JP4585231B2 - Household tissue paper - Google Patents
Household tissue paper Download PDFInfo
- Publication number
- JP4585231B2 JP4585231B2 JP2004146966A JP2004146966A JP4585231B2 JP 4585231 B2 JP4585231 B2 JP 4585231B2 JP 2004146966 A JP2004146966 A JP 2004146966A JP 2004146966 A JP2004146966 A JP 2004146966A JP 4585231 B2 JP4585231 B2 JP 4585231B2
- Authority
- JP
- Japan
- Prior art keywords
- pulp
- value
- paper
- weight
- ctmp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 102100031260 Acyl-coenzyme A thioesterase THEM4 Human genes 0.000 claims description 21
- 101000638510 Homo sapiens Acyl-coenzyme A thioesterase THEM4 Proteins 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 16
- 239000003963 antioxidant agent Substances 0.000 claims description 14
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 9
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 6
- -1 benzotrithianol Chemical compound 0.000 claims description 5
- 239000004611 light stabiliser Substances 0.000 claims description 4
- 229920001651 Cyanoacrylate Polymers 0.000 claims description 3
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 3
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 3
- SIWVEOZUMHYXCS-UHFFFAOYSA-N oxo(oxoyttriooxy)yttrium Chemical compound O=[Y]O[Y]=O SIWVEOZUMHYXCS-UHFFFAOYSA-N 0.000 claims description 3
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims description 3
- 239000002530 phenolic antioxidant Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229960004889 salicylic acid Drugs 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 239000000123 paper Substances 0.000 description 67
- 239000002994 raw material Substances 0.000 description 19
- 238000002156 mixing Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 9
- 238000004049 embossing Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- 238000005562 fading Methods 0.000 description 5
- 238000010009 beating Methods 0.000 description 4
- 238000004061 bleaching Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920005610 lignin Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 239000005445 natural material Substances 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000004902 Softening Agent Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 239000002655 kraft paper Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000011122 softwood Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000002013 dioxins Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000011121 hardwood Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 229940095676 wafer product Drugs 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Paper (AREA)
Description
本発明は、塩素等による漂白処理がされていない家庭用薄葉紙に関し、特にキッチンペーパー等に使用される無漂白のペーパータオルに関する。 The present invention relates to a household thin paper that is not bleached with chlorine or the like, and more particularly to an unbleached paper towel used for kitchen paper or the like.
ペーパータオルは、下記文献にも示されるとおり、食材や食器についた水分、油分の拭取り、揚げ物などの過剰油分の吸い取り、使用後の油こし等に用いられるキッチンペーパー、飲食店等の店舗における使い捨て手拭用タオルなどに用いられる。ペーパータオルは、塩素漂白など各種の方法で漂白処理された漂白パルプのみを原料とするもの、非常に安価なＮＵＫＰ（漂白処理をしていない針葉樹パルプをいう。以下、同じ）を原料とするものがあるが、ＮＵＫＰを原料とするペーパータオルは、漂白パルプを利用したペーパータオルと比較して白色度が格段に低く（通常は濃い茶色を呈しているものがほとんどである）、また柔らかさに劣るため、これまではＮＵＫＰを原料とするペーパータオルよりも漂白パルプを利用したペーパータオルのほうが格段に需要者に好まれる傾向にあった。特に、キッチンペーパー用途についてはこの傾向が顕著であった。そして、ＮＵＫＰを利用したペーパータオルは、主に高品質を必要としない用途、例えば大量消費される使い捨て手拭用タオル等としての需要がほとんどであった。 Paper towels are disposable in stores such as kitchen paper and restaurants used to wipe off excess oil such as fried foods, wipe off excess oil such as fried foods, as well as the following literature. Used for hand towels. Paper towels are made only from bleached pulp that has been bleached by various methods such as chlorine bleaching, and are made from very cheap NUKP (which means softwood pulp that has not been bleached; hereinafter the same). However, paper towels made from NUKP are much less white than paper towels using bleached pulp (usually most of them are dark brown), and are inferior in softness. So far, paper towels using bleached pulp have tended to be favored by consumers more than paper towels made from NUKP. In particular, this tendency was remarkable for kitchen paper applications. The paper towels using NUKP are mostly in demand for applications that do not require high quality, such as disposable towels for mass consumption.
しかし、近年では、漂白処理工程で使用する塩素が有害物質であるダイオキシン類の発生原因となることが指摘され、また、昨今の天然素材を原料とする製品が流行していることから、特に食材あるいは肌に直接触れる用途において、塩素等の漂白剤を使用していな未晒パルプを原料とするペーパータオルを使用したいとの要求が需要者の間で高まってきている。他方、飲食店等の店舗における使い捨て手拭用タオルの使用が一般的になりつつあり需要が急増してきたことから、これまで求められなかった柔らかさなどの製品の品質向上が求められるようになってきた。
しかし、上述のようにＮＵＫＰを原料とする従来のペーパータオルは、白色度が極めて低い。各種の拭取りに用いられるペーパータオルでは、ペーパータオル表面に付着した被拭取り物の状態を目視にて確認することにより、拭取りが行われたか不十分であったかを判断するのが一般的であり、白色度が高いほうがかかる確認をしやすいため、ペーパータオルでは高白色度であることが一般的には望まれる。しかし、需要者は、一般的に白いと感じるほどの高白色度のペーパータオルよりも、茶色を呈するペーパータオルのほうが天然素材である感じを受け、このような製品を漂白処理されていないペーパータオルとして好む傾向にある。したがって、原料パルプとして未晒パルプ（漂白処理していないパルプ）を用いつつ従来の濃い茶色から薄い茶色の色目にする、すなわち白色度を適当値向上させて、需要者に与える安全性、清潔感のイメージを損なうことなく、視認性を向上させることが要求される。 However, as described above, the conventional paper towel made of NUKP has a very low whiteness. In paper towels used for various types of wiping, it is common to determine whether wiping has been performed or insufficient by visually checking the state of the object to be wiped attached to the surface of the paper towel, Higher whiteness is generally desirable for paper towels because higher whiteness is easier to check. However, consumers generally feel that brown paper towels are more natural than paper towels that are white enough to feel white, and prefer these products as unbleached paper towels. It is in. Therefore, while using unbleached pulp (raw pulp that has not been bleached) as the raw material pulp, the conventional dark brown to light brown color is changed, that is, the whiteness is increased to an appropriate value, giving the customer safety and cleanliness. It is required to improve the visibility without damaging the image.
