JP4861610B2 - Method for producing concrete using recycled aggregate - Google Patents

Method for producing concrete using recycled aggregate Download PDF

Info

Publication number
JP4861610B2
JP4861610B2 JP2004172820A JP2004172820A JP4861610B2 JP 4861610 B2 JP4861610 B2 JP 4861610B2 JP 2004172820 A JP2004172820 A JP 2004172820A JP 2004172820 A JP2004172820 A JP 2004172820A JP 4861610 B2 JP4861610 B2 JP 4861610B2
Authority
JP
Japan
Prior art keywords
aggregate
concrete
recycled
recycled aggregate
seconds
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP2004172820A
Other languages
Japanese (ja)
Other versions
JP2005350303A (en
Inventor
親典 橋本
史朗 新居
仁 牛尾
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SEIA CO., LTD.
Original Assignee
SEIA CO., LTD.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SEIA CO., LTD. filed Critical SEIA CO., LTD.
Priority to JP2004172820A priority Critical patent/JP4861610B2/en
Publication of JP2005350303A publication Critical patent/JP2005350303A/en
Application granted granted Critical
Publication of JP4861610B2 publication Critical patent/JP4861610B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Description

本発明は、コンクリート分野における再生骨材によるコンクリートの製造方法に関す
るものである。
The present invention relates to a method for producing concrete using recycled aggregate in the concrete field.

舗装道路のアスファルト骨材への再生骨材の利用についてはよく知られて実施され、
また建物の解体などによるコンクリート廃材のコンクリートへの再生についても研究、開
発されて、再利用率が斬次高くなってきている。
The use of recycled aggregate for asphalt aggregate on paved roads is well known and implemented,
Research and development has also been conducted on the recycling of waste concrete into concrete, such as by demolishing buildings, and the reuse rate is increasing dramatically.

しかし、建物の解体などによるコンクリート廃材のコンクリートへの再利用は、道路
の路盤材や埋め戻し材が中心で、建物の柱、梁、スラブなどには強度などの基本性能が天
然骨材を用いたものよりも劣るため、特殊な処理を行わねばならず、品質、価格の面でメ
リットがなく、実施されていない。
However, the reuse of concrete waste materials such as building demolition to concrete is mainly for roadbed materials and backfill materials, and natural aggregates such as strength are used for building columns, beams and slabs. Because it is inferior to what we had, special processing had to be performed, and there was no merit in terms of quality and price, and it was not implemented.

特に、コンクリート廃材を粉砕機で粉砕して利用する低度処理による再生骨材は、品
質の悪さから再生路盤材以外での利用はほとんどない状態である。しかし、低度処理の再
生は、加熱すりもみなどによる高度処理の再生骨材より省エネルギーであり、また環境負
荷の減少や廃棄コンクリートの再利用率の向上がはかれるなど多くの利点がある。
そこで、コンクリート廃材の再利用について先行特許調査した結果、特開2002−
20154号公報、特開2004−41859号公報などが検索された。
In particular, recycled aggregates produced by low-level processing using concrete waste material after being pulverized by a pulverizer are in a state of little use other than recycled roadbed material due to poor quality. However, low-level regeneration has many advantages such as saving energy compared to high-grade recycled aggregates such as heated grits, and reducing the environmental burden and improving the reuse rate of waste concrete.
Then, as a result of conducting a prior patent search on the reuse of concrete waste,
No. 20154, Japanese Patent Application Laid-Open No. 2004-41859, and the like were searched.

上記特開2002−20154号公報は、コンクリート構造物の解体等に伴って排出
されるコンクリート塊を壊し、このようにして得られる多数のコンクリート塊の間に粗骨
材を含む充填コンクリートを投入して再生コンクリート全体の圧縮強度を高くするもので
ある。
The above Japanese Patent Laid-Open No. 2002-201554 breaks a concrete lump discharged along with the dismantling of a concrete structure, and puts filled concrete containing coarse aggregate among a large number of concrete lumps thus obtained. This increases the compressive strength of the entire recycled concrete.

また、特開2004−41859号公報は、コンクリート廃材を球状の磨鉱部材が収
納されたコニカル式ボールミルに投入し、コニカル式ボールミルの破砕作用および磨鉱作
用によって分離した粗骨材および細骨材に付着した付着物を剥離させてコンクリート廃材
から粗骨材および細骨材を再生製造するものである。
特開2002−20154号公報 特開2004−41859号公報
Japanese Laid-Open Patent Publication No. 2004-41859 discloses a coarse aggregate and a fine aggregate separated by a crushing action and a grinding action of a conical-type ball mill by putting concrete waste into a conical-type ball mill containing spherical grinding members. In this case, the deposits adhering to the material are peeled off to regenerate the coarse aggregate and fine aggregate from the concrete waste.
JP 2002-20154 A JP 2004-41859 A

しかし、前者のものは特定のコンクリート構造物に利用できても、一般のコンクリー
ト構造物に適用できなく、また後者のものではコニカル式ボールミルといった特殊な破砕
装置を必要とするものであった。
However, even though the former can be used for a specific concrete structure, it cannot be applied to a general concrete structure, and the latter requires a special crushing device such as a conical ball mill.

そのため、本発明は、コンクリート廃材を特別な装置を必要とせずに従来のコンクリ
ート製造技術の範囲内で、再生コンクリートの品質向上をはかるようにすることにある。
Therefore, an object of the present invention is to improve the quality of recycled concrete within the scope of conventional concrete manufacturing technology without requiring any special equipment for the waste concrete material.

