JP4627562B2 - Manufacturing method for cosmetics - Google Patents

Description

  The present invention relates to a method for producing a cosmetic, and in particular, for example, after a cosmetic liquid is filled in a cup-shaped container, the opening of the container is sealed with a lid material, and the portion that becomes the lid is cut to obtain the cosmetic liquid. The present invention relates to a method for producing a filled cosmetic.

Conventionally, many cosmetics that do not use preservatives (parapens, etc.) have been marketed as "parapen-free", but since they are not aseptically filled, other additives that actually have a preservative effect comparable to that of parapenes. In many cases, products such as phenoxyethanol are added.
In general, cosmetic products often contain chemical synthetic products that cannot be eaten in order to improve stability in addition to preservatives.

JP 2006-188441 A

Cosmetics stipulated by the Pharmaceutical Affairs Law are “similar to, rubbed or sprayed on the body to cleanse, beautify, enhance appeal, change appearance, or keep skin or hair healthy” It is defined as “thing that is intended to be used in a method and has a mild effect on the human body”, but must not deviate from it.
Therefore, effective raw materials are added, but when they are made into aqueous solutions, they are spoiled by microorganisms and are difficult to store for a long time.
It is possible to use preservatives, but it may affect the human body.
Therefore, a main object of the present invention is to provide a safe cosmetic production method that uses only raw materials that are expected to be useful and effective for the human body and does not use preservatives.

The cosmetic manufacturing method according to claim 1 of the present invention is configured as follows.
(1) sterilizing plastic container molding material;
(2) In a sterile environment, a container molding material suitable for filling heated cosmetic liquid is softened by heating to a temperature of 125 ° C. or higher, and the softened container molding material is compressed and molded by blowing sterile air. Forming an accommodation recess having a capacity sufficient to fill a single use amount of the cosmetic liquid ;
(3) Aseptically filling a cosmetic liquid that does not contain the following liquid preservative , which is heated and sterilized and maintained in a sterile state, in a continuously formed housing recess in an aseptic environment;
The cosmetic liquid does not contain a preservative and is prepared by mixing the following (1) collagen peptide and (2) platinum nanocolloid in water.
(1) 10% to 50% by weight of collagen peptide
(2) Platinum nanocolloid 0.035 wt% to 0.285 wt%
(3) remaining amount of water (4) in a sterile environment, sealing the lid held in a sterile state around the opening of the small container to close the opening of the small container;
(5) including a step of separating each of the small containers filled with the cosmetic liquid together with the periphery of the housing recess and the lid.
Manufacturing method for cosmetics.
The cosmetic manufacturing method according to claim 2 of the present invention is configured as follows.
(1) sterilizing plastic container molding material;
(2) In a sterile environment, a container molding material suitable for filling heated cosmetic liquid is softened by heating to a temperature of 125 ° C. or higher, and the softened container molding material is compressed and molded by blowing sterile air. Forming an accommodation recess having a capacity sufficient to fill a single use amount of the cosmetic liquid ;
(3) Aseptically filling a cosmetic liquid that does not contain the following liquid preservative , which is heated and sterilized and maintained in a sterile state, in a continuously formed housing recess in an aseptic environment;
The cosmetic liquid is a hair care liquid, does not contain a preservative, and is a hair care liquid obtained by mixing the following (1) water-soluble keratin and (2) platinum nanocolloid in water. The cosmetics described.
(1) 1.5% to 5.8% by weight of water-soluble keratin
(2) Platinum nanocolloid 0.035 wt% to 0.315 wt%
(3) remaining amount of water (4) in a sterile environment, sealing the lid held in a sterile state around the opening of the small container to close the opening of the small container;
(5) including a step of separating each of the small containers filled with the cosmetic liquid together with the periphery of the housing recess and the lid.
Manufacturing method for cosmetics.
In the cosmetic manufacturing method according to claim 3 of the present invention, the step of sterilizing the container molding material includes sterilizing the surface of the container molding material by immersing the container molding material in a hydrogen peroxide tank and sterilizing the sterilized container molding material. It is a manufacturing method of the cosmetics of Claim 1 or Claim 2, including removing the hydrogen peroxide of the surface of a container molding material by spraying the air which was performed with the air knife.
The cosmetic manufacturing method according to claim 4 of the present invention is the cosmetic manufacturing method according to any one of claims 1 to 3, wherein the container molding material is a sheet of polyethylene terephthalate.
According to claim 5 of the present invention, in the cosmetic manufacturing method, after the small container is filled with the cosmetic liquid, the sterilized air is supplied into the housing recess and sealed to maintain the positive pressure. A cosmetic production method according to any one of claims 1 to 4.

Since the cosmetic manufacturing method according to the invention of claim 1 is configured as follows, a safe cosmetic that does not use a preservative is formed only from raw materials that are expected to be useful and effective for the human body. Can be manufactured.
(1) sterilizing plastic container molding material;
(2) In a sterile environment, a container molding material suitable for filling heated cosmetic liquid is softened by heating to a temperature of 125 ° C. or higher, and the softened container molding material is compressed and molded by blowing sterile air. Forming an accommodation recess having a capacity sufficient to fill a single use amount of the cosmetic liquid ;
(3) Aseptically filling a cosmetic liquid that does not contain the following liquid preservative , which is heated and sterilized and maintained in a sterile state, in a continuously formed housing recess in an aseptic environment;
The cosmetic liquid does not contain a preservative and is prepared by mixing the following (1) collagen peptide and (2) platinum nanocolloid in water.
(1) 10% to 50% by weight of collagen peptide
(2) Platinum nanocolloid 0.035 wt% to 0.285 wt%
(3) remaining amount of water (4) in a sterile environment, sealing the lid held in a sterile state around the opening of the small container to close the opening of the small container;
(5) including a step of separating each of the small containers filled with the cosmetic liquid together with the periphery of the housing recess and the lid.
Manufacturing method for cosmetics.
According to invention of Claim 2, since it is comprised as follows, it can comprise only the raw material with which the effect and effect useful for a human body are anticipated, and the safe cosmetics which do not use a preservative can be manufactured.
(1) sterilizing plastic container molding material;
(2) In a sterile environment, a container molding material suitable for filling heated cosmetic liquid is softened by heating to a temperature of 125 ° C. or higher, and the softened container molding material is compressed and molded by blowing sterile air. Forming an accommodation recess having a capacity sufficient to fill a single use amount of the cosmetic liquid ;
(3) Aseptically filling a cosmetic liquid that does not contain the following liquid preservative , which is heated and sterilized and maintained in a sterile state, in a continuously formed housing recess in an aseptic environment;
The cosmetic liquid is a hair care liquid, does not contain a preservative, and is a hair care liquid obtained by mixing the following (1) water-soluble keratin and (2) platinum nanocolloid in water. The cosmetics described.
(1) 1.5% to 5.8% by weight of water-soluble keratin
(2) Platinum nanocolloid 0.035 wt% to 0.315 wt%
(3) remaining amount of water (4) in a sterile environment, sealing the lid held in a sterile state around the opening of the small container to close the opening of the small container;
(5) including a step of separating each of the small containers filled with the cosmetic liquid together with the periphery of the housing recess and the lid.
Manufacturing method for cosmetics.
According to the invention of claim 3, the step of sterilizing the container molding material includes immersing the container molding material in a hydrogen peroxide tank to sterilize the surface and sterilizing the sterilized container molding material with air. Since it includes removing hydrogen peroxide from the surface of the container molding material by spraying with a knife, it is possible to manufacture safe cosmetics that do not use preservatives by using only raw materials that are expected to have useful effects on the human body. .
According to invention of Claim 4, since a container molding material consists of a sheet-like thing of polyethylene terephthalate, water vapor permeability and oxygen permeability are low, it prevents moisture and suppresses oxidation of cosmetics.
According to the invention of claim 5, since the small container is filled with the cosmetic liquid and then supplied with sterile air into the housing recess and sealed to maintain a positive pressure, the small container is maintained in a sterile state. And can make cosmetics.

