JP4847376B2 - Method for producing coated paper for offset printing and coated paper - Google Patents

Method for producing coated paper for offset printing and coated paper Download PDF

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JP4847376B2
JP4847376B2 JP2007071151A JP2007071151A JP4847376B2 JP 4847376 B2 JP4847376 B2 JP 4847376B2 JP 2007071151 A JP2007071151 A JP 2007071151A JP 2007071151 A JP2007071151 A JP 2007071151A JP 4847376 B2 JP4847376 B2 JP 4847376B2
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paper
coated
base paper
coated paper
offset printing
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裕 鈴木
敬人 目黒
仁 桑野
正雄 三上
勤 佐藤
耕作 小林
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Hokuetsu Kishu Paper Co Ltd
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本発明は、印刷塗被紙の製造方法に関し、特にギャップフォーマーとシュープレスを組み合わせた抄紙機で抄紙された原紙を使用した、効率のよいオフセット印刷用塗被紙の製造方法及びその塗被紙に関するもので、白紙、印刷物にヒジワなどの波打ち現象の発生のない外観上に優れた塗被紙を製造する技術に関する。   TECHNICAL FIELD The present invention relates to a method for producing a coated coated paper, and more particularly to a method for producing a coated paper for offset printing using a base paper produced by a paper machine that combines a gap former and a shoe press, and the coating thereof. The present invention relates to a paper, and relates to a technique for producing a coated paper excellent in appearance without occurrence of a wavy phenomenon such as a wrinkle on a white paper or printed matter.

近年、省力化傾向と相まって、抄紙機の高速化、大型化への要求はますます高まっている。そして、最新の抄紙機では、抄造速度1000m/分以上での操業が一般的となっている。また抄紙部、塗被部、仕上げ部が一体となったオンマシン製造設備も一般的となっている。   In recent years, coupled with the labor-saving trend, demands for higher speed and larger paper machines are increasing. And in the latest paper machine, operation with a paper making speed of 1000 m / min or more is common. An on-machine manufacturing facility in which a papermaking part, a coating part, and a finishing part are integrated is also common.

ところで、このような高速化、大型化へ移行するにあたって、その抄紙方式、特に抄紙機のワイヤーパートとプレスパートの変革が大きく寄与している。   By the way, in making a shift to such high speed and large size, the change of the paper making method, particularly the wire part and press part of the paper machine, greatly contributes.

すなわち、ワイヤーパートを具備した抄紙機としては、従来、主として使用されている、上方が自由で下方にのみ長網(抄紙ワイヤー)を通して脱水を行う長網抄紙機といわれるもの、次いで長網抄紙機の長網の後半部の上方にループをなすトップワイヤーを配置して、その部分では上下で脱水が行われるツインワイヤーによる抄紙方式のオントップフォーマー型又はハイブリットフォーマー型抄紙機といわれるものが実用化されている。特に、このツインワイヤーの開発が抄紙機の高速化を可能とした1つの要因でもある。   That is, as a paper machine equipped with a wire part, a so-called long-mesh paper machine that is mainly used in the past and performs dewatering through a long mesh (paper-making wire) only in the upper part and freely in the lower part, and then a long-mesh machine. A top wire that forms a loop is placed above the second half of the long net, and the so-called on-top former type or hybrid former type paper machine using twin wire, in which dewatering is performed at the top and bottom, It has been put into practical use. In particular, the development of this twin wire is one factor that has made it possible to increase the speed of paper machines.

しかしながら、ハイブリットフォーマー型抄紙機の場合であっても、さらに高速化を図ると、トップワイヤーより前半、所謂従来の長網部に相当する部分で、相対的にパルプ濃度の低い初期脱水部分での紙料のジャンピングや乱れが発生し、結果として、得られる紙の地合が極めて劣ったものとなり商品価値が低下するという問題があった。   However, even in the case of a hybrid former type paper machine, if the speed is further increased, the first half of the top wire, the part corresponding to the so-called conventional long net part, the initial dewatering part having a relatively low pulp concentration. As a result, there was a problem that the resulting paper was extremely inferior and the product value was lowered.

そこで考案されたのが、ハイブリットフォーマー型抄紙機におけるトップワイヤーからなる脱水ゾーンを、下部のボトムワイヤー部分と同規模に大きくし、つまり従来の長網式のように下方からの脱水機構を殆んどとることなく、インレットを出た紙料が当初から2枚(上下)のワイヤー間に流入し、それらワイヤーの両側(外側)へ脱水が推進されるようにした構成をとる、所謂ギャップフォーマー型抄紙機と呼ばれる、ツインワイヤーによる脱水機構をとる抄紙機である。   Therefore, the dewatering zone consisting of the top wire in the hybrid former type paper machine was devised to be the same size as the bottom wire portion in the lower part, that is, the dewatering mechanism from the lower side was almost the same as the conventional long net type. It is a so-called gap-forth structure in which the stock discharged from the inlet flows between two wires (upper and lower) from the beginning, and dehydration is promoted to both sides (outside) of the wires. It is a paper machine that uses a twin wire dewatering mechanism, called a mer type paper machine.

このギャップフォーマー型抄紙機は、トップワイヤーとボトムワイヤーで形成されるギャップ(くさび状の開口部)にインレットより吐出された紙料を供給することによって、インレットを出た直後から紙料が2枚(上下)のワイヤーに挟まれた状態で脱水、紙層が形成されていくので、前記のハイブリッドフォーマー型抄紙機の場合のように原料の乱れを誘発することなく、均一な紙層形成ができるものとして、高く評価されている。   In this gap former type paper machine, by supplying the paper material discharged from the inlet to the gap (wedge-shaped opening) formed by the top wire and the bottom wire, 2 A dehydrated paper layer is formed in the state of being sandwiched between sheets (upper and lower) of wire, so a uniform paper layer can be formed without inducing material disturbance as in the case of the hybrid former type paper machine. It is highly appreciated that it can.

また、プレスパートにおいても、高速化への対応として、シュープレスが導入されている。シュープレスは、湿紙を脱水させるもので通常2基使用されるが、1基目はフェルト−フェルトの組み合わせ、2基目はフェルト−ベルトの組み合わせで使用されることが多い。これによって、高速での脱水効率の向上、高速での走行安定性に寄与し、更には最終製品の水分プロファイルにも優れたものとなる。   Also, in the press part, a shoe press is introduced as a measure for speeding up. The shoe press is used to dehydrate the wet paper and is usually used in two units, but the first unit is often used as a felt-felt combination and the second unit is used as a felt-belt combination. This contributes to improved dewatering efficiency at high speed, running stability at high speed, and excellent moisture profile of the final product.

