JP4749320B2 - Manufacturing method of composite nonwoven fabric - Google Patents

Manufacturing method of composite nonwoven fabric Download PDF

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JP4749320B2
JP4749320B2 JP2006348340A JP2006348340A JP4749320B2 JP 4749320 B2 JP4749320 B2 JP 4749320B2 JP 2006348340 A JP2006348340 A JP 2006348340A JP 2006348340 A JP2006348340 A JP 2006348340A JP 4749320 B2 JP4749320 B2 JP 4749320B2
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nonwoven fabric
composite
fiber
manufacturing
fabric
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JP2008156793A (en
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祥一 種市
啓介 長島
泰樹 内山
渉 坂
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Kao Corp
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    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5414Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres side-by-side
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • D04H1/5412Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres sheath-core

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Nonwoven Fabrics (AREA)

Description

本発明は、複合不織布の製造方法に関わり、特に、生理用ナプキンや使い捨ておむつ等の吸収性物品の表面材に用いて好適な、複合不織布の製造方法に関する。   The present invention relates to a method for producing a composite nonwoven fabric, and more particularly to a method for producing a composite nonwoven fabric suitable for use as a surface material for absorbent articles such as sanitary napkins and disposable diapers.

吸収性物品の表面材等に使用されるシートの製造方法に関する従来技術として、例えば、下記特許文献1及び2に記載の技術が提案されている。特許文献1に記載の技術は、カード機により開繊した繊維ウェブどうしを重ねてエンボスロール間に通して複合化するものであるが、得られる不織布は、繊維どうしがエンボスロールによる接合部分以外では、熱融着していないため、毛羽立ちやすいものとなってしまい、吸収性物品の表面材として用いる場合には、好ましくない。また、カード機により開繊した繊維ウェブからなる複合不織布は潰れやすく、厚みが薄いものしか得られない。特許文献2に記載の技術は、少なくとも2枚の短繊維不織布同士を熱エンボスによって圧着して複合化するものである。特許文献2には短繊維不織布の製造方法に関する詳細の記述はないが、短繊維不織布は、その製造工程で一度、ロール状に巻回され原反とする場合には、巻き回れされる前は嵩高なために、巻き潰れやすい。したがって、2枚の短繊維不織布どうしを熱エンボスによって圧着して複合化したものは厚みが薄く、風合いや柔軟性が十分に得られない。   As a prior art regarding the manufacturing method of the sheet | seat used for the surface material etc. of an absorbent article, the technique of the following patent documents 1 and 2 is proposed, for example. The technology described in Patent Document 1 is a technique in which fiber webs opened by a card machine are overlapped and passed between embossing rolls to form a composite, but the obtained nonwoven fabric has a fiber other than the joining part by the embossing rolls. Since it is not heat-sealed, it becomes fuzzy and is not preferable when used as a surface material for absorbent articles. Moreover, the composite nonwoven fabric which consists of the fiber web opened with the card machine is easy to be crushed, and only a thin one can be obtained. The technique described in Patent Document 2 is a technique in which at least two short fiber nonwoven fabrics are bonded together by hot embossing to be combined. Although there is no detailed description regarding the manufacturing method of a short fiber nonwoven fabric in patent document 2, when a short fiber nonwoven fabric is wound once in the manufacturing process and made into a raw fabric, before being wound, Due to its bulkiness, it tends to collapse. Accordingly, a composite of two short fiber nonwoven fabrics bonded by hot embossing is thin, and the texture and flexibility cannot be sufficiently obtained.

一方、本出願人は、下記特許文献3に記載の技術を提案している。この技術は、ロール状に巻回された不織布原反から不織布を繰り出し、その嵩を回復させるものである。   On the other hand, the present applicant has proposed the technique described in Patent Document 3 below. In this technique, a nonwoven fabric is fed from a nonwoven fabric raw material wound in a roll shape, and its bulk is recovered.

特表平8−504136号公報Japanese National Patent Publication No. 8-504136 特開2005−312601号公報Japanese Patent Laid-Open No. 2005-312601 特開2004−137655号公報JP 2004-137655 A

本発明は、凹凸を有し、嵩高で風合いの良好な複合不織布の製造方法を提供することを目的とする。   An object of this invention is to provide the manufacturing method of a composite nonwoven fabric which has an unevenness | corrugation, and is bulky and favorable in texture.

本発明者らは、上記特許文献3に記載の技術に着目し、特定の不織布に嵩回復処理を施し、別の不織布、特に、嵩の高い不織布と部分的に接合して複合化することで、嵩高で風合いの良好な複合不織布が製造できることを知見し、本発明を完成するに至った。   The present inventors pay attention to the technology described in Patent Document 3 above, and perform bulk recovery treatment on a specific nonwoven fabric, and then partially join with another nonwoven fabric, particularly a bulky nonwoven fabric to form a composite. The present inventors have found that a composite nonwoven fabric that is bulky and has a good texture can be produced, thereby completing the present invention.

本発明は、上記知見に基づきなされたものであり、カード機により開繊した繊維ウェブを原料として製造された不織布をそのロール状に巻回されている原反から繰り出し、加熱して嵩回復処理を行って第1の不織布を製造した後、第1の不織布と、第1の不織布とは別の第2の不織布とを重ね合わせてエンボス加工を施し、これらの不織布を凹凸を付しながら部分的に接合して一体化する複合不織布の製造方法を提供するものである。   The present invention has been made on the basis of the above knowledge, and a nonwoven fabric produced using a fiber web opened by a card machine as a raw material is unwound from a raw material wound in a roll shape, and heated to restore the bulk. To produce a first nonwoven fabric, and then embossing the first nonwoven fabric and a second nonwoven fabric different from the first nonwoven fabric, and making these nonwoven fabrics uneven A method for producing a composite nonwoven fabric that is integrally bonded and integrated.