  The above-described object, other objects, features, and advantages of the present invention will become more apparent from the following description of embodiments for carrying out the invention with reference to the drawings.

It is a perspective view solution figure of the hair care product with which the portion pack which is one embodiment of this invention was filled. It is a top view solution figure of the hair care product with which the portion pack which is one embodiment of this invention was filled. It is a longitudinal cross-section solution figure of the hair care product with which the portion pack which is one embodiment of this invention was filled. It is the photograph (1) which shows the state after the permanent when the example is used for the permanent agent and when it is not used. It is the photograph (2) which shows the state after the color when the example is used for the color agent and when it is not used. It is a photograph (3) which shows the hair verification result by an electron microscope. It is the photograph (4) which shows the state after the permanent when the example is used for the permanent agent and when it is not used. It is the photograph (5) which shows the state after the color when the example is used for the color agent and when it is not used. It is a photograph (6) which shows the hair verification result by an electron microscope. It is a front view solution figure which shows the whole structure of the filling sealing apparatus which concerns on one embodiment of this invention. It is a front view solution figure of the container molding material supply mechanism. It is a front view solution figure of the 1st sterilization mechanism 118. FIG. It is a perspective view solution figure of the 1st sterilization mechanism 118. FIG. It is a front view solution figure of the container shaping | molding mechanism 114 and the lid | cover material supply mechanism 122. FIG. It is a perspective view solution figure of a container shaping | molding mechanism. It is a front view solution figure of the lid | cover material supply mechanism 122. FIG. 3 is a perspective view illustrating a state in which a lid member 102 is bonded to a container molding material 100. FIG. It is a front view solution figure which shows a conveyance means and a winding-up means.

The cosmetic product according to the present invention is a preservative that is made of a plastic having a low permeability of oxygen and / or water vapor and is kept in a sterilized state in a small container having a capacity sufficient to fill a single use amount. A liquid cosmetic liquid containing no sterilization is aseptically filled in a single use amount, and the opening of the small container is sealed by sealing the cover held in a sterile state around the opening of the small container. ing.
The small container includes a container main body having an opening at the upper end of the body part and filled with a cosmetic liquid in a housing recess of the body part, and a collar extending outward from the upper end of the body part of the container body. In order to close the opening, the lid is heat-sealed with a lid material, so it is composed only of raw materials that are expected to be useful and effective for the human body, and safe without preservatives. Can provide cosmetics.

The small container 10 includes a cup-shaped container body 12 having an opening 12a at its upper end.
The body portion 16 of the container body 12 is formed to extend upward from the edge portion 14 c of the bottom 14. In order to increase the mechanical strength of the body portion 16, a portion extending from the central portion to the lower portion may be formed in a pleated shape.
A flange portion 18 is formed extending outward from the upper end of the body portion 16. This collar part 18 is for attaching the lid | cover 22 mentioned later there.
Further, a knob portion 20 is formed extending outward from one end of the collar portion 18. In addition, the lid 22 is formed so that the flange portion 18 and the lid portion 22 are welded and the upper surface of the opening 12a of the container body 12 is closed. A stepped portion 24 is formed from the center to the tip of the knob portion 20 so that the lid 22 can be easily separated from the collar portion 18.
The container body 12 is made of a weldable container molding material such as a synthetic resin such as polyethylene terephthalate such as A-PET (amorphous polyethylene terephthalate), for example, pressure molding (with plug assist), vacuum It is formed by molding by a molding method such as molding.
The container molding material has a water vapor permeability of 45 cc / m 2 · 24 hr / atm and an oxygen permeability of 43 cc / m 2 · 24 hr / atm.
The container molding material of this embodiment has low water vapor permeability and oxygen permeability, prevents moisture and is difficult to oxidize.
The thermal shrinkage is 4 to 5/1000, the proper molding temperature is 120 to 130 ° C., the softening temperature (glass transition point) is 70 to 81 ° C., and the thermal conductivity (J / m · s · cc) is 0.29. It is.

  Further, a lid 22 having the same shape as that of the flange portion 18 and the knob portion 20 is attached to the surfaces of the flange portion 18 and the knob portion 20 in plan view. The lid 22 is formed, for example, in a four-layer structure, and the upper layer is formed of a material that easily conducts heat, such as polyethylene terephthalate and then aluminum, and the lower layer is a synthetic resin such as polyethylene terephthalate and then polyethylene. For example, it is bonded to the collar portion 18 with an ethylene vinyl acetate (EVA) adhesive.

