JP4623265B2 - Biaxially stretched polyester film - Google Patents

Description

  The present invention relates to a biaxially stretched polyester film. More specifically, it maintains the practical characteristics without losing the excellent properties of the biaxially stretched polyester film, such as heat resistance, scent retention, water resistance, etc., has good twist retention, twist packaging, folding The present invention relates to a biaxially stretched polyester film suitable for bending packaging and capable of being bent and fixed.

  Conventionally, cellophane has been known as a film excellent in twist retention and bendability. Cellophane is used for various packaging materials and pressure-sensitive adhesive tapes due to its excellent transparency, easy cutting property, and twist retention. However, on the other hand, since cellophane has hygroscopicity, its characteristics fluctuate depending on the season, and it is difficult to always supply a product of a certain quality. In addition, a packaging material using a polyethylene terephthalate film as a base film is suitably used for various applications due to excellent properties such as toughness, heat resistance, water resistance, and transparency of a stretched polyethylene terephthalate film. A polyester film having good dimensional stability has been used as a base film on which an inorganic substance or the like is deposited as a conductive film. On the other hand, there are drawbacks in terms of cutability, mouth tearability in packaging bags, and difficulty in tearing with adhesive tape. Further, in applications requiring bendability, there is a drawback that the shape cannot be maintained after folding because of its strong waist. Furthermore, in twist packaging applications, there are drawbacks such as poor twist retention, making it difficult to use as a cellophane substitute.

  In addition, the solid packaging film found in twist packaging must be easily handled by the packaging machine, for example, 200 to 1000 solids per minute can be packaged on a single machine. Must be a thing. That is, generally, the area required for wrapping must be cut before twisting and wrapping the article, and the film must be completely flat before and after wrapping. In addition, if the film after printing or vapor deposition is wrinkled or distorted due to dimensional changes, problems such as distortion during cutting or packaging, and poor appearance of the packaged product arise.

As a method for solving the above drawbacks, a biaxially stretched film made of a copolymer of polyethylene terephthalate, having a yield point in the stress-strain curve, and an average refractive index of the unstretched film of the copolymer An easily foldable polyester film satisfying 0.003 ≦ N ₁ −N ₀ ≦ 0.021 (for example, see Patent Document 1) or a polyester resin, where N ₀ and the average refractive index of the biaxially stretched film are N ₁ (1) A polyester resin (2) having a melting point higher by 10 ° C. or higher than the melting point of the polyester resin (1) layer on at least one surface of the layer and having a thickness of 5% or more and 60% or less with respect to the total thickness. ) At least a temperature lower than the melting point of the polyester resin (1) layer by at least 10 ° C. after the unstretched laminated film laminated with the layer is at least uniaxially stretched, and the melting point of the polyester resin (2) layer is not yet melted. A method for producing a polyester film having a good tearing property and twist holding property that is heat-treated at a full temperature (for example, see Patent Document 2) has been proposed.
Japanese Patent No. 2505474 Japanese Patent Laid-Open No. 5-104618

However, in the above prior art, a biaxially stretched film made of a copolymer of polyethylene terephthalate, having a yield point in the stress-strain curve, and the average refractive index of the unstretched film of the copolymer When the average refractive index of N ₀ and the biaxially stretched film is N ₁ , the method of 0.003 ≦ N ₁ −N ₀ ≦ 0.021 leaves molecular orientation in the film, and the present invention is aimed at It is not possible to obtain bending property and twist holding property. In addition, when processing such as printing, laminating, and vapor deposition is performed, there is a problem that wrinkles are generated due to shrinkage due to heat and a dimensional change of the film in the width direction occurs. Further, the polyester resin (1) has a melting point higher by 10 ° C. or more than the melting point of the polyester resin (1) layer on at least one surface of the polyester resin (1) layer and has a thickness of 5 to 60% of the total thickness ( 2) In a method of heat-treating an unstretched laminated film in which layers are laminated at least at a temperature 10 ° C. lower than the melting point of the polyester resin (1) layer after uniaxial stretching and at a temperature lower than the melting point of the polyester resin (2) layer, In order to obtain film strength, it is necessary to increase the thickness of the polyester resin layer having a high melting point, and in such a case, sufficient twist retention cannot be obtained due to the influence of the polyester resin layer having a high melting point, and twist holding If the thickness of the resin layer having a high melting point is reduced in order to develop the properties, the film becomes brittle, and the film is torn at the corners of the contents during twist packaging, or Had problem film is torn off by the clip gripping the Lum.