そこで、本発明の主たる課題は、塩素などによる漂白処理を行っていない未晒パルプを原料とするペーパータオルにおける白色度の向上を図り、さらに柔らかさの向上をも図り、もって従来製品よりも白色度が高くかつやわらかい未晒パルプを原料とするペーパータオルを提供することにある。 Therefore, the main problem of the present invention is to improve the whiteness of paper towels made from unbleached pulp that has not been bleached with chlorine or the like, and to further improve the softness. The object is to provide a paper towel made from unbleached pulp which is high and soft.
上記課題を解決した本発明は次記のとおりである。
＜請求項１記載の発明＞
漂白処理が施されていない未晒パルプのみを原料パルプとし、
前記未晒パルプは、ＬＵＫＰを４０重量％以上、ＣＴＭＰを１０〜１５重量％含み、
前記原料パルプに対して紫外線吸収剤及び酸化防止剤の少なくとも一方が１〜３重量％含有され、
その紫外線吸収剤が、サリチル酸系、ベンゾフェノン系、ベンゾトリチアノール系、シアノアクリレート系、酸化亜鉛、酸化セリウム、酸化チタン、酸化イットリウムのうち、少なくとも１種以上からなり、
酸化防止剤が、フェノール系酸化防止剤、リン系酸化防止剤、硫黄系酸化防止剤、ヒンダードアミ系光安定剤のうち、少なくとも１種以上からなる、
ことを特徴とする家庭用薄葉紙。
The present invention that has solved the above problems is as follows.
<Invention of Claim 1>
Only unbleached pulp that has not been bleached is used as raw pulp,
The unbleached pulp contains 40% by weight or more of LUKP, 10-15% by weight of CTMP,
At least one of an ultraviolet absorber and an antioxidant is contained in an amount of 1 to 3% by weight with respect to the raw pulp,
The ultraviolet absorber comprises at least one of salicylic acid, benzophenone, benzotrithianol, cyanoacrylate, zinc oxide, cerium oxide, titanium oxide, yttrium oxide,
Antioxidant consists of at least one or more of phenolic antioxidants, phosphorus antioxidants, sulfur antioxidants, hindered light stabilizers,
A thin paper for household use.
＜請求項２記載の発明＞
ＪＩＳ Ｚ ８７３０で規定されるハンター色差式においてＤ＝（Ｌ2＋ａ2＋ｂ2）1/2におけるＤの値が１５以上、Ｌの値が１０〜８０、ａの値が−１０〜２、ｂの値が−１０〜３０である請求項１記載の家庭用薄葉紙。
<Invention of Claim 2>
In the Hunter color difference formula defined by JIS Z 8730, the value of D at D = (L 2 + a 2 + b 2 ) 1/2 is 15 or more, the value of L is 10 to 80, the value of a is −10 to 2, b The household thin paper according to claim 1, wherein the value of -10 is -10 to 30.
＜請求項３記載の発明＞
ＪＩＳ Ｌ １０９６Ｅに基づくハンドルオメーター法によるソフトネスの値が３〜２０ｇである請求項１又は２記載の家庭用薄葉紙。
<Invention of Claim 3>
The household thin paper according to claim 1 or 2, wherein a softness value according to a handle ohm method based on JIS L 1096E is 3 to 20 g.
＜請求項４記載の発明＞
幅方向の少なくとも２０％以上の領域に、かつ、長手方向に対して連続的にまたは間欠的にエンボス加工が施されている請求項１〜３の何れか１項に記載の家庭用薄葉紙。
<Invention of Claim 4>
The household thin paper according to any one of claims 1 to 3, wherein at least 20% or more of the width direction is embossed continuously or intermittently with respect to the longitudinal direction.
漂白処理していない未晒パルプを原料とする家庭用薄葉紙により、天然素材である感じを呈しつつ白色度の向上を図られるペーパータオルを製造することができる。 By using household thin paper made from unbleached pulp that has not been bleached, it is possible to produce a paper towel that can improve whiteness while exhibiting the feeling of being a natural material.
また、ＬＵＫＰ（漂白処理していない広葉樹クラフトパルプ）はＮＵＫＰ（漂白処理していない針葉樹クラフトパルプ）と比較して白色度低下の原因となるリグニンの含有量が低いため、これを含む原料パルプを抄紙してなるものとすれば、天然素材である感じを呈しつつ白色度を従来製品より向上することができる。 In addition, LUKP (unbleached hardwood kraft pulp) has a lower content of lignin that causes a decrease in whiteness than NUKP (unbleached softwood kraft pulp). If it is made from paper, the whiteness can be improved over the conventional product while presenting the feeling of being a natural material.