(Embodiment)
The hair care liquid 50 according to the present invention has the following configuration.
The following (1) collagen peptide and (2) platinum nanocolloid are mixed in water.
(1) 10% to 50% by weight of collagen peptide
(2) Platinum nanocolloid 0.035 wt% to 0.285 wt%
(3) Water remaining

  If the platinum nanocolloid is less than 0.035% by weight, the action of suppressing the oxidation, which is the action of platinum, is extremely reduced, and if it exceeds 0.285% by weight, the effect is not further increased.

Collagen peptides and platinum are the grades used in cosmetics.
Collagen peptides moisturize and nourish hair, and have a function to make a cuticle that is a protective function of hair firmly.
Platinum (Platinum) is a nano-sized platinum nano colloid that is made into ultrafine particles (3 parts per billion). It has an anti-oxidation effect and functions to suppress hair oxidation by permanents and colors. Can be sufficiently penetrated.
Since it is a liquid, it dissolves easily in permanent liquids (which give curls, suppleness, and firmness to the hair) or color liquids (which color the hair).
Aseptic filling portion pack packaging does not use preservatives, there is no risk of spoilage even with liquids, and it is hygienic for a long time before opening.

The hair care liquid 50 according to the present invention particularly relates to an additive added to a permanent liquid used for, for example, a cold permanent and an iron permanent.
The background art relating to the hair care liquid according to the present invention will be described. Conventionally, a powdered collagen peptide is used by dissolving it in a perm liquid or a color liquid in order to give the hair “gloss”, “moisture”, and “moist feeling” (Japanese Patent Application Laid-Open No. 2005-318867). 2006-188441).
The hair care liquid according to the present invention solves the following problems.
Since collagen peptides are usually powders, there is a problem that they are difficult to dissolve in perm solution.
Moreover, the response | compatibility with respect to the hair hurting by oxidation was not enough.
The hair care product added to the permanent liquid or the color liquid needs to be dissolved in a short time. Therefore, the liquid to be added is preferably a liquid similar to a permanent liquid or a color liquid.
However, an aqueous collagen peptide solution is spoiled by microorganisms and is difficult to store for a long time.
Preservatives can be used but can damage the hair.
As described above, the collagen peptide cannot solve the hair oxidation by the permanent liquid or the color liquid.
Therefore, the main object of the invention of this hair care solution is to provide a hair care solution that can impart “gloss”, “moisture”, and “moist feeling” to hair, and can suppress hair oxidation.
The effects of the hair care liquid according to the present invention are as follows.
For hair oxidation by perm solution or color solution, by adding platinum nano colloid with anti-oxidation effect that has been made ultrafine to nano level (3m / billion), perm solution or color solution A function to suppress hair oxidation is added.
When actually added to the perm solution and used, the gloss and moist feeling increased compared to conventional powdered collagen, and the finger was smooth. Further, when the hair was closely observed, it was confirmed that the cuticle was less damaged.

A hair care solution in which the following (1) collagen peptide (molecular weight 5000) and (2) platinum nanocolloid are aseptically filled into a truncated cone-shaped container body 12 and the lid is heat sealed.
(1) Collagen peptide 30% by weight
(2) 0.19% by weight of platinum nanocolloid
(3) Remaining water Since the hair care solution of Example 1 is aseptically filled, it can be stored for a long period of time regardless of storage conditions, there is no risk of decay, and no preservative is added. Manufacture is possible.

When 10 ml of the hair care solution of Example 1 was mixed with 50 ml of the perm solution and used to verify the effect on the hair, the hair tip was smooth, the hair tip settled down, and it was easy to unite. Further, when 10 ml of the hair care liquid of Example 1 was mixed with 50 ml of the color liquid at the time of coloring and the effect brought on to the hair was verified, the fluffiness of the bristles disappeared, the bristles settled down, and it was easy to gather.
Since the container is filled to 10ml, it is easy to use and there is no waste.

In the attached FIG. 2 (Photo 1) and FIG. 3 (Photo 2), the use of platinum is an example using the hair care solution of Example 1.
As shown in FIG. 2 (Photo 1), the present example using platinum has higher gloss and moist feeling than the comparative example not using platinum, and the finger is smooth. .
As shown in FIG. 3 (Photo 2), the present example using platinum is free from fluffiness at the tip of the hair, and the tip of the hair settles down more easily than the comparative example not using platinum. .

An example of using the hair care solution of Example 1 is platinum + collagen.
The results of hair verification using an electron microscope are as shown in FIG. 4 (Photo 3).
As shown in FIG. 4 (Photo 3), the present example using platinum is more consistent with the permanent solution when used when shampooing and rinsing than the comparative example not using platinum. The cuticle is less damaged even when dissolved at a ratio of 5 parts by weight (perm liquid 5 parts by weight, 1 part by weight of this embodiment product).

A hair care solution in which the following (1) collagen peptide (molecular weight 5000) and (2) platinum nanocolloid are aseptically filled into a truncated cone-shaped container body 12 and the lid is heat sealed.
(1) Collagen peptide 30% by weight
(2) 0.035% by weight of platinum nanocolloid
(3) Water remaining

A hair care solution in which the following (1) collagen peptide (molecular weight 3000) and (2) platinum nanocolloid is aseptically filled into a truncated cone-shaped container body 12 and the lid is heat sealed.
(1) Collagen peptide 30% by weight
(2) 0.19% by weight of platinum nanocolloid
(3) Water remaining

  When 10 ml of the hair care solution of Example 1 was dissolved in 50 ml of the permanent solution and permed, the results shown in Table 1 were obtained.

  The present invention is not limited to the hair care liquid of the above-described embodiment, and various modifications can be made based on the idea of the present invention.

  Instead of the container body 12, strip packaging, that is, mainly using polyethylene film, moisture-proof cellophane, polyethylene-processed cellophane (so-called polycello), aluminum foil, etc., is used to divide and package a single use amount of hair care liquid with a three-way seal. Thus, each section may be easily cut out. In addition, using polyethylene terephthalate (PET), aluminum foil, polyamide, polyethylene laminated film, etc., use a three-sided seal to package a single amount of hair care solution so that each segment can be easily cut. Also good. In addition, the packaging container may have another shape as long as it is suitable for filling the hair care solution 50, which is heated to 130 ° C. to 150 ° C. and kept in the heated state for 4 to 5 seconds, for example. Moreover, the thing excellent in light-shielding property and sealing performance is good.