  In view of the above-mentioned problems of the conventional polyester film, the present invention maintains the characteristics of practical use without losing the excellent characteristics of heat resistance, aroma retention, water resistance, etc. An object of the present invention is to supply a biaxially stretched polyester film that has bendability and can be twisted, folded, or fixed.

In order to achieve the above object, the biaxially stretched polyester film for packaging of the present invention is a polyester laminated film in which a polyester resin (B) layer is laminated on at least one surface of a polyester resin (A) layer, polyester resin (a) layer and the polyester resin (B) layer, terephthalic acid as the dicarboxylic acid component, ethylene glycol / neopentyl glycol copolymerized ing with polyester resin as the diol component or terephthalic acid as the dicarboxylic acid component, the diol ethylene glycol / 1,4-cyclohexanedimethanol copolymerized ing to the polyester resin as a component, or the consist either of a polyester resin and a polyethylene terephthalate, a polyester resin (a) layer of a polyester laminated film after biaxial stretching of The polyester resin (A) layer is substantially free of molecular orientation and the polyester resin (B) layer is molecularly oriented by heat treatment at a temperature equal to or higher than the temperature at which the child orientation disappears and below the melting point of the polyester resin (B) layer. And the refractive index Nx in the longitudinal direction of the polyester laminated film and the refractive index Ny in the width direction satisfy the formula | Nx−Ny | ≦ 0.001, and the refractive index Nx in the longitudinal direction of the film is Nx ≦ The refractive index Nz in the thickness direction of the film is 1.490 ≦ Nz ≦ 1.550.

  Further, the polyester resin A layer may be formed from a polyester resin that is not substantially crystalline, and the polyester resin B layer may be formed from a polyethylene terephthalate copolymer having a melting point of 200 to 250 ° C.

  The polyester resin which is not substantially crystalline here is DSC (Differential Scanning Calorimeter), and after heating the polyester resin at a temperature of 285 ° C. for 15 minutes, it is rapidly cooled using liquid nitrogen. It is a resin that does not have a crystallization exothermic peak and a melting endothermic peak when the temperature is raised at a rate of ° C / min.

  Moreover, the thermal contraction rate of the film longitudinal direction in 150 degreeC can be 5.0% or less.

Further, it is possible to package that twist wrapping an object to be packaged using the packaging biaxially oriented polyester film described above.

According to the biaxially stretched polyester film for packaging of the present invention, while having the original characteristics of a polyester film such as heat resistance, cold resistance, water resistance, transparency, and fragrance retention, it is excellent in twist retention and bendability. The toughness is maintained, and wrinkles are not generated during post-processing such as printing, laminating and vapor deposition film formation.

  In the biaxially stretched polyester film of the present invention, the refractive index Nx in the longitudinal direction of the laminated film and the refractive index Ny in the width direction satisfy the formula | Nx−Ny | ≦ 0.001, and the refractive index Nx in the longitudinal direction of the film. Nx ≦ 1.577, and the refractive index Nz in the thickness direction of the film is 1.490 ≦ Nz ≦ 1.550, and the laminated film has at least the polyester resin A layer. It is a film in which a polyester resin B layer is laminated on one surface.

  As the polyester laminated film exhibiting such characteristics, the polyester resin A layer can be composed of a laminated film having substantially no molecular orientation and the polyester resin B layer has molecular orientation. It can be formed of a laminated film formed of a polyester resin that is formed of a polyester resin that is substantially non-crystalline and the polyester resin B layer is formed of a polyethylene terephthalate copolymer having a melting point of 200 to 250 ° C.

