JP5969758B2 - Brush, brush manufacturing method, cleaning system, chemical substance processing system, and electrophotographic apparatus - Google Patents

Description

  The present invention relates to a brush in which particles are thermally fused to a brush bristle made of synthetic fiber, a brush manufacturing method, a cleaning system, a chemical substance processing system, and an electrophotographic apparatus.

  2. Description of the Related Art Conventionally, in electrophotographic apparatuses such as copying machines, printers, and facsimiles, for example, a roll-shaped cleaning brush is provided for cleaning residual toner remaining on a photoreceptor after transfer to a recording medium. This roll-shaped cleaning brush is formed by implanting brush bristles made of fibers on a roll-shaped substrate.

By the way, in this type of roll-shaped cleaning brush, in recent years, in order to improve cleaning performance, inorganic particles are fixed to brush bristles made of fibers.
For example, the cleaning brush disclosed in Patent Document 1 is provided with a large number of brush fibers in a radial pattern and inorganic oxide fine particles which are the same material as at least one kind of toner external additive at the brush fiber tip. As a result, titanium oxide is adsorbed. This provides a cleaning brush that can improve the recovery efficiency of the toner external additive and can improve the reliability of the image quality.

On the other hand, in the field of filters such as an air filter, a filter made of a fiber brush with a photocatalytic function has been proposed.
For example, as shown in FIGS. 15A and 15B, the general-purpose filter 100 having a photocatalytic function disclosed in Patent Document 2 includes a brush body 102 in which a titanium oxide is applied inside a cylindrical body 101. The brush body 102 is formed by brushing brush hairs 102b on a shaft 102a which is a core material. Nitrogen oxide (NO _{X) is} produced by passing a gas or a liquid through the cylindrical body 101 of the general-purpose filter 100 and using a photocatalytic function of titanium oxide, which is a functional substance for removing harmful substances applied to the bristles 102b.
) Or E. coli can be sterilized. In Patent Document 2, as a confirmation experiment, there is a disclosure that titanium oxide is coated on an aluminum (Al) plate, but there is no disclosure about a method for fixing titanium oxide to a brush.

  By the way, as a method for supporting solid particles on the surface of the fiber brush described above, for example, there are known means for mixing and spinning solid particles in a fiber and means for fixing solid particles on the fiber surface. The former mixed spinning includes, for example, a method in which fine particles of a silver antibacterial agent having a size of 5 μm or less are mixed with a synthetic fiber polymer and then spun. However, the mixed spinning method has a problem that most of the antibacterial agent fine particles remain inside the fiber, and exposure of the necessary antibacterial agent fine particles to the fiber surface is reduced, so that the antibacterial effect is hardly exhibited.

  On the other hand, the latter means for fixing the solid particles to the fiber surface is generally a method of supporting the solid particles on the fiber product using an adhesive. However, this method has the disadvantages that the fine particles are embedded in the adhesive and the effect of the functional agent is low, and the fibers are bonded to each other by the adhesive, the gap is reduced, and the brush hair is hardened. In particular, in a product called a brush, it is difficult to solve the problem that fibers are bonded to each other due to the structure of the product in which a large number of brush hairs are raised with a single fiber. Furthermore, even if an adhesive is applied so as not to impair the texture of the bristles, the film thickness depends on the fiber diameter of the bristles, but the film thickness on the order of 10 nm is the limit. Adhesive strength is weak because there is a concern that the adhesive may peel off from the fiber as well as the strength. For this reason, only particles having a particle size of about 1 nm or less, which is finer than the thickness of the binder, can be adhered, and the adhesive force to the particles is weak.

  Also, as a means for fixing solid particles to the fiber surface, for example, a hot melt fixing method in which, for example, silver antibacterial agent particles are fixed by melting a low melting point fiber using a fiber structure including a low melting point synthetic fiber is proposed. ing. However, this technology can be expected to have the effect of a functional agent when the silver antibacterial agent fine particles are exposed to a large amount. There are disadvantages that the gaps of the material are reduced and the texture becomes worse.

  Then, as what prevents the fault of the fusion | melting solidification of such fibers, for example, in patent document 3, as shown in FIG. 16, the fiber raw material containing the sliver which arranged the wet heat adhesive fiber in parallel The functional fine particles 202 are temporarily fixed using 201 as a raw material, and hydrothermal treatment is performed. As a result of crimp shrinkage of the fiber material 201 due to the hot water treatment, voids 203 are formed, and at least one of the fine particles on the surface of the fiber material 201. A method of manufacturing a flexible fiber material 200 in which many protrusions due to fine particles 202 protrude from the surface of the fiber material 201 by wet-heat bonding of the portions is described. In this method, since voids can be generated by crimp shrinkage of the fiber material by the hot water treatment, it is possible to prevent fusion and solidification of adjacent fibers, improve the texture of the product, antibacterial agent, whitening agent, moisturizing agent It is said that the original functions of fine particles such as antioxidants can be sufficiently exhibited.

  Further, for example, in Patent Document 4, in order to fix solid particles to a fiber made of a thermoplastic resin, the solid particles are brought into contact with the fiber in a state of being heated to a temperature higher than the melting point of the thermoplastic resin. A method for producing a solid particle-supporting fiber is disclosed in which solid particles are supported on the surface by fusing the fiber surface and the solid particle fused fiber is cooled to fix the solid particles to the fiber surface.

  However, the technologies disclosed in each of these patent documents have the following problems.

That is, in Patent Document 1, for example, by supplying a high bias to the recovery roller as a counter electrode while supplying titanium oxide to the cleaning brush, a small discharge is generated between the recovery roller and the brush fiber tip of the cleaning brush. The discharge product generated at this time is adsorbed on the tip of the brush fiber of the cleaning brush.
However, this method has a form in which titanium oxide is fixed only to the tip portion of the brush fiber, and does not have a large amount of particles fixed, and functions only for the contact with the pile tip portion. I can't show it.

  Moreover, the technique disclosed in Patent Document 3 is a method for manufacturing a nonwoven fabric and a pile fabric using the flexible fiber material 200, and does not have enough hardness to be applicable to a brush. Therefore, there is a problem that it is difficult to apply to a brush.

  Further, in the method disclosed in Patent Document 3, specifically, the wet heat adhesive fiber is formed of two parts of a skin and a core, and the skin part is made of an ethylene vinyl alcohol copolymer, The core is made of polyester. That is, in Patent Document 3, the air gap 203 is generated by crimp shrinkage of the fiber material 201 by hot water treatment. However, in order to cause crimp shrinkage of the fiber material 201 by hot water treatment, the fiber material 201 is It must be hydrophilic and cannot be applied to a fiber material 201 such as polyester having a hydrophobic sheath. For this reason, it can be applied only to brushes and pile fabrics that may cause crimp shrinkage. Synthetic fibers with the core-sheath structure of the same kind of material prevent fusion-bonding between adjacent synthetic fibers. It has a problem that it is difficult to do so and the texture becomes worse. Further, according to this method, the particles can be heat-sealed only under hydrothermal treatment, so that the method is limited to the fiber having a melting point of 100 ° C. or less. For this reason, there is a problem that only a brush or a pile fabric having poor heat resistance can be produced. Furthermore, in this method, since the treatment is carried out under hot water treatment, it is affected by the water flow during heat fusion. For this reason, pressure due to the water flow is applied to the melt-bonded fibers and the heat-sealed particles, thereby generating detached particles. For this reason, there exists a problem that the covering state of the particle | grains to a fiber will deteriorate.

  Further, in Patent Document 4, heated particles are brought into contact with fibers to fix the particles. However, when this method is applied to a brush, a sufficient contact pressure can be obtained due to repulsion even when the bristles come into contact with the heated particles. In addition, sufficient heat fusion time cannot be obtained. For this reason, the adhesion force of the particles to the brush hair is weak. Furthermore, since the particles are in contact only with the tips of the bristles, there is a problem that the amount of particles to be fixed cannot be increased.

  As described above, in the conventional technology, there is no brush and pile in which a sufficient amount of particles are fixed uniformly in the particle fixed brush or particle fixed pile using the hot melt fiber suitable for the utilization of the surface property of the particles. In addition, as a result of insufficient avoidance of fusion bonding between brushes or piles, there is a problem that the texture becomes worse.

JP 2009-204654 A (published on September 10, 2009) JP 2002-1022 A (published on January 8, 2002) JP 2008-63690 A (published March 21, 2008) JP 2009-174114 A (released on August 6, 2009)

  The present invention has been made in view of the above-mentioned conventional problems, and its purpose is to prevent heat fusion between adjacent brush hairs and to appropriately heat-fuse particles to brush hairs made of synthetic fibers. It is an object of the present invention to provide a brush, a brush manufacturing method, a cleaning system, a chemical substance processing system, and an electrophotographic apparatus.

  As a result of studying to solve the conventional problems, the inventors of the present application have found that the above-described problems can be solved by adopting the following configuration, and have completed the present invention.

  That is, the brush according to the present invention is a brush provided with brush bristles made of synthetic fibers in order to solve the above-mentioned problems, and the brush bristles are polyester resin, polyamide resin, acrylic resin, fluorine-based brush. A core-sheath structure comprising at least one synthetic fiber selected from the group consisting of a resin and a polypropylene-based resin, and having a core and a sheath having a melting point lower than that of the core; In part, at least a part of particles having an average maximum diameter of 40% or less of the fiber diameter of the brush bristle is heat-sealed so as to be exposed from the sheath portion by heat melting of the sheath portion, and the brush In a bristle of 70% or more with respect to the total number of bristles, the coverage by exposed and heat-sealed particles is 50% or more.

  According to the above configuration, the bristles are made of synthetic fibers, and the synthetic fibers are at least one selected from the group consisting of polyester resins, polyamide resins, acrylic resins, fluorine resins, and polypropylene resins. Become. The brush hair has a core-sheath structure including a core part and a sheath part having a melting point lower than that of the core part. Here, particles are heat-sealed to the sheath portion of the bristle by heat melting of the sheath portion. That is, the configuration is such that the shape of the brush hair can be maintained by the core portion while the sheath portion functions as a sufficient amount of the particle adhesion layer.

  The average maximum diameter of the particles is 40% or less of the fiber diameter of the brush hair. For this reason, the adhesion of the particles to the brush hair is increased, and the coverage of the particles can be increased. Further, some of the heat-sealed particles may be buried in the sheath portion, but at least some of the particles are heat-sealed in a state of being exposed from the sheath portion. Therefore, it is possible to prevent the bristle from fusing as described later. Furthermore, the surface roughness of the brush hair surface can be increased, and when applied to a cleaning brush of an electrophotographic apparatus, it is possible to efficiently and easily remove toner remaining on the photoreceptor after transfer. It becomes. Further, it is sufficient that the region where the particles are thermally fused is at least a part of the sheath portion. The degree of exposure from the sheath portion of the particles is sufficient if at least a part of the particles is exposed.

  Moreover, in the said structure, in 70% or more of bristle with respect to the total number of brush bristle, the coverage of the bristle surface by the particle | grains exposed and heat-seal | fused is 50% or more. This state is already formed before heat fusion, and when the sheath is heat-melted, the adjacent brush hairs are in contact with each other and heat-fused in a sufficiently covered and exposed state. Particles adhering to the brush hair prevent. As a result, a gap between the brush hairs can be secured, and the particles can be thermally fused to the surface of the brush hair while preventing thermal fusion between adjacent brush hairs. That is, with the above-described configuration, it is possible to provide a brush in which particles are thermally fused to each brush hair without thermal fusion between the brush hairs.

