JP4931578B2 - Repellent method and repellent for rats - Google Patents
Repellent method and repellent for rats Download PDFInfo
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- JP4931578B2 JP4931578B2 JP2006355015A JP2006355015A JP4931578B2 JP 4931578 B2 JP4931578 B2 JP 4931578B2 JP 2006355015 A JP2006355015 A JP 2006355015A JP 2006355015 A JP2006355015 A JP 2006355015A JP 4931578 B2 JP4931578 B2 JP 4931578B2
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- 230000002940 repellent Effects 0.000 title claims description 25
- 239000005871 repellent Substances 0.000 title claims description 25
- 241000700159 Rattus Species 0.000 title claims description 10
- 238000000034 method Methods 0.000 title description 13
- 239000000779 smoke Substances 0.000 claims description 55
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical group NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 24
- 239000004156 Azodicarbonamide Substances 0.000 claims description 23
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 23
- 241000699670 Mus sp. Species 0.000 claims description 12
- 239000000428 dust Substances 0.000 claims description 10
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 5
- 241000699666 Mus <mouse, genus> Species 0.000 description 9
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- 230000000694 effects Effects 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 6
- 230000001846 repelling effect Effects 0.000 description 6
- 235000006679 Mentha X verticillata Nutrition 0.000 description 5
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- 238000005192 partition Methods 0.000 description 5
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- 241000607479 Yersinia pestis Species 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
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- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
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- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
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- 239000004509 smoke generator Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
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- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
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- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 description 1
- 239000001605 (5-methyl-2-propan-2-ylcyclohexyl) acetate Substances 0.000 description 1
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- OMOVVBIIQSXZSZ-UHFFFAOYSA-N [6-(4-acetyloxy-5,9a-dimethyl-2,7-dioxo-4,5a,6,9-tetrahydro-3h-pyrano[3,4-b]oxepin-5-yl)-5-formyloxy-3-(furan-3-yl)-3a-methyl-7-methylidene-1a,2,3,4,5,6-hexahydroindeno[1,7a-b]oxiren-4-yl] 2-hydroxy-3-methylpentanoate Chemical compound CC12C(OC(=O)C(O)C(C)CC)C(OC=O)C(C3(C)C(CC(=O)OC4(C)COC(=O)CC43)OC(C)=O)C(=C)C32OC3CC1C=1C=COC=1 OMOVVBIIQSXZSZ-UHFFFAOYSA-N 0.000 description 1
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- WUOACPNHFRMFPN-UHFFFAOYSA-N alpha-terpineol Chemical compound CC1=CCC(C(C)(C)O)CC1 WUOACPNHFRMFPN-UHFFFAOYSA-N 0.000 description 1
- KHPLPBHMTCTCHA-UHFFFAOYSA-N ammonium chlorate Chemical compound N.OCl(=O)=O KHPLPBHMTCTCHA-UHFFFAOYSA-N 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
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- SQIFACVGCPWBQZ-UHFFFAOYSA-N delta-terpineol Natural products CC(C)(O)C1CCC(=C)CC1 SQIFACVGCPWBQZ-UHFFFAOYSA-N 0.000 description 1
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- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
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- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
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- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は、煙を用いたネズミの忌避方法及び忌避用剤に関する。 The present invention relates to a method for repelling rats using smoke and a repellent .
従来、ネズミが食品や壁材、電線ケーブル等を齧ることによる被害が問題となっており、それを防止するために種々の殺鼠剤や忌避剤が検討されてきた。しかし、殺鼠剤や忌避剤が処理された箇所でしか所期の効果を得ることができず、室内、倉庫、床下等の広い空間からネズミを追い出すことは難しい。 Conventionally, the damage caused by rats scolding food, wall materials, electric cables and the like has been a problem, and various rodenticides and repellents have been studied to prevent such damage. However, the desired effect can be obtained only at the place where the rodenticide or repellent is treated, and it is difficult to expel the mouse from a wide space such as a room, a warehouse, or under the floor.