他方、ＪＩＳ Ｚ ８７３０で規定されるハンター色差式においてＤ＝（Ｌ2＋ａ2＋ｂ2）1/2におけるＤの値が１５以上、Ｌの値が１０〜８０、ａの値が−１０〜２、ｂの値が−１０〜３０であると従来製品より格段に白色度が高いものであり、拭取り時の確認性に優れる。 On the other hand, in the Hunter color difference formula defined by JIS Z 8730, the value of D at D = (L 2 + a 2 + b 2 ) 1/2 is 15 or more, the value of L is 10 to 80, and the value of a is −10 to 2 When the value of b is -10 to 30, the whiteness is remarkably higher than that of the conventional product, and the confirmation at the time of wiping is excellent.
他方、前記原料パルプ中にＣＴＭＰ（ケミサーモメカニカルパルプ）を５〜５０重量％含有せしめるとより柔らかいものとなる。 On the other hand, when 5 to 50% by weight of CTMP (chemothermomechanical pulp) is contained in the raw material pulp, it becomes softer.
ＪＩＳ Ｌ １０９６Ｅに基づくハンドルオメーター法によるソフトネスの値が３〜２０ｇであるものは拭取りに好適な柔らかさ（拭取り操作をしやすくかつ柔らかな感じ）を示す。 Those having a softness value of 3 to 20 g by the handle ohm method based on JIS L 1096E exhibit softness suitable for wiping (easy to perform wiping operation and soft feeling).
紫外線吸収剤および酸化防止剤の少なくとも一方を、原料パルプに添加したのち抄紙してなるものとすると、耐候性に優れたものとなる。 When at least one of the ultraviolet absorber and the antioxidant is added to the raw material pulp and then paper is made, the weather resistance is excellent.
エンボスが付与されたものは、需要者に厚み感、ふんわり感を与える。また、原料パルプに対して柔軟剤を０．０１〜１重量％添加すれば、より柔らかいものとなる。 Those with embossing give the consumer a sense of thickness and softness. Moreover, if a softening agent is added 0.01 to 1 weight% with respect to raw material pulp, it will become a softer thing.
また、本発明における家庭用薄葉紙の原料パルプはすべて未晒パルプである。 In addition, all the raw pulp of household thin paper in the present invention is unbleached pulp.
次いで、本発明の実施の形態を以下に詳述する。
本発明の家庭用薄葉紙は、漂白処理が施されていないパルプを原料とする。また、その原料パルプは、ＬＵＫＰを含むものであり、ＬＵＫＰ以外のパルプも未晒パルプを用いる。ＬＵＫＰは原料パルプ中に４０重量％以上、特に好適には７０重量％以上含む。ＬＵＫＰ以外の未晒パルプとしては、例えばＮＵＫＰなど漂白処理をしていない適宜のパルプを用いることができる。
Next, embodiments of the present invention will be described in detail below.
The thin paper for household use of the present invention is made from pulp that has not been bleached. Moreover, the raw material pulp contains LUKP, and unbleached pulp is also used for pulp other than LUKP. LUKP is contained in the raw pulp at 40% by weight or more, particularly preferably 70% by weight or more. As the unbleached pulp other than LUKP, for example, an appropriate pulp that has not been bleached, such as NUKP, can be used.
柔らかさおよび吸収性を発現させるためには、原料パルプ中にＣＴＭＰを１５〜３０重量％含有せしめる。ＣＴＭＰは結束繊維が少ないためかかる範囲で含有せしめると、ＬＵＫＰ繊維と良好に絡み合い柔らかさが向上する。なお、ＣＴＭＰによる柔らかさの発現は５重量％未満ではほとんどなく、また５０重量％を越えるとペーパータオルとして使用するさいに好適なコシを担保するのが困難となる。ここで、ＣＴＭＰは結束繊維が少ないことから叩解せずあるいは叩解度を低くして用いることができる。したがって、ＣＴＭＰを原料パルプに配合するにあたっては、上記ＬＵＫＰやＮＵＫＰなどの他の未晒パルプあるいはこれらの混合パルプの叩解処理を行ったのちに、ＣＴＭＰを別叩解あるいは未叩解で混合して原料パルプとするのが好適である。このように配合すると、ＣＴＭＰが不要に叩解されることがなく嵩だか感のあるペーパータオルにもなる。 In order to express softness and absorbability, the raw material pulp contains CTMP in an amount of 15 to 30% by weight. Since CTMP contains few binding fibers, if incorporated in such a range, it will be well entangled with LUKP fibers to improve softness. In addition, the expression of the softness by CTMP is hardly less than 5% by weight, and when it exceeds 50% by weight, it is difficult to secure a firmness suitable for use as a paper towel. Here, CTMP can be used without beating or having a low beating degree because it has few binding fibers. Therefore, when blending CTMP into the raw pulp, after the other unbleached pulp such as LUKP and NUKP or a mixed pulp thereof is beaten, the CTMP is mixed separately or unbeaten to obtain the raw pulp Is preferable. When blended in this way, CTMP is not beaten unnecessarily, and it becomes a paper towel with a feeling of bulk.
本発明のペーパータオルの抄紙方法は特に限定されないが、坪量１０〜４０ｇ／ｍ2程度に調整する。従来技術にしたがって、各種抄紙機を用いて抄紙することができる。なお、原料パルプのパルプ組成とペーパータオルのパルプ組成とはほぼ同様であり、ペーパータオル中のパルプ組成はＪＩＳ Ｐ ８１２０により測定することが可能である。 Papermaking process of paper towels of the present invention is not particularly limited, but adjusted to about basis weight of 10 to 40 g / m 2. Paper making can be performed using various paper machines according to the prior art. The pulp composition of the raw material pulp and the pulp composition of the paper towel are almost the same, and the pulp composition in the paper towel can be measured according to JIS P 8120.