  The “core-sheath structure” means a structure comprising a core part and a sheath part as a surface layer part covering at least the side peripheral surface. The “thermal fusion” means that the sheath made of the synthetic fiber is melted by heat and joined to the particles, that is, a mode of joining to the particles including heat melting of the sheath by heat as an indispensable process. Means. Further, the “coverage” means the ratio of the coating of exposed and heat-sealed particles to the entire surface area other than the cross section per brush hair.

  In the above configuration, the synthetic fiber is preferably made of a hydrophobic resin having a melting point of 100 ° C. or higher.

The said structure WHEREIN: It is preferable that the bending rigidity of the bristle in which the said particle | grains were heat-seal | fused to the said sheath part is 5 times or less with respect to the bending rigidity of the bristle before the thermal fusion | bonding of the said particle | grains.
When the particles are thermally fused by thermal melting of the sheath portion, the bristle of the brush bristles and the bristles are fused, and the bending rigidity of the bristles may increase. If the bending stiffness of the brush bristles becomes too large, for example, when the brush is used as a cleaning brush for a photoconductor, the surface of the photoconductor as a contact object may be damaged.
However, as described above, by setting the bending stiffness of the brush bristles in which the particles are heat-sealed to the sheath portion to 5 times or less than the bending stiffness of the bristles before heat fusing, for example, the cleaning brush Even when applied to, the surface of the photoreceptor is not damaged. As a result, it is possible to provide a brush in which particles are thermally fused to the bristle, which can effectively perform functions such as a cleaning function.

  The said structure WHEREIN: The said particle | grain may consist of 1 or more types of inorganic materials or polymer materials different from the said synthetic fiber. Thereby, the brush of this invention is applicable to various uses. For example, in an electrophotographic apparatus, it is possible to use as a cleaning brush capable of increasing the electrostatic attraction force by selecting a material having a charge train opposite to toner charging as particles. Furthermore, in addition to the electrophotographic apparatus, it can be used as a cleaning brush that can easily remove a cleaning target in a cleaning application such as a vacuum cleaner or a semiconductor cleaning process.

  Further, in the above configuration, the particles may be at least one selected from the group consisting of carbon, metal, and a conductive polymer material having a lower electrical resistance than the synthetic fiber. Particles made of these materials exhibit a function as a conductive agent. Moreover, since it is thermally fused to the surface of the bristle without interposing a binder, the electric resistance value can be further reduced compared to a conventional charge control brush using conductive fibers kneaded with a conductive agent at the spinning stage. Can do. As a result, for example, in an electrophotographic apparatus, the brush having the above-described configuration is excellent in performance of injecting or removing charges from an object to be cleaned such as toner, and the charging polarity of toner remaining on the photoreceptor after transfer is more uniform. It can be used for a charge control brush capable of providing a uniform charge distribution. In addition, it is possible to remove the charge of the cleaning object such as the toner firmly adhered by the electrostatic charge etc. with high efficiency to weaken the adhesive force or to remove the charge of the charged object itself with high efficiency. It can also be used for a control brush.

  In the above-described configuration, the particles may be at least one selected from the group consisting of a catalyst, a porous material, and a composite thereof. Thereby, it can provide as a harmful substance removal filter and a cleaning brush excellent in the removal performance of harmful chemical substances, viruses, bacteria, discharge products and the like in gas and liquid fluids. That is, for example, when a porous material is used as particles, harmful chemical substances and the like in the fluid can be adsorbed and removed. Further, by using, for example, a metal catalyst or a photocatalyst as the catalyst, it becomes possible to decompose and remove the harmful chemical substances and the like. Furthermore, by using a porous material carrying these catalysts as particles, it is possible not only to adsorb the harmful chemical substances but also to decompose and remove them. In addition, in the said structure, since the particles of the said catalyst etc. are heat-seal | fused to the bristle, by allowing the fluid containing a hazardous chemical substance to pass between the bristle, the particles are simply placed on the flat surface of the filter or the like. Compared with the applied one, the adsorption efficiency and decomposition efficiency of harmful chemical substances and the like can be significantly improved.

  In order to solve the above-mentioned problem, the brush manufacturing method of the present invention is a method for manufacturing a brush as described above, wherein the particle dispersion is brought into contact with the brush bristles and the particles are applied to the brush bristles. An adhering step for adhering, a drying step for drying the bristles so that the brush bristles are opened, and the brush bristles in the opened state are higher than the melting point of the sheath, and The sheath is heated and melted at a temperature lower than the melting point of the core and the particles, whereby at least some of the particles are thermally fused to at least a portion of the sheath while being exposed from the sheath. And a heat fusing step of attaching.

  According to the above method, the brush is brought into contact with the dispersion liquid in which the particles are dispersed, and the particles are attached to the brush hair. Further, the brush hairs are dried with the brush hairs opened. In this way, the brush hairs are opened in the drying step so that adjacent brush hairs are not in contact with each other as much as possible. Moreover, since the particles are attached to each brush hair, each brush hair is prevented from coming into contact with the sheath portion of the adjacent brush hair at the sheath portion. Subsequently, the particles adhering to the bristles are thermally fused by thermal melting of the sheath. That is, the sheath is heated and melted at a temperature higher than the melting point of the sheath and lower than the melting points of the core and the particles. At this time, the bristles are in an open state, and the particles attached to the bristles prevent contact between the sheath and the sheath. Therefore, it is possible to prevent the brush hairs from being thermally fused. That is, according to the above method, it is possible to manufacture a brush in which particles are thermally fused to each brush hair while preventing gaps between adjacent brush hairs and securing a gap. The “opening” means that the brush hairs are separated into one brush hair without gathering into a bundle.

  In the above method, it is preferable to use a dispersion medium having a surface tension smaller than that of water as the dispersion. When the dispersion liquid is attached to the brush hair, the dispersion medium is also attached to the brush hair. And as above-mentioned, a dispersion medium has surface tension smaller than water. Therefore, the surface of the brush hair to which the particles are attached can be made hydrophobic, thereby facilitating the opening of the brush hair in the brush hair drying step and improving the fiber opening efficiency.

  In addition, a cleaning system according to the present invention includes the brush described above in order to solve the above-described problems. Accordingly, it is possible to provide a cleaning system including a brush in which particles are thermally fused to each brush hair while preventing gaps between adjacent brush hairs and securing a gap.

  Moreover, in order to solve the said subject, the chemical substance processing system which concerns on this invention is equipped with the said description brush, It is characterized by the above-mentioned. Accordingly, it is possible to provide a chemical treatment system including a brush in which particles are thermally fused to each brush hair while preventing gaps between adjacent brush hairs and securing a gap.

  In addition, an electrophotographic apparatus according to the present invention is characterized by including the brush described above in order to solve the above problems. Accordingly, it is possible to provide an electrophotographic apparatus including a brush in which particles are thermally fused to each brush hair while preventing gaps between adjacent brush hairs and securing a gap.

The present invention has the following effects by the configuration described above.
That is, according to the brush of the present invention, particles are thermally fused to the sheath portion of the bristle by thermal melting of the sheath portion, compared with the case where the brush bristle is fixed to the bristle by a general method such as a binder. Thus, the adhesion of the particles to the sheath is strong. Moreover, since the average maximum diameter of the particles is 40% or less of the fiber diameter of the brush hair, the coverage of the brush hair with the exposed and heat-sealed particles can be increased. Furthermore, in the present invention, the coverage of the brush bristle surface by the exposed and heat-sealed particles is set to 50% or more in 70% or more of the bristle with respect to the total number of the bristle. Therefore, when the sheath part is melted by heat, the adjacent brush hairs come into contact with each other and are thermally fused, and the exposed and thermally fused particles prevent the gap between the brush hairs. Can do. That is, according to the present invention, there is an effect that it is possible to provide a brush in which particles are thermally fused to each brush hair while preventing gaps between adjacent brush hairs and securing a gap. .

  Moreover, according to the manufacturing method of the brush of this invention, after making a brush contact the dispersion liquid which disperse | distributed particle | grains and making the said particle | grain adhere to a brush hair, it will be in the state which opened the brush hairs. Then, dry the brush hair. In this way, since the brush hairs are opened in the drying process, the adjacent brush hairs are kept from contacting each other as much as possible. Furthermore, the particles adhering to each brush hair also prevent contact between the sheath and the sheath. As a result, heating at a temperature higher than the melting point of the sheath part and lower than the melting point of the core part and particles, and thermally melting the sheath part, while preventing the bristle from being thermally fused, Only the particles can be thermally fused to the sheath. That is, according to the method for producing a brush of the present invention, it is possible to produce a brush in which particles are thermally fused to each brush hair while preventing gaps between adjacent brush hairs and securing a gap. There is an effect that can be done.

Fig.1 (a) shows one Embodiment of the brush and pile fabric which concern on this Embodiment, Comprising: It is sectional drawing which shows the structure of a bristle or a pile, FIG.1 (b) is a brush or It is sectional drawing which shows the structure of a pile fabric. It is a front view which shows the whole structure of the said brush. It is a flowchart which shows the manufacturing method of a roll brush. It is a whole block diagram which shows the image formation part of the electrophotographic apparatus provided with the said brush. FIG. 5A is a side cross-sectional view showing the configuration of the harmful substance removal device provided with the brush, and FIG. 5B is a front view showing the configuration of the harmful substance removal device. It is a perspective view which shows the structure of the harmful substance removal device provided with the cylindrical structure which consists of a square cylinder. It is a perspective view which shows the structure of the harmful substance removal device bent in the waveform. It is a figure which shows the image by the electron microscope of the said roll brush. FIG. 9A and FIG. 9B are diagrams showing microscope images of brush hairs obtained by thermally fusing carbon by two different methods. FIG. 10A is an enlarged view showing a brush in which particles are uniformly heat-sealed, and FIG. 10B is an enlarged view showing a brush in which particles are heat-sealed unevenly. It is a schematic diagram which shows the test method of a cleaning brush. It is a graph which shows the cleaning performance of the said cleaning brush. It is a graph which shows the filter performance in the said hazardous substance removal device. It is a table | surface showing the measurement result of the friction fastness of the brush which concerns on an Example and a comparative example. FIG. 15A is a side sectional view showing the configuration of a conventional harmful substance removal device, and FIG. 15B is a front view showing the configuration of a conventional harmful substance removal device. It is a figure which shows the synthetic fiber which adhered the other particle | grains in the past.

(Embodiment 1)
One embodiment of a brush in which particles are thermally fused to brush hair made of the synthetic fiber of the present invention and a method for producing the same will be described with reference to FIGS.

  As shown in FIG. 1B, the brush 10 according to the present embodiment includes a base material 11 and brush hairs 12 made of a plurality of synthetic fibers raised on the surface of the base material 11. Further, the brush bristles 12 are heat-sealed with particles 13.

