JP4774698B2 - Aluminum honeycomb core manufacturing method and apparatus, and foil thickness control method for aluminum honeycomb core - Google Patents

Aluminum honeycomb core manufacturing method and apparatus, and foil thickness control method for aluminum honeycomb core Download PDF

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JP4774698B2
JP4774698B2 JP2004217209A JP2004217209A JP4774698B2 JP 4774698 B2 JP4774698 B2 JP 4774698B2 JP 2004217209 A JP2004217209 A JP 2004217209A JP 2004217209 A JP2004217209 A JP 2004217209A JP 4774698 B2 JP4774698 B2 JP 4774698B2
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honeycomb core
aluminum honeycomb
etching solution
tank
aluminum
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祐仁 菊地
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Yokohama Rubber Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/08Apparatus, e.g. for photomechanical printing surfaces
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00Etching metallic material by chemical means
    • C23F1/02Local etching
    • C23F1/04Chemical milling

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Description

この発明は、アルミハニカムコアの製造方法及びその装置、アルミハニカムコアの箔厚制御方法に係わり、更に詳しくはアルミハニカムコアの長手方向の箔厚を均一に減少させ、アルミハニカムコアのエッチング全面を同じ座屈強度にすることが出来るアルミハニカムコアの製造方法及びその装置、アルミハニカムコアの箔厚制御方法に関するものである。   The present invention relates to an aluminum honeycomb core manufacturing method and apparatus, and an aluminum honeycomb core foil thickness control method. More specifically, the foil thickness in the longitudinal direction of the aluminum honeycomb core is uniformly reduced, and the entire surface of the aluminum honeycomb core is etched. The present invention relates to a method and apparatus for manufacturing an aluminum honeycomb core that can have the same buckling strength, and a method for controlling the foil thickness of the aluminum honeycomb core.

一般に、六角柱状のアルミハニカムコアは、空間層(空気層)が95%〜99%、コア材が5%〜1%の容積比率であるため、非常に軽量で縦剛性が高く、しかも製造が容易で設計の自由度も大きく、安価に製作出来る等の特徴を有している。   In general, a hexagonal columnar aluminum honeycomb core has a volume ratio of 95% to 99% for the space layer (air layer) and 5% to 1% for the core material. It is easy, has a high degree of design freedom, and can be manufactured at low cost.

従って、アルミハニカムコアを複数組み合わせてブロック状に形成したハニカムコアブロック等は、車輌の衝撃試験材や衝撃吸収材、或いは建築用の資材、フロアーパネル、容器等、あらゆる分野において使用されている(例えば、特許文献1参照)。   Accordingly, a honeycomb core block formed by combining a plurality of aluminum honeycomb cores into a block shape is used in various fields such as vehicle impact test materials and impact absorbing materials, building materials, floor panels, containers, and the like ( For example, see Patent Document 1).

ところで、上記のようなアルミハニカムコアを車輌の衝撃試験材や衝撃吸収材として使用する場合、箔厚を均一とした場合、衝撃荷重に対して座屈強度が変化しないため、アルミハニカムコアの長手方向に対して箔厚を順次変化させたり、容積比率を変化する構成も提案されている。   By the way, when the aluminum honeycomb core as described above is used as an impact test material or an impact absorber for a vehicle, the buckling strength does not change with respect to the impact load when the foil thickness is uniform. A configuration in which the foil thickness is sequentially changed with respect to the direction and the volume ratio is also proposed.

例えば、アルミハニカムコアの長手方向に対して箔厚を順次変化させる方法としては、アルミハニカムコアをエッチング溶液に順次浸してエッチングにより箔厚を加工する方法が知られている。しかし、従来のエッチングによる方法は、図14(a)〜(d)に示すように、エッチング槽1のエッチング溶液2に対して、アルミハニカムコアWを漬けた状態で一定時間毎に段階的に引き上げる方法で行っていたため、エッチングしたアルミハニカムコアWの箔厚hは、図15に示すように階段状になってしまい、アルミハニカムコアWの長手方向に対して箔厚haを順次変化させても座屈強度も段階的に変化し、円滑(直線的)に座屈強度を変化させることが出来なかった。   For example, as a method for sequentially changing the foil thickness with respect to the longitudinal direction of the aluminum honeycomb core, a method is known in which the aluminum honeycomb core is sequentially immersed in an etching solution and the foil thickness is processed by etching. However, in the conventional etching method, as shown in FIGS. 14A to 14D, the aluminum honeycomb core W is immersed in the etching solution 2 in the etching tank 1 step by step at regular intervals. Since the foil thickness h of the etched aluminum honeycomb core W is stepped as shown in FIG. 15, the foil thickness ha is sequentially changed with respect to the longitudinal direction of the aluminum honeycomb core W. The buckling strength also changed step by step, and the buckling strength could not be changed smoothly (linearly).