本発明は、上記したような点に鑑み、上記の課題を解決するために、セメントとコンクリート廃材の再生骨材と水、混和剤の原料を配合し、これらをミキサーで攪拌混練してコンクリートを製造する再生骨材によるコンクリートの製造方法であって、セメントとコンクリート廃材の低度処理骨材の再生骨材と水、混和剤の原料を配合してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために、棒状の振動機で所定時間にわたって原料に振動を与えてモルタルの付着をよくしてコンクリートの強度を向上させるようにすることを特徴とする再生骨材によるコンクリートの製造方法を提供するものである。 In view of the above-mentioned points, the present invention mixes recycled aggregates of cement and concrete waste, water, and raw materials for admixture, and stirs and kneads these with a mixer to produce concrete. A method for producing concrete using recycled aggregates to be produced, comprising mixing recycled aggregates of cement and concrete waste with low-grade aggregate, water, and raw materials of admixture and mixing the recycled aggregates in the mixer. In order to peel off old powder adhering to the surface, a regenerated bone characterized by improving the strength of concrete by applying vibration to the raw material for a predetermined time with a rod-shaped vibrator to improve adhesion of mortar The manufacturing method of the concrete by a material is provided.

また、原料を搬入してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために30〜180秒間にわたって原料に振動を与えることを特徴とする再生骨材によるコンクリートの製造方法を提供するものである。 In addition, the concrete made from recycled aggregate is characterized in that the raw material is vibrated for 30 to 180 seconds in order to peel off the old powder adhering to the surface of the recycled aggregate during the mixing of the raw material in the mixer. The manufacturing method of this is provided.

さらに、原料を搬入してミキサーでの混練途中に、再生骨材の表面に付着した古い粉
体を剥離させるために30〜180秒間にわたって原料に振動を与えることを特徴とする
再生骨材によるコンクリートの製造方法を提供するものである。
Furthermore, the concrete made from recycled aggregate is characterized in that the raw material is vibrated for 30 to 180 seconds in order to peel off the old powder adhering to the surface of the recycled aggregate during the mixing of the raw material in the mixer. The manufacturing method of this is provided.

またさらに、セメントとコンクリート廃材の再生細骨材をミキサーに投入して30秒間混練し、水、混和剤を混入して60秒間混練し、再生粗骨材を投入して60秒間混練し、これらの原料に振動を与えることを特徴とする再生骨材によるコンクリートの製造方法を提供するものである。 Furthermore, recycled fine aggregate of cement and concrete waste is put into a mixer and kneaded for 30 seconds, mixed with water and admixture for 60 seconds, recycled coarse aggregate is added and kneaded for 60 seconds, The present invention provides a method for producing concrete using recycled aggregate, which is characterized by imparting vibration to the raw material .

本発明の再生骨材によるコンクリートの製造方法は、セメントとコンクリート廃材の再生骨材と水、混和剤の原料を配合し、これらをミキサーで攪拌混練してコンクリートを製造する再生骨材によるコンクリートの製造方法であって、セメントとコンクリート廃材の低度処理骨材の再生骨材と水、混和剤の原料を配合してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために、棒状の振動機で所定時間にわたって原料に振動を与えてモルタルの付着をよくしてコンクリートの強度を向上させるので、コンクリート廃材の低度処理骨材の再生骨材であっても、コンクリート廃材を特別な装置を必要とせずに従来のコンクリート製造技術の範囲内で、再生コンクリートの品質向上をはかれ、再生骨材へのモルタルの付着が向上し、コンクリートの圧縮強度も十分に発現できる。 The method for producing concrete by using the recycled aggregate according to the present invention comprises mixing cement, recycled concrete aggregate, water, and raw materials of admixture, and stirring and kneading them with a mixer to produce concrete. This is a manufacturing method, in which cement and concrete waste low-grade aggregate recycled aggregate, water, and raw materials of admixture are mixed and old powder adhering to the surface of the recycled aggregate is mixed in the mixer. In order to exfoliate, the raw material is vibrated with a rod-shaped vibrator for a predetermined time to improve the adhesion of the mortar and improve the strength of the concrete. Therefore, the quality of recycled concrete can be improved within the scope of conventional concrete manufacturing technology without the need for special equipment, and mortar can be attached to recycled aggregate. There was improved, compressive strength of the concrete can be sufficiently exhibited.

そして、コンクリート廃材の再生骨材が低度処理骨材であっても、再生骨材の表面に
付着した古い粉体を剥離させるために、所定時間にわたって原料に振動を与えることによ
って、再生骨材へのモルタルの付着が向上し、コンクリートの圧縮強度も十分に発現させ
ることができる。
And even if the recycled aggregate of concrete waste is a low-level processed aggregate, in order to peel off the old powder adhering to the surface of the recycled aggregate, the recycled aggregate is given a vibration for a predetermined time. The adhesion of mortar to the surface is improved, and the compressive strength of the concrete can be sufficiently developed.

また、原料を搬入してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体
を剥離させるために30〜180秒間にわたって原料に振動を与えて、モルタルの付着を
よくしてコンクリートの強度を向上させるようにすることによって、コンクリート廃材の
低度処理骨材であっても、上記のように十分な効果を得ることができる。
Also, during the mixing of the raw material and mixing with the mixer, in order to peel off the old powder adhering to the surface of the recycled aggregate, the raw material is vibrated for 30 to 180 seconds to improve the adhesion of the mortar. By improving the strength, it is possible to obtain a sufficient effect as described above even with a low-grade aggregate of concrete waste.

さらにまた、セメントとコンクリート廃材の再生細骨材をミキサーに投入して30秒間混練し、水、混和剤を混入して60秒間混練し、再生粗骨材を投入して60秒間混練し、これらの原料に振動を与えることによって、コンクリート廃材の低度処理骨材であっても、適度のスランプのものが得られて従来と同様に施工することができる。 Furthermore, recycled fine aggregates of cement and concrete waste are put into a mixer and kneaded for 30 seconds, mixed with water and admixture for 60 seconds, recycled coarse aggregate is added and kneaded for 60 seconds, By giving vibration to the raw material, a moderately slumped material can be obtained even if it is a low-grade aggregate of concrete waste, and it can be constructed in the same manner as before.