また、従来から、煙により獣害虫を忌避することが検討されている。例えば、木粉や澱粉等からなる成形物に着火し、発煙せしめて鳥類を忌避すること(特許文献1参照。)、害虫の生息場所を燻煙して、害虫を追い出し、設置した粘着材で捕獲、駆除すること(特許文献2参照。)等が知られている。
しかし鳥類や害虫とネズミとは習性、行動、さらに刺激に対する反応等も異なるうえ、上記文献にはネズミに適用することについて記載はない。
そしてネズミについては、煙を利用した忌避方法について検討されてはおらず、タール等の煙成分の匂いを持つものを部材に含浸させたもの(特許文献3参照。)が知られている程度である。
Conventionally, it has been studied to avoid animal pests with smoke. For example, ignite a molded product made of wood powder, starch, etc., smoke it to avoid birds (see Patent Document 1), smoke the pest habitat, expel the pest, and use the adhesive material installed Capture and extermination (see Patent Document 2) and the like are known.
However, birds, pests, and rats differ in habits, behaviors, responses to stimuli, etc., and the above document does not describe application to mice.
And about the mouse | mouth, the repelling method using smoke is not examined, but what impregnates the member with the smell of smoke components, such as tar (refer patent document 3) is a grade known. .
そこで本発明では、所詮、忌避剤を用いなくてもネズミに対し強い忌避効果を発揮する、煙を用いたネズミの忌避方法及び忌避用剤を提供するものである。 Therefore, in the present invention, after all, to exhibit a strong repellent effect on rats without using a repellent, and provides a repelling methods and repelling agent murine using smoke.
本発明者らは、上記課題を解決するために鋭意検討した結果、忌避剤を含有しない、アゾジカルボンアミドが熱分解して発生する煙を有効成分とし、前記煙を、床面からの高さが10〜30cmにおいて、デジタル粉じん計で測定した1分間の平均粉塵量が45cpm以上の煙量となるように発生させることを特徴とするネズミの忌避方法を見出し本発明に至った。
さらに、本発明は、アゾジカルボンアミドを含有し、忌避剤を含有せず、加熱により熱分解した際にネズミを忌避する有効成分となる煙を発生し、その煙が45cpm以上の煙量を発生するものであることを特徴とするネズミの忌避用剤を提供するものである。
As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention have , as an active ingredient, smoke generated by thermal decomposition of azodicarbonamide , which does not contain a repellent, and the smoke has a height from the floor surface. but in 10 to 30 cm, the average amount of dust per minute was measured with a digital dust meter reaches the heading invention repellency method murine, characterized in that to generate such a more smoke volume 45 cpm.
Furthermore, the present invention contains azodicarbonamide, does not contain a repellent, and generates smoke as an active ingredient that repels rats when thermally decomposed by heating, and the smoke generates a smoke amount of 45 cpm or more. It is intended to provide a mouse repellent characterized by the above.
本発明によれば、忌避剤を用いなくてもアゾジカルボンアミドが熱分解して発生する煙だけで、かつ45cpm以上の煙量をもつときにネズミに対して強い忌避効果を発揮することができる。 According to the present invention, to exert a strong repellent effect against murine when azodicarbonamide without using the memorial避剤is only smoke produced by thermal decomposition and having a smoke of more than 45cpm it can.
本発明のネズミの忌避方法は、アゾジカルボンアミドが熱分解して発生する煙を有効成分とし、前記煙を45cpm以上、好ましくは100cpm以上、より好ましくは200cpm以上の煙量となるように拡散させることで、所謂、忌避剤を用いなくてもネズミを忌避することができる。特に、前記煙量をネズミに直接暴露させることが好ましい。これによって、ネズミを確実に忌避(追い出す)することができる。 The method for avoiding a rat according to the present invention uses smoke generated by thermal decomposition of azodicarbonamide as an active ingredient, and diffuses the smoke so as to have a smoke amount of 45 cpm or more, preferably 100 cpm or more, more preferably 200 cpm or more. Thus, mice can be repelled without using a so-called repellent. In particular, it is preferable to directly expose the smoke amount to mice. This can surely avoid (purge) the rat.