この原因としては、アルミハニカムコアWのエッチングは、エッチング溶液2にアルミハニカムコアWを浸すと、エッチング溶液2とアルミとの化学反応により溶液温度が上昇し、温度上昇と共にエッチング反応が大きくなることが判っている。このため、エッチング溶液2に予め容積の大きいアルミハニカムコアWを浸した場合、エッチング溶液2に対してアルミハニカムコアWの接触面積も大きくなり、この結果、エッチング溶液2の温度上昇も大きくなってエッチング反応の大きくなることから、アルミハニカムコアWをエッチング溶液2に漬けた状態で段階的に引き上げた場合、アルミハニカムコアWの長手方向の箔厚hは段階的に変化してしまうことが判った。   The cause of this is that when the aluminum honeycomb core W is etched in the etching solution 2, the temperature of the solution rises due to a chemical reaction between the etching solution 2 and aluminum, and the etching reaction increases as the temperature rises. Is known. For this reason, when the aluminum honeycomb core W having a large volume is immersed in the etching solution 2 in advance, the contact area of the aluminum honeycomb core W with respect to the etching solution 2 also increases, and as a result, the temperature rise of the etching solution 2 also increases. Since the etching reaction becomes large, it is understood that when the aluminum honeycomb core W is immersed in the etching solution 2 in a stepwise manner, the foil thickness h in the longitudinal direction of the aluminum honeycomb core W changes stepwise. It was.

また、従来のアルミハニカムコアWのエッチング方法では、アルミハニカムコアWを静的なエッチング溶液2にドブ漬けする方法であるため、アルミハニカムコアWの外側と内側とでは箔厚の差が発生しており、従ってアルミハニカムコアWの長手方向の場所により座屈強度バラツキが発生し、安定した座屈性能を得ることが出来ないと言う問題があった。 Further, in the conventional etching method of the aluminum honeycomb core W, since the aluminum honeycomb core W is immersed in the static etching solution 2, a difference in foil thickness occurs between the outside and inside of the aluminum honeycomb core W. and which, therefore variation in buckling strength due longitudinal location of the aluminum honeycomb core W is generated, there is a problem that the can not be obtained a stable buckling capacity.

この発明は、かかる従来の問題点に着目して案出されたもので、アルミハニカムコアをエッチング加工する場合に、箔厚の肉厚を長手方向に沿って均一に加工することが出来ると共に、座屈強度のバラツキを減少させ、安定した座屈性能を得ることが出来るアルミハニカムコアの製造方法及びその装置、アルミハニカムコアの箔厚制御方法を提供することを目的とするものである。   This invention was devised by paying attention to such conventional problems, and when etching an aluminum honeycomb core, the foil thickness can be uniformly processed along the longitudinal direction, It is an object of the present invention to provide an aluminum honeycomb core manufacturing method and apparatus, and an aluminum honeycomb core foil thickness control method capable of reducing the variation in buckling strength and obtaining stable buckling performance.

この発明は、上記目的を達成するため、この発明のアルミハニカムコアの製造方法は、エッチング溶液を液面に対して水平方向に対流させ、底壁面を一方に傾斜させたエッチング溶液槽にアルミハニカムコアの先端側から後端側に向かって下降させながら一定時間に連続的に浸漬させ、このアルミハニカムコアの浸漬工程中に、アルミハニカムコアに対して噴射ノズルからエッチング溶液を所定の圧力で噴射させ、アルミハニカムコアの先端側から後端側に箔厚が厚くなるように制御し、その後、アルミハニカムコアを洗浄処理槽に移送して洗浄した後、この洗浄されたアルミハニカムコアをディップ処理槽に移送してディップ処理して製造するアルミハニカムコアの製造方法であって、前記アルミハニカムコアの浸漬工程中に、該アルミハニカムコアに対してエッチング溶液を噴射ノズルにより所定の圧力で噴射させる際、アルミハニカムコアの場所に対応させて噴射角度を異ならせて任意の噴射角度で設定した複数の噴射ノズルによりエッチング溶液を噴射させることを要旨とするものである。 The present invention, in order to achieve the above object, a manufacturing method of an aluminum honeycomb core of this invention is to convection horizontally etching solution to the liquid surface, the etching solution tank is tilted bottom wall surface on one aluminum The honeycomb core is continuously dipped for a predetermined time while being lowered from the front end side to the rear end side. During the dipping process of the aluminum honeycomb core, the etching solution is applied to the aluminum honeycomb core from the spray nozzle at a predetermined pressure. The foil is controlled so that the foil thickness increases from the front end side to the rear end side of the aluminum honeycomb core, and then the aluminum honeycomb core is transferred to a cleaning treatment tank for cleaning, and then the cleaned aluminum honeycomb core is dipped a manufacturing method of an aluminum honeycomb core be manufactured by dipping in and transferred to a processing tank, during the immersion step of the aluminum honeycomb core, the aluminum When the etching solution is sprayed onto the Nicam core at a predetermined pressure by the spray nozzle, the etching solution is sprayed by a plurality of spray nozzles set at arbitrary spray angles by varying the spray angle corresponding to the location of the aluminum honeycomb core. This is the gist.

ここで、前記ルミハニカムコアをエッチングする際、バケットに入れて行うものである。 Here, when etching the A Rumi honeycomb core, it is performed taking into buckets.

また、前記アルミハニカムコアを製造工程において、アルミハニカムコアを収容したバケットを昇降かつ移動可能な搬送装置により連続的に行い、前記エッチング溶液として、アルカリ溶液(例えば、水酸化ナトリウム溶液等)を使用する。   Further, in the manufacturing process of the aluminum honeycomb core, the bucket containing the aluminum honeycomb core is continuously performed by a transport device that can move up and down, and an alkaline solution (for example, sodium hydroxide solution) is used as the etching solution. To do.

