制御装置5に接続されたパーソナルコンピュータ等の端末からなり、発電プラントの予測停止期間を入力することができるように構成してある。停止期間入力手段2から入力された予測停止期間は、中央制御装置5へ送られるようにしてある。   In the embodiment shown in FIG. 1, the stop period input means 2 is composed of a terminal such as a personal computer connected to the central controller 5 and is configured to be able to input the predicted stop period of the power plant. The predicted stop period input from the stop period input means 2 is sent to the central controller 5.

薬品注入手段3は、停止期間入力手段2から入力された予測停止期間に対応した薬品量を記憶手段1から呼び出し、該薬品量に基づいてヒドラジンやアンモニア等の薬品を給水に注入することができるように構成してある。実施例において、給水に注入する薬品の量は、薬品の濃度、注入ポンプのストローク、注入時間などで調節することができるようにしてある。   The chemical injection means 3 can call the chemical amount corresponding to the predicted stop period input from the stop period input means 2 from the storage means 1 and inject chemicals such as hydrazine and ammonia into the water supply based on the chemical amount. It is constituted as follows. In the embodiment, the amount of the chemical injected into the water supply can be adjusted by the concentration of the chemical, the stroke of the injection pump, the injection time, and the like.

水処理手段4は、発電プラント起動時に、停止期間に対応した水処理手順を記憶手段1から呼び出し、該水処理手順に基づいて給水の水処理を行うことができるように構成してある。水処理手段4は、停止期間に対応した水処理手順を定めてあることにより、図4〜6に示すように、各薬品注入工程及びブロー工程において水質の測定が不要になり、点火前の給水の電気伝導率の確認のみで水処理を行うことができるようにしてある。また、水処理手段4は、電気伝導率の確認後に、薬品注入を自動に切り替えて通常運転時の水処理工程に移行することができるようにしてある。   The water treatment means 4 is configured to call a water treatment procedure corresponding to the stop period from the storage means 1 when the power plant is started, and to perform water treatment of the feed water based on the water treatment procedure. Since the water treatment means 4 determines the water treatment procedure corresponding to the stop period, as shown in FIGS. 4 to 6, it is not necessary to measure the water quality in each chemical injection step and the blow step, and the water supply before ignition The water treatment can be performed only by confirming the electrical conductivity. Moreover, the water treatment means 4 can switch to chemical | medical agent injection | pouring automatically after confirmation of electrical conductivity, and can transfer to the water treatment process at the time of normal operation.

なお、記憶手段1は、発電プラントの設備更新等による薬品注入量の変化などに対応できるように、記憶手段1に記憶された薬品量及び水処理手順を変更することができる変更手段を備えていることが好ましい。   The storage unit 1 includes a changing unit that can change the chemical amount and the water treatment procedure stored in the storage unit 1 so as to cope with a change in the chemical injection amount due to the equipment update of the power plant. Preferably it is.

本発明に係る発電プラントの停止・起動時の水処理装置の一実施例を示す構成図。The block diagram which shows one Example of the water treatment apparatus at the time of the stop of the power plant which concerns on this invention, and starting. その一実施例の給水の水処理系統図。The water treatment system figure of the water supply of the one Example. その一実施例の停止期間と水処理の関係を説明する図。The figure explaining the relationship between the stop period of the one Example, and water treatment. その一実施例の起動時水処理の一例を示すチャート図。The chart figure which shows an example of the water treatment at the time of the one Example. その一実施例の起動時水処理の他の一例を示すチャート図。The chart figure which shows another example of the water treatment at the time of the one Example. その一実施例の起動時水処理の他の一例を示すチャート図。The chart figure which shows another example of the water treatment at the time of the one Example.

符号の説明Explanation of symbols

1 記憶手段
2 停止期間入力手段
3 薬品注入手段
4 水処理手段
5 中央制御装置
10 復水系統
11 給水系統
12 蒸気系統
13 試料採取点
14 薬品注入点
DESCRIPTION OF SYMBOLS 1 Memory | storage means 2 Stop period input means 3 Chemical injection means 4 Water treatment means 5 Central controller 10 Condensate system 11 Water supply system 12 Steam system 13 Sampling point 14 Chemical injection point

Claims (2)

発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水処理方法において、
発電プラント停止時に前記給水に注入する薬品量を発電プラントの停止期間に対応して記憶する薬品量記憶手段と、発電プラントの停止期間に対応した発電プラント起動時の水処理手順を記憶する水処理手順記憶手段と、を備え、
発電プラント停止時に停止期間を予測する予測工程と
この予測した停止期間に対応して前記薬品量記憶手段に記憶された薬品量を前記給水に注入する薬品注入工程と、
発電プラント起動時に前記水処理手順記憶手段に記憶された水処理手順に基づいて前記給水の水処理を行う水処理工程と、を有し、
前記水処理工程は、前記給水の電気伝導率を確認した後に通常運転時の水処理に移行するようにした発電プラントの停止・起動時の水処理方法。
In a water treatment method for feed water that is supplied to a boiler of a power plant and circulated and used in a boiler, a steam-driven turbine, and a condenser,
A chemical amount storage means for storing a chemical amount to be injected into the water supply when the power plant is stopped corresponding to a power plant stop period, and a water process for storing a water treatment procedure at the time of power plant startup corresponding to the power plant stop period A procedure storage means,
A prediction process for predicting the outage period when the power plant is shut down;
A chemical injection step of injecting the chemical amount stored in the chemical amount storage means into the water supply corresponding to the predicted stop period ;
A water treatment step of performing water treatment of the feed water based on a water treatment procedure stored in the water treatment procedure storage means at the time of power plant startup,
The said water treatment process is the water treatment method at the time of the stop and starting of a power plant which made it transfer to the water treatment at the time of normal operation, after confirming the electrical conductivity of the said water supply .
発電プラントのボイラに給水され、ボイラ、蒸気駆動タービン及び復水器で循環使用される給水の水処理装置において、
発電プラント停止時に前記給水に注入する薬品量を発電プラントの停止期間に対応して記憶した薬品量記憶部、及び、発電プラントの停止期間に対応した発電プラント起動時の水処理手順を記憶した水処理手順記憶部を備えた記憶手段と、
発電プラントの予測停止期間を入力する停止期間入力手段と、
発電プラント停止時に入力された停止期間に対応した薬品量を前記給水に注入する薬品注入手段と
発電プラント起動時に前記記憶手段に記憶された水処理手順に基づいて前記給水の水処理を行う水処理手段と、を有し、
前記水処理手段は、前記給水の電気伝導率を確認した後に通常運転時の水処理に移行するようにした発電プラントの停止・起動時の水処理装置。
In a water treatment system for water supplied to a boiler of a power plant and circulated and used in a boiler, a steam driven turbine and a condenser,
A chemical amount storage unit storing a chemical amount to be injected into the water supply when the power plant is stopped corresponding to a power plant stop period, and water storing a water treatment procedure at the time of power plant start corresponding to the power plant stop period Storage means including a processing procedure storage unit ;
A stop period input means for inputting a predicted stop period of the power plant;
A chemical injection means for injecting into the feed water a chemical amount corresponding to the stop period input when the power plant is stopped ;
Water treatment means for performing water treatment of the feed water based on a water treatment procedure stored in the storage means at the time of power plant startup,
The said water treatment means is a water treatment apparatus at the time of the stop and start-up of a power plant which made it transfer to the water treatment at the time of normal operation, after confirming the electrical conductivity of the said water supply .
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