  As the polyester resin used for forming the polyester resin A layer of the biaxially stretched polyester film of the present invention, it is usually preferable to use a polyester resin that is not substantially crystalline.

  Moreover, it is preferable to use the copolymer of the polyethylene terephthalate whose melting | fusing point is 200-250 degreeC normally for the polyester resin used for forming the polyester resin B layer of the biaxially stretched polyester film of this invention. When the melting point is less than 200 ° C., the heat resistance is insufficient and the heat resistance of the film tends to be lowered, and when the melting point exceeds 250 ° C., the bending property and the twist holding property tend to be lowered.

  As a constituent monomer of the polyester resin that is usually used for forming the polyester resin A layer and the polyester resin B layer, for example, terephthalic acid and ethylene glycol are the main components, and other acid components and / or other glycol components are used. It is polyester contained as a copolymerization component. Other acid components include aliphatic dibasic acids such as adipic acid, sebacic acid and azelaic acid, isophthalic acid, diphenyldicarboxylic acid, 5-tert-butylisophthalic acid, 2,2,6,6-tetramethyl Aromatic dibasic acids such as biphenyl-4,4-dicarboxylic acid, 2,6-naphthalenedicarboxylic acid, 1,1,3-trimethyl-3-phenylindene-4,5-dicarboxylic acid are used. Examples of the glycol component include aliphatic diols such as neopentyl glycol, diethylene glycol, propylene glycol, butanediol, and hexanediol, aliphatic diols such as 1,4-cyclohexanedimethanol, xylene glycol, and bis (4-β-hydroxyphenyl). ) Aromatic diols such as sulfone and 2,2- (4-hydroxyphenyl) propane derivatives are used, but are not particularly limited.

  As a preferred resin composition for obtaining a film excellent in twist retention and bendability of the present invention, as a resin used to form the polyester resin A layer, for example, terephthalic acid / isophthalic acid as a dicarboxylic acid component, Polyester resin mainly composed of ethylene glycol as diol component, terephthalic acid as dicarboxylic acid component, polyester resin mainly composed of ethylene glycol / neopentyl glycol as diol component, or terephthalic acid as dicarboxylic acid component, ethylene glycol / 1 as diol component Polyester resins mainly composed of 1,4-cyclohexanedimethanol are particularly preferred polyester resins.

  Examples of the resin used to form the polyester resin B layer include a polyester resin mainly composed of terephthalic acid / isophthalic acid as a dicarboxylic acid component and ethylene glycol as a diol component, terephthalic acid as a dicarboxylic acid component, and diol component as a diol component. Polyester resin mainly composed of ethylene glycol / neopentyl glycol, terephthalic acid as dicarboxylic acid component, polyester resin mainly composed of ethylene glycol / neopentyl glycol / butanediol as diol component, or terephthalic acid as diol component as diol component Polyester resins mainly composed of ethylene glycol / 1,4-cyclohexanedimethanol are particularly preferred polyester resins.

  In the resin which forms the said polyester resin A layer and the polyester resin B layer, you may contain various additives other than a polyester resin as needed. Additives include titanium dioxide, fine particle silica, kaolin, calcium carbonate, and other inorganic lubricants, and fine particle materials made of acrylic cross-linked polymers, such as acrylic acid, methacrylic acid, acrylic ester, and methacrylic ester. Examples thereof include organic lubricants such as cross-linked polymers made of monomers. Moreover, a stabilizer, a coloring agent, antioxidant, an antifoamer, an antistatic agent, a ultraviolet absorber etc. may be contained independently as needed, and 2 or more types may be used together.

  Each of the polyester resins can be produced by polymerization by a conventionally known method. For example, a polyester can be obtained using a direct esterification method in which a dicarboxylic acid and a diol are directly reacted, or a transesterification method in which a dialkyl ester such as a dicarboxylic acid dimethyl ester is reacted with a diol. The polymerization may be performed by either a batch method or a continuous method.