また、この発明のアルミハニカムコアの製造装置は、作業台上に、エッチング溶液を収容した底壁面を一方に傾斜させたエッチング溶液槽と、エッチングされたアルミハニカムコアを洗浄する洗浄処理槽と、洗浄されたアルミハニカムコアをディップ処理するディップ処理槽とを水平で、かつ直列に設置し、前記エッチング溶液槽と洗浄処理槽とディップ処理槽との間に、アルミハニカムコアを収容したバケットを保持して移送する昇降、かつ移動可能な搬送装置を設置し、前記エッチング溶液槽に、エッチング溶液を液面に対して水平方向に対流させる対流手段と、エッチング溶液をアルミハニカムコアの場所に対応させて噴射角度を異ならせて任意の噴射角度で噴射可能に設定した複数の噴射ノズルとを設けことを要旨とするものである。 In addition, the aluminum honeycomb core manufacturing apparatus of the present invention includes an etching solution tank in which the bottom wall surface containing the etching solution is inclined on one side on the work table, a cleaning treatment tank for cleaning the etched aluminum honeycomb core, A dip treatment tank for dipping the cleaned aluminum honeycomb core is installed horizontally and in series, and a bucket containing the aluminum honeycomb core is held between the etching solution tank, the cleaning treatment tank, and the dip treatment tank. A transfer device that can be moved up and down and transported, and in the etching solution tank, convection means for convection of the etching solution in the horizontal direction with respect to the liquid surface, and the etching solution corresponding to the location of the aluminum honeycomb core. The gist of the invention is to provide a plurality of injection nozzles that are set to be capable of injection at an arbitrary injection angle with different injection angles.

ここで、前記搬送装置は、エッチング溶液槽と洗浄処理槽とデップ処理槽との上方に設置されたガイドレールに、アルミハニカムコアを収容したバケットを保持し、かつ昇降可能なクランプ手段を設けたものである。   Here, the transfer device is provided with clamp means that holds the bucket containing the aluminum honeycomb core and can be moved up and down on the guide rail installed above the etching solution tank, the cleaning treatment tank, and the dipping tank. Is.

更に、この発明のアルミハニカムコアの箔厚制御方法は、エッチング溶液を液面に対して水平方向に対流させ、底壁面を一方に傾斜させたエッチング溶液槽にアルミハニカムコアを連続的に浸漬させてアルミハニカムコアの長手方向の箔厚を制御するアルミハニカムコアの箔厚制御方法であって、前記アルミハニカムコアをエッチング溶液槽にアルミハニカムコアの先端側から後端側に向かって一定時間に連続的に浸漬させると共に、このアルミハニカムコアの浸漬工程中に、アルミハニカムコアの場所に対応させて噴射角度を異ならせて任意の噴射角度で設定した複数の噴射ノズルにより所定の圧力でエッチング溶液を噴射させてエッチングする際、アルミハニカムコアの先端側から後端側に向かって浸漬速度を制御しながら箔厚を制御することを要旨とするものである。 Further, the foil thickness control method for an aluminum honeycomb core according to the present invention is such that the aluminum honeycomb core is continuously immersed in an etching solution tank in which the etching solution is convected in a horizontal direction with respect to the liquid surface and the bottom wall surface is inclined to one side. And controlling the foil thickness in the longitudinal direction of the aluminum honeycomb core to control the foil thickness of the aluminum honeycomb core, wherein the aluminum honeycomb core is used as an etching solution tank for a predetermined time from the front end side to the rear end side of the aluminum honeycomb core. During this aluminum honeycomb core dipping process, etching is performed at a predetermined pressure by a plurality of injection nozzles set at arbitrary injection angles with different injection angles corresponding to the location of the aluminum honeycomb core. When etching by spraying the solution, the foil thickness is controlled while controlling the immersion speed from the front end side to the rear end side of the aluminum honeycomb core. It is an gist of Rukoto.

ここで、前記アルミハニカムコアをエッチング溶液槽に浸漬する際、エッチング溶液を液面に対して水平方向に対流させ、また前記エッチング溶液をアルミハニカムコアに所定の圧力で噴射させる際、エッチング溶液の噴射ノズルの角度を場所によって変化させるものである。前記エッチング溶液として、アルカリ溶液を使用する。   Here, when the aluminum honeycomb core is immersed in an etching solution tank, the etching solution is convected in a horizontal direction with respect to the liquid surface, and when the etching solution is sprayed onto the aluminum honeycomb core at a predetermined pressure, The angle of the spray nozzle is changed depending on the location. An alkaline solution is used as the etching solution.

この発明は上記のように構成したので、以下のような優れた効果を奏するものである。(a).アルミハニカムコアをエッチング加工する場合に、箔厚の肉厚を長手方向に沿って均一に加工することが出来る。
(b).座屈強度のバラツキを減少させ、安定した座屈性能を得ることが出来る。
(c).アルミハニカムコアのエッチング加工時間を短縮化することが出来ることから、生産性の向上を図ることが出来る。
Since the present invention is configured as described above, the following excellent effects can be obtained. (A). When the aluminum honeycomb core is etched, the thickness of the foil can be uniformly processed along the longitudinal direction.
(B). The variation in buckling strength can be reduced, and stable buckling performance can be obtained.
(C). Since the etching time of the aluminum honeycomb core can be shortened, productivity can be improved.