(Embodiment)
The hair care liquid 52 according to the present invention has the following configuration.
The following (1) water-soluble keratin and (2) platinum nanocolloid are mixed in water.
(1) 1.5% to 5.8% by weight of water-soluble keratin
(2) Platinum nanocolloid 0.035 wt% to 0.315 wt%
(3) Water remaining

  When the platinum nanocolloid is less than 0.035% by weight, the action of suppressing oxidation, which is the action of platinum, is extremely reduced, and when it exceeds 0.315% by weight, the effect is not further increased.

Water-soluble keratin is a grade used for foods, and platinum (platinum) is a grade used for cosmetics.
Water-soluble keratin moisturizes and nourishes the hair and works to make the cuticles that protect the hair sturdy.
Platinum (Platinum) is a nano-sized platinum nano colloid that is made into ultrafine particles (3 parts per billion). It has an anti-oxidation effect and functions to suppress hair oxidation by permanents and colors. Can be sufficiently penetrated.
Keratin is a protein that accounts for 90% of the hair components and is a protein that is insoluble in water, but water-soluble keratin is a hydrolyzed keratin that is composed of amino acids close to the hair, and the hair It has a high sorbing power, prevents a decrease in strength due to the treatment, and can keep the hair out.
Since it is a liquid, it dissolves easily in permanent liquids (which give curls, suppleness, and firmness to the hair) or color liquids (which color the hair).
Especially for soft hair and porous hair (hair that is heavily damaged), the damage is complemented by mixing with pre-perm shampoo, perm liquid or color agent, and shampoo treatment after perm treatment, and the hair is "swelled" It has the function of giving a “koshi” and “curl feeling (rigid feeling)”.
It also works beautifully on normal and healthy hair that wants to enhance its “harness”, “koshi” and “curl feeling (rigidity)”.
Aseptic filling portion pack packaging does not use preservatives, there is no risk of spoilage even with liquids, and it is hygienic for a long time before opening.

The hair care liquid 52 according to the present invention particularly relates to an additive added to a permanent liquid used for, for example, a cold permanent and an iron permanent.
The background art relating to the hair care solution according to the invention will be described. Conventionally, keratin has been used as a main component of PPT (polypeptide pretreatment agent regeneration) treatment and treatment in the previous stage of applying perm and color (Japanese Patent Application Laid-Open No. 2005-318867). 2003-138296).
The hair care liquid according to the present invention solves the following problems.
The hair care product added to the permanent liquid or the color liquid needs to be dissolved in a short time. Therefore, the liquid to be added is preferably a liquid similar to a permanent liquid or a color liquid.
However, water-soluble keratin aqueous solutions are spoiled by microorganisms and are difficult to store for a long time.
Preservatives can be used but can damage the hair.
Moreover, the response | compatibility with respect to the hair hurting by oxidation was not enough.
Thus, the oxidation of hair by a permanent solution or a color solution cannot be solved by water-soluble keratin.
Therefore, the main object of the invention of this hair care solution is to provide a hair care solution that can impart “harness”, “koshi”, and “curl feeling (rigid feeling)” to hair, and can suppress hair oxidation.
The effects of the hair care solution according to the present invention are as follows.
For hair oxidation by perm solution or color solution, by adding platinum nano colloid with anti-oxidation effect that has been made ultrafine to nano level (3m / billion), perm solution or color solution A function to suppress hair oxidation is added.
When it was actually added to the perm solution and used, the “harness”, “koshi”, and “curl feeling” improved compared to the conventional water-soluble keratin. In addition, when the hair was closely observed, it was confirmed that there was little damage to the cuticle.

A hair care solution in which the following (1) water-soluble keratin and (2) platinum nanocolloid are aseptically filled in a frustoconical container body and the lid is heat-sealed.
(1) 2.90% by weight of water-soluble keratin
(2) Platinum nanocolloid 0.21% by weight
(3) Remaining water Since the hair care liquid of this Example 4 is aseptically filled, it can be stored for a long period of time regardless of storage conditions, there is no risk of decay, and no preservative is added. Manufacture is possible.

When 10 ml of the hair care solution of Example 4 was mixed with 50 ml of the perm solution and used to verify the effect on the hair, the fluffiness of the hair ends disappeared, the hair tips settled down, and it was easy to unite. In addition, when mixed with a treatment material at the time of coloring and used to verify the effect on hair, the hair ends are no longer crusty, the hair ends settle down, and it is easy to unite.
In addition, when the hair was closely observed, it was confirmed that there was little damage to the cuticle.
As a single use amount, 10ml is filled in a container, so it is easy to use and is used up so there is no waste.

In the attached FIG. 5 (Photo 4) and FIG. 6 (Photo 5), platinum keratin is shown as an example using the hair care solution of Example 4.
As shown in FIG. 5 (photo 4) and FIG. 6 (photo 5), the present example using platinum is more “smooth”, “koshi”, and “curl feeling” than the comparative example not using platinum. Is up.
Further, in this example using platinum, compared to the comparative example not using platinum, the fluffiness of the hair ends disappears, the hair ends settle down, and it becomes easier to unite.

The results of hair verification using an electron microscope are as shown in FIG. 7 (Photo 6). In FIG. 7, platinum keratin is an example using the hair care solution of Example 4.
As shown in FIG. 7 (Photo 6), compared to the comparative example in which platinum was not used, it was used after being dissolved in the perm solution at a certain ratio (5 parts by weight of the perm solution, 1 part by weight of the product of this example). The cuticle is less damaged.

A hair care solution in which the following (1) water-soluble keratin and (2) platinum nanocolloid are aseptically filled in a frustoconical container body and the lid is heat-sealed.
(1) 2.90% by weight of water-soluble keratin
(2) 0.035% by weight of platinum nanocolloid
(3) Water remaining

  When 10 ml of the hair care solution of Example 4 was added to 50 ml of the permanent solution and a questionnaire was given to the person who received the permanent, the results shown in Tables 2 to 7 were obtained.

  The present invention is not limited to the hair care liquid of the above-described embodiment, and various modifications can be made based on the idea of the present invention.

  Instead of the container body 12, strip packaging, that is, mainly using polyethylene film, moisture-proof cellophane, polyethylene-processed cellophane (so-called polycello), aluminum foil, etc., separate and package hair care liquid for one use with a three-side seal. Thus, each section may be easily cut out. In addition, using polyethylene terephthalate (PET), aluminum foil, polyamide, polyethylene laminated film, etc., use a three-way seal to package a single amount of hair care solution so that each segment can be easily cut. Also good. In addition, the packaging container may have other shapes as long as it is suitable for filling the hair care liquid 52 that is heated to 130 ° C. to 150 ° C. and kept in the heated state for 4 to 5 seconds. Moreover, the thing excellent in light-shielding property and sealing performance is good.

