JP4773247B2 - Molding method of polypropylene resin foam sheet - Google Patents

Molding method of polypropylene resin foam sheet Download PDF

Info

Publication number
JP4773247B2
JP4773247B2 JP2006099363A JP2006099363A JP4773247B2 JP 4773247 B2 JP4773247 B2 JP 4773247B2 JP 2006099363 A JP2006099363 A JP 2006099363A JP 2006099363 A JP2006099363 A JP 2006099363A JP 4773247 B2 JP4773247 B2 JP 4773247B2
Authority
JP
Japan
Prior art keywords
polypropylene resin
foam sheet
molding
resin foam
storage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2006099363A
Other languages
Japanese (ja)
Other versions
JP2007268919A (en
Inventor
幸司 五所尾
俊信 古木
信介 林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Kasei Co Ltd
Original Assignee
Sekisui Kasei Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Kasei Co Ltd filed Critical Sekisui Kasei Co Ltd
Priority to JP2006099363A priority Critical patent/JP4773247B2/en
Publication of JP2007268919A publication Critical patent/JP2007268919A/en
Application granted granted Critical
Publication of JP4773247B2 publication Critical patent/JP4773247B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Description

本発明は、ポリプロピレン系樹脂発泡シートの成形方法に関し、詳しくは、ポリプロピレン系樹脂発泡シートを用いて、IC部品等の電子部品,液晶表示パネル(LCD)、携帯情報端末装置(PDA)、液晶盤等の電気・電子製品(部品を含む)を収納する緩衝包装容器(トレイ含む)を成形する方法に関する。   The present invention relates to a method for molding a polypropylene resin foam sheet, and more specifically, using a polypropylene resin foam sheet, an electronic component such as an IC component, a liquid crystal display panel (LCD), a personal digital assistant (PDA), and a liquid crystal panel The present invention relates to a method for forming a buffer packaging container (including a tray) for storing electrical / electronic products (including parts) such as the above.

ポリプロピレン系樹脂発泡シートを用いて成形された電気・電子製品(部品を含む)用包装用容器(トレイ)が、緩衝包装材として使用されている。輸送コスト、保管コストなどの削減のためコンパクトな包装が可能な包装用容器(トレイ)が望まれており、特に電気・電子製品(部品を含む)を収納する包装用容器(トレイ)の収納部において当該電気・電子製品(部品を含む)を一定位置に保持する微小な支持部のコーナーを丸まりの少ないシャープな形状となした包装用容器(トレイ)として構成し、前記包装物の緩衝性を維持しつつ収納性を高めたトレイが要望されるようになってきた。   A packaging container (tray) for electric / electronic products (including parts) molded using a polypropylene resin foam sheet is used as a buffer packaging material. Packaging containers (tray) that can be compactly packed to reduce transportation costs, storage costs, etc. are desired, especially the packaging container (tray) storage part that stores electrical and electronic products (including parts). In this case, the corners of the minute support portions that hold the electric / electronic products (including parts) in a fixed position are configured as a packaging container (tray) having a sharp shape with little rounding, and the cushioning property of the package is improved. There has been a demand for trays that maintain and improve storage.

ところで従来、発泡ポリプロピレンシートの成形方法として、発泡ポリプロピレンシートを、密閉されたオーブンにて、155〜200℃の雰囲気温度、シート表面温度160±5℃等の成形条件にて成形することにより、加熱時間を短縮し、発泡PPシートの加熱不足や加熱オーバーを防止し、成形品の外観不良の発生を防止し品質のすぐれた成形品を得る成形方法が提供されている(特許文献1)。
特開平6−218805号公報
Conventionally, as a method for forming a foamed polypropylene sheet, the foamed polypropylene sheet is heated by molding it in a sealed oven under molding conditions such as an atmospheric temperature of 155 to 200 ° C. and a sheet surface temperature of 160 ± 5 ° C. There is provided a molding method that shortens the time, prevents insufficient heating and overheating of the foamed PP sheet, prevents appearance defects of the molded product, and obtains a molded product with excellent quality (Patent Document 1).
JP-A-6-218805

また、発泡ポリプロピレンシートの成形方法として、ポリプロピレン系樹脂からなる発泡シートを、加熱炉内にて5〜30秒加熱した後、成形直前におけるポリプロピレン系樹脂発泡シートの上下の表面温度差が10℃以下となるように、加熱されたポリプロピレン系樹脂発泡シートを成形金型の成形位置に導き、成形し、外観美麗、剛性、耐熱性のすぐれたポリプロピレン系樹脂発泡シートを成形する方法が提供されている。
特開2001−138349号公報
Further, as a method for forming a foamed polypropylene sheet, after a foamed sheet made of polypropylene resin is heated in a heating furnace for 5 to 30 seconds, the difference between the upper and lower surface temperature of the polypropylene resin foamed sheet immediately before molding is 10 ° C. or less. Thus, there is provided a method for forming a polypropylene resin foam sheet having excellent appearance, rigidity, and heat resistance by guiding the heated polypropylene resin foam sheet to the molding position of the molding die and molding it. .
JP 2001-138349 A

また、発泡ポリプロピレンシートの他の成形方法として、ポリプロピレン系樹脂発泡シートを予備加熱した後、成形金型により所望の成形品を得るポリプロピレン系樹脂発泡シートの成形方法において、上記成形金型の温度を予め40℃〜100℃に設定しておき、上記予備加熱によってポリプロピレン系樹脂発泡シートの表面温度を160℃〜200℃に設定した後に、上記金型により成形し、断熱性、緩衝性のすぐれたポリプロピレン系樹脂発泡シートの成形方法が提供されている。
特開平11−254518号公報
Further, as another molding method of the foamed polypropylene sheet, in the molding method of the polypropylene resin foamed sheet in which a polypropylene resin foamed sheet is preheated and a desired molded product is obtained by a molding die, the temperature of the molding die is set as follows. It was set in advance to 40 ° C. to 100 ° C., and after setting the surface temperature of the polypropylene-based resin foam sheet to 160 ° C. to 200 ° C. by the preheating, it was molded by the mold, and had excellent heat insulation and buffering properties. A method for forming a polypropylene resin foam sheet is provided.
JP-A-11-254518

前記特許文献1の方法は、155〜200℃の雰囲気温度、シート表面温度160±5℃等の成形条件にて成形することから、ポリプロピレン系樹脂発泡シートの伸びを最大限に発揮させ、成形品への残留歪を小さくするには良好な方法である。従ってこの方法は、収納面をシャープに成形したり、あるいはまた高い耐熱性を要求されるが、皿や浅い丼や弁当容器など角ばった凹凸状形状の少ない形状の食品容器用としては適している。
しかし、前記特許文献1の方法や特許文献3の方法では、シートの表面温度が高すぎて、既述した電気・電子製品(部品を含む)用包装用トレイのように、角ばった凸凹が多く、側壁の垂直度の高い形状のトレイにおいては、収納面をシャープに成形すると、部分的に成形品の側壁厚みが薄肉化しやすく、そのため外観不良や強度不足などが発生しやすかった。そこで、それを補うためにポリプロピレン系樹脂発泡シートの目付けを大きくすると、容器重量が重くなる上コストの高いものとなってしまうという問題があった。
Since the method of Patent Document 1 is molded under molding conditions such as an atmospheric temperature of 155 to 200 ° C. and a sheet surface temperature of 160 ± 5 ° C., the expanded product of the polypropylene-based resin foam sheet is maximized, and a molded product is obtained. This is a good method for reducing the residual strain. Therefore, this method is suitable for a food container having a shape with few irregularities such as a dish, a shallow bowl, a lunch box, etc., although the storage surface is sharply formed or high heat resistance is required. .
However, in the method of Patent Document 1 and the method of Patent Document 3, the surface temperature of the sheet is too high, and there are many angular irregularities like the packaging tray for electrical / electronic products (including parts) described above. In the tray having a shape with a high degree of verticality of the side walls, if the storage surface is sharply formed, the side wall thickness of the molded product is likely to be partially thinned, so that appearance defects and insufficient strength tend to occur. Therefore, if the basis weight of the polypropylene resin foam sheet is increased in order to compensate for this, there is a problem that the weight of the container increases and the cost becomes high.