アゾジカルボンアミドとしては、200℃前後で熱分解して煙を発生するものが好ましく、例えば、ユニフォームAZ(大塚化学社製)、セルマイクCE(三協化成)等が挙げられる。 As the azodicarbonamide, those that thermally decompose at around 200 ° C. to generate smoke are preferable, and examples thereof include Uniform AZ (manufactured by Otsuka Chemical Co., Ltd.), Cellmic CE (Sankyo Kasei) and the like.
本発明における煙量とは、屋内、倉庫、床下等における床面からの高さが10〜30cm付近において、デジタル粉じん計で測定した1分間の平均粉塵量(cpm)を意味し、具体的には、例えば、デジタルダストインジケーター モデル P−3(柴田化学社製)により測定することができる。
本発明においては、例えば、煙の発生から30分間、任意の間隔で複数回の測定を行い、その平均値を煙量とする。
本発明のネズミの忌避方法及び忌避用剤では、アゾジカルボンアミドを熱分解して発生する煙を所定の煙量発生させるには、20〜50m3に対して0.2g以上、好ましくは1〜30gを用いればよい。
The smoke amount in the present invention means an average dust amount (cpm) measured for 1 minute with a digital dust meter when the height from the floor surface is about 10 to 30 cm indoors, in a warehouse, under the floor, etc. Can be measured by, for example, a digital dust indicator model P-3 (manufactured by Shibata Chemical Co., Ltd.).
In the present invention, for example, measurement is performed a plurality of times at arbitrary intervals for 30 minutes from the generation of smoke, and the average value is defined as the amount of smoke.
In repelling methods and repelling agent of murine present invention, azodicarbonamide to generate a predetermined smoke amount smoke generated by thermal decomposition, 0.2 g or more with respect to 20 to 50 m 3, preferably 1 to 30 g may be used.
また以下の図1に示すような二重容器を用いた装置等では、容器を加熱するだけでも煙が多少発生するので、アゾジカルボンアミドを熱分解して発生する煙の煙量としては、アゾジカルボンアミドが容器内にある時と、ない時とで煙量をそれぞれ測定し、その差をアゾジカルボンアミドを熱分解して発生する煙の煙量とするものである。 In addition, in an apparatus using a double container as shown in FIG. 1 below, smoke is slightly generated just by heating the container. Therefore, the amount of smoke generated by thermally decomposing azodicarbonamide is azo The amount of smoke is measured when dicarbonamide is present in the container and when it is not present, and the difference is defined as the amount of smoke generated by thermally decomposing azodicarbonamide.
本発明のネズミの忌避方法においてアゾジカルボンアミドの熱分解は、例えば、アゾジカルボンアミドを図1に示した発煙装置の容器に収容し、該容器の外側に配置された加熱手段により加熱することにより行うことができる。 In the murine repellent method of the present invention, the thermal decomposition of azodicarbonamide is carried out by, for example, storing azodicarbonamide in the container of the smoke generator shown in FIG. 1 and heating it by heating means arranged outside the container. It can be carried out.
容器としては、例えば、プラスチック容器、紙容器、金属容器、セラミック容器、ガラス容器等が挙げられる。また、加熱手段としては、例えば、酸化カルシウム、酸化マグネシウム、塩化マグネシウム、塩化アルミニウム、塩化カルシウム、塩化鉄等の加水発熱物質と水との反応を用いる加水発熱方式(図1参照)、炭化鉄、鉄粉と塩素酸アンモニウムの混合物、鉄と硫酸カリウムとの混合物等の酸化反応により発熱する金属類を用いる空気酸化発熱方式、ニクロム線、正特性サーミスタ、半導体ヒータ等のヒータを用いる電気加熱方式、白金触媒方式等が挙げられる。 Examples of the container include a plastic container, a paper container, a metal container, a ceramic container, and a glass container. In addition, as a heating means, for example, a hydrothermal exothermic method using a reaction between a hydrothermal exothermic substance such as calcium oxide, magnesium oxide, magnesium chloride, aluminum chloride, calcium chloride, iron chloride and water (see FIG. 1), iron carbide, Air oxidation heat generation method using metals that generate heat due to oxidation reaction such as a mixture of iron powder and ammonium chlorate, a mixture of iron and potassium sulfate, electric heating method using heaters such as nichrome wire, positive temperature coefficient thermistor, semiconductor heater, A platinum catalyst system etc. are mentioned.
