JP4932230B2 - Dust removal filter for vacuum cleaner - Google Patents
Dust removal filter for vacuum cleaner Download PDFInfo
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- JP4932230B2 JP4932230B2 JP2005335588A JP2005335588A JP4932230B2 JP 4932230 B2 JP4932230 B2 JP 4932230B2 JP 2005335588 A JP2005335588 A JP 2005335588A JP 2005335588 A JP2005335588 A JP 2005335588A JP 4932230 B2 JP4932230 B2 JP 4932230B2
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- dust
- filter
- fine particles
- inorganic fine
- mesh
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- 239000000428 dust Substances 0.000 title claims description 178
- 239000010419 fine particle Substances 0.000 claims description 59
- 239000000835 fiber Substances 0.000 claims description 56
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 46
- 239000000178 monomer Substances 0.000 claims description 46
- 229920005989 resin Polymers 0.000 claims description 46
- 239000011347 resin Substances 0.000 claims description 46
- 229910000077 silane Inorganic materials 0.000 claims description 46
- 239000010409 thin film Substances 0.000 claims description 22
- 238000010559 graft polymerization reaction Methods 0.000 claims description 15
- 239000000126 substance Substances 0.000 claims description 10
- 230000003746 surface roughness Effects 0.000 claims description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 22
- 229920000742 Cotton Polymers 0.000 description 16
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- 239000004576 sand Substances 0.000 description 12
- 239000004408 titanium dioxide Substances 0.000 description 10
- 239000002689 soil Substances 0.000 description 8
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- 239000008096 xylene Substances 0.000 description 2
- LTQBNYCMVZQRSD-UHFFFAOYSA-N (4-ethenylphenyl)-trimethoxysilane Chemical compound CO[Si](OC)(OC)C1=CC=C(C=C)C=C1 LTQBNYCMVZQRSD-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
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- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 229920002972 Acrylic fiber Polymers 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
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- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
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- BLJNPOIVYYWHMA-UHFFFAOYSA-N alumane;cobalt Chemical compound [AlH3].[Co] BLJNPOIVYYWHMA-UHFFFAOYSA-N 0.000 description 1
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- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 1
- VKJLWXGJGDEGSO-UHFFFAOYSA-N barium(2+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[Ti+4].[Ba+2] VKJLWXGJGDEGSO-UHFFFAOYSA-N 0.000 description 1
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- 238000004140 cleaning Methods 0.000 description 1
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- OTARVPUIYXHRRB-UHFFFAOYSA-N diethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](C)(OCC)CCCOCC1CO1 OTARVPUIYXHRRB-UHFFFAOYSA-N 0.000 description 1
- YYLGKUPAFFKGRQ-UHFFFAOYSA-N dimethyldiethoxysilane Chemical compound CCO[Si](C)(C)OCC YYLGKUPAFFKGRQ-UHFFFAOYSA-N 0.000 description 1
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- 125000003700 epoxy group Chemical group 0.000 description 1
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- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
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- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
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- 235000014413 iron hydroxide Nutrition 0.000 description 1
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Description
本発明は、塵や埃が付着し難くて、且つ、付着した塵や埃が簡単に除去できる塵離れ性に優れた掃除機用除塵フィルターに関する。 The present invention relates to a dust removal filter for a vacuum cleaner that is difficult for dust and dust to adhere to and that is excellent in dust separation and can easily remove the dust and dust that has adhered.
電気掃除機には塵や埃を集塵袋、一般には紙パックと呼ばれる袋に集塵して除去する方式と、集塵部にダストボックス内で塵や埃と空気を遠心分離によって分離するサイクロン集塵部を設けたサイクロン方式が提案されている。特にサイクロン方式は紙パックが不要でその交換の手間も掛からないこと、また、集塵した集塵部に集めた塵や埃を、集塵部を開閉してゴミ箱に捨てることができることなど、紙パック方式に比べて便利性に優れていることから、近年、多くの製品が開発され商品化されている。 A vacuum cleaner collects and removes dust and dust in a dust collection bag, generally called a paper pack, and a cyclone collection that separates dust, dust, and air by centrifugal separation in the dust box at the dust collection section. A cyclone system with a dust part has been proposed. In particular, the cyclone method does not require a paper pack and takes time to replace it, and the dust and dust collected in the collected dust collection unit can be thrown into the trash bin by opening and closing the dust collection unit. In recent years, many products have been developed and commercialized because they are more convenient than the pack method.
サイクロン方式の掃除機(以下、サイクロン掃除機と呼ぶ)は、強力な旋回気流を形成し、旋回により形成される遠心力を利用して塵や埃を空気と分離して収集する機構であるが、分離した塵や埃は、メッシュ状フィルターとヘパフィルターなどの除塵フィルターを通して最終的に空気と分離されて集塵部内に集められる機構が一般的に採用されている(例えば、特許文献1、特許文献2参照)。また、排気する空気には分離しきれない塵や綿埃などが残存するので、除塵フィルターを通し残存する塵や綿埃を分離しているが、これらの塵が除塵フィルター上に堆積して吸引力の低下を招くことから、堆積した塵が簡単に除去できることを目的に塵離れ性の改善も行われている(例えば、特許文献3)。
掃除機で集塵される塵や埃は、砂や土埃などの微粒子からなる比較的に質量の大きいものと、糸くずや綿埃などの質量の小さいものに分けられる。質量の大きい塵は比較的容易に空気と分離可能であるが、質量の小さい糸くずや綿埃などは分離しきれないで除塵フィルター上に堆積する。よって、特許文献1や2では、除塵フィルター上に質量の小さい糸くずや綿埃が堆積して吸引力の低下を招き、それによりサイクロンとしての機能が低下するなどの問題が発生する。また、特許文献3に記載されているように、堆積した塵や埃を簡単に取り除ことを目的に、除塵フィルターの表面に摩擦帯電を防止するために金属をスパッタリングで形成することも提案されているが、特に高メッシュのメッシュフィルターでは糸くずが絡まってしまい、ブラシなどでも除去ができない場合がある。さらに、関東ロームのような粘土質の土塵では、メッシュフィルターの表面に堆積し固着して帯電防止効果が低下し、他の塵や埃が付着しやすくなると共に、ヘパフィルターの目詰まりの原因ともなり、吸引力の低下を招くなどの問題があった。 Dust and dust collected by the vacuum cleaner are classified into those having a relatively large mass made of fine particles such as sand and dirt and those having a small mass such as lint and cotton dust. Dust with a large mass can be separated from the air relatively easily, but lint and cotton dust with a small mass cannot be completely separated and accumulate on the dust removal filter. Therefore, in Patent Documents 1 and 2, there is a problem that lint or cotton dust having a small mass accumulates on the dust removal filter and causes a reduction in suction force, thereby reducing the function as a cyclone. Further, as described in Patent Document 3, for the purpose of easily removing accumulated dust and dust, it has been proposed to form a metal on the surface of the dust removal filter by sputtering in order to prevent frictional charging. However, particularly with a high mesh mesh filter, lint is entangled and may not be removed with a brush. In addition, clay-like dust such as Kanto Loam accumulates on the surface of the mesh filter and adheres to it, reducing the antistatic effect, making it easier for other dust and dirt to adhere, and causing clogging of the hepa filter At the same time, there were problems such as a reduction in suction power.