  Here, an example of the manufacturing method of the biaxially stretched polyester film of this invention is demonstrated. Two kinds of polyester resins with different crystallinity (polyester resin A and polyester resin B) that have been vacuum-dried are supplied to two different extruders, melt extruded at a temperature at which each polyester resin is completely melted, and combined. An unstretched film is formed by passing through an adapter, extruding from a die as a two-kind three-layer (crystalline resin / substantially amorphous resin / crystalline resin), and solidifying by cooling.

  The unstretched film thus obtained is 2 to 4 times in the longitudinal direction at a temperature of glass point transfer temperature to glass point transfer temperature + 30 ° C. of the polyester resin having a high glass transition temperature among the two types of polyester resins. Stretch and immediately cool to 20-40 ° C.

  Next, the film is stretched 3 to 4.5 times in the transverse direction at a stretching temperature in the longitudinal direction +10 to 40 ° C. The biaxially stretched film thus obtained is at a temperature at which the layer made of a substantially amorphous polyester resin melts and lower than the melting point of the layer made of a crystalline polyester resin. Heat treatment is performed according to temperature. In this heat treatment, a relaxation treatment may be performed as necessary. Under the above stretching conditions, preheating is preferably performed at a temperature not lower than the glass transition temperature and not higher than the melting point of the polymer composition constituting the resin composition before longitudinal stretching or lateral stretching.

  For the biaxially stretched polyester film of the present invention, depending on the purpose, for example, surface treatment by a conventionally known method such as corona discharge treatment, plasma treatment, ozone treatment, chemical treatment, or an anchor using a known anchor treatment agent. Processing etc. may be given. Examples of the antistatic coating agent include alkylsulfonic acid, glycerin ester, polyglycerin ester, and the like, and are not particularly limited as long as they can impart antistatic properties. Examples of the coating method include a conventionally known reverse roll coating method, roll knife coating method, die coating method, and gravure coating method, and are not particularly limited. Further, it may be a coating by in-line coating.

  In the biaxially stretched polyester film of the present invention, usually, the polyester resin A layer has substantially no molecular orientation, and the polyester resin B layer has molecular orientation. If the molecular orientation remains substantially in the polyester resin A layer, the twist holding property and the bending property tend not to be obtained sufficiently. Further, the polyester resin B layer usually has molecular orientation. If no molecular orientation remains, film formation becomes unstable. In addition, the strength of the film is insufficient. The degree of molecular orientation of the polyester resin A layer can be expressed by the difference between the refractive index Nx in the longitudinal direction and the refractive index Ny in the width direction and the refractive index in the longitudinal direction. That is, if the formula | Nx−Ny | ≦ 0.001 is satisfied and the refractive index Nx in the longitudinal direction of the film is Nx ≦ 1.577, the molecular orientation of the polyester resin A layer is broken, that is, the molecular orientation is Nonetheless, if | Nx−Ny | exceeds 0.001, the bendability and the twist retention are insufficient. Further, even if Nx exceeds 1.577, the bendability and the twist retention are insufficient. Further, Nz is an index of molecular orientation of the polyester resin B layer, and the refractive index Nz in the thickness direction of the film must be 1.490 ≦ Nz ≦ 1.550, preferably 1.500 ≦ Nz ≦ 1. 540. When Nz is less than 1.490, the bendability and twist retention are insufficient, and when Nz exceeds 1.550, the film forming property becomes unstable.

  The method for obtaining such a biaxially stretched polyester film is not particularly limited. For example, the heat treatment temperature after biaxial stretching is equal to or higher than the temperature at which the molecular orientation of the polyester resin A layer is completely eliminated and less than the melting point of the polyester resin B layer. It is obtained by setting it as the temperature of. However, production of the biaxially stretched polyester film of the present invention by a method other than the above is not hindered.

The layer thickness ratio of the polyester resin A layer and the polyester resin B layer is not particularly limited,
(Polyester resin A layer / polyester resin B layer) = (1/3 to 3/1)
Preferably, (Polyester resin A layer / Polyester resin B layer) = (1/2 to 2/1)
It is.