図示される発煙装置1は、有底円筒状の外容器2を備えており、その底部から側部にかけて加水発熱物質Aが収容されている。また、外容器2の内部は、仕切部材4により2つの空間に区画されている。外容器2は、底部に複数の通水孔を有し、通水孔は通水性を有する部材、例えば不織布シート3によって塞がれている。使用に際して、発煙装置1を水Wが入った容器20に入れることにより、水Wが通水孔を通じて外容器2に流入し、更に不織布シート3を浸透して加水発熱物質Aと接触し、そのとき発生した反応熱によりアゾジカルボンアミドBが加熱されて分解し、発生した煙が熱溶融フィルム7の通気孔や蓋部材6の開口部を通じて外部(室内等)に放出される。
The illustrated smoke generating apparatus 1 includes a cylindrical outer container 2 with a bottom, and a hydrothermal exothermic substance A is accommodated from the bottom to the side. Further, the inside of the outer container 2 is partitioned into two spaces by a partition member 4. The outer container 2 has a plurality of water holes at the bottom, and the water holes are closed by a member having water permeability, for example, a nonwoven fabric sheet 3. In use, the smoke generator 1 is placed in a
このような装置をネズミの生息、活動場所に置いたり、屋根裏や床下等の狭い場所では、別の場所で発生させた煙をパイプ等で供給して用いることができる。 Such a device can be placed in a place where a mouse lives or is active, or in a narrow place such as an attic or under the floor, smoke generated in another place can be supplied by a pipe or the like.
本発明のネズミの忌避方法及び忌避用剤は、忌避剤を用いなくてもアゾジカルボンアミドが熱分解して発生する煙だけで、その所定の煙量により十分にネズミの忌避効果を発揮するものである。また、必要に応じてネズミに対して香料や消臭剤等を併用することもできる。 The mouse repellent method and repellent of the present invention is a smoke that is generated by thermal decomposition of azodicarbonamide without using a repellent, and exhibits a repellent effect of the mouse sufficiently by the predetermined amount of smoke. It is . Moreover, a fragrance | flavor, a deodorizing agent, etc. can also be used together with respect to a mouse | mouth as needed .
以下に実施例によって本発明をさらに詳しく説明するが、本発明はこれらに限定されるものではない。
〔試験例1〕
図2に示した試験装置を用いて、以下のとおりに本発明の忌避方法によるネズミの忌避効果を確認した。
A室(縦3m、横4.5m、高さ2.5m)にバット(縦1m、横1.5m、高さ1m)を設置した。つぎにB室(縦3m、横4.5m、高さ2.5m)にケージ(縦40cm、横25cm、高さ20cm)を設置した。そしてバットとケージの間を壁を貫通するパイプ(直径7.5cm、長さ50cm)で繋ぎ、ネズミが自由に移動できるようにした。
さらにA室は部屋を暗くし、B室のケージは300Wの照明で照射した(ネズミは光を嫌うので、通常であれば、B室へは侵入しない条件とした)。そしてA室にネズミ5頭(マウス)を放してB室側を観察した。
A室の床面に設置した、表1に記載の試験検体から煙を発生させ、30分間にわたりB室へ侵入したネズミの数を忌避されたネズミの数として計数し、更に、その時の滞在時間を観察した。尚、B室へ侵入してA室へ戻ったネズミは、再度B室へ移動したとき同様に計数した。
試験検体としては、実施例1〜3は、表1に記載の量(薬量)のアゾジカルボンアミドを発煙装置の仕切部材内に収納し、該仕切部材外側に位置するように外容器内に酸化カルシウム65gを収納し、水を加えて約300℃に発熱させて加熱し、アゾジカルボンアミドを熱分解させて煙を発生させた。
比較例1は、表1に記載の量(薬量)の市販の燻煙剤であるニトロセルロースを容器に収納し、着火することで煙を発生させた。
コントロールは、実施例の仕切部材内にアゾジカルボンアミドを収納せず、空の状態で酸化カルシウムにより実施例1と同様の方法で加熱した。
EXAMPLES The present invention will be described in more detail with reference to examples below, but the present invention is not limited to these examples.