一方、前記特許文献2は、5〜30秒以内の加熱時間でシート表面温度差を10℃以内の条件にて成形する方法であるから、収納面をシャープに成形するために成形温度を比較的高温にすると、前記の方法と同様、部分的に成形品の側壁厚みが薄肉化しやすく、そのため外観不良や強度不足などが発生しやすい。成形品の側壁厚みの薄肉化を防止するめに、上下シート温度差10℃以内に設定しつつ成形温度を下げると、成形品での部分的な薄肉化は少なくなるが、収納面にシャープな成形ができないという問題があった。
従来、シート成形する際は出来るだけシート温度差をつけずに成形することが好ましいとされてきたが、角ばった凸凹形状の多い、側壁の垂直度の高い形状の容器の成形においては薄肉化の防止とシャープな形状の両立はできなかった。
On the other hand, since Patent Document 2 is a method of forming a sheet surface temperature difference within 10 ° C. within a heating time of 5 to 30 seconds, the forming temperature is relatively low in order to form the storage surface sharply. When the temperature is increased, the side wall thickness of the molded product is likely to be partially reduced as in the above-described method, so that appearance defects and insufficient strength are likely to occur. If the molding temperature is lowered while setting the temperature difference between the upper and lower sheets to be within 10 ° C to prevent the side wall thickness of the molded product from becoming thinner, the partial thinning of the molded product will be reduced, but the molded surface will be sharply molded. There was a problem that could not.
Conventionally, when forming a sheet, it has been considered preferable to form the sheet with as little difference in sheet temperature as possible. However, in forming a container having a lot of angular irregularities and a shape with a high degree of verticality of the side wall, it is thinned. It was impossible to achieve both prevention and sharp shape.

本発明の解決すべき課題は、シャープな断面形状を有し、かつ部分的な厚みの薄肉化が抑えられた収納面を備えた軽量で強度のある容器(トレイ)、特に前記電気・電子製品(部品を含む)用容器(トレイ)を成形することができるポリプロピレン系樹脂発泡シートの成形方法を提供するところにある。   The problem to be solved by the present invention is a lightweight and strong container (tray) having a sharp cross-sectional shape and a storage surface in which partial thickness reduction is suppressed, particularly the electric / electronic product. The object of the present invention is to provide a method for forming a polypropylene resin foam sheet capable of forming a container (tray) for (including parts).

上記課題を解決するため本発明は、
ポリプロピレン系樹脂発泡シートを成形機の加熱炉内にて加熱した後、次の成形ゾーンにて製品(部品を含む)の収納部を有する成形品を成形するポリプロピレン系樹脂発泡シートの成形方法において、
成形直前における、製品(部品を含む)の収納側の面を形成する前記発泡シートの表面温度が150〜155℃、反対側の表面温度が135〜145℃、当該反対側の発泡シートの表面温度が前記収納側の面の表面温度よりも10〜15℃低い温度となるようにして成形することを特徴とするポリプロピレン系樹脂発泡シートの成形方法を採用した。
In order to solve the above problems, the present invention
In a method for molding a polypropylene resin foam sheet, in which a polypropylene resin foam sheet is heated in a heating furnace of a molding machine, and then a molded product having a product (including parts) storage portion is molded in the next molding zone.
Immediately before molding, the surface temperature of the foamed sheet forming the storage side surface of the product (including parts) is 150 to 155 ° C., the surface temperature of the opposite side is 135 to 145 ° C., the surface temperature of the foam sheet on the opposite side A method for molding a polypropylene-based resin foam sheet is employed, in which molding is performed at a temperature lower by 10 to 15 ° C. than the surface temperature of the storage side surface.

これにより、本発明は、シャープな断面形状を有し、かつ部分的な厚みの薄肉化が抑えられた収納面を備えた軽量で強度のある容器(トレイ)を成形することができる。   As a result, the present invention can form a lightweight and strong container (tray) having a sharp cross-sectional shape and having a storage surface in which partial thickness reduction is suppressed.

従って、本発明は、高い耐熱性を要求される食品用容器というよりは、むしろ角ばった凹凸断面を食品用容器より多く備えた前記電気・電子製品(部品を含む)用容器(トレイ)の成形方法として好適に用いられる。具体的には、断面が垂直方向の側面要素と水平方向の平面要素で構成され、容器(トレイ)の縦横XY方向の少なくとも一方向における一方又は両方の側壁において角ばった凹凸断面をなして、製品(部品を含む)を支える段差部を備えている緩衝包装用容器を成形するポリプロピレン系樹脂発泡シートの成形方法に好ましく適用できる。さらに具体的には、断面が垂直方向の側面要素と水平方向の平面要素で構成され、容器(トレイ)の縦横XY方向の少なくとも一方向における一方又は両方の側壁において角ばった凹凸断面をなして当該凸部の数を合計3個以上/150mm有する成形方法に好ましく適用できる。またさらには、製品(部品を含む)を底側から支える前記平面要素を段差部として構成し、当該製品(部品を含む)を両側から支える突起を前記側面要素に形成した前記容器の成形方法にも適用できる。なお、前記側面要素(側面部)と水平要素(水平部)のなす角度は、90〜100度が好ましい。90度を超える場合は特に前記突起(小突起)をさらに設けることが好ましい。
なお、前記150mmの測定箇所は、収納部の縦横XY方向の図1に示す平面長さS1あるいはS2によって測定した。
Therefore, the present invention is not a food container that requires high heat resistance, but rather a container (tray) for an electric / electronic product (including parts) having a more angular uneven cross section than a food container. It is suitably used as a method. Specifically, the cross section is composed of a vertical side element and a horizontal plane element, and the product has a concavo-convex cross section which is angular on one or both side walls in at least one of the vertical and horizontal XY directions of the container (tray). The present invention can be preferably applied to a method for forming a polypropylene resin foam sheet for forming a buffer packaging container having a stepped portion for supporting (including parts). More specifically, the cross section is composed of a vertical side element and a horizontal plane element, and forms a concave-convex cross section that is angular on one or both side walls in at least one of the vertical and horizontal XY directions of the container (tray). It can be preferably applied to a molding method having a total number of convex portions of 3 or more / 150 mm. Still further, in the molding method of the container, the planar element that supports the product (including parts) from the bottom side is configured as a stepped portion, and the protrusion that supports the product (including parts) from both sides is formed on the side element. Is also applicable. The angle formed between the side element (side part) and the horizontal element (horizontal part) is preferably 90 to 100 degrees. When the angle exceeds 90 degrees, it is particularly preferable to further provide the protrusion (small protrusion).
The measurement location of 150 mm was measured by the plane length S1 or S2 shown in FIG.