本発明は、上述した従来の問題を解決し、糸くずや綿埃などが絡まり難く、また、土埃や砂埃などの微粒子からなる塵も付着し難く、且つ、フィルター上に堆積した塵が簡単に除去できる塵離れ性に優れた掃除機用の除塵フィルターを提供することを目的とする。 The present invention solves the above-mentioned conventional problems, makes it difficult for lint and cotton dust to get entangled, and also makes it difficult for dust made of fine particles such as dirt and sand to adhere to it, and the dust accumulated on the filter can be easily obtained. An object of the present invention is to provide a dust removal filter for a vacuum cleaner that is excellent in dust removal and can be removed.
本発明者らは、鋭意研究を重ねた結果、除塵フィルターの表面にシランモノマーで被覆された無機微粒子の薄膜を形成することで、土や砂などの微粒子からなる塵が付着し難く、また付着しても容易に除去できる塵離れ性に優れた特性を発現することを見出し、さらに、メッシュの厚さや開口率などの構成を特定することで、糸くずや綿埃などの繊維状の塵が絡まりにくくすることが可能な知見を得るに至り、サイクロン掃除機に用いて有用な新規な掃除機用の除塵フィルターを創出した。 As a result of intensive research, the present inventors have formed a thin film of inorganic fine particles coated with a silane monomer on the surface of the dust removal filter, so that dust composed of fine particles such as soil and sand is difficult to adhere and adheres. It has been found that it has excellent dust separation characteristics that can be easily removed, and by specifying the configuration such as mesh thickness and aperture ratio, fibrous dust such as lint and cotton dust is removed. As a result, we have obtained knowledge that can make it difficult to get tangled, and have created a new dust filter for vacuum cleaners that is useful for cyclone vacuum cleaners.
すなわち、第一の発明は、空気と塵埃を分離する除塵フィルターであって、除塵フィルターが樹脂繊維からなり、樹脂繊維の表面には、不飽和結合を有するシランモノマーで被覆された無機微粒子からなる薄膜が形成されてなり、不飽和結合を有するシランモノマーで被覆された無機微粒子同士が化学結合して薄膜を形成するとともに、薄膜を形成するシランモノマーで被覆された無機微粒子と樹脂繊維表面との間が化学結合して薄膜と樹脂繊維が固着してなり、樹脂繊維の表面は、樹脂繊維の表面の不飽和結合を有するシランモノマーで被覆された無機微粒子からなる薄膜により微細な凹凸が形成され、微細な凹凸の表面粗さは、算術平均粗さRaで5〜15nm、かつ、十点平均粗さRzで30〜120nmであることを特徴とする掃除機用除塵フィルターを提供するものである。
That is, the first invention is a dust removing filter for separating air and dust, the dust removing filter is made of resin fibers, and the surface of the resin fibers is made of inorganic fine particles coated with a silane monomer having an unsaturated bond. Ri Na thin film is formed, with inorganic fine particles coated with a silane monomer having an unsaturated bond to form a thin film by chemical bonding, and the coated inorganic fine particles and resin fiber surface with a silane monomer to form a thin film The thin film and the resin fiber are firmly bonded to each other, and the surface of the resin fiber is finely uneven with a thin film made of inorganic fine particles coated with a silane monomer having an unsaturated bond on the surface of the resin fiber. is, the surface roughness of the fine irregularities is, 5 to 15 nm in arithmetic mean roughness Ra and, cleaning, characterized in 30~120nm der Rukoto a ten-point average roughness Rz It is to provide a use dust-removing filter.
さらに、第二の発明は、上記化学結合は、グラフト重合であることを特徴とする掃除機用除塵フィルターを提供するものである。
Furthermore, the second invention provides a dust removal filter for a vacuum cleaner, wherein the chemical bond is graft polymerization.
さらにまた、第三の発明は、上記樹脂繊維からなる除塵フィルターがメッシュ構造体であって、除塵フィルターのメッシュ数が20〜200で、除塵フィルターのメッシュ厚さが70〜460μmで、且つ、除塵フィルターのメッシュ開口率が39〜65%であることを特徴とする掃除機用除塵フィルターを提供するものである。
Furthermore, in the third invention, the dust filter comprising the resin fiber is a mesh structure, the dust filter has a mesh number of 20 to 200, the dust filter has a mesh thickness of 70 to 460 μm, and the dust filter. The present invention provides a dust removal filter for a vacuum cleaner, wherein the filter has a mesh opening ratio of 39 to 65%.
本発明によれば、樹脂繊維からなる空気と塵埃を分離する除塵フィルターの表面にシランモノマーで被覆された無機微粒子の薄膜が、樹脂表面に形成されていることから、摩擦による帯電も発生せず、また、無機微粒子の凹凸形状により土や砂などからなる塵の付着も抑制され、さらに、付着しても無機微粒子の凹凸形状により土や砂などからなる塵の付着力が緩和されて、軽い衝撃を加えることで簡単に付着した塵が除去可能な、塵離れ性に優れた特徴を発現する。よって、塵の堆積による目詰まりを抑制することが可能となる。 According to the present invention, since a thin film of inorganic fine particles coated with a silane monomer is formed on the surface of a dust removal filter that separates air and dust made of resin fibers on the resin surface, charging due to friction does not occur. In addition, the uneven shape of the inorganic fine particles suppresses the adhesion of dust made of soil and sand, and even if attached, the uneven shape of the inorganic fine particles reduces the adhesion of dust made of soil and sand, making it light. It is characterized by excellent dust-removing properties that can easily remove dust adhering to it by applying an impact. Thus, clogging due to dust accumulation can be suppressed.
したがって、本発明によれば、サイクロン掃除機での除塵フィルター表面への土や砂埃の付着が防止でき、付着しても簡単に塵が容易に除去できることから、刷毛による除去や洗浄が不必要となり、長期間塵による目詰まりが防止でき、サイクロン掃除機の吸引特性を最大限発揮することが可能となる。 Therefore, according to the present invention, dirt and dust can be prevented from adhering to the surface of the dust removal filter in the cyclone vacuum cleaner, and even if it adheres, dust can be easily removed easily. Therefore, it is possible to prevent clogging due to dust for a long period of time, and to maximize the suction characteristics of the cyclone vacuum cleaner.
以下に、本発明の実施形態の掃除機用除塵フィルターについて詳述する。 Below, the dust removal filter for vacuum cleaners of the embodiment of the present invention will be described in detail.