  The substrate 11 is not particularly limited, and for example, a shaft, sheet metal, film, mold, or the like made of metal or resin can be used. In the case of a shaft, a rotational effect can be obtained. On the other hand, in the case of a sheet metal, a film, a mold, or the like, space can be saved. The base material 11 is coated with an adhesive (not shown) for adhering the brush hair 12 that has been electrostatically implanted. It does not specifically limit as the said adhesive agent, A conventionally well-known thing is employable.

  The plurality of brush hairs 12 are provided on the base material 11 by electrostatic flocking, for example. However, the brush bristles 12 are not necessarily limited to electrostatic flocking. For example, the bristles 12 may be flocked to the base material by mechanical flocking found in toothbrushes other than electrostatic flocking. Further, a pile woven fabric can be used as the brush 10, and a pile woven perpendicularly to the base material 11 woven by warp and weft can be used as the brush bristles 12. In addition, in the case where such a pile woven fabric or the above film is used as the base material 11, it can be used by being attached to a secondary base material such as a shaft 14 or a sheet metal shown in FIG. It is.

In addition, the length, thickness (diameter, fiber diameter), and flocking density of the brush bristles 12 of the present embodiment are parameters that are optimized depending on the application, and are not particularly limited. Is preferably about 0.5 mm to 50 mm, and more preferably about 0.5 mm to 10 mm. Further, the diameter of one brush hair 12 is preferably about 3 μm to 500 μm, and more preferably 10 μm to 100 μm. Furthermore, the flock density of the brush bristles 12 is preferably about 1 × 10 ² to 2 × 10 ⁶ filaments / inch ^{2, and} more preferably 1 × 10 ³ to 1 × 10 ⁶ filaments / inch ² . In the present embodiment, even if the brush hairs 12 have a diameter and a flocking density within the above-mentioned numerical ranges, the particles 13 are heat-sealed to the brush hairs 12 without heat-sealing with other adjacent brush hairs 12. Can be made. Regarding the flocking density, by setting the lower limit to 1 × 10 ² / inch ² or more, for example, when used as a cleaning brush, various functions as the brush 10 can be prevented, such as preventing the cleaning function from deteriorating. It is possible to suppress the reduction in performance. Further, by setting the upper limit to 2 × 10 ⁶ filaments / inch ² or less, it is possible to further reduce the contact between the bristles 12 when the particles 13 are thermally fused, and to prevent thermal fusion between them. . The flocking density means the number of bristles 12 per unit area (inch ² ) in the substrate 11.

  In the present embodiment, the bristle 12 has a core-sheath structure as shown in FIG. That is, it has a structure comprising a core portion 12a and a sheath portion 12b that covers at least the side peripheral surface of the core portion 12a. Here, in Fig.1 (a), although the sheath part 12b does not exist in the front-end | tip part of the bristle 12, this invention is not limited to this aspect. That is, the aspect in which the sheath part 12b was formed in the front-end | tip part of the bristle 12 is also included. Moreover, the melting point of the sheath part 12b is lower than the melting point of the core part 12a. Furthermore, the brush bristles 12 are made of synthetic fibers, and the combination of materials of the core portion 12a and the sheath portion 12b may be the same or different.

  The synthetic fiber is made of at least one resin selected from the group consisting of polyester resins, polyamide resins, acrylic resins, fluorine resins, and polypropylene resins.

  It does not specifically limit as said polyester-type resin, A conventionally well-known thing can be used. Specifically, for example, polyethylene terephthalate, polybutylene terephthalate, or a copolymerized polyester obtained by copolymerizing a third component such as adipic acid, isophthalic acid, isophthalic acid sulfonate, and polyethylene glycol can be used. These polyester resins can be used singly or in combination of two or more.

  It does not specifically limit as said polyamide-type resin, A conventionally well-known thing can be used. Specifically, nylon 6,6, nylon 6, nylon 4,6 etc. are mentioned, for example. These polyamide resins can be used alone or in combination of two or more.

  It does not specifically limit as said acrylic resin, A conventionally well-known thing can be used. Specific examples include a polymer of acrylonitrile and a monomer copolymerizable with the acrylonitrile. Examples of the monomer include acrylic acid, methyl acrylate, ethyl acrylate, itaconic acid, methacrylic acid, methyl methacrylate, styrene, acrylamide, methacrylamide, vinyl acetate, vinyl chloride, vinylidene chloride, methallylsulfonic acid, methallylsulfone. And vinyl monomers such as acid salts, styrene sulfonic acid, styrene sulfonic acid salts, allyl sulfonic acid, and allyl sulfonic acid salts. Various acrylic resins obtained by copolymerization of these monomers with acrylonitrile can be used singly or in combination of two or more.

  The fluorine-based resin is not particularly limited, and conventionally known resins can be used. Specifically, for example, polytetrafluoroethylene (PTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), ethylene-tetrafluoroethylene copolymer (ETFE), polyvinylidene fluoride (PVDF), etc. Can be mentioned. These fluororesins can be used alone or in combination of two or more.

  It does not specifically limit as said polypropylene resin, A conventionally well-known thing can be used. Specifically, polypropylene etc. are mentioned, for example.

  Among the resins exemplified above, the present invention can also be suitably used for synthetic fibers made of hydrophobic resins, synthetic fibers that do not cause crimp shrinkage, and synthetic fibers having a melting point of 100 ° C. or higher. For example, as disclosed in Patent Document 3, conventionally, wet-heat adhesion of particles is performed by hot water treatment using wet-heat adhesive fibers that cause crimp shrinkage. However, for fibers that do not cause crimp shrinkage due to the hot water treatment, voids cannot be generated, and thus adhesion between the fibers cannot be prevented. On the other hand, in the present invention, as will be described later, the particles 13 attached to the sheath portion 12b prevent thermal fusing between adjacent brush hairs 12, so that synthetic fibers made of hydrophilic resin or crimp shrinkage are prevented. It is not limited to the use of the resulting synthetic fiber. Furthermore, it does not matter whether the core portion 12a and the sheath portion 12b have a crimp contraction function. Moreover, the conventional method can be applied only to brushes and pile fabrics that may cause crimp shrinkage, and it is difficult to apply to brushes with very high fiber density of brush hair, and the melting point of the sheath part. However, in the present invention, there is no such limitation. In the conventional method described above, heat fusion between the fibers cannot be avoided due to the influence of a weak water flow other than the method of reducing the contact between the fibers due to crimp shrinkage. Moreover, the said hydrophobic resin means that the ratio of a hydrophobic monomer unit exceeds 50 mass% on the basis of the total amount of the monomer unit of the polymer which comprises this.

  The particles 13 are thermally fused by thermal melting of the sheath 12b of the brush bristles 12. A method is also conceivable in which the particles 13 are thermally melted and thermally fused to the sheath portion 12b (for example, Patent Document 4). In this case, the thermally melted particles 13 contact the sheath portion 12b and immediately heat fuse. In addition, the strength of heat fusion is also reduced. Furthermore, the amount of particles 13 to be heat-sealed is also reduced. However, with the method in which the sheath portion 12b is thermally melted, more particles 13 can be reliably and firmly heat-sealed to the sheath portion 12b.

  The particles 13 are preferably made of one or more inorganic materials or polymer materials different from the synthetic fibers of the brush hairs 12. The inorganic material or the polymer material can be appropriately selected depending on the use, but is preferably higher than the melting point of the sheath 12b of the bristles 12. Thereby, as described later, when the sheath portion 12b is thermally melted, it is possible to avoid the particles 13 from being melted simultaneously. The inorganic material is not particularly limited, and examples thereof include carbon, metal, or a conductive polymer material having an electric resistance value lower than that of the synthetic fiber. Moreover, at least 1 sort (s) chosen from the group which consists of a catalyst, a porous material, and these composites can also be used. Furthermore, a carbon nanotube etc. are employable. In addition, the polymer material is not particularly limited, and examples of the material used for applications that dislike brush contamination such as a charge control brush of an electrophotographic apparatus include particles having surface properties with high surface energy. More specifically, a fluororesin etc. are mentioned.

  The shape of the particle 13 is not particularly limited, and examples thereof include a substantially spherical shape and a rectangular parallelepiped shape. The substantially spherical shape is meant to include a deformed spherical shape such as an elliptical shape in addition to a true sphere.

  In addition, the melting point of the particles 13 needs to be higher than the melting point of the sheath 12b. This is because when the melting point of the particles 13 is equal to or lower than the melting point of the sheath portion 12b, the particles 13 are also melted at the same time when the sheath portion 12b is melted.

  Moreover, the coverage with respect to one brush hair 12 of the particle | grains 13 which are exposed and heat-seal | fused is 50% or more, Preferably it is 70%-100%, More preferably, it is 90%-100%. Conventionally, binders (adhesives) have been widely used as a method for fixing particles to fibers. However, this method has a problem that the binder covers the particles and the function of the particles cannot be utilized. On the other hand, in the present invention, as described above, the coverage of the particles 13 heat-sealed with at least a portion exposed is 50% or more of the surface of the brush bristles 12. For this reason, the heat-bonded particles 13 are buried in the sheath 12b, thereby preventing the activity and surface characteristics from being hindered and failing to function, and a sufficient amount of particles exhibiting the function. Can do.

Here, the coverage means the ratio of the coating of the exposed and heat-sealed particles 13 with respect to the entire surface area other than the cross section per brush hair 12, for example, a laser microscope (Keyence Corporation). ), Product name; VK-8700). Specifically, first, fibers of the same material as the brush bristles 12 for thermally fusing the particles 13 are measured with a laser microscope, and the height of the surface irregularities is measured. In this measurement, for example, the brush bristle height data is collected using a 100 × objective lens, and the line roughness (Ra) is measured for an arbitrary line region having a width of 100 μm (JIS B0601). : 1994 cut-off value: 0.08 mm).
Next, the height of the surface irregularities in the measurement range in the bristle 12 after the thermal fusion of the particles 13 is measured again with a laser microscope, and the line roughness of the bristle thermally fused by the particles 13 is measured. Measure (Ra). It is determined whether the particles are thermally fused in the measurement range based on the difference in the line roughness. A criterion of whether the ratio of the difference in line roughness before and after thermal fusion is 200% or more is whether the particles 13 are thermally fused in this measurement region. Subsequently, this measurement is performed at an arbitrary 10 points in one brush hair. The coverage is calculated by the ratio of the number of measurement areas exceeding the reference in this measurement. In addition, it is preferable to perform the measurement area | region of this measurement at least 3 or more points. About a covering state, it is not necessarily limited to this method, For example, according to the kind of particle | grains 13, it is also possible to confirm by correlation with an electrical resistance value or a friction coefficient.

Furthermore, the ratio of the bristle 12 having the above-mentioned coverage of 50% or more is 70% or more of the total number, preferably 80% to 100%, more preferably 90% to 100%. The ratio is calculated by, for example, selecting 100 arbitrary brush hairs to which the particles 13 are heat-sealed, and counting the number of brush hairs having a coverage calculated by the above method of 50% or more. It is.
This calculation is preferably performed with at least 10 brush hairs.