本発明によれば、凹凸を有し、嵩高で風合いの良好な複合不織布を好適に製造することができる。   According to the present invention, it is possible to suitably manufacture a composite nonwoven fabric having irregularities, bulky and good texture.

以下本発明を、その好ましい実施形態に基づき図面を参照しながら説明する。   The present invention will be described below based on preferred embodiments with reference to the drawings.

図1に示すように、本実施形態の複合不織布の製造方法は、カード機2Aにより開繊した繊維ウェブを原料として製造された不織布10をそのロール状に巻回されている原反100から繰り出し、加熱して嵩回復処理を行って第1の不織布11を製造した後、第1の不織布11と、第1の不織布11とは別の第2の不織布12とを重ね合わせて一対のエンボスロール31、32でエンボス加工を施し、これらの不織布を凹凸を付しながら部分的に接合して一体化し、複合不織布1とするものである。   As shown in FIG. 1, the manufacturing method of the composite nonwoven fabric of this embodiment pays out the nonwoven fabric 10 manufactured using the fiber web opened by the card machine 2A from the raw fabric 100 wound in the roll shape. The first nonwoven fabric 11 and the second nonwoven fabric 12 different from the first nonwoven fabric 11 are superposed on each other after heating and bulk recovery treatment to produce the first nonwoven fabric 11. Embossing is performed at 31 and 32, and these nonwoven fabrics are partially joined and integrated with unevenness to form a composite nonwoven fabric 1.

本実施形態では、不織布10は、カード機2Aによって繊維を開繊した繊維ウェブ110を原料として製造される。カード機により開繊した繊維ウェブを原料として用いることで、該繊維ウェブを不織布化する工程において、嵩高で風合いが良好な不織布が得られる種々の方法を採用できる。この場合、繊維ウェブの繊維長は、100mm以下が好ましく、80mm以下が特に好ましい。繊維ウェブを不織布化する方法は、特に嵩高で風合いが良好な不織布が得られる点からエアスルー方式が好ましい。   In this embodiment, the nonwoven fabric 10 is manufactured using the fiber web 110 which opened the fiber with the card machine 2A as a raw material. By using a fiber web opened by a card machine as a raw material, various methods can be employed in which a nonwoven fabric having a high bulk and good texture can be obtained in the step of forming the fiber web into a nonwoven fabric. In this case, the fiber length of the fiber web is preferably 100 mm or less, and particularly preferably 80 mm or less. As a method for forming a fibrous web into a nonwoven fabric, an air-through method is preferable from the viewpoint of obtaining a nonwoven fabric that is particularly bulky and has a good texture.

不織布10をエアスルー方式によって製造するときの熱処理温度は、不織布10の構成繊維の融点以上、融点+20℃未満であることが、得られる不織布の風合いや生産性の観点から好ましい。不織布10が複合繊維(例えば、芯鞘型やサイドバイサイド型の複合繊維)で構成されている場合は、前記構成繊維の融点には、複合繊維を構成する最も低融点の樹脂の融点が採用される。   The heat treatment temperature when the nonwoven fabric 10 is produced by the air-through method is preferably not less than the melting point of the constituent fibers of the nonwoven fabric 10 and less than the melting point + 20 ° C. from the viewpoint of the texture and productivity of the resulting nonwoven fabric. When the nonwoven fabric 10 is composed of a composite fiber (for example, a core-sheath type or a side-by-side type composite fiber), the melting point of the lowest melting point resin constituting the composite fiber is adopted as the melting point of the constituent fiber. .

不織布10を構成する繊維は、特に制限はないが、嵩高性に優れることから、熱融着性を有する複合繊維であることが好ましい。また、複合繊維は、機械捲縮を発現していると、嵩高性に優れるので好ましい。さらに、前記複合繊維は、熱可塑性樹脂からなる芯鞘型やサイドバイサイド型等の複合繊維であることが嵩高性に優れる不織布を得る上で好ましく、特に偏芯芯鞘構造を有する場合、スパイラル状の立体捲縮を発現するため、より嵩高性に優れるので好ましい。   Although the fiber which comprises the nonwoven fabric 10 does not have a restriction | limiting in particular, Since it is excellent in bulkiness, it is preferable that it is a composite fiber which has heat-fusion property. In addition, it is preferable that the composite fiber is mechanically crimped because it is excellent in bulkiness. Further, the composite fiber is preferably a core-sheath type or side-by-side type composite fiber made of a thermoplastic resin in order to obtain a nonwoven fabric excellent in bulkiness. Since steric crimp is expressed, it is preferable because it is more bulky.

不織布10を構成する熱可塑性樹脂としては、ポリエステル系重合体、ポリアミド系重合体、ポリオレフィン系重合体等が挙げられる。
ポリエステル系重合体としては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリトリメチレンテレフタレート、ポリエチレンナフタレート等及びこれらの共重合体が挙げられ、使用に際しては、これらを単独又は2種以上混合して用いることができる。
ポリアミド系重合体としては、ナイロン6、ナイロン66、ナイロン2、ナイロン3、ナイロン4、ナイロン7、ナイロン11、ナイロン12、ナイロン610、及び共重合体等のポリアミド系重合体が挙げられ、使用に際しては、これらを単独又は2種以上混合して用いることができる。
ポリオレフィン系重合体としては、プロピレン単独重合体、エチレン−プロピレン共重合体、エチレン−ブテン1−プロピレン3元共重合体、高密度ポリエチレン、低密度ポリエチレン、直鎖状低密度ポリエチレン、エチレン−酢酸ビニル共重合体、エチレン−エチルアクリレート共重合体、エチレン−メチルアクリレート共重合体等が挙げられ、使用に際しては、これらを単独又は2種以上混合して用いることができる。
Examples of the thermoplastic resin constituting the nonwoven fabric 10 include polyester polymers, polyamide polymers, polyolefin polymers, and the like.
Examples of the polyester-based polymer include polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, polyethylene naphthalate, and the like, and copolymers thereof. In use, these may be used alone or in combination of two or more. it can.
Examples of polyamide polymers include polyamide polymers such as nylon 6, nylon 66, nylon 2, nylon 3, nylon 4, nylon 7, nylon 11, nylon 12, nylon 610, and copolymers. These can be used alone or in admixture of two or more.
Polyolefin polymers include propylene homopolymer, ethylene-propylene copolymer, ethylene-butene 1-propylene terpolymer, high density polyethylene, low density polyethylene, linear low density polyethylene, ethylene-vinyl acetate. A copolymer, an ethylene-ethyl acrylate copolymer, an ethylene-methyl acrylate copolymer, and the like can be mentioned, and these can be used alone or in combination of two or more.