また、本発明においては、原料パルプ中には適宜柔軟剤や界面活性剤を添加することができる。柔軟剤の例示としては、脂肪酸エステル系軟化剤（米国特許第３２９６０６５号明細書）、第４級アンモニウム塩型カチオン活性剤（特開昭４８−２２７０１号公報）、ウレタンアルコールもしくはその塩、またはカチオン化合物（特開昭６０−１３９８９７号公報）、非陽イオン系界面活性剤（特開平２−９９６９０号公報）、ポリシロキサン（特開平２−２２４６２６号公報、同３−９００号公報）等がある。柔軟剤の添加量は、パルプ１トンあたり５．０ｋｇ以下とするのが望ましい。 In the present invention, a softener and a surfactant can be appropriately added to the raw material pulp. Examples of softeners include fatty acid ester softeners (US Pat. No. 3,296,065), quaternary ammonium salt type cationic activators (Japanese Patent Laid-Open No. 48-22701), urethane alcohols or salts thereof, or cations. Compounds (Japanese Patent Laid-Open No. 60-139897), non-cationic surfactants (Japanese Patent Laid-Open No. 2-99690), polysiloxanes (Japanese Patent Laid-Open Nos. 2-224626 and 3-900), and the like. . The addition amount of the softening agent is desirably 5.0 kg or less per ton of pulp.
本発明にかかるペーパータオルは、ＪＩＳ Ｚ ８７３０で規定されるハンター色差式においてＤ＝（Ｌ2＋ａ2＋ｂ2）1/2におけるＤの値が１５以上、Ｌの値が１０〜８０、ａの値が−１０〜２、ｂの値が−１０〜３０であるのが望ましい。かかる範囲であると、従来例と未晒パルプを原料とするペーパータオルと比較して観者が白いと感じるものであり、使用者が拭取りに使用したときに拭取り具合を視識しやすく、また、高級感もあるものとなる。ここで、Ｄの値が１５未満であると白色度が低く拭取り時の視認性に劣るようになる。また、Ｌ値が１０未満であるとくすんだ感じになり、８０を越えるとあざやかさがあり天然素材感が得られなくなる。なお、ハンター色差式であらわされる上記各値は、従来既知の分光測色計等により測定することができる。 The paper towel according to the present invention has a D value of 15 or more, a value of L of 10 to 80, and a value of D = (L 2 + a 2 + b 2 ) 1/2 in the Hunter color difference formula defined in JIS Z 8730. Is preferably −10 to 2, and b is preferably −10 to 30. In such a range, the viewer feels white compared to the conventional example and a paper towel made from unbleached pulp, and when the user uses it for wiping, it is easy to see the wiping condition, In addition, there is a sense of quality. Here, when the value of D is less than 15, the degree of whiteness is low and the visibility at the time of wiping is inferior. Further, if the L value is less than 10, it becomes dull, and if it exceeds 80, there is vividness and a natural material feeling cannot be obtained. In addition, each said value represented by a Hunter color difference type | formula can be measured with a conventionally known spectrocolorimeter etc.
他方、本発明にかかるペーパータオルは、ＪＩＳ Ｌ １０９６Ｅに基づくハンドルオメーター法によるソフトネスの値が３〜２０ｇ、好ましくは４〜１５ｇ、特に好適には５〜１０ｇであるのが望ましい。ソフトネスの値が３ｇ未満であるとコシが発現しづらく拭取り性が悪化し、２０ｇを越えると硬く拭取り性が悪化する。かかるソフトネスの調整は、上述の本発明にかかるＬＵＫＰの配合割合、ＣＴＭＰの配合割合の範囲で各パルプの配合割合を適宜調整することおよび適宜の坪量の調整により達成することができる。 On the other hand, the paper towel according to the present invention desirably has a softness value of 3 to 20 g, preferably 4 to 15 g, particularly preferably 5 to 10 g according to a handle ohm method based on JIS L 1096E. If the softness value is less than 3 g, the wiping property is difficult to develop, and if it exceeds 20 g, the wiping property is hard and deteriorates. Such softness adjustment can be achieved by appropriately adjusting the blending ratio of each pulp within the range of the blending ratio of LUKP according to the present invention and the blending ratio of CTMP and adjusting the basis weight.
他方、本発明にかかるペーパータオルは、原料パルプ中に紫外線吸収剤および酸化防止剤の少なくとも一方を含有せしめる。添加量としては、１〜３重量％含有せしめる。本発明のペーパータオルは、従来例の未晒パルプを原料とするものと比較すれば格段に少ない量ではあるがリグニンが含まれている。リグニンは光酸化などの酸化により黄色あるいは茶色に変色するので、これが含まれていると経時的に白色度の後退が見られる。すなわち退色する。このような退色は製品の使用に影響がなくても需要者に対して品質低下したとの感じを与える。紫外線吸収剤あるいは酸化防止剤を適当量添加することにより、このようなリグニンの酸化による退色が防止され、従来にない白色度がより長期に渡って維持される。 On the other hand, the paper towel according to the present invention contains at least one of an ultraviolet absorber and an antioxidant in the raw material pulp. As addition amount, it is made to contain 1-3 weight%. The paper towel of the present invention contains lignin although it is a much smaller amount than that of a conventional example using unbleached pulp as a raw material. Lignin turns yellow or brown due to oxidation such as photo-oxidation, and if it is included, the whiteness is retreated over time. That is, it fades. Such discoloration gives the customer a feeling that the quality has deteriorated without affecting the use of the product. By adding an appropriate amount of an ultraviolet absorber or an antioxidant, such fading due to oxidation of lignin is prevented, and unprecedented whiteness is maintained for a longer period.