しかしながら、このギャップフォーマーとシュープレスを組み合わせた抄紙機で抄紙し、その後にフィルムメタリングサイズプレスによって接着剤を塗布した原紙を用いて、塗被液(水性塗被組成物)を塗被し、乾燥させてオフセット輪転(以後、「オフ輪」と称す。)印刷用塗被紙に仕上げた場合、オフ輪印刷時に、ブリスターが発生し易いといった難点を抱えている。   However, paper is made with a paper machine that combines this gap former and shoe press, and then a coating liquid (aqueous coating composition) is applied using a base paper coated with an adhesive by a film metering size press. In the case of being dried and finished in a coated paper for offset printing (hereinafter referred to as “off-wheel”), there is a problem that blisters are likely to occur during off-wheel printing.

同時にギャップフォーマー型抄紙機で抄紙された原紙は、インレットから吐出された後、2枚のトップワイヤーとボトムワイヤーで脱水、紙層形成がなされるため、紙の縦横比が大きい。そして、塗被紙の製造においてフィルムメタリングサイズプレス装置などによる水性液の塗布やブレード塗工機などによる塗被液(水性塗被組成物)の塗被がなされると、原紙への水の吸収・乾燥、ドローなどの紙の引っ張りによって、紙の幅方向の伸縮が著しく生じ、白紙又はオフ輪印刷物の紙面にヒジワなどの波打ち現象も発生し易いといった難点も抱えている。このヒジワなどの波打ち現象は、原紙坪量が少ないほど顕著に発生する。   At the same time, the base paper produced by the gap former type paper machine is discharged from the inlet and then dehydrated and a paper layer is formed by the two top wires and the bottom wire, so that the aspect ratio of the paper is large. Then, in the production of coated paper, when an aqueous liquid is applied by a film metering size press apparatus or a coating liquid (aqueous coating composition) is applied by a blade coating machine, Stretching in the width direction of the paper is significantly caused by pulling of the paper such as absorption, drying, and drawing, and there is also a problem that a wavy phenomenon such as wrinkles is likely to occur on the paper surface of the white paper or the off-ring printed matter. The wavy phenomenon such as wrinkles is more prominent as the base paper basis weight is smaller.

ここに、ブリスターとは、両面塗被紙をオフ輪印刷機にかけて、印刷、熱乾燥する過程で該塗被紙中の水分が急激な加熱によって水蒸気化して紙層内部から外へ出る際に、その水蒸気圧で紙層内部に亀裂等を生じさせることによって起こる層間剥離現象である。そして、ブリスターは製品価値を著しく低下させる。また、ヒジワとは、オフ輪印刷で両面に高濃度の絵柄を印刷した場合、用紙の流れ方向に沿って発生するシワのことをいう。   Here, the blister is when the moisture in the coated paper is vaporized by rapid heating in the process of printing and heat drying on a double-sided coated paper on an off-wheel printer, This is a delamination phenomenon that occurs by causing cracks or the like inside the paper layer by the water vapor pressure. And blisters significantly reduce product value. In addition, wrinkles refer to wrinkles that occur along the paper flow direction when high-density images are printed on both sides by off-ring printing.

このようなギャップフォーマー型抄紙機で得られた原紙特有の欠点を改善するために種々の提案が出されている。例えば、ギャップフォーマー型抄紙機で抄紙された原紙に、フィルムメタリングタイプのサイズプレス装置で、接着剤を主成分とする固形分濃度が2〜12重量%の水性液が塗布、乾燥されてなる原紙の提案がなされている(例えば特許文献1を参照。)。   Various proposals have been made in order to improve the defects inherent to the base paper obtained with such a gap former type paper machine. For example, an aqueous liquid having a solid content concentration of 2 to 12% by weight, mainly composed of an adhesive, is applied to a base paper produced by a gap former type paper machine and dried using a film metalling type size press. There is a proposal of a base paper (see, for example, Patent Document 1).

特許第3744115号公報Japanese Patent No. 3744115

特許文献1に記載のこの方法によればブリスターはある程度解消される。しかし、もう一方の問題である白紙又は印刷物紙面にヒジワなどの波打ち現象が発生する現象に関しては未だ解決できてない。   According to this method described in Patent Document 1, blisters are eliminated to some extent. However, it has not been possible to solve the other problem, ie, a phenomenon in which a wavy phenomenon such as a wrinkle occurs on the surface of white paper or printed paper.

そこで本発明の目的は、ギャップフォーマーとシュープレスを組み合わせた抄紙機で抄紙された塗被紙の乾燥工程後のヒジワなどの波打ち現象を抑制し、かつ、オフ輪印刷時の耐ブリスター性をも有する塗被紙を提供することである。   Therefore, the object of the present invention is to suppress wavy phenomenon such as wrinkles after the drying process of the coated paper made by a paper machine combining a gap former and a shoe press, and to improve blister resistance during off-wheel printing. It is to provide a coated paper which also has.

本発明者らは、上記課題を解決するために、原紙に固形分濃度が13〜20質量%の接着剤を主成分とする水性液を塗布、乾燥することでブリスター及びヒジワの発生を抑制できることを見出し、本発明を完成させた。すなわち、本発明に係るオフセット印刷用塗被紙の製造方法は、顔料及び接着剤を主成分とする水性塗被組成物を原紙に塗被し、乾燥して仕上げるオフセット印刷用塗被紙の製造方法において、前記原紙として、ギャップフォーマーとシュープレスとを組み合わせた抄紙機で抄紙した紙匹に、フィルムメタリングサイズプレス装置を使用して、接着剤として澱粉を主成分とし接着剤固形分濃度が13〜20質量%で、粘度が、固形分濃度20質量%、温度50℃でB型粘度60rpmの測定条件にて、100mPa・s以下である水性液が、両面で1.0〜3.0g/m の乾燥塗布量で、塗布、乾燥されてなる原紙を用い、かつ、前記原紙が、ブレード塗工機で塗被、乾燥される手前の工程において、カレンダー設備によって平滑化されることを特徴とする。 In order to solve the above-mentioned problems, the present inventors can suppress the generation of blisters and wrinkles by applying and drying an aqueous liquid mainly composed of an adhesive having a solid content of 13 to 20% by mass on a base paper. The present invention was completed. That is, the method for producing a coated paper for offset printing according to the present invention is a method for producing a coated paper for offset printing in which an aqueous coating composition mainly composed of a pigment and an adhesive is coated on a base paper and dried. In the method, as the base paper, on a paper sheet made by a paper machine combining a gap former and a shoe press, using a film metalizing size press apparatus, starch as a main ingredient and adhesive solid content concentration Is an aqueous liquid having a viscosity of 13 to 20% by mass, a solid content concentration of 20% by mass, a temperature of 50 ° C., and a B-type viscosity of 60 rpm . Using a base paper that has been applied and dried at a dry coating amount of 0 g / m 2 , and the base paper is smoothed by a calendar facility in a step before being coated and dried by a blade coating machine. It is characterized by that.