このようなことから、本発明は、ポリプロピレン系樹脂発泡シートからなる容器を軽薄短小化でき、コンパクトな包装が可能となるほか、容器の収納面の当該容器内側にて前記段差部と側壁部もしくは側壁部に形成された突起部分(微小な突起部分)において製品(部品を含む)を良好に支えることができ、緩衝性、収納性に優れた成形品を得ることができる。   For this reason, the present invention can make a container made of a polypropylene resin foam sheet light and thin, can be compactly packed, and the step portion and the side wall portion or the inner side of the container on the container storage surface. A product (including parts) can be favorably supported by the projecting portion (small projecting portion) formed on the side wall, and a molded product having excellent cushioning and storage properties can be obtained.

本発明は、ポリプロピレン系樹脂発泡シートを成形機の加熱炉内にて加熱した後、次の成形ゾーンにて製品(部品を含む)の収納部を有する成形品を成形するポリプロピレン系樹脂発泡シートの成形方法において、
成形直前における、製品(部品を含む)の収納側の面を形成する前記発泡シートの表面温度が150〜155℃、反対側の表面温度が135〜145℃、当該反対側の前記発泡シートの表面温度が前記収納側の表面温度よりも10〜15℃低い温度となるようにして成形することを特徴とするポリプロピレン系樹脂発泡シートの成形方法である。
The present invention relates to a polypropylene resin foam sheet that heats a polypropylene resin foam sheet in a heating furnace of a molding machine and then molds a molded product having a product (including parts) storage in a next molding zone. In the molding method,
Immediately before molding, the surface temperature of the foamed sheet forming the storage side surface of the product (including parts) is 150 to 155 ° C., the surface temperature of the opposite side is 135 to 145 ° C., the surface of the foam sheet on the opposite side A method for molding a polypropylene resin foam sheet, wherein the molding is performed such that the temperature is lower by 10 to 15 ° C. than the surface temperature on the storage side.

前記発泡シートにおける収納面側の面のシート表面温度が150℃未満では、当該収納面側の面をシャープな断面形状に成形することが困難である。前記収納面側の面のシート表面温度が155℃を超えると、成形品に薄肉化現象が生じやすい。また前記収納面側と反対側の前記発泡シートの面の表面温度が135℃未満では、伸びが不足して成形することが困難である。反対側の前記発泡シートの面の表面温度が145℃を超えると、成形品に薄肉化現象が生じやすい。
さらに、反対側の発泡シートの表面温度と前記収納側の面の表面温度の温度差が10℃未満では、シャープ性を追及するため成形温度を前記のように高温に設定したとき、成形品に薄肉化現象が生じやすい。前記温度差を10℃以内に設定しつつ成形温度を下げると、薄肉化は抑えられるが、収納面にシャープな成形ができない。既述の通り、シートを成形する際は出来るだけシート温度差をつけずに成形する事が好ましいとされてきたが、薄肉化の防止とシャープな形状の両立は困難である。
一方、前記温度差が15℃を超えると、シート温度差が大きく、前記収納側と反対側の両面でのシート伸びの差が大きくなりすぎ、良好な成形品を得る事が困難である。
前記表面温度の測定は非接触温度計(例えばHORIBA社製非接触放射温度計 IT−550L)を用いて測定することができる。温度測定は、成形直前の温度を測定することが好ましい。具体的には、成形機の加熱ゾーンで加熱された発泡シートが成形ゾーンに移動して成形位置に停止させられた後に測定する。発泡シートの表面温度が前記条件を満足しておれば直ちに成形する。成形までの時間は、長いと発泡シートの表面温度が低下しすぎる恐れがあるので3秒以内が好ましく、2秒以内がより好ましい。
When the sheet surface temperature of the storage surface side of the foamed sheet is less than 150 ° C., it is difficult to form the storage surface side surface into a sharp cross-sectional shape. When the sheet surface temperature on the storage surface side exceeds 155 ° C., a thinning phenomenon tends to occur in the molded product. Further, when the surface temperature of the surface of the foam sheet opposite to the storage surface is less than 135 ° C., it is difficult to mold due to insufficient elongation. If the surface temperature of the surface of the foam sheet on the opposite side exceeds 145 ° C., a thinning phenomenon tends to occur in the molded product.
Furthermore, when the temperature difference between the surface temperature of the opposite foam sheet and the surface temperature of the storage side surface is less than 10 ° C., in order to pursue sharpness, when the molding temperature is set to a high temperature as described above, Thinning phenomenon is likely to occur. If the molding temperature is lowered while setting the temperature difference within 10 ° C., thinning can be suppressed, but sharp molding cannot be performed on the storage surface. As described above, when forming a sheet, it has been preferable to form the sheet with as little difference in sheet temperature as possible, but it is difficult to achieve both prevention of thinning and a sharp shape.
On the other hand, if the temperature difference exceeds 15 ° C., the sheet temperature difference is large, the difference in sheet elongation on both sides opposite to the storage side becomes too large, and it is difficult to obtain a good molded product.
The surface temperature can be measured using a non-contact thermometer (for example, a non-contact radiation thermometer IT-550L manufactured by HORIBA). In the temperature measurement, it is preferable to measure the temperature immediately before molding. Specifically, the measurement is performed after the foam sheet heated in the heating zone of the molding machine has moved to the molding zone and stopped at the molding position. If the surface temperature of the foamed sheet satisfies the above conditions, it is molded immediately. If the time to molding is long, the surface temperature of the foamed sheet may be excessively lowered, so that it is preferably within 3 seconds, and more preferably within 2 seconds.

なお、成形するにあたっては、収納面の形状をよりシャープにするために、少なくとも前記発泡シートの収納側の面を真空吸引し成形することが好ましい。また、前記成形ゾーンにおいて、10〜15℃表面温度差を発泡シートに安定してつけられることから、前記発泡シートの前記収納側の面を下側にして成形することが好ましい。   In molding, in order to make the shape of the storage surface sharper, it is preferable to vacuum and form at least the surface on the storage side of the foam sheet. Further, in the molding zone, a surface temperature difference of 10 to 15 ° C. can be stably applied to the foamed sheet. Therefore, it is preferable to mold the foamed sheet with the storage side surface facing downward.

