JP4679449B2 - Release sheet - Google Patents

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JP4679449B2
JP4679449B2 JP2006176445A JP2006176445A JP4679449B2 JP 4679449 B2 JP4679449 B2 JP 4679449B2 JP 2006176445 A JP2006176445 A JP 2006176445A JP 2006176445 A JP2006176445 A JP 2006176445A JP 4679449 B2 JP4679449 B2 JP 4679449B2
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sheet
release
release agent
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protective
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JP2008006598A (en
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田 武 志 櫻
田 任 徳 前
崎 昭 彦 柴
邉 良 輔 渡
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Sun A Kaken Co Ltd
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本発明は、離型シートに係り、特に、裏面に転写移行した離型剤を容易に除去することができる離型シートに関する。     The present invention relates to a release sheet, and more particularly to a release sheet that can easily remove a release agent transferred and transferred to a back surface.

従来、基材シートの表面に離型剤層を形成した離型シートを製造する離型シートメーカーにあっては、離型シートをロール状に巻いて工場等を出荷する。
これを利用するラベルメーカーは、ロール状の離型シートを解いて、離型シートの離型剤層に接着剤又は粘着剤を塗布し、シート状部材を貼ってラベルを形成し、ロール状に巻いて、又は、平版状態にカットしてユーザーに提供している。
なお、平版状態にカットする場合にあっては、その製造工程において、ラベルをロール状に巻き、その後、カットするようにしている。
Conventionally, in a release sheet manufacturer that manufactures a release sheet having a release agent layer formed on the surface of a base sheet, the release sheet is wound into a roll and shipped to a factory or the like.
The label maker using this unravels the roll-shaped release sheet, applies an adhesive or a pressure-sensitive adhesive to the release agent layer of the release sheet, forms a label by sticking a sheet-like member, and forms a roll. It is rolled or cut into a lithographic state and provided to the user.
In the case of cutting into a lithographic state, in the manufacturing process, the label is wound in a roll shape and then cut.

ところが、ユーザーがラベルの表面の側に印刷、インクジェット等を施す場合、該表面の一部に印刷、インクジェット等を施すことができない部位が生じるという問題点があった。
これは、先ず第一に、離型シートメーカーが、離型シートをロール状に巻いた状態で、出荷するため、離型シートの裏面に、離型シートの表面の離型剤層の離型剤の一部が離型シートの裏面に転写移行すること、
次に、離型シートの表面である離型剤層にシート状部材を貼ってラベルを形成するラベルメーカーにあっては、上記した離型シートメーカーの「裏面に離型剤の一部が転写移行した離型シート」を使用してラベルをロール状に巻くため、ラベルの離型シートの裏面に転写移行した離型剤がラベルの表面に再度転写移行し、その結果、ユーザーが印刷、インクジェット等を施すことができないことによることが判明した。
However, when the user performs printing, inkjet, or the like on the surface side of the label, there is a problem in that a portion where printing, inkjet, or the like cannot be performed on a part of the surface occurs.
This is because, first of all, the release sheet maker rolls the release sheet in a roll shape and ships it, so that the release agent layer on the surface of the release sheet is released on the back surface of the release sheet. Transfer of a part of the agent to the back side of the release sheet,
Next, in a label maker that forms a label by attaching a sheet-like member to the release agent layer that is the surface of the release sheet, a part of the release agent is transferred to the back surface of the release sheet manufacturer. Since the label is rolled into a roll shape using the `` transferred release sheet '', the release agent transferred and transferred to the back side of the release sheet of the label is transferred and transferred again to the surface of the label. It became clear that it was not possible to apply etc.

本発明は、上記の問題点を除去するようにした離型シートを提供することを目的とする。     An object of this invention is to provide the release sheet which removed the said problem.

上記目的を達成するために、本発明の離型シートは、基材シートと、この基材シートの表面に形成された離型剤層と、前記基材シートの裏面に、弱い接着力で接着された保護シートとを備え、前記基材シートと前記保護シートとの接着力は手で剥離できる程度のものである。     In order to achieve the above object, the release sheet of the present invention is bonded to the base sheet, the release agent layer formed on the surface of the base sheet, and the back surface of the base sheet with a weak adhesive force. The adhesive strength between the base sheet and the protective sheet is such that it can be peeled off by hand.