Further, the particles 13 have an average maximum diameter of 40% or less, preferably 30% or less, more preferably 20% or less with respect to the fiber diameter of the brush bristles 12. By setting the average maximum diameter to 40% or less of the fiber diameter of the brush bristles 12, the particles 13 can be firmly heat-sealed to the sheath portion 12b with a strength equal to or higher than that of the binder. However, from the viewpoint of preventing the particles 13 from being buried in the bristles 12 and preventing the yarns from sticking to each other, the average maximum diameter is preferably 0.1% or more with respect to the fiber diameter of the bristles 12. The average maximum diameter is a value obtained by observing and measuring the particles 13 after heat fusion by observation and measurement with the laser microscope. In addition, the average maximum diameter means the average value of the diameter (maximum particle diameter) when the particle 13 is substantially spherical.
In the production of the brush, the particle size distribution of the particles 13 is measured by, for example, a particle size distribution measuring apparatus (Shimadzu Corporation, trade name: SALD-7100) using a laser diffraction / confusion method, and appropriate particles are selected. Can be used. In this case, 50% particle size can be used as a reference for the average maximum diameter in the volume cumulative distribution.

  Moreover, the thickness of the sheath part 12b in the brush bristles 12 has a thickness of 25% or more of the average maximum diameter of the particles from the viewpoint of the adhesive strength by heat fusion and the range of the particle size range capable of heat fusion. Preferably, it has a thickness of 40% or more. By making the sheath portion 12b have a thickness of 25% or more with respect to the average maximum diameter of the particles, it becomes possible to heat-bond the particles 13 that are impossible with a conventional binder or the like. Further, from the viewpoint of maintaining the shape of the brush bristles 12, the thickness of the sheath portion 12b is preferably within a range of 5% to 30% with respect to the fiber diameter of the bristles 12 (the diameter of the brush bristles 12), and is 20% or less. Within the range is more preferable. Thereby, even if heat-melting, the bristle 12 can maintain the shape of the bristle, and the heat fusion of the particles 13 can also obtain a sufficient fixing force. Further, at least a part of the heat-sealed particles 13 is exposed to the outside from the sheath portion 12b. The exposure may be at least part of the particles 13. Furthermore, the particle | grains 13 buried inside the sheath part 12b may exist.

  In the brush 10, the bending rigidity of the brush bristles 12 to which the particles 13 are heat-sealed is preferably in the range of 5 times or less than the bending rigidity of the bristles 12 before the heat-bonding of the particles 13. A range of 2 to 4 times is more preferable, and a range of 0.5 to 3 times is particularly preferable. When the particles 13 are thermally fused to the bristle 12 and the fibers are cured or the thermal fusion between the bristle 12 occurs, and the bending stiffness of the bristle 12 becomes too large, for example, the brush 10 is cleaned of the photoreceptor. When used as a brush, the surface of the photoreceptor may be damaged. However, in the present embodiment, as described above, the bending rigidity of the brush bristles 12 to which the particles 13 are heat-sealed is set to be five times or less than the bending rigidity of the bristles 12 before the heat fusing of the particles 13. Even when used as a cleaning brush for a photoconductor, the surface of the photoconductor as a contact object is not damaged. As a result, it is possible to provide the brush 10 in which the particles 13 that can effectively exhibit functions such as a cleaning function are thermally fused. From the viewpoint of improving the scraping performance of toner or the like in cleaning, it is not preferable to soften more than before heat fusion, and the lower limit value of the bending rigidity is more preferably 0.5 times. The bending rigidity can be controlled by adjusting the heat fusion temperature, the concentration of the particle dispersion, and the like. The numerical range of the bending stiffness is an appropriate value obtained by experimental observation.

The bending stiffness EI (E is a longitudinal elastic modulus, I is a cross-sectional secondary moment) can be obtained, for example, by the product of the longitudinal elastic modulus E and the cross-sectional secondary moment I. Also, for example, the fiber deflection δ (mm) = PL ³
/ KEI can be obtained indirectly. Here, P is the load applied to the fiber axis, and L is the fiber length. Further, k is a constant that varies depending on the fiber shaft support method.
The bending stiffness may be calculated by, for example, an average value of values obtained by measuring the weight applied to a probe having a certain width using a load cell or the like, or a comparison based on a value obtained by measuring the pressure of a brush with a certain amount of biting width. Can also be measured.

  In the present embodiment, as shown in FIG. 2, a roll brush formed by forming a base material 11 on which the bristles 12 are planted into a strip shape and, for example, spirally wound around a rotatable shaft 14. 10a is possible. The roll brush 10a shown in FIG. 2 is an example in which the brush 10 having the flexible substrate 11 is wound around the shaft 14. However, this invention is not limited to this, For example, it is also possible to produce the roll brush of the form similar to the roll brush 10a by making shaft 14 itself into the base material 11 shown in FIG. 1 by methods, such as electrostatic flocking. .

  Next, a method for manufacturing the brush 10 according to the present embodiment will be described using the roll brush 10a as an example. FIG. 3 is a flowchart showing a method for manufacturing the roll brush 10a.

  First, as shown in FIG. 3, the brush-shaped thing which has the bristle 12 which made the core-sheath-type molten yarn into electrostatic flocking or pile weave is produced (S1). As the bristle 12, a core-sheath synthetic fiber having a core part 12a and a sheath part 12b having a melting point lower than that of the core part 12a is used.

  Next, particles 13 having an average maximum diameter of 40% or less with respect to the diameter (fiber diameter) of the brush bristles 12 are mixed with alcohol to prepare a dispersion (S2). The dispersion medium in the dispersion is not particularly limited, and examples thereof include water, alcohol such as isopropyl alcohol (IPA) and ethanol. Among these dispersion media, alcohol is preferable from the viewpoint of creating a good open state of the bristles 12 in the drying step described later. This is because alcohol has a surface tension lower than that of water, so that the dispersion liquid covering the fibers and the fibers are less likely to aggregate, and the brush bristles 12 can be easily opened and dried. In the case of using a dispersion medium other than alcohol such as water, an appropriate treatment can be performed by lowering the surface tension of the dispersion using a surfactant or the like. In addition, a method for improving the coverage by controlling the zeta potential of the fine particles and fibers using an alternate lamination method or the like is also effective.

  Next, this dispersion is brought into contact with the brush bristles 12 (S3: adhesion step). It does not specifically limit as a contact method, For example, brush coating, spraying by a spray, the dip method etc. are mentioned. By this process, the particles 13 can be attached to the brush hairs 12.

  Next, the brush hair 12 brought into contact with the dispersion is dried (S4: drying step). It does not specifically limit as a drying method, For example, the method by heating, the natural drying, the method of spraying dry air, etc. are mentioned. In the case of drying by heating, the drying temperature is appropriately set as necessary, and is usually 25 ° C to 100 ° C, preferably 25 ° C to 80 ° C, more preferably 40 ° C to 60 ° C. Also, the drying time is appropriately set as necessary, and is usually 5 minutes to 120 minutes, preferably 10 minutes to 90 minutes, and more preferably 30 minutes to 60 minutes.

  Moreover, in this process, in order to reduce that the bristle brush 12 which adjoins contacts in the sheath part 12b at least, it dries so that the bristle 12 after drying may be in the opened state. When opening the brush hair 12 to make it open, it is not preferable to apply the opening to only the tip of the brush hair 12. This is because the brush hairs 12 may be heat-sealed at the base portion of the brush hairs 12. In addition, it is preferable to appropriately adjust the conditions for the fiber-opening treatment so that a large amount of particles are not detached. Moreover, it does not specifically limit as a method of opening, For example, a hair split etc. are mentioned. The hair splitting is not limited to one time but may be performed a plurality of times. However, when the brush hairs 12 after drying are in an open state depending on the conditions of the dispersion medium and the particles 13, the above-described splitting of the hairs is not necessarily required.

  Next, the particles 13 are thermally fused to the dried bristle 12 (S5: thermal fusion process). The method for heat sealing is not particularly limited, and for example, it can be performed by placing it in an atmosphere at a high temperature using an oven or the like. The heating time can be appropriately set as necessary. Moreover, as heating temperature, it is more than melting | fusing point of the sheath part 12b, and lower than melting | fusing point of the core part 12a and the particle | grains 13. As a result, only the melting point 12b is thermally melted, and the particles 13 can be heat-sealed. Further, since the particles 13 are attached so as to cover the surface of the brush hairs 12, they serve as spacers and prevent the adjacent brush hairs 12 from contacting each other in the sheath 12b that has been melted by heat. Can do. As a result, it is possible to prevent heat fusion between the brush bristles 12 which is difficult with the conventional method of fixing the particles by melting the core-sheath-type heat-melting fiber, and heat fusion of a sufficient amount of particles 13 is also possible. I have to. Furthermore, since the core portion 12a is not melted, the shape of the brush 12 can be prevented from being greatly deformed. In the present embodiment, it is not necessary to use synthetic fibers that cause crimp shrinkage as the bristle 12 in order to prevent thermal fusion between the bristle 12, so the bristle 12 (for pile weaving) In the case of application, the shape of the pile) can be maintained, and since heating is performed by the atmospheric temperature, there is no restriction on the fiber melting temperature.

  After the heat fusion step, a step of removing the particles 13 that have not been heat-fused or the particles 13 that are insufficiently heat-fused may be performed (S6). The removal step is performed, for example, by blowing air or the like. At this time, it is preferable to separate the brush hairs 12 by blowing air so that the brush hairs 12 do not contact each other. As described above, the roll brush 10a in which the particles 13 are thermally fused to the bristles 12 is obtained.

  In the manufacturing method of the roll brush 10a, the sheath portion uses the bristles 12 having a core-sheath structure that is easier to melt than the core portion. It enables heat fusion to 13 brush hairs. Further, when the sheath portion 12b is thermally melted, the particles 13 prevent the adjacent brush hairs 12 from being thermally fused together in the sheath portion 12b, so that even if the brush has no crimp and has a high fiber density. A sufficient amount of particles 13 can be thermally fused to the bristles 12 without reducing the particle activity.

The brush 10 according to the present embodiment can be suitably applied to various uses. For example, a cleaner in a field that requires precise design such as an electrophotographic apparatus can use brush bristles 12 made of synthetic fibers that do not cause crimp shrinkage, so that the shape is maintained even when the particles 13 are heat-sealed. It is possible to apply a brush that suppresses the occurrence of variation in the crimp state for each product. Further, since the particles 13 are not adhered using a binder, the affinity can be controlled by the type of the object to be cleaned, and the cleaning performance can be controlled by the type of the object to be cleaned. Furthermore, since a sufficient amount of the particles 13 can be heat-sealed to coat the brush hairs 12 with the particles 13, the surface of the brush hairs 12 can be made to approach the characteristics of the particles 13 uniformly. In the field of polishing brushes, the friction coefficient, wettability, hardness and the like can be improved. In the field of conductive brushes, the electrical resistance value can be greatly reduced. Furthermore, since the brush 10 has less heat fusion between the bristles 12, in the field of cleaners and polishing brushes, it is possible to provide a brush that can perform uniform functions with little variation in brush rigidity. .
In the following, a specific example to which the brush 10 is applied will be described in more detail.

(Embodiment 2)
The following will describe another embodiment of the present invention with reference to FIG. The configurations other than those described in the present embodiment are the same as those in the first embodiment. For convenience of explanation, members having the same functions as those shown in the drawings of the first embodiment are given the same reference numerals, and explanation thereof is omitted.