(ポリプロピレン系樹脂発泡シート)
本発明のポリプロピレン系樹脂発泡シートは、メルトテンションが20〜40gで、かつ自由末端長鎖分岐を有するポリプロピレン系樹脂(a)10〜50重量%と、メルトテンションが0.01g〜6gで、かつ重量平均分子量と数平均分子量の比の値が3〜8であるポリプロピレン系樹脂(b)90〜50重量%とからなるポリプロピレン系樹脂混合物を基材樹脂として、押出発泡されたポリプロピレン系樹脂発泡シートであることが好ましい。
(Polypropylene resin foam sheet)
The polypropylene resin foam sheet of the present invention has a melt tension of 20 to 40 g and a polypropylene resin (a) having a free-end long chain branch of 10 to 50% by weight, a melt tension of 0.01 g to 6 g, and Polypropylene resin foam sheet extruded and foamed using a polypropylene resin mixture comprising 90 to 50% by weight of a polypropylene resin (b) having a ratio of the weight average molecular weight to the number average molecular weight of 3 to 8 as a base resin. It is preferable that

これは、(a)の割合が多いほど、低密度で独立気泡率の高いポリプロピレン系樹脂発泡シートが製造しやすく、熱成形性にも優れるからである。一方で、(a)の樹脂は、製造方法が煩雑であり汎用の樹脂に比べると高価であるという問題があり、安価な汎用樹脂に含まれる(b)を混合するでコストダウンできる。   This is because the higher the proportion of (a), the easier it is to produce a polypropylene resin foam sheet having a low density and a high closed cell ratio, and excellent thermoformability. On the other hand, the resin (a) has a problem that the production method is complicated and expensive compared with a general-purpose resin, and the cost can be reduced by mixing (b) contained in an inexpensive general-purpose resin.

ポリプロピレン系樹脂(a)のメルトテンションは、20〜40gであり、より好ましくは20〜30gである。メルトテンションが20gより低いと、良好な発泡性を得ることができず、40gを超えると、極端に流動性が悪くなったり、ゲルを生じ易くなったりして、押出加工性が低下する。また、ポリプロピレン系樹脂(a)の重量平均分子量と数平均分子量の比(Mw/Mn)の値は、7〜20が好ましく、7〜15がさらに好ましい。この値が7より低いと良好な発泡性が得られ難く、20を超えるとゲルを生じ易くなり、外観が悪くなり易い。   The melt tension of the polypropylene resin (a) is 20 to 40 g, and more preferably 20 to 30 g. When the melt tension is lower than 20 g, good foamability cannot be obtained, and when it exceeds 40 g, the fluidity is extremely deteriorated or a gel is easily formed, and the extrusion processability is lowered. Moreover, 7-20 are preferable and, as for the value of the ratio (Mw / Mn) of the weight average molecular weight and number average molecular weight of polypropylene resin (a), 7-15 are more preferable. When this value is lower than 7, good foamability is difficult to obtain, and when it exceeds 20, gel is likely to be formed, and the appearance tends to be deteriorated.

(a)の樹脂は、特開昭62−121704号公報や特開平2−69533号公報に開示されているような方法で製造され、例えば、サンアロマー社から高溶融張力ポリプロピレン(HMSPP)として商品名「PF−814」として販売されている。   The resin (a) is produced by a method as disclosed in Japanese Patent Application Laid-Open No. 62-121704 and Japanese Patent Application Laid-Open No. 2-69533. It is sold as “PF-814”.

また、本発明で用いられるポリプロピレン系樹脂(b)のメルトテンションは0.01〜6gである。メルトテンションが0.01gより低いと、張力が低すぎるために熱成形する際、加熱時に垂れ下がり現象(ドローダウン)が生じ、良好な熱成形ができない。また、メルトテンションが6gを超えると、溶融粘度が高くなるため融点近傍まで樹脂温度を下げることが困難となる。その結果、得られる発泡体は連続気泡体となり易く、熱成形性が低下する。   The melt tension of the polypropylene resin (b) used in the present invention is 0.01 to 6 g. When the melt tension is lower than 0.01 g, since the tension is too low, a drooping phenomenon (drawdown) occurs during heating, and good thermoforming cannot be performed. On the other hand, when the melt tension exceeds 6 g, it becomes difficult to lower the resin temperature to near the melting point because the melt viscosity increases. As a result, the obtained foam tends to be open-celled and the thermoformability is lowered.

ポリプロピレン系樹脂(b)の重量平均分子量と数平均分子量の比の値は3〜8であり、好ましくは4〜6である。この値が3より小さいと弾性が低くて熱成形性が悪くなり、8を超えると均一に樹脂温度を下げることが困難となり、連続気泡率の低い発泡シートが得られ難くなる。このようなポリプロピレン系樹脂(b)としては、例えば、上記の条件を満足するホモポリプロピレン、エチレン−プロピレン共重合体などが挙げられる。   The value of the ratio of the weight average molecular weight to the number average molecular weight of the polypropylene resin (b) is 3 to 8, preferably 4 to 6. If this value is less than 3, the elasticity is low and the thermoformability is poor, and if it exceeds 8, it is difficult to uniformly lower the resin temperature, and it becomes difficult to obtain a foam sheet having a low open cell ratio. Examples of such a polypropylene resin (b) include homopolypropylene and ethylene-propylene copolymers that satisfy the above conditions.

ポリプロピレン系樹脂(a)とポリプロピレン系樹脂(b)との混合割合は、(a)10〜50重量%(b)90〜50重量%であり、(a)20〜50重量%(b)80〜50重量%がより好ましく、(a)30〜50重量%(b)70〜50重量%が特に好ましい。ポリプロピレン系樹脂(a)の混合割合が10重量%より少ないと、ポリプロピレン系樹脂(b)の発泡性を向上させることが困難となり、得られた発泡シートの熱成形性が劣る。   The mixing ratio of the polypropylene resin (a) and the polypropylene resin (b) is (a) 10 to 50% by weight (b) 90 to 50% by weight, and (a) 20 to 50% by weight (b) 80. -50% by weight is more preferred, and (a) 30-50% by weight (b) 70-50% by weight is particularly preferred. When the mixing ratio of the polypropylene resin (a) is less than 10% by weight, it becomes difficult to improve the foamability of the polypropylene resin (b), and the thermoformed property of the obtained foamed sheet is inferior.

本発明で使用されるポリプロピレン系樹脂発泡シートの製造に使用する発泡剤としては、種々の揮発性発泡剤や分解型発泡剤が挙げられる。揮発性発泡剤としては、例えば、プロパン、ブタン、ペンタンなどの炭化水素、テトラフルオロエタン、クロロジフルオロエタン、ジフルオロエタン等のハロゲン化炭化水素が挙げられる。分解型発泡剤としては、アゾジカルボンアミド、ジニトロソペンタメチレンテトラミン等の有機系発泡剤、重炭酸ナトリウムまたはクエン酸のような有機酸もしくはその塩と重炭酸塩との組み合わせなどが挙げられる。また、場合によっては、二酸化炭素、窒素ガス、水なども適宜用いることができる。これらの発泡剤は単独で、または2種以上を組み合わせて用いてもよい。
本発明のポリプロピレン系樹脂発泡シートの基材樹脂には、上記のような発泡剤が添加されるほか、例えばタルク、重炭酸ナトリウム−クエン酸などの、発泡の際に気泡の大きさ等を調整する気泡調整剤や、顔料、安定剤、充填剤、帯電防止剤などの種々の添加剤を添加してもよい。充填材としては、例えばタルク、クレー、炭酸カルシウム、シリカ、水酸化マグネシウム等の無機充填剤が好ましく、基材樹脂100重量部に対して5〜50重量部添加するのが好ましい。
Examples of the foaming agent used in the production of the polypropylene resin foam sheet used in the present invention include various volatile foaming agents and decomposable foaming agents. Examples of the volatile blowing agent include hydrocarbons such as propane, butane, and pentane, and halogenated hydrocarbons such as tetrafluoroethane, chlorodifluoroethane, and difluoroethane. Examples of the decomposable foaming agent include organic foaming agents such as azodicarbonamide and dinitrosopentamethylenetetramine, organic acids such as sodium bicarbonate or citric acid, or a combination of a salt thereof and a bicarbonate. In some cases, carbon dioxide, nitrogen gas, water, or the like can be used as appropriate. These foaming agents may be used alone or in combination of two or more.
In addition to the above-mentioned foaming agent added to the base resin of the polypropylene resin foam sheet of the present invention, for example, talc, sodium bicarbonate-citric acid, etc., adjust the size of bubbles when foaming Various additives such as an air-conditioning agent, a pigment, a stabilizer, a filler, and an antistatic agent may be added. As the filler, for example, inorganic fillers such as talc, clay, calcium carbonate, silica, and magnesium hydroxide are preferable, and it is preferable to add 5 to 50 parts by weight with respect to 100 parts by weight of the base resin.