発明が実施しょうとする最良の形態The best mode of the invention

本発明の再生骨材によるコンクリートの製造方法は、セメントとコンクリート廃材の再生骨材と水、混和剤の原料を配合し、これらをミキサーで攪拌混練してコンクリートを製造する再生骨材によるコンクリートの製造方法であって、セメントとコンクリート廃材の低度処理骨材の再生骨材と水、混和剤の原料を配合してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために、棒状の振動機で所定時間にわたって原料に振動を与えてモルタルの付着をよくしてコンクリートの強度を向上させるようにすることを特徴としている。 The method for producing concrete by using the recycled aggregate according to the present invention comprises mixing cement, recycled concrete aggregate, water, and raw materials of admixture, and stirring and kneading them with a mixer to produce concrete. This is a manufacturing method, in which cement and concrete waste low-grade aggregate recycled aggregate, water, and raw materials of admixture are mixed and old powder adhering to the surface of the recycled aggregate is mixed in the mixer. In order to exfoliate, the raw material is vibrated over a predetermined time with a rod-shaped vibrator to improve adhesion of the mortar to improve the strength of the concrete.

コンクリート廃材は、コンクリート建物を解体した廃材等が利用でき、このコンクリ
ートの廃材の塊を破砕した全粒度についてその再生細骨材と再生粗骨材が利用できる。ま
た、これらの再生骨材は、コンクリート塊を破砕装置で破砕処理した低度処理のものを利
用し、必要により現在行われている加熱すりもみして粉砕処理した高度処理のものも利用
することができる。
As the concrete waste material, waste material or the like obtained by dismantling a concrete building can be used, and the recycled fine aggregate and recycled coarse aggregate can be used for the entire particle size obtained by crushing the lump of the concrete waste material. In addition, these recycled aggregates should be low-level processed by crushing concrete lumps with a crushing device, and if necessary, high-level processed by crushing by grinding with heating. Can do.

これらの再生骨材の諸性状の一例として、表1(a)、(b)に示す。
表1 再生骨材の諸性状表

Figure 0004861610
Table 1 (a) and (b) show examples of the properties of these recycled aggregates.
Table 1 Properties table of recycled aggregates
Figure 0004861610

そして、再生骨材コンクリートは、セメントと再生細骨材を、たとえば図1(a)、(b)のような二軸ミキサー1に投入して30秒間混練し、また水、混和剤(減水剤を含む)を混入して60秒間混練し、ついで再生粗骨材を投入して60秒間混練する。その後、棒状振動機2を挿入して原料に振動を与え、振動を与えられた原料がミキサー内に十分に流動して全体に行きわたるようにして、再生骨材の表面に付着した古い粉体を剥離させるようにする。 The recycled aggregate concrete is made by mixing cement and recycled fine aggregate into, for example, a twin-screw mixer 1 as shown in FIGS. 1 (a) and 1 (b) and kneading for 30 seconds. Also, water, an admixture (water reducing agent) mixed for 60 seconds kneading the containing), then 60 seconds kneaded by injecting regeneration coarse aggregate. After that, the rod-like vibrator 2 is inserted to give vibration to the raw material, and the old raw material adhered to the surface of the recycled aggregate so that the given raw material flows sufficiently in the mixer and reaches the whole. To peel off.

この加振時間としては、30〜180秒間の所定時間にわたって行えるものであり、
後述するように60秒以上振動を与えてもそう効果は高められなく、30〜60秒、好ま
しくは60秒前後で十分な効果を高められる。
As this excitation time, it can be performed over a predetermined time of 30 to 180 seconds,
As will be described later, even if vibration is applied for 60 seconds or more, the effect is not enhanced, and a sufficient effect can be enhanced in 30 to 60 seconds, preferably around 60 seconds.

その後、材料分離を防ぐために、再度30〜60秒混練して排出するのが好ましい。
上記全混練時間としては、5〜6分間位のもので、本発明の趣旨にもとづいて適宜な混練
、振動付与を行って再生骨材コンクリートの品質を高めるようにできる。
Thereafter, in order to prevent material separation, it is preferable to knead and discharge again for 30 to 60 seconds.
The total kneading time is about 5 to 6 minutes, and the quality of the recycled aggregate concrete can be improved by performing appropriate kneading and applying vibration according to the gist of the present invention.

本発明の実施例について、コンクリート廃材の低度処理再生骨材(R)および高度処
理再生骨材(RH)を、比較例の普通骨材(N)と比較し、水・セメント比(W/C)を
固定し、目標スランプを8±2.5cm、目標空気量を4.5±1.5%とした。表2に再
生骨材(R、RH)の配合を、表3に普通骨材(N)の配合を示す。
About the Example of this invention, compared with the normal aggregate (N) of a comparative example, the low processing recycled aggregate (R) and high processing recycled aggregate (RH) of a concrete waste material, water-cement ratio (W / C) was fixed, the target slump was 8 ± 2.5 cm, and the target air amount was 4.5 ± 1.5%. Table 2 shows the composition of recycled aggregate (R, RH), and Table 3 shows the composition of ordinary aggregate (N).