不織布10を複合繊維で構成する場合には、嵩高性・凹凸構造の保持性の観点から、少なくとも複合繊維を構成する樹脂の一方は、ポリエステル系の単独重合体又はポリオレフィン系の単独重合体を用いることが好ましい。また、嵩回復性に優れる点を考慮すると、複合繊維を構成する樹脂の一方のガラス転移点が室温(10〜30℃程度)以上であることが好ましい。また凹凸複合不織布の形成性や保形成の観点から、複合繊維を構成する2種類の樹脂の融点差を、少なくとも10℃以上、好ましくは30℃以上、より好ましくは60℃以上とすることが好ましい。   When the nonwoven fabric 10 is composed of composite fibers, at least one of the resins constituting the composite fibers uses a polyester-based homopolymer or a polyolefin-based homopolymer from the viewpoint of bulkiness and retention of the uneven structure. It is preferable. Moreover, when the point which is excellent in bulk recovery property is considered, it is preferable that one glass transition point of resin which comprises a composite fiber is room temperature (about 10-30 degreeC) or more. Further, from the viewpoint of the formability and retention of the concavo-convex composite nonwoven fabric, the difference in melting point between the two types of resins constituting the composite fiber is preferably at least 10 ° C or higher, preferably 30 ° C or higher, more preferably 60 ° C or higher. .

次に、ロール状に巻き回されている原反100から繰り出された不織布10を加熱して嵩回復処理を行う。   Next, the nonwoven fabric 10 drawn out from the raw fabric 100 wound in a roll shape is heated to perform a bulk recovery process.

嵩回復処理における不織布10の加熱方法に特に制限はないが、嵩回復を効率的に実施する観点からエアスルー方式が好ましい。ここでエアスルー方式とは、不織布10に熱風を吹き付け、吹き付けた熱風が該不織布10を貫通し、不織布10の嵩を回復させる方式である。不織布10に吹き付ける熱風の温度は、不織布10の構成繊維の融点−(マイナス)50℃以上で且つ該融点未満とすることが得られる不織布の嵩回復性や生産性の点で好ましい。不織布10が複合繊維(例えば、芯鞘型やサイドバイサイド型の複合繊維)で構成されている場合は、前記構成繊維の融点には、複合繊維を構成する最も低融点の樹脂の融点が採用される。   Although there is no restriction | limiting in particular in the heating method of the nonwoven fabric 10 in a bulk recovery process, From a viewpoint of implementing a bulk recovery efficiently, an air through system is preferable. Here, the air-through method is a method in which hot air is blown onto the nonwoven fabric 10 and the blown hot air penetrates the nonwoven fabric 10 to recover the bulk of the nonwoven fabric 10. The temperature of the hot air blown onto the nonwoven fabric 10 is preferable in terms of the bulk recoverability and productivity of the nonwoven fabric obtained by setting the melting point of the constituent fibers of the nonwoven fabric 10 to (minus) 50 ° C. or higher and lower than the melting point. When the nonwoven fabric 10 is composed of a composite fiber (for example, a core-sheath type or a side-by-side type composite fiber), the melting point of the lowest melting point resin constituting the composite fiber is adopted as the melting point of the constituent fiber. .

エアスルー方式で嵩回復処理を行う場合の、熱風の吹き付け面は特に制限はないが、より嵩高な不織布を得る観点から不織布10の製造時の熱風吹き付け面10A側から熱風を吹き付けることが好ましい。   When performing the bulk recovery process by the air-through method, the hot air blowing surface is not particularly limited, but it is preferable to blow hot air from the hot air blowing surface 10A side during the production of the nonwoven fabric 10 from the viewpoint of obtaining a bulkier nonwoven fabric.

嵩回復処理後における第1の不織布11の厚みは、1.0〜10.0mmが好ましく、1.5〜5.0mmがより好ましい。また、第1の不織布の坪量は、5〜60g/m2が好ましく、10〜30g/m2がより好ましい。嵩回復処理後における第1の不織布11の厚みは、嵩回復処理前に比して1.5〜10倍とすることが好ましく、2〜5倍とすることが一層好ましい。 1.0-10.0 mm is preferable and, as for the thickness of the 1st nonwoven fabric 11 after a bulk recovery process, 1.5-5.0 mm is more preferable. Moreover, 5-60 g / m < 2 > is preferable and, as for the basic weight of a 1st nonwoven fabric, 10-30 g / m < 2 > is more preferable. The thickness of the first nonwoven fabric 11 after the bulk recovery process is preferably 1.5 to 10 times, more preferably 2 to 5 times that before the bulk recovery process.