また、本発明のポリプロピレン系樹脂発泡シートは、成形品の外観ならびに強度を向上させるために、ポリプロピレン系樹脂発泡シートの片面あるいは両面に非発泡性の樹脂からなるフィルムを積層してもよい。   In addition, in the polypropylene resin foam sheet of the present invention, a film made of non-foamable resin may be laminated on one side or both sides of the polypropylene resin foam sheet in order to improve the appearance and strength of the molded product.

フィルムを構成する樹脂としては、特に限定されないが、発泡シートと同タイプのプロピレン系樹脂を主成分とするものが好ましい。   Although it does not specifically limit as resin which comprises a film, What has the propylene-type resin of the same type as a foam sheet as a main component is preferable.

フィルムは延伸フィルムでも無延伸フィルムでもよく、フィルム層の厚さは、通常0.02〜1.0mm、好ましくは0.1〜0.5mmである。このフィルム層には、例えばタルク、クレー、炭酸カルシウム、シリカ、水酸化マグネシウム等の無機充填剤、帯電防止剤、カーボンなどの導電性材料が含まれていてもよい。フィルムの積層は、例えば熱ラミネート法、共押出法等、常法により行われる。   The film may be a stretched film or an unstretched film, and the thickness of the film layer is usually 0.02 to 1.0 mm, preferably 0.1 to 0.5 mm. This film layer may contain, for example, an inorganic filler such as talc, clay, calcium carbonate, silica, and magnesium hydroxide, an antistatic agent, and a conductive material such as carbon. Lamination of the film is performed by a conventional method such as a heat lamination method or a coextrusion method.

本発明のポリプロピレン系樹脂発泡シートは、ポリプロピレン系樹脂(a)およびポリプロピレン系樹脂(b)からなる基材樹脂と発泡剤とを押出機で溶融混練し、次いで押出機先端に取り付けられた金型を通して押出発泡する方法により製造される。
このようにして製造されるポリプロピレン系樹脂発泡シートは、例えば、厚み0.5〜5.0mm、好ましくは0.5〜3mmに成形される。厚みが0.5mm未満であると、強度が弱く、緩衝性が低下するので好ましくない。また、5.0mmを超えると熱成形性が悪くなり好ましくない。
The polypropylene resin foam sheet of the present invention is a mold in which a base resin comprising a polypropylene resin (a) and a polypropylene resin (b) and a foaming agent are melt-kneaded with an extruder and then attached to the tip of the extruder. Produced by extrusion foaming through.
The polypropylene resin foam sheet produced in this way is molded to a thickness of 0.5 to 5.0 mm, preferably 0.5 to 3 mm, for example. If the thickness is less than 0.5 mm, the strength is weak and the buffering property is lowered, which is not preferable. On the other hand, if it exceeds 5.0 mm, the thermoformability is deteriorated.

ポリプロピレン系樹脂発泡シートは0.1〜0.45g/cm3、好ましくは0.18〜0.45g/cm3程度の密度を有している。密度が0.1g/cm3より低いと強度が弱くなり好ましくない。また、0.45g/cm3より高いと緩衝性が低下するので好ましくない。 The polypropylene resin foam sheet has a density of about 0.1 to 0.45 g / cm 3 , preferably about 0.18 to 0.45 g / cm 3 . When the density is lower than 0.1 g / cm 3 , the strength is unfavorable. Moreover, since buffer property will fall when it is higher than 0.45 g / cm < 3 >, it is not preferable.

ポリプロピレン系樹脂発泡シートの目付けは、小さいと本発明の成形方法であっても、成形品の形状にもよるが部分的な薄肉化を生じたり、成形品の強度が不足する恐れがあるので500g/m以上であるものを使用することが好ましい。 If the basis weight of the polypropylene resin foam sheet is small, even if it is the molding method of the present invention, although it depends on the shape of the molded product, partial thinning may occur or the strength of the molded product may be insufficient. It is preferable to use one that is / m 2 or more.

本発明における、ポリプロピレン系樹脂のメルトテンションは、次の方法により求められる。(株)東洋精機製作所製のキャピログラフPMD−Cを使用して、ポリプロピレン系樹脂を230℃に加熱し、溶融したポリプロピレン系樹脂をピストン押出式プラストメーターでノズル(口径2.095mm、長さ8mm)からピストンの降下速度を10mm/分の一定速度に保ちながらひも状に押出し、次いで該ひも状物を前記ノズルの下方35cmに位置する張力検出プーリーに通過させた後、巻き取りロールで約66m/分2程度の割合で、ひも状物が切れるまで巻き取り速度を徐々に増加させていき、その切れた時点の張力(g)をその樹脂のメルトテンションとした。ただし、巻き取り速度が60m/分を超えてもひも状物が切断しない場合には、巻き取り速度60m/分での張力(g)をその樹脂のメルトテンションとした。 The melt tension of the polypropylene resin in the present invention is determined by the following method. Using Capillograph PMD-C manufactured by Toyo Seiki Seisakusho Co., Ltd., the polypropylene resin is heated to 230 ° C., and the melted polypropylene resin is nozzled with a piston extrusion plastometer (2.095 mm in diameter and 8 mm in length). The piston is extruded into a string while maintaining the piston descending speed at a constant speed of 10 mm / min, and then the string is passed through a tension detection pulley located 35 cm below the nozzle, and then is wound at about 66 m / At a rate of about 2 minutes, the winding speed was gradually increased until the string-like material was cut, and the tension (g) at that time was taken as the melt tension of the resin. However, if the string did not cut even when the winding speed exceeded 60 m / min, the tension (g) at the winding speed of 60 m / min was used as the melt tension of the resin.