表2 再生骨材の配合表

Figure 0004861610
Table 2 Recycled aggregate formulation
Figure 0004861610

表3 普通骨材の配合表

Figure 0004861610
Table 3 Composition table of ordinary aggregate
Figure 0004861610

そして、再生骨材の配合について、0分、1分、3分間の棒状の振動機を挿入した場
合、低度処理再生骨材について(RV−0、RV−1、RV−3)、高度処理骨材につい
て(RHV−0、RHV−1、RHV−3)と、振動機の代わりに0分、1分、3分間の
練混ぜ時間を延長した場合(RM−0、RM−1、RM−3)、および普通骨材(N)の
練混ぜを振動機を挿入しない場合(NV−0)と2分間振動機を挿入した場合(NV−2
)について試験した。
And about the mixing | blending of recycled aggregate, when a rod-shaped vibrator for 0 minute, 1 minute, and 3 minutes is inserted, about a low processing recycled aggregate (RV-0, RV-1, RV-3), advanced processing For aggregates (RHV-0, RHV-1, RHV-3) and when mixing time is extended for 0 minutes, 1 minute, 3 minutes instead of a vibrator (RM-0, RM-1, RM- 3), and when mixing the normal aggregate (N) when the vibrator is not inserted (NV-0) and when the vibrator is inserted for 2 minutes (NV-2)
).

コンクリートの練混ぜは、図1のような容量60リットルの強制二軸練りミキサーを用いた。全練混ぜ時間は360秒で一定とした。練混ぜ手順は、セメントと細骨材を投入して30秒混練し、水、混和剤(補助減水剤を含む)を投入して60秒間混練し、粗骨材を投入して60秒間順次混練し、練混ぜ開始後150秒で一旦ミキサーを停止して棒状振動機を挿入して60秒間および180秒間コンクリート原料にそれぞれ振動を与えて十分に流動攪拌し、ミキサーでの混練途中に再生骨材の表面に付着した古い粉体を剥離させた。そして、60秒の振動のものについては、その後再び30秒間練混ぜを行って排出した。 For the mixing of the concrete, a forced biaxial kneading mixer having a capacity of 60 liters as shown in FIG. 1 was used. The total mixing time was constant at 360 seconds. For the mixing procedure, cement and fine aggregate were added and kneaded for 30 seconds, water and admixture (including auxiliary water reducing agent) were added and kneaded for 60 seconds, and coarse aggregate was added and sequentially kneaded for 60 seconds. 150 seconds after mixing starts, the mixer is temporarily stopped, a rod-like vibrator is inserted, the concrete raw material is vibrated for 60 seconds and 180 seconds, and is sufficiently fluidized and stirred. The old powder adhering to the surface of was peeled off. And about the thing of 60 second vibration, it kneaded again for 30 seconds after that, and discharged | emitted.

上記の試験によるコンクリートについて、空気量、スランプ試験を行い、100mm
径×200mmの標準円柱供試体型枠を用い、バイブレーターを使用して締固めて供試体
を作製した。そして、材齢1日で脱型し、脱型後直ちに20℃の水中養生を行った。
About concrete by the above test, air quantity, slump test is performed, 100mm
Using a standard cylindrical specimen form with a diameter of 200 mm, a specimen was prepared by compaction using a vibrator. And it demolded by material age 1 day, and 20 degreeC water curing was performed immediately after demolding.

これらについて、スランプ試験(JIS A 1101)、空気量試験(JIS A
1128)の結果、図2(a)、(b)の通りで、低度処理の再生骨材を使用したコン
クリートは、高度処理の再生骨材を使用したコンクリートよりスランプが小さい。低度処
理の再生骨材には、原コンクリートのモルタルやセメントペースト粒子の付着が多いため
であると考えられる。低度処理の再生骨材を使用したものにおいて比較すると、振動機の
投入時間や練混ぜ時間の延長時間に関わらず、RV(振動機をかけたもの)よりRM(練
混ぜ時間を延長したもの)の方がスランプが大きい。低度処理の再生骨材を表乾状態にせ
ずに、外に放置した自然状態(最初は絶対乾燥状態)で使用したため、骨材の含水率の影
響と考えられる。
About these, slump test (JIS A 1101), air quantity test (JIS A)
As a result of 1128), as shown in FIGS. 2A and 2B, the concrete using the low-grade recycled aggregate has a smaller slump than the concrete using the high-grade recycled aggregate. This is probably because low-grade recycled aggregates have a lot of adhesion of raw concrete mortar and cement paste particles. Compared to those using low-grade recycled aggregates, RM (extended mixing time) over RV (vibrated one) regardless of the time to add the vibrator and the mixing time extension ) Has a larger slump. This is considered to be due to the moisture content of the aggregate, because the low-grade recycled aggregate was used in a natural state (at first it was absolutely dry) that was left outside without being in a dry state.

しかし、低度処理の再生骨材を使用したコンクリートは、振動を与えることや練混ぜ
時間を延ばすことによって、流動性を改善させることができている。スランプが3〜4c
m増大しており、高度処理した再生骨材を使用したコンクリートではこの傾向は認められ
ない。モルタルやセメントペースト粒子が付着した骨材を多く含む低度処理の再生骨材は
、振動を与えることや練混ぜ時間を増やすことによって、これらの付着粒子を剥離させる
ことが可能であると考えられる。さらに、この付着粒子が剥離することによってスランプ
が大きくなったと考える。なお、今回使用した骨材においては、1分間の振動機挿入や練
混ぜ時間を増やすことが、最もスランプを得やすい時間であることがわかる。
However, the concrete using the low-grade recycled aggregate can improve the fluidity by applying vibration and extending the mixing time. Slump is 3-4c
m, and this tendency is not observed in concrete using highly processed recycled aggregate. Low-grade recycled aggregate containing a lot of aggregate with mortar and cement paste particles attached is thought to be able to peel off these attached particles by applying vibration and increasing the mixing time. . Further, it is considered that the slump is increased by the separation of the adhered particles. In addition, in the aggregate used this time, it can be seen that increasing the one-minute vibrator insertion and mixing time is the time when slump is most easily obtained.