(Embodiment)
The lotion 54 according to the present invention has the following configuration.
The following (1) hyaluronic acid and (2) platinum nanocolloid are mixed in water.
(1) Hyaluronic acid 0.05 wt% to 0.22 wt%
(2) Platinum nanocolloid 0.025 wt% to 0.285 wt%
(3) Water remaining

  When the platinum nanocolloid is less than 0.025% by weight, the action of suppressing oxidation, which is the action of platinum, is extremely reduced.

Hyaluronic acid and platinum (platinum) are the grades used in cosmetics.
Hyaluronic acid moisturizes and nourishes the skin.
Hyaluronic acid is a mixture of hyaluronic acid having an average molecular weight of 850,000 to 1.6 million and hyaluronic acid having an average molecular weight of 10,000 or less that penetrates into the stratum corneum. Hyaluronic acid having an average molecular weight of 850,000 to 1.6 million cannot penetrate into the stratum corneum because of its high molecular weight.
Platinum (Platinum) is a nano-sized platinum nano colloid that has been made into ultrafine particles down to the nano level (3 parts per billion). It has an anti-oxidant action and functions to suppress skin oxidation, and penetrates the skin sufficiently. Can be made.
Aseptic filling portion pack packaging does not use preservatives, there is no risk of spoilage even with liquids, and it is hygienic for a long time before opening.

A skin lotion in which the following (1) hyaluronic acid and (2) platinum nanocolloid are aseptically filled in a frustoconical container body and the lid is heat sealed.
(1) 0.05% by weight of hyaluronic acid
(2) Platinum nanocolloid 0.21% by weight
(3) Remaining amount Since the lotion of Example 7 is aseptically filled, it can be stored for a long period of time regardless of storage conditions, there is no risk of decay, and no preservative is added. Manufacture is possible.

A skin lotion in which the following (1) hyaluronic acid and (2) platinum nanocolloid are aseptically filled in a frustoconical container body and the lid is heat sealed.
(1) Hyaluronic acid 0.22% by weight
(2) Platinum nanocolloid 0.285 wt%
(3) Residual amount Since the lotion of Example 8 is aseptically filled, it can be stored for a long period of time regardless of storage conditions, there is no risk of decay, and no preservative is added. Manufacture is possible.

Next, the cosmetic manufacturing method of the present invention will be described based on a manufacturing apparatus shown in the drawings.
FIG. 8 is an illustrative front view showing the overall configuration of the filling and sealing apparatus according to one embodiment of the present invention.
This molded filling seal device 110 is a small container formed by a container molding material supply mechanism 112 that supplies a container molding material 100 for molding the container body 12 and a container molding material 100 supplied by the container molding material supply mechanism 112. A container molding mechanism 114 for molding the container molding material 100, a container molding material transport mechanism 116 for transporting the container molding material 100, a first sterilization mechanism 118 for sterilizing the container molding material 100, and hair care liquid 50, 52 or lotion 54. A filling mechanism 120 that fills the container body 12, a lid material supply mechanism 122 that conveys the lid material 102, a second sterilization mechanism 124 that sterilizes the lid material 102, and a seal that welds the lid material 102 to the container body 12 A mechanism 126 and a cutting mechanism 128 that cuts the container molding material 100 and the lid material 102 and shapes them into an appropriate shape are provided.
Then, a plurality of rows of container main bodies 12 formed by the container forming mechanism 114 are supplied at predetermined intervals, and a filling mechanism provided in a predetermined container stop portion of a container conveyance path through which the container main bodies 12 are intermittently conveyed. 120 is filled with cosmetic liquid 50, 52 or lotion 54, and the lid 102 is supplied to the container body 12 by the lid supply mechanism 122 that conveys the lid 102, and the lid 102 is removed from the container body 12 by the seal mechanism 126. Then, the container molding material 100 and the lid material 102 are cut by the cutting mechanism 128 or the like and then sent to the next step.

  The container molding material supply mechanism 112 is provided in the middle of a container molding material holding / supplying means 130 for holding and supplying the raw material of the container molding material 100 provided upstream, and a winding means 132 provided downstream. Transporting means 134. The conveying means 134 of the container molding material supply mechanism 112 conveys a plurality of (6 × 3 rows in this embodiment) cup-shaped container bodies 12 at equal intervals. The transport means 134 is configured to travel intermittently. For example, the transport unit 134 transports the container body 12 in a cycle of stopping for 1 second and moving for 0.8 seconds.

  The container molding material holding / supplying means 130 pulls out the container molding material 100 wound in a roll shape, that is, a holding machine 136 that holds the polyethylene terephthalate sheet, and the container molding material 100 held by the holding machine 136 and sends it downstream. A container molding material exchange base 138 provided below the container molding material 100 and a container molding material replacement space 140 are provided.

A first sterilization mechanism 118 for sterilizing the container molding material 100 is provided downstream of the container molding material holding and supplying means 130 for sterilizing the container molding material 100 by immersing the container molding material 100 in hydrogen peroxide (H 2 O 2). A container molding material hydrogen peroxide tank 142 is provided.
Furthermore, the first sterilization mechanism 118 removes hydrogen peroxide by spraying the container molding material 100 immersed in the container molding material hydrogen peroxide tank 142 and sterilized with an air knife with sterilized hot air. A sterile warm air device 146a is provided.
The first sterilization mechanism 118 is provided with a dancer roller 154a that adjusts the tension of the container molding material 100 to be delivered. The container molding material 100 is sent upward via the dancer roller 154a and is sent to the container molding mechanism 114. Supplied.

  On the other hand, the container molding material 100 to be the container body 12 is sent to a dancer roller 154 a provided in the first sterilization mechanism 118. The dancer roller 154a repeatedly moves up and down to adjust the tension of the container molding material 100. The dancer roller 154a rises and the upper limit sensor detects this and starts driving the feed roller 148. When the dancer roller 154a is lowered to the lowest position, the lower limit sensor detects this and stops the driving of the feed roller 148.