  In the present embodiment, a case where the brush 10 described in the first embodiment is applied to an electrophotographic apparatus will be described. That is, the brush 10 described in the first embodiment can be applied to, for example, a cleaning brush of an electrophotographic apparatus or a charging control brush. First, the structure of the image forming unit in the electrophotographic apparatus will be described with reference to FIG. FIG. 4 is a front view schematically showing the structure of the image forming unit in the electrophotographic apparatus provided with the cleaning brush and the charge control brush of the present embodiment. The electrophotographic apparatus outputs data read by a scanner included in the electrophotographic apparatus or data from an external device (for example, an image processing apparatus such as a personal computer) connected to the electrophotographic apparatus as an image. It is.

  As shown in FIG. 4, the image forming unit 30 includes a photosensitive drum 1, a charging device 2, an exposure device 3, a developing device 4, a transfer roll 5, a conveyance belt 6, a charging control device 7, And a cleaning device 20. Around the photosensitive drum 1, along the rotation direction, the charging device 2, the exposure device 3, the developing device 4, the transfer roll 5 and the transport belt 6, the charging control device 7, and the cleaning The apparatus 20 is arranged in this order.

  The photosensitive drum 1 serves as the electrostatic latent image carrier and the photosensitive member of the present invention in the image forming apparatus, and has a cylindrical shape.

  The charging device 2 is in physical contact with the photosensitive drum 1 to uniformly charge the surface of the photosensitive drum 1 to a predetermined potential. The charging device 2 is composed of a charging control brush, and is installed adjacent to and opposed to the photosensitive drum 1 with their rotation axes parallel to each other.

  The exposure device 3 exposes the surface of the photosensitive drum 1 charged by the charging device 2 with a laser beam or the like based on data from an image processing apparatus such as a personal computer, for example, so that the surface of the photosensitive drum 1 is statically exposed. This is for forming an electrostatic latent image. As the exposure apparatus 3, for example, a semiconductor laser or a light emitting diode can be used.

  The developing device 4 supplies developer to the surface of the photosensitive drum 1 and visualizes, that is, develops the electrostatic latent image formed on the surface of the photosensitive drum 1 as a developer image. In the developing device 4, the developer is supplied to the developing roll 4 b at a constant thickness by the developer supply roll 4 a, and the developer roll 4 b comes into contact with the photosensitive drum 1, whereby the developer is applied to the surface of the photosensitive drum 1. Is supplied. In the developing device 4 of the present embodiment, for example, a developer made of a non-magnetic one-component developer is used, and a so-called non-magnetic one-component developing system is adopted. In the present invention, not only the non-magnetic one-component developer but all developers can be targeted.

  The conveyance belt 6 is for conveying a recording medium 8 such as PPC (Plain Paper Copy) paper to the photosensitive drum 1 after a developer image is formed on the surface of the photosensitive drum 1.

  The transfer roll 5 is for transferring the developer image on the surface of the photosensitive drum 1 to a recording medium 8 as a transfer material. The surface direction of the sheet metal and the surface direction of the recording medium 8 are parallel to each other. It is installed so as to face and adjoin the photosensitive drum 1 with the conveying belt 6 interposed therebetween. The recording medium 8 is, for example, paper, OHP, or the like. The transfer roll 5 is made of, for example, a urethane rubber roll.

  The charge control device 7 controls the charge of the remaining positive and negative developer remaining on the photosensitive drum 1 after transfer, for example, so as to be all negative. Note that the charging control device 7 may not exist.

  The cleaning device 20 includes a cleaning brush 22 and removes developer, paper dust, and the like remaining on the surface of the photosensitive drum 1. The cleaning device 20 will be described in detail later.

In the image forming apparatus configured as described above, the following image forming operation is performed.
That is, the surface of the photosensitive drum 1 is uniformly charged by the charging device 2. The photosensitive drum 1 whose surface is charged is exposed based on data by the exposure device 3, and an electrostatic latent image is formed on the surface of the photosensitive drum 1. Then, a developer is supplied to the surface of the photosensitive drum 1 by the developing roller 4b of the developing device 4, and the electrostatic latent image on the surface of the photosensitive drum 1 is developed and visualized. Subsequently, the recording medium 8 is conveyed to the photosensitive drum 1 by the conveyance belt 6, and the developer image on the surface of the photosensitive drum 1 is transferred to the recording medium 8 by the transfer roll 5. After the transfer, the remaining developer, paper dust, and the like are subjected to charge control to be negative or positive by the charge control device 7 and then removed by the cleaning brush 22. Image formation is performed in such a cycle.

Next, details of the cleaning device 20 of the present embodiment will be described below with reference to FIG.
As described above, the cleaning device 20 according to the present embodiment removes the cleaning object such as the developer and paper dust remaining on the surface of the photosensitive drum 1. A conductive roller 23 that contacts the brush 22 and a cleaning member 24 that slides on the conductive roller 23 are provided. The cleaning device 20 is an example, and for example, the conductive roller 23 and the cleaning member 24 may not exist.

  The cleaning brush 22 is in physical contact with the photosensitive drum 1 and removes a cleaning object such as developer and paper dust remaining on the surface of the photosensitive drum 1. The conductive roller 23 in contact with the cleaning brush 22 adsorbs the negative residual developer adsorbed at the tip of the brush bristles 22a having the positive polarity of the cleaning brush 22 by being charged to positive polarity, for example. The remaining developer adsorbed on the conductive roller 23 is removed by a cleaning member 24 that slides on the conductive roller 23.

In the present embodiment, the cleaning brush 22 has the same configuration as the brush 10 described in the first embodiment.
That is, as shown in FIG. 4, the cleaning brush 22 of the present embodiment has a base material 22b wound around a roller 22c and a brush thread made of a plurality of fibers raised on the surface of the base material 22b. And bristles 22a. The cleaning brush 22 is formed by electrostatically flocking the plurality of brush bristles 22a on the base material 22b, for example. Therefore, in the cleaning brush 22 in the brush 10 in the first embodiment, the roller 22c corresponds to the shaft 14 shown in FIG. 2, the base material 22b corresponds to the base material 11, and the brush bristles 22a thermally melt the particles 13. It corresponds to the worn bristle 12.

  The cleaning brush 22 is spirally wound around a rotatable roller 22c, and the photosensitive drum 1 has a rotational axis direction of the photosensitive drum 1 and a rotational axis direction of the roller 22c parallel to each other. It is installed adjacent to so as to face.

  As described above, the cleaning brush 22 of the present embodiment heats the brush bristles 12 so that at least a part of the particles 13 made of an inorganic material or a polymer material, which is one or more kinds of materials different from the synthetic fiber, are exposed. Since it is fused, the surface roughness can be made larger than that of conventional brush bristles. Thereby, it is possible to provide the cleaning brush 22 capable of easily removing the cleaning object such as the toner remaining on the photoreceptor after the transfer in the electrophotographic machine.

  Further, it is possible to provide the cleaning brush 22 capable of increasing the electrostatic attraction force by selecting a material having a charge column that is opposite to the charging of the toner.

Furthermore, a cleaning brush that can remove substances other than solids that cannot be removed by conventional synthetic fiber cleaning brushes such as harmful gases and discharge products by using particles 13 made of a porous material or a catalyst. 22 can be provided.
Furthermore, an electrical adsorption function can be provided by fusing together with conductive particles.

  Further, it is possible to provide the cleaning brush 22 that can easily remove a cleaning target even in a cleaning application such as a vacuum cleaner or a semiconductor cleaning process, which is an application other than an electrophotographic machine.

  The cleaning device 20 as the cleaning system of the present embodiment includes the brush 10 or the cleaning brush 22 described in the first embodiment. Thereby, even in the synthetic fiber made of a hydrophobic resin, the brush 10 and the cleaning brush 22 that can reduce the fusion-solidification of adjacent brush hairs and appropriately heat-fuse the particles to the brush hair made of the synthetic fiber. A cleaning device 20 as a provided cleaning system can be provided.

  In the above description, the case where the brush 10 is applied to the cleaning brush 22 and the cleaning device 20 has been described. However, the present invention is not limited to this. For example, the brush 10 may be applied to a charging control brush in the charging device 2. In this case, as the particles 13, it is preferable to use a conductive material (conductive agent) such as carbon or metal having a resistance value lower than that of the fiber.

  The carbon is not particularly limited, and examples thereof include silicon carbide (SiC), acetylene black, and carbon nanotube. Moreover, it does not specifically limit about electroconductive materials, such as the said metal, For example, copper, silver, etc. are mentioned. As a result, the conductive agent as the particles 13 can be heat-sealed to the brush bristles 12 without a binder, and compared with a conventional charge control brush using conductive fibers in which the conductive agent is kneaded at the spinning stage. The resistance value can be further reduced. As a result, it is possible to inject charges into a cleaning object such as toner that adheres firmly due to electrostatic charge or the like, remove the charge, and weaken the adhesion of toner or the like. In addition, charging of the charged object itself can be removed with high efficiency. Furthermore, the charge polarity of the toner remaining on the photoreceptor after transfer can be made to have a more uniform charge distribution. That is, by using the brush 10 as a charge control brush, a product having excellent charge controllability can be obtained.

  Thus, the electrophotographic apparatus according to the present embodiment is provided with at least one of the brush 10 according to the first embodiment, the cleaning brush 22 according to the present embodiment, or the charging control brush. Can do.

(Embodiment 3)
The following will describe another embodiment of the present invention with reference to FIGS. The configurations other than those described in the present embodiment are the same as those in the first and second embodiments. For convenience of explanation, members having the same functions as those shown in the drawings of Embodiments 1 and 2 are given the same reference numerals, and descriptions thereof are omitted.

In the present embodiment, a case where the brush 10 described in the first embodiment is applied to a harmful substance removal filter and a chemical substance processing system will be described.
As shown in FIGS. 5 (a) and 5 (b), the harmful substance removing filter 40 of the present embodiment has a tubular structure 41 and a pile 42a raised in a brush hair shape on the inner wall surface 41a. It consists of a harmful substance removal module 42 having a harmful substance removal function. 5 (a) and 5 (b), the chemical substance processing system of the present embodiment is configured by a single harmful substance removal filter 40. However, the present invention is not limited to this embodiment, and may include at least one brush 10 or a plurality of harmful substance removing filters 40.

  The said cylindrical structure 41 becomes a base | substrate for planting the harmful substance removal module 42 directly, and is circular as shown in FIG.5 (b). Moreover, the cylindrical structure 41 is comprised as a ground thread which consists of warp and weft. Therefore, in the present embodiment, the harmful substance removal module 42 is composed of a pile that is directly woven into the tubular structure 41 that is the ground yarn. The tip of the pile is cut, for example, but may be formed in a loop shape without being cut. Note that the raising method of the harmful substance removal module 42 is not necessarily limited to this. For example, the harmful substance removal module 42 may be electrostatically flocked on a base material, or a flexible base material such as a film may be used. It may be the one in which the harmful substance removing module 42 is implanted.