本実施形態においては、図1に示したように、第2の不織布12は、カード機2Bにより開繊した繊維ウェブを原料として製造される。カード機により開繊した繊維ウェブを原料として用いることで、該繊維ウェブを不織布化する工程において、嵩高で風合いが良好な不織布が得られる種々の方法を採用できる。この場合、繊維ウェブの繊維長は、100mm以下が好ましく、80mm以下が特に好ましい。繊維ウェブを不織布化する方法は、特に嵩高で風合いが良好な不織布が得られる点からエアスルー方式が好ましい。   In this embodiment, as shown in FIG. 1, the 2nd nonwoven fabric 12 is manufactured by using the fiber web opened by the card machine 2B as a raw material. By using a fiber web opened by a card machine as a raw material, various methods can be employed in which a nonwoven fabric having a high bulk and good texture can be obtained in the step of forming the fiber web into a nonwoven fabric. In this case, the fiber length of the fiber web is preferably 100 mm or less, and particularly preferably 80 mm or less. As a method for forming a fibrous web into a nonwoven fabric, an air-through method is preferable from the viewpoint of obtaining a nonwoven fabric that is particularly bulky and has a good texture.

第2の不織布12をエアスルー方式によって製造するときの熱処理温度は、第2の不織布12の構成繊維の融点以上、融点+20℃未満であることが、得られる不織布の風合いや生産性の観点から好ましい。第2の不織布12が複合繊維(例えば、芯鞘型やサイドバイサイド型の複合繊維)で構成されている場合は、前記構成繊維の融点には、複合繊維を構成する最も低融点の樹脂の融点が採用される。   The heat treatment temperature when the second nonwoven fabric 12 is produced by the air-through method is preferably not less than the melting point of the constituent fibers of the second nonwoven fabric 12 and less than the melting point + 20 ° C. from the viewpoint of the texture and productivity of the resulting nonwoven fabric. . When the second nonwoven fabric 12 is composed of a composite fiber (for example, core-sheath type or side-by-side type composite fiber), the melting point of the constituent fiber is the melting point of the lowest melting point resin constituting the composite fiber. Adopted.

第2の不織布12を構成する繊維は、特に制限はないが、嵩高性に優れることから、熱融着性を有する複合繊維であることが好ましい。また、複合繊維は、機械捲縮を発現していると、嵩高性に優れるので好ましい。さらに、前記複合繊維は、熱可塑性樹脂からなる芯鞘型やサイドバイサイド型等の複合繊維であることが嵩高性に優れる不織布を得る上で好ましく、特に偏芯芯鞘構造を有する場合、スパイラル状の立体捲縮を発現するため、より嵩高性に優れるので好ましい。   Although the fiber which comprises the 2nd nonwoven fabric 12 does not have a restriction | limiting in particular, Since it is excellent in bulkiness, it is preferable that it is a composite fiber which has heat-fusability. In addition, it is preferable that the composite fiber is mechanically crimped because it is excellent in bulkiness. Further, the composite fiber is preferably a core-sheath type or side-by-side type composite fiber made of a thermoplastic resin in order to obtain a nonwoven fabric excellent in bulkiness. Since steric crimp is expressed, it is preferable because it is more bulky.

前記第2の不織布12を構成する熱可塑性樹脂としては、ポリエステル系重合体、ポリアミド系重合体、ポリオレフィン系重合体等が挙げられる。
ポリエステル系重合体としては、ポリエチレンテレフタレート、ポリブチレンテレフタレート、ポリトリメチレンテレフタレート、ポリエチレンナフタレート等及びこれらの共重合体が挙げられ、使用に際しては、これらを単独又は2種以上混合して用いることができる。
ポリアミド系重合体としては、ナイロン6、ナイロン66、ナイロン2、ナイロン3、ナイロン4、ナイロン7、ナイロン11、ナイロン12、ナイロン610、及び共重合体等のポリアミド系重合体が挙げられ、使用に際しては、これらを単独又は2種以上混合して用いることができる。
ポリオレフィン系重合体としては、プロピレン単独重合体、エチレン−プロピレン共重合体、エチレン−ブテン1−プロピレン3元共重合体、高密度ポリエチレン、低密度ポリエチレン、直鎖状低密度ポリエチレン、エチレン−酢酸ビニル共重合体、エチレン−エチルアクリレート共重合体、エチレン−メチルアクリレート共重合体等が挙げられ、使用に際しては、これらを単独又は2種以上混合して用いることができる。
Examples of the thermoplastic resin constituting the second nonwoven fabric 12 include a polyester polymer, a polyamide polymer, and a polyolefin polymer.
Examples of the polyester-based polymer include polyethylene terephthalate, polybutylene terephthalate, polytrimethylene terephthalate, polyethylene naphthalate, and the like, and copolymers thereof. In use, these may be used alone or in combination of two or more. it can.
Examples of polyamide polymers include polyamide polymers such as nylon 6, nylon 66, nylon 2, nylon 3, nylon 4, nylon 7, nylon 11, nylon 12, nylon 610, and copolymers. These can be used alone or in admixture of two or more.
Polyolefin polymers include propylene homopolymer, ethylene-propylene copolymer, ethylene-butene 1-propylene terpolymer, high density polyethylene, low density polyethylene, linear low density polyethylene, ethylene-vinyl acetate. A copolymer, an ethylene-ethyl acrylate copolymer, an ethylene-methyl acrylate copolymer, and the like can be mentioned, and these can be used alone or in combination of two or more.

第2の不織布12の厚みは、1.0〜10.0mmが好ましく、2.0〜5.0mmがより好ましい。また、第2の不織布12の坪量は、5〜60g/m2が好ましく、10〜30g/m2がより好ましい。 1.0-10.0 mm is preferable and, as for the thickness of the 2nd nonwoven fabric 12, 2.0-5.0 mm is more preferable. Moreover, 5-60 g / m < 2 > is preferable and the basic weight of the 2nd nonwoven fabric 12 has more preferable 10-30 g / m < 2 >.