図1は、本発明の実施形態の掃除機用除塵フィルター100の部分拡大図であり、図2は、本発明の実施形態の掃除機用除塵フィルター100の樹脂繊維1の断面の一部を拡大した模式図である。本実施形態の掃除機用除塵フィルター100は、樹脂繊維1上に無機微粒子2からなる薄膜が形成されることにより構成されている。 FIG. 1 is a partially enlarged view of a vacuum cleaner dust filter 100 according to an embodiment of the present invention. FIG. 2 is an enlarged view of a part of a cross section of a resin fiber 1 of the vacuum cleaner dust filter 100 according to an embodiment of the present invention. FIG. The vacuum cleaner dust filter 100 of this embodiment is configured by forming a thin film made of inorganic fine particles 2 on a resin fiber 1.
なお、図2では本発明の実施形態の一例を判りやすく模式的に示すため、微粒子が1層で形成された図であらわしたが、微粒子が複数重なって微粒子の層を形成してあってもよく、また微粒子同士が化学結合していてもよい。 In FIG. 2, an example of the embodiment of the present invention is schematically illustrated so that the fine particles are formed in one layer. However, a plurality of fine particles may overlap to form a fine particle layer. The fine particles may be chemically bonded to each other.
本実施形態の掃除機用除塵フィルター100に用いられる樹脂繊維1を構成する材料としては、不飽和結合を有するシランモノマー3による化学結合5が可能なものであれば良い。 As a material constituting the resin fiber 1 used for the vacuum cleaner dust filter 100 of the present embodiment, any material may be used as long as the chemical bond 5 by the silane monomer 3 having an unsaturated bond is possible.
ここで、樹脂繊維1は、合成樹脂からなる繊維(合成繊維や化学繊維)であって、例えば、ポリエステル繊維や、ポリアミド繊維や、ポリビニルアルコール繊維や、アクリル繊維や、塩化ビニル繊維や、塩化ビニリデン繊維や、ポリオレフィン繊維や、ポリカーボネート繊維や、フッソ繊維や、ポリ尿素繊維や、エラストマー繊維や、また、これら繊維を構成する材料と上記樹脂材料との複合繊維などが挙げられる。 Here, the resin fiber 1 is a fiber (synthetic fiber or chemical fiber) made of a synthetic resin. For example, the polyester fiber, the polyamide fiber, the polyvinyl alcohol fiber, the acrylic fiber, the vinyl chloride fiber, or the vinylidene chloride. Examples thereof include fibers, polyolefin fibers, polycarbonate fibers, fluorine fibers, polyurea fibers, elastomer fibers, and composite fibers of the materials constituting these fibers and the above resin materials.
本実施形態での掃除機用除塵フィルター100は樹脂繊維1によるメッシュ構造体からなり、これらの樹脂繊維1は、モノフィラメント、マルチフィラメントなどが用いられる。また、樹脂繊維1が交差している個所は融着されてあっても無くても良く、さらに、メッシュ構造体全体がカレンダー加工されてあっても良い。 The vacuum cleaner dust filter 100 in the present embodiment is made of a mesh structure made of resin fibers 1, and the resin fibers 1 are monofilaments, multifilaments, or the like. Further, the portion where the resin fibers 1 intersect may or may not be fused, and the entire mesh structure may be calendered.
本実施形態でのメッシュ数は、20〜200メッシュで、20メッシュ未満では糸くずや綿埃などの質量の小さい埃が透過し、ヘパフィルターの目詰まりの原因になるので好ましくない。また、200メッシュより大きい場合には、繊維状の糸くずや綿埃などがメッシュに絡まるので好ましくない。また、メッシュ厚さは、70〜460μmで、且つ、メッシュ開口率が39〜65%であると、糸くずや綿埃などの繊維状の塵がメッシュ構造体に絡まり難くなり、メッシュ上に堆積した塵が簡単に除去できるので、特に好ましい。 The number of meshes in this embodiment is 20 to 200 meshes, and if it is less than 20 meshes, dust with a small mass such as lint and cotton dust is transmitted, which causes clogging of the hepa filter, which is not preferable. On the other hand, when it is larger than 200 mesh, fibrous lint, cotton dust and the like are entangled with the mesh, which is not preferable. In addition, when the mesh thickness is 70 to 460 μm and the mesh opening ratio is 39 to 65%, fibrous dust such as lint and cotton dust is difficult to get entangled in the mesh structure and is deposited on the mesh. It is particularly preferable because the dust that has been removed can be easily removed.
メッシュ厚さが70μm未満ではメッシュの強度が弱く、空気流の圧力によりメッシュが変形したり破壊に至るため好ましくない。また、メッシュ厚さが460μmより大きい場合には、メッシュを構成する糸の径が太くなるため所望の開口率を得るのが難しく、かつ縦糸、横糸の交点部での変形が大きく、メッシュ上に堆積した塵を一様に除去する特性が低下する。空気流の圧力損失すなわち掃除機の吸引能力の点からは、メッシュの開口率は大きいほうが望ましいが、掃除機用フィルターとして十分な強度を保持してフィルター機能を発現させるには39〜65%が好ましく、特に45〜55%が好ましい。 If the mesh thickness is less than 70 μm, the strength of the mesh is weak, and the mesh is deformed or broken by the pressure of the air flow, which is not preferable. In addition, when the mesh thickness is larger than 460 μm, it is difficult to obtain a desired opening ratio because the diameter of the yarn constituting the mesh is thick, and deformation at the intersection of the warp and weft is large, and the mesh is on the mesh. The characteristic of uniformly removing accumulated dust is deteriorated. From the viewpoint of the pressure loss of the air flow, that is, the suction ability of the vacuum cleaner, it is desirable that the mesh opening ratio is large. However, 39 to 65% is required to maintain the sufficient strength as a filter for the vacuum cleaner and to exhibit the filter function. Particularly preferred is 45 to 55%.
ここでメッシュ数とは、25.4mm間隔に存在する織物としての縦糸または横糸の数を示す。縦糸および横糸のメッシュ数は等しくとも、また異なっていても良い。またメッシュ開口率とは、メッシュ面に垂直に平行光線を投射した時の投影面において、投射されたメッシュ面積に対する平行光線の透過面積の割合である。 Here, the number of meshes indicates the number of warp yarns or weft yarns as a woven fabric existing at intervals of 25.4 mm. The number of meshes of the warp and weft may be the same or different. The mesh aperture ratio is the ratio of the transmission area of parallel rays to the projected mesh area on the projection surface when parallel rays are projected perpendicularly to the mesh surface.