前記接着剤を主成分とする水性液の粘度をこのような範囲とするのは、接着剤を主成分とする固形分濃度が13〜20質量%の水性液を両面で乾燥塗布量として1.0〜3.0g/m塗布するのに適しているからである The viscosity of the aqueous liquid containing the adhesive as a main component is set in such a range as follows: 1. An aqueous liquid containing an adhesive as a main component and having a solid content concentration of 13 to 20% by mass is dry coated on both sides. It is because it is suitable to apply 0-3.0 g / m 2 .

前記接着剤を主成分とする水性液の乾燥塗布量をこのような範囲とするのは、ブリスターの発生をより抑制できるからである Wherein to a dry coating amount of the aqueous solution mainly composed of an adhesive in such a range is because it further suppress the occurrence of blisters.

レード塗工機で塗被、乾燥される手前の工程において、カレンダー設備によって原紙を平滑化するのは、オフ輪印刷後のヒジワの発生をより抑制することができるからである
Coated in blade coating machine, in front of the step to be dried, to smooth the sheet by calendering equipment, because it is possible to further suppress the occurrence of Hijiwa after offset printing.

本発明に係るオフセット印刷用塗被紙の製造方法では、前記水性塗被組成物が固形分濃度65質量%以上の塗被液であり、前記原紙が該水性塗被組成物を塗被されて乾燥されることが好ましい。ヒジワを助長すると考えられる水分量を減らすことができる。   In the method for producing a coated paper for offset printing according to the present invention, the aqueous coating composition is a coating liquid having a solid content concentration of 65% by mass or more, and the base paper is coated with the aqueous coating composition. It is preferable to be dried. It can reduce the amount of water that is thought to promote hydrangea.

本発明に係るオフセット印刷用塗被紙の製造方法では、前記原紙の坪量が35〜70g/mであることが好ましい。 In the manufacturing method of the coated paper for offset printing which concerns on this invention, it is preferable that the basic weight of the said base paper is 35-70 g / m < 2 >.

本発明に係るオフセット印刷用塗被紙の製造方法では、抄紙による原紙抄造工程と前記原紙への水性塗被組成物の塗被工程と仕上げ処理する工程とが一体となったオンマシン製造設備によって製造されることが好ましい。   In the method for producing a coated paper for offset printing according to the present invention, an on-machine production facility in which a base paper making process using paper making, a coating process of an aqueous coating composition on the base paper, and a finishing process are integrated. Preferably it is manufactured.

本発明に係るオフセット印刷用塗被紙は、本発明に係るオフセット印刷用塗被紙の製造方法によって製造されたことを特徴とする。   The coated paper for offset printing according to the present invention is manufactured by the method for producing a coated paper for offset printing according to the present invention.

本発明のオフセット印刷用塗被紙の製造方法によれば、ギャップフォーマーとシュープレスを組み合わせた抄紙機で抄紙された塗被紙の乾燥工程後のヒジワなどの波打ち現象が抑制され、かつ、オフ輪印刷時の耐ブリスター性をも有する塗被紙が得られる。   According to the method for producing a coated paper for offset printing of the present invention, undulation phenomena such as wrinkles after the drying process of the coated paper produced by a paper machine combining a gap former and a shoe press are suppressed, and A coated paper having blister resistance at the time of off-wheel printing can be obtained.

本実施形態に係るオフセット印刷用塗被紙の製造方法は、顔料及び接着剤を主成分とする水性塗被組成物を原紙に塗被し、乾燥して仕上げるオフセット印刷用塗被紙の製造方法において、前記原紙として、ギャップフォーマーとシュープレスとを組み合わせた抄紙機で抄紙した紙匹に、フィルムメタリングサイズプレス装置を使用して、接着剤を主成分とし接着剤固形分濃度が13〜20質量%の水性液が塗布、乾燥されてなる原紙を用いる。   The method for producing a coated paper for offset printing according to the present embodiment is a method for producing a coated paper for offset printing in which an aqueous coating composition mainly composed of a pigment and an adhesive is coated on a base paper and dried. In this case, as the base paper, a sheet metal made by a paper machine combining a gap former and a shoe press is used, and a film metalling size press apparatus is used, and an adhesive is a main component and an adhesive solid content concentration is 13 to 13. A base paper formed by applying and drying a 20% by mass aqueous liquid is used.

[作用]
紙匹にフィルムメタリングサイズプレス装置によって、接着剤を主成分とし接着剤固形分濃度が13〜20質量%の水性液を両面絶乾で1.0〜3.0g/m、好ましくは1.5〜2.5g/mで塗布し、乾燥を行い、原紙として仕上げる。この原紙は、ブレード塗工する前にカレンダー処理し、平滑化しても良い。オフ輪印刷後のヒジワの発生をより抑制することができる。
[Action]
An aqueous liquid containing an adhesive as a main component and having an adhesive solid content concentration of 13 to 20% by mass is dry-dried at 1.0 to 3.0 g / m 2 on both sides by a film metalizing size press on a paper web, preferably 1 Apply at 5 to 2.5 g / m 2 , dry and finish as a base paper. This base paper may be smoothed by calendaring before blade coating. Occurrence of wrinkles after off-wheel printing can be further suppressed.

その後、この原紙に1層の塗被層を設ける塗被工程において、平均粒子径が0.8〜1.2μmの重質炭酸カルシウムを60〜100質量部用い、固形分65質量%以上、好ましくは70〜90質量%の水性塗被組成物を用い、片面の塗被量が8〜13g/m、好ましくは9〜12g/mとなるよう両面塗被し仕上げた時に、白紙、印刷後のヒジワなどの波打ち現象のない外観に優れた印刷用塗被紙を提供できる。 Thereafter, in the coating step of forming a single coating layer on the base paper, 60 to 100 parts by mass of heavy calcium carbonate having an average particle size of 0.8 to 1.2 μm is used, and the solid content is 65% by mass or more, preferably Is 70 to 90% by weight aqueous coating composition, and when coated on both sides so that the coating amount on one side is 8 to 13 g / m 2 , preferably 9 to 12 g / m 2 , It is possible to provide a coated paper with excellent appearance that does not have a wavy phenomenon such as later wrinkles.