  Of the total total thickness (polyester resin A layer + polyester resin B layer), when the ratio of the layer thickness of the polyester resin B layer is less than 1/4, the strength of the resulting film is weakened, which only impedes practical use. In addition, the film is likely to melt during heat treatment, making film formation difficult. Moreover, when the ratio of the layer thickness of the polyester resin B layer exceeds 3/4 in the total total thickness, the target bendability and twist retention are lowered. Furthermore, although it is 12-50 micrometers as thickness of the biaxially stretched polyester film used for the use which requires the bendability and twist holding | maintenance property made into the objective of this invention, it is not specifically limited.

  Moreover, the heat shrinkage rate when the biaxially stretched polyester film of the present invention is allowed to stand for 30 minutes in an atmosphere of 150 ° C. is 5.0% or less and 3.0% or less in the film longitudinal direction. More preferably. If the thermal shrinkage in the longitudinal direction of the film when left at 150 ° C for 30 minutes is greater than 5.0%, wrinkles and flatness will be disturbed during post-processing such as printing, laminating, and forming a deposited layer on the film. It is not preferable.

  A method suitable for reducing the heat shrinkage rate is not particularly limited. For example, as a film forming method, a resin melt-kneaded by an extruder is cast to obtain an unstretched film. Thereafter, biaxial stretching, such as simultaneous biaxial stretching or sequential biaxial stretching, is performed, and then a heat treatment can be used while the stretched film is relaxed under tension or in the width direction. In this case, the heat treatment temperature is preferably 170 to 240 ° C, more preferably 180 to 230 ° C, and the heat treatment time is preferably 0.5 to 10 seconds. Furthermore, the relaxation treatment is performed in the cooling process from the heat treatment temperature, preferably in the range of 100 to 200 ° C. in the longitudinal direction and / or the width direction, preferably 0.1 to 2.0% with respect to the width direction. The relaxation process may be one stage or multiple stages, and a change in temperature distribution may be provided.

  As described above, the present invention pays attention to the twist retention and bendability among the characteristics of cellophane, and is excellent in heat resistance, water resistance, fragrance retention, etc., and further biaxially stretched with twist retention. A polyester film is obtained. Twist retention and bendability are obtained by having no orientation of the film or lowering the orientation degree and / or not crystallizing or lowering the crystallinity, in particular, the film has no orientation, and By having a layer in which the film is not crystallized, it is possible to obtain a film that is most excellent in bendability and twist retention.

  In addition, the biaxially stretched polyester film of the present invention is used to form a twist package that individually wraps an object to be packaged made of solids such as various foods, stationery, and industrial parts due to its excellent twist retention and bendability. In addition, it can be made into a package of various packaging forms.

  Next, although an example of the manufacturing method of this invention film is demonstrated, this is a specific example to the last, and does not restrain the content of this invention. The physical properties, characteristics measurement and evaluation methods used in the present invention are described below.

(1) Refractive index The refractive index was measured with NaD ray light by an Abbe refractometer according to JIS-K-7142 except that the state of the sample was adjusted and the measurement temperature was 30 ° C. The mounting liquid was methylene iodide, and the refractive index in the longitudinal direction (Nx), the refractive index in the width direction (Ny), and the refractive index in the thickness direction (Nz) were measured.

(2) Melting point (Tm)
Measurement was performed by connecting a TA60WS disk station (manufactured by Shimadzu Corporation) to a robot DSC (differential scanning calorimeter) DSC-60 (manufactured by Shimadzu Corporation). After adjusting 10 mg of the sample to an aluminum pan, it is set in a DSC apparatus (reference: aluminum pan of the same type without a sample). After heating, it was quenched with liquid nitrogen. The sample was heated at a rate of 10 ° C./min, and the melting point (Tm) was measured from the DSC chart.