本発明における、ポリプロピレン系樹脂の重量平均分子量と数平均分子量の比の値は、ゲルパーミエイションクロマトグラフによる分子量分布測定により以下の条件で求められる。
測定装置:Waters社製 GPC 150−C
カラム :UT−806M 3本(SHODEX)
カラム温度:145℃
注入温度: 145℃
ポンプ温度:55℃
使用溶剤: o−ジクロロベンゼン
流量: 1.0ml/分
In the present invention, the ratio of the weight average molecular weight to the number average molecular weight of the polypropylene-based resin can be determined under the following conditions by molecular weight distribution measurement by gel permeation chromatography.
Measuring device: GPC 150-C manufactured by Waters
Column: 3 UT-806M (SHODEX)
Column temperature: 145 ° C
Injection temperature: 145 ° C
Pump temperature: 55 ° C
Solvent used: o-dichlorobenzene Flow rate: 1.0 ml / min

本発明で用いられるポリプロピレン系樹脂(a)および(b)における、自由末端長鎖分岐の有無は、特開昭62−121704号公報に記載の方法に従って、樹脂の伸び特性を見ることにより確認した。   The presence or absence of free end long chain branching in the polypropylene resins (a) and (b) used in the present invention was confirmed by observing the elongation characteristics of the resin according to the method described in JP-A No. 62-121704. .

本発明の成形方法を用いて図1に示する電子部品収納用のトレイを成形した。   The electronic component storage tray shown in FIG. 1 was molded using the molding method of the present invention.

(発泡シートの製造)
ポリプロピレン系樹脂として、サンアロマー社製、商品名「PF−814」(MI値3、メルトテンション24.5g)40重量%、日本ポリプロ社製、商品名「BC6C」(MI値2.5、メルトテンション2.3g)60重量%の混合樹脂100重量部に、気泡調整剤として重曹−クエン酸系マスターバッチ(大日精化社製、商品名「ファインセルマスターPO410K」)0.3重量部をドライブレンドし、この混合物を、口径φ65−φ90mmの第1押出機および第2押出機からなるタンデム押出機の口径φ65mm押出機のホッパーを通じて供給し、加熱溶融した後、発泡剤としてブタン(イソブタン/ノルマルブタン=35/65)を圧入し、溶融混合させた。次いで、口径90mm押出機に移送して均一に冷却した後、口径60mmの円筒状ダイから吐出量40kg/時間で押出発泡させ、得られた円筒状発泡体を内部が約20℃の水で冷却されているφ170のマンドレル上を沿わせ、またその外面をその径よりも大きいエアリングによりエアーを吹き付けることにより冷却成形し、円周上の1点でカッターにより切開して、目付け700g/m、厚み2.2mm、密度0.318g/cmのポリプロピレン系樹脂発泡シートを得た。
(Manufacture of foam sheet)
As polypropylene-based resin, trade name “PF-814” (MI value 3, melt tension 24.5 g) 40% by weight, manufactured by Sun Polymer Co., Ltd., trade name “BC6C” (MI value 2.5, melt tension) 2.3 g) Dry blend of 100 parts by weight of a mixed resin of 60% by weight with 0.3 parts by weight of a baking soda-citric acid master batch (trade name “Fine Cell Master PO410K”, manufactured by Dainichi Seika Co., Ltd.) as a foam regulator. Then, this mixture was fed through a hopper of a caliber φ65 mm extruder of a tandem extruder consisting of a first extruder and a second extruder having a caliber φ65-φ90 mm, heated and melted, and then butane (isobutane / normal butane as a blowing agent) = 35/65) was melted and mixed. Next, it is transferred to an extruder with a diameter of 90 mm and cooled uniformly, and then extruded and foamed from a cylindrical die with a diameter of 60 mm at a discharge rate of 40 kg / hour, and the obtained cylindrical foam is cooled with water having an inside of about 20 ° C. The outer surface is cooled and formed by blowing air with an air ring larger than the diameter of the mandrel having a diameter of φ170, cut at a point on the circumference with a cutter, and a basis weight of 700 g / m 2. A polypropylene resin foam sheet having a thickness of 2.2 mm and a density of 0.318 g / cm 3 was obtained.

上記ポリプロピレン系樹脂発泡シートを用い、成形機は入口と出口のみ開放された加熱炉を有する連続成形機を使用した。成形用金型はマッチモールド成形金型を使用し、前期発泡シートの前記収納側の面を下側にし下金型側で成形し、反対側の面は上金型側で成形した。また当該成形は、前記発泡シートの収納側の面を真空吸引(真空度:85KPa)して成形した。成形金型温度は40℃以下とした。   The above-mentioned polypropylene resin foam sheet was used, and the molding machine used was a continuous molding machine having a heating furnace opened only at the inlet and outlet. The mold for molding was a match mold mold, and the above-mentioned foamed sheet was molded on the lower mold side with the storage side surface facing down, and the opposite side was molded on the upper mold side. Moreover, the said shaping | molding carried out vacuum suction (vacuum degree: 85 KPa) and shape | molded the surface by the side of the accommodation of the said foam sheet. The mold temperature was 40 ° C. or less.

発泡シート成形の温度条件は表1に示す通りである。発泡シートの表面温度は、非接触放射温度計 HORIBA IT−550Lを用いて、発泡シートが加熱炉から成形金型面に移動し、成形直前の温度を測定した。   Table 1 shows the temperature conditions for forming the foamed sheet. The surface temperature of the foam sheet was measured by using a non-contact radiation thermometer HORIBA IT-550L, and the foam sheet moved from the heating furnace to the molding die surface, and the temperature immediately before molding was measured.

図1は本発明の実施例の方法により成形される電子部品収納用のトレイの平面図、図2は同正面図、図3は同右側面図、図4は同トレイに形成された収納部の要部拡大平面図、図5は図4におけるA−A線断面図である。   1 is a plan view of an electronic component storage tray formed by the method of the embodiment of the present invention, FIG. 2 is a front view thereof, FIG. 3 is a right side view thereof, and FIG. 4 is a storage portion formed on the tray. FIG. 5 is a cross-sectional view taken along line AA in FIG.

図において、1は電子部品3の収納用のトレイ、2は電子部品を嵌め入れて収納する凹形状の収納部である。本トレイ1は、縦幅550mm、横幅310mm、高さ20mmであり、図示の通り、電子部品を嵌め入れて収納する収納部2が横2列にて縦方向に5箇所形成されている。収納部2は、図1及び図5に示すように、縦幅S1は75mm、横幅S2は55mm、深さS3は15mmで構成されている。   In the figure, reference numeral 1 denotes a tray for storing electronic components 3, and 2 denotes a concave storage portion for receiving and storing electronic components. The tray 1 has a vertical width of 550 mm, a horizontal width of 310 mm, and a height of 20 mm. As shown in the drawing, storage portions 2 for storing electronic components therein are formed in two horizontal rows in five vertical directions. As shown in FIGS. 1 and 5, the storage unit 2 has a vertical width S1 of 75 mm, a horizontal width S2 of 55 mm, and a depth S3 of 15 mm.