紙匹にフィルムメタリングサイズプレス装置で接着剤を主成分とする水性液を塗布するにあたっては、接着剤固形分濃度が13〜20質量%、好ましくは15〜18質量%の水性液を塗布した原紙に、ブレード塗工機で固形分濃度65%質量以上の水性塗被組成物を塗被することが重要である。必要に応じて水性液に顔料や接着剤成分以外の物質を配合することも可能である。その際、水性液の固形分濃度は上昇するが、接着剤の固形分濃度については13〜20質量%の範囲であることが必要である。   When applying an aqueous liquid mainly composed of an adhesive to a paper sheet using a film metalizing size press, an aqueous liquid having an adhesive solid content concentration of 13 to 20% by mass, preferably 15 to 18% by mass was applied. It is important to coat the base paper with an aqueous coating composition having a solid content concentration of 65% by mass or more with a blade coating machine. If necessary, substances other than pigments and adhesive components can be blended in the aqueous liquid. At that time, the solid content concentration of the aqueous liquid increases, but the solid content concentration of the adhesive needs to be in the range of 13 to 20% by mass.

一般的にフィルムメタリングサイズプレス装置を使用し、接着剤を主成分とする水性液を塗布し、原紙の内部結合強度を向上させることで、オフ輪印刷時のブリスター性に効果があることが知られている。   In general, using a film metering size press machine, applying an aqueous liquid mainly composed of an adhesive, and improving the internal bond strength of the base paper may have an effect on the blister properties during off-wheel printing. Are known.

しかしながら、ギャップフォーマーとシュープレスを組み合わせた場合、フィルムメタリングサイズプレス装置で接着剤を塗布すると、白紙面に波打ったようなヒジワと呼ばれる現象が発生し、印刷前の白紙面では目立たないもののオフ輪印刷を掛けた場合に顕在化してくる現象が見られる。このヒジワの現象を抑えながら、ブリスターの発生も抑えるためには、接着剤を主成分とする固形分濃度が13〜20質量%の水性液を、乾燥塗布量として両面で1.0〜3.0g/m塗布するのが最適である。接着剤を主成分とする水性液の固形分濃度が20質量%を超える場合は、塗布量コントロールが難しくなり、紙離れの不安定化にもつながる。特にこれらの現象は、高速での塗布で顕著になり、塗布ムラなどを発生する恐れがある。一方で紙匹にフィルムメタリングサイズプレス装置を使用して接着剤を主成分とする水性液の固形分濃度が13質量%未満の水性液を塗布、乾燥する場合は、ヒジワなどの波打ち現象が生じるなどの問題がある。これは、紙の縦横比の大きいギャップフォーマーで抄紙した紙匹に、固形分濃度の低い水性液をフィルムメタリングサイズプレス装置で塗布した場合に、水性液の浸透によって紙の幅方向に伸縮が生じ、その結果ヒジワなどの波打ち現象が生じるものであると推測される。また、ヒジワなどの波打ち現象は、原紙坪量が少ないほど顕著に発生する。 However, when a gap former is combined with a shoe press, a phenomenon called wrinkles that rippled on the white paper surface occurs when the adhesive is applied with a film metering size press device, which is inconspicuous on the white paper surface before printing. There is a phenomenon that becomes apparent when off-wheel printing is applied. In order to suppress the occurrence of blisters while suppressing the phenomenon of wrinkles, an aqueous liquid having a solid content concentration of 13 to 20% by mass containing an adhesive as a main component is 1.0 to 3. It is optimal to apply 0 g / m 2 . When the solid content concentration of the aqueous liquid containing an adhesive as a main component exceeds 20% by mass, it becomes difficult to control the coating amount, leading to destabilization of paper separation. In particular, these phenomena become conspicuous when applied at a high speed, and there is a possibility of causing uneven coating. On the other hand, when using a film metering size press on a paper web and applying and drying an aqueous liquid having a solid content concentration of less than 13% by mass of an aqueous liquid mainly composed of an adhesive, a wavy phenomenon such as wrinkles may occur. There are problems, such as occurring. This is because when an aqueous liquid with a low solid content concentration is applied to a paper base made with a gap former with a large aspect ratio of the paper with a film metering size press device, the aqueous liquid penetrates and expands and contracts in the width direction of the paper. As a result, it is presumed that a wavy phenomenon such as a wrinkle occurs. Further, the waviness phenomenon such as wrinkles is more prominent as the base paper basis weight is smaller.

接着剤を主成分とする固形分濃度が13〜20質量%の水性液の乾燥塗布量が、両面3.0g/mを超える場合は、塗被紙の透気度が高くなり、耐ブリスター性の低下につながる恐れがある。一方、当該水性液の乾燥塗布量が両面1.0g/m未満の場合は、内部結合強度が低下し、ブリスターの発生が抑えられない場合がある。 When the dry coating amount of an aqueous liquid having a solid content concentration of 13 to 20% by mass with an adhesive as the main component exceeds 3.0 g / m 2 on both sides, the air permeability of the coated paper increases and blister resistance May lead to a decline in sex. On the other hand, when the dry coating amount of the aqueous liquid is less than 1.0 g / m 2 on both sides, the internal bond strength is lowered, and the generation of blisters may not be suppressed.

接着剤を主成分とする固形分濃度が13〜20質量%の水性液を乾燥塗布量として両面で1.0〜3.0g/m塗布するためには、固形分濃度20質量%、温度50℃でB型粘度計60rpmでの測定値が100mPa・s以下、好ましくは30〜80mPa・sの澱粉が適している。 In order to apply an aqueous liquid having a solid content concentration of 13 to 20% by mass based on an adhesive as a dry coating amount on both sides of 1.0 to 3.0 g / m 2 , a solid content concentration of 20% by mass, temperature A starch having a measured value at 50 ° C. with a B-type viscometer of 60 rpm is 100 mPa · s or less, preferably 30 to 80 mPa · s is suitable.

さらに、ブレード塗工機での塗被液である水性塗被組成物の固形分濃度を65質量%以上にすることが、ヒジワを助長すると考えられる水性塗被組成物の水分量を減らす観点から重要である。高速時の流動性のよい重質炭酸カルシウムを多く使用し、水性塗被組成物の固形分濃度を高くすることが望まれる。   Furthermore, from the viewpoint of reducing the water content of the aqueous coating composition, which is considered to promote the generation of wrinkles, by setting the solid content concentration of the aqueous coating composition that is the coating liquid in the blade coating machine to 65% by mass or more. is important. It is desired to use a large amount of heavy calcium carbonate with good fluidity at high speed to increase the solid content concentration of the aqueous coating composition.