本実施形態の掃除機用除塵フィルター100に用いられる無機微粒子2としては、非金属酸化物として酸化珪素や、金属酸化物として、例えば、酸化マグネシウムや、酸化バリウムや、過酸化バリウムや、酸化アルミニウムや、酸化スズや、酸化チタンや、過酸化チタンや、酸化ジルコニウムや、酸化鉄や、水酸化鉄や、酸化タングステンや、酸化ビスマスや、酸化インジウムなどの酸化物や、酸化チタンバリウムや、酸化コバルトアルミニウム、アルミナーシリカなどの複合酸化物が挙げられる。これらの無機微粒子の結晶性は、非晶性あるいは結晶性のどちらでも良い。 Examples of the inorganic fine particles 2 used in the vacuum cleaner dust filter 100 of the present embodiment include silicon oxide as a non-metal oxide, and metal oxides such as magnesium oxide, barium oxide, barium peroxide, and aluminum oxide. And oxides such as tin oxide, titanium oxide, titanium peroxide, zirconium oxide, iron oxide, iron hydroxide, tungsten oxide, bismuth oxide, indium oxide, titanium barium oxide, oxidation Examples of the composite oxide include cobalt aluminum and alumina-silica. The crystallinity of these inorganic fine particles may be either amorphous or crystalline.
本実施形態の掃除機用除塵フィルター100では、無機微粒子2を、不飽和結合を有するシランモノマー3により、上述した樹脂繊維1上に化学結合5(図中の黒丸部)により固定するものである。 In the vacuum cleaner dust filter 100 of this embodiment, the inorganic fine particles 2 are fixed to the above-described resin fibers 1 by the chemical bonds 5 (black circles in the figure) with the silane monomer 3 having an unsaturated bond. .
具体的なシランモノマー3が有する不飽和結合としては、ビニル基や、エポキシ基や、スチリル基や、メタクリロ基や、アクリロキシ基や、イソシアネート基などが挙げられる。 Specific examples of the unsaturated bond of the silane monomer 3 include a vinyl group, an epoxy group, a styryl group, a methacrylo group, an acryloxy group, and an isocyanate group.
本実施形態の掃除機用除塵フィルター100は、反応性に優れたシランモノマー3を用いることで、無機微粒子2を、シランモノマー3が有するシラノール基の脱水縮合反応による無機微粒子2の化学結合5と上記官能基の樹脂繊維1の樹脂表面への、後述するグラフト重合による化学結合5により、樹脂繊維表面に結合せしめた掃除機用除塵フィルターである。 The dust-removing filter 100 for a vacuum cleaner of the present embodiment uses the silane monomer 3 excellent in reactivity, so that the inorganic fine particles 2 are bonded to the chemical bonds 5 of the inorganic fine particles 2 by the dehydration condensation reaction of silanol groups of the silane monomer 3. The vacuum cleaner dust filter is bonded to the resin fiber surface by a chemical bond 5 by graft polymerization, which will be described later, to the resin surface of the functional group resin fiber 1.
本実施形態の掃除機用除塵フィルター100で用いられるシランモノマー3の一例としては、ビニルトリメトキシシランや、ビニルトリエトキシシランや、ビニルトリアセトキシシランや、N−β−(N−ビニルベンジルアミノエチル)−γ−アミノプロピルトリメトキシシランや、N−(ビニルベンジル)−2−アミノエチル−3−アミノプロピルトリメトキシシランの塩酸塩や、2−(3、4エポキシシクロヘキシル)エチルトリメトキシシランや、3−グリシドキシプロピルトリメトキシシランや、3−グリシドキシプロピルメチルジエトキシシランや、3−グリシドキシプロピルトリエトキシシランや、p−スチリルトリメトキシシランや、3−メタクリロキシプロピルメチルジメトキシシランや、3−メタクリロキシプロピルトリメトキシシランや、3−メタクリロキシプロピルメチルジエトキシシランや、3−メタクリロキシプロピルトリエトキシシランや、3−アクリロキシプロピルトリメトキシシランや、3−イソシアネートプロピルトリエトキシシランなどが挙げられる。 Examples of the silane monomer 3 used in the vacuum cleaner dust removal filter 100 according to the present embodiment include vinyltrimethoxysilane, vinyltriethoxysilane, vinyltriacetoxysilane, N-β- (N-vinylbenzylaminoethyl). ) -Γ-aminopropyltrimethoxysilane, N- (vinylbenzyl) -2-aminoethyl-3-aminopropyltrimethoxysilane hydrochloride, 2- (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane, 3-glycidoxypropylmethyldiethoxysilane, 3-glycidoxypropyltriethoxysilane, p-styryltrimethoxysilane, 3-methacryloxypropylmethyldimethoxysilane And 3-methacryloxypropyltrime Kishishiran and 3-meth and methacryloxy propyl methyl diethoxy silane, and 3-methacryloxypropyl triethoxysilane, 3-acrylic or trimethoxy silane, and 3-isocyanate propyl triethoxy silane.
これらのシランモノマー3は、一種もしくは二種以上混合して用いられる。その使用形態としては、必要量のシランモノマー3をメタノールやエタノールや、アセトンや、トルエンや、キシレンなどの有機溶剤に溶解して用いられる。また、分散性を改善するために塩酸や、硝酸などの鉱酸などが加えられる。 These silane monomers 3 are used alone or in combination. As a form of use, a necessary amount of the silane monomer 3 is dissolved in an organic solvent such as methanol, ethanol, acetone, toluene or xylene. In addition, hydrochloric acid or mineral acid such as nitric acid is added to improve dispersibility.
用いられる溶剤としては、エタノールや、メタノールや、プロパノールやブタノールなどの低級アルコール類や、蟻酸やプロピオン酸などの低級アルキルカルボン酸類や、トルエンやキシレンなどの芳香族化合物、酢酸エチルや酢酸ブチルなどのエステル類や、メチルセルソルブやエチルセルソルブなどのセロソルブ類を単独または複数組み合わせて用いても良い。 Solvents used include lower alcohols such as ethanol, methanol, propanol and butanol, lower alkyl carboxylic acids such as formic acid and propionic acid, aromatic compounds such as toluene and xylene, ethyl acetate and butyl acetate, etc. Esters and cellosolves such as methyl cellosolve and ethyl cellosolve may be used alone or in combination.
本実施形態の掃除機用除塵フィルター100に用いられる無機微粒子2は、前述したシランモノマー3の溶液に分散した状態で製造に用いられる。無機微粒子2の分散は、ホモミキサーやマグネットスターラーなどを用いた撹拌分散や、ボールミルや、サンドミルや、高速回転ミルや、ジェットミルなどを用いた粉砕・分散、超音波を用いた分散などにより行われる。 The inorganic fine particles 2 used in the vacuum cleaner dust removing filter 100 of the present embodiment are used for production in a state of being dispersed in the solution of the silane monomer 3 described above. The inorganic fine particles 2 are dispersed by stirring and dispersing using a homomixer or a magnetic stirrer, pulverizing / dispersing using a ball mill, sand mill, high-speed rotating mill, jet mill, or the like, or using ultrasonic waves. Is called.