また、空気量においては、通常振動を加えると空気量は減少するが、逆の傾向である
。練混ぜ時間を増やした方が、空気量が増大した。これは、練混ぜ時の振動機の挿入や練
混ぜ時間の増加によって、空気を多く取り込んだことが原因であると考える。
In addition, in the air amount, when the normal vibration is applied, the air amount decreases, but the tendency is opposite. The amount of air increased as the mixing time was increased. This is thought to be due to the fact that a large amount of air was taken in due to the insertion of a vibrator during mixing and an increase in mixing time.

図3(a)は、振動時間を変化させた場合の低度処理骨材の圧縮強度を示す。図3(
b)は、練混ぜ時間を変化させた場合の低度処理骨材の圧縮強度を示す。一般的な設計基
準材齢である28日の圧縮強度においてはRV−1、RV−3(振動をかけたもの)の方
がRV−0(振動をかけないもの)と比較して30%程度大きい。振動機を挿入すること
により、再生骨材に付着している微粉を剥離させ、再び新しいモルタルを付着させ、強度
が十分に発現する。また、振動時間1分間と3分間の違いは顕著ではない。したがって、
低度処理骨材においては、振動機挿入時間は1分間で十分効果を得ることができると判断
される。
FIG. 3A shows the compressive strength of the low-level processed aggregate when the vibration time is changed. FIG.
b) shows the compressive strength of the low-grade aggregate when the kneading time is changed. RV-1, RV-3 (vibrated) is about 30% compared to RV-0 (non-vibrated) in compressive strength of 28 days, which is a general design standard age. large. By inserting the vibrator, the fine powder adhering to the recycled aggregate is peeled off, new mortar is attached again, and the strength is sufficiently developed. Further, the difference between the vibration time of 1 minute and 3 minutes is not remarkable. Therefore,
In the low-grade treated aggregate, it is judged that the vibrator insertion time can be sufficiently effective in one minute.

材齢28日において、RM−1、RM−3(練混ぜ時間を延長したもの)は、RM−
0(練混ぜ時間を延長しないもの)より若干大きいが、材齢91日においては練混ぜ時間
の延長に関係なく、ほぼ同じ強度となる。低度処理の再生骨材においては、圧縮強度への
改善効果は、振動機をかけた方が練混ぜ時間の延長よりも得られる。
At 28 days of age, RM-1 and RM-3 (extended mixing time) are RM-
It is slightly larger than 0 (one that does not extend the mixing time), but at the age of 91 days, the strength is almost the same regardless of the extension of the mixing time. In the low-grade recycled aggregate, the improvement effect on the compressive strength can be obtained by applying a vibrator rather than extending the mixing time.

図4は、高度処理骨材使用コンクリートの圧縮強度における振動機挿入時間の影響を
示す。振動をかけない場合、振動時間1分および3分ともに、各材齢時での圧縮強度に差
がほんとんどない。高度処理の再生骨材は加熱すりもみで骨材から微粉を取り除いている
ため、普通骨材とほとんど同じ状態である。その結果、普通骨材に近く、振動機を挿入し
ても圧縮強皮に影響が現れなかったと考えられる。
FIG. 4 shows the influence of the vibrator insertion time on the compressive strength of highly processed aggregate concrete. When vibration is not applied, there is almost no difference in compressive strength at the age of each material for both vibration times of 1 minute and 3 minutes. Highly processed recycled aggregates are almost in the same state as ordinary aggregates because fine powder is removed from the aggregates by heating and grinding. As a result, it is considered that it was close to ordinary aggregate, and even if the vibrator was inserted, the compression bast was not affected.

図5は、振動機挿入の有無が、普通骨材を用いたコンクリートの圧縮強度に与える影
響を示す。普通骨材使用コンクリートの圧縮強度は、同一材齢での強度はほぼ同様の値で
ある。よって、普通骨材に対する振動機の挿入は、圧縮強度に与える影響はない。普通骨
材には、骨材界面にセメントペーストの粉砕微粉末粒子の付着が無いためである。低度処
理骨材の振動機挿入による圧縮強度の増進は、骨材界面の改善に起因すると推測される。
FIG. 5 shows the effect of whether or not a vibrator is inserted on the compressive strength of concrete using ordinary aggregate. The compressive strength of ordinary aggregate concrete is almost the same value at the same age. Therefore, the insertion of the vibrator into the normal aggregate has no effect on the compressive strength. This is because ordinary aggregates have no adhesion of pulverized fine powder particles of cement paste to the aggregate interface. It is speculated that the increase in compressive strength due to the insertion of the vibrator of the low-level treated aggregate is due to the improvement of the aggregate interface.

材齢28日におけるビッカース硬さを各試料毎に10点以上計測し、それらの平均を
図6(a)、(b)、図7に示す。ビッカース硬さはHVで表される。縦軸の微小硬度(
0.005HV)は、コンクリート界面に指す針の強さを表す。RVのビッカース硬さでは、
界面からの距離が100μmから300μmまでの間隔において、振動機をかけないRV
−0の硬度が振動をかけたRV−1、RV−3と比較して大きく下がっている。振動機の
挿入が原コンクリートのモルタルやぺースト粒子を剥離させ、骨材界面の遷移帯の強化に
伴う圧縮強度改善に有効であると考えられる。また、圧縮強度の差がほとんどないRV−
1とRV−3は微小硬度においても同様に差はほとんど見られなかった。
Ten or more Vickers hardnesses at the age of 28 days were measured for each sample, and the averages thereof are shown in FIGS. 6 (a), (b), and FIG. 7. Vickers hardness is expressed in HV. Micro hardness on the vertical axis (
0.005HV) represents the strength of the needle pointing to the concrete interface. In RV Vickers hardness,
RV that does not vibrate when the distance from the interface is 100 μm to 300 μm
The hardness of −0 is significantly lower than those of RV-1 and RV-3 that are vibrated. It is thought that the insertion of the vibrator is effective in improving the compressive strength accompanying the strengthening of the transition zone at the aggregate interface by peeling off the mortar and paste particles of the raw concrete. Also, there is almost no difference in compressive strength RV-
1 and RV-3 showed little difference in microhardness as well.