かくして、ギャップフォーマーとシュープレスを組み合わせた抄紙機による抄紙・塗被・仕上げされた塗被紙で、白紙面のヒジワなどの波打ち現象がなく、オフ輪印刷時の耐ブリスター性を有し、かつ、ヒジワなどの波打ち現象の発生が無い塗被紙を得ることができる。   Thus, it is a coated paper that has been made, coated, and finished by a paper machine that combines a gap former and a shoe press, has no wavy phenomenon such as wrinkles on the white paper surface, and has blister resistance during off-wheel printing, In addition, it is possible to obtain a coated paper free from the occurrence of waviness such as wrinkles.

以下に本発明に関するオフセット印刷用塗被紙の製造方法の好ましい態様例を挙げて具体的に説明する。   Hereinafter, preferred embodiments of the method for producing offset-coated coated paper according to the present invention will be described in detail.

本発明に用いられる塗被原紙は、広葉樹晒クラフトパルプ、針葉樹晒クラフトパルプ等の化学パルプ、GP、TMP等の機械パルプや古紙由来のパルプを適宜原料として用い、公知のギャップフォーマーとシュープレスを組み合わせた抄紙機を用いて、二枚のワイヤーで脱水作用をもつ機構の付いたギャップフォーマーで抄紙後、1基又は2基のシュープレスで脱水されて得られる。そして塗被原紙は、酸性紙、中性紙を包含するものである。原紙を、坪量が35〜70g/m、好ましくは40〜65g/mとなるように抄紙することが好ましい。原紙の坪量が35g/m未満であると、高速での抄造が難しくなる。一方、原紙の坪量が70g/mを超えると、ヒジワの発生がなくなる場合がある。塗被原紙中には、カチオン澱粉、ポリアクリルアマイド等の紙力増強剤、ロジンサイズ、アルケニル無水琥珀酸、アルキルケテンダイマー、合成サイズ剤等のサイズ剤、タルク、炭酸カルシウム、合成ゼオライト、チタン等の填料及びコロイダルシリカ、ポリアクリルアマイド、ポリエチレンオキサイド等の歩留まり向上剤、濾水剤等の抄紙補助薬品が含まれる。 The coated base paper used in the present invention is made of chemical pulp such as hardwood bleached kraft pulp, softwood bleached kraft pulp, mechanical pulp such as GP and TMP, and pulp derived from waste paper as a raw material, and a known gap former and shoe press Using a paper machine with a combination of, the paper is made with a gap former having a mechanism of dehydrating action with two wires, and then dehydrated with one or two shoe presses. The coated base paper includes acid paper and neutral paper. It is preferable to make a base paper so that the basis weight is 35 to 70 g / m 2 , preferably 40 to 65 g / m 2 . If the basis weight of the base paper is less than 35 g / m 2 , papermaking at high speed becomes difficult. On the other hand, if the basis weight of the base paper exceeds 70 g / m 2 , generation of wrinkles may be lost. In coated base paper, paper strength enhancers such as cationic starch and polyacrylamide, sizing agents such as rosin size, alkenyl succinic anhydride, alkyl ketene dimer, synthetic sizing agent, talc, calcium carbonate, synthetic zeolite, titanium, etc. And a paper making aid such as a yield improver such as colloidal silica, polyacrylamide, and polyethylene oxide, and a filtering agent.

プレスパートで脱水された湿紙は、プレドライヤーパートに移行し、乾燥される。プレドライヤーパートは、通常オープンドローのないシングルデッキドライヤーが用いられる。   The wet paper dehydrated in the press part is transferred to the pre-dryer part and dried. For the pre-dryer part, a single deck dryer without an open draw is usually used.

プレドライヤー後、フィルムメタリングサイズプレス装置で澱粉などの接着剤を主成分とする水性液が塗布され、乾燥される。   After the pre-dryer, an aqueous liquid mainly composed of an adhesive such as starch is applied and dried with a film metalizing size press.

フィルムメタリングサイズプレスに使用される前記水性液に含有させる接着剤としては、例えば、熱化学変性澱粉、カルバミン酸澱粉、酸化澱粉、エステル化澱粉などがある。必要に応じて、顔料や接着剤成分以外の物質を配合することも可能である。   Examples of the adhesive contained in the aqueous liquid used in the film metering size press include thermochemically modified starch, carbamic acid starch, oxidized starch, and esterified starch. If necessary, substances other than pigments and adhesive components can be blended.

ブレード塗工機で用いる印刷用塗被紙用の水性塗被組成物の顔料としては、カオリン、軽質炭酸カルシウム、重質炭酸カルシウム、サチンホワイト、酸化チタン、水酸化アルミニウム、タルク、シリカ、プラスチックピグメントなどが挙げられる。   Examples of pigments for aqueous coating compositions for printing coated paper used in blade coating machines include kaolin, light calcium carbonate, heavy calcium carbonate, satin white, titanium oxide, aluminum hydroxide, talc, silica, and plastic pigment. Etc.

また、本発明で用いるバインダーは、特に制限されるものではなく、公知のバインダーを用いることができる。例えば、スチレン・ブタジエン系、スチレン・アクリル系、酢酸ビニル・アクリル系、ブタジエン・メチルメタクリル系などの各種共重合体ラテックス、又は、ポリビニルアルコール、酸化澱粉、エステル化澱粉、熱化学変性澱粉、酵素変性澱粉やそれらをフラッシュドライして得られる冷水可溶性澱粉、カゼイン、デキストリンなどから選択して単独又は2種類以上を適宜混合して使用することができる。   The binder used in the present invention is not particularly limited, and a known binder can be used. For example, various copolymer latexes such as styrene / butadiene, styrene / acrylic, vinyl acetate / acrylic, butadiene / methylmethacrylic, or polyvinyl alcohol, oxidized starch, esterified starch, thermochemically modified starch, enzyme modified It can be selected from starch, cold water soluble starch obtained by flash drying them, casein, dextrin and the like alone or in combination of two or more.

前記共重合体ラテックスとしては、スチレン、α―メチルスチレンなどの芳香族ビニル単量体、1,3ブタジエン、2−メチル−1,3ブタジエンなどの脂肪族共役ジエン系単量体、アクリル酸、メタクリル酸などのエチレン性不飽和酸単量体、アクリロニトリル単量体、又は、エチレン性不飽和カルボン酸アルキルエステル、エチレン性不飽和カルボン酸アミド、他の有機カルボン酸若しくはその誘導体などの共重合可能な単量体を公知の方法で共重合して得られるもので、好ましくはスチレン・ブタジエン・メタクリル酸メチル・アクリロニトリル共重合体である。   Examples of the copolymer latex include aromatic vinyl monomers such as styrene and α-methylstyrene, aliphatic conjugated diene monomers such as 1,3 butadiene and 2-methyl-1,3 butadiene, acrylic acid, Copolymerization of ethylenically unsaturated acid monomers such as methacrylic acid, acrylonitrile monomers, ethylenically unsaturated carboxylic acid alkyl esters, ethylenically unsaturated carboxylic acid amides, other organic carboxylic acids or their derivatives And a styrene / butadiene / methyl methacrylate / acrylonitrile copolymer.

