JP4862576B2 - Aggregation apparatus and aggregation method - Google Patents

Description

  The present invention relates to a flocculation apparatus and a flocculation method for performing a flocculation process by adding a flocculant to raw water in a water treatment using natural water as a raw material or a wastewater treatment for treating factory wastewater or sewage.

  In water treatment using natural water as raw material and wastewater treatment for treating industrial wastewater or sewage, a flocculant is added to the raw water to condense and coarsen suspended substances, colloidal components and organic substances in the raw water. After that, solid-liquid separation is performed by precipitation, flotation, filtration, membrane filtration or the like.

  The agglomeration treatment is for increasing the solid-liquid separation efficiency such as precipitation, flotation, filtration, membrane filtration and the like located in the latter stage, and as the aggregating agent, generally an inorganic aggregating agent such as aluminum salt or iron salt is used. In many cases, a polymer flocculant is used in combination as an agglomeration aid for further coarsening the particles coagulated with the inorganic flocculant.

  Aggregation or coagulation by such inorganic flocculants is inhibited by synthetic organic substances such as humic and fulvic substances in raw water, natural organic substances such as intracellular and extracellular metabolites produced by algae, and surfactants. It may cause agglomeration or agglomeration speed to be slow or agglomeration failure. When such an agglomeration failure occurs, an adverse effect such as clogging occurs in a filtration device that may be provided at a subsequent stage of the agglomeration treatment step.

  Conventionally, in irrigation water and wastewater treatment, an operation for determining the addition concentration and pH of a flocculant using a separate jar tester has been carried out in order to set optimal coagulation conditions, but such operations are generally complicated. It takes a long time to operate, and therefore, it cannot cope with fluctuations in the quality of raw water, and the determined amount of flocculant added and pH adjustment value cannot be immediately reflected, resulting in poor aggregation. .

  Japanese Examined Patent Publication No. 6-103296 proposes a test apparatus for automatically performing a jar test for setting optimum conditions in a combination of a flocculant addition rate to raw water, a stirring time, and a stirring speed. However, this apparatus is a jar tester, and is not for performing the agglomeration treatment by reflecting the test result in an actual stirring tank.

In Japanese Patent No. 3205450, the aggregation floc particle size in the stirring tank and the ultraviolet absorbance of the soluble organic substance are measured, and the amount of flocculant added is controlled based on these results. There has been proposed a chemical injection device that determines the number of rotations of the agitator in the agitation tank. This device detects the concentration of soluble organic matter in the agitation tank, that is, the concentration of soluble organic matter in the coagulating liquid to which the coagulant is added and is stirred, and this is added together with the detected value of the particle size of the coagulation floc. On the other hand, the stirring strength is set based on the particle size of the agglomerated floc, but it cannot be said that a sufficiently satisfactory agglomeration treatment result has been obtained, and further improvement is achieved. It is desired.
Japanese Patent Publication No. 6-103296 Japanese Patent No. 3205450

  As described above, when natural raw materials such as humic substances, synthetic organic chemicals such as surfactants, or turbidity components such as colloidal components are present in the raw water, the aggregating action is inhibited.

  Further, as a result of various studies by the present inventors, it has been found that if saccharides, particularly charged saccharides, are present in the raw water, aggregation and membrane separation are adversely affected. It has also been found that charged saccharides are concentrated with ion exchange resins and the like.

  The present invention provides a flocculation apparatus and a flocculation method for accurately controlling the amount of flocculant added by detecting the saccharide concentration in raw water, particularly the charged saccharide concentration, and the concentration of an inhibitor such as a humic / fulvic acid organic substance. For the purpose.

The flocculation apparatus of the present invention (Claim 1) includes a flocculant addition means for adding a flocculant to raw water, a sugar concentration measuring device for measuring a sugar concentration in raw water, and an absorbance for detecting the concentration of an aggregation inhibitor in the raw water. Based on the detection value of the measuring device, the sugar concentration measuring device and the absorbance measuring device, the amount of flocculant added determined according to the detected value of the sugar concentration and determined according to the detected value of the inhibitor concentration And a flocculant addition amount control means for controlling the flocculant addition amount of the flocculant addition means so as to be the sum of the flocculant addition amounts.

  According to a second aspect of the present invention, there is provided the coagulating apparatus according to the first aspect, further comprising a concentrating means for concentrating the raw water supplied to the sugar concentration measuring device.

  According to a third aspect of the present invention, there is provided the coagulation apparatus according to the first or second aspect, further comprising a selective permeable membrane treatment apparatus for treating the treated water after the coagulation treatment.