酸化防止剤としては熱や酸素による酸化を防止するフェノール系酸化防止剤、リン系酸化防止剤、硫黄系酸化防止剤と、ＨＡＬＳ（Hindered Amine Light Stabilizer）と呼ばれるヒンダードアミン系光安定剤が挙げられる。 Examples of antioxidants include phenolic antioxidants that prevent oxidation due to heat and oxygen, phosphorus antioxidants, sulfur antioxidants, and hindered amine light stabilizers called HALS (Hindered Amine Light Stabilizer).
紫外線吸収剤としては、有機系、無機系のものが例示できる。有機系、無機系のものが例示できる。有機系のものとしては、サリチル酸系、ベンゾフェノン系、ベンゾトリチアゾール系、シアノアクリート系、公知のものが挙げられる。無機系の紫外線吸収剤としては酸化亜鉛、酸化セリウム、酸化チタン、酸化イットリウム等の遷移金属酸化物が適宜使用できる。 Examples of the ultraviolet absorber include organic and inorganic ones. Organic and inorganic materials can be exemplified. Examples of the organic type include salicylic acid type, benzophenone type, benzotrithiazole type, cyanoacrylate type, and known ones. As the inorganic ultraviolet absorber, transition metal oxides such as zinc oxide, cerium oxide, titanium oxide, yttrium oxide can be appropriately used.
また、本発明にかかるペーパータオルは、エンボス加工が付与されているものであると、使用者に厚み感を与えるものとなるとともに、拭取り性能が向上する。エンボス加工方法については特に限定されえず、従来既知のエンボス付与方法に従って適宜付与すればよい。例えば、湿紙あるいは乾紙に対してエンボスロールを押圧して付与する方法をとることができる。 Moreover, the paper towel concerning this invention will give a user a feeling of thickness, and the wiping performance improves that embossing is provided. The embossing method is not particularly limited, and may be appropriately applied according to a conventionally known embossing method. For example, the embossing roll can be pressed and applied to wet paper or dry paper.
他方、本発明にかかるペーパータオルの形状等については特に限定されるものではない、いわゆるロール巻きタイプであってもよいし、枚葉タイプであってもよい。また、１プライであってもよいし２プライ（二枚重ね）のものであってもよい。これらは、従来既知の技術にしたがって、適宜の形状にすればよい。 On the other hand, the shape of the paper towel according to the present invention is not particularly limited, and may be a so-called roll type or a single wafer type. Further, it may be one ply or two plies (double stack). These may be appropriately shaped according to a conventionally known technique.
また、本発明にかかるペーパータオルは、エンボス加工が施されていてもよい。エンボス加工を施すのであれば、製品の幅方向の２０％の領域であって、かつ長手方向に連続的にまたは間欠的に施されているのが望ましい。なお、枚葉の製品の場合の幅方向とは製品時における短手方向であり、ロール製品の幅方向とは引き出し方向に対して直行する方向である。 Moreover, the paper towel concerning this invention may be embossed. If embossing is performed, it is desirable that the region is 20% in the width direction of the product and is continuously or intermittently applied in the longitudinal direction. In addition, the width direction in the case of a single wafer product is a short direction at the time of product, and the width direction of the roll product is a direction perpendicular to the drawing direction.
本発明にかかるペーパータオルは、漂白処理を行わない未晒パルプを原料とすることから排水中に漂白処理を含まない。
＜試験例１＞
Since the paper towel according to the present invention uses unbleached pulp that is not subjected to bleaching as a raw material, the wastewater does not include bleaching.
<Test Example 1>
次いで、試験例を以下に詳述する。
試験例１（ＬＵＫＰ、ＮＵＫＰ及びＣＴＭＰを原料パルプとするペーパータオル）、比較例１（ＮＵＫＰ、ＬＵＫＰを原料パルプとするペーパータオル）、従来製品１（市販に供されている漂白パルプを原料とするペーパータオル）および従来製品２（市販に供されている未晒パルプを原料とするペーパータオル）について、ソフトネス、色差、耐候性について比較試験を行った。なお、各試験例および比較例のＪＩＳ Ｐ ８１２４に規定される米坪は全て２１ｇ／ｍ2に調整した。
Next, test examples are described in detail below.
Test Example 1 (paper towel using LUKP, NUKP and CTMP as raw material pulp ) , Comparative Example 1 ( paper towel using NUKP and LUKP as raw material pulp ), conventional product 1 (paper towel using raw material bleached pulp) and with the conventional product 2 (paper towels unbleached pulp that has been subjected to commercial as a raw material), softness, color difference, Comparative tests have been carried out for weather resistance. In addition, all the rice tsubo prescribed | regulated to JISP8124 of each test example and a comparative example was adjusted to 21 g / m < 2 >.
試験例１、比較例１及び各従来製品についての物性の測定方法および試験方法は下記のとおりであり、結果は表１に示す。
［ソフトネス］
ＪＩＳ Ｌ １０９６Ｅに基づいてハンドルオメーター法により測定した。
［色差］
分光色彩・白色度計を用いて、ＪＩＳ Ｚ ８７３０に基づいて測定した。
［耐候性］
各資料に対して、２０℃、９０％ＲＨの条件下でキセノンウェザーメーターにより放射照度２００Ｗで紫外線（波長：３００ｎｍ）を１００時間照射したのち、試料表面の色の変化（退色具合）を目視にて確認した。表中の評価は、○：退色は確認できなかった、△：やや退色が見られる、×：はっきりと退色しているのが確認できる、をそれぞれ表す。
The physical property measurement methods and test methods for Test Example 1, Comparative Example 1 and each conventional product are as follows, and the results are shown in Table 1.