また、無機微粒子2は、分散したコロイド状分散液や、粉砕により微粒子化して得られた分散液の状態で、掃除機用除塵フィルター100の製造に用いられる。無機微粒子2の分散液は、コロイド状分散液や粉砕して得られた分散液に、シランモノマー3を加え、その後、還流下で加熱させながら、無機微粒子2の表面にシランモノマー3を脱水縮合反応により結合させてシランモノマー3からなる薄膜を形成する方法や、粉砕により微粒子化して得られた分散液にシランモノマー3を加えた後、或いは、シランモノマー3を加えて粉砕により微粒子化した後、固液分離して100℃から180℃で加熱してシランモノマーを無機微粒子2の表面に脱水縮合反応により結合させ、次いで、粉砕・解砕して再分散して用いられる。 The inorganic fine particles 2 are used in the manufacture of the vacuum cleaner dust filter 100 in the form of a dispersed colloidal dispersion or a dispersion obtained by pulverization. The dispersion of inorganic fine particles 2 is obtained by adding silane monomer 3 to a colloidal dispersion or a dispersion obtained by pulverization, and then dehydrating and condensing silane monomer 3 on the surface of inorganic fine particles 2 while heating under reflux. A method of forming a thin film made of silane monomer 3 by bonding by reaction, or after adding silane monomer 3 to a dispersion obtained by pulverization or by adding silane monomer 3 and pulverizing to pulverization The silane monomer is bonded to the surface of the inorganic fine particles 2 by a dehydration condensation reaction by solid-liquid separation and heated at 100 to 180 ° C., and then pulverized and pulverized for redispersion.
さらに、無機微粒子2からなる無機微粒子層10が厚くなると、無機微粒子層10の応力や使用環境によっては凝集破壊により無機微粒子層10が劣化することもあるので、還流処理後必要に応じて、不飽和結合を有するシランモノマーや、Si(OR1)4(式中、R1は炭素数1〜4のアルキル基を示す)で示されるアルコキシラン化合物、一例として、テトラメトキシシランや、テトラエトキシシランなどや、R2nSi(OR3)4-n(式中、R2は炭素数1〜6の炭化水素基、R3は炭素数1〜4のアルキル基、nは1〜3の整数を示す)で示されるアルコキシシラン化合物、一例として、メチルトリルメトキシシランや、メチルトリエトキシシランや、ジメチルジエトキシシランや、フェニルトリエトキシシランや、ヘキサメチルジシラザンや、ヘキシルトリメトキシシランなど、他にアルコキシオリゴマーなどが添加されて用いられる。 Furthermore, if the inorganic fine particle layer 10 made of the inorganic fine particles 2 is thick, the inorganic fine particle layer 10 may be deteriorated due to cohesive failure depending on the stress of the inorganic fine particle layer 10 or the usage environment. A silane monomer having a saturated bond, an alkoxylane compound represented by Si (OR 1 ) 4 (wherein R 1 represents an alkyl group having 1 to 4 carbon atoms), for example, tetramethoxysilane or tetraethoxysilane R 2n Si (OR 3 ) 4-n (wherein R 2 is a hydrocarbon group having 1 to 6 carbon atoms, R 3 is an alkyl group having 1 to 4 carbon atoms, and n is an integer of 1 to 3) For example, methyltolylmethoxysilane, methyltriethoxysilane, dimethyldiethoxysilane, phenyltriethoxysilane, hexamethyldisilazane, Such Sil trimethoxysilane, etc. Other alkoxy oligomer is used are added.
次に、樹脂繊維1と、上記無機微粒子2とシランモノマー3の混合した溶液とを化学結合する方法について説明する。本実施形態においては、樹脂繊維1と無機微粒子2とを化学結合させる方法として、グラフト重合による結合方法を用いている。 Next, a method for chemically bonding the resin fiber 1 and a solution in which the inorganic fine particles 2 and the silane monomer 3 are mixed will be described. In the present embodiment, as a method for chemically bonding the resin fibers 1 and the inorganic fine particles 2, a bonding method by graft polymerization is used.
本実施形態の掃除機用除塵フィルター100におけるグラフト重合としては、例えばパーオキサイド触媒を用いるグラフト重合や、熱や光エネルギーを用いるグラフト重合や、放射線によるグラフト重合(放射線グラフト重合)などが挙げられる。 Examples of the graft polymerization in the vacuum cleaner dust filter 100 of the present embodiment include graft polymerization using a peroxide catalyst, graft polymerization using heat and light energy, and graft polymerization using radiation (radiation graft polymerization).
このうち、重合プロセスの簡便性や、生産スピード等の観点より、放射線グラフト重合が特に適している。ここで、グラフト重合において用いられる放射線としては、α線や、β線や、γ線や、電子線や、紫外線などを挙げることができるが、本実施形態において用いるには、γ線や、電子線や、紫外線が特に適している。 Of these, radiation graft polymerization is particularly suitable from the viewpoints of simplicity of the polymerization process and production speed. Here, examples of the radiation used in the graft polymerization include α rays, β rays, γ rays, electron beams, ultraviolet rays, and the like. Lines and ultraviolet rays are particularly suitable.
本実施形態でのグラフト重合を用いた掃除機用除塵フィルター100の製造方法は、以下に記した方法により好適に製造される。 The manufacturing method of the dust removal filter 100 for vacuum cleaners using the graft polymerization in this embodiment is suitably manufactured by the method described below.
本実施形態における第一の好適な方法としては、シランモノマー3が結合された無機微粒子2が分散した溶液を、結合しようとする掃除機用除塵フィルター100の樹脂繊維1の表面に塗布し、必要に応じて溶剤を加熱乾燥などの方法により除去した後、γ線や、電子線や、紫外線などの放射線を、シランモノマー3が結合した無機微粒子2が塗布された掃除機用除塵フィルター100の樹脂繊維1の表面に照射することで、シランモノマー3を掃除機用除塵フィルター100の樹脂繊維1の表面にグラフト重合させると同時に無機微粒子2を結合させる、所謂同時照射グラフト重合により製造される。 As a first preferred method in this embodiment, a solution in which inorganic fine particles 2 to which a silane monomer 3 is bonded is dispersed is applied to the surface of the resin fiber 1 of the vacuum cleaner dust filter 100 to be bonded. Resin of the dust removal filter 100 for a vacuum cleaner to which inorganic fine particles 2 to which silane monomer 3 is bonded are applied after removing the solvent by a method such as heating and drying according to the conditions, and then applying radiation such as γ rays, electron beams, or ultraviolet rays. By irradiating the surface of the fiber 1, the silane monomer 3 is graft-polymerized on the surface of the resin fiber 1 of the vacuum cleaner dust filter 100, and at the same time, the inorganic fine particles 2 are bonded, so-called simultaneous irradiation graft polymerization.