図4及び図5に示すように、本トレイ1は、当該容器(トレイ)の縦X方向それぞれの収納部2内側の各側壁B、Cにおいて、収納部2の開口部2a側より深さ方向に向って、断面が水平方向の平面要素22a、断面が垂直方向の側面要素21a、断面が水平方向の平面要素22b、断面が垂直方向の側面要素21b、断面が水平方向の平面要素22cとで構成されている。そして、当該容器(トレイ)の縦X方向それぞれの収納部2内側の各側壁B、Cには、角ばった凹凸断面をなして収納部2の深さ方向に当該凸部23a、23bをそれぞれ有している。24aは側面要素21aと平面要素22bで構成された凹部、24bは側面要素21bと平面要素22cで構成された凹部である。平面要素22cは収納部2の底面部26を構成している。凹部24aと凸部23b間の平面要素22bと、凸部23bと凹部24b間の側面要素21bとは、各側壁B、Cにおいて、電子部品3を当該平面要素22bにおいて底側から支える段差部27を構成している。また各側壁B、Cには、収納部2の開口部側の側面要素21aの前記凹部24a側の一部に、収納する電子部品3を両側から支える微小な突部25a(小突起)が突出形成されている。
なお、この例では、凸部23a、23bは側壁Bにおいて2個、側壁Cにおいて2個あり、X方向の収納部平面長さ75mmあたり合計4個有している。またこの例では、各側壁B、Cの側面要素21aと平面要素22bとがなす角度及び側面要素21bと平面要素22cとがなす角度は97度である。
As shown in FIGS. 4 and 5, the main tray 1 has a depth direction from the side of the opening 2 a of the storage portion 2 in each side wall B, C inside the storage portion 2 in the vertical X direction of the container (tray). The horizontal plane element 22a, the cross-section is a vertical side element 21a, the cross-section is a horizontal plane element 22b, the cross-section is a vertical side element 21b, and the cross-section is a horizontal plane element 22c. It is configured. And each side wall B and C inside the storage part 2 inside each vertical X direction of the said container (tray) has the said convex part 23a, 23b in the depth direction of the storage part 2 by making the square uneven | corrugated cross section, respectively. is doing. Reference numeral 24a denotes a recess composed of the side element 21a and the planar element 22b, and reference numeral 24b denotes a recess composed of the side element 21b and the planar element 22c. The planar element 22 c constitutes the bottom surface portion 26 of the storage portion 2. The planar element 22b between the concave portion 24a and the convex portion 23b and the side surface element 21b between the convex portion 23b and the concave portion 24b are stepped portions 27 that support the electronic component 3 from the bottom side in the planar element 22b on each of the side walls B and C. Is configured. Further, on each of the side walls B and C, a minute protrusion 25a (small protrusion) that supports the electronic component 3 to be stored from both sides protrudes from a part of the side element 21a on the opening side of the storage 2 on the concave portion 24a side. Is formed.
In this example, there are two convex portions 23a and 23b on the side wall B and two on the side wall C, and a total of four convex portions per 75 mm in the length of the storage portion plane in the X direction. In this example, the angle formed between the side surface element 21a and the planar element 22b and the angle formed between the side surface element 21b and the planar element 22c on each side wall B and C are 97 degrees.

かかる構成は、図4に示す当該容器(トレイ)の横Y方向の横断面においても同様に形成されている。   Such a configuration is similarly formed in the cross section in the horizontal Y direction of the container (tray) shown in FIG.

また比較のため、表1に示す条件以外は同条件で前記実施例と同様に図1に示する電子部品収納用のトレイを成形した。   For comparison, a tray for storing electronic components shown in FIG. 1 was molded in the same manner as in the above example except for the conditions shown in Table 1.

Figure 0004773247
Figure 0004773247

次に、成形して得られたそれぞれの電子部品収納用のトレイについて、収納面のシャープ性を評価するため、前記凸部23の断面アール(R)を測定した。この断面アール(R)は、断面をカットして拡大写真を撮影し測定した。成形品からN=5(サンプル数)を抽出してその平均値で下記の基準で評価した。表2にその結果を示す。
○ 凸部Rが1.3mm未満
△ 凸部Rが1.3mm以上、2mm未満
× 凸部Rが2mm以上
Next, in order to evaluate the sharpness of the storage surface of each electronic component storage tray obtained by molding, the cross-sectional radius (R) of the convex portion 23 was measured. This cross-section R (R) was measured by cutting a cross-section and taking an enlarged photograph. N = 5 (number of samples) was extracted from the molded product, and the average value was evaluated according to the following criteria. Table 2 shows the results.
○ Convex part R is less than 1.3 mm Δ Convex part R is 1.3 mm or more and less than 2 mm × Convex part R is 2 mm or more

次に、成形性を、トレイを10個成形して下記の基準で評価した。
○ 10個のトレイすべて、側面要素である側壁部分に薄肉化による成形前発泡シートの厚みの1/10以下の厚みの部分または穴あきがない。
△ 1〜2個のトレイに、側面要素である側壁部分に薄肉化にによる成形前発泡シートの厚みの1/10以下の厚みの部分または穴あきがある。
× 3個以上のトレイに、側面要素である側壁部分に薄肉化による成形前発泡シートの厚みの1/10以下の厚みの部分または穴あきがある。
Next, moldability was evaluated according to the following criteria after forming 10 trays.
○ All the 10 trays have no portion or perforation with a thickness of 1/10 or less of the thickness of the foam sheet before molding due to thinning on the side wall portion which is a side element.
Δ In one or two trays, there are portions or perforations having a thickness of 1/10 or less of the thickness of the pre-molding foamed sheet due to thinning of the side wall portions which are side elements.
X Three or more trays have a portion or perforation having a thickness of 1/10 or less of the thickness of the foam sheet before molding by thinning on the side wall portion which is a side surface element.

さらに総合評価を下記の基準で評価した。
○ 収納面シャープ性評価、及び成形性評価ともに○
× 収納面シャープ性評価、及び成形性評価ともに○でないもの
Furthermore, comprehensive evaluation was evaluated according to the following criteria.
○ Both storage surface sharpness evaluation and moldability evaluation ○
× Storage surface sharpness evaluation and moldability evaluation are not ○

Figure 0004773247
Figure 0004773247

本発明の方法により、ポリプロピレン系樹脂発泡シートを用いて、断面が角ばった凸凹形状の多く、側壁の垂直度の高い形状の容器、例えばIC部品等の電子部品,液晶表示パネル(LCD)、携帯情報端末装置(PDA)、液晶盤等の電気・電子製品(部品を含む)を収納する緩衝包装容器(トレイ含む)を、シャープな断面形状を有し、かつ部分的な厚みの薄肉化が抑えられた収納面を備えた容器(トレイ)として成形することができる。   By using the method of the present invention, a container having a lot of irregularities with a square cross section and a high degree of verticality of the side wall using a polypropylene resin foam sheet, for example, an electronic component such as an IC component, a liquid crystal display panel (LCD), a portable Buffer packaging containers (including trays) that store electrical and electronic products (including parts) such as information terminal devices (PDAs) and liquid crystal panels have a sharp cross-sectional shape and suppress partial thinning. It can shape | mold as a container (tray) provided with the accommodated storage surface.

本発明の実施例の方法により成形される電子部品収納用のトレイの平面図である。It is a top view of the tray for electronic component accommodation shape | molded by the method of the Example of this invention. 同正面図である。It is the same front view. 同右側面図である。It is the same right view. 同トレイに形成された収納部の要部拡大平面図である。It is a principal part enlarged plan view of the accommodating part formed in the tray. 図4におけるA−A線断面図である。It is the sectional view on the AA line in FIG.