本実施形態においては、上述のようにして得られた第1の不織布11及び第2の不織布12を重ね合わせる。第1の不織布11と第2の不織布を構成する繊維は同じ材質でもよいし、異なる材質でもよい。   In the present embodiment, the first nonwoven fabric 11 and the second nonwoven fabric 12 obtained as described above are overlapped. The fibers constituting the first nonwoven fabric 11 and the second nonwoven fabric may be the same material or different materials.

本実施形態では、第1の不織布11を反転させ、不織布10の製造時の熱風の吹き付け面10Aと、第2の不織布12の製造時の熱風の吹き付け面12Aとを重ねて接合する。これによって、得られる複合不織布1の表面の風合いをより良好にすることができる。特に、複合不織布1を吸収性物品の表面材として用いる場合には、耐毛羽立ち性能の観点から前述のように製造時の熱風の吹き付け面どうしを重ね合わせる構成が好ましい。   In the present embodiment, the first nonwoven fabric 11 is inverted, and the hot air blowing surface 10 </ b> A at the time of manufacturing the nonwoven fabric 10 and the hot air blowing surface 12 </ b> A at the time of manufacturing the second nonwoven fabric 12 are overlapped and joined. Thereby, the texture of the surface of the composite nonwoven fabric 1 obtained can be made more favorable. In particular, when the composite nonwoven fabric 1 is used as a surface material of an absorbent article, a structure in which hot air blowing surfaces at the time of manufacture are overlapped as described above from the viewpoint of fuzz resistance.

そして、重ね合わされた不織布を、一対のエンボスロール31、32によって挟圧し、部分的に熱融着して接合する。一対のエンボスロール31、32のうち、ロール31は、その周面に多数の凸部が形成された彫刻ロールである。第1の不織布11と第2の不織布12との接合する際に、十分な凹凸構造を発現する観点から、ロール31の高さは、0.5mm以上であることが好ましく、エンボス加工を施す前の第1の不織布11と第2の不織布12の厚みの合計より大きいことがより好ましい。一方、ロール32は、その周面が平滑な平滑ロールである。ここで、エンボス高さとは、エンボスロール31における凸部の法線方向における周面からの高さをいう。   And the laminated nonwoven fabric is pinched by a pair of embossing rolls 31 and 32, and is partially heat-sealed and joined. Of the pair of embossing rolls 31 and 32, the roll 31 is a sculpture roll having a large number of convex portions formed on its peripheral surface. When the first nonwoven fabric 11 and the second nonwoven fabric 12 are joined, the height of the roll 31 is preferably 0.5 mm or more from the viewpoint of expressing a sufficient uneven structure, before embossing. More preferably, the thickness of the first nonwoven fabric 11 and the second nonwoven fabric 12 is greater than the total thickness. On the other hand, the roll 32 is a smooth roll having a smooth peripheral surface. Here, the embossing height refers to the height from the circumferential surface in the normal direction of the convex portion of the embossing roll 31.

各ロール31、32は、それぞれ所定温度に加熱されていてもよく、或いは加熱されていなくてもよい。加熱する場合その温度は、接合部を強固に接着させる観点から、各不織布11、12の構成繊維中の最も融点の低い樹脂の融点近傍であることが好ましい。繊維の種類にもよるが、構成繊維の融点−20℃<エンボスロールの加熱温度<構成繊維の融点+50℃であることが好ましい。   Each roll 31, 32 may be heated to a predetermined temperature, or may not be heated. In the case of heating, the temperature is preferably in the vicinity of the melting point of the resin having the lowest melting point in the constituent fibers of the nonwoven fabrics 11 and 12, from the viewpoint of firmly bonding the joints. Although it depends on the type of fiber, it is preferable that the melting point of the constituent fiber−20 ° C. <the heating temperature of the embossing roll <the melting point of the constituent fiber + 50 ° C.

第1の不織布11と第2の不織布12との接合部13の形態及び配列パターンは、複合不織布の用途に応じて設定することができ、特に制限はないが、図2に示すように、平面視して円形であり千鳥配列パターンで点状に配置されていることが好ましい。接合部13は、1〜20mm、特に3〜10mmのピッチで配置されていることが、複合不織布1の嵩高さ、風合い、強度の観点から好ましい。   The form and arrangement pattern of the joint portion 13 between the first nonwoven fabric 11 and the second nonwoven fabric 12 can be set according to the use of the composite nonwoven fabric, and there is no particular limitation, but as shown in FIG. It is preferably circular in shape and arranged in a dot pattern in a staggered arrangement pattern. It is preferable from the viewpoint of bulkiness, texture, and strength of the composite nonwoven fabric 1 that the joint portions 13 are arranged at a pitch of 1 to 20 mm, particularly 3 to 10 mm.