The cross-sectional shape of the cylindrical structure 41 is not limited to a circular shape, and may be, for example, an ellipse, a polygon such as a triangle, a quadrangle, a pentagon, or the like, or any other cross-sectional shape. May be. For example, as a case where the cross section is a quadrangular shape, there is a cylindrical structure 41 as shown in FIG. In this case, for example, the harmful substance removal module 42 may be raised on the floor surface and the ceiling surface of the inner wall surface 41a of the tubular structure 41, respectively. FIG. 6 shows a substrate 43 in which a harmful substance removal module 42 is implanted. The dimensions of the cylindrical component 41 of the harmful substance removal filter 40 shown in FIG. 6 are, for example, an inner width W of 50 mm, an inner height H of, for example, 50 mm, and a tube length L of 30 mm. ing. Moreover, the pile length d which is the raising length of the harmful substance removal module 42 is, for example, 15 mm, respectively. Here, the dimension etc. of the cylindrical structure 41 are not necessarily restricted to this. For example, the area of the opening in the tubular structure 41 is 10 mm ² to 10 m ² , the fiber length of the harmful substance removal module 42 is 0.5 mm to 30 cm, and harmful substances are removed in the cylinder of the tubular structure 41. The volume occupancy of the module 42 is preferably 0.01% to 40%.

Thus, the cylindrical structure 41 according to the present embodiment can have a circular cross-section with a diameter of about 3 mm or a square with a side of about 3 m, and as a result, a water pipe And can be applied to large exhaust ducts. In addition, the area of the opening part of the cylindrical structure 41 is preferably within a range of 50 mm ^{2 to 1} m ² (a square cross section having a diameter of 1 cm to a side of 30 cm). The fiber length of the harmful substance removal module 42 is preferably in the range of 0.5 mm to 5 cm.

  When manufacturing the harmful substance removing filter 40 having the above-described configuration, for example, a plate-like ground yarn woven with piles may be rounded into a cylindrical shape, and both ends of the plate may be bonded with an adhesive or the like. It can also be manufactured by winding a belt-like ground yarn in which a pile is woven in a spiral shape so as to form a cylinder and adhering both side ends of the belt with an adhesive or the like. Further, in order to reinforce the strength, it is also possible to bond the sheet from the outside of the cylinder after rounding it into a cylindrical shape and bonding both ends. Thereby, the harmful substance removal module 42 brushed indirectly on the inner wall surface 41a of the tubular structure 41 in a brush shape is obtained.

  Moreover, as the cylindrical structure 41, as shown in FIG. 7, what consists of a flexible material which enables the bending | flexion in arbitrary positions can also be used. Thereby, a turbulent flow can be generated when the gas or liquid is passed through the cylindrical structure 41, and the frequency of contact with the harmful substance removal module 42 is increased. As a result, the harmful substance removal effect can be improved. The bent shape of the cylindrical structure 41 is not particularly limited as long as it is within a range that does not hinder the passage of gas or the like, and can be an arbitrary shape.

  As shown in FIGS. 5 (a) and 5 (b), the harmful substance removal module 42 includes a pile 42a made of synthetic fiber and fine particles 42b having a harmful substance removal function thermally fused to the pile 42a. . The harmful substance removal module 42 provides not only dust removal by the sieve function in the pile 42a but also a function as a chemical filter by thermally fusing the fine particles 42b having a harmful substance removal function to the pile 42a. The fine particles 42b are heat-sealed so that at least a part thereof is exposed from the sheath portion of the pile 42a (however, the fine particles 42b embedded in the sheath portion may exist). For this reason, when the gas or liquid containing a harmful substance passes between the piles 42a brushed in a brush shape, the harmful substance can be easily brought into contact with the fine particles 42b. In this way, the fine particles 42b are thermally fused to the pile 42a without using a binder. For example, when a harmful substance is passed between the piles 42a, the fine particles 42b are finer than those coated on a plane. Since the surface area of 42b is remarkably increased, the contact area can be increased. As a result, the adsorption or decomposition efficiency of harmful substances is significantly improved. The pile 42 a corresponds to the bristles 12 in the first embodiment, the fine particles 42 b correspond to the particles 13, and the inner wall surface 41 a corresponds to the base material 11.

  As in the case of the brush hair 12, the pile 42a has a core-sheath structure made of a hot melt yarn in which the melting point of the sheath 12b is lower than the melting point of the core 12a. For example, a polyester resin, a polyamide resin, The synthetic fiber is at least one material selected from an acrylic resin, a fluorine resin, and a polypropylene resin. Thereby, a flexible polymer fiber can be selected.

  Moreover, the diameter (fiber diameter) of the pile 42a is preferably within a range of 3 μm to 70 μm (in terms of fineness, 0.1 dtex) to 30 dtex (dtex)), and is preferably 10 μm to 50 μm (in terms of fineness, 1 dtex). Within the range of -15 decitex (dtex) is more preferred. By making the diameter of the pile 42a 3 μm or more, the harmful substance removal module 42 can be manufactured. On the other hand, when the diameter of the pile 42a is 70 μm or less, the surface area can be remarkably increased, and the harmful substance removal efficiency can be increased. This is because the surface area of the pile 42a increases in inverse proportion to the fiber diameter.

  The length of the pile 42a is not particularly limited, and may be set as necessary depending on the size of the cylindrical structure 41. In the present embodiment, the length of the pile 42 a is set so that the space 44 is formed at the center of the harmful substance removal module 42. By providing the space 44 in this manner, resistance to the fluid passing through the inside of the harmful substance removal module 42 can be suppressed, and pressure loss can be reduced. That is, with the configuration of the present embodiment, it is possible to efficiently remove harmful substances while reducing the pressure loss while increasing the contact area with the harmful substance removing substance as much as possible. However, the present invention is not limited to such a mode, and the pile 42a has such a length that it reaches the center of the harmful substance removal module 42 so that the space 44 is not substantially formed. It may be a mode.

  The volume occupancy of the pile 42a in the harmful substance removal module 42 is not particularly limited, but is in the range of 0.01% to 40% (that is, the volume occupancy of the space 44 is 99.99% to 60%). The inside is preferable. By making the volume occupation ratio 0.01% or more, it is possible to prevent the contact area with the hazardous substance removing substance from being lowered. On the other hand, by setting the volume occupation ratio to 40% or less, it is possible to prevent the deterioration of air permeability and to prevent the pressure loss from becoming too large. That is, by setting the value within the above numerical range, it is possible to provide a harmful substance removal filter 40 that has a wide contact area with a hazardous substance removing substance and that can reduce pressure loss and efficiently remove harmful substances. .

  The fine particles 42b having the function of removing harmful substances are preferably those that perform at least one of adsorption, decomposition, and sterilization. Thereby, the harmful substance removal module 42 can exhibit various harmful substance removal functions.

  Further, it is preferable that the fine particles 42b express or improve the function of removing harmful substances by applying energy such as light, electricity or heat. Examples of the light energy include ultraviolet rays, visible light, and electromagnetic waves. In addition, the electric energy includes that by voltage application. In addition, as the fine particles 42b, a harmful substance removing function may be expressed or improved by using energy such as light, electricity or heat in combination.

  Specific examples of the fine particles 42b include at least one selected from the group consisting of a catalyst, a porous material, and a composite thereof.

Examples of the catalyst include a metal catalyst and a photocatalyst. The metal catalyst is not particularly limited. For example, platinum (Pt), silver (Ag), magnesium (Mg), gold (Au), copper (Cu), zinc (Zn), calcium (Ca), or these An oxide etc. are mentioned. These metal catalysts can be used alone or in combination of two or more. By using a metal catalyst as the fine particles 42b, gas decomposition performance corresponding to various catalysts can be exhibited. For example, platinum (Pt) contains harmful gases such as nitrogen oxide (NO _x ) and sulfur oxide (SO _x ) contained in automobile exhaust gas, non-toxic carbon dioxide (CO ₂ ) and water (H ₂ O). ) Etc. Further, when manganese dioxide (MnO ₂ ) is used, ozone resolution can be imparted. Further, as the photocatalyst is not particularly limited, for example, titanium _(TiO 2) dioxide, such as tungsten oxide (WO ₃₎ can be mentioned. These photocatalysts can be used alone or in combination of two or more. For example, when titanium dioxide (TiO ₂ ) is used as the fine particles 42b, aldehyde (HCHO), acetaldehyde (CH ₃ CHO), and other volatile organic compounds (VOC), or nitrogen oxides (NO) _x ), harmful gases such as sulfur oxide (SO _x ) can be decomposed into non-toxic carbon dioxide (CO ₂ ), water (H ₂ O), and the like. It is also possible to sterilize and sterilize E. coli and the like.

The porous material is not particularly limited, and examples thereof include activated carbon, silica gel, and zeolite. These porous materials can be used alone or in combination of two or more. In addition, by using a porous material, gas can be taken into the voids of the pores, and high gas adsorption ability and the like are obtained. As a result, for example, toluene (C ₆ H ₅ CH ₃ ), formaldehyde (HCHO), acetaldehyde (CH ₃ CHO), other volatile organic compounds (VOC), nitrogen oxides (NOx), sulfur oxidation A large number of harmful gases such as substances (SOx) can be adsorbed.

  Examples of the composite include those in which the porous material carries the catalyst on its pores or surfaces.

Next, a harmful substance removal method in the harmful substance removal filter 40 having the above-described configuration will be described.
As shown in FIG. 5A, a fluid such as a gas or a liquid containing a harmful substance is introduced from an inflow opening 40 a serving as one opening in the tubular structure 41, and is harmful in the harmful substance removal module 42. After the substance is removed, the substance is discharged from the discharge opening 40b as the other opening.

  The inner wall surface 41a of the tubular structure 41 is provided with a harmful substance removal module 42 having a function of removing a harmful substance raised in a brush shape. Therefore, the harmful substance is removed by the harmful substance removal module 42, and the harmful substance is removed. The removed gas or liquid is discharged from the discharge opening 40 b in the tubular structure 41. Therefore, the hazardous substance removing filter 40 having a simple configuration can be realized.

  The harmful substance removal filter 40 having the above-described structure has a honeycomb structure having a functional part having a high specific surface area with a very low pressure loss and not having a harmful substance removal module 42 generally used as a conventional filter. Even compared, it has a very high function. In addition, by applying the harmful substance removal filter 40 of the present embodiment to members such as pipes and tubes that are conventionally considered only as a means for transferring fluid, not only the transfer but also the effect of removing harmful substances can be obtained. It is done.

  Furthermore, when the harmful substance removal filter 40 of the present embodiment is applied to a chemical substance processing system that removes harmful substances such as an air conditioner, a clean room apparatus, a pure water apparatus, and a chemical filter, the harmful substance removal filter 40 is a fluid. It becomes a device capable of efficiently adsorbing, decomposing, and sterilizing and removing harmful substances therein, and can provide a highly functional chemical substance processing system capable of removing harmful substances. Further, if the harmful substance removal filter 40 of the present embodiment is applied to a chemical substance processing apparatus such as a chemical plant apparatus, the harmful substance removal filter 40 is a device carrying a high-quality catalyst / adsorbent, A chemical substance processing system such as a chemical plant apparatus that performs efficient chemical synthesis and purification can be provided. Thereby, the trouble of separating the product and the catalyst / adsorbent particles and the inefficiency due to insufficient surface area of the catalyst / adsorbent can be greatly improved.

  The present invention is not limited to the above-described embodiments, and various modifications can be made within the scope of the claims, and the technical means disclosed in different embodiments can be appropriately combined. Such embodiments are also included in the technical scope of the present invention.