(3) Crystallinity Measurement was performed by connecting a TA60WS disk station (manufactured by Shimadzu Corporation) to a robot DSC (differential scanning calorimeter) DSC-60 (manufactured by Shimadzu Corporation). After adjusting 10 mg of the sample to an aluminum pan, it is set in a DSC apparatus (reference: aluminum pan of the same type without a sample), the sample is heated at a rate of 10 ° C./min, and the temperature is 285 ° C. for 15 minutes. After heating, it was quenched with liquid nitrogen. The sample was heated at a rate of 10 ° C./min, and the crystallization exothermic peak and the melt endothermic peak were measured from the DSC chart. A resin having no crystallization exothermic peak and no melt endothermic peak was defined as a polyester resin that was not substantially crystalline.

(4) Intrinsic viscosity A chip sample (0.1 g) was precisely weighed, dissolved in 25 mL of a mixed solvent of phenol / tetrachloroethane = 6/4 (mass ratio), and measured at 30 ° C. using an Ostwald viscometer. In addition, the measurement was performed 3 times and the average value was calculated | required.

(5) Thermal contraction rate Except the following, it measured according to JIS-C-2318. In the longitudinal direction of the film, a sample having a width of 10 mm and a length of 250 mm is cut out, marked at intervals of 200 mm, and the interval A is measured with a constant tension of 5 g. Subsequently, it was left in an oven in an atmosphere at 150 ° C. for 30 minutes with no load. After taking out from the oven and cooling to room temperature, the interval B was obtained with a constant tension of 5 g, and the thermal shrinkage rate was obtained by the following equation. For measurement, samples were cut out from five locations at equal intervals in the width direction of the film, and the maximum value and variation (difference between the maximum value and the minimum value) were obtained.
Thermal contraction rate = (A−B) / A × 100 (%)

(6) Twist retention property Twist packaging was performed at a rate of 200 pieces / minute using a twist packaging machine TA200 type manufactured by Tenchi. The film is twisted 1.5 turns (540 degrees) into individual packages. Thereafter, the angle at which the twist was held after a slight return (hereinafter referred to as “twist holding angle”) was measured.
The larger the holding angle, the better the twist holding ability, and the classification was evaluated as follows.
○: Twist holding angle is 230 degrees or more ×: Twist holding angle is less than 230 degrees

(7) Heat resistance Heat resistance was evaluated by the flatness after vapor deposition. The film was set on the unwinding side of a wind-up type vacuum deposition apparatus, the pressure in the chamber was reduced to 4 × 10 ⁻³ Pa, and aluminum was evaporated by high-frequency induction overheating to form an aluminum deposition layer having a thickness of 50 nm. At this time, the film supply speed was 40 m / min, and the chill roll temperature was −15 ° C. The film after vapor deposition was unwound from a roll, the flatness of the film was observed visually, and the following three-stage evaluation was performed.
○: Flatness is good even when no tension is applied.
(Triangle | delta): When tension | tensile_strength is applied to a film slightly, flatness will be favorable and there will be no problem practically.
X: Even if tension is applied, there is a problem in practical use because there is a disorder in flatness.

(8) Glass transition temperature Using a DSC-60 differential scanning calorimeter manufactured by Shimadzu Corporation, the glass transition temperature was measured at a temperature elevation rate of 20 ° C / min. The glass transition temperature (Tg) was measured at the tangential intersection of displacement.

EXAMPLES Hereinafter, although an Example demonstrates this invention, this invention is not limited by these Examples.
Example 1
Polyester resin A composed of 100% by weight of ethylene terephthalate copolymer polyester copolymerized with 30% by mole of neopentyl glycol and 55% by weight of polyethylene terephthalate copolymer, 45% by weight of ethylene terephthalate copolymer polyester copolymerized with 30% by mole of neopentyl glycol Polyester resin B consisting of the above is melted at 285 ° C. by separate extruders, and this melt is joined by a composite adapter, extruded from a T die, and rapidly cooled by a cooling drum at 30 ° C. (B / A / B) 3 An unstretched sheet having a layer structure was obtained. Here, the intrinsic viscosity of the polyester resin A was 0.72 dL / g, and the intrinsic viscosity of the polyester resin B was 0.67 dL / g.