RMのビッカース硬さでは、界面からの距離が100μmから300μmまでの間隔
において、練混ぜ時間を延長したもの(RM−1、RM−3)は練混ぜ時間を延長しない
もの(RM−0)より微小硬度が若干小さい。しかし、400μm〜500μmではほぼ
同じ値になった。練混ぜ時間を延長したものの圧縮強度は、練混ぜの延長時間の違いによ
る差がほぼ無い。これは、練混ぜ時間を長くすることによる骨材界面における付着の改善
効果がないことが原因と考えられる。また、微小硬度の大きさに関しては、振動機を投入
するRVと練混ぜ時間を延長するRMが20HV程度で同じ値を示す。
In the RM Vickers hardness, the distance from the interface is 100 μm to 300 μm, and those with longer mixing time (RM-1, RM-3) than those without longer mixing time (RM-0) Micro hardness is slightly small. However, the values were almost the same between 400 μm and 500 μm. There is almost no difference in the compressive strength of what extended the mixing time by the difference in the extended time of mixing. This is considered to be because there is no effect of improving the adhesion at the aggregate interface by increasing the mixing time. In addition, regarding the magnitude of the microhardness, the RV to which the vibrator is charged and the RM that extends the mixing time are about the same value at about 20 HV.

RHのビッカース硬度では、全供試体の微小強度はほぼ同様の値だった。高度処理再
生骨材の微小硬度は棒状振動機の挿入に関係なく、圧縮強度と同様の結果になった。また
、低度処理と高度処理の再生骨材同士で微小硬さの違いを比較すると、高度処理再生骨材
で最大値が15HVに対して、低度処理再生骨材は20HV以上であった。高度処理再生
骨材の骨材界面は普通骨材とほぼ同じで、低処理再生骨材のような微粉を含んでいないた
め、骨材界面の状態が変化しないと考えられる。
In the RH Vickers hardness, the minute strengths of all the specimens were almost the same value. The microhardness of the highly processed recycled aggregate was the same as the compressive strength regardless of the insertion of the rod-shaped vibrator. Further, when the difference in microhardness was compared between the low-level processed and high-level processed recycled aggregates, the maximum value of the high-level processed recycled aggregates was 15 HV, and the low-level processed recycled aggregates were 20 HV or higher. The aggregate interface of the high-processed recycled aggregate is almost the same as that of ordinary aggregate and does not contain fine powder like the low-processed recycled aggregate. Therefore, it is considered that the state of the aggregate interface does not change.

低度処理再生骨材及び普通骨材を用いて作製した材齢91日のコンクリート供試体を
使用して実験を行った。表4は、低度処理再生骨材に対して、振動機挿入とミキシングの
2種類の方法によって作製した供試体における簡易凍結融解試験の結果であり、ひび割れ
発生時のサイクル数、動弾性係数及び相対動弾性係数の平均値を示している。
An experiment was conducted using a 91-day-old concrete specimen prepared using low-grade recycled aggregate and normal aggregate. Table 4 shows the results of a simple freeze-thaw test on specimens prepared by two methods of vibrator insertion and mixing for low-grade recycled aggregates. The number of cycles at the time of cracking, the dynamic elastic modulus, and The average value of the relative dynamic elastic modulus is shown.

表4 ひび割れ発生時の各位

Figure 0004861610
Table 4 Degree of cracking
Figure 0004861610

JIS−A 1148−2101「コンクリートの凍結融解試験方法」で定められて
いる凍結融解の温度はマイナス18℃で、300サイクルもしくは相対動弾性係数が60
%を切ったときが試験終了である。しかし、ひび割れ発生を目視で確認するまで凍結融解
を続けたので60%を下回る値まで計測した。すべての種類において、3サイクルでひび
割れを確認できた。しかし、相対動弾性係数に着目すると、振動をかけたRVは50%程
度でひび割れが発生したのに対し、練混ぜを延長したRMはほぼ60%を示した。RVシ
リーズのコンクリートの空気量の方がRMのそれと比較して小さいため、RMのほうが凍
害への抵抗性が向上していたためと考えられる。振動機挿入の低度処理再生骨材を使用し
たコンクリートの簡易凍結融解試験の動弾性係数及び相対動弾性係数を図8(a)、(b
)に示す。
The freeze-thaw temperature specified in JIS-A 1148-2101 “Method for Freezing and Thawing Concrete” is minus 18 ° C., and 300 cycles or a relative dynamic elastic modulus is 60.
The test ends when% is cut off. However, since freeze-thaw was continued until the occurrence of cracks was visually confirmed, the value was measured to a value below 60%. In all types, cracks could be confirmed in 3 cycles. However, paying attention to the relative kinematic modulus, cracks occurred when the RV subjected to vibration was about 50%, whereas the RM with prolonged mixing showed almost 60%. The amount of air in the RV series concrete is smaller than that in the RM, which is considered to be because the resistance to frost damage was improved in the RM. Fig. 8 (a) and (b) show the dynamic elastic modulus and relative dynamic elastic modulus of a simple freeze-thaw test for concrete using low-grade recycled aggregate with vibrator insertion.
).