このようにして得られた凹凸を有する複合不織布1は、嵩高で風合いが良好である。また、上記効果が奏される複合不織布の製造は、製造設備に大幅な改良等が不要であるため、低コストで製造することができる。複合不織布1は、その用途にもよるが、例えば複合不織布1を吸収性物品の表面シートとして用いる場合は、坪量が10g/m2〜120g/m2、特に20g/m2〜60g/m2であることが好ましい。また、複合不織布1の厚みは、これを例えば吸収性物品の表面シートとして用いる場合には1.0〜20mmが好ましく、2.0〜10.0mmがより好ましい。
特に複合不織布全体の柔らかさ・しなやかさ及び表面シートとしての尿や経血等のシートへの低残り性や、すばやく尿や経血を透過させる観点からは、複合不織布は、坪量を10〜40g/m2の低坪量で且つ厚みを2.0〜10.0mmと厚めにすることが好ましい。
The composite nonwoven fabric 1 having irregularities thus obtained is bulky and has a good texture. Moreover, since the manufacturing of the composite nonwoven fabric with the above effects does not require significant improvement in the manufacturing facility, it can be manufactured at low cost. Composite nonwoven fabric 1, depending on the application, for example, when using a composite nonwoven fabric 1 as a surface sheet of an absorbent article has a basis weight of 10g / m 2 ~120g / m 2 , especially 20g / m 2 ~60g / m 2 is preferred. Moreover, when using this as a surface sheet of an absorbent article, for example, 1.0-20 mm is preferable and, as for the thickness of the composite nonwoven fabric 1, 2.0-10.0 mm is more preferable.
In particular, from the viewpoint of softness and flexibility of the entire composite nonwoven fabric and low residual property to the sheet such as urine and menstrual blood as a surface sheet, and from the viewpoint of quickly transmitting urine and menstrual blood, the composite nonwoven fabric has a basis weight of 10 to 10%. It is preferable to have a low basis weight of 40 g / m 2 and a thickness of 2.0 to 10.0 mm.

本実施形態の複合不織布の製造方法は、吸収性物品の製造工程にそのまま適用することができる。この場合、複合不織布1を、そのまま吸収性物品の製造工程に連続的に供給することもできるし、一端原反として巻き取り、原反として供給することもできる。   The manufacturing method of the composite nonwoven fabric of this embodiment is applicable as it is to the manufacturing process of an absorbent article. In this case, the composite nonwoven fabric 1 can be continuously supplied to the manufacturing process of the absorbent article as it is, or it can be wound up as a raw material and supplied as a raw material.

以上説明したように、本実施形態の複合不織布の製造方法によれば、嵩回復処理を行った第1の不織布11と嵩の高い第2の不織布12を部分的に接合することによって、嵩高で風合いの良好な凹凸を有する複合不織布1を簡便・安価に製造することができる。また、本実施形態の複合不織布の製造方法では、各不織布を任意に選択可能であり、多様な不織布を製造可能である。   As described above, according to the method for manufacturing a composite nonwoven fabric of this embodiment, the first nonwoven fabric 11 subjected to the bulk recovery treatment and the bulky second nonwoven fabric 12 are partially joined, thereby being bulky. The composite nonwoven fabric 1 having unevenness with a good texture can be produced easily and inexpensively. Moreover, in the manufacturing method of the composite nonwoven fabric of this embodiment, each nonwoven fabric can be selected arbitrarily and various nonwoven fabrics can be manufactured.

このようにして得られた複合不織布1は、例えば生理用ナプキンやパンティライナー、使い捨てオムツなどの各種吸収性物品の表面シートとして用いると、肌触りが良好で装着感に優れた吸収性物品を得ることができる。   When the composite nonwoven fabric 1 obtained in this way is used as a surface sheet of various absorbent articles such as sanitary napkins, panty liners, and disposable diapers, for example, an absorbent article having a good feel and excellent wearing feeling can be obtained. Can do.

本発明は前記実施形態に制限されない。
本発明は、前記実施形態の複合不織布の製造方法におけるように、第1の不織布11に使用する嵩回復処理前の不織布10は、エアスルー方式により製造された不織布をその原反から繰り出し、加熱して嵩回復した不織布を用いることが好ましいが、カード機により開繊した繊維ウェブを原料として製造されたもので、加熱による嵩回復処理によって、不織布10の嵩が回復するものであれば、ヒートロール法、スパンレース法、ニードルパンチ法、ケミカルボンド法、エアレイド法、メルトブローン法、スパンボンド法等の各種の不織布製造方法で製造された不織布を用いることもできる。
The present invention is not limited to the embodiment.
As in the method for producing a composite nonwoven fabric of the above embodiment, the nonwoven fabric 10 before bulk recovery treatment used for the first nonwoven fabric 11 is a non-woven fabric produced by an air-through method. It is preferable to use a nonwoven fabric that has been recovered in bulk, but if it is manufactured using a fiber web opened by a card machine as a raw material and the bulk of the nonwoven fabric 10 is recovered by a bulk recovery process by heating, a heat roll Nonwoven fabrics manufactured by various nonwoven fabric manufacturing methods such as a method, a spunlace method, a needle punch method, a chemical bond method, an airlaid method, a melt blown method, and a spunbond method can also be used.

また、本発明は、前記実施形態の複合不織布の製造方法におけるように、第2の不織布12に、カード機により開繊した繊維ウェブに熱風をエアスルー方式で吹き付けて製造した不織布を用いることが好ましいが、それ以外の不織布で、カード機により開繊した繊維ウェブをヒートロール方式で熱接着して製造した不織布を用いることもできる。また、図3に示すように、カード機2Bにより開繊した繊維ウェブ110’を原料として製造された不織布10’の原反100’から繰り出し、不織布10’の製造時の熱風吹き付け面10A’側から、前述の第1の不織布と同様に熱風を吹き付けて嵩回復処理を行った不織布を、第2の不織布12として使用することもできる。   In addition, as in the method for manufacturing a composite nonwoven fabric of the above embodiment, the present invention preferably uses a nonwoven fabric manufactured by spraying hot air on a fiber web opened by a card machine by an air-through method. However, the nonwoven fabric manufactured by heat-bonding the fiber web opened with the card machine by the heat roll system with the other nonwoven fabric can also be used. Further, as shown in FIG. 3, the hot air blowing surface 10A ′ side when the nonwoven fabric 10 ′ is manufactured by unwinding from the raw fabric 100 ′ of the nonwoven fabric 10 ′ manufactured using the fiber web 110 ′ opened by the card machine 2B as a raw material. Thus, a nonwoven fabric that has been subjected to bulk recovery treatment by blowing hot air in the same manner as the first nonwoven fabric described above can also be used as the second nonwoven fabric 12.