以下、添付図面に基づきこの発明の実施の形態を説明する。
なお、従来例と同一構成要素は、同一符号を付して説明は省略する。
Embodiments of the present invention will be described below with reference to the accompanying drawings.
Note that the same components as those in the conventional example are denoted by the same reference numerals and description thereof is omitted.

図1は、この発明のアルミハニカムコアの製造方法を実施するためのアルミハニカムコアWの製造装置の概略正面図、図2は図1の平面図、図3は図1の側面図を示し、このアルミハニカムコアWの製造装置は、エッチング溶液2(例えば、アルカリ溶液:水酸化ナトリウム溶液)に金網状のバケット3内に収容したアルミハニカムコアWの先端側から後端側に向かって一定時間に連続的に浸漬させながらアルミハニカムコアWの箔厚hを制御するエッチング溶液槽1と、エッチングされたアルミハニカムコアWを水洗浄する洗浄処理槽4と、洗浄されたアルミハニカムコアWを水等によりデップ処理するデップ処理槽5とを作業台6上に水平で直列に設置されている。なお、エッチング溶液槽1内のエッチング溶液2の温度としては、20〜70度が好ましい。 1 is a schematic front view of an apparatus for manufacturing an aluminum honeycomb core W for carrying out the method for manufacturing an aluminum honeycomb core of the present invention, FIG. 2 is a plan view of FIG. 1, and FIG. 3 is a side view of FIG. This aluminum honeycomb core W manufacturing apparatus has a certain period of time from the front end side to the rear end side of the aluminum honeycomb core W housed in the wire mesh-like bucket 3 in the etching solution 2 (for example, alkaline solution: sodium hydroxide solution). An etching solution tank 1 for controlling the foil thickness h of the aluminum honeycomb core W while being continuously immersed in water, a cleaning treatment tank 4 for cleaning the etched aluminum honeycomb core W with water, and the cleaned aluminum honeycomb core W with water. a de I-up processing tank 5 to de-I-up process is placed in series horizontally on working platform 6 by like. The temperature of the etching solution 2 in the etching solution tank 1 is preferably 20 to 70 degrees.

前記エッチング溶液槽1と洗浄処理槽4とデップ処理槽5との間には、アルミハニカムコアWを収容した前記バケット3を保持して移送する昇降、かつ移動可能な搬送装置7が設置され、この搬送装置7は、エッチング溶液槽1と洗浄処理槽4とデップ処理槽5との上方に架設されたガイドレール8に往復移動可能に取付けられ、搬送装置7には、ガイドレール9に沿って昇降するバケット3を保持するクランプ手段10が取付けられている。   Between the etching solution tank 1, the cleaning treatment tank 4, and the dipping treatment tank 5, an elevating and moving transfer device 7 that holds and transfers the bucket 3 containing the aluminum honeycomb core W is installed, The transfer device 7 is attached to a guide rail 8 installed above the etching solution tank 1, the cleaning treatment tank 4, and the dipping treatment tank 5 so as to be reciprocally movable. Clamp means 10 is attached to hold the bucket 3 that moves up and down.

前記エッチング溶液槽1には、図4〜図6に示すように、エッチング溶液2を液面に対して水平方向に対流させる対流手段11と、エッチング溶液2をアルミハニカムコアWに対して任意の角度で噴射可能な複数の噴射ノズル12とが設けられている。前記対流手段11は、図4〜図6に示すように、エッチング溶液槽1の底壁面1aを傾斜させて形成すると共に、エッチング溶液槽1からオーバーフローしたエッチング溶液2は、循環ポンプ13及び循環経路14を介して循環させることによりエッチング溶液2を液面に対して水平方向に対流させ、更にエッチング溶液2の噴射ノズル12は、エッチング溶液槽1の下部に配設された配管15に所定の間隔で複数のノズル12が取付けられている。   In the etching solution tank 1, as shown in FIGS. 4 to 6, convection means 11 for convection the etching solution 2 in the horizontal direction with respect to the liquid surface, and the etching solution 2 with respect to the aluminum honeycomb core W A plurality of injection nozzles 12 that can be injected at an angle are provided. 4 to 6, the convection means 11 is formed by inclining the bottom wall surface 1a of the etching solution tank 1, and the etching solution 2 overflowing from the etching solution tank 1 is supplied to the circulation pump 13 and the circulation path. The etching solution 2 is circulated in a horizontal direction with respect to the liquid level by circulating through the nozzle 14, and the spray nozzle 12 for the etching solution 2 is further provided at a predetermined interval in a pipe 15 disposed in the lower part of the etching solution tank 1. A plurality of nozzles 12 are attached.

前記ノズル12の先端は、任意の方向に角度調整出来るように構成され、供給ホンプから供給されたエッチング溶液2を所定の流速でアルミハニカムコアWの内外面に噴射出来るように構成されている。   The tip of the nozzle 12 is configured such that the angle can be adjusted in an arbitrary direction, and the etching solution 2 supplied from the supply pump can be sprayed onto the inner and outer surfaces of the aluminum honeycomb core W at a predetermined flow rate.