上述した顔料、ラテックスを含む水性塗被組成物の塗被方法は、ブレード塗工機によって塗被される。そして、塗被原紙に1層の塗被層を設けた、オンマシンで塗被された印刷用塗被紙が得られる。このようにして塗被された印刷用塗被紙は、公知の乾燥機で乾燥された後に、スーパーカレンダーやソフトカレンダーのような表面の仕上げ設備で平滑化処理される。   The coating method of the aqueous coating composition containing the pigment and latex described above is applied by a blade coating machine. Then, an on-machine coated printing paper having a coating layer provided on the coated base paper is obtained. The coated paper for printing thus coated is dried by a known dryer and then smoothed by a surface finishing facility such as a super calender or a soft calender.

本発明のオフセット印刷用塗被紙の製造方法では、1000m/分以上の抄造速度で操業される抄紙機に対応でき、特に抄紙による原紙抄造工程と原紙への水性塗被組成物の塗被工程と仕上げ処理する工程とが一体となったオンマシン製造設備を用いて、オフセット印刷用塗被紙を得る場合に、耐ブリスター性を付与しつつ、ヒジワの発生を抑制できる。   The method for producing a coated paper for offset printing according to the present invention can be applied to a paper machine operated at a paper making speed of 1000 m / min or more, and in particular, a base paper making process by paper making and a coating process of an aqueous coating composition on the base paper. When the coated paper for offset printing is obtained using an on-machine manufacturing facility in which the finishing process and the finishing process are integrated, generation of wrinkles can be suppressed while providing blister resistance.

以下に実施例を挙げて本発明をより具体的に説明するが、勿論本発明はこれによって限定されるものではない。なお、以下において%とあるのは、全て質量%を示す。水性塗被組成物(塗被液)の配合は部数で示す。   Hereinafter, the present invention will be described more specifically with reference to examples. However, the present invention is not limited thereto. In the following description,% means mass%. The formulation of the aqueous coating composition (coating solution) is shown in parts.

(実施例1)
フリーネス450mlcsf(カナダ標準ろ水度)の広葉樹さらしクラフトパルプ100%の木材パルプ原料に、絶乾パルプ質量当たりで軽質炭酸カルシウム(商標TP121 奥多摩工業社製)の含有量が10%となるよう添加し、更に中性ロジンサイズ剤(商標CC167 星光PMC社製)0.2%を添加し、ワイヤーパート部がメッツオペーパー社製ギャップフォーマー、プレスパート部がメッツオペーパー社製タンデムシュープレスを用い、1基目がフェルト−フェルト、2基目がフェルト−ベルトでの脱水後、オープンドローがないシングルデッキドライヤーによって乾燥させて、坪量45g/mの紙匹を抄造した。さらに、該紙匹をメッツオペーパー社製のフィルムメタリングサイズプレス装置オプチサイザーを用いて、接着剤を主成分とする固形分濃度が14質量%の水性液を乾燥塗布量として1.4g/m両面塗布・乾燥した後、カレンダーで原紙を平坦化した塗被原紙を得た。該原紙について、ブレード塗工機を用い1600m/分の塗被速度で、片面乾燥塗被量10g/mとなるように両面に水性塗被組成物を塗被した後、乾燥し、ニップ線圧240kg/cm、ロール温度85℃、700m/分の処理速度でスーパーカレンダー処理して実施例1の印刷用塗被紙を仕上げた。
Example 1
Freeness 450ml csf (Canadian standard freeness) hardwood bleached kraft pulp 100% wood pulp raw material is added so that the content of light calcium carbonate (trademark TP121 Okutama Kogyo Co., Ltd.) is 10% per mass of dry pulp Furthermore, 0.2% of neutral rosin sizing agent (trademark CC167, manufactured by Seiko PMC Co., Ltd.) was added, the wire part part was a gap former made by Metso Paper, and the press part part was a tandem shoe press made by Metso Paper. After the dehydration with the first group felt-felt and the second group felt-belt, the sheet was dried with a single deck dryer having no open draw to produce a paper sheet having a basis weight of 45 g / m 2 . Further, the paper sheet was measured by using a film metalizing size press apparatus opticizer manufactured by Metso Paper Co., Ltd., and an aqueous liquid having a solid content concentration of 14% by mass based on an adhesive as a dry coating amount of 1.4 g / After m 2 double-sided coating and drying, a coated base paper obtained by flattening the base paper with a calendar was obtained. The base paper is coated with an aqueous coating composition on both sides at a coating speed of 1600 m / min using a blade coating machine so that the dry coating amount on one side is 10 g / m 2, and then dried. The coated paper for printing of Example 1 was finished by supercalendering at a pressure of 240 kg / cm, a roll temperature of 85 ° C., and a processing speed of 700 m / min.

実施例1において、フィルムメタリングサイズプレス装置で使用した水性液の配合及びブレード塗工機で使用した水性塗被組成物の配合を、次のとおりとした。
(フィルムメタリングサイズプレス装置の水性液の配合)

Figure 0004847376

(ブレード塗工機の水性塗被組成物の配合)
Figure 0004847376
In Example 1, the composition of the aqueous liquid used in the film metering size press and the composition of the aqueous coating composition used in the blade coating machine were as follows.
(Formation of aqueous liquid for film metering size press)
Figure 0004847376

(Composition of aqueous coating composition of blade coating machine)
Figure 0004847376