また、本発明は、前記実施形態のように、嵩回復処理における加熱を、前記不織布に熱風をエアスルー方式で吹き付けて行うことが好ましいが、これに代えて、遠赤外線を照射して加熱を行ったり、ヒートロール等の加熱源に接触させて加熱を行ったりすることもできる。   Further, in the present invention, as in the above embodiment, it is preferable to perform heating in the bulk recovery treatment by blowing hot air to the nonwoven fabric by an air-through method, but instead, heating is performed by irradiating far infrared rays. Or, it can be heated by bringing it into contact with a heating source such as a heat roll.

また、前記実施形態では、第1の不織布11の製造時の熱風の吹き付け面10Aと、第2の不織布の製造時の熱風の吹き付け面12Aどうしを重ねて接合したが、接合面の向きは、これに限られず、用途に応じて任意に選択することができる。第1の不織布における熱風の吹き付け面を外側に向け、第2の不織布の熱風の吹き付け面と接合することもできるし、熱風の吹き付け面の裏面同士を接合面として接合することもできる。   Moreover, in the said embodiment, although the hot-air blowing surface 10A at the time of manufacture of the 1st nonwoven fabric 11 and the hot-air blowing surface 12A at the time of manufacture of the 2nd nonwoven fabric were overlapped and joined, the direction of a joining surface is, It is not restricted to this, It can select arbitrarily according to a use. The hot air blowing surface of the first nonwoven fabric can be directed outward and bonded to the hot air blowing surface of the second nonwoven fabric, or the back surfaces of the hot air blowing surfaces can be bonded to each other as a bonding surface.

以下、実施例により、本発明をさらに具体的に説明する。本発明は、本実施例により何ら制限されない。   Hereinafter, the present invention will be described more specifically with reference to examples. This invention is not restrict | limited at all by this Example.

表1に示す二種類の不織布を使用し、下記実施例1、2及び比較例1〜3のようにして複合不織布を作製した。そして、得られた不織布の厚み、比容積及び風合いを下記のように評価した。それらの結果を表2に示した。   Two types of nonwoven fabrics shown in Table 1 were used, and composite nonwoven fabrics were produced as in Examples 1 and 2 and Comparative Examples 1 to 3 below. And the thickness, specific volume, and texture of the obtained nonwoven fabric were evaluated as follows. The results are shown in Table 2.

Figure 0004749320
Figure 0004749320

〔実施例1〕
以下のようにして、表1に示す不織布を作製した。
<第1の不織布の作製>
表1に示す芯鞘型複合繊維をカード機で開繊した繊維ウェブを原料として、エアスルー方式によって不織布を作製し、ロール状に巻き取って原反を得た。そして、この原反から不織布を繰り出し、表1に示す嵩回復処理を施して第1の不織布とした。
[Example 1]
The nonwoven fabric shown in Table 1 was produced as follows.
<Production of first nonwoven fabric>
Using a fiber web obtained by opening the core-sheath type composite fiber shown in Table 1 with a card machine as a raw material, a nonwoven fabric was produced by an air-through method and wound into a roll to obtain a raw fabric. And the nonwoven fabric was drawn | fed out from this raw fabric, the bulk recovery process shown in Table 1 was given, and it was set as the 1st nonwoven fabric.

<第2の不織布の作製>
表1に示す芯鞘型複合繊維をカード機で開繊した繊維ウェブを原料として、エアスルー方式によって不織布を作製した。
<Production of second nonwoven fabric>
Using a fiber web obtained by opening the core-sheath type composite fiber shown in Table 1 with a card machine, a nonwoven fabric was produced by an air-through method.

<複合不織布の作製>
上述のようにして作製された第1の不織布と第2の不織布とを表2に示す接合面の向きで重ね合わせ、表2に示す温度設定された一対のエンボスロール(エンボス高さ1mm)間に通してエンボス加工を施し、両不織布を凹凸を付しながら部分的に接合して一体化し、図2に示すような複合不織布を得た。
<Production of composite nonwoven fabric>
The first nonwoven fabric and the second nonwoven fabric produced as described above are overlapped in the orientation of the joining surface shown in Table 2, and between the pair of temperature-embossed rolls (emboss height 1 mm) shown in Table 2. The two nonwoven fabrics were partly joined and integrated with unevenness to obtain a composite nonwoven fabric as shown in FIG.

得られた複合不織布の単位面積当たりの接合部の面積率は12.8%であり、各接合部は円形の形状を有し、その配列パターンは図2に示すような千鳥配列であった。   The area ratio of the bonded portion per unit area of the obtained composite nonwoven fabric was 12.8%, each bonded portion had a circular shape, and the arrangement pattern thereof was a staggered arrangement as shown in FIG.

〔厚みの測定〕
得られた複合不織布の厚みは、定圧式厚み計を用いて測定した。そのときの圧力は0.5g/cm2であった。
[Measurement of thickness]
The thickness of the obtained composite nonwoven fabric was measured using a constant pressure type thickness meter. The pressure at that time was 0.5 g / cm 2 .

〔比容積の測定〕
得られた複合不織布の比容積は、前記の厚み測定により得られた厚みと複合不織布の坪量を測定し、下記の算出式によって算出した。
比容積=厚み/坪量
[Measurement of specific volume]
The specific volume of the obtained composite nonwoven fabric was calculated by the following calculation formula by measuring the thickness obtained by the above thickness measurement and the basis weight of the composite nonwoven fabric.
Specific volume = thickness / basis weight

〔風合いの評価〕
得られた複合不織布について、5人のモニターに、柔らかさの程度を評価させた。このとき、以下の評価基準に従い、5人のモニターの平均点を算出した。
柔らかい:+1
どちらともいえない:0
柔らかくない:−1
[Evaluation of texture]
About the obtained composite nonwoven fabric, the degree of softness was evaluated by five monitors. At this time, the average score of five monitors was calculated according to the following evaluation criteria.
Soft: +1
Neither: 0
Not soft: -1

〔実施例2及び比較例1、2〕
表1に示した不織布を使用し、表2に示した接合条件で接合した以外は、実施例1と同様にして、複合不織布を作製し、その厚み・比容積及び風合いを評価した。
[Example 2 and Comparative Examples 1 and 2]
A composite nonwoven fabric was produced in the same manner as in Example 1 except that the nonwoven fabric shown in Table 1 was used and joined under the joining conditions shown in Table 2, and the thickness / specific volume and texture were evaluated.