  According to a fourth aspect of the present invention, there is provided the aggregating apparatus according to the third aspect, further comprising means for detecting the permeation performance of the selective permeable membrane treatment apparatus, and the flocculant addition amount control means is further based on a detection value of the detecting means. And controlling the addition amount of the flocculant.

The method of agglomeration present invention (Claim 5), in the aggregation method for aggregating treatment by adding a coagulant to the raw water, to detect the sugar concentration and aggregation inhibitor concentration in the raw water, based on these detected values, The amount of flocculant added to the raw water so that the sum of the amount of flocculant added determined according to the detected value of the sugar concentration and the amount of flocculant added determined according to the detected value of the inhibitor concentration It is characterized by controlling.

  In the present invention, the concentration of sugar in raw water that causes aggregation inhibition, in particular, the concentration of charged sugar, is measured, and the concentration of aggregation inhibiting substances such as turbidity components and organic substances is detected with an absorbance meter, and based on these detected values. By controlling the addition amount of the flocculant, a good flocculant treatment can be performed without excessive addition of the flocculant.

  This also prevents or suppresses contamination of these membranes when there is a membrane separation device such as an MF membrane, UF membrane, NF membrane, or RO membrane in the subsequent stage of the aggregation treatment step. It should be noted that treated water having a good quality can be obtained by further treating the treated water after the aggregation treatment with a selective permeable membrane treatment apparatus.

  In addition, when measuring a charged sugar concentration, a highly accurate measurement result can be obtained by measuring after concentrating raw | natural water.

In the present invention, not only the concentration of sugar in raw water and the concentration of inhibitors such as organic substances and turbidity components that cause aggregation inhibition as described above are detected, but also the permeation performance of the selective permeable membrane treatment apparatus is detected. By controlling the addition amount of the flocculant based on the detected value of the inhibitor concentration and the detected value of the permeation performance, a very good flocculation / separation process can be performed.

  Embodiments of the aggregating apparatus and the aggregating method of the present invention will be described below in detail with reference to the drawings.

  FIG. 1 is a system diagram showing an embodiment of a coagulation sedimentation apparatus provided with the coagulation apparatus of the present invention.

  In FIG. 1, reference numeral 1 denotes a raw water tank, which includes an absorbance measuring device 11. 2A is a rapid flocculation agitation tank, which includes an agitator 2a and a pH sensor 13. The coagulant is supplied from the coagulant storage tank 4 to the coagulation agitation tank 2A through the chemical injection pump 14, and acid and alkali for pH adjustment are supplied from the storage tanks 6 and 7 through the chemical injection pumps 15 and 16, respectively. Supplied. Reference numeral 2B denotes a slow stirring tank, which includes a stirrer 2b and an aggregation state detection sensor 17. 3 is a settling tank.

  A sand filter 8 and a membrane filtration device 9 are installed at the subsequent stage of the settling tank 3. Examples of the membrane of the membrane filtration device 9 include MF membranes, UF membranes, NF membranes, and RO membranes.

  A part of the raw water is collected from the raw water tank 1, concentrated by the sugar concentrating device 21, and then supplied to the sugar concentration meter 22. However, raw water may be collected from locations other than the raw water tank.

  Saccharides are classified into neutral polysaccharides, acidic polysaccharides, amino sugars, etc. Among them, particularly charged sugars include amino sugars such as N-acetylglucosamine and N-acetylgalactosamine, uron sugars (galacturonic acid, iduronic acid, glucuronic acid). ), But is not limited to this.

  As the sugar concentration device 21 for concentrating the raw water containing the charged sugar, a device for concentrating the charged sugar with an ion exchange resin is suitable.

  As the sugar concentration meter 22, an apparatus for analyzing the absorbance of a sample colored by the phenol sulfuric acid method or the like is suitable. Sugar analysis may be performed continuously or periodically and representative values may be used for control.

  Reference numeral 20 denotes a control device to which detection values of the absorbance measuring device 11, the sugar concentration meter 22, the pH sensor 13 and the aggregation state detection sensor 17 are input, and the aggregating agent injection pump 14, the acid injection pump 15 and the alkaline injection. A rotation speed control signal of the pump 16 is output.

  The raw water is introduced into the raw water tank 1, and the agglutination-inhibiting substance concentration, for example, the organic substance concentration in the raw water is detected by the absorbance measuring device 11, and the detection result is input to the control device 20. The absorbance measuring device 11 may be an immersion type or a sampling type. As the absorbance measuring device 11, an ultraviolet short wavelength absorptiometer having a wavelength of 200 to 490 nm is suitable, but in addition to the ultraviolet absorptiometer, a device equipped with a visible light absorptiometer having a wavelength of 500 nm to 700 nm is suitable. It is.