  The container molding mechanism 114 heats and softens the container molding material 100, and in a sterile environment, the container molding material 100 softened by the heating device 170 is stretched by a molding plug 178 to form a container. A molding apparatus 172 for molding the container body 12 is provided by aseptic air being blown into the material 100 and continuously compressed with a molding die.

The molding apparatus 172 includes an upper mold 174 and a lower mold 176, and includes a molding plug 178 that allows the container molding material 100 to enter the female mold of the lower mold 176.
The upper mold 174 and the lower mold 176 are provided with a paragraph of the upper mold 174 as a paragraph of the upper mold 174 and a paragraph of the portions 174a and 176 on a mating surface on which the knob portion 20 as an opening portion is molded.
In the paragraph part 174a and the paragraph part 176a, A-PET (amorphous polyethylene terephthalate) constituting the container molding material 100 is folded with a groove to peel the lid 22 from the collar part 18 of the container body 12. Therefore, when the lid 22 is bonded to the container body 12 as will be described later, a part of the container body 12 forming the knob portion 20 is stepped, that is, hangs downward. A part of the knob part 20 is configured not to adhere to a part of the knob part 20 of the container body 12.
The molding plug 178 inserted into the opening of the upper mold 174 is configured so that a gap is formed between the molding plug 178 and the opening of the upper mold 174, and aseptic air is formed from the gap when the container molding material 100 is molded. The container molding material 100 is configured to expand into the shape of the container body 12.
The container molding material 100 is heated (heating device) by setting the heater temperature to 125 to 127 ° C. and heating the container molding material 100 to 125 ° C. (reference) in order to heat the container molding material 100 to an appropriate molding temperature. .
However, since it crystallizes at 130 ° C. or higher (whitens and becomes brittle), it must be kept at an appropriate temperature.
The molding plug 178 constituting the molding apparatus is made of polyacetal. Since this has high thermal conductivity, the container molding material 100 is cooled at the time of contact with the molding plug 178. For this purpose, the corner of the tip portion is made large so that the container molding material 100 is made slippery.

The filling mechanism 120 includes a metering type filling pump 180 for aseptically filling the cosmetic liquid into the housing recess 12 of the container body 12 continuously molded in an aseptic environment, and a filling device 182 connected thereto.
The heat-sterilized cosmetic liquid (hair care liquid 50, 52 or lotion 54) is stored in a tank previously sterilized by steam sterilization, and steam and excess between the pipe up to the filling device 182 and the filling device 182 aseptic chamber are stored. Sterilize with hydrogen oxide to make it aseptic.
When the sterilized state is reached, cosmetic liquid (hair care liquid 50, 52 or cosmetic liquid 54) is fed from the tank, and sterilized filling device 182 performs aseptic filling packaging.

A sealing mechanism 126 and a cutting mechanism 128 are sequentially provided at a predetermined interval on the downstream side of the filling mechanism 120. Between the filling mechanism 120 and the seal mechanism 126, a lid material 102 constituting the lid 22 is supplied from above by a lid material supply mechanism 122 (indicated by reference numeral 122 as a whole), which will be described later. 22 is changed in direction toward the downstream side (left side in FIG. 1) upstream of the pre-seal device 126a constituting the sealing mechanism 126, and toward the downstream sealing mechanism 126 and the cutting mechanism 128. Then, it is sent between the upper surface of the container main body 12 conveyed by the lower conveying means 134.
The lid member 102 constituting the lid 22 is thermocompression bonded to the flange portion 18 of the opening of the container body 12 by the sealing mechanism 126 at the stop position of the container body 12, and then the small container 10, the collar portion 18, and The periphery of the portion that becomes the lid 22 is punched out along the shape of the knob portion 20.

Next, the configuration of the lid material supply mechanism 122 will be described based on FIG. 8 and FIG. 14 showing the main part of the lid material supply mechanism 122.
A supply stand (cover material roll support means) 152 of the cover material supply mechanism 122 is provided so as to protrude from the upper part of the machine casing 110A where the main body of the molded filling seal device 110 is provided (see FIG. 14). ). The supply stand 152 supports a lid roll 102A in which the lid 102 is wound in a roll shape by a drive shaft 152A. The lid 102 pulled out from the lid roll 102A is sent through a plurality of rollers 152a supported by a supply stand 152. As described above, the cover material 102 used as the cover 22 of the small container 10 is generally made of an aluminum or resin film, or a film coated with these.

The second sterilization mechanism 124 is provided to sterilize the lid member 102 for forming the lid 22.
The second sterilization mechanism 124 for sterilizing the lid member 102 includes a lid member hydrogen peroxide tank 144 for sterilizing the lid member 102 by immersing the lid member 102 in hydrogen peroxide (H 2 O 2).
Further, the second sterilization mechanism 124 is a sterile temperature that removes hydrogen peroxide by spraying the sterilized cover material 102 immersed in the cover material hydrogen peroxide tank 144 with an air knife with sterilized warm air. A wind air device 146b is provided.

  A first upper roller 156 parallel to the conveying direction A of the conveying means 134 is installed on the upper side of the aseptic warm air device 146b. The lid member 102 whose feeding direction has been changed by approximately 90 degrees by the first upper roller 156 can be changed by the second upper roller 158 substantially downward in the vertical direction. Further, a lower roller 160 and a roller 162 are disposed below the second upper roller 158 and slightly above the conveying surface of the conveying means 134.

  The lid material supply mechanism 122 is provided with a dancer roller 154b for adjusting the tension of the lid material 102 to be sent out, and the lid material 102 is sent upward via the dancer roller 154b and installed in the machine casing 110A. The sealed mechanism 126 is supplied.

  Under the side frame 110B of the machine frame 110A, in the vicinity of the rear of the position where the pre-sealing device 126a of the sealing mechanism 126 is provided, the container conveying direction by the conveying means 134 (see arrows A in FIGS. 8 and 14) and A roller 162 (see FIG. 14) installed in parallel is attached, and the lid 102 sent via the dancer roller 154b is moved in the container conveying direction by the roller 162 installed in parallel with the container conveying direction A. It is supplied into the main body of the molded filling sealing device 110 in a direction orthogonal to A.

  The lid material 102 fed into the molded filling seal device 110 via the roller 162 installed in parallel with the conveyance direction A of the container body 12 is changed in direction by approximately 90 degrees by the lower roller 160, and upstream of the conveyance means 134. Directed sideways and sent downstream. The lid member 102 sent from the upper side to the lower side is almost horizontally changed toward the downstream side in the conveying direction of the conveying means 134 by the lower roller 160 and is sent in the horizontal direction along the container body 12. .