(Measurement of average particle size)
The average (maximum) particle size of the particles to be thermally fused to the brush bristles was measured by a laser diffraction / confusion method. As a measuring apparatus, a particle size distribution measuring apparatus (manufactured by Shimadzu Corporation, trade name: SALD-7100) was used.

(Particle coverage)
The coverage of the particles exposed to the brush bristles and thermally fused was calculated as follows. That is, the height of the unevenness on the surface was measured with a laser microscope (manufactured by Keyence Corporation, trade name: VK-8700) on 10 brush bristles before heat fusing the particles. In this measurement, the brush hair height data was collected using a 100 × objective lens, and the line roughness (Ra) was measured for an arbitrary line region having a width of 100 μm in the longitudinal direction (JIS B0601: 1994). Cut-off value: 0.08 mm). The average value of the line roughness (Ra) value obtained by this measurement was used as the reference value for the line roughness (Ra) of the brush hair before heat fusion. Next, the line roughness (Ra) was measured by the same method as described above for the brush bristles after heat fusion of the particles. In this measurement result, the rate of change from the reference value of the line roughness (Ra) before heat fusion being 200% or more was used as a reference for whether or not the particles were thermally fused in this measurement region. Subsequently, this measurement was performed at an arbitrary 10 points in one brush hair, and it was confirmed how many points were thermally fused in the reference. The coverage was calculated from the ratio of this region. Further, the same measurement was performed on 100 arbitrary brush bristles after heat-sealing, and the ratio of the brush bristles whose coverage ratio satisfied the standard was calculated.

(Bending rigidity)
The bristle bending stiffness EI (E is a longitudinal elastic modulus and I is a cross-sectional secondary moment) was measured by a pressure load applied to the flat plate by the bristle bending stiffness. Specifically, a roll-shaped brush core metal was fixed to a rotating jig in an environment of a temperature of 25 ° C. and a humidity of 60% Rh. This brush was brought into contact with a glass plate having a thickness of 1 mm set on a precision balance (manufactured by Shimadzu Corporation, trade name: AUX320) so that the brush hair could bite into 1 mm. The glass flat plate was set on a precision balance so that a brush hair load corresponding to a width of 5 cm at the biting amount was applied. Further, the brush was rotated for 60 seconds at a rotation speed of 100 rpm, the load applied to the glass plate at this time was measured every second, and the pressure load of the brush hair was determined from the average value of the measured values. In addition, the measured value in the brush hair of each Example, a comparative example, and a prior art example is shown in following Table 1.

(Change rate of bending stiffness)
The rate of change in bending stiffness was calculated using the following equation after measuring the bending stiffness of the bristles before heat fusing the particles and the bending stiffness of the bristles after heat fusing as described above.
(Change rate of bending stiffness) = (Bending stiffness after thermal fusion) / (Bending stiffness before thermal fusion) × 100 (%)

Example 1
In this example, a roll brush in which a pile fabric was wound around a shaft was used as the brush (see FIG. 2). Fibers (brush hairs) used in pile fabrics are made of hydrophobic polyester with a melting point of 250 ° C. in the core and polyethylene terephthalate with a melting point of 160 ° C. (trade name “Melset”, Unitika Ltd.) Made). The diameter (fiber diameter) of the bristles was about 25 μm (fineness 5.8 dtex) and the length was 5 mm. Furthermore, the density of the bristle was 1 × 10 ⁵ filaments (F) / inch ² . In this example, using such a roll brush, a brush according to this example was produced according to the process diagram shown in FIG.

  That is, first, a dispersion liquid in which silicon carbide (SiC) having a particle size range of 3 to 8 μm and an average maximum particle size of 5 μm is dispersed at a concentration of 5% by mass in a dispersion medium composed of isopropyl alcohol (IPA). Produced. A sufficient amount of this dispersion was applied to the roll brush by brushing. Furthermore, a squeezing was applied while rotating the brush, so that the same amount of dispersion as the pile fabric wound around the shaft was attached to the brush. Next, the brush bristles coated with the dispersion were dried while splitting the fibers so that the fibers did not adhere to each other. The drying temperature at this time was 60 ° C., and the drying time was 30 minutes.

  The average maximum particle diameter of the particles is smaller than the diameter of the brush hairs. In this example, the average maximum particle diameter of the particles is 20.0% of the fiber diameter of the brush hairs (that is, the brush hairs). Within 40% or less of the fiber diameter).

  Next, the dried roll brush was placed in an oven and heated at a high temperature. The heating conditions at this time were a heating temperature of 165 ° C. and a heating time of 30 minutes. Thereby, only the sheath portion was melted by heat to fuse the particles. Thereafter, air was blown to remove particles that were not thermally fused.

  About the brush (refer Table 2) which concerns on the present Example obtained by making it above, the state of the heat-fusion of particle | grains and the state of opening of a bristle were observed using the electron microscope. The results are shown in FIGS. 8 and 9 (a). FIG. 8 is an electron micrograph showing a state in which particles are thermally fused to the bristle, and FIG. 9A is a micrograph showing a state of opening of the bristle. As can be seen from FIG. 8, it was confirmed that the surface of the bristle was covered with particles by thermal fusion. Further, as can be seen from FIG. 9 (a), it was confirmed that the adjacent brush hairs were opened without thermal fusion. In this example, the measurement of the laser microscope described above was performed at 10 points per brush hair and repeated for 100 brush hairs. The ratio of the brush hair covered by 50% or more was 100%. Met.

(Example 2)
In this example, the dispersion medium of the dispersion in Example 1 was changed to pure water, and the hair was not split when the brush hair was dried thereafter. Thus, a brush according to this example was produced (see Table 2). The state of opening of the bristle in the brush according to this example obtained in this way was observed with an electron microscope. The result is shown in FIG. FIG.9 (b) is a microscope picture showing the state of opening of a bristle. As can be seen from the figure, although there are portions where the adjacent bristle parts are heat-sealed, it is confirmed that the bristle parts are in an open state and there is no problem. In this example, the number of brush hairs having a coverage of 50% or more per brush hair was 90% of the total number.

(Example 3)
In this example, as compared with Example 1, Example 1 was different from Example 1 except that the particles were replaced with porous silica gel having an average maximum particle size of 0.1 μm, and the brush was changed as described below. Similarly, a brush according to this example was produced (see Table 2). In addition, the colored thing was used for the porous silica gel.
Moreover, as a brush, the core part is made of a hydrophobic polyester having a melting point of 250 ° C., the sheath part is made of a polyester having a melting point of 160 ° C., and the flocking density is 50 × 10 ³ filaments (F) / inch ² A planted cleaning brush was used (see FIG. 6). Moreover, the diameter (fiber diameter) of the bristle was 30 μm (fineness 8.5 dtex), and the length was 5 mm. As the particles, substantially spherical porous silica gel having both properties suitable for cleaning and gas adsorbability was used.
In the brush produced according to this example, the ratio of the brush hair whose coverage per brush hair was 50% or more was determined to be 93% of the total number.

Example 4
In this example, the brush according to this example was used in the same manner as in Example 3 except that a treatment for lowering the particle coverage after drying was performed as compared with Example 3. It produced (refer Table 2). Specifically, as a treatment for reducing the particle coverage, a brush rotated at 100 rpm was sprayed for 1 minute at a distance of 30 cm so that air adjusted to a pressure of 0.05 MPa hit the entire surface in the longitudinal direction of the brush. Moreover, about the bristle and particle | grains, the thing similar to the said Example 3 was used. In the brush produced according to this example, the ratio of the brush hair whose coverage per brush hair was 50% or more was determined to be 73% of the total number.

(Comparative Example 1)
In this comparative example, compared with Example 4, in the process for lowering the particle coverage after drying, the air blowing distance was changed from 30 cm to 10 cm in the same manner as in Example 4. Then, a brush according to this comparative example was produced (see Table 2). In the brush produced by this comparative example, when the ratio of the brush hair whose coverage per brush hair was 50% or more was determined, it was 60% of the total number (see Table 3).

(Comparative Example 2)
In this comparative example, as compared with the above-mentioned Example 4, in the treatment for lowering the particle coverage after drying, except that the air pressure was changed from 0.05 MPa to 0.1 MPa, Similarly, a brush according to this comparative example was produced (see Table 2). In the brush produced by this comparative example, when the ratio of the brush hair whose coverage per brush hair was 50% or more was determined, it was 40% of the total number (see Table 3).

(Comparative Example 3)
In this comparative example, compared with Example 3, the same procedure as in Example 3 was performed except that the concentration of the dispersion liquid in which the particles were dispersed was changed from 5% by mass to 1% by mass. Such a brush was produced (see Table 2). In the brush produced by this comparative example, when the ratio of the brush hair whose coverage per brush hair was 50% or more was determined, it was 10% of the total number (see Table 3).

(Comparative Example 4)
In this comparative example, as compared with Example 3, the comparison was made in the same manner as in Example 3 except that the concentration of the dispersion liquid in which the particles were dispersed was changed from 5% by mass to 0.5% by mass. A brush according to the example was produced (see Table 2). In the brush produced by this comparative example, when the ratio of the brush hair whose coverage per brush hair was 50% or more was determined, it was 5% of the total number (see Table 3).

(Conventional example 1)
In this conventional example, a brush according to this conventional example was produced in the same manner as in Example 3 except that the sheath portion was not melted by heat and the particles were not thermally fused to the bristles.

(Non-adhesive state between brush hairs)
For each of the brushes of Examples 3 and 4, Comparative Examples 1 to 4 and Conventional Example 1, the non-adhesion state between the brush bristles was visually observed. As a result, as shown in Table 3 below, in Examples 3 and 4, the degree of non-adhesion between the bristles is good, the adhesion between the bristles is small, and the rate of change in bending rigidity is low, so the product As a practical use. That is, as shown to Fig.10 (a), it can grasp | ascertain that particle | grains heat-seal to the whole brush hair, and each brush hair is uniformly black.

  On the other hand, in Comparative Example 1 to Comparative Example 4, as shown in FIG. 10 (b), it is observed that there is much heat fusion between the brush hairs, and a plurality of brush hairs are aggregated in a bundle shape. In addition, since the rate of change in flexural rigidity is high, it cannot be put into practical use as a product. As a result, it has been found that a state in which 70% or more of the brush hairs are covered with 50% or more of the surface area by the particles is judged to have a small thermal fusion between the brush hairs.

(Cleaning performance)
For the brushes of Examples 3 and 4, Comparative Examples 1 to 4, and Conventional Example 1, cleaning performance confirmation experiments were performed. In the experiment, image abnormalities occurred when the brush was wound around a shaft and used as a cleaning brush using each test specimen when the above-mentioned test for confirming the degree of non-thermal fusion between the brush bristles was performed. The number of printing durability until the printing was confirmed. Specifically, as shown in FIG. 11, a cleaning brush was brought into contact with the photosensitive member, an image was printed on a sheet, and the number of printing durability until an image abnormality occurred was confirmed.

  The result is shown in FIG. FIG. 12 shows the number of printing durability until image abnormality occurs in each specimen. As shown in FIG. 12, the number of printing durability until the occurrence of the image abnormality was 21,000 in Example 3 and 20000 in Example 4. On the other hand, in Comparative Example 1, it was 10,000 sheets, in Comparative Example 2, it was 6000 sheets, in Comparative Example 3, it was 7000 sheets, in Comparative Example 4, it was 6000 sheets, and in Conventional Example 1, it was 6000 sheets. As a result, in Example 3 and Example 4, it is understood that the number of printing durability until the occurrence of image abnormality in each test specimen increases compared to Comparative Examples 1 to 4 and Conventional Example 1. did it.