That is, as a result of close examination of the aggregation characteristics of natural water, a result of measuring one or more wavelengths each of the ultraviolet absorbance at a wavelength of 200 nm to 490 nm, preferably 230 to 300 nm and the visible absorbance at a wavelength of 500 nm to 700 nm, preferably 500 to 600 nm. There is a correlation between the inhibitor concentration calculated from the above and the optimum amount of flocculant added determined from the time required to filter a certain amount of sample water using a 0.45 μm membrane filter (hereinafter referred to as KMF value). It has been found that there is a relationship, and there is a correlation between the inhibitor concentration and the absorbance in the ultraviolet and visible regions as shown in the following equation. Therefore, the inhibitor concentration can be estimated by measuring the absorbance in the ultraviolet region and the visible region by one wavelength or more.
(Inhibitor concentration) = [(Total organic matter)-(Turbidity substance)]
= A × [(UV absorbance)-(visible absorbance)]

  The raw water in the raw water tank 1 is then introduced into the rapid flocculation stirring tank 2A. In this rapid flocculation agitation tank 2A, the raw water is agglomerated by adding the flocculant in the flocculant storage tank 4 by the chemical injection pump 14, adjusting the pH by adding acid and alkali, and stirring by the agitator 2a. . The pH in the rapid flocculation agitation tank 2 </ b> A is detected by the pH sensor 13, and the detection result is input to the control device 20. The water that has flowed out of the rapid flocculation agitation tank 2A is introduced into the slow flocculation agitation tank 2B, and is slowly stirred to grow a floc. The aggregation state in the slow stirring tank 2B is detected by the sensor 17.

  In this embodiment, the amount of the flocculant added to the aggregation stirring tank 2A is controlled based on the detection values of the absorbance measuring device 11, the sugar concentration meter 22, and the aggregation state detection sensor 17. That is, for example, the control device 20 substitutes each input detection value into a predetermined determination formula for the amount of flocculant added, and the number of revolutions of the medicinal pump 14 is controlled based on the calculation result, so that an appropriate amount is obtained. Of flocculant is added. As this medicine injection pump 14, a commercially available variable metering pump or the like is used.

In order to control the addition amount of the flocculant according to the sugar concentration and the inhibitor concentration, the sum of the addition amount determined according to the sugar concentration and the addition amount determined according to the inhibitor concentration is used. preferable. In general, the amount of flocculant added is calculated by multiplying the m-th power of the sugar concentration by a coefficient and multiplying the n-th power of the inhibitor concentration by a coefficient. That is,
Addition amount of flocculant = a · (sugar concentration) ^m + b · (inhibitor concentration) ⁿ + c
It is. a, b, and c are constants.
In addition, m and n are the dimensions of the function calculated | required from the relationship between sugar concentration and inhibitory substance concentration, and the optimal addition amount of coagulant | flocculants. That is, as described above, the inhibitor concentration is proportional to the difference between the absorbance in the ultraviolet region and the visible region, and therefore, the dose of medicine according to the concentration of the inhibitor (however, c is omitted) is expressed by the following formula: It is preferable to calculate by multiplying the external absorbance and the visible absorbance by the coefficient b.
Addition amount of flocculant according to inhibitor concentration = b × [(UV absorbance) − (visible absorbance)]
A specific example of a method for determining each coefficient and constant will be described later.
Among saccharides, glycoproteins have a slight absorption in ultraviolet light. Therefore, when the raw water contains glycoprotein, the glycoprotein concentration slightly affects the inhibitor concentration. In that case, an adjustment may be made to subtract the glycoprotein concentration from the inhibitor concentration.

  The UV absorbance is 200 to 490 nm, particularly 230 to 300 nm, for example 260 nm (E260), and the visible absorbance is 500 to 700 nm, particularly 600 to 700 nm, for example, 660 nm (E660).

  a, b, and c are constants determined from KMF values measured by jar test using raw water previously measured for sugar concentration and absorbance.

An example of determining an arithmetic expression is shown below.
The aggregation test is performed using raw waters having different sugar concentrations and (E260-E660) values, and the minimum PAC addition amount that is stable at a low KMF value is determined as the optimum PAC addition concentration. Note that the KMF value here is the sum of the first 500 mL filtration time and the subsequent 500 mL filtration time when filtering with a vacuum suction pressure of 500 mmHg using a membrane filter with a diameter of 47 mm.

  FIG. 2 shows the relationship between the optimum PAC addition concentration and E260-E660, and FIG. 3 shows the relationship between the optimum PAC addition concentration and the sugar concentration.