  A roller 162 is provided between the second upper roller 158 and the lower roller 160. The lid member 102 is adhered to the collar portion 18 of the small container 10 by the sealing mechanism 126 and then advances together with the container body 12 conveyed by the traveling conveying means 134, but may be pulled by the movement of the container body 12. This drive shaft 152A rotates so that there is no. The rotation of the drive shaft 152A is sent when the dancer roller 154b is detected by the upper limit sensor, and is stopped when the lower limit sensor detects it.

  A mark sensor 164 for detecting marks printed on the lid member 102 at a predetermined pitch is provided downstream of the lower roller 160 (see FIG. 14). As described above, the drive shaft 152A is operated by a motor in synchronization with the movement of the conveying means 134. However, the feed amount of the lid member 102 increases or decreases according to the detection result of the mark position by the mark sensor 164. Is done.

  The conveying means 134 intermittently conveys the container main body 12 by repeatedly running and stopping, and the small containers 10 to be conveyed are provided in order on the container conveying path downstream of the container molding material supply mechanism 112. It stops at the position of the filling mechanism 120, the sealing mechanism 126 and the cutting mechanism 128. The small container 10 first stops below the filling mechanism 120 and is filled with contents such as liquid. The small container 10 filled with the contents is conveyed below the next sealing mechanism 126 by the conveying means 134.

  A lower roller 160 is provided below the roller 162, and the lid member 102 sent vertically downward from the second upper roller 158 and the roller 162 is brought into a horizontal state by the lower roller 160. The direction is changed and sent downstream. A pre-seal device 126a that constitutes a seal mechanism 126 is provided downstream of the lower roller 160, and both ends of the container molding material 100 and the lid material 102 are thermo-compressed to be side-sealed (pre-seal).

The first sterilization mechanism 118 of the container molding material supply mechanism 112, the heating device 170 and molding device 172 of the container molding mechanism 114, the filling mechanism 120, the second sterilization mechanism 124 of the lid material supply mechanism 122, and the pre-seal device 126a are aseptic. The sterilization chamber 190 is housed in a sealed sterilization chamber 190 for maintaining the sterility, and the sterility is maintained by positive pressure by supplying clean air (sterile air).
The container molding material 100 enters the sterilization chamber 190 from the container molding material inlet 192 of the sterilization chamber 190, and the lid 102 enters the sterilization chamber 190 from the lid material inlet 194 of the sterilization chamber 190. Aseptic air (air from the outside that has passed through a sterile filter) is fed into the container, and the sterile air is discharged from the container molding material inlet and the lid material inlet 194, and the inside of the sterilization chamber 190 is positively pressurized from the outside. Prevent entry.
The pre-sealed container molding material 100 and the lid member 102 are sent from the outlet of the sterilization chamber 190 to the sealing device 126b of the next sealing mechanism 126, and the outlet is provided with a sterilization chamber outlet shutter 196 to maintain sterility. It is comprised so that it may aim.

  In the sterilization chamber 190, the edges of the container molding material 100 and the lid material 102 are bar-sealed by the pre-seal device 126a, and the container molding material 100 and the lid material 102 are maintained at a positive pressure. It is configured to go outside.

  The lid 102 that is directed to the downstream side of the transport means 134 and is supplied in a substantially horizontal state is provided at the opening of the container body 12 that is transported on the container transport means 134 by the seal mechanism 126 and temporarily stopped at this position. It is thermocompression-bonded to the collar portion 18. At this time, an ethylene vinyl acetate (EVA) adhesive is used for bonding the collar portion 18 and the lid member 102.

  Subsequently, the sealed container molding material 100 and the lid material 102 are sent to the cooling board 200, and the thermocompression-bonded portion is cooled.

  Subsequently, when notching the container molding material 100, the container molding material 100 and the lid material 102 are sent to the notch device 210. In this embodiment, the step portion 24 is engraved in the container molding material 100. Therefore, notch is not engraved.

Subsequently, in the next cutting mechanism 128, the periphery of the portion that becomes the lid 22 by being attached to the mouth portion of the container body 12 of the lid member 102 is cut.
The portion of the collar portion 18 that is the opening portion of the container main body 12 that is a punched portion container is in a state where the container main body 12 and the lid 22 are attached due to the pressure at the time of punching. Correspondingly, the container constituting the container main body 12 in the knob portion 20 by expanding the stepped portion 24 formed in the knob portion 20 continuous with the flange portion 18 portion which is an opening portion from 0.5 mm to 1.3 mm. Adhesion between the molding material 100 and the lid material 102 constituting the bottom material 22 was prevented.
This phenomenon is derived from the characteristics of the container molding material 100 and the lid material 102. A-PET constituting the container body 12 is a sticky material, and the ethylene vinyl acetate (EVA) layer of the lid 102 is excellent in adhesiveness at a low temperature. The properties of each other were in the state of temporary bonding due to the pressure at the time of punching. This problem was solved by making the container molding material 100 and the lid material 102 easy to separate by increasing the level difference.

  The portions of the stepped portion 24 of the unsealed container forming material 100 and the lid material 102 caused vibration during transport of the machine and caused the filling to overflow outside the container main body 12. In particular, there was a significant influence on the connecting part of the guide. In order to eliminate the influence, all portions through which the stepped portion 24 passes are ground so that no vibration is generated.

In the next cutting mechanism 128, the lid 22 made of the lid material 102 cut out after the periphery of the portion of the lid material 102 affixed to the upper surface of the container body 12 to be the lid 22 of the small container 10 is cut. The small container 10 sealed by is conveyed by the conveying means 134 as it is, taken out on the downstream side, and sent to the next step.
On the other hand, the container molding material 100 from which the container portion of the container molding material 100 and the lid portion of the lid material 102 are cut out and the remaining portion 102 a of the lid material 102 are wound around the winding means 132 via the roller 220.