また、本実施形態における第二の好適な方法としては、予め、掃除機用除塵フィルター100の樹脂繊維1の表面にγ線や、電子線や、紫外線などの放射線を照射した後に、シランモノマー3が結合された無機微粒子2が分散した溶液を塗布して、シランモノマー3と樹脂繊維1とを反応させると同時に無機微粒子2を結合させる所謂前照射グラフト重合により製造される。 In addition, as a second preferred method in the present embodiment, the surface of the resin fiber 1 of the vacuum cleaner dust filter 100 is irradiated with radiation such as γ rays, electron beams, or ultraviolet rays in advance before the silane monomer 3. It is manufactured by so-called pre-irradiation graft polymerization in which a solution in which inorganic fine particles 2 bonded with water are dispersed and the silane monomer 3 and the resin fiber 1 are reacted and simultaneously bonded with the inorganic fine particles 2.
本実施形態では、上述したように、固定化する無機微粒子2が分散した溶液を、固定化する掃除機用除塵フィルター100の樹脂繊維1の表面に塗布して掃除機用除塵フィルターを製造する。 In this embodiment, as described above, the solution in which the inorganic fine particles 2 to be immobilized are dispersed is applied to the surface of the resin fiber 1 of the vacuum cleaner dust filter 100 to be immobilized to manufacture the vacuum cleaner dust filter.
具体的な無機微粒子2の分散液の塗布方法としては、一般に行われているスピンコート法や、ディップコート法や、スプレーコート法や、キャストコート法や、バーコート法や、マイクログラビアコート法や、グラビアコート法や、または部分的に塗布する方法として、スクリーン印刷法や、パッド印刷法や、オフセット印刷法や、ドライオフセット印刷法や、フレキソ印刷法や、インクジェット印刷法などの様々な方法が用いられ、目的に合った塗布ができれば特に限定されない。 As a specific method for applying the dispersion liquid of the inorganic fine particles 2, generally used spin coating method, dip coating method, spray coating method, cast coating method, bar coating method, micro gravure coating method, Various methods such as screen printing, pad printing, offset printing, dry offset printing, flexographic printing, and inkjet printing can be used as gravure coating methods or partial coating methods. There is no particular limitation as long as it can be used and can be applied according to the purpose.
また、シランモノマー3のグラフト重合を効率良く、かつ、均一に行わせるためには、予め、樹脂繊維1の表面が、コロナ放電処理やプラズマ放電処理や、火炎処理や、クロム酸や過塩素酸などの酸化性酸水溶液や水酸化ナトリウムなどを含むアルカリ性水溶液による化学的な処理などにより親水化処理されてあっても良い。 Moreover, in order to perform the graft polymerization of the silane monomer 3 efficiently and uniformly, the surface of the resin fiber 1 is previously subjected to corona discharge treatment, plasma discharge treatment, flame treatment, chromic acid or perchloric acid. It may be hydrophilized by chemical treatment with an aqueous solution of an oxidizing acid such as an alkaline aqueous solution containing sodium hydroxide or the like.
上記した製造方法により、シランモノマーで被覆された無機微粒子の薄膜が形成された樹脂繊維1の表面には微細な凹凸が形成される。この微細な凹凸を触針式の表面粗さ計((株)アルバック製 DEKTAK3030ST)により計測すると、算術平均粗さRaは5〜15nm、十点平均粗さRzは30〜120nmの表面粗さであった。図3は本発明の実施形態の掃除機用除塵フィルター100の断面の一部を拡大し、表面の凹凸状態を模式的に表した図である。このような微細な表面の凹凸形状と、無機微粒子を被覆するシランモノマーとの相乗作用により、土や砂などからなる塵の付着の抑制や付着力が緩和される表面を形成した。 By the manufacturing method described above, fine irregularities are formed on the surface of the resin fiber 1 on which the thin film of inorganic fine particles coated with the silane monomer is formed. When this fine unevenness is measured with a stylus type surface roughness meter (DEKTAK3030ST manufactured by ULVAC, Inc.), the arithmetic average roughness Ra is 5 to 15 nm, and the ten-point average roughness Rz is 30 to 120 nm. there were. FIG. 3 is an enlarged view of a part of the cross section of the vacuum cleaner dust removal filter 100 according to the embodiment of the present invention, schematically showing the surface unevenness state. Due to the synergistic action of such fine irregularities on the surface and the silane monomer that coats the inorganic fine particles, a surface that suppresses the adhesion of dust made of soil or sand and reduces the adhesion force was formed.
以上説明したように、本発明の実施形態の掃除機用除塵フィルター100によれば、樹脂繊維からなる空気と塵埃を分離する除塵フィルターの表面に、シランモノマーで被覆された無機微粒子の薄膜が樹脂表面に形成されていることから、摩擦による帯電も発生せず、また、無機微粒子の凹凸形状により土や砂などからなる塵の付着も抑制され、さらに、付着しても無機微粒子の凹凸形状により土や砂などからなる塵の付着力が緩和されて、軽い衝撃を加えることで簡単に付着した塵が除去可能な、塵離れ性に優れた特徴を発現するので、塵の堆積による目詰まりが抑制できる。また、上記樹脂繊維よりなる除塵フィルターが糸くずや綿埃などの繊維状の埃が絡まり難い構造を有するメッシュ構造体であることから、集塵した塵が簡単にフィルター表面から除去できるものである。 As described above, according to the vacuum cleaner dust filter 100 of the embodiment of the present invention, a thin film of inorganic fine particles coated with a silane monomer is formed on the surface of the dust filter for separating air and dust made of resin fibers. Since it is formed on the surface, there is no charging due to friction, and the uneven shape of the inorganic fine particles suppresses the adhesion of dust such as soil and sand. The adhesion of dust such as soil and sand is alleviated, and it exhibits a feature that makes it easy to remove attached dust by applying a light impact. Can be suppressed. In addition, since the dust removal filter made of the resin fiber is a mesh structure having a structure in which fibrous dust such as lint and cotton dust is difficult to be entangled, the collected dust can be easily removed from the filter surface. .
本実施形態によれば、前述したように、メッシュ以外の不織布などの繊維状、布状など、使用目的に合った様々な形態(形状、大きさ等)に無機微粒子からなる薄膜が形成できるので、掃除機用以外の換気扇や、エアコン用フィルター、自動車用エアーエレメント、カーエアコン用フィルター、ヘパフィルターなど、様々なフィルターへの応用が可能となる。 According to this embodiment, as described above, a thin film made of inorganic fine particles can be formed in various forms (shape, size, etc.) suitable for the purpose of use, such as a fiber shape such as a nonwoven fabric other than a mesh, or a cloth shape. It can be applied to various filters such as ventilation fans other than for vacuum cleaners, air conditioner filters, automotive air elements, car air conditioner filters, hepa filters.
次に、実施例を挙げて本発明をより具体的に説明する。ただし、本発明はこれらの実施例のみに限定されるものではない。 Next, the present invention will be described more specifically with reference to examples. However, the present invention is not limited to only these examples.