[Test Example 1]
Using the test apparatus shown in FIG. 2, the repellent effect of mice by the repellent method of the present invention was confirmed as follows.
A bat (length 1 m, width 1.5 m, height 1 m) was installed in Room A (length 3 m, width 4.5 m, height 2.5 m). Next, a cage (length 40 cm, width 25 cm,
Furthermore, the room A was darkened and the cage of the room B was irradiated with 300 W illumination (mice don't like light, so the condition was that they would normally not enter the room B). Then, 5 mice (mouse) were released in the A room and the B room side was observed.
Smoke was generated from the test specimens listed in Table 1 installed on the floor of Room A, and the number of mice that entered Room B over 30 minutes was counted as the number of mice evaded, and the residence time at that time Was observed. The mice that entered the B room and returned to the A room were counted in the same manner when they moved to the B room again.
The test specimens, Examples 1 to 3, housed in a partition member of the smoke apparatus azodicarbonamide amounts described (dose) Table 1, the outer container so as to be located outside the partition member Storing 65 g of calcium oxide, adding water to generate heat at about 300 ° C. and heating, pyrolyzing azodicarbonamide to generate smoke.
In Comparative Example 1, nitrocellulose, which is a commercially available smoke agent in the amount (dose amount) shown in Table 1, was stored in a container and ignited to generate smoke.
As a control, azodicarbonamide was not housed in the partition member of the example, and heated in the same manner as in Example 1 with calcium oxide in an empty state.
試験の結果は、表1に示した。
アゾジカルボンアミドを用いた実施例1〜3では薬量の増加に従い、忌避されたネズミの合計値が増加している。また、0.2gの使用量でもコントロールと比べ明らかな差を認めた。比較例であるニトロセルロースを用いた場合はコントロールと比べ大きな差はなかった。
The test results are shown in Table 1.
In Examples 1 to 3 using azodicarbonamide, the total value of the repelled mice increases as the dosage increases. Further, even when the amount used was 0.2 g, a clear difference was recognized as compared with the control. When the nitrocellulose which is a comparative example was used, there was no big difference compared with control.
〔試験例2〕
試験例1で用いた、実施例1と2、比較例1、コントロールについて、デジタルダストインジケーター モデル P−3(柴田化学社製)により煙量を測定した。
煙量の測定は、試験例1のA室の床面に各検体を置いて煙を発生させ、煙の発生から30分間、5分間隔で煙量を測定し、その平均値を求めた。
測定の結果、コントロールであっても容器が加熱されることで、平均粉塵量として約309cpmがあった。そこで実施例1と2、比較例1の平均粉塵量について、コントロールの値を差し引いて補正しその値を表2に記載した。
試験の結果は表2に示した。アゾジカルボンアミドを用いた場合は、使用量にほぼ比例する煙量であった。比較例のニトロセルロースを用いた場合の煙量はアゾジカルボンアミドを用いた場合に比べ、約7倍であった。
この結果から、煙量が多ければよいわけではなく、アゾジカルボンアミドを熱分解して発生する煙が、比較例と比べて少ない煙量でネズミの忌避に有効であることがわかる。
[Test Example 2]
For Examples 1 and 2, Comparative Example 1, and Control used in Test Example 1, the amount of smoke was measured with a digital dust indicator model P-3 (manufactured by Shibata Chemical Co., Ltd.).
The smoke amount was measured by placing each specimen on the floor surface of the room A of Test Example 1 to generate smoke, measuring the smoke amount at intervals of 5 minutes for 30 minutes from the generation of smoke, and obtaining the average value.