[Softness]
It measured by the handle ohm method based on JISL1096E.
[Color difference]
It measured based on JISZ8730 using the spectral color and whiteness meter.
[Weatherability]
Each sample was irradiated with ultraviolet rays (wavelength: 300 nm) with a irradiance of 200 W for 100 hours using a xenon weather meter under the conditions of 20 ° C. and 90% RH, and then the color change (fading condition) of the sample surface was visually observed. Confirmed. The evaluations in the table represent ◯: no fading was observed, Δ: some fading was observed, and X: clear fading was confirmed.
表１からもみてとれるように、試験例１のペーパータオルは、従来製品２（未晒パルプを原料としたもの）と比較して白色度が高くまた耐候性に優れしかも柔らかさも同等かそれ以上である。また、塩素漂白処理をしている漂白パルプを原料とする従来製品１と比較して環境負荷の低いものである。してみると、試験例１のペーパータオルは環境に与える影響がなくまた白色度が高く、しかも柔らかさが発現しやすく、耐候性が向上されることが理解される。
＜試験例２＞
As can be seen from Table 1, the paper towel of Test Example 1 has higher whiteness and excellent weather resistance than the conventional product 2 (made from unbleached pulp), and the softness is equal to or higher than that. . Moreover, it is a thing with a low environmental impact compared with the conventional product 1 which uses the bleached pulp which is chlorine-bleached as a raw material. As a result, it is understood that the paper towel of Test Example 1 has no influence on the environment, has high whiteness, easily develops softness, and has improved weather resistance .
<Test Example 2>
ＣＴＭＰの配合の仕方および割合等の効果について検討した。原料の配合割合および調整手順を変更して６種類の試料を作成し、各資料について物性等を測定した。試料１〜試料６の原料および調整手順は表２に示す。試料の調整については、表２中の手順の欄の（Ａ）〜（Ｇ）の順に操作して調整した。なお、表中のヤング率は、ＳＳＴにより測定した超音波伝播速度より算出し、試料１を１００として基準とした。 The effects of the method and proportion of CTMP were examined. Six types of samples were prepared by changing the mixing ratio of raw materials and the adjustment procedure, and the physical properties and the like of each material were measured. Table 2 shows the raw materials and preparation procedures of Sample 1 to Sample 6. About adjustment of the sample, it adjusted by operating in order of (A)-(G) of the column of the procedure in Table 2. The Young's modulus in the table was calculated from the ultrasonic propagation velocity measured by SST, and the sample 1 was taken as 100 as a reference.
試料１と試料２とを比較してみると、試料２のほうが比容積（嵩）が高い。すなわち、ＣＴＭを配合していない場合より、他のパルプとＣＴＭＰ混合（ＣＴＭＰ配合割合１５重量％）したのちに叩解したほうが嵩だかにできる。 When sample 1 and sample 2 are compared, sample 2 has a higher specific volume (bulk). That is, it is more bulky to beat after mixing with other pulp and CTMP (CTMP blending ratio of 15% by weight) than when CTM is not blended.
また、試料１〜試料３を比較すると、試料１→３の順に比容積（嵩）が高くなっている。すなわち、ＣＴＭＰの配合割合を増加させると嵩だかなる。 Further, when Samples 1 to 3 are compared, the specific volume (bulk) increases in the order of Sample 1 → 3. That is, when the blending ratio of CTMP is increased, it becomes bulky.
さらに、試料２と試料５とを比較してみると、試料５のほうが比容積（嵩）が高い。他のパルプとともに叩解するよりも未叩解のほうが嵩だかとなる。 Furthermore, when the sample 2 and the sample 5 are compared, the sample 5 has a higher specific volume (bulk). Unbeaten is more bulky than beating with other pulp.
他方、紙力について、試料１〜３を比較してみると、ＣＴＭＰの添加による紙力の低下はほとんど見られない、むしろ向上している。また、試料５は、試料１〜試料３と比較して紙力は若干低いが十分な数値である。ＣＴＭＰを未叩解で配合しても紙力の低下がほとんどないことが解る。 On the other hand, when the samples 1 to 3 are compared with respect to the paper strength, a decrease in paper strength due to the addition of CTMP is hardly seen, but rather improved. Sample 5 has a slightly lower paper strength than Samples 1 to 3, but is a sufficient value. It can be seen that there is almost no decrease in paper strength even when CTMP is blended without beating.
他方、試料５と試料６とを比較すると試料５のほうが紙力が高い。すなわち、界面活性剤の添加については、ＣＴＭＰ添加後に添加したほうが好ましい。 On the other hand, when Sample 5 and Sample 6 are compared, Sample 5 has higher paper strength. That is, it is preferable to add the surfactant after adding CTMP.
以上のように、ＣＴＭＰの配合割合および添加方法によって適宜、紙力、比容積など効果が相違することが確認できるが、試料１〜試料６のいずれもペーパータオル製品としては十分な性能である。なお、コスト面をも考慮すると未叩解でＣＴＭＰを添加する試料５が好適である。 As described above, it can be confirmed that the effects such as paper strength and specific volume are appropriately different depending on the blending ratio and addition method of CTMP. However, all of Sample 1 to Sample 6 have sufficient performance as a paper towel product. In view of cost, the sample 5 to which CTMP is added without being beaten is preferable.