<掃除機用除塵フィルターの作製>
本実施例での掃除機用除塵フィルターの作製は、電子線照射装置として岩崎電気株式会社製、エレクトロカーテン型、CB250/15/180L、を用いて実施した。
<Production of vacuum cleaner dust filter>
The dust removal filter for a vacuum cleaner in this example was manufactured using an Iwazaki Electric Co., Ltd., electro curtain type, CB250 / 15 / 180L as an electron beam irradiation device.
(実施例1)
市販の二酸化チタン微粒子(テイカ株式会社製、MT−100HD)をメタノールに対して10.0重量%、シランモノマーとして3−メタクリロキシプロピルトリメトキシシラン(信越化学工業株式会社製、KBM−503)を微粒子に対して10.0重量%加えてpHを3.0に塩酸で調製した後、ビーズミルにより平均粒子径17nmに粉砕分散した。その後、凍結乾燥機により固液分離して120℃で加熱してシランモノマーを二酸化チタン微粒子の表面に脱水縮合反応により化学結合させて薄膜を形成した。得られたシランモノマー被覆二酸化チタン微粒子をメタノールに10.0重量%分散してビーズミルにより平均粒子径20nmに再度粉砕分散した後、メタノールを加えて固形分を5.0重量%に調整した。
Example 1
10.0 wt% of commercially available titanium dioxide fine particles (manufactured by Teika Co., Ltd., MT-100HD) with respect to methanol and 3-methacryloxypropyltrimethoxysilane (manufactured by Shin-Etsu Chemical Co., Ltd., KBM-503) as a silane monomer. After adding 10.0% by weight to the fine particles to adjust the pH to 3.0 with hydrochloric acid, the mixture was pulverized and dispersed to an average particle size of 17 nm by a bead mill. Thereafter, solid-liquid separation was performed by a freeze dryer, and the film was heated at 120 ° C. to chemically bond the silane monomer to the surface of the titanium dioxide fine particles by a dehydration condensation reaction to form a thin film. The obtained silane monomer-coated titanium dioxide fine particles were dispersed in 10.0% by weight in methanol and pulverized and dispersed again to an average particle size of 20 nm by a bead mill, and then methanol was added to adjust the solid content to 5.0% by weight.
また、メッシュ数が(1)60、(2)80、(3)120、のポリエステル樹脂製モノフィラメントからなるメッシュ状フィルターをコロナ放電処理した後、上記シランモノマーが結合した二酸化チタン微粒子分散メタノール溶液に1〜2分間浸漬した。次に、余剰の二酸化チタン微粒子分散メタノール溶液をエアーブローして除去し、120℃、3分間乾燥した後、二酸化チタン微粒子分散メタノール溶液を塗布した(1)〜(3)のメッシュ状フィルターに電子線を200kVの加速電圧で5Mrad照射することで、メッシュ表面に、シランモノマーで被覆された二酸化チタン微粒子からなる薄膜を結合させて形成した。
Further, after a mesh filter made of polyester resin monofilaments having mesh numbers (1) 60, (2) 80, and (3) 120 is subjected to corona discharge treatment, the titanium dioxide fine particle-dispersed methanol solution to which the silane monomer is bonded is used. Immersion for 1-2 minutes. Next, the excess titanium dioxide fine particle-dispersed methanol solution was removed by air blowing, dried at 120 ° C. for 3 minutes, and then coated with the titanium dioxide fine particle-dispersed methanol solution (1) to (3). by 5Mrad irradiating a line at an acceleration voltage of 200 kV, the mesh surface was formed by bonding a thin film made of coated titanium dioxide particles with a silane monomer.
(比較例1)
実施例1で用いたメッシュ(1)、(2)、(3)をそのまま用いた。
(Comparative Example 1)
The meshes (1), (2), and (3) used in Example 1 were used as they were.
<掃除機用メッシュフィルターへの塵付着性評価>
10×10cmの大きさの、シランモノマーで被覆された二酸化チタン微粒子の薄膜が形成された(1)〜(3)のメッシュに、JISZ8901に準拠した塵、関東ローム、混合ダスト(コットンリンタ、関東ローム、ケイ砂を含む)をまんべんなく降りかけた後、余剰の塵を軽い衝撃を加えて取り除き、塵の付着前後の重量を測定することで、塵付着性を評価した。結果を表1に示した。
<Dust adhesion evaluation to mesh filter for vacuum cleaner>
The size of 10 × 10 cm, the mesh of thin titanium dioxide particles coated with the silane monomer was formed (1) to (3), the dust conforming to JISZ8901, Kanto loam, mixed dust (cotton linters, Dust adhesion was evaluated by thoroughly removing the dust (including Kanto Loam and silica sand), removing the excess dust with a light impact, and measuring the weight before and after the dust was deposited. The results are shown in Table 1.
表1の結果が示すように、シランモノマーで被覆された二酸化チタン微粒子の薄膜が形成された(1)〜(3)のメッシュでは、JISZ8901に準拠した関東ローム、混合ダストなどの塵は殆ど付着しないことから、除塵性に優れていることが実証された。これに対し、無処理のメッシュでは多量の塵が付着した。
As shown in Table 1 the results of a thin film of titanium dioxide particles coated with the silane monomer was formed (1) in the mesh to (3), Rohm Kanto conforming to JISZ8901, dust, etc. mixed dust almost Since it does not adhere, it has been demonstrated that it is excellent in dust removal. In contrast, a large amount of dust adhered to the untreated mesh.
<掃除機による実装試験>
(実施例2)
市販されているサイクロン掃除機(日立ホーム&ライフソリューション株式会社製、たつまきサイクロンCV−SJ10)のダストケースに付いているメッシュフィルターを外し、実施例1で得られた(2)のメッシュフィルターを装着して、室内で1時間実装試験を行った。試験後、ダストケースを掃除機より外して、ダストケース内に集められた塵を、ダストケースにある蓋を開けて開口部を下にして塵箱に捨てた後、メッシュフィルター部を観察したところ、メッシュの表面には塵の付着は認められなかった。
<Mounting test with vacuum cleaner>
(Example 2)
Remove the mesh filter attached to the dust case of a commercially available cyclone vacuum cleaner (Tatsumaki Cyclone CV-SJ10, manufactured by Hitachi Home & Life Solutions Co., Ltd.), and remove the mesh filter of (2) obtained in Example 1. A mounting test was conducted for 1 hour indoors. After the test, the dust case was removed from the vacuum cleaner, and the dust collected in the dust case was opened in the dust case, thrown into the dust box with the opening down, and the mesh filter was observed. No dust was observed on the mesh surface.
(比較例2)
実施例2で用いたメッシュフィルターを比較例1の(2)に替えた以外は実施例2の条件で実装試験を実施し、集めた塵を除去した後、メッシュ表面を観察したところ、メッシュの中央部には塵が付着していた。
(Comparative Example 2)
Except that the mesh filter used in Example 2 was changed to (2) of Comparative Example 1, a mounting test was performed under the conditions of Example 2, and after removing collected dust, the mesh surface was observed. There was dust on the center.