また、請求項2記載の離型シートは、請求項1記載の離型シートにおいて、基材シートは、紙、PEラミネート紙、PPラミネート紙、プラスチックフィルム、不織布の内のいずれかであり、保護シートは、紙、PEラミネート紙、PPラミネート紙、プラスチックフィルム、不織布の内のいずれかであり、前記保護シートは、前記基材シートの裏面に、樹脂層を介して貼り合わせたものである。     The release sheet according to claim 2 is the release sheet according to claim 1, wherein the base sheet is one of paper, PE laminate paper, PP laminate paper, plastic film, and non-woven fabric. The sheet is one of paper, PE laminated paper, PP laminated paper, plastic film, and non-woven fabric, and the protective sheet is bonded to the back surface of the base sheet via a resin layer.

また、請求項3記載の離型シートは、請求項1又は2記載の離型シートにおいて、離型シートは、ロール状に巻かれているものである。     The release sheet according to claim 3 is the release sheet according to claim 1 or 2, wherein the release sheet is wound in a roll shape.

請求項1記載の離型シートによれば、離型シートをロール状に巻いても、基材シートの表面の離型剤層の離型剤は裏面の保護シートに転写移行するが、離型シートの表面である離型剤層に接着剤又は粘着剤を介してシート状部材を貼って、ラベルを形成した後、又は、ラベルを形成する前、保護シートを基材シートから剥がして、離型シートの裏面に転写移行した離型剤を除去することができる。
その結果、保護シートを除去してラベルをロール状に巻いても、ラベルの表面に、離型剤が再度転写移行することを防止でき、ラベルの表面に、印刷、インクジェット等を施すことができる。
According to the release sheet of claim 1, even if the release sheet is rolled up, the release agent of the release agent layer on the surface of the base sheet is transferred to the protective sheet on the back surface. After forming a label by sticking a sheet-like member to the release agent layer, which is the surface of the sheet, via an adhesive or pressure-sensitive adhesive, or before forming the label, the protective sheet is peeled off from the base material sheet and released. The release agent transferred and transferred to the back surface of the mold sheet can be removed.
As a result, even if the protective sheet is removed and the label is wound in a roll shape, the release agent can be prevented from being transferred again to the surface of the label, and printing, ink jet, or the like can be performed on the surface of the label. .

本発明の一実施例を図面を参照して説明する。
(実施例1)
図1において、Sは離型シートで、離型シートSは、例えば、ロール状に巻かれて、ラベル貼着用離型シートである。離型シートSは、図2及び図3に示すように、基材シート1と、この基材シート1の表面に形成された離型剤層2と、基材シート1の裏面に、弱い接着力で接着された保護シート3とから構成されている。
An embodiment of the present invention will be described with reference to the drawings.
Example 1
In FIG. 1, S is a release sheet, and the release sheet S is, for example, a release sheet that is wound in a roll and is attached to a label. 2 and 3, the release sheet S is weakly bonded to the base sheet 1, the release agent layer 2 formed on the surface of the base sheet 1, and the back surface of the base sheet 1. The protective sheet 3 is adhered by force.