また、エッチング溶液槽1の上部開口部には、エッチング溶液槽1の側面に取付けられた一対の開閉シリンダー17a,17bを介して支点18a,18bを中心に開閉する開閉蓋19a,19bが取付けられ、アルミハニカムコアWのエッチング加工時、及びアルミハニカムコアWの挿入,取出し時にエッチング溶液槽1の上部開口部を開閉させるものである。なお、20はバケット3に収容した複数個のアルミハニカムコアWを固定させておくためのエッチング溶液2に耐え得るためのゴムバンド等の紐状部材であり、20aは、エッチング溶液槽1上に設置された排気ダクト装置である。   Opening and closing lids 19a and 19b that open and close around fulcrums 18a and 18b are attached to the upper opening of the etching solution tank 1 through a pair of opening and closing cylinders 17a and 17b attached to the side surfaces of the etching solution tank 1. When the aluminum honeycomb core W is etched, and when the aluminum honeycomb core W is inserted and removed, the upper opening of the etching solution tank 1 is opened and closed. Reference numeral 20 denotes a string-like member such as a rubber band that can withstand the etching solution 2 for fixing a plurality of aluminum honeycomb cores W accommodated in the bucket 3, and 20a is formed on the etching solution tank 1. It is an installed exhaust duct device.

前記洗浄処理槽4の上部には、図7〜図9に示すように、搬送されて来たアルミハニカムコアWに水を噴射させて洗浄させる複数の水噴射ノズル21が配設され、この水噴射ノズル21は、洗浄処理槽4の上部に配設された洗浄水の配管22に所定の間隔で取付けられ、この配管22は、洗浄水の駆動ポンプ(図示せず)に接続されている。   As shown in FIGS. 7 to 9, a plurality of water injection nozzles 21 are disposed above the cleaning treatment tank 4 to inject water into the aluminum honeycomb core W that has been conveyed and clean it. The spray nozzle 21 is attached to a cleaning water pipe 22 disposed at an upper portion of the cleaning treatment tank 4 at a predetermined interval, and the pipe 22 is connected to a cleaning water drive pump (not shown).

なお、この洗浄処理槽4の上部開口部にも、前記エッチング溶液槽1と同様に、一対の開閉シリンダー24a,24bを介して支点25a,25bを中心に開閉する開閉蓋26a,26bが取付けられている。   Opening and closing lids 26a and 26b that open and close around fulcrums 25a and 25b via a pair of opening and closing cylinders 24a and 24b are attached to the upper opening of the cleaning treatment tank 4 as well as the etching solution tank 1. ing.

更に、前記デップ処理槽5は、図1〜図3に示すように洗浄されたアルミハニカムコアWを水タンク27に漬けてアルミハニカムコアWの表面を水によりデップ処理するもので、デップ処理槽5の上部開口部には、上記エッチング溶液槽1及び洗浄処理槽4と同様に一対の開閉シリンダーを介して開閉する開閉蓋が取付けられている。 Furthermore, the de-I-up processing tank 5, the surface of the aluminum honeycomb core W de I-up process with water by dipping in an aluminum honeycomb core W water tank 27 that has been cleaned, as shown in FIGS. 1 to 3 what is, the upper opening of the de I-up processing tank 5, close lid for opening and closing through a pair of opening and closing cylinders in the same manner as the etching solution tank 1 and the cleaning tank 4 is mounted.

次に、アルミハニカムコアの製造方法について説明する。
この発明の製造方法では、先ずエッチング溶液槽1内に入れた水酸化ナトリウム溶液等のエッチング溶液2を対流手段11を介して液面に対して水平方向に対流させた状態で、バケット3に収容した複数個のアルミハニカムコアWを、図10に示すように、搬送装置7によりそのバケット3と共に、アルミハニカムコアWの先端側から端側に向かって一定時間に連続的に浸漬させながら、かつエッチング溶液2を噴射ノズル12により所定の圧力でアルミハニカムコアWに噴射させてその箔厚hを、図11に示すように箔厚h1 となるようにテーパ状にエッチングして制御する。
Next, a method for manufacturing the aluminum honeycomb core will be described.
In the manufacturing method of the present invention, first, the etching solution 2 such as sodium hydroxide solution placed in the etching solution tank 1 is accommodated in the bucket 3 while being convected in a horizontal direction with respect to the liquid level via the convection means 11. a plurality of aluminum honeycomb core W that, as shown in FIG. 10, with its bucket 3 by the transfer device 7, while continuously immersed in a predetermined time toward the rear end side from the front end side of the aluminum honeycomb core W, In addition, the etching solution 2 is sprayed onto the aluminum honeycomb core W by the spray nozzle 12 at a predetermined pressure, and the foil thickness h is controlled by etching in a taper shape so as to be the foil thickness h1 as shown in FIG.