As shown in FIG. 2, when no sugar is contained, the optimum PAC addition concentration (flocculant addition concentration) is
Optimal PAC addition concentration = 204.63 ×
(UV absorbance E260-visible absorbance E660) -5.3
Can be expressed as As the sugar concentration increases, the optimal PAC addition concentration increases.

As shown in FIG. 3, the optimal PAC addition concentration is proportional to the sugar concentration with a proportionality constant of 0.14. Therefore,
Optimal PAC addition concentration = 0.14 × (sugar concentration [μg / L]) +
204.63 × (E260-E660 [abs./50 mm]) − 5.3
It can be expressed as.

The acid and alkali chemical injection pumps 15 and 16 are controlled by the control device 20 so that the pH in the aggregation stirring tank 2 is 5.0 to 8.0.
As the aggregation state detection sensor 17 installed in the slow flocculation stirring tank 2B, the liquid in the slow flocculation stirring tank 2B is transferred to another precipitation tank, and the turbidity of the supernatant that has been allowed to settle for a certain time is detected. Devices and sensors, devices and sensors that detect the zeta potential or flow potential of condensed or agglomerated particles can also be used, but the clarity between particles aggregated or agglomerated in the slow agitation agitation tank 2B is detected. A light blocking fine particle sensor or a light scattering fine particle sensor is preferably used.

  The agglomerated water in which flocs have grown by being slowly stirred in the slow agitation agitation tank 2B is introduced into the sedimentation tank 3 to coagulate and aggregated particles are settled and separated, and the supernatant water is filtered through the sand filter 8 and membrane filter. It is processed sequentially by the device 9.

  FIG. 1 shows an example of an embodiment of the present invention, and the present invention is not limited to the illustrated one as long as the gist of the present invention is not exceeded.

For example, in FIG. 1, the flocculant is added to the aggregation stirring tank 2A, but the flocculant may be injected into the raw water introduction pipe to the aggregation stirring tank 2A. Furthermore, in FIG. 1, although the precipitation tank 3 was shown as a solid-liquid separation means of coagulation process water, a floating tank etc. may be sufficient.
Further, a means for detecting the permeation performance of the membrane filtration device 9 may be provided, and the addition amount of the flocculant may be controlled based on the detection value of the detection means. As the means for detecting the permeation performance, a permeation differential pressure gauge, a permeation flux measuring device, or the like can be used.

  Hereinafter, the present invention will be described more specifically with reference to Examples and Comparative Examples.

Example 1
In the flocculation / precipitation / sand filtration / UF membrane filtration facility using Lake A with advanced organic matter contamination as the water source, the flocculation / precipitation treatment according to the present invention was performed using the flocculation / precipitation apparatus shown in FIG. In the case of Lake A, 80% of all saccharides were charged saccharides. The sand filter 8 was a column in which 600 mm of filter sand having an effective diameter of 0.45 mm was laminated. The coagulation agitation tanks 2A and 2B are square agitation tanks with an effective capacity of 300 m ^{3 and} a paddle type agitator, the raw water amount is 30 m ³ / h, and the residence time of the rapid aggregation agitation tank is 6 minutes. In the quick flocculation stirring tank 2A, stirring was performed at 60 rpm, and in the slow flocculation stirring tank 2B, stirring was performed at 30 rpm.

Polyaluminum chloride (PAC) was used as the flocculant. The arithmetic expression for controlling the PAC addition amount was obtained in advance from the result of jar test using Lake A and was as follows.
PAC addition concentration = 0.14 × (sugar concentration) + 208.93 × E260 + 2.3
Moreover, the chemical injection control of acid and alkali was performed so that the pH of the rapid aggregation stirring tank 2A was 6.5.

  As an absorptivity measuring instrument, an absorptiometer manufactured by HACH, which can scan an ultraviolet to visible light region in the vicinity of a wavelength of 200 nm to 700 nm, was used, and an ultraviolet absorbance was measured at 260 nm.

The sugar concentration apparatus 21 was abbreviate | omitted and the sugar concentration in raw | natural water was measured with the absorption type | mold continuous flow analyzer by Actac.
The water flow test results are shown in Table 1.

Example 2
In Example 1, the visible light absorbance at a wavelength of 660 nm was further measured with the absorbance meter 11, and the test was performed in the same manner except that the PAC addition amount calculation formula was as follows.
PAC addition concentration = 0.14 × (sugar concentration) +204.63
× (E260-E660) -5.3
The water flow test results are shown in Table 1.