基材シート1は、例えば、紙、PEラミネート紙、PPラミネート紙、プラスチックフィルム(PET、LDPE、HDPE、LLDPE、EVA、CPP、OPP、ONy)、不織布等で、厚みは、10μ〜130μ程度である。
離型剤層2は、例えば、シリコーン系離型剤、フッ素系離型剤、変性シリコーン系離型剤で、厚みは、2μ以下、望ましくは、1μ以下である。
保護シート3は、例えば、紙、PEラミネート紙、PPラミネート紙、プラスチックフィルム(PET、LDPE、HDPE、LLDPE、EVA、CPP、OPP、ONy)、不織布等で、厚みは、10μ〜50μ程度である。
この保護シート3と基材シート1の裏面とは、弱い接着力で接着されている。弱い接着力とは、基材シート1と保護シート3との接着力が手で剥離できる程度であり、接着力を剥離力で言えば、JIS−Z0237に準じ、剥離速度0.3mm/min、剥離角度180°、測定巾25mmの測定法で、剥離強度が0.1〜5.0N/25mm程度である。
具体的には、保護シート3と基材シート1との間に、樹脂[例えば、LDPE、LLDPE、HDPE、MLLDPE、PP、EVA、IO、EAA、EMAA、EEA、ポリアミド樹脂、ポリエステル樹脂(PET ポリエチレンテレフタレート)]を溶融押し出しによりラミネート(サンドラミネート)して、保護シート3と基材シート1との間に、接着剤層(樹脂層)4を形成している。
かかる場合、接着剤層(樹脂層)4は基材シート1の裏面とは強固に接着するが、保護シート3とは、接着が弱いため、基材シート1の裏面から保護シート3を容易に手で剥がすことができる。
The base sheet 1 is, for example, paper, PE laminated paper, PP laminated paper, plastic film (PET, LDPE, HDPE, LLDPE, EVA, CPP, OPP, ONy), non-woven fabric, etc., and the thickness is about 10 μm to 130 μm. is there.
The release agent layer 2 is, for example, a silicone release agent, a fluorine release agent, or a modified silicone release agent, and has a thickness of 2 μm or less, preferably 1 μm or less.
The protective sheet 3 is, for example, paper, PE-laminated paper, PP-laminated paper, plastic film (PET, LDPE, HDPE, LLDPE, EVA, CPP, OPP, ONy), non-woven fabric, etc., and the thickness is about 10 to 50 μm. .
The protective sheet 3 and the back surface of the base sheet 1 are bonded with a weak adhesive force. The weak adhesive strength is such that the adhesive strength between the base sheet 1 and the protective sheet 3 can be peeled by hand. In terms of the adhesive strength, the peeling speed is 0.3 mm / min according to JIS-Z0237, The peel strength is about 0.1 to 5.0 N / 25 mm by a measurement method with a peel angle of 180 ° and a measurement width of 25 mm.
Specifically, a resin [for example, LDPE, LLDPE, HDPE, MLLDPE, PP, EVA, IO, EAA, EMAA, EEA, polyamide resin, polyester resin (PET polyethylene) is formed between the protective sheet 3 and the base sheet 1. Terephthalate)] is laminated (sand lamination) by melt extrusion to form an adhesive layer (resin layer) 4 between the protective sheet 3 and the base sheet 1.
In such a case, the adhesive layer (resin layer) 4 adheres firmly to the back surface of the base sheet 1, but since the adhesion to the protective sheet 3 is weak, the protective sheet 3 can be easily removed from the back surface of the base sheet 1. Can be peeled off by hand.

従って、離型シートメーカーは、上述した図3記載の離型シートSを、図1記載のように、ロール状に巻いて出荷して、基材シート1の表面の離型剤層2の離型剤は裏面の保護シート3に転写移行するが、これを利用するラベルメーカーは、ロール状の離型シートSを解いて、離型剤層2に粘着剤又は接着剤を塗布し、シート状部材(図示せず)を貼ってラベル(図示せず)を形成し、その後、(又は、ラベルを形成する前)、離型剤の一部が転写移行した保護シート3を基材シート1から剥がして、離型シートSの裏面に転写移行した離型剤を除去することができる。
そのため、ラベルメーカーが、離型剤の一部が転写移行した保護シート3を除去して、ラベル(図示せず)をロール状に巻いても、ラベル(図示せず)の表面に、離型剤が再度転写移行することを防止でき、これを利用するユーザーは、ラベル(図示せず)の表面に、印刷、インクジェット等を施すことができる。
Therefore, the release sheet manufacturer ships the release sheet S shown in FIG. 3 in the form of a roll as shown in FIG. 1 and releases the release agent layer 2 on the surface of the base sheet 1. The mold is transferred and transferred to the protective sheet 3 on the back side, but the label maker using this unrolls the roll-shaped release sheet S, applies a pressure-sensitive adhesive or an adhesive to the release agent layer 2, and forms a sheet. A member (not shown) is pasted to form a label (not shown), and then (or before the label is formed), the protective sheet 3 to which a part of the release agent is transferred is transferred from the base sheet 1. The release agent that has been peeled off and transferred to the back surface of the release sheet S can be removed.
Therefore, even if the label maker removes the protective sheet 3 from which a part of the release agent has been transferred and rolls the label (not shown) in a roll shape, the release is applied to the surface of the label (not shown). It is possible to prevent the agent from transferring and transferring again, and a user who uses the agent can perform printing, inkjet, or the like on the surface of a label (not shown).