そして、このエッチングされたアルミハニカムコアWを、搬送装置7により洗浄処理槽4に移送して水により洗浄した後、この洗浄されたアルミハニカムコアWを搬送装置7によりデップ処理槽5に移送してデップ処理して製造するものである。前記エッチング溶液槽1では、上記のようにエッチング溶液2をアルミハニカムコアWに噴射させてエッチングする際、噴射角度を異ならせて任意の噴射角度で設定した複数の噴射ノズル12によりアルミハニカムコアWの噴射場所に対応させてエッチング溶液を噴射させることで、アルミハニカムコアWの内外面を均一にエッチングすることが出来る。 Then, the etched aluminum honeycomb core W, washed with water and transferred to the cleaning tank 4 by a conveying device 7, de I-up processing tank 5 The washed aluminum honeycomb core W by the transfer device 7 is intended to be produced by de I-up process is transferred to. Wherein the etching solution tank 1, when the etching solution 2 is injected into the aluminum honeycomb core W etching as described above, an aluminum honeycomb core W by a plurality of injection nozzles 12 set at an arbitrary injection angle at different injection angle The inner and outer surfaces of the aluminum honeycomb core W can be uniformly etched by spraying the etching solution in correspondence with the spray locations.

具体的には、前記アルミハニカムコアWをエッチング溶液槽1に浸漬すると共に、エッチング溶液2をアルミハニカムコアWに所定の圧力で噴射させてエッチングする際、アルミハニカムコアWの先端側から端側に向かって浸漬速度を制御しながら連続的に浸漬させることで、箔厚hが制御出来るのである。 Specifically, while immersing the aluminum honeycomb core W in the etching solution tank 1, when the etching solution 2 is injected at a predetermined pressure in an aluminum honeycomb core W is etched, the end rear from the front end side of the aluminum honeycomb core W The foil thickness h can be controlled by continuously dipping while controlling the dipping rate toward the side.

特に、この発明ではアルミハニカムコアWの先端側から端側に向かって一定時間に連続的に浸漬させることで、エッチング溶液2が反応速度(温度上昇)も抑えることが出来、かつエッチング溶液2を対流させることで均一な濃度となり、更にアルミハニカムコアWの内外面に噴射ノズル12の噴射角度を任意に調整しながらエッチング溶液2を均一に吹き付けるので、アルミハニカムコアWの先端側から端側に向かって均一な箔厚hでエッチングすることが可能となるものである。 In particular, in this invention, by which continuously immersed in a predetermined time toward the rear end side from the front end side of the aluminum honeycomb core W, the etching solution 2 is the reaction rate (temperature rise) can also be suppressed, and the etching solution 2 since the suspension became a homogeneous density by causing convection, further uniformly spray the etching solution 2 while arbitrarily adjusting the injection angle of the injection nozzle 12 to the inner and outer surfaces of the aluminum honeycomb core W, end the rear from the front end side of the aluminum honeycomb core W It is possible to perform etching with a uniform foil thickness h toward the side.

以上のように、アルミハニカムコアWをエッチング加工する場合に、上記のような方法により連続的にエッチング加工するので、箔厚hの肉厚を長手方向に沿って均一に加工することが出来、従って、このようなアルミハニカムコアWを車輛の衝撃試験材や衝撃吸収材に使用した場合、座屈強度のバラツキを減少させ、安定した座屈性能を得ることが出来る。また、アルミハニカムコアWのエッチング加工時間を短縮化することが出来ることから、生産性の向上を図ることが出来る。   As described above, when the aluminum honeycomb core W is etched, the thickness of the foil thickness h can be uniformly processed along the longitudinal direction because the etching is continuously performed by the method as described above. Therefore, when such an aluminum honeycomb core W is used as a vehicle impact test material or shock absorbing material, variations in buckling strength can be reduced and stable buckling performance can be obtained. Moreover, since the etching time of the aluminum honeycomb core W can be shortened, productivity can be improved.

なお、図12及び図13は、本願発明のアルミハニカムコアWと、従来のアルミハニカムコアWとの荷重と変位との関係を示すグラフ説明図であり、本願発明のアルミハニカムコアW(図12)の場合と従来例のアルミハニカムコアWとの相違が明確である。   12 and 13 are graph explanatory views showing the relationship between the load and displacement of the aluminum honeycomb core W of the present invention and the conventional aluminum honeycomb core W, and the aluminum honeycomb core W of the present invention (FIG. 12). ) And the conventional aluminum honeycomb core W are clear.

この発明のアルミハニカムコアの製造方法を実施するためのアルミハニカムコアWの製造装置の概略正面図である。1 is a schematic front view of an apparatus for manufacturing an aluminum honeycomb core W for carrying out an aluminum honeycomb core manufacturing method of the present invention. 図1の平面図である。It is a top view of FIG. 図1の側面図である。It is a side view of FIG. エッチング溶液槽の正面図である。It is a front view of an etching solution tank. 図4の平面図である。FIG. 5 is a plan view of FIG. 4. 図4の側面図である。FIG. 5 is a side view of FIG. 4. 洗浄処理槽の正面図である。It is a front view of a washing processing tank. 図7の平面図である。FIG. 8 is a plan view of FIG. 7. 図7の側面図である。FIG. 8 is a side view of FIG. 7. (a)〜(d)は、この発明のアルミハニカムコアの製造工程の説明図である。(A)-(d) is explanatory drawing of the manufacturing process of the aluminum honeycomb core of this invention. この発明の製造方法により箔厚が制御されたアルミハニカムコアの側面図である。It is a side view of an aluminum honeycomb core whose foil thickness is controlled by the manufacturing method of the present invention. 本願発明のアルミハニカムコアの荷重と変位との関係を示すグラフ説明図である。It is graph explanatory drawing which shows the relationship between the load and displacement of the aluminum honeycomb core of this invention. 従来のアルミハニカムコアの荷重と変位との関係を示すグラフ説明図である。It is graph explanatory drawing which shows the relationship between the load and displacement of the conventional aluminum honeycomb core. (a)〜(d)は、従来のアルミハニカムコアの製造工程の説明図である。(A)-(d) is explanatory drawing of the manufacturing process of the conventional aluminum honeycomb core. 従来の製造方法により箔厚が制御されたアルミハニカムコアの側面図である。It is a side view of an aluminum honeycomb core whose foil thickness is controlled by a conventional manufacturing method.