符号の説明Explanation of symbols

1 トレイ
2 収納部
3 電子部品
1 Tray 2 Storage 3 Electronic parts

Claims (5)

ポリプロピレン系樹脂発泡シートを成形機の加熱炉内にて加熱した後、次の成形ゾーンにて製品(部品を含む)の収納部を有する成形品を成形するポリプロピレン系樹脂発泡シートの成形方法において、
成形直前における、製品(部品を含む)の収納側の面を形成する前記発泡シートの表面温度が150〜155℃、反対側の表面温度が135〜145℃、当該反対側の前記発泡シートの表面温度が前記収納側の表面温度よりも10〜15℃低い温度となるようにして成形することを特徴とするポリプロピレン系樹脂発泡シートの成形方法。
In a method for molding a polypropylene resin foam sheet, in which a polypropylene resin foam sheet is heated in a heating furnace of a molding machine, and then a molded product having a product (including parts) storage portion is molded in the next molding zone.
Immediately before molding, the surface temperature of the foamed sheet forming the storage side surface of the product (including parts) is 150 to 155 ° C., the surface temperature of the opposite side is 135 to 145 ° C., the surface of the foam sheet on the opposite side A method for molding a polypropylene resin foam sheet, wherein the molding is performed such that the temperature is lower by 10 to 15 ° C than the surface temperature on the storage side.
少なくとも前記発泡シートの収納側の面を真空吸引し成形することを特徴とする請求項1に記載のポリプロピレン系樹脂発泡シートの成形方法。   2. The method for molding a polypropylene resin foam sheet according to claim 1, wherein at least a surface on the storage side of the foam sheet is vacuum sucked and molded. 前記ポリプロピレン系樹脂発泡シートが、メルトテンションが20〜40gで、かつ自由末端長鎖分岐を有するポリプロピレン系樹脂(a)10〜50重量%と、メルトテンションが0.01g〜6gで、かつ重量平均分子量と数平均分子量の比の値が3〜8であるポリプロピレン系樹脂(b)90〜50重量%とからなるポリプロピレン系樹脂混合物を基材樹脂として、押出発泡されたポリプロピレン系樹脂発泡シートであることを特徴とする請求項1又は2記載のポリプロピレン系樹脂発泡シートの成形方法。   The polypropylene resin foam sheet has a melt tension of 20 to 40 g, a polypropylene resin (a) having a free-end long chain branch of 10 to 50% by weight, a melt tension of 0.01 to 6 g, and a weight average. A polypropylene resin foam sheet that is extruded and foamed using a polypropylene resin mixture comprising 90 to 50% by weight of a polypropylene resin (b) having a ratio of the molecular weight and the number average molecular weight of 3 to 8 as a base resin. The method for molding a polypropylene resin foam sheet according to claim 1 or 2. 断面が垂直方向の側面要素と水平方向の平面要素で構成され、
容器(トレイ)の縦横XY方向の少なくとも一方向における一方又は両方の側壁において角ばった凹凸断面をなして、当該凸部の数を合計3個以上/150mm有し、且つ製品(部品を含む)を支える段差部を備えている緩衝包装用容器を成形する請求項1乃至3のいずれかの項に記載のポリプロピレン系樹脂発泡シートの成形方法。
The cross section consists of vertical side elements and horizontal plane elements,
Forming a concavo-convex cross section at one or both side walls in at least one of the vertical and horizontal XY directions of the container (tray), and having a total of 3 or more / 150 mm of the convex portions, and a product (including parts) The method for molding a polypropylene resin foam sheet according to any one of claims 1 to 3, wherein a buffer packaging container having a stepped portion to be supported is molded.
前記製品(部品を含む)が電気・電子製品(部品を含む)である請求項4記載のポリプロピレン系樹脂発泡シートの成形方法。

The method for molding a polypropylene resin foam sheet according to claim 4, wherein the product (including parts) is an electric / electronic product (including parts).

JP2006099363A 2006-03-31 2006-03-31 Molding method of polypropylene resin foam sheet Expired - Fee Related JP4773247B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006099363A JP4773247B2 (en) 2006-03-31 2006-03-31 Molding method of polypropylene resin foam sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006099363A JP4773247B2 (en) 2006-03-31 2006-03-31 Molding method of polypropylene resin foam sheet

Publications (2)

Publication Number Publication Date
JP2007268919A JP2007268919A (en) 2007-10-18
JP4773247B2 true JP4773247B2 (en) 2011-09-14

Family

ID=38672202

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006099363A Expired - Fee Related JP4773247B2 (en) 2006-03-31 2006-03-31 Molding method of polypropylene resin foam sheet

Country Status (1)

Country Link
JP (1) JP4773247B2 (en)

Also Published As

Publication number Publication date
JP2007268919A (en) 2007-10-18

Similar Documents

Publication Publication Date Title
US20210332209A1 (en) Insulated container
JP5649175B2 (en) Inner fitting container using a container made of polystyrene resin laminated foam sheet as the container body
JP2001315277A (en) Polypropylene resin-laminated foam and molded container using the foam
JP2004043813A (en) Polyethylene-based resin extruded and foamed sheet, shaped product of the foamed sheet, assembled box, lining sheet for concrete formwork, and manufacturing method of the formed sheet
JP3704034B2 (en) Polypropylene-based resin foam, molded product and method for producing the same
JP4680528B2 (en) Ethylene resin foam sheet for thermoforming, molded article, and method for producing ethylene resin foam sheet for thermoforming
JP4064754B2 (en) Polypropylene resin foam sheet
JP2006274038A (en) Uncrosslinked polyethylene-based resin extrusion-foamed body and molded body thereof
JP4605697B2 (en) Non-crosslinked polyethylene resin extruded foam for molding and molded body thereof
JP3718635B2 (en) Laminated foam molded product of polypropylene resin, laminated foam used in the production thereof, and production method thereof
JPH08259721A (en) Modified polypropylene resin foam, multilayer foam, and molded article obtained therefrom
JP4773247B2 (en) Molding method of polypropylene resin foam sheet
JP4055540B2 (en) Polypropylene resin extruded foam sheet, method for producing the same, and molded article thereof
JP3717376B2 (en) Non-crosslinked polyethylene resin foam, method for producing the same, and molded article using the same
JP7030598B2 (en) Laminated foam sheet and molded body
JP3851651B2 (en) High density polyethylene resin foam sheet and method for producing the sheet container
JP5198086B2 (en) Polypropylene resin foam sheet
US10513589B2 (en) Polymeric material for an insulated container
JP5757622B2 (en) Polyethylene resin multilayer foam sheet for thermoforming
JPH08174737A (en) Laminated foamed polypropylene resin sheet and molded piece thereof
JP5808841B2 (en) Method for producing polyethylene resin extruded foam sheet
JP7299032B2 (en) Laminated foam sheet and molding
JP5751670B2 (en) Polyethylene resin multilayer foam sheet and molded article thereof
JP2007246776A (en) Uncrosslinked polyethylene-based resin foamed sheet for molding
JP2003313348A (en) Polypropylene resin single-layer extrusion-foamed sheet and foamed forming formed therefrom

Legal Events

Date Code Title Description
RD04 Notification of resignation of power of attorney

Free format text: JAPANESE INTERMEDIATE CODE: A7424

Effective date: 20071206

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20081110

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20110526

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110607

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20110623

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140701

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

Ref document number: 4773247

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150

LAPS Cancellation because of no payment of annual fees