(実施例2)
なお、上述した実施例においては、基材シート1の裏面と保護シート3との間に、樹脂層4を介在させ、保護シート3を基材シート1の裏面から剥がす際、接着剤層(樹脂層)4を基材シート1の裏面に残したが、本発明にあっては、これに限らず、保護シート3と基材シート1との接着力は弱い(接着力が弱い点は実施例1と同じ)ため、手で剥がす際、接着剤層(樹脂層)5を保護シート3の側に残すようにしても良い(図4参照)。
即ち、保護シート3の基材シート1に対向する面に、接着剤、例えば、溶剤系接着剤を塗布、乾燥させた後、保護シート3の接着面を基材シート1の裏面側に合わせる。つまり、保護シート3と基材シート1の裏面側をドライラミネート加工により接着層5を介して貼り合わせる。
その際、保護シート3の基材シート1に面する側には、接着剤を塗布する前に、予め、コロナ処理を施して接着剤との接着強度を増すようにするが、基材シート1の保護シート3に面する側には、接着剤との接着強度を増さないように、コロナ処理を施さないようにしている。
次に、基材シート1の表面にシリコーン系離型剤、フッ素系離型剤、変性シリコーン系離型剤を塗布し、離型剤層2を形成し、ロール状に巻き取る。
(Example 2)
In addition, in the Example mentioned above, when the resin layer 4 is interposed between the back surface of the base material sheet 1 and the protective sheet 3, and the protective sheet 3 is peeled from the back surface of the base material sheet 1, an adhesive layer (resin Layer) 4 is left on the back surface of the base sheet 1, but in the present invention, the adhesive force between the protective sheet 3 and the base sheet 1 is weak (not limited to this example). Therefore, the adhesive layer (resin layer) 5 may be left on the protective sheet 3 side when peeling by hand (see FIG. 4).
That is, an adhesive, for example, a solvent-based adhesive, is applied to the surface of the protective sheet 3 facing the base sheet 1 and dried, and then the adhesive surface of the protective sheet 3 is matched with the back side of the base sheet 1. That is, the protective sheet 3 and the back surface side of the base sheet 1 are bonded together via the adhesive layer 5 by dry lamination.
At that time, on the side of the protective sheet 3 facing the base sheet 1, before applying the adhesive, a corona treatment is applied in advance to increase the adhesive strength with the adhesive. The side facing the protective sheet 3 is not subjected to corona treatment so as not to increase the adhesive strength with the adhesive.
Next, a silicone release agent, a fluorine release agent, and a modified silicone release agent are applied to the surface of the substrate sheet 1 to form a release agent layer 2 and wound into a roll.

(実施例3)
また、次の実施例においては、保護シート3の基材シート1に対向する面に、粘着剤、例えば、再剥離性の粘着剤を塗布し、保護シート3の接着面を基材シート1の裏面側に合わせ、再剥離性の粘着剤層6を介して保護シート3を基材シート1に貼り合わせている(図5参照)。
次に、基材シート1の表面にシリコーン系離型剤、フッ素系離型剤、変性シリコーン系離型剤を塗布し、離型剤層2を形成し、ロール状に巻き取る。
保護シート3と基材シート1との接着力は弱い(接着力が弱い点は実施例1と同じ)ため、手で剥がす際、特に、再剥離性粘着剤層6を保護シート3の側に残して、つまり、基材シート1の裏面と再剥離性粘着剤層6との境界面にて剥離するようになっている。
なお、再剥離粘着剤6としては、合成ゴム系、アクリル樹脂系、シリコン樹脂系等がある。前記合成ゴム系としては、ポリイソブチレンゴム、イソプレンゴム等がある。また、アクリル樹脂系には、アクリル酸、アクリル酸エチル、アクリル酸メチル等がある。シリコン樹脂系には、ジメチルポリシロキサン等である。
(Example 3)
In the following embodiment, a pressure sensitive adhesive, for example, a releasable pressure sensitive adhesive, is applied to the surface of the protective sheet 3 facing the base material sheet 1, and the adhesive surface of the protective sheet 3 is applied to the surface of the base material sheet 1. The protective sheet 3 is bonded to the base sheet 1 via the releasable pressure-sensitive adhesive layer 6 in accordance with the back side (see FIG. 5).
Next, a silicone release agent, a fluorine release agent, and a modified silicone release agent are applied to the surface of the substrate sheet 1 to form a release agent layer 2 and wound into a roll.
Since the adhesive strength between the protective sheet 3 and the base sheet 1 is weak (the adhesive strength is the same as in Example 1), the peelable pressure-sensitive adhesive layer 6 is particularly on the protective sheet 3 side when peeling by hand. It leaves and peels in the boundary surface of the back surface of the base material sheet 1, and the releasable adhesive layer 6 left.
The re-peeling adhesive 6 includes a synthetic rubber type, an acrylic resin type, a silicon resin type, and the like. Examples of the synthetic rubber include polyisobutylene rubber and isoprene rubber. Examples of the acrylic resin system include acrylic acid, ethyl acrylate, and methyl acrylate. Examples of silicon resin include dimethylpolysiloxane.