符号の説明Explanation of symbols

1 エッチング槽 2 エッチング溶液
1a エッチング槽の底面
W アルミハニカムコア h,h1,ha 箔厚
3 バケット 4 洗浄処理槽
5 デップ処理槽 7 搬送装置 8 ガイドレール
9 ガイドレール 10 クランプ手段
11 対流手段 12 噴射ノズル
13 循環ポンプ 14 循環経路
15 配管
17a,17b 開閉シリンダー
18a,18b 支点
19a,19b 開閉蓋 20 紐状部材
20a 排気ダクト装置
21 水噴射ノズル 22 配管
23 駆動ポンプ
24a,24b 開閉シリンダー
25a,25b 支点
26a,26b 開閉蓋
27 水タンク
DESCRIPTION OF SYMBOLS 1 Etching tank 2 Etching solution 1a Bottom face of etching tank W Aluminum honeycomb core h, h1, ha Foil thickness 3 Bucket 4 Cleaning treatment tank 5 Depth treatment tank 7 Conveying device 8 Guide rail 9 Guide rail 10 Clamping means 11 Convection means 12 Injection nozzle DESCRIPTION OF SYMBOLS 13 Circulation pump 14 Circulation path 15 Piping 17a, 17b Opening and closing cylinder 18a, 18b Supporting point 19a, 19b Opening / closing lid 20 String member 20a Exhaust duct device 21 Water injection nozzle 22 Piping 23 Drive pump
24a, 24b Open / close cylinder 25a, 25b Support point 26a, 26b Open / close lid 27 Water tank

Claims (10)