As a result of the measurement, even if it was a control, the container was heated, and the average amount of dust was about 309 cpm. Therefore, the average dust amounts of Examples 1 and 2 and Comparative Example 1 were corrected by subtracting the control value, and the value is shown in Table 2.
The test results are shown in Table 2. When azodicarbonamide was used, the amount of smoke was almost proportional to the amount used. The amount of smoke when the nitrocellulose of the comparative example was used was about 7 times that when azodicarbonamide was used.
From this result, it is understood that the amount of smoke is not necessarily large, and smoke generated by thermal decomposition of azodicarbonamide is effective in avoiding rats with a small amount of smoke as compared with the comparative example.
〔試験例3〕
実施例3の検体に加えて、ハッカ油10%(参考例1)、ハッカ油10%と精油類2%(参考例2)、ハッカ油8%と精油類4%(参考例3)を配合した試験検体を製造し、試験例1と同様に試験を行いネズミの忌避効果を確認した。
精油類は、ローズマリーオイル40%、テルピネオール10%、テルピネン10%、P−シメン10%、ヘキシルアセテート5%を含むオイルである。
ハッカ油は、l−メントール40%、酢酸メンチル20%を含むオイルである。
試験の結果は、表3に示した。ハッカ油を配合した場合(参考例1)とハッカ油に精油類2%を配合した場合(参考例2)では、忌避効果に差は認められなかった。精油類の添加量を増やした場合(参考例3)は、明らかな忌避効果の向上が認められた。
[Test Example 3]
In addition to the sample of Example 3,
The essential oils are oils containing 40% rosemary oil, 10% terpineol, 10% terpinene, 10% P-cymene and 5% hexyl acetate.
Mentha oil is an oil containing 40% l-menthol and 20% menthyl acetate.
The test results are shown in Table 3. When mint oil was blended ( Reference Example 1 ) and when mint oil was blended with 2% essential oils ( Reference Example 2 ), there was no difference in repellent effect. When the amount of essential oil added was increased ( Reference Example 3 ), a clear improvement in repellent effect was observed.
1 発煙装置
2 外容器
3 不織布シート
4 仕切部材
6 蓋部材
7 熱溶融フィルム
20 容器
A 加水発熱物質
B アゾジカルボンアミド
W 水
DESCRIPTION OF SYMBOLS 1 Smoke generator 2 Outer container 3 Nonwoven fabric sheet 4 Partition member 6 Lid member 7
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JP2006355015A JP4931578B2 (en) | 2006-12-28 | 2006-12-28 | Repellent method and repellent for rats |
US12/521,332 US20110008264A1 (en) | 2006-12-27 | 2007-12-17 | Method for repelling a rodent, method for capturing a rodent and rodent repellent |
PCT/JP2007/074253 WO2008078594A1 (en) | 2006-12-27 | 2007-12-17 | Method for repelling rat or mouse, method for capturing rat or mouse, and repellent for rat or mouse |
KR1020097013459A KR20090103900A (en) | 2006-12-27 | 2007-12-17 | Method for repelling rat or mouse, method for capturing rat or mouse, and repellent for rat or mouse |
TW096150016A TW200841822A (en) | 2006-12-27 | 2007-12-25 | Method for repelling rat or mouse, method for capturing rat or mouse, and repellent for rat or mouse |
ARP070105885A AR064518A1 (en) | 2006-12-27 | 2007-12-26 | METHOD TO FLOOD ROLLERS METHOD TO CAPTURE ROLLERS AND ROLLER REPELLENT |
CL2007003843A CL2007003843A1 (en) | 2006-12-27 | 2007-12-27 | METHOD FOR REPELLING ROLLERS THAT INCLUDE USING SMOKE GENERATED BY THERMAL DECOMPOSITION OF AZODICARBONAMIDE AS ACTIVE INGREDIENT AND DISSEMINING SUCH SMOKE UNTIL OBTAINING A SMOKE AMOUNT OF 45 CPM OR MORE, OR VAPORIZING A VAPORIZATION INGREDIENT; |
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