  The sheet was first stretched 3.7 times in the longitudinal direction at 90 ° C., then stretched 4.0 times in the transverse direction in the tenter, and then heat treated at 215 ° C. while performing a 3% relaxation treatment. A biaxially stretched polyester film having a thickness of 18 μm was obtained. The thickness ratio of each layer of B / A / B of this film was 1/2/1.

(Example 2)
Polyester resin A 35% by weight polyethylene terephthalate and 30% by mole of neopentyl glycol copolymerized ethylene terephthalate copolymer 65% by weight polyester, polyester resin B 70% by weight polyethylene terephthalate and 30% by mole neopentyl glycol A biaxially stretched polyester film having a thickness of 18 μm was obtained in the same manner as in Example 1 except that a mixture of 30% by weight of polymerized ethylene terephthalate copolymer polyester was used and the heat treatment temperature after biaxial stretching was 225 ° C. The intrinsic viscosity of the polyester resin A was 0.69 dL / g, and the intrinsic viscosity of the polyester resin B was 0.65 dL / g.

( Reference Example 1 )
Polyester resin B is a mixture of 60% by weight of polyethylene terephthalate, 30% by weight of ethylene terephthalate copolymer polyester copolymerized with 30% by mole of neopentyl glycol, and 10% by weight of polybutylene terephthalate, and the heat treatment temperature after biaxial stretching is 210 ° C. A biaxially stretched polyester film having a thickness of 18 μm was obtained in the same manner as in Example 2 except that. The intrinsic viscosity of the polyester resin B was 0.71 dL / g.

(Example 3 )
Polyester resin A is 100% by weight of ethylene terephthalate copolymer polyester copolymerized with 30% by mole of 1,4-cyclohexanedimethanol, polyester resin B is 70% by weight of polyethylene terephthalate, and 30% by mole of 1,4-cyclohexanedimethanol. A biaxially stretched polyester film having a thickness of 18 μm was obtained in the same manner as in Example 1 except that a copolymer of 30% by weight of copolymerized ethylene terephthalate copolymer polyester was used and the heat treatment temperature after biaxial stretching was 220 ° C. . The intrinsic viscosity of the polyester resin A was 0.72 dL / g, and the intrinsic viscosity of the polyester resin B was 0.65 dL / g.

(Reference Example 2 )
Ethylene terephthalate copolymer polyester 50 obtained by copolymerizing polyester resin A with 100% by weight of ethylene terephthalate copolymer polyester copolymerized with 20% by mole of isophthalic acid, polyester resin B with 50% by weight of polyethylene terephthalate, and 20% by mole of isophthalic acid. A biaxially stretched polyester film having a thickness of 18 μm was obtained in the same manner as in Example 1 except that the weight was% and the heat treatment temperature after biaxial stretching was 200 ° C. The intrinsic viscosity of the polyester resin A was 0.64 dL / g, and the intrinsic viscosity of the polyester resin B was 0.63 dL / g.

(Comparative Example 1)
Biaxial stretching with a thickness of 18 μm in the same manner as in Example 2 except that the polyester resin B is a mixture of 90% by weight of polyethylene terephthalate and 10% by weight of ethylene terephthalate copolymer polyester copolymerized with 30% by mole of neopentyl glycol. A polyester film was obtained. The intrinsic viscosity of the polyester resin B was 0.63 dL / g.

(Comparative Example 2)
Example 1 except that polyester resin A is a mixture of 20% by weight of polyethylene terephthalate and 80% by weight of ethylene terephthalate copolymer polyester copolymerized with 30% by mole of neopentyl glycol, and the heat treatment temperature after biaxial stretching is 190 ° C. In the same manner as above, a biaxially stretched polyester film having a thickness of 18 μm was obtained. The intrinsic viscosity of the polyester resin A was 0.70 dL / g.