〔比較例3〕
表1に示したカードウェブを使用し、表2に示した接合条件で接合した以外は、実施例1と同様にして複合不織布作製し、その厚み、比容積及び風合いを評価した。
[Comparative Example 3]
A composite nonwoven fabric was prepared in the same manner as in Example 1 except that the card web shown in Table 1 was used and the joining was performed under the joining conditions shown in Table 2, and the thickness, specific volume and texture were evaluated.

Figure 0004749320
Figure 0004749320

表2に示したように、実施例1、2の複合不織布は、第1の不織布に嵩回復処理を施しているので、比較例1〜3の複合不織布よりも厚みが厚く、比容積が大きいことがわかった。特に、坪量の低い(10g/m2)の不織布同士を用いた実施例1と比較例1の複合不織布においては、嵩回復の効果はより明確になり、複合化する不織布に嵩回復処理を施している実施例1の場合と、嵩回復していない比較例1の場合で、凹凸性に大きな差が生じることが分かった。また、実施例の複合不織布は、比容積が大きいため、柔軟でしなやかなものとなっており、風合いに優れることが分かった。 As shown in Table 2, since the composite nonwoven fabrics of Examples 1 and 2 are subjected to bulk recovery treatment on the first nonwoven fabric, the composite nonwoven fabrics of Comparative Examples 1 to 3 are thicker and have a larger specific volume. I understood it. In particular, in the composite nonwoven fabric of Example 1 and Comparative Example 1 using nonwoven fabrics having a low basis weight (10 g / m 2 ), the effect of bulk recovery becomes clearer, and the composite nonwoven fabric is subjected to bulk recovery treatment. It was found that there was a large difference in unevenness between the case of the applied Example 1 and the case of Comparative Example 1 where the bulk was not recovered. Moreover, since the composite nonwoven fabric of the Example had a large specific volume, it turned out that it was flexible and supple, and was excellent in the texture.

本発明の複合不織布は、前記実施形態のような吸収性物品以外に、使い捨ての着衣等の使い捨ての着用物品を構成する不織布としても用いることができる。   The composite nonwoven fabric of this invention can be used also as a nonwoven fabric which comprises disposable wearing articles, such as disposable clothing other than the absorbent article like the said embodiment.

本発明の複合不織布の製造方法による製造工程の一実施形態を示す模式図である。It is a schematic diagram which shows one Embodiment of the manufacturing process by the manufacturing method of the composite nonwoven fabric of this invention. 本発明の複合不織布の製造方法により製造される複合不織布の一形態を示す模式図であり、(a)は斜視図、(b)は断面図である。It is a schematic diagram which shows one form of the composite nonwoven fabric manufactured by the manufacturing method of the composite nonwoven fabric of this invention, (a) is a perspective view, (b) is sectional drawing. 本発明の複合不織布の製造方法による製造工程の他の実施形態を示す模式図である。It is a schematic diagram which shows other embodiment of the manufacturing process by the manufacturing method of the composite nonwoven fabric of this invention.

符号の説明Explanation of symbols

1 複合不織布
10 不織布
11 第1の不織布
12 第2の不織布
DESCRIPTION OF SYMBOLS 1 Composite nonwoven fabric 10 Nonwoven fabric 11 1st nonwoven fabric 12 2nd nonwoven fabric

Claims (4)

カード機により開繊した繊維ウェブを原料として製造された不織布をそのロール状に巻回されている原反から繰り出し、加熱して嵩回復処理を行って第1の不織布を製造した後、第1の不織布と、第1の不織布とは別の第2の不織布とを重ね合わせてエンボス加工を施し、これらの不織布を凹凸を付しながら部分的に接合して一体化する複合不織布の製造方法。   A non-woven fabric produced using a fiber web opened by a card machine as a raw material is fed out from the raw material wound in the form of a roll, heated to perform a bulk recovery process, and then the first non-woven fabric is produced. A non-woven fabric and a second non-woven fabric that is different from the first non-woven fabric are embossed and embossed, and these non-woven fabrics are partially joined and integrated to form a composite nonwoven fabric. 前記嵩回復処理における加熱を、前記不織布に熱風をエアスルー方式で吹き付けるか又は加熱源で加熱して行う請求項1に記載の複合不織布の製造方法。   The manufacturing method of the composite nonwoven fabric of Claim 1 which heats in the said bulk recovery process by spraying a hot air on the said nonwoven fabric by an air through system, or heating with a heating source. 前記嵩回復処理を行う前の前記不織布をエアスルー方式により製造する請求項1又は2に記載の複合不織布の製造方法。   The manufacturing method of the composite nonwoven fabric of Claim 1 or 2 which manufactures the said nonwoven fabric before performing the said bulk recovery process by an air through system. 第2の不織布を、カード機により開繊した繊維ウェブを用いてエアスルー方式により製造する請求項1〜3の何れかに記載の複合不織布の製造方法。   The manufacturing method of the composite nonwoven fabric in any one of Claims 1-3 which manufactures a 2nd nonwoven fabric by an air through system using the fiber web opened with the card machine.
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