得られた印刷用塗被紙の物性を次の方法で測定、評価した。
(1)顔料の平均粒子径:
堀場製作所社製のLA−920(レーザー式粒度分布測定)を使用して測定し、操作方法は、メーカーの取扱い作業書に準拠し測定した。
(2)ブルックフィールド粘度(B型粘度):
TOKIMEC社製ブルックフィールド粘度計のBM型を使用して60rpmの回転で測定した。操作方法は、メーカーの取扱い作業書に準拠し測定した。フィルムメタリングサイズプレスで塗布する接着剤を主成分とする水性液は、接着剤である澱粉を固形分濃度20質量%で糊化した後、温度50℃の条件で測定した。
(3)塗布量コントロール性
フィルムメタリングサイズプレスでの塗布量をコントロールし易いものを○、コントロールがややし難いもの(作業性が実用レベルの下限)を△、コントロールし難いもの(作業性が実用レベルでない)を×として評価した。
(4)紙離れ性
フィルムメタリングサイズプレス装置でのアプリケーターロールからの紙離れ性の良いものを○、紙離れの悪いもの(作業性が実用レベルでない)を×として評価した。特に紙離れの悪いものは、紙面に塗被ムラを発生する。
(5)塗被紙ヒジワの評価:
得られた印刷用塗被紙表面を視感評価した。ヒジワの無いもの(良好で実用に耐える)を○、多いもの(劣り、実用に耐えない)を×、及びこれらの中間のもの(やや劣り、実用に耐えない)を△として評価した。
(6)耐ブリスター性評価:
三菱重工社製オフセット輪転機リソピア(BT 2L‐800NEO) 印刷速度:600rpm
紙面温度140℃で、ブリスターが発生しないもの○、発生するもの(劣り、実用に耐えない)を×として評価した。
(7)オフ輪印刷後のヒジワ評価:
三菱重工社製オフセット輪転機リソピア(BT 2L‐800NEO)印刷速度:600rpm
紙面温度130℃で、ヒジワの無いものを○、多いものを×とし、これらの中間のものを△(やや劣るが、実用に耐える)として評価した。
The physical properties of the obtained coated paper for printing were measured and evaluated by the following methods.
(1) Average particle diameter of pigment:
The measurement was performed using LA-920 (laser particle size distribution measurement) manufactured by HORIBA, Ltd., and the operation method was measured according to the manufacturer's handling work manual.
(2) Brookfield viscosity (B-type viscosity):
It was measured at a rotation of 60 rpm using a BM model of Brookfield viscometer manufactured by TOKIMEC. The operation method was measured according to the manufacturer's handling work manual. The aqueous liquid mainly composed of an adhesive applied by a film metering size press was measured under the condition of a temperature of 50 ° C. after the starch as an adhesive was gelatinized at a solid content concentration of 20% by mass.
(3) Coating amount controllability Good for controllable coating amount in film metering size press ○, difficult to control (workability is lower limit of practical level), difficult to control (workability is low) (Not practical level) was evaluated as x.
(4) Paper Separability Evaluation was made with ◯ indicating that the paper releasing property from the applicator roll in the film metering size press was good, and x indicating poor paper separation (workability was not practical). In particular, those with poor paper separation cause uneven coating on the paper surface.
(5) Evaluation of coated paper elbow:
The obtained coated paper surface for printing was visually evaluated. The evaluation was evaluated as ◯ for no wrinkles (good and practical), x for many (inferior and unusable for practical use), and △ for intermediate ones (slightly inferior and unusable for practical use).
(6) Blister resistance evaluation:
MHI offset web offset press lithopier (BT 2L-800NEO) Printing speed: 600 rpm
When the paper surface temperature was 140 ° C., the case where no blister occurred, and the case where it occurred (inferior and unbearable for practical use) were evaluated as x.
(7) Hijiwa evaluation after off-wheel printing:
MHI offset web offset press lithopier (BT 2L-800NEO) Printing speed: 600 rpm
A paper surface temperature of 130 ° C. was evaluated as “◯” when there was no wrinkle, and “×” when there was a lot, and Δ between them (evaluated as being slightly inferior but practical).

(実施例2)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の乾燥塗布量を両面で1.5g/m塗布・乾燥した後、カレンダー処理をしない以外は、実施例1と同様にして実施例2の印刷用塗被紙を仕上げた。
(Example 2)
Aside from applying a dry coating amount of an aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press device to 1.5 g / m 2 on both sides and then drying, Finished the coated paper for printing of Example 2 in the same manner as in Example 1.

(実施例3)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の固形分濃度を16質量%にし、乾燥塗布量を1.7g/m両面にした以外は、実施例1と同様にして実施例3の印刷用塗被紙を仕上げた。
(Example 3)
The solid content concentration of the aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press apparatus was 16% by mass, and the dry coating amount was 1.7 g / m 2 except for two sides. Finished the coated paper for printing of Example 3 in the same manner as in Example 1.

(実施例4)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の固形分濃度を18質量%にし、乾燥塗布量を2.4g/m両面にした以外は、実施例1と同様にして実施例4の印刷用塗被紙を仕上げた。
Example 4
The solid content concentration of the aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press apparatus was 18% by mass, and the dry coating amount was 2.4 g / m 2 on both sides. Finished the coated paper for printing of Example 4 in the same manner as in Example 1.

(実施例5)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の固形分濃度を20質量%にし、乾燥塗布量を2.8g/m両面にした以外は、実施例1と同様にして実施例5の印刷用塗被紙を仕上げた。
(Example 5)
The solid content concentration of the aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metalizing size press apparatus was set to 20% by mass, and the dry coating amount was 2.8 g / m 2 on both sides. Finished the coated paper for printing of Example 5 in the same manner as in Example 1.

(比較例1)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の固形分濃度を12質量%にし、乾燥塗布量を1.7g/m両面にした以外は、実施例1と同様にして比較例1の印刷用塗被紙を仕上げた。
(Comparative Example 1)
A solid content concentration of an aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press apparatus was set to 12% by mass, and the dry coating amount was 1.7 g / m 2 on both sides. In the same manner as in Example 1, the coated paper for printing of Comparative Example 1 was finished.

(比較例2)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の乾燥塗布量を3.2g/m両面にした以外は、実施例1と同様にして比較例2の印刷用塗被紙を仕上げた。
(Comparative Example 2)
Except that the dry coating amount of the aqueous liquid containing phosphoric acid esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press apparatus was 3.2 g / m 2 on both sides, it was the same as in Example 1. The coated paper for printing of Comparative Example 2 was finished.

(比較例3)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の固形分濃度を22質量%にし、乾燥塗布量を3.5g/m両面にした以外は、実施例1と同様にして比較例3の印刷用塗被紙を仕上げた。
(Comparative Example 3)
The solid content concentration of the aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press apparatus was 22% by mass, and the dry coating amount was 3.5 g / m 2 on both sides. In the same manner as in Example 1, the coated paper for printing of Comparative Example 3 was finished.

(比較例4)
フィルムメタリングサイズプレス装置での酸化澱粉MS3800(日本食品加工社製)の固形分濃度20質量%での糊化時のブルックフィールド粘度が、温度50℃で150mPa・sのものを含有する水性液の固形分濃度20質量%にし、乾燥塗布量を3.4g/m両面にした以外は、実施例1と同様にして比較例4の印刷用塗被紙を仕上げた。
(Comparative Example 4)
An aqueous liquid containing Brookfield viscosity of 150 mPa · s at a temperature of 50 ° C. when gelatinized at a solid content concentration of 20% by mass of oxidized starch MS3800 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press. The coated paper for printing of Comparative Example 4 was finished in the same manner as in Example 1 except that the solid content concentration was 20% by mass and the dry coating amount was 3.4 g / m 2 on both sides.