(Comparative Example 3)
Polyester resin A 70% by weight of polyethylene terephthalate and 30% by mole of neopentyl glycol copolymerized 30% by weight of ethylene terephthalate copolymer polyester, polyester resin B 80% by weight of polyethylene terephthalate and 30% by mole of neopentyl glycol A biaxially stretched polyester film having a thickness of 18 μm was obtained in the same manner as in Example 1 except that a mixture of 20% by weight of polymerized ethylene terephthalate copolymer polyester was used and the heat treatment temperature after biaxial stretching was 180 ° C. The intrinsic viscosity of the polyester resin A was 0.65 dL / g, and the intrinsic viscosity of the polyester resin B was 0.64 dL / g.

(Comparative Example 4)
A biaxially stretched polyester film having a thickness of 18 μm was obtained in the same manner as in Reference Example 2 except that the heat treatment temperature was set to 170 ° C.

Table 1 shows the evaluation results of the films obtained in Examples 1, 2, and 3, Reference Examples 1 and 2, and Comparative Examples 1, 2, 3, and 4. As is clear from Table 1, the films obtained in Examples 1 , 2 , and 3 all had good twist retention. Moreover, heat resistance was also favorable. The biaxially stretched polyester film of the present invention has high quality and high practicality, and is suitable for twist packaging and folding packaging.

  On the other hand, all of the films obtained in Comparative Examples 1, 2, 3, and 4 have poor twist retention. Moreover, Comparative Examples 2 and 3 are also inferior in heat resistance. Thus, all the biaxially stretched polyester films obtained in the comparative examples were inferior in quality and low in practicality.

  As described above, the biaxially stretched polyester film of the present invention has been described based on a plurality of examples. However, the present invention is not limited to the configurations described in the above examples, and the configurations described in the respective examples are appropriately selected. The configuration can be changed as appropriate within a range not departing from the gist, such as a combination.

  The biaxially stretched polyester film of the present invention maintains practical characteristics without losing heat resistance, fragrance retention, water resistance, etc., which are excellent characteristics of the biaxially stretched polyester film, and has good twist retention and folding. Since it has bendability, it can be used in a wide range of application fields such as foods such as candy, chocolate, and tea, and individual packaging materials such as stationery, and contributes greatly to the industry.

Claims (4)

A polyester laminated film in which a polyester resin (B) layer is laminated on at least one surface of a polyester resin (A) layer, wherein the polyester resin (A) layer and the polyester resin (B) layer are used as a dicarboxylic acid component. terephthalic acid, ethylene glycol / neopentyl glycol copolymerized ing with polyester resin as the diol component or terephthalic acid as the dicarboxylic acid component, that Do by copolymerizing ethylene glycol / 1,4-cyclohexane dimethanol as the diol component Polyester resin or any one of the above polyester resins and polyethylene terephthalate, the polyester laminated film after biaxial stretching is at a temperature higher than the temperature at which the molecular orientation of the polyester resin (A) layer disappears, and less than the melting point of the polyester resin (B) layer of The polyester resin (A) layer has substantially no molecular orientation, the polyester resin (B) layer has molecular orientation, and the polyester laminated film has a refractive index Nx in the longitudinal direction and a width direction. The refractive index Ny of the film satisfies the formula | Nx−Ny | ≦ 0.001, the refractive index Nx in the longitudinal direction of the film is Nx ≦ 1.577, and the refractive index Nz in the thickness direction of the film is 1.490 ≦ A biaxially stretched polyester film for packaging, wherein Nz ≦ 1.550.   The polyester resin (A) layer is formed from a substantially non-crystalline polyester resin, and the polyester resin (B) layer is formed from a polyethylene terephthalate copolymer having a melting point of 200 to 250 ° C. Item 2. A biaxially stretched polyester film for packaging according to item 1.   The biaxially stretched polyester film for packaging according to claim 1 or 2, wherein the thermal shrinkage in the film longitudinal direction at 150 ° C is 5.0% or less.   A twist packaging body, wherein the biaxially stretched polyester film for packaging according to claim 1, 2 or 3 is obtained by twist-wrapping an article to be packaged.