エッチング溶液を液面に対して水平方向に対流させ、底壁面を一方に傾斜させたエッチング溶液槽にアルミハニカムコアの先端側から後端側に向かって下降させながら一定時間に連続的に浸漬させ、このアルミハニカムコアの浸漬工程中に、アルミハニカムコアに対して噴射ノズルからエッチング溶液を所定の圧力で噴射させ、アルミハニカムコアの先端側から後端側に箔厚が厚くなるように制御し、その後、アルミハニカムコアを洗浄処理槽に移送して洗浄した後、この洗浄されたアルミハニカムコアをディップ処理槽に移送してディップ処理して製造するアルミハニカムコアの製造方法であって、
前記アルミハニカムコアの浸漬工程中に、該アルミハニカムコアに対してエッチング溶液を噴射ノズルにより所定の圧力で噴射させる際、アルミハニカムコアの場所に対応させて噴射角度を異ならせて任意の噴射角度で設定した複数の噴射ノズルによりエッチング溶液を噴射させるアルミハニカムコアの製造方法。
Dipping continuously in a certain time while descending from the front end side of the aluminum honeycomb core to the rear end side in an etching solution tank in which the etching solution is convected in a horizontal direction with respect to the liquid level and the bottom wall surface is inclined to one side. During the dipping process of the aluminum honeycomb core, the etching solution is sprayed from the spray nozzle to the aluminum honeycomb core at a predetermined pressure so that the foil thickness increases from the front end side to the rear end side of the aluminum honeycomb core. Then, after the aluminum honeycomb core is transferred to the cleaning tank and cleaned, the cleaned aluminum honeycomb core is transferred to the dip tank and manufactured by dip processing,
During the immersion step of the aluminum honeycomb core, when to inject at a predetermined pressure etching solution by the injection nozzle with respect to the aluminum honeycomb core, at different injection angle so as to correspond to the location of the aluminum honeycomb core of any injection angle A method for manufacturing an aluminum honeycomb core, wherein an etching solution is sprayed by a plurality of spray nozzles set in step 1.
前記アルミハニカムコアをエッチングする際、バケットに入れて行う請求項1に記載のアルミハニカムコアの製造方法。   The method for manufacturing an aluminum honeycomb core according to claim 1, wherein the aluminum honeycomb core is etched in a bucket. 前記アルミハニカムコアを製造工程において、アルミハニカムコアを収容したバケットを昇降かつ移動可能な搬送装置により連続的に移動させながらエッチング溶液槽に浸漬させてアルミハニカムコアをエッチング処理する請求項1または2に記載のアルミハニカムコアの製造方法。   3. The aluminum honeycomb core is subjected to an etching process by immersing the aluminum honeycomb core in an etching solution tank while continuously moving the bucket containing the aluminum honeycomb core by a transporting device capable of moving up and down and moving the aluminum honeycomb core. The manufacturing method of the aluminum honeycomb core of description. 前記エッチング溶液として、アルカリ溶液を使用する請求項1,2または3に記載のアルミハニカムコアの製造方法。   4. The method for manufacturing an aluminum honeycomb core according to claim 1, wherein an alkaline solution is used as the etching solution. 作業台上に、エッチング溶液を収容した底壁面を一方に傾斜させたエッチング溶液槽と、エッチングされたアルミハニカムコアを洗浄する洗浄処理槽と、洗浄されたアルミハニカムコアをディップ処理するディップ処理槽とを水平で、かつ直列に設置し、前記エッチング溶液槽と洗浄処理槽とディップ処理槽との間に、アルミハニカムコアを収容したバケットを保持して移送する昇降、かつ移動可能な搬送装置を設置し、前記エッチング溶液槽に、エッチング溶液を液面に対して水平方向に対流させる対流手段と、エッチング溶液をアルミハニカムコアの場所に対応させて噴射角度を異ならせて任意の噴射角度で噴射可能に設定した複数の噴射ノズルとを設けことを特徴とするアルミハニカムコアの製造装置。 An etching solution tank in which the bottom wall surface containing the etching solution is inclined to one side on the work table, a cleaning processing tank for cleaning the etched aluminum honeycomb core, and a dip processing tank for dip processing the cleaned aluminum honeycomb core Are moved in a horizontal and series manner, and a transfer device that can move up and down and move while holding and transferring a bucket containing an aluminum honeycomb core between the etching solution tank, the cleaning treatment tank, and the dip treatment tank. Installed in the etching solution tank, convection means for convection of the etching solution in the horizontal direction with respect to the liquid surface, and the etching solution is sprayed at an arbitrary spraying angle corresponding to the location of the aluminum honeycomb core. An apparatus for manufacturing an aluminum honeycomb core, comprising: a plurality of spray nozzles set in a possible manner. 前記搬送装置は、エッチング溶液槽と冷却処理槽とディップ処理槽との上方に設置されたガイドレールに、アルミハニカムコアを収容したバケットを保持し、かつ昇降可能なクランプ手段を設けた請求項5に記載のアルミハニカムコアの製造装置。   The said conveying apparatus provided the clamp means which hold | maintains the bucket which accommodated the aluminum honeycomb core in the guide rail installed above the etching solution tank, the cooling processing tank, and the dip processing tank, and can raise / lower. An apparatus for manufacturing an aluminum honeycomb core according to 1. エッチング溶液を液面に対して水平方向に対流させ、底壁面を一方に傾斜させたエッチング溶液槽にアルミハニカムコアを連続的に浸漬させてアルミハニカムコアの長手方向の箔厚を制御するアルミハニカムコアの箔厚制御方法であって、
前記アルミハニカムコアをエッチング溶液槽にアルミハニカムコアの先端側から後端側に向かって一定時間に連続的に浸漬させると共に、このアルミハニカムコアの浸漬工程中に、アルミハニカムコアの場所に対応させて噴射角度を異ならせて任意の噴射角度で設定した複数の噴射ノズルにより所定の圧力でエッチング溶液を噴射させてエッチングする際、アルミハニカムコアの先端側から後端側に向かって浸漬速度を制御しながら箔厚を制御するアルミハニカムコアの箔厚制御方法。
Aluminum for controlling the foil thickness in the longitudinal direction of the aluminum honeycomb core by continuously immersing the aluminum honeycomb core in an etching solution tank in which the etching solution is convected in the horizontal direction with respect to the liquid surface and the bottom wall surface is inclined to one side. A method for controlling the thickness of a honeycomb core foil,
The aluminum honeycomb core is continuously immersed in the etching solution tank from the front end side to the rear end side of the aluminum honeycomb core for a predetermined time, and the aluminum honeycomb core is made to correspond to the location of the aluminum honeycomb core during the dipping process of the aluminum honeycomb core. When etching is performed by spraying the etching solution at a predetermined pressure with multiple spray nozzles set at any spray angle with different spray angles, the immersion speed is controlled from the front end side to the rear end side of the aluminum honeycomb core. A method for controlling the foil thickness of the aluminum honeycomb core while controlling the foil thickness.
前記アルミハニカムコアをエッチング溶液槽に浸漬する際、エッチング溶液を液面に対して水平方向に対流させる請求項7に記載のアルミハニカムコアの箔厚制御方法。   The method for controlling the foil thickness of an aluminum honeycomb core according to claim 7, wherein when the aluminum honeycomb core is immersed in an etching solution tank, the etching solution is convected in a horizontal direction with respect to the liquid surface. 前記エッチング溶液をアルミハニカムコアに所定の圧力で噴射させる際、噴射角度を異ならせた複数の噴射ノズルによりアルミハニカムコアの場所に対応させて所定の圧力で噴射させる請求項7または8に記載のアルミハニカムコアの箔厚制御方法。   9. The spray according to claim 7, wherein when the etching solution is sprayed onto the aluminum honeycomb core at a predetermined pressure, the plurality of spray nozzles having different spray angles are sprayed at a predetermined pressure corresponding to the location of the aluminum honeycomb core. Foil thickness control method for aluminum honeycomb core. 前記エッチング溶液として、アルカリ溶液を使用する請求項7,8または9に記載のアルミハニカムコアの箔厚制御方法。   10. The foil thickness control method for an aluminum honeycomb core according to claim 7, 8 or 9, wherein an alkaline solution is used as the etching solution.
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