振動機の挿入の有無に関係なく、各サイクルで動弾性係数、及び相対動弾性係数が既
往のものと異なり大きく下がるという結果を得た。これは、液体窒素を用いた簡易凍結融
解試験はマイナス193℃と非常に厳しい環境で行い、さらに超音波伝播時間を測定した
場所(下部から約150mm)が凍結融解の影響を既往のものより受けやすい場所であっ
たため、振動機を挿入したRV−1、RV−3と挿入しないRV−0の圧縮強度差30%
の違いを、簡易凍結融解試験の結果においては認められなかった。
Regardless of whether or not the vibrator was inserted, the dynamic modulus of elasticity and the relative dynamic modulus of elasticity were greatly lowered in each cycle, unlike the conventional ones. This is because the simple freezing and thawing test using liquid nitrogen was conducted in a very severe environment of minus 193 ° C, and the place where the ultrasonic propagation time was measured (about 150 mm from the bottom) was affected by the freezing and thawing from the past. Because it was an easy place, 30% compression strength difference between RV-1 and RV-3 with a vibrator inserted and RV-0 without a vibrator
This difference was not observed in the results of the simple freeze-thaw test.

普通骨材を使用したコンクリートとの比較では、3サイクルで低度処理の再生骨材コ
ンクリートはひび割れが生じたのに対して、普通コンクリートは6サイクルにおいてもひ
び割れが生じず、相対動弾性係数は70%以上であった。また、振動機挿入の有無に関係
なく、相対動弾性係数が2倍の速さで低下した。再生骨材が耐凍害性に劣るという既往の
ものと同様の結果を得た。
Compared with concrete using ordinary aggregate, the recycled aggregate concrete treated at a low level in 3 cycles was cracked, whereas ordinary concrete was not cracked in 6 cycles, and the relative kinematic modulus was It was 70% or more. Moreover, the relative kinematic modulus decreased at twice the speed regardless of whether or not the vibrator was inserted. The same result as that in the past that the recycled aggregate was inferior in frost damage resistance was obtained.

練混ぜ時間を延ばした低度処理再生骨材を使用したコンクリートと、普通骨材を使用
したコンクリートにおける簡易凍結融解試験の動弾性係数、及び相対動弾性係数を図9(
a)、(b)に示す。振動機を挿入したコンクリートの試験結果と同様に、練混ぜ時間を
延ばして作製した供試体においても、普通骨材コンクリートと比較しておよそ2倍の速さ
で動弾性係数は低下した。練混ぜ時間の違いによる動弾性係数への影響も同様に判別は難
しかった。
The dynamic elastic modulus and relative dynamic elastic modulus of the simple freeze-thaw test for concrete using low-grade recycled aggregate with extended mixing time and concrete using ordinary aggregate are shown in Fig. 9 (
Shown in a) and (b). Similar to the test results of the concrete with the vibrator inserted, the dynamic modulus of elasticity of the test piece produced by extending the mixing time decreased at about twice the speed of ordinary aggregate concrete. Similarly, it was difficult to discriminate the influence on the kinematic modulus due to the difference in mixing time.

本発明に使用したミキサーの立面図(a)と側断面図(b)、Elevated view (a) and side sectional view (b) of the mixer used in the present invention, 同上の再生骨材コンクリートのスランプ試験比較図(a)と空気量試験比較図(b)、Slump test comparison diagram of recycled aggregate concrete (a) and air volume test comparison diagram (b), 同上の低度処理骨材使用の振動を与えた場合のコンクリート圧縮強度比較図(a)と練混ぜ時間延長の場合のコンクリート圧縮強度比較図(b)、Concrete compressive strength comparison chart (a) when vibration of low-grade aggregate use is given, and concrete compressive strength comparison chart when mixing time is extended (b), 同上の高度処理骨材使用のの振動を与えた場合のコンクリート圧縮強度比較図、Comparison diagram of concrete compressive strength when vibration of high-processed aggregate is used, 同上の振動の有無による普通骨材使用の場合のコンクリート圧縮強度比較図、Comparison of concrete compressive strength when using normal aggregates with or without vibration 同上の低度処理骨材使用のの振動を与えた場合のビッカース硬度図(a)と練混ぜ時間延長の場合のビッカース硬度図(b)、Vickers hardness diagram (a) when given the vibration of using the low-grade aggregate as above (b) and Vickers hardness diagram (b) when mixing time is extended, 同上の高度処理骨材使用のの練混ぜ時間延長の場合のビッカース硬度図、Vickers hardness diagram in the case of mixing time extension using the high processing aggregate as above, 同上の低度処理骨材使用の振動を与えた場合のサイクル数と動弾性係数の関係図(a)、(b)(A), (b) Relationship diagram between cycle number and kinematic elastic modulus when vibration of low-grade aggregate is used 同上の低度処理骨材使用の練混ぜ時間延長の場合と普通骨材使用の場合の動弾性係数の関係図(a)、相対動弾性係数の関係図(b)。The relational diagram (a) of the dynamic elastic modulus in the case of the mixing time extension using the low-grade treated aggregate and the normal aggregate use, and the relative diagram (b) of the relative dynamic elastic modulus.

符号の説明Explanation of symbols

1…ミキサー     1 ... Mixer

Claims (4)