In this embodiment, the heating temperature is confirmed when the container is molded. Aiming to heat the container molding material 100 to 125 ° C., the temperature of the heating device 170 is set to 127 ° C.
When the cycle speed of the machine is slow, the drawdown increases during the interval, and the container molding material 100 adheres to the bottom heater of the lower mold 176, and wrinkles are generated.
By increasing the cycle speed, the draw-down state can be stabilized and prevented from adhering to the bottom heater.
The cycle speed is greatly affected by the viscosity of the cosmetic liquid to be filled (hair care liquid 50, hair care liquid 52, and skin lotion 54). When the viscosity is low, it overflows from the container body 12 at the time of filling, so that it is necessary to slow down the speed at the time of filling. This speed affects the cycle speed of the machine.
In order to adjust the degree of molding, the amount of insertion of the molding plug 178 is adjusted. When there is much penetration, the thickness of the container molding material 100 at the bottom of the molding becomes too thick. Moreover, it is easy to make a wave at the bottom.
If the amount of the molded plug 178 is reduced and inflated with compressed air, it can be finished into a beautiful shape. In the case of A-PET, unlike polystyrene, it is resistant to crushing and deformation due to external pressure, and can maintain the same strength as a polystyrene container even when the sheet is thin.
As for the drag line by the molding plug 178, the smaller the penetration amount, the thinner the thickness and the less noticeable.

While the machine is stopped, the container molding material 100 is deformed due to elongation by the dry air in the air knife portion of the sterile hot air air device 146a. Therefore, the temperature of the dry air is changed to 70 ° C. so that the removal of hydrogen peroxide and the damage to the container molding material 100 are minimized.
Further, during the stop, the portion that was in the air knife portion of the sterile hot air air device 146a is not molded until it passes through the heating device 170. This is because it is subjected to a thermal load and is easily adhered to the container molding material 100 by the heating device 170.

“Aseptic filling” means that the contents after filling are free of any bacteria, and the inside of the container body 12 of the small container 10 is free of any bacteria. If even one bacterium remains, the contents themselves become nutrients for the bacterium, so it will quickly grow and rot.
Bacteria zero has been confirmed in the inspection after filling, and since there is no element that allows the bacteria to grow over time, sterility can be secured even for those that have passed one year after production.

DESCRIPTION OF SYMBOLS 10 Small container 12 Container body 12a Opening part 14 Bottom 14c Edge part 16 Body part 18 Collar part 20 Knob part 24 Step part 22 Lid 50,52 Hair care liquid 54 Lotion 100 Container molding material 102 Lid material 102a Container molding material 100 and lid Remaining part of material 102A Lid material roll 110 Molding filling seal device 110A Machine frame 110B Frame 112 Container molding material supply mechanism 114 Container molding mechanism 116 Container molding material transport mechanism 118 First sterilization mechanism 120 Filling mechanism 122 Lid material supply mechanism 124 Second sterilization mechanism 126 Sealing mechanism 126a Pre-sealing device 126b Sealing device 128 Cutting mechanism 130 Container molding material holding / supplying means 132 Winding means 134 Conveying means 136 Holding machine 138 Container molding material replacement stand 140 Container molding material replacement space 142 Container Molding material hydrogen peroxide tank 144 Lid hydrogen peroxide tank 146a, 146b Aseptic hot air air device 148 Feed roller 152 Supply stand 152A Drive shaft 152a Roller 152b Introduction roller 154a, 154b Dancer roller 156 First upper roller 158 Second upper roller 160 Lower roller 162 Roller 164 Mark sensor 170 Heating device 172 Molding device 174 Upper die 176 Lower die 174a, 176a Paragraph 176b Bottom heater 178 Molding plug 180 Filling pump 182 Filling device 190 Aseptic chamber 192 Container molding material inlet 194 Cover material inlet 196 Aseptic Room exit shutter 200 Cooling panel 210 Notch device 220 Roller A Conveying direction

Claims (5)

(1) sterilizing plastic container molding material;
(2) In a sterile environment, a container molding material suitable for filling heated cosmetic liquid is softened by heating to a temperature of 125 ° C. or higher, and the softened container molding material is compressed and molded by blowing sterile air. Forming an accommodation recess having a capacity sufficient to fill a single use amount of the cosmetic liquid ;
(3) Aseptically filling a cosmetic liquid that does not contain the following liquid preservative , which is heated and sterilized and maintained in a sterile state, in a continuously formed housing recess in an aseptic environment;
The cosmetic liquid does not contain a preservative and is prepared by mixing the following (1) collagen peptide and (2) platinum nanocolloid in water.
(1) 10% to 50% by weight of collagen peptide
(2) Platinum nanocolloid 0.035 wt% to 0.285 wt%
(3) remaining amount of water (4) in a sterile environment, sealing the lid held in a sterile state around the opening of the small container to close the opening of the small container;
(5) including a step of separating each of the small containers filled with the cosmetic liquid together with the periphery of the housing recess and the lid.
Manufacturing method for cosmetics. (1) sterilizing plastic container molding material;
(2) In a sterile environment, a container molding material suitable for filling heated cosmetic liquid is softened by heating to a temperature of 125 ° C. or higher, and the softened container molding material is compressed and molded by blowing sterile air. Forming an accommodation recess having a capacity sufficient to fill a single use amount of the cosmetic liquid ;
(3) Aseptically filling a cosmetic liquid that does not contain the following liquid preservative , which is heated and sterilized and maintained in a sterile state, in a continuously formed housing recess in an aseptic environment;
The cosmetic liquid is a hair care liquid, does not contain a preservative, and is a hair care liquid obtained by mixing the following (1) water-soluble keratin and (2) platinum nanocolloid in water. The cosmetics described.
(1) 1.5% to 5.8% by weight of water-soluble keratin
(2) Platinum nanocolloid 0.035 wt% to 0.315 wt%
(3) remaining amount of water (4) in a sterile environment, sealing the lid held in a sterile state around the opening of the small container to close the opening of the small container;
(5) including a step of separating each of the small containers filled with the cosmetic liquid together with the periphery of the housing recess and the lid.
Manufacturing method for cosmetics.   The step of sterilizing the container molding material is performed by immersing the container molding material in a hydrogen peroxide tank to sterilize the surface, and sterilizing the sterilized container molding material with an air knife to blow the surface of the container molding material. The manufacturing method of the cosmetics of Claim 1 or Claim 2 including removing hydrogen peroxide.   The method for producing a cosmetic product according to any one of claims 1 to 3, wherein the container molding material comprises a sheet of polyethylene terephthalate.   The cosmetic container according to any one of claims 1 to 4, wherein the small container is filled with a cosmetic liquid and then sealed by supplying sterile air into the housing recess to maintain a positive pressure. Production method.