<メッシュフィルターの綿埃・糸くず離脱試験>
一般家庭や事務所などで捕集される塵には、綿埃や糸くずなどの嵩高く重量の小さな塵が比較的多く含まれる。一般家庭で捕集した綿埃や糸くずを多く含む塵を用いて、メッシュフィルターからの塵の離脱試験を行った。掃除機の吸い込みパイプ先端(内径35mmφ)にメッシュフィルターを取り付け、前記の塵、約10gを吸引してメッシュフィルター先端に堆積させた。その後メッシュフィルター近傍のパイプ部を軽くタッピングし、堆積した塵を離脱させ、メッシュフィルターに絡みつく糸くずの有無を目視により確認した。また試験前後におけるダストケースの重量差より、メッシュフィルターを通過し捕集できない塵の重量を測定した。使用したメッシュフィルターは、実施例1と同様の処理によりメッシュ表面にシランモノマーで被覆された二酸化チタン微粒子からなる薄膜を形成したメッシュ数14、20、60、120、200、230の6種類のポリエステル製樹脂モノフィラメントからなるメッシュを用いた。試験の結果を表2に示した。
<Mesh filter cotton dust and lint removal test>
Dust collected in ordinary households and offices contains relatively large amounts of bulky and light dust such as cotton dust and lint. A dust detachment test from a mesh filter was performed using dust collected in a general household and dust containing a lot of lint. A mesh filter was attached to the suction pipe tip (inner diameter: 35 mmφ) of the vacuum cleaner, and about 10 g of the dust was sucked and deposited on the tip of the mesh filter. Thereafter, the pipe near the mesh filter was lightly tapped, the accumulated dust was removed, and the presence or absence of lint entangled with the mesh filter was visually confirmed. Moreover, the weight of the dust that passed through the mesh filter and could not be collected was measured from the weight difference between the dust cases before and after the test. The mesh filters used were 6 types of polyesters with a mesh number of 14, 20, 60, 120, 200, 230 on which a thin film made of titanium dioxide fine particles coated with a silane monomer was formed on the mesh surface by the same treatment as in Example 1. A mesh made of resin monofilament was used. The test results are shown in Table 2.
メッシュフィルターへ堆積した綿埃は、軽い振動を与えることにより容易に離脱するが、メッシュ数が200より大きくなるとメッシュへの糸くずの絡まりが生じており、容易には離脱しなくなる。メッシュ数が20未満では、メッシュフィルターに捕集されずに通過する塵の重量が増加しており、その結果として、後段に設置されるヘパフィルターへの負荷の増大、目詰まりや吸引力低下等の機能低下を引き起こし、好ましくない。 The cotton dust deposited on the mesh filter is easily detached by applying a light vibration. However, when the number of meshes is larger than 200, the yarn is entangled in the mesh and is not easily detached. If the number of meshes is less than 20, the weight of the dust that passes without being collected by the mesh filter is increased. As a result, the load on the hepa filter installed in the subsequent stage is increased, clogging, reduction in suction force, etc. This is not preferable because it causes a decrease in function.
以上説明したように、本発明の掃除機用除塵フィルターは、樹脂繊維からなる空気と塵埃を分離する除塵フィルターの表面に、シランモノマーで被覆された無機微粒子の薄膜が樹脂表面に形成されていることから、摩擦による帯電も発生せず、また、無機微粒子の凹凸形状により土や砂などからなる塵の付着も抑制され、さらに、付着しても無機微粒子の凹凸形状により土や砂などからなる塵の付着力が緩和されて、軽い衝撃を加えることで簡単に付着した塵が除去可能な、塵離れ性に優れた特徴を発現するので、塵の堆積による目詰まりが抑制できる。また、樹脂繊維よりなる除塵フィルターが糸くずや綿埃などの繊維状の埃が絡まり難い構造を有するメッシュ構造体であることから、集塵した塵が簡単に除塵フィルター表面から除去できるものであり、実用性に優れた除塵フィルターである。 As described above, the dust removing filter for a vacuum cleaner of the present invention has a thin film of inorganic fine particles coated with a silane monomer formed on the surface of the dust removing filter that separates air and dust made of resin fibers. Therefore, charging due to friction does not occur, the uneven shape of the inorganic fine particles suppresses the adhesion of dust made of soil and sand, and even if it adheres, the uneven shape of the inorganic fine particles makes the soil and sand. Since the adhesion force of the dust is relaxed and the feature of excellent dust separation property that can be removed easily by applying a light impact, clogging due to dust accumulation can be suppressed. In addition, since the dust removal filter made of resin fiber is a mesh structure that has a structure in which fibrous dust such as lint and cotton dust is difficult to get entangled, the collected dust can be easily removed from the surface of the dust removal filter. It is a dust filter with excellent practicality.
1:樹脂繊維
2:無機微粒子
3:シランモノマー
5:化学結合
10:無機微粒子層
100:掃除機用除塵フィルター
1: Resin fiber 2: Inorganic fine particle 3: Silane monomer 5: Chemical bond 10: Inorganic fine particle layer 100: Dust removal filter for vacuum cleaner
Claims (3)
前記樹脂繊維の表面は、前記樹脂繊維の表面の不飽和結合を有するシランモノマーで被覆された無機微粒子からなる薄膜により微細な凹凸が形成され、当該微細な凹凸の表面粗さは、算術平均粗さRaで5〜15nm、かつ、十点平均粗さRzで30〜120nmであることを特徴とする掃除機用除塵フィルター。 A dust filter for separating air and dust, wherein the dust filter is made of resin fiber, and a thin film made of inorganic fine particles coated with a silane monomer having an unsaturated bond is formed on the surface of the resin fiber. The inorganic fine particles coated with the silane monomer having an unsaturated bond are chemically bonded to form the thin film, and the inorganic fine particles coated with the silane monomer forming the thin film and the resin fiber surface The space is chemically bonded, and the thin film and the resin fiber are fixed,
The surface of the resin fiber is formed with fine irregularities by a thin film made of inorganic fine particles coated with a silane monomer having an unsaturated bond on the surface of the resin fiber, and the surface roughness of the fine irregularities is an arithmetic average roughness. is 5~15nm in Ra, and dust filters for vacuum cleaners, wherein 30~120nm der Rukoto a ten-point average roughness Rz.
前記除塵フィルターのメッシュ数が20〜200で、
前記除塵フィルターの厚さが70μm〜460μmで、
且つ、前記除塵フィルターの開口率が39〜65%であることを特徴とする請求項1または2に記載の掃除機用除塵フィルター。 The dust filter made of the resin fiber is a mesh structure,
The number of meshes of the dust filter is 20 to 200,
The dust filter has a thickness of 70 μm to 460 μm,
And the dust removal filter for vacuum cleaners of Claim 1 or 2 whose opening ratio of the said dust removal filter is 39 to 65%.
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