(比較例5)
フィルムメタリングサイズプレス装置でのリン酸エステル化澱粉MS4600(日本食品加工社製)を含有する水性液の乾燥塗布量を0.9g/m両面にした以外は、実施例1と同様にして比較例5の印刷用塗被紙を仕上げた。
(Comparative Example 5)
Except that the dry coating amount of the aqueous liquid containing phosphate esterified starch MS4600 (manufactured by Nippon Food Processing Co., Ltd.) in a film metering size press device was 0.9 g / m 2 on both sides, it was the same as in Example 1. The coated paper for printing of Comparative Example 5 was finished.

結果を表3にまとめた。   The results are summarized in Table 3.

Figure 0004847376
Figure 0004847376

表3からも明らかなように、ギャップフォーマーとシュープレスの組み合わせを持った抄紙機で抄造された塗被紙について、実施例1〜実施例5の塗被紙は、ヒジワなどの波打ち現象を防いだ塗被紙であり、かつ、オフ輪印刷時のヒジワなどの波打ち現象も防いだ塗被紙である。   As is apparent from Table 3, the coated paper produced in the paper machine having a combination of a gap former and a shoe press has a wavy phenomenon such as wrinkles. It is a coated paper that has been prevented, and has also been prevented from wavy phenomena such as wrinkles during off-ring printing.

比較例1は、水性液の接着剤の固形分濃度が12質量%と低いため、塗被紙ヒジワとオフ輪印刷後のヒジワが見られた。比較例2は、水性液の塗布量が3.2g/m両面と多いため、塗被紙ヒジワとオフ輪印刷後のヒジワが見られ、また耐ブリスター性がなかった。比較例3は、固形分濃度が22質量%と高いため、塗布量のコントロールがし難く、紙離れも悪く、塗被紙ヒジワが見られ、また耐ブリスター性がなかった。比較例4は、水性液の塗布量が3.4g/m両面と多いため、塗布量のコントロールがし難く、紙離れも悪く、塗被紙ヒジワが見られ、また耐ブリスター性がなかった。比較例5は、水性液の塗布量が0.9g/m両面と少ないため、オフ輪印刷後のヒジワが見られ、また耐ブリスター性がなかった。
In Comparative Example 1, since the solid content concentration of the aqueous liquid adhesive was as low as 12% by mass, coated paper wrinkles and wrinkles after off-wheel printing were observed. In Comparative Example 2, since the coating amount of the aqueous liquid was as large as 3.2 g / m 2 on both sides, the coated paper crease and the crease after the off-ring printing were seen, and the blister resistance was not exhibited. In Comparative Example 3, since the solid content concentration was as high as 22% by mass, it was difficult to control the coating amount, paper separation was poor, coated paper wrinkles were observed, and there was no blister resistance. In Comparative Example 4, since the coating amount of the aqueous liquid was large at both sides of 3.4 g / m 2 , it was difficult to control the coating amount, paper separation was poor, coated paper wrinkles were observed, and there was no blister resistance. . In Comparative Example 5, since the coating amount of the aqueous liquid was as small as 0.9 g / m 2 on both sides, creases after off-wheel printing were observed, and there was no blister resistance.

Claims (5)

顔料及び接着剤を主成分とする水性塗被組成物を原紙に塗被し、乾燥して仕上げるオフセット印刷用塗被紙の製造方法において、
前記原紙として、ギャップフォーマーとシュープレスとを組み合わせた抄紙機で抄紙した紙匹に、フィルムメタリングサイズプレス装置を使用して、接着剤として澱粉を主成分とし接着剤固形分濃度が13〜20質量%で、粘度が、固形分濃度20質量%、温度50℃でB型粘度60rpmの測定条件にて、100mPa・s以下である水性液が、両面で1.0〜3.0g/m の乾燥塗布量で、塗布、乾燥されてなる原紙を用い、かつ、前記原紙が、ブレード塗工機で塗被、乾燥される手前の工程において、カレンダー設備によって平滑化されることを特徴とするオフセット印刷用塗被紙の製造方法。
In a method for producing a coated paper for offset printing, a base paper is coated with an aqueous coating composition mainly composed of a pigment and an adhesive, and dried to finish.
As the base paper, a paper meter made with a paper machine combining a gap former and a shoe press, using a film metalizing size press device, starch as a main component and an adhesive solid content concentration of 13 to 13 An aqueous liquid having a viscosity of 20% by mass and a solid content concentration of 20% by mass, a temperature of 50 ° C. and a B-type viscosity of 60 rpm is 100 mPa · s or less is 1.0 to 3.0 g / m on both sides. A base paper that is coated and dried at a dry coating amount of 2 is used , and the base paper is smoothed by a calendar facility in a step before being coated and dried by a blade coating machine. A manufacturing method of coated paper for offset printing.
前記水性塗被組成物が固形分濃度65質量%以上の塗被液であり、前記原紙が該水性塗被組成物を塗被されて乾燥されることを特徴とする請求項に記載のオフセット印刷用塗被紙の製造方法。 The offset according to claim 1 , wherein the aqueous coating composition is a coating liquid having a solid content concentration of 65% by mass or more, and the base paper is coated with the aqueous coating composition and dried. A method for producing a coated paper for printing. 前記原紙の坪量が35〜70g/mであることを特徴とする請求項1又は2に記載のオフセット印刷用塗被紙の製造方法。 The basis weight of the base paper is 35 to 70 g / m 2 , The method for producing a coated paper for offset printing according to claim 1 or 2 . 抄紙による原紙抄造工程と前記原紙への水性塗被組成物の塗被工程と仕上げ処理する工程とが一体となったオンマシン製造設備によって製造されることを特徴とする請求項1、2又は3に記載のオフセット印刷用塗被紙の製造方法。 Claim the method comprising coated process and finishing process of aqueous coated composition to the base paper sheet forming step by papermaking base paper is characterized in that it is produced by on-machine manufacturing facility that integrates 1, 2 or 3 A method for producing a coated paper for offset printing as described in 1. 請求項1、2、3又は4に記載のオフセット印刷用塗被紙の製造方法によって製造されたことを特徴とするオフセット印刷用塗被紙。 A coated paper for offset printing produced by the method for producing a coated paper for offset printing according to claim 1, 2, 3 or 4 .
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