本発明は、家庭用薄葉紙、特にキッチンペーパー、クッキングペーパーなどの、各種拭取りの用途等に用いられるペーパータオルに利用することができる。 INDUSTRIAL APPLICABILITY The present invention can be used for paper towels used for various wiping applications such as household thin paper, particularly kitchen paper and cooking paper.
Claims (4)
前記未晒パルプは、ＬＵＫＰを４０重量％以上、ＣＴＭＰを１０〜１５重量％含み、
前記原料パルプに対して紫外線吸収剤及び酸化防止剤の少なくとも一方が１〜３重量％含有され、
その紫外線吸収剤が、サリチル酸系、ベンゾフェノン系、ベンゾトリチアノール系、シアノアクリレート系、酸化亜鉛、酸化セリウム、酸化チタン、酸化イットリウムのうち、少なくとも１種以上からなり、
酸化防止剤が、フェノール系酸化防止剤、リン系酸化防止剤、硫黄系酸化防止剤、ヒンダードアミ系光安定剤のうち、少なくとも１種以上からなる、
ことを特徴とする家庭用薄葉紙。 Only unbleached pulp that has not been bleached is used as raw pulp,
The unbleached pulp contains 40% by weight or more of LUKP, 10-15% by weight of CTMP,
At least one of an ultraviolet absorber and an antioxidant is contained in an amount of 1 to 3% by weight with respect to the raw pulp,
The ultraviolet absorber comprises at least one of salicylic acid, benzophenone, benzotrithianol, cyanoacrylate, zinc oxide, cerium oxide, titanium oxide, yttrium oxide,
Antioxidant consists of at least one or more of phenolic antioxidants, phosphorus antioxidants, sulfur antioxidants, hindered light stabilizers,
A thin paper for household use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004146966A JP4585231B2 (en) | 2004-05-17 | 2004-05-17 | Household tissue paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2004146966A JP4585231B2 (en) | 2004-05-17 | 2004-05-17 | Household tissue paper |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005325493A JP2005325493A (en) | 2005-11-24 |
| JP2005325493A5 JP2005325493A5 (en) | 2007-02-15 |
| JP4585231B2 true JP4585231B2 (en) | 2010-11-24 |
Family
ID=35472043
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004146966A Expired - Fee Related JP4585231B2 (en) | 2004-05-17 | 2004-05-17 | Household tissue paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4585231B2 (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4916830B2 (en) * | 2006-09-27 | 2012-04-18 | 大王製紙株式会社 | Sanitary thin paper |
| JP5352102B2 (en) * | 2008-03-25 | 2013-11-27 | 大王製紙株式会社 | napkin |
| JP5305986B2 (en) * | 2009-02-27 | 2013-10-02 | 大王製紙株式会社 | Sanitary tissue paper |
| JP2011051613A (en) * | 2009-08-31 | 2011-03-17 | Daio Paper Corp | Sanitary tissue paper product |
| JP5755464B2 (en) * | 2011-02-28 | 2015-07-29 | 大王製紙株式会社 | Liquid absorbing sheet manufacturing method and liquid absorbing sheet |
| PT115563B (en) | 2019-06-03 | 2022-02-01 | Raiz Instituto De Investig Da Floresta E Papel | RAW EUCALYPTUS GLOBULUS CELLULOSIC PASTE FOR TISSUE PAPER PRODUCTS |
Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05503553A (en) * | 1989-12-28 | 1993-06-10 | ザ、プロクター、エンド、ギャンブル、カンパニー | Cellulose fiber modified with poly(methyl vinyl ether co-maleate) and polyol |
| JPH07500641A (en) * | 1991-11-01 | 1995-01-19 | ザ、プロクター、エンド、ギャンブル、カンパニー | Flexible absorbent tissue paper with high permanent wet strength |
| JPH1193095A (en) * | 1997-09-19 | 1999-04-06 | Eight:Kk | Highly water-absorbing sheet and its production |
| JPH11189959A (en) * | 1997-12-26 | 1999-07-13 | Uni Charm Corp | Nonwoven fabric and production of the same |
| JP2000239953A (en) * | 1999-02-19 | 2000-09-05 | Oji Packaging Systems Co Ltd | Wet fiber sheet and mat product |
| JP2001098481A (en) * | 1999-09-27 | 2001-04-10 | Toyo Media Relations:Kk | Method for manufacturing paper product and toilet tissue paper |
| JP2001159089A (en) * | 1999-11-29 | 2001-06-12 | Crecia Corp | Sanitary paper in which good-quality cellulosic fiber taken out from plastic-coated paper raw material is highly formulated |
| JP2001207399A (en) * | 2000-01-21 | 2001-08-03 | Lion Corp | Kitchen paper |
| JP2002046245A (en) * | 2000-08-01 | 2002-02-12 | Crecia Corp | Highly water absorbable paper |
| JP2002511537A (en) * | 1998-04-15 | 2002-04-16 | キンバリー クラーク ワールドワイド インコーポレイテッド | Bulky paper |
| JP2002325697A (en) * | 2001-05-02 | 2002-11-12 | Uni Charm Corp | Wet wiper containing antiseptic and mildew-proof composition |
| JP2002327398A (en) * | 2002-04-24 | 2002-11-15 | Sogo Musen:Kk | Mixing of small amount of strongly antibacterial titanium oxide as means for ensuring sanitation of paper article produced from pulp fiber as raw material, such as kitchen paper for household use, toilet paper, make-up paper, or tissue paper, to ensure antibacterial property and good skin touch |
| JP2003342899A (en) * | 2002-05-24 | 2003-12-03 | Daio Paper Corp | Sanitary tissue paper and method for producing sanitary tissue paper |
| JP2004044058A (en) * | 2002-05-22 | 2004-02-12 | Seiko Pmc Corp | Softening agent for paper, method for producing paper by using the same and paper |
| WO2005054577A1 (en) * | 2003-12-02 | 2005-06-16 | Daio Paper Corporation | Colored sanitary tissue paper and process for producing the same |
| JP2005204868A (en) * | 2004-01-22 | 2005-08-04 | Daio Paper Corp | Tissue paper for household use |
-
2004
- 2004-05-17 JP JP2004146966A patent/JP4585231B2/en not_active Expired - Fee Related