(Durable filter performance)
For the brushes of Examples 3 and 4, Comparative Examples 1 to 4 and Conventional Example 1, confirmation experiments were conducted for filter durability. In the experiment, each test body when the experiment for confirming the degree of non-thermal fusion between the brush bristles was performed was used as the inner wall surface of the cylindrical structure 41 having a circular shape shown in FIGS. 7 (a) and 7 (b). The harmful substance removal module 42 was affixed to 41a, and toluene gas was passed through the harmful substance removal module 42, and the concentration after ventilation was measured. Specifically, the toluene gas concentration was measured every 30 minutes after aeration, and the time until the adsorption performance decreased to 50% or less was measured.

  The result is shown in FIG. FIG. 13 shows the time required for the toluene adsorption performance of each test specimen to drop to 50% or less. As shown in FIG. 13, the time required for the toluene adsorption performance of each test specimen to drop to 50% or less was 390 hours in Example 3 and 360 hours in Example 4. On the other hand, it was 210 hours in Comparative Example 1, 150 hours in Comparative Example 2, 180 hours in Comparative Example 3, 150 hours in Comparative Example 4, and 0 hour in Conventional Example 1. As a result, in Example 3 and Example 4, compared with Comparative Examples 1-4 and Conventional Example 1, the removal performance of toluene can be maintained for a long time, and it was understood that it was excellent.

(Examples 5-7)
In Examples 5 to 7, as compared with Example 3, except that the average maximum particle size was changed to particles of 1.5 μm, 6 μm, and 12 μm, respectively, as in Example 3, A brush according to this example was produced (see Table 2). However, as shown in Table 2, the average maximum particle size of the particles is 1.5 μm (5% of the fiber diameter) in Example 5, and 6 μm (20% of the fiber diameter) in Example 6. %), And in Example 7, the average maximum particle size was 12 μm (40% of the fiber diameter). Moreover, in the brush produced by Examples 5-7, when the ratio of the brush hair whose coverage per brush hair was 50% or more was calculated | required, 100%, 85%, and 74% of the total number, respectively. Met.

(Example 8)
In this Example 8, as compared with Example 3, except that a brush hair having a sheath thickness of 1 μm was used and a particle having an average maximum particle diameter of 6 μm was used. A brush according to this example was produced in the same manner as Example 3 (see Table 2).
Example 9
In Example 9, as compared with Example 3, the same as Example 3 except that particles having an average maximum particle size of 0.02 μm were used. A brush was produced (see Table 2).

(Comparative Examples 5 and 6)
In Comparative Examples 5 and 6, compared with Example 3, the same as Example 3, except that particles having average maximum particle diameters of 18 μm and 24 μm were used. Such a brush was produced (see Table 2).

(Friction fastness and non-adhesion between brush hairs)
For the brushes of Examples 5 to 9 and Comparative Examples 5 and 6, confirmation experiments were conducted on the friction fastness of the particles thermally fused to the brush bristles. Specifically, with the amount of biting 1 mm, the brush was rotated while pressed against the white cloth, and the color transfer to the white cloth after 2 hours was visually observed.

  As a result of the experiment, as shown in FIG. 14, in Examples 5 to 7 and Example 9, there was no color transfer of the particles to the white cloth, and even in Example 8, the color transfer was slight. On the other hand, in Comparative Examples 5 and 6, there was a color transfer of particles to a white cloth. As a result, it was found that the average maximum particle size of the particles to be thermally fused to the brush bristles is preferably 40% or less of the diameter (fiber diameter) of the bristles. That is, when the average maximum particle size of the particles to be thermally fused to the bristles exceeds 40% of the diameter of the bristles as in Comparative Examples 5 and 6, color transfer of the particles to the white cloth occurs. This means that when the average maximum particle diameter of the particles exceeds 40% of the diameter, the degree of exposure of the particles from the sheath portion becomes too large, and the particles may easily peel off due to contact with the opposite object. In this regard, when the particle size of the particles to be thermally fused to the bristles is 40% or less of the diameter, even if the brush is brought into contact with the opposite object, it does not easily peel off and has high friction fastness It becomes.

  Moreover, about the non-adhesion state of brush bristles, as shown in the following Table 4, in Examples 5-9, there is some good or bad, but the non-adhesion between the brush bristles is seen from the rate of change in bending rigidity. The degree of was generally good, the adhesion between the brush hairs was small, and the rate of change was low, so that it was practically usable as a product. On the other hand, in Comparative Examples 5 and 6, it was observed that there was much thermal fusion between the brush hairs, and a plurality of brush hairs were aggregated in a bundle, and the rate of change was high, making it practical for use as a product. Was unbearable.

(Examples 10 and 11)
In Examples 10 and 11, as compared with Example 5, the present example was the same as Example 5 except that the dispersion medium of the dispersion was changed as shown in Table 5 below. The brush which concerns on was produced.

(Evaluation regarding the type of dispersion medium)
As in Examples 5 and 10, when a solvent having a surface tension smaller than that of water is used as the dispersion medium, the brush hair is easily opened in the brush hair drying process, and the efficiency of the opening is improved. I was able to. As a result, it was confirmed that thermal fusion between the brush bristles can be further prevented and the rate of change in bending rigidity can be reduced.

(Comparative Example 7)
In this comparative example, as compared with Example 5, the brush bristles were made of PET without a sheath and the particles were fixed to the bristles. ), Trade name: Nichigo Polyester). Other than that was carried out similarly to Example 5, and produced the brush which concerns on this comparative example (refer Table 6). That is, a dispersion was prepared by blending the binder so that its concentration was 2% by mass relative to the total mass, and this dispersion was applied to the brush hair. Thereafter, the particles were dried to adhere the particles to the brush hair.

(Comparative Example 8)
In this comparative example, as compared with Example 5, the particles were heated and fixed to the brush bristles as a method of fixing the particles to the bristles. Other than that was carried out similarly to Example 5, and produced the brush which concerns on this comparative example (refer Table 6). That is, particles made of alumina were placed in a petri dish and the particles were heated to 165 ° C. Next, the bristle in Example 1 was put in this petri dish, the petri dish was covered, held in the hand, shaken up and down five times, and then the bristle with the particles fixed thereon was quickly taken out. Next, the particles that did not adhere were washed with water to obtain the bristles according to this comparative example.

(Comparative Example 9)
In this comparative example, as compared with Example 5 described above, a hydrophilic fiber made of polyvinyl alcohol was used as the brush hair, and the hydrothermal treatment was performed as a method of heat fusing the particles. A brush according to this comparative example was produced in the same manner as in Example 5 (see Table 6). That is, after applying the bristles to the dispersion, the particles were adhered by drying at 70 ° C. Next, the brush bristles with the particles attached thereto were put into hot water heated to 95 ° C., treated with hot water for 20 minutes, and dried.

(Evaluation on fixing method)
As can be seen from Table 6 below, in Comparative Examples 7 to 9, the brush bristles in which the coverage by exposed and heat-sealed particles was 50% or more were 40%, 0%, respectively, 30%. In Comparative Example 9, crimp shrinkage occurred in the brush hair because the hot water treatment was performed when the particles were attached to the brush hair.

  On the other hand, the brush bristles of Example 5 did not cause crimp shrinkage because no hot water treatment was performed. Further, even when hydrophobic synthetic fibers were used as the brush hair, the brush hair whose coverage by exposed and heat-sealed particles was 50% or more was 100% of the total number.

  Moreover, about Example 5 and Comparative Examples 7-9, the confirmation experiment about the friction fastness similar to the above was also conducted. As a result, as shown in Table 6, in Example 1, there was no color transfer of the particles to the white cloth. In contrast, in Comparative Examples 7 to 9, there was a color transfer of the particles to the white cloth.

  A brush obtained by thermally fusing particles to the brush hair of the present invention includes a cleaning brush, a charging control brush, a harmful substance removing brush, a brush manufacturing method, a cleaning system, an electrophotographic apparatus, a harmful substance removing system, and a chemical. Applicable to material processing systems. It can also be applied to electromagnetic shielding. This is because, when the conductor is heat-sealed, a brush and pile fabric having a very low resistance value can be manufactured and has a characteristic structure.

1 Photoconductor drum (photoconductor)
2 Charging device 4 Developing device 10 Brush 11 Base material 12 Brush hair 12a Core portion 12b Sheath portion 13 Particle 14 Shaft 20 Cleaning device (cleaning system)
22 Cleaning brush 22a Brush hair 22b Base material 22c Roller 23 Conductive roller 24 Cleaning member 30 Image forming unit 40 Filter for removing harmful substances (hazardous substance removing system, chemical substance processing system)
41 Tubular structure 41a Inner wall surface 42 Hazardous substance removal module 42a Pile 42b Fine particles (particles)

Claims (9)

A brush having brush hair made of synthetic fiber,
The brush bristles comprise at least one synthetic fiber selected from the group consisting of polyester resins, polyamide resins, acrylic resins, fluorine resins and polypropylene resins,
And having a core-sheath structure having a core and a sheath having a melting point lower than that of the core,
At least a part of the particles having an average maximum diameter of 40% or less of the fiber diameter of the bristle is thermally fused so that at least part of the sheath part is exposed from the sheath part by thermal melting of the sheath part. Worn,
In the total number of 70% or more bristles to the bristle coverage due to exposure to heat-sealed particles Ri der least 50%,
Flexural rigidity of bristles wherein the particles are heat-sealed to the sheath portion, the brush characterized by 5-fold der Rukoto less with respect to the bending stiffness of the bristles before thermal fusion of the particles.   The brush according to claim 1, wherein the synthetic fiber is made of a hydrophobic resin having a melting point of 100 ° C. or higher. The particles brush according to claim 1 or 2, characterized in Rukoto a different one or more inorganic materials or polymeric material and the synthetic fibers. The particles, said carbon having a low electrical resistance than the synthetic fibers, the brush of claim 3, wherein at least one Tanedea Rukoto selected from the group consisting of metal and a conductive polymer material. The brush according to claim 3 , wherein the particles are at least one selected from the group consisting of a catalyst, a porous material, and a composite thereof. It is a manufacturing method of the brush which manufactures the brush in any one of Claims 1-5,
An attachment step of bringing the particles into contact with the bristles by contacting a dispersion liquid in which the particles are dispersed in a dispersion medium having a surface tension smaller than that of water; and
After the attaching step, a drying step of drying the brush hairs so that the brush hairs are in an open state,
The brush hair in the opened state is heated at a temperature higher than the melting point of the sheath part and lower than the melting point of the core part and the particles to thermally melt the sheath part. A heat fusion step of heat-sealing the particles to at least a part of the sheath in a state exposed from the sheath, and preventing the adjacent bristles from being heat-sealed . Lube brush method of manufacturing. Cleaning system characterized in that it comprises a brush according to any one of claims 1-5. Chemical processing system characterized that you have provided a brush according to any one of claims 1 to 5. An electrophotographic apparatus comprising the brush according to any one of claims 1 to 5 .

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