Example 3
In Example 2, the test was performed in the same manner except that the raw water was led to the sugar concentration device 21 and concentrated five times and supplied to the sugar concentration meter 22. As the sugar concentrator 21, an ion exchange resin built-in column was used.
The water flow test results are shown in Table 1.

Example 4
In Example 3, the PAC addition amount was corrected in consideration of the detection value of the aggregation state detection sensor 17. As the aggregation state detection sensor, an aggregation sensor (Kripitari) manufactured by Kurita Kogyo Co., Ltd. was used. Specifically, when the supernatant water turbidity measured by the sensor that detects the aggregation state exceeds 1 degree, the PAC addition amount is corrected to add 1.2 times the value derived from the calculation formula. did.
The water flow test results are shown in Table 1.

Comparative Example 1
The aggregation precipitation treatment was performed in the same manner as in Example 1 except that the PAC addition amount was not controlled by measuring the absorbance, and the PAC addition amount was kept constant at 60 mg / L.

Comparative Example 2
The PAC addition concentration was controlled based on E260 and E660 only. That is, the sugar concentration was not adopted for PAC addition control, and the PAC addition concentration was controlled by the following equation.
PAC addition concentration = 517 × (E260−E660) −10.6

[Comparison between Examples 1-4 and Comparative Examples 1-2]
Water flow was conducted for one month each when the water quality changed due to fine weather and rain in April. In addition, in order to use the same raw | natural water, Examples 1-4 and Comparative Examples 1-2 were performed in parallel. Table 1 shows E260 of the raw water during the water flow test period, the PAC addition concentration, the KMF value of the coagulated sediment treated water, and the rate of increase in the filtration differential pressure ΔP of the UF membrane.

  The KMF value used here is the sum of the first 500 mL filtration time and the subsequent 500 mL filtration time when filtration was performed at a vacuum suction pressure of 500 mmHg using a membrane filter having a diameter of 47 μm.

In Example 1, by controlling the PAC addition amount based on the sugar concentration and the absorbance E260, the KMF value and the ΔP increase rate changed at low values.
In Example 2, the rate of increase in ΔP was lower than that in Example 1 by controlling the amount of PAC added by the sugar concentration and E260 and E660 (raw water turbidity index).
In Example 3, the rate of increase in ΔP was lower than that in Example 2 by concentrating charged sugars and increasing the sugar analysis accuracy.
In Example 4, the rate of increase in ΔP was lower than that in Example 3 by correcting the PAC addition amount from the aggregation state.
In Comparative Examples 1 and 2, ΔP increased rapidly.

It is a systematic diagram which shows embodiment of the coagulation sedimentation apparatus provided with the coagulation apparatus of this invention. It is a graph which shows PAC addition density | concentration. It is a graph which shows PAC addition density | concentration.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Raw water tank 2A Rapid flocculation stirring tank 2B Slow flocculation stirring tank 3 Precipitation tank 4 Coagulant storage tank 8 Sand filter 9 Membrane filtration device 11 Absorbance measuring device 13 pH sensor 14, 15, 16 Drug injection pump 17 Aggregation state detection sensor 20 Control device 21 Sugar concentration device 22 Sugar concentration meter

Claims (5)

A flocculant addition means for adding the flocculant to the raw water;
A sugar concentration measuring device for measuring the sugar concentration in raw water;
An absorbance meter that detects the concentration of aggregation-inhibiting substances in the raw water;
An aggregating agent addition amount determined according to the detected value of the sugar concentration and an aggregating agent determined according to the detected value of the inhibitor concentration based on the detected values of the sugar concentration measuring device and the absorbance measuring device An aggregating apparatus comprising: an aggregating agent addition amount control unit that controls the aggregating agent addition amount of the aggregating agent addition unit so as to be the sum of the addition amount.   2. The aggregating apparatus according to claim 1, further comprising a concentrating means for concentrating the raw water supplied to the sugar concentration measuring device.   The coagulation apparatus according to claim 1, further comprising a selective permeable membrane treatment apparatus for treating the treated water after the coagulation treatment.   4. The permeation performance detection means of the selective permeable membrane processing apparatus according to claim 3, wherein the flocculant addition amount control means further controls the flocculant addition amount based on a detection value of the detection means. An aggregating apparatus characterized by that. In the coagulation method of coagulating by adding a coagulant to the raw water,
Detecting the sugar concentration and aggregation inhibitor concentration in the raw water, based on these detected values, a flocculant amount determined in accordance with the detected value of the sugar concentration, in accordance with the detected value of the inhibitor concentration A coagulation method characterized by controlling the amount of coagulant added to raw water so as to be the sum of the coagulant addition amount determined.

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