図1は、本発明の一実施例の離型シートがロール状に巻かれた状態の概略的側面図である。FIG. 1 is a schematic side view of a state in which a release sheet according to an embodiment of the present invention is wound in a roll shape. 図2は、図1の離型シートから一部を引き出した状態の概略的側面図である。FIG. 2 is a schematic side view of a state in which a part is pulled out from the release sheet of FIG. 図3は、図2の3−3線による概略的断面図である。3 is a schematic cross-sectional view taken along line 3-3 of FIG. 図4は、図3の実施例と異なる他の実施例の離型シートの概略的断面図である。FIG. 4 is a schematic cross-sectional view of a release sheet of another embodiment different from the embodiment of FIG. 図5は、図4の実施例と異なる他の実施例の離型シートの概略的断面図である。FIG. 5 is a schematic cross-sectional view of a release sheet of another embodiment different from the embodiment of FIG.

符号の説明Explanation of symbols

S 離型シート
1 基材シート
2 離型剤層
3 保護シート
S release sheet 1 base sheet 2 release agent layer 3 protective sheet

Claims (3)

基材シートと、
この基材シートの表面に形成された離型剤層と、
前記基材シートの裏面に、弱い接着力で接着された保護シートとを備え、前記基材シートと前記保護シートとの接着力は手で剥離できる程度のものであることを特徴とする離型シート。
A base sheet;
A release agent layer formed on the surface of the base sheet,
A release sheet comprising a protective sheet adhered to the back surface of the base sheet with a weak adhesive force, and the adhesive force between the base sheet and the protective sheet is such that it can be peeled by hand. Sheet.
基材シートは、紙、PEラミネート紙、PPラミネート紙、プラスチックフィルム、不織布の内のいずれかであり、
保護シートは、紙、PEラミネート紙、PPラミネート紙、プラスチックフィルム、不織布の内のいずれかであり、
前記保護シートは、前記基材シートの裏面に、樹脂層を介して貼り合わせたことを特徴とする請求項1記載の離型シート。
The base sheet is one of paper, PE laminated paper, PP laminated paper, plastic film, and non-woven fabric,
The protective sheet is one of paper, PE laminated paper, PP laminated paper, plastic film, non-woven fabric,
The release sheet according to claim 1, wherein the protective sheet is bonded to the back surface of the base sheet via a resin layer.
離型シートは、ロール状に巻かれていることを特徴とする請求項1又は2記載の離型シート。     The release sheet according to claim 1 or 2, wherein the release sheet is wound in a roll shape.
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Citations (3)

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Publication number Priority date Publication date Assignee Title
JP2002038111A (en) * 2000-04-28 2002-02-06 Lintec Corp Adhesive sheet and adhesive body
JP2003003132A (en) * 2001-06-19 2003-01-08 Lintec Corp Adhesive sheet and pasting material
JP2004306452A (en) * 2003-04-08 2004-11-04 Mitsubishi Polyester Film Copp Release film

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11300896A (en) * 1998-04-24 1999-11-02 Toyo Metallizing Co Ltd Release film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002038111A (en) * 2000-04-28 2002-02-06 Lintec Corp Adhesive sheet and adhesive body
JP2003003132A (en) * 2001-06-19 2003-01-08 Lintec Corp Adhesive sheet and pasting material
JP2004306452A (en) * 2003-04-08 2004-11-04 Mitsubishi Polyester Film Copp Release film

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