セメントとコンクリート廃材の再生骨材と水、混和剤の原料を配合し、これらをミキサーで攪拌混練してコンクリートを製造する再生骨材によるコンクリートの製造方法であって、
セメントとコンクリート廃材の低度処理骨材の再生骨材と水、混和剤の原料を配合してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために、棒状の振動機で所定時間にわたって原料に振動を与えて、モルタルの付着をよくしてコンクリートの強度を向上させるようにすることを特徴とする再生骨材によるコンクリートの製造方法。
It is a method for producing concrete by using recycled aggregate, in which recycled aggregate of cement and concrete waste, water, and raw materials of admixture are mixed, and these are stirred and kneaded with a mixer to produce concrete,
Low-treated cement and concrete waste aggregate Recycled aggregate of aggregate, water, and admixture raw materials are mixed in the mixer, and in the middle of kneading in the mixer, stick-shaped to peel off the old powder adhering to the surface of the recycled aggregate A method for producing concrete using recycled aggregate, wherein the vibration is applied to the raw material for a predetermined time to improve adhesion of the mortar and improve the strength of the concrete.
原料を搬入してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために30〜180秒間にわたって原料に振動を与えることを特徴とする請求項1に記載の再生骨材によるコンクリートの製造方法。   2. The regeneration according to claim 1, wherein the raw material is vibrated for 30 to 180 seconds in order to peel off the old powder adhering to the surface of the recycled aggregate during the mixing of the raw material in the mixer. A method for producing concrete using aggregates. 原料を搬入してミキサーでの混練途中に、再生骨材の表面に付着した古い粉体を剥離させるために、30〜180秒間にわたって原料に振動を与えてモルタルの付着をよくし、原料に振動を与えた後、さらに原料を混練することを特徴とする請求項1または2に記載の再生骨材によるコンクリートの製造方法。   In order to peel off the old powder adhering to the surface of the recycled aggregate during the mixing of the raw material and mixing with the mixer, the raw material is vibrated for 30 to 180 seconds to improve the adhesion of the mortar, and the raw material is vibrated. 3. The method for producing concrete using recycled aggregate according to claim 1, wherein the raw material is further kneaded after giving. セメントとコンクリート廃材の再生細骨材をミキサーに投入して30秒間混練し、水、混和剤を混入して60秒間混練し、再生粗骨材を投入して60秒間混練し、これらの原料に振動を与えることを特徴とする請求項1ないし3のいずれかに記載の再生骨材によるコンクリートの製造方法。   Recycled fine aggregate of cement and concrete waste is put into a mixer and kneaded for 30 seconds, mixed with water and admixture for 60 seconds, recycled coarse aggregate is added and kneaded for 60 seconds, and these raw materials are mixed. The method for producing concrete using recycled aggregate according to any one of claims 1 to 3, wherein vibration is applied.
JP2004172820A 2004-06-10 2004-06-10 Method for producing concrete using recycled aggregate Expired - Lifetime JP4861610B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2004172820A JP4861610B2 (en) 2004-06-10 2004-06-10 Method for producing concrete using recycled aggregate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004172820A JP4861610B2 (en) 2004-06-10 2004-06-10 Method for producing concrete using recycled aggregate

Publications (2)

Publication Number Publication Date
JP2005350303A JP2005350303A (en) 2005-12-22
JP4861610B2 true JP4861610B2 (en) 2012-01-25

Family

ID=35585084

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2004172820A Expired - Lifetime JP4861610B2 (en) 2004-06-10 2004-06-10 Method for producing concrete using recycled aggregate

Country Status (1)

Country Link
JP (1) JP4861610B2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5068082B2 (en) * 2007-01-25 2012-11-07 日本原子力発電株式会社 Interlocking block reusing the whole amount of demolished concrete and manufacturing method thereof
JP7090504B2 (en) * 2018-08-08 2022-06-24 株式会社日本触媒 Additives for cement compositions containing recycled aggregate

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09109136A (en) * 1995-10-16 1997-04-28 Mitsubishi Materials Corp Manufacture of mortar or concrete
JP3988974B2 (en) * 2001-02-15 2007-10-10 株式会社浅見製作所 Concrete production method
JP2002338321A (en) * 2001-03-06 2002-11-27 Taiheiyo Cement Corp Concrete composition using regenerated aggregate and product
CN1538900A (en) * 2001-08-03 2004-10-20 ��ʽ����dz�������� Concrete mixer

Also Published As

Publication number Publication date
JP2005350303A (en) 2005-12-22

Similar Documents

Publication Publication Date Title
JP2012025631A (en) Regenerated concrete comprising reclaimed material from waste concrete as main material, and method for producing the same, and method for processing waste concrete for obtaining the reclaimed material
CN103819109A (en) Processing method for waste old rubber powder used for cement-based material
JP2009234863A (en) Recycled aggregate concrete and method for producing the same
CN107759156A (en) A kind of concrete formulation and preparation method and its concrete regenerating technique
JP3555987B2 (en) Recyclable concrete, mortar and recycling method
JP4861610B2 (en) Method for producing concrete using recycled aggregate
JP2019151536A (en) Manufacturing method of recycled coarse aggregate
CN112110664A (en) Method for preparing recycled concrete based on activated water and recycled concrete
EP2085366A2 (en) Method for producing hydraulic binding agent in a form of activated fly ash, activated fly ash, hydraulic binding agent, sulfur or cement concrete, mineral-asphalt mixture and application of the activated fly ash
KR100517202B1 (en) Round polished concrete aggregate utilizing concrete scraps and method of manufacturing the concrete aggregate
Valdez et al. Use of waste from the marble industry as filler for the production of self-compacting concretes
JP2001130944A (en) Freshly mixed concrete
JP2003025321A (en) Method for determining composition of concrete
KR20100071272A (en) Method for manufacturing cement additive using slag from pretreatment of hot meta
JP2001302314A (en) High-toughness, fiber-reinforced concrete and its production process
JP3995087B2 (en) Construction method of steel plate concrete structure
JP4654549B2 (en) Method for producing fine-grained recycled fine aggregate
JP3348380B2 (en) Round polished aggregate and method for producing round polished aggregate
JP5001732B2 (en) Concrete for building foundation ground
JP3305414B2 (en) How to use demolition concrete waste
JPH0354137A (en) Reuse of concrete taken to piece
WO2001038250A1 (en) Production method for abrasive cement
JP5192140B2 (en) Concrete materials and concrete products using waste tile recycled aggregate
JPH1171155A (en) Production of asphalt mixture for pavement
JPH0834654A (en) Production of concrete

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20070605

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20091201

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100608

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100804

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101109

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20110426

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110524

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20111101

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20111107

R150 Certificate of patent or registration of utility model

Ref document number: 4861610

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20141111

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250