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05503553A (en) * | 1989-12-28 | 1993-06-10 | ザ、プロクター、エンド、ギャンブル、カンパニー | Cellulose fiber modified with poly(methyl vinyl ether co-maleate) and polyol |
| JPH07500641A (en) * | 1991-11-01 | 1995-01-19 | ザ、プロクター、エンド、ギャンブル、カンパニー | Flexible absorbent tissue paper with high permanent wet strength |
| JPH1193095A (en) * | 1997-09-19 | 1999-04-06 | Eight:Kk | Highly water-absorbing sheet and its production |
| JPH11189959A (en) * | 1997-12-26 | 1999-07-13 | Uni Charm Corp | Nonwoven fabric and production of the same |
| JP2002511537A (en) * | 1998-04-15 | 2002-04-16 | キンバリー クラーク ワールドワイド インコーポレイテッド | Bulky paper |
| JP2000239953A (en) * | 1999-02-19 | 2000-09-05 | Oji Packaging Systems Co Ltd | Wet fiber sheet and mat product |
| JP2001098481A (en) * | 1999-09-27 | 2001-04-10 | Toyo Media Relations:Kk | Method for manufacturing paper product and toilet tissue paper |
| JP2001159089A (en) * | 1999-11-29 | 2001-06-12 | Crecia Corp | Sanitary paper in which good-quality cellulosic fiber taken out from plastic-coated paper raw material is highly formulated |
| JP2001207399A (en) * | 2000-01-21 | 2001-08-03 | Lion Corp | Kitchen paper |
| JP2002046245A (en) * | 2000-08-01 | 2002-02-12 | Crecia Corp | Highly water absorbable paper |
| JP2002325697A (en) * | 2001-05-02 | 2002-11-12 | Uni Charm Corp | Wet wiper containing antiseptic and mildew-proof composition |
| JP2002327398A (en) * | 2002-04-24 | 2002-11-15 | Sogo Musen:Kk | Mixing of small amount of strongly antibacterial titanium oxide as means for ensuring sanitation of paper article produced from pulp fiber as raw material, such as kitchen paper for household use, toilet paper, make-up paper, or tissue paper, to ensure antibacterial property and good skin touch |
| JP2004044058A (en) * | 2002-05-22 | 2004-02-12 | Seiko Pmc Corp | Softening agent for paper, method for producing paper by using the same and paper |
| JP2003342899A (en) * | 2002-05-24 | 2003-12-03 | Daio Paper Corp | Sanitary tissue paper and method for producing sanitary tissue paper |
| WO2005054577A1 (en) * | 2003-12-02 | 2005-06-16 | Daio Paper Corporation | Colored sanitary tissue paper and process for producing the same |
| JP2005204868A (en) * | 2004-01-22 | 2005-08-04 | Daio Paper Corp | Tissue paper for household use |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005325493A (en) | 2005-11-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4250057B2 (en) | Household hygiene tissue paper | |
| JP4762846B2 (en) | Household tissue paper and its manufacturing method | |
| EP1861544B1 (en) | High quality paperboard and products made thereof | |
| CA2387822C (en) | Fibers from plant seeds and use | |
| EP3302201B1 (en) | Soft tissue comprising non-wood fibers | |
| JP4585231B2 (en) | Household tissue paper | |
| WO2011114529A1 (en) | Low basis weight tipping paper and cigarette with filter | |
| JP4313354B2 (en) | Cardboard exterior liner | |
| JP2005325493A5 (en) | ||
| JP2006320688A (en) | Toilet rolling for shower toilet seat | |
| JP4750557B2 (en) | Manufacturing method of colored sanitary thin paper | |
| JP2001159089A (en) | Sanitary paper in which good-quality cellulosic fiber taken out from plastic-coated paper raw material is highly formulated | |
| JP4119930B2 (en) | Madler paper | |
| JP2004187930A (en) | Tissue paper product | |
| CN113584939A (en) | Household paper and preparation method thereof | |
| JPH04228692A (en) | Bleaching method of high yield paper-making pulp using hydrogen peroxide | |
| Watson et al. | Influence of fibre morphology on paper properties | |
| JP2003027389A (en) | Tissue product | |
| JP7138420B2 (en) | Nonwoven duster and method for producing nonwoven duster | |
| JP2006283233A (en) | Sanitary tissue paper and method for producing sanitary tissue paper | |
| JP7163031B2 (en) | Sanitary tissue paper and method for producing sanitary tissue paper | |
| JP3838155B2 (en) | Tissue paper manufacturing method | |
| CN117751219A (en) | Hemp paper packaging material for food | |
| EP3748073A1 (en) | Semi-bleached or unbleached eucalyptus globulus pulp for tissue products | |
| JPH0598597A (en) | Tissue paper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20061227 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20061227 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20090601 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20090605 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20090804 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20100521 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20100714 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20100827 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20100903 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 4585231 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130910 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130910 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20130910 Year of fee payment: 3 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |