JP4579586B2 - Manufacturing method of paper in which non-contact type IC tag is inserted - Google Patents

Manufacturing method of paper in which non-contact type IC tag is inserted Download PDF

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JP4579586B2
JP4579586B2 JP2004174552A JP2004174552A JP4579586B2 JP 4579586 B2 JP4579586 B2 JP 4579586B2 JP 2004174552 A JP2004174552 A JP 2004174552A JP 2004174552 A JP2004174552 A JP 2004174552A JP 4579586 B2 JP4579586 B2 JP 4579586B2
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tag
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layer
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宏長 宮内
敏典 小林
幸夫 駒形
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Hokuetsu Kishu Paper Co Ltd
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本発明は電波を用いてデータの読み出しや書き込みを行い、非接触で対象物を自認する技術(RFID Radio Frequency Identification)に関する。更に詳細すれば、RFIDを用いたデバイスである非接触型ICタグを紙の紙層内に漉き込んだ用紙及びその製造方法に関する。   The present invention relates to a technology (RFID Radio Frequency Identification) that reads and writes data using radio waves and recognizes an object without contact. More specifically, the present invention relates to a paper in which a non-contact type IC tag, which is a device using RFID, is inserted in a paper layer of paper, and a method for manufacturing the same.

図書館、交通機関等の種々の公共施設その他施設において、利用者の確認や識別のための通行証、保険証、会員登録証等のカード内に、情報量の増大や記録の書き換え等に対応するために、アンテナコイルやコンデンサ等の共振回路とICチップを実装した非接触型ICタグを封入したものが用いられている。この様なICカード基材としては通常ポリエステル樹脂、ABS樹脂又は塩化ビニル樹脂等のプラスチックが主に用いられている。   To cope with the increase in the amount of information and the rewriting of records in cards such as passports, insurance cards, and membership registration cards for confirmation and identification of users in various public facilities and other facilities such as libraries and transportation facilities In addition, a non-contact type IC tag in which a resonance circuit such as an antenna coil or a capacitor and an IC chip are mounted is used. As such an IC card substrate, plastics such as polyester resin, ABS resin, or vinyl chloride resin are mainly used.

これらICカードの汎用性を進めるにあたり、カードの薄型化や低コスト化が求められている。この様な観点から、印刷等の加工処理の容易さ、コストの大幅な低減等の要求から紙製のICカードが提案されている。   In order to promote the versatility of these IC cards, there is a demand for thinner and lower cost cards. From such a viewpoint, a paper IC card has been proposed in view of demands for easy processing such as printing and a significant reduction in cost.

例えば、カード用紙に非接触型ICダグを挟み貼り合わせしたもの(例えば、特許文献1参照。)や、更に該カード用紙表面に導電性インクを用いアンテナパターンを印刷したものが提案されている(例えば、特許文献2参照。)。   For example, a non-contact type IC doug sandwiched between card sheets (for example, see Patent Document 1), and a card sheet surface printed with an antenna pattern using conductive ink have been proposed ( For example, see Patent Document 2.)

また、前記紙製のICカードの非接触型ICタグの張り替え等による偽造防止を目的に、用紙を抄造する際にICタグを用紙の層間に漉き込んだ紙製のICカード(例えば、特許文献3又は4参照。)や、紙層内に漉き込んだ偽造防止用紙(例えば、特許文献5又は特許文献6参照。)等が提案されている。   In addition, for the purpose of preventing counterfeiting by replacing the non-contact type IC tag of the paper IC card, a paper IC card in which the IC tag is inserted between the layers of the paper when paper is made (for example, patent document) 3 or 4), and anti-counterfeit paper (see, for example, Patent Document 5 or Patent Document 6) encased in a paper layer.

また、非接触型ICタグも薄物化が図られており、厚さ60〜70μmの非接触型ICタグ(特許文献7参照)も提案されている。   Further, the non-contact type IC tag is also made thinner, and a non-contact type IC tag having a thickness of 60 to 70 μm (see Patent Document 7) has also been proposed.

特開2003−85518号公報JP 2003-85518 A 特開2003−85510号公報JP 2003-85510 A 特開2003−58856号公報JP 2003-58856 A 特開2004−102353号公報JP 2004-102353 A 特開2002−319006号公報JP 2002-319006 A 特開2004−139405号公報JP 2004-139405 A 特開2002−49901号公報JP 2002-49901 A

従来の抄紙時に非接触型ICタグを紙層間に漉き込んだ紙製ICカードは漉き込んだ用紙の表面にICタグによる膨らみ又は光沢のムラが発生した。これにより、ICタグの存在が目視され、表面平滑性が劣り、印刷適性や意匠性に劣り、また、耐水性や寸法安定性が劣り、実用的には大きな障害があった。   In a conventional paper IC card in which a non-contact type IC tag is inserted between paper layers at the time of conventional papermaking, the surface of the inserted paper has a swelling or uneven gloss due to the IC tag. As a result, the presence of the IC tag was visually observed, surface smoothness was inferior, printability and designability were inferior, and water resistance and dimensional stability were inferior.

また、従来の非接触型ICタグを紙層内に漉き込んだ紙製ICカードは、紙層内にICタグを漉き込むに当たりワイヤー上に形成された紙料マットに歪みを生じさせたり、最終用途をカード大の寸法等の比較的小さな用途を対象とした場合、非接触型ICタグを抄紙機の幅方向の紙層内に頻度を密にして漉き込まざるをえず、インレット、バット、乃至ポンド内の希釈紙料の流れを塞いだり、乱したり、汚れを発生させたりして、用紙の地合不良、筋及び汚れを発生させ、表面平滑性、印刷適性や意匠性を低下させ、また、耐水性や寸法安定性が劣り、実用的には大きな障害があった。   In addition, a paper IC card in which a conventional non-contact type IC tag is encased in a paper layer may cause distortion in the paper mat formed on the wire when the IC tag is encased in the paper layer. When the application is intended for relatively small applications such as card-sized dimensions, the non-contact type IC tag must be squeezed into the paper layer in the width direction of the paper machine, and the inlet, bat, Or block the flow of diluted stock in the pound, disturb it, or generate stains, which may cause poor paper formation, streaks and stains, and reduce surface smoothness, printability and design. In addition, the water resistance and dimensional stability were inferior, and there were major obstacles in practical use.

また、紙製のICカード又は偽造防止印刷用紙においては、長期使用時におけるICタグの金属腐食等による受発信機能の停止が心配されている。   In addition, in the case of paper IC cards or anti-counterfeit printing paper, there is a concern that the function of receiving and transmitting / receiving is stopped due to metal corrosion of the IC tag during long-term use.

また、一般の紙・板紙の抄紙機で非接触型ICタグをただ単に漉き込んで用紙を製造した場合、用紙に漉き込んだ非接触型ICタグに受発信機能停止トラブルが頻発し、ICタグの欠番を生ずるという大きな問題のあることを見出した。   In addition, when a paper is manufactured by simply swiping a non-contact type IC tag on a general paper / paperboard machine, troubles of stopping the transmission / reception function frequently occur in the non-contact type IC tag that has been tucked into the paper. I found that there was a big problem that caused the missing number.

そこで本発明の第1の目的は、非接触型ICタグを破壊することなしに紙層内に漉き込むことで、用紙の表面にICタグによる膨らみ又は光沢のムラの発生を抑止した用紙を提供することである。すなわち、ICタグの存在が目視されることがなく、表面平滑性、印刷適性や意匠性に優れ、また、耐水性や寸法安定性に優れた実用的な用紙を提供することである。また、本発明の第2の目的は、非接触型ICタグを紙層内に漉き込んだ用紙の製造方法であって、一般的な紙・板紙抄紙機の大幅な変更をすることがなく、また非接触型ICタグを破壊することがなく、用紙とした後も安定して非接触型ICタグが作動しうる用紙の製造方法を提供することである。   Accordingly, a first object of the present invention is to provide a sheet that suppresses the occurrence of swelling or uneven glossiness due to the IC tag on the surface of the sheet by interposing into the paper layer without destroying the non-contact type IC tag. It is to be. That is, it is to provide a practical paper that is excellent in surface smoothness, printability and designability, and excellent in water resistance and dimensional stability, without the presence of an IC tag. The second object of the present invention is a method for producing a paper in which a non-contact type IC tag is inserted in a paper layer, without significantly changing a general paper / paperboard machine, It is another object of the present invention to provide a paper manufacturing method in which a non-contact type IC tag can be stably operated even after the non-contact type IC tag is destroyed without being destroyed.

即ち、本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法によって得られる用紙は、一層からなる用紙基材の紙層内に、又は二層以上からなる多層用紙基材を構成する紙層のうち少なくとも一つの紙層内に、非接触型ICタグが漉き込まれてなり、抄紙機の各加圧装置の加圧が線圧0kgf/cmを超えて45kgf/cm以下として製造され、前記用紙基材又は前記多層用紙基材のJIS P 8122:2004で規定されるステキヒト法によるサイズ度(以下、「ステキヒトサイズ度」という)が0.0093×(坪量)^2.00秒以上であり、前記用紙基材又は前記多層用紙基材のJIS P 8133:1998で規定される冷水抽出pHが6.2を超え、且つ、前記用紙基材又は前記多層用紙基材の全塩素含有量が400ppm以下であり、且つ、前記用紙基材又は前記多層用紙基材のJIS P 8144:1998で規定される水溶性塩化物含有量が80ppm以下であることを特徴とする。紙層内に非接触型ICタグを漉き込むことで、紙層間にそれを漉き込んだ場合と比較してICタグによる膨らみ又は光沢のムラの発生が少ない。ここで、用紙基材又は多層用紙基材のJIS P 8122:2004で規定されるステキヒトサイズ度を0.0093×(坪量)^2.00秒以上とすることで紙厚の戻りもなく、非接触型ICタグの紙中の存在がより明らかとならず、偽造防止乃至意匠性に優れる。なお、用紙基材又は多層用紙基材の用語が表す意味としては、顔料を含んだ塗被組成物を表面に塗工した塗工紙における用紙基材の部分又は多層用紙基材の部分を含む。もちろん非塗工紙の用紙基材の部分又は多層用紙基材の部分を含む(以下同じ)。前記冷水抽出pH、前記用紙基材又は前記多層用紙基材の全塩素含有量及びJIS P 8144:1998で規定される水溶性塩化物含有量の条件を全て満たす中性用紙の紙層内に非接触型ICタグを配置することにより、非接触型ICタグを安定させて作動しうる環境とするものである。特に封止剤により封止されてない絶縁フィルムに、アンテナコイル、配線パターン、ICチップ等が実装されたままの非接触型ICタグ、及びアンテナ内蔵型ICタグの場合に有効である。 That is, the paper obtained by the method for producing a paper in which the non-contact type IC tag according to the present invention is encased constitutes a multi-layer paper base material composed of two or more layers in the paper layer of the paper base material made of one layer. A non-contact type IC tag is inserted in at least one of the paper layers to be manufactured, and the pressurization of each pressurization device of the paper machine is produced with the linear pressure exceeding 0 kgf / cm and not more than 45 kgf / cm. The sizing degree of the paper base material or the multilayer paper base material according to the Steecht method defined in JIS P 8122: 2004 (hereinafter referred to as “Steecht sizing degree”) is 0.0093 × (basis weight) ^ 2. 00 seconds or more, the cold water extraction pH specified in JIS P 8133: 1998 of the paper base material or the multilayer paper base material exceeds 6.2, and all of the paper base material or the multilayer paper base material Chlorine content is 400 pm or less, and the JIS P of the paper substrate or the multilayer sheet substrate 8144: water-soluble chloride content defined by 1998 is equal to or less than 80 ppm. By inserting the non-contact type IC tag into the paper layer, the occurrence of swelling or uneven gloss due to the IC tag is less than when the non-contact type IC tag is inserted between the paper layers. Here, the thickness of the paper base or multilayer paper base specified by JIS P 8122: 2004 is 0.0093 × (basis weight) ^ 2.00 seconds or more so that the paper thickness does not return. Further, the presence of the non-contact type IC tag in the paper is not clear, and the anti-counterfeiting or design property is excellent. In addition, as the meaning which the term of a paper base material or a multilayer paper base material represents, the part of the paper base material in the coated paper which coated the coating composition containing a pigment on the surface, or the part of a multilayer paper base material is included. . Of course, it includes a paper base portion or a multilayer paper base portion of non-coated paper (the same applies hereinafter). In the paper layer of the neutral paper satisfying all the conditions of the cold water extraction pH, the total chlorine content of the paper base material or the multilayer paper base material and the water-soluble chloride content specified in JIS P 8144: 1998 By disposing the contact type IC tag, the non-contact type IC tag can be stabilized and operated. This is particularly effective in the case of a non-contact type IC tag in which an antenna coil, a wiring pattern, an IC chip and the like are mounted on an insulating film that is not sealed with a sealant, and an IC tag with a built-in antenna.

本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法によって得られる用紙では、主に顔料と接着剤からなる塗被組成物が片面及び/又は両面に片面塗被量5〜15g/mで塗被されている用紙が含まれる。用紙の印刷適性及び意匠性をより高めることができる。 In the paper obtained by the paper manufacturing method in which the non-contact type IC tag according to the present invention is encased, the coating composition mainly composed of a pigment and an adhesive is coated on one side and / or on both sides with a coating amount of 5 to 15 g on one side. Includes paper coated at / m 2 . The printability and designability of the paper can be further improved.

本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法によって得られる用紙では、単品で若しくは該非接触型ICタグを貼着したテープと共に前記紙層内の所定の一定の位置に漉き込まれてなる場合を含む。非接触型ICタグ単品でも或いはテープをガイドとしても、所定位置に非接触型ICタグが配置されることとなる。 In the paper obtained by the method for producing a paper in which the non-contact type IC tag according to the present invention is inserted, the paper is individually sold or is put together with the tape to which the non-contact type IC tag is attached at a predetermined fixed position in the paper layer. Including the case of being included. Whether the contactless IC tag is a single product or the tape is used as a guide, the contactless IC tag is disposed at a predetermined position.

本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法は、原料パルプ繊維としてECF漂白化学パルプを用いた中性抄紙紙料を使用し、用紙基材又は多層用紙基材のJIS P 8122:2004で規定されるステキヒト法によるサイズ度が0.0093×(坪量)^2.00秒以上となる量のサイズ剤を前記紙料に添加する工程と、抄紙機のワイヤーパートのワイヤー上で形成途中の紙料マットの中に非接触型ICタグを漉き込む工程と、一層からなる用紙基材又は二層以上からなる多層用紙基材の湿紙を得る工程と、前記抄紙機の各加圧装置の加圧を線圧0kgf/cmを超えて45kgf/cm以下としてプレスする工程と、を有することを特徴とする。形成途中の紙料マットの中に非接触型ICタグを漉き込むことで、紙層に歪みを生じることなく容易に紙層内に非接触型ICタグを入れることができ、また、非接触型ICタグの破壊を防ぐことができる。また、前記サイズ剤を添加する工程を有することで、紙厚の戻りもなく、非接触型ICタグの紙中の存在が明らかとならず、偽造防止乃至意匠性に優れた用紙ができる。原料パルプ繊維としてECF漂白化学パルプを用いた中性抄紙紙料を使用するのは、酸に弱い非接触型ICタグを安定させて作動しうる環境とするものである。特に封止剤により封止されてない絶縁フィルムに、アンテナコイル、配線パターン、ICチップ等が実装されたままの非接触型ICタグ、及びアンテナ内蔵型ICタグの場合に有効である。 The method for producing a paper in which the non-contact type IC tag according to the present invention is engraved uses a neutral papermaking material using ECF bleached chemical pulp as a raw material pulp fiber, and a paper base or a multilayer paper base JIS. The step of adding a sizing agent in such an amount that the degree of sizing by the Steecht method specified in P 8122: 2004 is 0.0093 × (basis weight) ^ 2.00 seconds or more, and the wire part of the paper machine A step of inserting a non-contact type IC tag into a paper mat that is being formed on a wire, a step of obtaining a wet paper of a paper substrate consisting of one layer or a multilayer paper substrate consisting of two or more layers, and the paper machine characterized in that it and a step of pressing in the following 45 kgf / cm beyond the linear pressure 0 kgf / cm pressurization of the pressure device. By inserting the non-contact type IC tag into the paper mat that is being formed, the non-contact type IC tag can be easily placed in the paper layer without causing distortion in the paper layer. The destruction of the IC tag can be prevented. Further, by including the step of adding the sizing agent, the paper thickness does not return, the presence of the non-contact IC tag in the paper is not clarified, and a paper excellent in forgery prevention and design properties can be obtained. The use of a neutral papermaking material using ECF bleached chemical pulp as a raw material pulp fiber provides an environment in which a non-contact IC tag that is weak against acid can be operated stably. This is particularly effective in the case of a non-contact type IC tag in which an antenna coil, a wiring pattern, an IC chip and the like are mounted on an insulating film that is not sealed with a sealant, and an IC tag with a built-in antenna.

本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法では、前記非接触型ICタグを漉き込む工程は、細長状の連続テープに所定間隔をおいて貼着された前記非接触型ICタグを該連続テープと共に前記形成途中の紙料マットの中に漉き込む工程であることが好ましい。用紙基材の紙層内に正確に所定間隔空けて非接触型ICタグを漉き込むことができる。これにより、例えば非接触型ICタグを備えたカードを製造する場合には、廃棄される用紙基材を少なくすることができる。   In the method for manufacturing a paper in which the non-contact type IC tag is inserted according to the present invention, the step of inserting the non-contact type IC tag includes the non-contact type that is attached to a continuous continuous tape at a predetermined interval. It is preferable that it is a step of rolling the mold IC tag into the paper mat that is being formed together with the continuous tape. The non-contact type IC tag can be inserted into the paper layer of the paper base material with a predetermined interval precisely. Thus, for example, when a card having a non-contact type IC tag is manufactured, it is possible to reduce the paper base material to be discarded.

本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法では、前記非接触型ICタグを漉き込む工程は、非接触型ICタグ導入管の先端を前記形成途中の紙料マットの中に配置し、水若しくは希釈紙料をキャリアとして所定間隔ごとに前記非接触型ICタグを漉き込む工程であることが好ましい。前記連続テープを用いて非接触型ICタグを漉き込む場合は勿論のこと、非接触型ICタグを単体で形成途中の紙料マットの中に漉き込む場合においても、所望の場所から一定時間をおいて漉き込むことにより、正確に一定間隔をあけて紙層に歪みを生ぜずに非接触型ICタグを漉き込むことができる。   In the method for manufacturing a paper in which the non-contact type IC tag is inserted according to the present invention, the step of inserting the non-contact type IC tag includes the step of inserting the tip of the non-contact type IC tag introduction tube into the paper mat that is being formed. It is preferable to dispose the non-contact type IC tag at predetermined intervals using water or diluted paper as a carrier. Of course, when a non-contact type IC tag is rolled in using the continuous tape, even when a non-contact type IC tag is rolled into a paper mat that is being formed as a single unit, a certain time is required from a desired location. In this case, the non-contact type IC tag can be inserted without causing any distortion in the paper layer at a precise interval.

また、本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法では、前記抄紙機は多層抄き抄紙機であり、且つ、前記非接触型ICタグを漉き込む工程は、紙幅方向で相隣り合う前記非接触型ICタグを異なる紙層内に漉き込む工程である場合を含む。完成品であるカードの大きさが小さい場合など、非接触型ICタグを高密度で漉き込む必要がある場合、非接触型ICタグ導入管同士の間隔を広げることができる。これにより、ポンド又はバット内に送り込まれた希釈紙料の水流を塞ぎ、乱すこともなく、用紙を厚薄、筋等を生じさせ地合の極めて劣ったものとなることもない。また、非接触型ICタグ導入管に紙料が堆積し、粕、汚れとなって用紙を汚すこともない。   Further, in the method for manufacturing a paper in which the non-contact type IC tag is inserted according to the present invention, the paper machine is a multilayer paper machine, and the step of inserting the non-contact type IC tag includes: In this case, the non-contact type IC tag adjacent to each other is included in a different paper layer. When it is necessary to swipe non-contact type IC tags at a high density, such as when the size of the finished card is small, the interval between the non-contact type IC tag introduction tubes can be increased. As a result, the water flow of the diluted stock fed into the pound or bat is not blocked and disturbed, and the paper is neither thick nor thin, streaks, etc., and the formation is not extremely inferior. Further, the paper material is accumulated on the non-contact type IC tag introduction tube, so that the paper does not become dirty and become dirty.

本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法では、主に顔料と接着剤からなる塗被組成物を用紙の片面及び/又は両面に片面塗被量5〜15g/mIn the method for producing a paper in which the non-contact type IC tag according to the present invention is encased, a coating composition mainly composed of a pigment and an adhesive is applied to one side and / or both sides of the paper at a coating amount of 5 to 15 g / m on one side. 2 で塗被する工程を更に有していることが好ましい。It is preferable to further have a step of coating with.

本発明は、一層からなる用紙基材の紙層内に又は二層以上からなる多層用紙基材で構成する紙層のうち少なくとも一つの紙層内に非接触型ICタグを漉き込んだ用紙であり、一般の印刷用紙と同等の表面性と紙層の均一性を有するので印刷適性並びに意匠性に優れる。さらに、寸法安定性並びに耐水性に優れるので実用的である。また、本発明に係る非接触型ICタグが漉き込まれた用紙の製造方法においては、一般的な紙・板紙抄紙機の大幅な変更をすることがなく、また非接触型ICタグを破壊することがない。さらに用紙とした後も非接触型ICタグが機能停止、それによる該ICタグの欠番を生じる恐れがない。   The present invention relates to a paper in which a non-contact type IC tag is inserted in a paper layer of a single-layer paper base material or in at least one paper layer of a multi-layer paper base material composed of two or more layers. In addition, since it has the same surface properties and paper layer uniformity as general printing paper, it is excellent in printability and design. Furthermore, since it is excellent in dimensional stability and water resistance, it is practical. Further, in the method for manufacturing paper in which the non-contact type IC tag according to the present invention is inserted, the non-contact type IC tag is destroyed without significantly changing a general paper / paperboard machine. There is nothing. Furthermore, there is no possibility that the non-contact type IC tag stops functioning even after the paper is used, and the IC tag is not missing.

以下、本発明について実施形態を示してさらに詳細に説明するが、本発明はこれらの記載に限定して解釈されることはない。図1は、本実施形態に係る非接触型ICタグが漉き込まれた用紙の一形態を示す断面概略図であって、(a)は1層の紙層からなる用紙の場合、(b)は多層の紙層からなる用紙の場合である。本発明に係る非接触型ICタグが漉き込まれた用紙は、図1(a)に示すように一層の紙層13からなる用紙基材の紙層内に非接触型ICタグ1が漉き込まれてなる。或いは、図1(b)に示すように二層以上の紙層からなる多層用紙基材を構成する紙層13a,13b,13cのうち少なくとも一つの紙層内3bに非接触型ICタグ1が漉き込まれてなる。紙層に歪みを生ずることなく非接触型ICタグは紙層内に漉き込まれる。   Hereinafter, the present invention will be described in more detail with reference to embodiments, but the present invention is not construed as being limited to these descriptions. FIG. 1 is a schematic cross-sectional view showing an embodiment of a sheet in which a non-contact type IC tag according to the present embodiment is inserted, in which (a) is a sheet composed of one sheet layer, (b) Is the case of a sheet of multiple paper layers. As shown in FIG. 1A, the paper in which the non-contact type IC tag according to the present invention is inserted is inserted into the paper layer of the paper base material composed of one paper layer 13. Be rare. Alternatively, as shown in FIG. 1B, the non-contact type IC tag 1 is provided in at least one paper layer 3b among the paper layers 13a, 13b, and 13c constituting the multilayer paper base material composed of two or more paper layers. It will be rubbed in. The non-contact type IC tag is inserted into the paper layer without causing distortion in the paper layer.

紙層内に漉き込まれる非接触型ICタグは、例えば、PET,PEN,PI等からなる厚さ5〜15μmの絶縁フィルムの片面に厚さ18〜50μmの銅、アルミニウム等の金属層が積層されてなる積層板をパターニングして、アンテナコイルと配線パターンを形成し、フイルムコンデンサー、ICチップを実装し一体化したもの、又は更にこれらをエポキシ樹脂等の熱硬化性樹脂、ポリエステル等のホットメルト樹脂で封止した厚さ60〜70μmのICダグがある。また、ICチップ上にアンテナコイルを設けたコイルオンチップ乃至アンテナ内蔵型ICタグも含まれる。また、本実施形態に係る非接触型ICタグが漉き込まれた用紙には、前記の絶縁フィルムにアンテナコイルのみを設けた共振タグ又はワイヤー状のアンテナが漉き込まれている場合も含まれる。   The non-contact type IC tag inserted into the paper layer is, for example, a metal layer such as copper or aluminum having a thickness of 18 to 50 μm laminated on one side of an insulating film having a thickness of 5 to 15 μm made of PET, PEN, PI or the like. The laminated plate is patterned to form an antenna coil and a wiring pattern, and a film capacitor, an IC chip mounted and integrated, or a thermosetting resin such as an epoxy resin, or a hot melt such as polyester. There is an IC doug with a thickness of 60 to 70 μm sealed with resin. Also included are coil-on-chip or antenna built-in IC tags in which an antenna coil is provided on an IC chip. Moreover, the case where the resonance tag which provided only the antenna coil in the said insulating film, or the wire-shaped antenna is included in the paper in which the non-contact-type IC tag which concerns on this embodiment was inserted.

以下、本実施形態に係る非接触型ICタグが漉き込まれた用紙の製造方法を説明しつつ、当該用紙の特徴についてあわせて説明する。   Hereinafter, while explaining a method of manufacturing a paper in which the non-contact type IC tag according to the present embodiment is inserted, characteristics of the paper will be described together.

本実施形態に係る非接触型ICタグが漉き込まれた用紙の製造方法では、一般的な紙及び板紙が製造されている抄紙機を大幅な変更をすることなく非接触型ICダグを紙料マット形成途中の紙層内に漉き込むことに係る発明である。そして、その後の製紙工程において非接触型ICタグを破壊せずに、用紙化する必要がある。一般的な紙及び板紙の抄紙機のフローを図2に示した。本フローに基づき、主に非接触型ICタグの破壊の大きな要因である各パートにおける紙に負荷される加圧状況について説明する。   In the method of manufacturing a paper in which the non-contact type IC tag according to the present embodiment is inserted, the non-contact type IC doug is used as a paper material without making a major change to a paper machine on which general paper and paperboard are manufactured. It is an invention relating to interleaving into a paper layer in the middle of mat formation. Then, it is necessary to form a sheet without destroying the non-contact type IC tag in the subsequent paper making process. The flow of a general paper and board machine is shown in FIG. Based on this flow, the pressurization condition applied to the paper in each part, which is a major factor of destruction of the non-contact type IC tag, will be described.

先ず、紙料調整において主原料であるパルプ等繊維と、サイズ剤、硫酸バンド、填料、染料等の薬品類が混合され、紙乃至板紙の紙料が3%程度の濃度に調整される。   First, fibers such as pulp, which is a main raw material, and chemicals such as a sizing agent, a sulfuric acid band, a filler, and a dye are mixed in paper stock adjustment, and the paper stock or paper stock stock is adjusted to a concentration of about 3%.

この紙料は濃度0.1〜0.6%に希釈され、所定の坪量の紙に相当する規定量がウェットパートに送られワイヤーで漉き取られる。紙料を漉き取る方式はワイヤーの形式により大きく分けて長網、円網、傾斜の3種類があり、単独又は組み合わせて採用されている。本パートはワイヤーパートとも云われる。本パートの出口の湿紙水分は90%前後である。   The stock is diluted to a concentration of 0.1 to 0.6%, and a specified amount corresponding to a paper having a predetermined basis weight is sent to the wet part and scraped off with a wire. There are three types of paper scraping methods depending on the type of wire: a long net, a circular net, and an inclination, which are used alone or in combination. This part is also called a wire part. The wet paper web at the outlet of this part is around 90%.

次に、90%前後の水分の湿紙はプレスパートに送られ、次段の加熱による乾燥の効率を高めるために、ゆっくりと絞られる。本プレスパートは湿紙の脱水を主目的とするが、湿紙表面は粗であり、ワイヤマークやフェルトマークもあり、これらを矯正してより平滑なものにし、また成紙の密度を高め、物理的強度を高めることもその機能としている。プレスパートに入ってくる湿紙水分は90%前後と高水分であるため、そのままの状態で急激に加圧すると、湿紙の潰れ、膨れ、層間剥離等色々のトラブルを生ずるため、2〜4段のベビープレスで徐々に脱水され、4〜5基のサクションロール、グルーブドロール等のメインプレスで脱水される。プレスパート出口の湿紙水分は52〜60%程度である。一般的紙及び板紙製造におけるプレスパートのプレスの線圧(kgf/cm)と湿紙水分を表1に示す。一般的な紙及び板紙の製造においては最大110kgf/cmのプレス線圧で湿紙が絞られている。なお、表1には、加圧パターンを2通り例示した。

Figure 0004579586
Next, wet paper with a moisture content of about 90% is sent to the press part and slowly squeezed to increase the efficiency of drying by heating in the next stage. The main purpose of this press part is dehydration of wet paper, but the wet paper surface is rough, and there are also wire marks and felt marks, which are corrected and made smoother, and the density of the paper is increased. Increasing physical strength is also a function. Since the wet paper moisture entering the press part is as high as about 90%, if the pressure is rapidly increased as it is, various troubles such as crushing, swelling and delamination of the wet paper occur. It is gradually dehydrated with a stepped baby press and dehydrated with a main press such as 4 to 5 suction rolls and grooved rolls. The wet paper web moisture at the press part outlet is about 52-60%. Table 1 shows the press line pressure (kgf / cm) and wet paper moisture of the press part in general paper and board production. In the manufacture of general paper and paperboard, wet paper is squeezed with a maximum press linear pressure of 110 kgf / cm. Table 1 illustrates two types of pressure patterns.
Figure 0004579586

次に、ドライパートにおいてプレスパート出口の水分52〜60%程度の湿紙は成紙水分5%程度まで乾燥される。本パートは蒸気により表面温度が100〜135℃程度に熱せられているシリンダードライヤー又はヤンキードライヤーからなる。ドライパートの途中には、紙の表面強度を増強するする目的で澱粉やPVA(ポリビニルアルコール)等紙力増強剤の3〜10%濃度の溶液を紙に塗布するサイズプレスが設けられている。通常30〜40kgf/cm程度の線圧で紙に紙力増強剤の溶液が塗布されている。   Next, in the dry part, the wet paper having a water content of about 52 to 60% at the outlet of the press part is dried to a water content of about 5%. This part consists of a cylinder dryer or Yankee dryer whose surface temperature is heated to about 100-135 ° C. by steam. In the middle of the dry part, there is provided a size press for applying a 3 to 10% strength solution of a paper strength enhancer such as starch or PVA (polyvinyl alcohol) to the paper for the purpose of enhancing the surface strength of the paper. Usually, a paper strength enhancer solution is applied to paper at a linear pressure of about 30 to 40 kgf / cm.

紙水分5%程度に乾燥されドライヤーパートを出てきた紙は、まだ表面が粗く、その組織も柔らかであることから、表面を平滑にし、組織を緻密にし、所定の紙厚にする目的でカレンダー処理される。一般に外表面に硬度の高いチルド層を設けたチルドロールが用いられている。又、弾性ロールを用いたソフトカレンダーも用いられている。通常55〜65kgf/cm程度の線圧で処理されている。   Paper that has been dried to a moisture content of about 5% and has come out of the dryer part has a rough surface and a soft tissue, so the surface is smooth, the texture is fine, and the calender is used to achieve a predetermined paper thickness. It is processed. In general, chilled rolls having a hardened chilled layer on the outer surface are used. A soft calendar using an elastic roll is also used. Usually, it is processed at a linear pressure of about 55 to 65 kgf / cm.

カレンダーパートまでの紙は連続した紙で作られてきているが、抄紙機の最終段でこの連続した紙はそのまま巻き取られたり(リール)、そのまま平判に指定の寸法に断裁されたりする(カッター)。また、そのまま巻き取られたリールは再度ワインダーで指定の幅の小巻ロールやカッターにより指定の寸法の平判に断裁される。   The paper up to the calendar part has been made of continuous paper, but at the final stage of the paper machine, this continuous paper is wound up as it is (reel) or cut into the specified dimensions in plain format ( cutter). In addition, the reel that has been wound as it is is cut again by a winder into a flat sheet having a specified size by a small roll or cutter having a specified width.

この様に一般の紙・板紙の抄紙機には、湿紙の脱水を図るために、或いは、印刷適性付与のための紙表面の平滑性向上や紙厚の均一性を図るために各種の紙を加圧する設備が設けられている。一般の紙・板紙抄紙機で単に非接触型ICタグを紙に漉き込むと、加圧によるICチップそのものの破壊又は非接触型ICタグのアンテナコイルとICチップの接点の破壊等により非接触型ICタグの機能障害が生じる。非接触型ICタグの機能障害を生ずることなく、非接触型ICタグを漉き込んだ用紙を得るには、抄紙機の各加圧装置の加圧を各加圧設備の加圧を線圧0kgf/cmを超えて45kgf/cm以下にすることが必要であることを見出した。さらにこの条件に加えて通常の紙・板紙製造時の線圧の70%以下とすると良い。一方、本発明の非接触型ICタグを漉き込んだ用紙の印刷適性、特に印刷平滑性を、一般的な印刷用紙・板紙の品質と同等レベルの品質に維持するには、特にプレスパートの各プレスの線圧を一般的紙・板紙の平常生産時における線圧の0%超、即ちプレスパートの各加圧装置を空通しするのではなく若干でも加圧する、好ましくは30%以上の線圧で加圧することが必要であることを見出した。即ち、一般の紙・板紙抄紙機の改造をすることなく、漉き込んだ非接触型ICタグに機能停止のトラブルが発生せず、且つ、一般の紙・板紙と同等の印刷適性を得るには、一般の紙・板紙抄紙機に用いられている加圧装置の線圧を0kgf/cmを超えて45kgf/cm以下とすることで達成できることを見出した。さらにこの条件に加えて各加圧設備の加圧を0%超から70%以下、好ましくは30%以上から70%以下とすると良い。   In this way, in general paper / paperboard paper machines, various papers are used to dehydrate wet paper or to improve the smoothness of the paper surface and to make the paper thickness uniform for imparting printability. The equipment which pressurizes is provided. When a non-contact type IC tag is simply squeezed into a paper with a general paper / paperboard machine, the non-contact type is caused by destruction of the IC chip itself by pressurization or destruction of the contact between the antenna coil and the IC chip of the non-contact type IC tag. IC tag malfunction occurs. In order to obtain a paper in which the non-contact type IC tag is inserted without causing a functional failure of the non-contact type IC tag, the pressurization of each pressurizing device of the paper machine is set to the linear pressure of 0 kgf. The present inventors have found that it is necessary to exceed 45 cmf / cm beyond / cm. Further, in addition to this condition, it is preferable that the linear pressure is 70% or less during normal paper / board manufacture. On the other hand, in order to maintain the printability of the paper containing the non-contact type IC tag of the present invention, in particular, the printing smoothness at the same level as the quality of general printing paper and board, The linear pressure of the press exceeds 0% of the linear pressure during normal production of general paper and paperboard, that is, pressurizes a little rather than emptying each pressurizing device of the press part, preferably a linear pressure of 30% or more It was found that it was necessary to pressurize with That is, without modifying the general paper / paperboard machine, there is no trouble of stopping the function of the non-contact type IC tag, and the same printability as that of general paper / paperboard is obtained. The present inventors have found that this can be achieved by setting the linear pressure of a pressure device used in a general paper / paperboard paper machine to more than 0 kgf / cm and not more than 45 kgf / cm. Further, in addition to this condition, the pressurization of each pressurization facility may be more than 0% to 70%, preferably 30% to 70%.

また、現在提供されている非接触型ICタグの厚さは60〜150μmであるが、この厚みは用紙の坪量とすると50〜130g/mに匹敵する。図3に示したように、積層される湿紙(水分90%前後)の層間に非接触型ICタグを漉き込んだ場合、該ICタグが漉き込まれた箇所は、ICタグが漉き込まれてない箇所に比較して紙層の密度が高くなり、その結果該箇所のみの光沢が高くなる。また、前記積層された紙の耐水性が特に弱い場合、紙厚の戻りが生じ非接触型ICタグの漉き込まれた箇所のみ紙厚が厚くなる。一方、図4に示したように、紙料マット形成途中の試料マット内に非接触型ICタグを漉き込んだ場合は、非接触型ICタグが漉き込まれた箇所とそうでない箇所の紙層密度に殆ど差が生ぜす、紙層に歪みを生ずることがない。更に、非塗工紙或いは顔料を含んだ塗料を塗被する前の紙のJIS P 8122:2004で規定されるステキヒトサイズ度を0.0093×(坪量)^2.00秒以上、好ましくは0.0212×(坪量)^1.90秒以上とすることで、紙厚の戻りもなく、且つ、非接触型ICタグの紙中の存在が明らかとならないため、偽造防止乃至意匠性に優れた非接触型ICタグを漉き込んだ用紙を得ることができた。なお、前記式内の「坪量」は特に断らない限り、一層からなる用紙基材の場合は「非塗工紙の一層の坪量」を表し、二層以上からなる多層用紙基材の場合は「非塗工紙の全坪量」を表す。 Further, the thickness of the non-contact type IC tag currently provided is 60 to 150 μm, and this thickness is equivalent to 50 to 130 g / m 2 when the basis weight of the paper is used. As shown in FIG. 3, when a non-contact type IC tag is inserted between layers of laminated wet paper (about 90% moisture), the IC tag is inserted at the place where the IC tag is inserted. The density of the paper layer is higher than that of the unexposed portion, and as a result, the gloss of only the portion increases. Further, when the water resistance of the laminated paper is particularly weak, the paper thickness is returned and the paper thickness is increased only at the portion where the non-contact type IC tag is inserted. On the other hand, as shown in FIG. 4, when the non-contact type IC tag is inserted into the sample mat in the middle of the paper mat formation, the paper layer at the part where the non-contact type IC tag is inserted and the part where it is not. There is almost no difference in density, and no distortion occurs in the paper layer. Furthermore, the non-coated paper or the paper before coating with the pigment-containing paint has a Steecht size defined by JIS P 8122: 2004 of 0.0093 × (basis weight) ^ 2.00 seconds or more, preferably Is 0.0212 × (basis weight) ^ 1.90 seconds or more, so that there is no return of paper thickness and the presence of non-contact type IC tags in paper is not clarified. Paper with a non-contact type IC tag excellent in the above can be obtained. Note that “basis weight” in the above formula represents “basis weight of one layer of non-coated paper” in the case of a single-layer paper base unless otherwise specified, and in the case of a multilayer paper base consisting of two or more layers Represents “total basis weight of uncoated paper”.

また、紙製ICカードにおいては、耐水性が弱く、寸法安定性に劣り、紙くせ及びカールが発生するという課題があった。非塗工紙或いは顔料を含んだ塗被組成物を塗被する前の紙のJIS P 8122:2004で規定されるステキヒトサイズ度を0.0093×(坪量)^2.00秒以上、好ましくは0.0212×(坪量)^1.90秒以上とすることで、非塗被紙及び塗被紙のカール乃至紙くせのない非接触型ICタグを漉き込んだ紙を得ることができた。   In addition, the paper IC card has a problem that water resistance is weak, dimensional stability is poor, and paper wrinkling and curling occur. 0.0093 × (basis weight) ^ 2.00 seconds or more, the degree of steecht stipulated in JIS P 8122: 2004 of the paper before applying the coating composition containing non-coated paper or pigment, Preferably, by making 0.0212 × (basis weight) ^ 1.90 seconds or more, it is possible to obtain non-coated paper and non-contact type IC tags without coated paper curled or non-coated IC tags. did it.

更に、一般の塗被紙・板紙の製造に用いられている塗被装置を用いて非接触型ICタグを漉き込んだ用紙に主に顔料と接着剤からなる塗被組成物を片面及び/又は両面に片面塗被量5〜15g/m塗被することで該用紙の印刷適性及び意匠性をより高めることができた。該用紙への塗被組成物の塗被は、ロールコーター、グラビアコーター、ダイコーター、カーテンコーター、スプレーコーター、ブレードコーター、ロッドコーター(バーコーター)、ノッチバーコーター、エアードクターコーター等が使用できる。より好ましくは、非接触方式のダイコーター、カーテンコーター、スプレーコーター、エアードクターコーター等が好ましい。 Further, a coating composition mainly composed of a pigment and an adhesive is applied on one side and / or on a paper in which a non-contact type IC tag is inserted using a coating apparatus used for manufacturing a general coated paper / paperboard. By applying a single-side coating amount of 5 to 15 g / m 2 on both sides, the printability and design of the paper could be further improved. A roll coater, a gravure coater, a die coater, a curtain coater, a spray coater, a blade coater, a rod coater (bar coater), a notch bar coater, an air doctor coater or the like can be used for coating the coating composition on the paper. More preferably, a non-contact type die coater, curtain coater, spray coater, air doctor coater or the like is preferred.

また、特に封止剤により封止されてない絶縁フィルムにアンテナコイル、配線パターン、ICチップ等が実装されたままの非接触型ICタグ、及びアンテナ内蔵型ICタグの場合、原料紙料の条件により非接触型ICタグの機能に障害を及ぼすことを見出した。抄紙時における該ICタグの機能障害の防止及び該ICタグの漉き込まれた用紙の長期使用時における該ICタグの機能障害を防ぐ為には、非塗工紙或いは顔料を含んだ塗料を塗被してない紙、すなわち用紙基材又は多層用紙基材のJIS P 8133:1998で規定される冷水抽出pHが6.2を超えることが好ましい。さらにこのpHを9以下、より好ましくはpHを8以下とすることが良い。このpHが9を超えると、アルカリ填料及び薬品によりパルプ繊維への紙力向上剤及びサイズ剤の定着が阻害され、その結果、強度及びサイズ度の発現が阻害さる。特に本発明の様な高サイズ度を要求する場合、冷水抽出pHが9以下、より好ましくは8以下が良い。また非塗工紙或いは顔料を含んだ塗料を塗被してない紙、すなわち用紙基材又は多層用紙基材の全塩素含有量が400ppm以下、好ましくは200ppm以下であることが好ましい。さらに、非塗工紙或いは顔料を含んだ塗料を塗被してない紙、すなわち用紙基材又は多層用紙基材のJIS P 8144:1998で規定される水溶性塩化物含有量が80ppm以下、好ましくは50ppm以下を満足する紙料配合であることが必要であることを見出した。   In particular, in the case of a non-contact type IC tag in which an antenna coil, a wiring pattern, an IC chip, etc. are still mounted on an insulating film that is not sealed with a sealant, and an IC tag with a built-in antenna, conditions for raw material stock Has found that the function of the non-contact type IC tag is impaired. In order to prevent functional failure of the IC tag during paper making and to prevent functional failure of the IC tag during long-term use of the paper in which the IC tag is inserted, a paint containing non-coated paper or pigment is applied. It is preferable that the cold water extraction pH prescribed | regulated by JISP8133: 1998 of the paper which does not cover, ie, a paper base material or a multilayer paper base, exceeds 6.2. Furthermore, the pH is 9 or less, more preferably 8 or less. When this pH exceeds 9, the fixing of the paper strength improver and the sizing agent to the pulp fiber is inhibited by the alkali filler and the chemical, and as a result, the development of strength and sizing degree is inhibited. In particular, when high sizing is required as in the present invention, the cold water extraction pH is 9 or less, more preferably 8 or less. Further, it is preferable that the total chlorine content of the non-coated paper or the paper not coated with the paint containing the pigment, that is, the paper base material or the multilayer paper base material is 400 ppm or less, preferably 200 ppm or less. Furthermore, the water-soluble chloride content defined by JIS P 8144: 1998 of the non-coated paper or the paper not coated with the paint containing the pigment, that is, the paper base material or the multilayer paper base material is preferably 80 ppm or less. Has found that it is necessary to have a paper blend satisfying 50 ppm or less.

次に非接触型ICタグを紙層内の定位置に漉き込む方法を以下に説明する。非接触型ICタグは非接触型ICタグ自体をそのままで又はPP,PE及びPET等のフィルム或いは不織布等のシート材をスリットした細いテープに非接触型ICタグを所定間隔に貼り付ける。この非接触型ICタグが貼り付けられたテープを水又は希釈紙料をキャリアとして非接触型ICタグ導入管を通じてワイヤー上の紙料マット形成途中で紙料マット中に漉き込む。紙層内の定位置に非接触ICタグを漉き込むワイヤー形式としては、一層からなる用紙基材の紙層内に漉き込む場合は、図5記載の傾斜型ワイヤーを用い、二層以上からなる多層用紙基材を構成する紙層のうち少なくとも一つの紙層内に漉き込む場合は、図6(A)又は(B)記載の円網型ワイヤーを用いる。尚、一層からなる用紙基材についても円網型を用いることが出来る。   Next, a method for inserting the non-contact type IC tag into a fixed position in the paper layer will be described below. The non-contact type IC tag is affixed at a predetermined interval with the non-contact type IC tag itself as it is or on a thin tape obtained by slitting a sheet material such as a film such as PP, PE and PET or a nonwoven fabric. The tape on which the non-contact type IC tag is affixed is inserted into the paper mat through the non-contact type IC tag introduction tube through the non-contact type IC tag introduction tube using water or diluted paper as a carrier. As a wire type for inserting a non-contact IC tag at a fixed position in a paper layer, when it is inserted into a paper layer of a single-layer paper substrate, the inclined wire shown in FIG. In the case where the paper layer is inserted into at least one paper layer among the paper layers constituting the multilayer paper base material, a circular mesh wire shown in FIG. 6 (A) or (B) is used. A circular net type can also be used for a single-layer paper base.

図5に傾斜型ワイヤーを示した。傾斜型ワイヤーはワイヤー5の傾斜領域a上にインレット4から導入された0.1〜0.3%程度に希釈された紙料からなるポンド6が形成されている。傾斜型ワイヤーの紙料マットの形成は、ポンド6に対しワイヤーを介して反対側に設置したサクションボックス7乃至テーブルロール(図示してない)により脱水されることで希釈紙料ポンドのワイヤーa領域において徐々に紙料マット8がワイヤー5上に形成され最終的に所定量の成紙坪量の紙料マット8となる。形成された紙料マット8はワイヤー5から分離され次工程のプレス工程へ送られる。   FIG. 5 shows an inclined wire. In the inclined wire, a pound 6 made of a paper material diluted to about 0.1 to 0.3% introduced from the inlet 4 is formed on the inclined region a of the wire 5. The slant-type wire stock mat is formed by dehydrating the pound 6 with a suction box 7 or a table roll (not shown) installed on the opposite side of the wire 6 through the wire, so that the wire a region of the diluted stock pond. The paper mat 8 is gradually formed on the wire 5 to finally become the paper mat 8 having a predetermined amount of the basis weight. The formed paper mat 8 is separated from the wire 5 and sent to the next pressing step.

図5の傾斜型ワイヤーによる非接触型ICタグの紙層内への漉き込みは、非接触型ICタグ自体をそのまま単体10で又は非接触型ICタグをテープに貼り付けたテープ10で非接触型ICタグ導入管9を通じて紙料マット形成の途中で紙層内に漉き込む。非接触型ICタグを紙料マット8内の紙の厚さ方向中央部に確実に漉き込むためには、非接触型ICタグ導入管9の先端を第二サクションボックス7又は多数本設置されてあるテーブルロール(図示してない)のインレット4側から1/3位置のテーブルロールの位置とすることが好ましい。   The non-contact type IC tag is inserted into the paper layer by the inclined wire shown in FIG. 5 in a non-contact manner with the non-contact type IC tag itself as it is or with the tape 10 with the non-contact type IC tag attached to the tape. In the middle of the formation of the paper mat through the mold IC tag introduction tube 9, the paper is cut into the paper layer. In order to surely insert the non-contact type IC tag into the center of the paper mat in the thickness direction of the paper mat 8, the tip of the non-contact type IC tag introduction tube 9 is installed in the second suction box 7 or many. It is preferable that the position of the table roll is 1/3 position from the inlet 4 side of a certain table roll (not shown).

図6に円網型ワイヤーを示した。(A)は順流型バットであり、(B)は逆流型バットを示す。2層以上からなる多層用紙基材を製造するには、これらのバットを多層用紙基材の漉き合わせ層数に応じたバット数を用いて漉き合わせる。   FIG. 6 shows a circular mesh wire. (A) is a forward flow type bat, (B) shows a reverse flow type bat. In order to produce a multilayer paper substrate composed of two or more layers, these bats are combined using the number of bats corresponding to the number of layers of the multilayer paper substrate.

順流型バット(A)では、0.1〜0.3%の希釈紙料はインレット4から導入され、円網型ワイヤー5の回転方向と同じ方向に流れ、余剰分はオーバーフロー口12からオーバーフローして行く。この途中で円網内部のサクションにより円網ワイヤー5上に徐々に紙料マットが形成される。形成された紙料マット8は毛布11に転移されてプレスパートへと送られる。順流型バット(A)から作られる成紙は地合が良く、幅方向の坪量や厚さの分布が均一である。   In the forward flow type bat (A), 0.1 to 0.3% of the diluted paper stock is introduced from the inlet 4 and flows in the same direction as the rotation direction of the circular wire 5, and the excess overflows from the overflow port 12. Go. In the middle of this, a paper mat is gradually formed on the circular mesh wire 5 by suction inside the circular mesh. The formed paper mat 8 is transferred to the blanket 11 and sent to the press part. The synthetic paper made from the forward flow type bat (A) has a good texture and has a uniform basis weight and thickness distribution in the width direction.

一方逆流型バット(B)は、0.3〜0.6%希釈紙料の成紙坪量に相当する量が円網型ワイヤー5の回転と逆方向にインレット4から導入され、紙料マット8は希釈紙料がインレット4から導入され円網型ワイヤーの回転方向と逆流し流れ、更に円網型ワイヤーの回転方向と順流し流れる間に導入された紙料の全量が紙料マット8として円網型ワイヤー5上に形成される。形成された紙料マット8は毛布11に転移されてプレスパートへと送られる。逆流型バット(B)は厚紙用の製造に適している。   On the other hand, the reverse flow type bat (B) is introduced from the inlet 4 in the direction opposite to the rotation of the circular mesh wire 5 in an amount corresponding to the basis weight of the 0.3 to 0.6% diluted paper stock. 8 shows that the diluted paper stock is introduced from the inlet 4 and flows backward in the direction of rotation of the circular mesh wire, and the total amount of the paper stock introduced while flowing forward and in the direction of rotation of the circular mesh wire is used as the paper mat 8. It is formed on the circular mesh wire 5. The formed paper mat 8 is transferred to the blanket 11 and sent to the press part. The backflow bat (B) is suitable for the manufacture of cardboard.

図6の円網型ワイヤー(A)乃至(B)による非接触型ICタグの紙層内への漉き込みは、非接触型ICタグ自体をそのまま単体10で又は非接触型ICタグをテープに貼り付けたテープ10で非接触型ICタグ導入管(図示してない)を通じて紙料マット8形成の途中で紙料マット内に漉き込む。非接触型ICタグを紙層内の厚さ方向中央部に確実に漉き込むためには、鋭意検討の結果、非接触型ICタグ導入管の先端を図6(A)順流バット場合は5時から7時の間、図のaの位置に、(B)逆流バットの場合は7時から9時の間、図のbの位置にすることが好ましいことがわかった。   The non-contact type IC tag is inserted into the paper layer by the circular mesh wires (A) to (B) in FIG. 6 by using the non-contact type IC tag itself as it is or by using the non-contact type IC tag as a tape. The attached tape 10 is inserted into the paper mat during the formation of the paper mat 8 through a non-contact type IC tag introduction tube (not shown). As a result of intensive studies, the tip of the non-contact type IC tag introduction tube is positioned at 5 o'clock in the case of the forward bat in FIG. It was found that it is preferable to set the position to a in the figure from 7 o'clock to 7 o'clock, and in the case of (B) the backflow bat, to the position b in the figure from 7 o'clock to 9 o'clock.

非接触型ICタグ導入管により紙料マット内に漉き込まれた非接触型ICタグは、傾斜型ワイヤーの場合はサクションボックス又はテーブルロールの吸引、又は円網型ワイヤーの場合も円網ワイヤー内部からの吸引による希釈紙料の吸引脱水による紙料マット形成に伴う吸引力により自然に容易に抄紙機の幅方向及び流れ方向の定めた所定の位置に正確に漉き込まれた。   The non-contact type IC tag inserted in the paper mat by the non-contact type IC tag introduction tube is a suction box or table roll suction in the case of inclined type wire, or the inside of the net wire in the case of circular type wire. The sheet was sucked into the predetermined position in the width direction and the flow direction of the paper machine easily and easily by the suction force associated with the formation of the paper mat due to the suction dehydration of the diluted paper.

最終用途がカード寸法(幅57mm×長さ84mm)の非接触型ICタグ漉き込み用紙を効率的に製造するには、用紙製造時の乾燥及び引っ張りによる紙の縮みを考慮して抄紙機の幅方向及び流れ方向の非接触型ICタグの漉き込み間隔を決める必要があるが、抄紙機の幅方向においては最小57mm間隔で、流れ方向においては最小84mm間隔で非接触型ICタグを密度高く紙層内に正確に漉き込む必要がある。特に、ワイヤーの幅方向は非接触型ICタグ導入管を最小57mm間隔で緻密に多数本設置しなければならい。このとき、非接触型ICタグ導入管が、ポンド又はバット内に送り込まれた希釈紙料の水流を塞いだり乱したりして用紙に厚薄、筋等を生じさせ地合の極めて劣ったものとなるという問題が生じた。また、非接触型ICタグ導入管に紙料が堆積し、粕、汚れとなって用紙を汚す原因となった。鋭意検討の結果、複数層に非接触型ICタグを漉き込むことで1バット当たり挿入する非接触型ICタグ導入管の本数を減らすことにより前記記載の問題を解決することができた。例えば、2台のバットを用い、2つの層に非接触型ICタグを漉き込むことにより非接触型ICタグ導入管の間隔は最小114mmとなる。このように非接触型ICタグ導入管の間隔を大きくすることで、非接触型ICタグ導入管がバット中の希釈紙料の水流を乱すことなく、粕・汚れの発生もなかった。非接触型ICタグ導入管の間隔を、用紙の地合を崩すことなく且つ汚れの発生もない間隔に設定し、また非接触型ICタグを複数層に漉き込むことにより、カード寸法の様な小さな寸法の最終用途のものにも連続して効率よく対応させ、非接触型ICタグを漉き込んだ用紙を得ることができた。   In order to efficiently manufacture non-contact type IC tag interleaved paper whose final application is card size (width 57mm x length 84mm), the width of the paper machine is taken into account when paper is shrinked due to drying and pulling. Although it is necessary to determine the spacing between the non-contact type IC tags in the direction and the flow direction, the non-contact type IC tags are densely printed at a minimum of 57 mm in the width direction of the paper machine and at a minimum of 84 mm in the flow direction. It is necessary to penetrate precisely into the layer. In particular, in the width direction of the wire, a large number of non-contact type IC tag introduction pipes must be densely arranged with a minimum spacing of 57 mm. At this time, the non-contact type IC tag introduction tube is extremely inferior because it blocks or disturbs the water flow of the diluted stock fed into the pound or bat, causing the paper to be thick and thin, causing streaks, etc. The problem of becoming. In addition, the paper was deposited on the non-contact type IC tag introduction tube, and the paper became dirty and became a cause of soiling. As a result of intensive studies, it was possible to solve the above-mentioned problem by reducing the number of non-contact type IC tag introduction tubes inserted per bat by inserting non-contact type IC tags into a plurality of layers. For example, by using two bats and inserting a non-contact type IC tag into two layers, the distance between the non-contact type IC tag introduction pipes becomes 114 mm at the minimum. Thus, by increasing the interval between the non-contact type IC tag introduction pipes, the non-contact type IC tag introduction pipes did not disturb the water flow of the diluted stock in the bat, and no wrinkles / stains were generated. By setting the interval between the non-contact type IC tag introduction pipes to an interval that does not destroy the formation of the paper and that does not generate dirt, and by interposing the non-contact type IC tag into a plurality of layers, It was possible to obtain a paper in which a non-contact type IC tag was inserted by continuously and efficiently dealing with a small-sized end use product.

非接触型ICタグ導入管の太さ及び断面の形状は、漉き込む非接触型ICタグの形状に応じて適宜調整した方が非接触型ICタグを一定の位置の漉き込むためにも、及び用紙の厚薄・筋等の発生を抑えるためにも好ましい。   The thickness and cross-sectional shape of the non-contact type IC tag introduction tube are appropriately adjusted in accordance with the shape of the non-contact type IC tag to be inserted, so that the non-contact type IC tag is inserted at a certain position, and This is also preferable in order to suppress the occurrence of paper thickness and streaks.

以下に、実施例を挙げてさらに詳細に説明するが、本発明はこれらの実施例に限定されるものではない。以下の実施例及び比較例で用いた抄紙機のワイヤーパートの形式及び材料は以下の通りである。   Hereinafter, the present invention will be described in more detail with reference to examples, but the present invention is not limited to these examples. The form and material of the wire part of the paper machine used in the following examples and comparative examples are as follows.

<ワイヤーパートの形式>
図5 傾斜型ワイヤー
図6(A)円網型ワイヤー(順流)、(B)円網型ワイヤー(逆流)、(C)円網型ワイヤーの組み合わせ例
<Wire part format>
Fig. 5 Inclined wire Fig. 6 (A) Circular mesh wire (forward flow), (B) Circular mesh wire (reverse flow), (C) Circular mesh wire combination example

<紙料配合>
表2に記載した紙料は一般紙・板紙に使用している紙料配合である。

Figure 0004579586
<Contains paper stock>
The paper materials listed in Table 2 are the paper material blends used for general paper and paperboard.
Figure 0004579586

<塗被組成物、塗被装置及び塗被量>
表3に塗被組成物、塗被装置及び塗被条件を示した。

Figure 0004579586
<Coating composition, coating apparatus and coating amount>
Table 3 shows the coating composition, the coating apparatus, and the coating conditions.
Figure 0004579586

<非接触型ICタグの種類と漉き込み形態>
表4に非接触型ICタグの種類と寸法を示した。

Figure 0004579586

表5に非接触型ICタグの漉き込み形態を示した。
Figure 0004579586
<Types of contactless IC tags and squeezing forms>
Table 4 shows the types and dimensions of non-contact type IC tags.
Figure 0004579586

Table 5 shows the contact form of the non-contact type IC tag.
Figure 0004579586

また、以下の実施例及び比較例で実施した試験方法及びその評価基準は以下の通りである。   Moreover, the test methods implemented in the following Examples and Comparative Examples and the evaluation criteria thereof are as follows.

<紙基材に漉き込んだ非接触型ICタグの機能測定>
非接触型ICタグの機能の作動状況は株式会社日立製作所製の形式HE−MU380−MMP201を用いて行った。非接触型ICタグそのものを及びテープに貼り付けた非接触型ICタグを用紙基材に漉き込む前に非接触型ICタグをランダムに選択し、正常に機能している非接触型ICタグを10個選び、それらにマーキングし試験用非接触型ICタグ(A)とした。マーキングした試験用非接触型ICタグ(A)を用紙基材に漉き込んだ後に、再度これらの非接触型ICタグの機能の作動を検査した。機能の停止した非接触型ICタグの個数を確認した(B)。用紙基材に漉き込んだ非接触型ICタグの機能停止頻度を(B)/(A)で表した。
<Functional measurement of non-contact type IC tag embedded in paper base>
The operation status of the function of the non-contact type IC tag was performed using a model HE-MU380-MMP201 manufactured by Hitachi, Ltd. A non-contact IC tag is selected at random before the non-contact IC tag itself and the non-contact IC tag affixed to the tape are inserted into the paper substrate, and the non-contact IC tag that is functioning normally is selected. Ten of them were selected and marked to obtain a test non-contact IC tag (A). After the marked test non-contact type IC tag (A) was poured into the paper base material, the operation of the functions of these non-contact type IC tags was inspected again. The number of non-contact type IC tags whose functions were stopped was confirmed (B). The frequency of function stoppage of the non-contact type IC tag inserted into the paper base material was represented by (B) / (A).

<ステキヒトサイズ度>
JIS P8122:2004の紙及び板紙−サイズ度試験方法−ステキヒト法に準じて行った。
<Stick human sizing degree>
The paper and paperboard of JIS P8122: 2004-Sizing test method-It was performed according to the Steecht method.

<紙くせ・カール>
非接触型ICタグを漉き込んだ用紙をカード寸法(幅54mm×長さ85mm)にカットし、温度40℃、湿度90%RH、24時間処理した直後、平らな金属盤上にカール面を上向きに据えて金属盤表面から最も浮いた箇所の距離をノギスで測定した。尚、はがき及び情報記録用紙を想定した実施例及び比較例においてもそれぞれの用途に対応した寸法にカットして、同様にして測定した。評価基準を表6に示した。

Figure 0004579586
<Paper / Curl>
Paper with non-contact type IC tag inserted is cut into card dimensions (width 54 mm x length 85 mm), treated immediately at a temperature of 40 ° C and humidity of 90% RH for 24 hours, and then the curled surface faces upward on a flat metal plate The distance of the most floating part from the surface of the metal plate was measured with a caliper. In Examples and Comparative Examples assuming postcards and information recording sheets, the measurements were made in the same manner by cutting them into dimensions corresponding to the respective uses. Table 6 shows the evaluation criteria.
Figure 0004579586

<白紙及び印刷平面性>
白紙平面性は非接触型ICタグを漉き込んだ用紙を1/10坪量判にカットしたものを温度40℃、湿度90%RH、24時間処理した後、温度23℃、湿度50%RHで24時間調湿した後の白紙の表面を目視観察して評価した。印刷平面性は白紙平面性を観察した用紙をRI―III型印刷適性試験機(石川島産業株式会社製)を用い、プロセス印刷インキ紅(東洋インキ製造株式会社製)0.4mlで、印刷圧力8.5mm、印刷速度60rpmで印刷し印刷表面を目視で観察評価した。非接触型ICタグの漉き込んでない白紙部分の面は紅インキで均一に印刷されていた。尚、はがき及び情報記録用紙を想定した実施例及び比較例においても同様にして測定した。表7に目視観察評価基準を示す。

Figure 0004579586
<Blank paper and printing flatness>
The flatness of blank paper is obtained by cutting a paper with a non-contact IC tag into 1/10 basis weight, treating it at a temperature of 40 ° C. and a humidity of 90% RH for 24 hours, and then at a temperature of 23 ° C. and a humidity of 50% RH. The surface of the white paper after humidity adjustment for 24 hours was visually observed and evaluated. The printing flatness was measured by using a RI-III type printing aptitude tester (Ishikawajima Sangyo Co., Ltd.) and 0.4 ml of process printing ink red (Toyo Ink Manufacturing Co., Ltd.) with a printing pressure of 8 The printing surface was visually observed and evaluated at a printing speed of 5 mm and a printing speed of 60 rpm. The surface of the non-intruded blank paper portion of the non-contact type IC tag was uniformly printed with red ink. In the examples and comparative examples assuming postcards and information recording paper, the same measurement was performed. Table 7 shows the visual observation evaluation criteria.
Figure 0004579586

<RI強度(膨れ)>
RI―III型印刷適性試験機(石川島産業株式会社製)を用い、タックバリュウ13のインキ(東洋インキ製造株式会社製)0.4mlで、印刷圧力8.5mm、印刷速度60rpmで非接触型ICタグを漉き込んだ用紙の1/10坪量判を印刷し、該用紙の膨れ状況を観察した。尚、はがき及び情報記録用紙を想定した実施例及び比較例においても同様にして測定した。評価基準を表8に示した。

Figure 0004579586
<RI strength (swelling)>
Using a RI-III type printability tester (Ishikawajima Sangyo Co., Ltd.), 0.4 ml of Takvalu 13 ink (Toyo Ink Manufacturing Co., Ltd.), non-contact type IC with printing pressure 8.5mm, printing speed 60rpm A 1/10 basis weight of the paper in which the tag was inserted was printed, and the swollen state of the paper was observed. In the examples and comparative examples assuming postcards and information recording paper, the same measurement was performed. Table 8 shows the evaluation criteria.
Figure 0004579586

<紙の水抽出pH>
JIS P8133:1998の紙,板紙及びパルプ−水抽出液pHの試験方法に準じて行った。
<Water extraction pH of paper>
It was carried out according to the test method for paper, paperboard and pulp-water extract pH of JIS P8133: 1998.

<紙中の全塩素含有量>
試料を燃焼試験装置により燃焼させ、発生するガスを活性炭に吸着後、塩素分析装置にて全塩素量を測定した。塩素分析装置は三菱化学株式会社製TOX―10を用いた。
<Total chlorine content in paper>
The sample was burned with a combustion test device, and the generated gas was adsorbed on activated carbon, and then the total chlorine content was measured with a chlorine analyzer. The chlorine analyzer used TOX-10 manufactured by Mitsubishi Chemical Corporation.

<紙の水溶性塩化物含有量>
JIS P8144:1998の紙,板紙及びパルプ−水溶性塩化物の分析方法に準拠して得られた抽出液をイオンクロマト法で行った。装置は日本ダイオネクス株式会社製DX320を用いた。
<Water-soluble chloride content of paper>
Extracts obtained in accordance with JIS P8144: 1998 paper, paperboard and pulp-water-soluble chloride analysis method were subjected to ion chromatography. The device used was DX320 manufactured by Nippon Daionex Corporation.

<用紙の製造紙料配合による非接触型ICタグの作動測定試験>
1/10坪量判にカットした非接触型ICタグが漉き込まれた用紙を温度40℃、湿度90%RH、一週間処理し、温度23℃、湿度50%RHで24時間放置調湿した後、用紙に漉き込まれた非接触型ICタグの作動を株式会社日立製作所製の形式HE−MU380−MMP201を用いて測定した。処理前の用紙に漉き込まれた非接触型ICタグの作動は正常に機能していたことを確認した。<紙基材に漉き込んだ非接触型ICタグの機能測定>と同様の方法で用紙の処理前後の漉き込まれた非接触型ICタグの機能停止頻度を表した。
<Operational measurement test of non-contact type IC tag by blending paper manufacturing stock>
Paper with a non-contact IC tag cut to 1/10 basis weight was inserted and treated for one week at a temperature of 40 ° C. and a humidity of 90% RH for 24 hours at a temperature of 23 ° C. and a humidity of 50% RH. Thereafter, the operation of the non-contact type IC tag inserted into the paper was measured using a model HE-MU380-MMP201 manufactured by Hitachi, Ltd. It was confirmed that the operation of the non-contact type IC tag inserted into the paper before processing was functioning normally. The function stop frequency of the non-contact type IC tag inserted before and after the paper processing was expressed in the same manner as in <Measurement of function of non-contact type IC tag inserted into the paper base>.

本実施例及び比較例は最終用途としてカード(坪量270g/m、寸法幅54mm×長さ85mm)、はがき(坪量190g/m、寸法幅100mm×長さ147mm)及び情報記録用紙(坪量80g/m、寸法幅210mm×長さ297mm)を想定して行った。 In this example and comparative example, the card (basis weight 270 g / m 2 , dimension width 54 mm x length 85 mm), postcard (basis weight 190 g / m 2 , dimension width 100 mm x length 147 mm) and information recording paper ( The basis weight was assumed to be 80 g / m 2 , dimension width 210 mm × length 297 mm).

<実施例1>
表9〜表11に抄紙機に設置されている加圧装置の加圧条件による漉き込んだ非接触型ICタグの機能の作動状況と非接触型ICタグが漉き込まれた用紙の品質について検討した結果を示した。

Figure 0004579586

Figure 0004579586

Figure 0004579586
<Example 1>
Tables 9 to 11 examine the operational status of the function of the non-contact type IC tag inserted according to the pressurizing condition of the press machine installed in the paper machine and the quality of the paper in which the non-contact type IC tag is inserted. The results were shown.
Figure 0004579586

Figure 0004579586

Figure 0004579586

本検討は、ウェットパートとして図6(A)円網型(順流)バット3台を用い、図6(C)に図示した様に配置したものを用い、紙料は<紙料配合>記載の紙料Aを用い、全坪量は最終用途をカード用途に想定して一層坪量90g/m×三層の全坪量270g/mで行い、非接触型ICタグの漉き込みは中層にあたる第2バットで図6(A)記載の方法で紙層内に漉き込んだ。抄速は5m/minで行った。最終的に該用紙を<塗被組成物、塗被装置及び塗被量>に記載の条件で両面塗被した。漉き込みに使用した非接触型ICタグ及び漉き込み形態は<非接触型ICタグの種類と漉き込み形態>に記載したICタグX及びICタグXを紙層内に漉き込む形態1で行った。ICタグXは樹脂で封止されてない非接触型ICタグである。 In this study, as the wet part, three round net type (forward flow) bats were used as the wet part, and those arranged as shown in FIG. 6C were used. with stock a, total basis weight performs end-use in all basis weight 270 g / m 2 of more basis weight 90 g / m 2 × three layers assuming the card application, the narrowing plow non-contact type IC tag middle The second bat corresponding to this was punched into the paper layer by the method shown in FIG. The paper making speed was 5 m / min. Finally, the paper was coated on both sides under the conditions described in <Coating composition, coating apparatus and coating amount>. The non-contact type IC tag used for engraving and the engraving form were performed in the form 1 in which the IC tag X and IC tag X described in <Types of non-contact type IC tag and engraving form> were encased in the paper layer. . The IC tag X is a non-contact type IC tag that is not sealed with resin.

ICタグXを第2バット目で紙層内に漉き込んだ方法を更に詳細すると、鋭意検討の結果、内側断面形状が22mm×2mmの非接触型ICタグ導入管を用い、図6(A)のaの箇所に非接触型ICタグ導入管(図示してない)の先端をワイヤーの幅方向に184mmの間隔で3本設置し、その導入管にワイヤーの回転速度とほぼ同速度でインレット1からバット内に供給されていると同じ希釈紙料を流しながら導入管に自動的に1.08秒間隔で連続的にICタグXを落とし込むことによって紙層内に漉き込んだ。尚、非接触型ICタグ導入管の隙間は161mmであった。   The method of inserting the IC tag X into the paper layer with the second butt eye will be described in more detail. As a result of intensive studies, a non-contact IC tag introduction tube having an inner cross-sectional shape of 22 mm × 2 mm is used. The tip of a non-contact type IC tag introduction pipe (not shown) is installed at a position of a in the width direction of the wire at intervals of 184 mm, and the inlet 1 is installed at the same speed as the rotation speed of the wire. The IC tag X was continuously dropped into the introduction tube at intervals of 1.08 seconds while flowing the same diluted paper stock as was supplied into the vat from the inside of the paper layer. The clearance between the non-contact type IC tag introduction pipes was 161 mm.

比較としてICタグXの紙層間への漉き込みも行った。図6(C)のバット(I)と(II)の2バットを用い、バット(II)で漉かれ毛布に転移され運ばれてきた湿紙表面に手動で軽くICタグXを貼り付けた。その後バット(I)で漉かれた湿紙によってICタグXを挟み込み層間に漉き込んだ。全坪量は一層坪量135g/m×二層の270g/mで行った。 As a comparison, the IC tag X was inserted between the paper layers. Using two bats (B) (I) and (II) in FIG. 6 (C), the IC tag X was manually and lightly attached to the surface of the wet paper that was rolled with the bat (II) and transferred to the blanket. Thereafter, the IC tag X was sandwiched between the layers with wet paper wound with a bat (I), and then sandwiched between the layers. The total basis weight was one layer basis weight of 135 g / m 2 × two layers of 270 g / m 2 .

紙料配合Aは、原料パルプ繊維としてECF漂白化学パルプを用いた中性抄紙紙料であるが、<紙料配合>記載の一般の紙・板紙に使用している該紙料Aと前記紙料Aのサイズ剤添加量をほぼ5倍量増量しステキヒトサイズ度を更に高めた紙料A5の2種類の紙料について検討した。   Paper stock blend A is a neutral papermaking stock using ECF bleached chemical pulp as raw pulp fiber, and the paper stock A and the paper used in general paper and paperboard described in <paper stock blend> Two types of paper stock A5 were examined in which the amount of sizing agent added to stock A was increased by about 5 times to further increase the degree of sizing.

また、抄紙機の加圧装置の加圧条件は表9〜表11に記載の通りであるが、プレスパートの加圧装置及びカレンダーの加圧条件は一般の紙・板紙の製造条件(100%)から空通し(0%)の範囲で変更した。サイズプレス等その他加圧設備の加圧条件は特に変更しなかった。これらの線圧は全て45kgf/cm以下であった。   Further, the press conditions of the press machine of the paper machine are as shown in Tables 9 to 11, but the press conditions of the press part and the press conditions of the calendar are the conditions for manufacturing general paper and paperboard (100% ) To empty (0%). The pressure conditions of other pressurization equipment such as size press were not particularly changed. All of these linear pressures were 45 kgf / cm or less.

ICタグXの漉き込まれた連続した成紙は(非塗被紙)は工程トラブルもなくリールに巻き取られた。該巻き取りはエアードクターを設置した塗被装置で前記塗被組成物を片面12g/m(絶乾)で両面塗被して、塗被紙を得た。工程トラブルもなくICタグXの漉き込まれた連続した塗被紙が得られた。この様にして得られた非塗被紙と塗被紙について、非塗被紙のステキヒトサイズ度、並びに、非塗被紙と塗被紙の紙くせ・カール、白紙平面性、印刷面平面性及びRI強度(膨れ)について評価した。その結果は表9〜表11に記載した通りである。 The continuous printed paper in which the IC tag X was inserted (uncoated paper) was wound on a reel without any process trouble. The winding was performed by coating the coating composition on both sides at 12 g / m 2 (absolutely dry) on one side with a coating apparatus provided with an air doctor to obtain a coated paper. A continuous coated paper in which the IC tag X was inserted was obtained without any process trouble. About the non-coated paper and the coated paper obtained in this way, the degree of sizing of the non-coated paper, the paper texture / curl of the non-coated paper and the coated paper, white paper flatness, printing plane surface Evaluation was made on the property and RI strength (bulging). The results are as described in Table 9 to Table 11.

結果は、次の通りである。
(1)漉き込まれたICタグXは所定の場所の紙層内に用紙の表面と平行に、且つワイヤー幅方向に整列して正確に漉き込まれていた。
(2)例えば、実施例1−1と比較例1−2との比較からわかるように、一般の紙・板紙抄紙機でICタグXの機能を維持しICタグXを漉き込んだ用紙を製造するには各加圧装置の線圧を45kgf/cm以下にしなければならない。実施例では、さらに各加圧装置の加圧条件を70%以下としている。
(3)比較例1−1を参照すると、一般の紙・板紙製造に使用している紙料Aをそのまま用いたICタグX漉き込み用紙は、通常の紙・板紙製加圧条件においても紙くせ・カール、白紙・印刷面平面性、及びRI強度(膨れ)が若干低下する。ステキヒトサイズ度は350秒であった。
(4)比較例1−1〜比較例1−5を参照すると、プレスパートの加圧を下げると用紙のステキヒトサイズ度が低下し、紙くせ・カール、白紙・印刷平面性が低下する。特に、塗被組成物の塗被により更に悪化する。塗被組成物の水による用紙の肌戻りによるものと考えられる。
(5)実施例1−1〜実施例1−3を参照すると、用紙のステキヒトサイズ度を883〜890秒としたことで、各加圧装置の加圧条件の線圧を0kgf/cmを超えて45kgf/cm以下にしても、紙くせ・カール、白紙・印刷面平面性及びRI強度(膨れ)を一般の紙・板紙の品質レベルを確保出来た。但し、比較例1−7〜比較例1−9を参照すると、用紙のステキヒトサイズ度を883〜889秒としたとしてもプレスパートを空通しした場合は、非塗被紙の紙くせ・カール、白紙・印刷面平面性、及び非塗被紙及び塗被紙のRI強度(膨れ)が不良であった。したがって、プレスパートでの加圧が必要である。
(6)比較例1−10と比較例1−11を参照すると、紙料A5を用い、ICタグXを紙層間に漉き込んだ用紙も検討した。該用紙のステキヒトサイズ度は886〜892秒であった。該用紙は紙くせ・カール、白紙・印刷面平面性及びRI強度(膨れ)ともに不良であった。白紙平面性はICタグXが漉き込まれた箇所が膨れていた。また印刷面は膨らんだ箇所の周りにインキの薄い、又は乗らない現象(着肉不良)が見られた。したがって、実施例との比較から、ICタグXを紙層内に漉き込んだ用紙のほうが、紙くせ・カール、白紙・印刷面平面性及びRI強度(膨れ)に優れることが明らかとなった。
(7)以上、一般の紙・板紙抄紙機を用いて漉き込んだICタグXの機能を維持し、一般の紙・板紙と同等の品質を持ったICタグX漉き込み用紙は、ICタグXを紙層内に漉き込み、抄紙機の各加圧装置の加圧条件を線圧0kgf/cmを超えて45kgf/cm以下とし、且つ、用紙のステキヒトサイズ度を883秒以上にすることで得られることが解った。この条件に加えて抄紙機の各加圧装置の加圧条件は、通常一般紙・板紙製造時の加圧条件の0%超から70%以下、好ましくは、30%以上から70%以下にすると良い。
The results are as follows.
(1) The inserted IC tag X was accurately inserted in a paper layer at a predetermined location in parallel with the surface of the paper and aligned in the wire width direction.
(2) For example, as can be seen from the comparison between Example 1-1 and Comparative Example 1-2, the paper with the IC tag X is manufactured while maintaining the function of the IC tag X with a general paper / paperboard machine. For this purpose, the linear pressure of each pressurizing device must be 45 kgf / cm or less. In the embodiment, the pressurizing condition of each pressurizing device is 70% or less.
(3) Referring to Comparative Example 1-1, the IC tag X interleaving paper using the stock A used for the production of general paper / paperboard as it is is paper even under normal paper / paperboard pressurizing conditions. The habit / curl, white paper / printing surface flatness, and RI strength (swelling) are slightly reduced. The Steecht sizing degree was 350 seconds.
(4) Referring to Comparative Example 1-1 to Comparative Example 1-5, when the press part pressurization is lowered, the degree of sizing of the paper decreases, and the paper curl / curl, blank paper / printing flatness decreases. In particular, it is further deteriorated by the coating of the coating composition. This is thought to be due to the paper returning to the skin due to the water of the coating composition.
(5) Referring to Example 1-1 to Example 1-3, the linear pressure of the pressurizing condition of each pressurizing device was set to 0 kgf / cm by setting the paper sizing degree to 883 to 890 seconds. Even if it exceeds 45 kgf / cm, the quality level of general paper / paperboard can be ensured such as paper curl / curl, white paper / printing surface flatness and RI strength (swell). However, referring to Comparative Example 1-7 to Comparative Example 1-9, if the press part is empty even if the paper sizing degree is set to 883 to 889 seconds, the non-coated paper is curled or curled. The flatness of the white paper / printing surface and the RI strength (swelling) of the uncoated paper and the coated paper were poor. Therefore, pressurization at the press part is necessary.
(6) Referring to Comparative Example 1-10 and Comparative Example 1-11, paper in which the paper A5 was used and the IC tag X was interposed between the paper layers was also examined. The steecht size of the paper was 886-892 seconds. The paper had poor paper curl / curl, white paper / printed surface flatness and RI strength (swell). As for the flatness of the blank paper, the portion where the IC tag X was inserted was swollen. In addition, the printed surface showed a phenomenon that the ink was thin or did not ride around the swollen part (imperfection of the wall). Therefore, it was clarified from the comparison with the example that the paper in which the IC tag X was inserted in the paper layer was superior in paper texture / curl, white paper / printing surface flatness and RI strength (swell).
(7) As described above, the IC tag X interleaved paper that maintains the function of the IC tag X that has been incorporated using a general paper / paperboard machine and that has the same quality as that of ordinary paper / paperboard is the IC tag X In the paper layer, the pressurizing condition of each press machine of the paper machine is set to a linear pressure exceeding 0 kgf / cm to 45 kgf / cm or less, and the paper has a Steecht sizing degree of 883 seconds or more. I understood that it was obtained. In addition to this condition, the pressurizing condition of each pressurizing device of the paper machine is usually more than 0% to 70% or less, preferably 30% or more to 70% or less of the pressurizing condition at the time of manufacturing general paper / paperboard. good.

<実施例2>
表12〜表14に紙料配合の違いによる非接触型ICタグの機能に与える影響を検討した結果を示した。

Figure 0004579586

Figure 0004579586

Figure 0004579586
<Example 2>
Tables 12 to 14 show the results of studying the influence on the function of the non-contact type IC tag due to the difference in the stock composition.
Figure 0004579586

Figure 0004579586

Figure 0004579586

抄紙機の加圧装置の加圧条件は表12〜表14に記載した通りであるが、線圧0kgf/cmを超えて45kgf/cm以下とした。ここで、抄紙機の加圧装置の加圧条件は、通常条件の30%以上から70%以下としている。   The pressurizing conditions of the press machine of the paper machine are as described in Tables 12 to 14, but the linear pressure exceeded 0 kgf / cm and was 45 kgf / cm or less. Here, the pressure condition of the pressure device of the paper machine is 30% or more to 70% or less of the normal condition.

非接触型ICタグは<非接触型ICタグの種類と漉き込み形態>に記載のICタグX、ICタグYとICタグZの3種類について検討した。ICタグXは樹脂で封止されてない外部アンテナ型ICタグであり、ICタグYは樹脂で封止されている外部アンテナ型ICタグであり、ICタグZはアンテナ内蔵型ICタグである。   Three types of non-contact type IC tags, IC tag X, IC tag Y, and IC tag Z described in <Types of non-contact type IC tag and insertion type> were examined. The IC tag X is an external antenna type IC tag not sealed with resin, the IC tag Y is an external antenna type IC tag sealed with resin, and the IC tag Z is an IC tag with a built-in antenna.

非接触型ICタグ導入管の内側断面形状は、ICタグX及びYについては実施例1で用いた22mm×2mmの長方形形状のものを用い、ICタグZについては、鋭意検討の結果、内側断面直径が3mmのパイプを用いて行った。   As for the inner cross-sectional shape of the non-contact type IC tag introduction tube, the rectangular shape of 22 mm × 2 mm used in Example 1 was used for the IC tags X and Y, and the inner cross-section of the IC tag Z was determined as a result of intensive studies. A pipe having a diameter of 3 mm was used.

紙料配合は<紙料配合>に記載の紙料A,紙料B及び紙料Cの3種類について検討した。紙料Aは実施例1で用いた紙料であり、紙料Bは原料パルプに塩素漂白化学パルプを用いた中性抄紙紙料であり、紙料Cは原料パルプにECF漂白化学パルプを用いた酸性抄紙紙料である。用紙のステキヒトサイズ度がほぼ890秒となるようにサイズ剤添加量を<紙料配合>のほぼ5倍量に増量した。   Three types of paper stocks, paper stock A, paper stock B, and paper stock C described in <Paper stock formulation> were examined. Paper A is the paper used in Example 1, Paper B is a neutral papermaking material using chlorine bleached chemical pulp as the raw material pulp, and Paper C uses ECF bleached chemical pulp as the raw material pulp. Acid papermaking stock. The amount of the sizing agent added was increased to about 5 times the amount of <paper blending> so that the sizing degree of the paper was about 890 seconds.

非接触型ICタグが漉き込まれた用紙への塗被組成物の塗被は行わなかった。   The coating composition was not applied to the paper in which the non-contact type IC tag was inserted.

その他の条件は実施例1と同様とし、抄速5m/minで、全坪量は270g/m、一層坪量90g/mの三層漉きで、第二層目に3種類の非接触型ICタグを1.08秒間隔で自動的に落とし込んで行った。この様にして得た用紙の製造直後及び長時間経過後を想定した条件での漉き込まれた非接触型ICタグの機能の作動状況を調べた。 The other conditions were the same as in Example 1. The papermaking speed was 5 m / min, the total basis weight was 270 g / m 2 , and the basis weight was 90 g / m 2. The type IC tag was automatically dropped at 1.08 second intervals. The operating state of the function of the non-contact type IC tag inserted was examined under the conditions that assumed immediately after the manufacture of the paper thus obtained and after a long time.

結果は、次の通りである。
(1)漉き込まれた非接触型ICタグの3種類とも所定の場所の紙層内に用紙の表面と平行に、且つワイヤー幅方向に整列して正確に漉き込まれていた。
(2)尚、用紙のステキヒトサイズ度は677〜902秒であった。非接触型ICタグを漉き込んだ用紙の紙くせ・カールは全て良好であった。
(3)実施例2−1〜実施例2−4を参照すると、紙料配合Aの用紙の冷水抽出pHは6.4であり、紙中の全塩素含有量は140ppm、紙中の水溶性塩化物含有量は42ppmであった。比較例2−1〜比較例2−4を参照すると、紙料配合Bは、各々6.2,460ppm,90ppmであり、比較例2−5〜比較例2−8を参照すると、紙料Cは各々5.0,145ppm、45ppmであった。
(4)比較例2−5と比較例2−7を参照すると、紙料C(酸性抄紙紙料)では、ICタグX及びZは製造直後において既に機能停止が生じた。
(5)比較例2−1,比較例2−3,比較例2−4,比較例2−8を参照すると、非接触型ICタグが漉き込まれた用紙の長期使用時を想定した条件での漉き込まれた非接触型ICタグの作動状況は、ICタグX及びICタグZでは紙料B及び紙料Cを用いて漉き込んだ用紙の場合、機能停止した。しかし、実施例2−1〜実施例2−4を参照すると、紙料Aの場合は機能停止が生じなかった。尚、比較例2−2と比較例2−6を参照すると、ICタグYは何れの紙料配合においても機能停止は生じなかった。
(6)ICタグX及びZは、硫酸根及び塩素分等の酸性物質に対し抵抗力がないことが解った。
(7)非接触型ICタグを漉き込む紙料としては、用紙の冷水抽出pHが6.2を超えて、pHが9以下の中性近辺であり、紙中の全塩素含有量が400ppm以下、好ましくは200ppm以下であり、紙中の水溶性塩化物含有量が80ppm以下、好ましくは50ppm以下であることが好ましいことが解った。
The results are as follows.
(1) All three types of non-contact type IC tags inserted were accurately inserted in a paper layer at a predetermined location in parallel with the surface of the paper and aligned in the wire width direction.
(2) It should be noted that the degree of sizing of the paper was 677 to 902 seconds. The paper texture and curl of the paper in which the non-contact type IC tag was inserted were all good.
(3) Referring to Example 2-1 to Example 2-4, the cold water extraction pH of the paper with stock formulation A is 6.4, the total chlorine content in the paper is 140 ppm, and the water solubility in the paper The chloride content was 42 ppm. Referring to Comparative Example 2-1 to Comparative Example 2-4, the stock formulation B is 6.2, 460 ppm and 90 ppm, respectively, and referring to Comparative Example 2-5 to Comparative Example 2-8, the stock C Were 5.0, 145 ppm and 45 ppm, respectively.
(4) Referring to Comparative Example 2-5 and Comparative Example 2-7, in Paper C (acidic papermaking paper), IC tags X and Z had already stopped functioning immediately after production.
(5) Referring to Comparative Example 2-1, Comparative Example 2-3, Comparative Example 2-4, and Comparative Example 2-8, under conditions assuming long-term use of the paper in which the non-contact type IC tag is inserted The operation status of the non-contact type IC tag inserted in the IC tag X and the IC tag Z stopped in the case of the paper fed using the paper material B and the paper material C. However, referring to Example 2-1 to Example 2-4, in the case of stock A, the function did not stop. In addition, referring to Comparative Example 2-2 and Comparative Example 2-6, the IC tag Y did not stop functioning in any of the paper stocks.
(6) It was found that the IC tags X and Z are not resistant to acidic substances such as sulfate radicals and chlorine.
(7) As a paper material for inserting a non-contact type IC tag, the cold water extraction pH of the paper exceeds 6.2, the pH is around 9 or less, and the total chlorine content in the paper is 400 ppm or less. It was found that the content of water-soluble chloride in the paper is preferably not more than 200 ppm and preferably not more than 80 ppm, preferably not more than 50 ppm.

<実施例3>
表15に最終用途をカード、はがき及び情報記録用紙を想定し、非接触型ICタグを紙層内に漉き込んだ用紙について鋭意検討した結果を示した。

Figure 0004579586
<Example 3>
Table 15 shows the result of earnest study on a paper in which a non-contact type IC tag is inserted in a paper layer, assuming that the end use is a card, a postcard, and an information recording paper.
Figure 0004579586

本実施例に用いた紙料、抄紙機の加圧装置の加圧条件及び非接触型ICタグの紙層内漉き込み方法は実施例1及び2から見出した結果をもとにして実施した。   The paper material used in this example, the press condition of the press machine of the paper machine, and the method of interleaving the non-contact type IC tag into the paper layer were carried out based on the results found from Examples 1 and 2.

紙料は、<紙料配合>記載の紙料Aの中性ロジンサイズ剤の添加量を5倍量に増量した実施例1に用いた紙料A5を用いた。   As the stock, the stock A5 used in Example 1 in which the amount of the neutral rosin sizing agent added in the stock A described in <Paper formulation> was increased to 5 times the amount was used.

抄紙機の加圧装置の加圧条件は実施例1−1の条件で実施した。即ち、プレスパートの各加圧装置の加圧は、通常一般紙製造時の70%に設定し、45kgf/cm超の線圧の加圧装置は線圧45kgf/cmに設定した。また、カレンダー線圧も45kgf/cmに設定した。   The press condition of the press machine of the paper machine was the same as that of Example 1-1. That is, the pressurization of each pressurizing device of the press part was set to 70% of that during normal paper production, and the pressurizing device having a linear pressure exceeding 45 kgf / cm was set to a linear pressure of 45 kgf / cm. The calendar linear pressure was also set to 45 kgf / cm.

また、非接触型ICタグ導入管は実施例2記載のものを用いた。   In addition, the non-contact type IC tag introduction tube described in Example 2 was used.

尚、塗被組成物の塗被は行わなかった。   The coating composition was not applied.

カード、はがき及び情報記録用紙を想定し、これらの紙層内に非接触型ICタグを漉き込んだ方法は表15記載の通りであるが、ここに実施例3−1と実施例3−5について具体的に詳細と結果について記載する。   Assuming cards, postcards, and information recording paper, the method of inserting a non-contact type IC tag in these paper layers is as shown in Table 15. Here, Example 3-1 and Example 3-5 are used. Specific details and results will be described.

実施例3−1は、幅20mm×長さ50mm×厚さ60μmのICタグXの漉き込まれた幅54mm×長さ85mmのカード(坪量270g/m)に関する実施例である。ICタグXの漉き込みは、図6(A)記載の円網型順流バット3台を図6(C)記載の配置に配置したものを用いて三層多層漉きで行った。各層の坪量は90g/mで、三層の全ての層にICタグを漉き込んだ。抄速は30m/minで行った。ICタグXの漉き込み形態は厚さ10μm×幅2mmのPEテープにICダグXを93.5mm間隔に連続で貼り付けたものである。該形態のICタグXを、内側断面形状が22mm×2mmの非接触型ICタグ導入管を用いバット内に供給されている希釈紙料をキャリアとしてワイヤー上に形成途中の紙料マット中に漉き込んだ。非接触型ICタグ導入管は1バットにワイヤー幅方向に184mm間隔に3本設置した。尚、非接触型ICタグ導入管の隙間は161mmであった。3つのバット間の非接触型ICタグ導入管の配置は全体としてワイヤー幅方向で正確に61.5mm間隔となるように各バットに設置した。また、各パットで漉き込まれたICタグXがワイヤー幅方向に整列するようにICタグX貼り付けテープの非接触型ICタグ導入管への供給開始タイミングを調整した。成紙のカード配列の隙間は5mmとした。用紙の品質は表15の実施例3−1に記載の通りである。 Example 3-1 is an example relating to a card (basis weight 270 g / m 2 ) of width 54 mm × length 85 mm in which IC tag X having a width of 20 mm × a length of 50 mm × a thickness of 60 μm is inserted. The IC tag X was punched by three-layer multilayer punching using three circular net type forward flow bats shown in FIG. 6 (A) arranged in the arrangement shown in FIG. 6 (C). The basis weight of each layer was 90 g / m 2 , and an IC tag was inserted into all three layers. The paper making speed was 30 m / min. The IC tag X is inserted into a PE tape having a thickness of 10 μm and a width of 2 mm, and the IC tag X is continuously attached at intervals of 93.5 mm. The IC tag X in this form is spread in a paper mat that is in the process of being formed on a wire using a non-contact type IC tag introduction tube having an inner cross-sectional shape of 22 mm × 2 mm as a carrier with diluted paper supplied in the bat. It was crowded. Three non-contact type IC tag introduction tubes were installed in one bat at intervals of 184 mm in the wire width direction. The clearance between the non-contact type IC tag introduction pipes was 161 mm. The arrangement of the non-contact type IC tag introduction pipes between the three bats was set on each bat so that the distance between them was exactly 61.5 mm in the wire width direction as a whole. In addition, the supply start timing of the IC tag X attachment tape to the non-contact type IC tag introduction tube was adjusted so that the IC tags X inserted in each pad were aligned in the wire width direction. The gap of the card arrangement of the formed paper was 5 mm. The paper quality is as described in Example 3-1 in Table 15.

結果は、次の通りである。
(1)各円網型順流バット内の希釈紙料の水流に乱れもなく、粕・汚れの発生もなく良好な地合の用紙を得た。
(2)ICタグXが幅方向に59mm間隔で、流れ方向に90mm間隔で正確に整列して漉き込まれた厚さ0.317mmの用紙を得た。
(3)用紙のステキヒトサイズ度は853秒であった。
(4)漉き込まれたICタグXの製造直後及び長期使用想定条件での機能停止はなかった。
(5)ICタグXの漉き込まれた用紙の紙くせ・カール、白紙・印刷面平面性及びRI強度(膨れ)は全く問題なく一般の紙・板紙に匹敵するものであった。
The results are as follows.
(1) There was no disturbance in the water flow of the diluted stock in each circular net type forward flow bat, and there was obtained paper having a good texture without generation of wrinkles and stains.
(2) A sheet having a thickness of 0.317 mm was obtained in which the IC tags X were accurately aligned at intervals of 59 mm in the width direction and at intervals of 90 mm in the flow direction.
(3) The degree of sizing of the paper was 853 seconds.
(4) There was no function stop immediately after the manufacture of the inserted IC tag X and under long-term use assumptions.
(5) Paper crease / curl, blank paper / printed surface flatness, and RI strength (swell) of the paper in which the IC tag X was inserted were comparable to ordinary paper / board without any problem.

実施例3−5は、幅20mm×長さ50mm×厚さ60μmのICタグXの漉き込まれた幅210mm×長さ297mm(A4)の情報記録用紙(坪量80g/m)に関する実施例である。ICタグXの用紙基材への漉き込みは、図5記載の傾斜型ワイヤーを用い、坪量80g/mの一層の紙層内に、インレット4からポンド6に供給されている希釈紙料をキャリアとして実施例3−1と同じ非接触型ICタグ導入管に自動的に3.62秒の一定間隔で落とし込み紙層内への漉き込みを行った。抄速は5m/minで行った。非接触型ICタグ導入管はワイヤーの幅方向に224mm間隔で6本設置した。尚、非接触型ICタグ導入管の隙間は201mmであった。漉き込まれたICタグXがワイヤー幅方向に整列するように各非接触型ICタグ導入管へのICタグXの落とし込み開始タイミングを調整した。成紙のA4寸法の配列の隙間は5mmとした。
用紙の品質は表15の実施例3−5に記載の通りである。
Example 3-5 is an example relating to an information recording sheet (basis weight 80 g / m 2 ) of width 210 mm × length 297 mm (A4) into which an IC tag X having a width of 20 mm × a length of 50 mm × a thickness of 60 μm is inserted. It is. The IC tag X is inserted into the paper base material by using the slanted wire shown in FIG. 5 and the diluted paper stock supplied from the inlet 4 to the pound 6 in a single paper layer having a basis weight of 80 g / m 2. Was used as a carrier and was automatically dropped into the same non-contact type IC tag introducing tube as in Example 3-1, at a constant interval of 3.62 seconds, and was poured into the paper layer. The paper making speed was 5 m / min. Six non-contact type IC tag introduction tubes were installed at intervals of 224 mm in the width direction of the wire. The clearance between the non-contact type IC tag introduction pipes was 201 mm. The start timing of dropping the IC tag X into each non-contact type IC tag introduction tube was adjusted so that the inserted IC tag X was aligned in the wire width direction. The gap of the A4 size array of the printed paper was 5 mm.
The paper quality is as described in Example 3-5 in Table 15.

結果は次の通りである。
(1)傾斜型ワイヤー上の希釈紙料のポンドの水流に乱れはなく、粕・汚れの発生もなく良好な地合の用紙を得た。
(2)ICタグXが幅方向に215mm間隔で、流れ方向に302mm間隔で正確に整列して漉き込まれた厚さ0.094mmの用紙を得た。
(3)用紙のステキヒトサイズ度は65秒であった。
(4)漉き込まれたICタグXの製造直後及び長期使用想定条件での機能停止はなかった。
(5)ICタグXの漉き込まれた用紙の紙くせ・カール、白紙・印刷面平面性及びRI強度(膨れ)は全く問題なく一般の紙・板紙に匹敵するものであった。
The results are as follows.
(1) There was no turbulence in the water flow of the diluted paper stock on the inclined wire, and a paper with good texture was obtained without any wrinkles or smudges.
(2) A sheet having a thickness of 0.094 mm was obtained in which IC tags X were accurately aligned and spaced at intervals of 215 mm in the width direction and at intervals of 302 mm in the flow direction.
(3) The degree of sizing of the paper was 65 seconds.
(4) There was no function stop immediately after the manufacture of the inserted IC tag X and under long-term use assumptions.
(5) Paper crease / curl, blank paper / printed surface flatness, and RI strength (swell) of the paper in which the IC tag X was inserted were comparable to ordinary paper / board without any problem.

本実施例3において、前記の実施例の他にも、最終用途を想定し、その想定最終用途の用紙の厚みを考慮して非接触型ICタグの種類、ワイヤー形式及び紙層内への漉く込み方法を選択した実施例を示したが、本発明による非接触型ICタグ紙層内漉き込み用紙は漉き込まれた非接触型ICタグの機能停止もなく、その用紙の品質は一般の用紙に匹敵するものであった。   In the third embodiment, in addition to the above-described embodiments, an end use is assumed, and the thickness of the paper for the assumed end use is taken into consideration, the type of the non-contact type IC tag, the wire type, and the paper layer. However, the non-contact type IC tag paper in the paper layer according to the present invention does not stop the function of the non-contact type IC tag, and the quality of the paper is a general paper type. It was comparable.

本実施形態に係る非接触型ICタグが漉き込まれた用紙の一形態を示す断面概略図であって、(a)は1層の紙層からなる用紙の場合、(b)は多層の紙層からなる用紙の場合である。1A and 1B are schematic cross-sectional views showing an embodiment of a sheet in which a non-contact type IC tag according to the present embodiment is inserted, in which FIG. 5A is a sheet composed of one sheet layer, and FIG. This is the case for a sheet of layers. 一般的な抄紙機のフローを示す図である。It is a figure which shows the flow of a general paper machine. 貼り合わせた用紙の紙層間に非接触型ICタグを漉き込んだ場合の紙表面の状態(従来技術)を示す断面概略図であり、(a)は非接触型ICタグが湿紙に漉き込まれる時の状況、(b)は非接触型ICタグが漉き込まれた成紙の状況を示した。It is the cross-sectional schematic which shows the state (prior art) of the paper surface at the time of inserting a non-contact type IC tag between the paper layers of the paper bonded together, (a) is a non-contact type IC tag inserted in a wet paper. (B) shows the situation of the paper with the non-contact type IC tag inserted. 紙層内に非接触型ICタグを漉き込んだ場合の紙表面の状態(本発明)を示す断面概略図であり、(a)は非接触型ICタグが湿紙に漉き込まれる時の状況、(b)は非接触型ICタグが漉き込まれた成紙の状況を示した。It is a cross-sectional schematic diagram showing the state of the paper surface (invention) when a non-contact type IC tag is encased in the paper layer, (a) is the situation when the non-contact type IC tag is encased in the wet paper , (B) shows the situation of the formed paper in which the non-contact type IC tag is inserted. 傾斜型ワイヤーと該ワイヤーによる非接触型ICタグの紙層内への漉き込み方法を示す概略図である。It is the schematic which shows the method of winding in the paper layer of the non-contact-type IC tag by an inclined type wire and this wire. 円網型ワイヤーと該ワイヤーによる非接触型ICタグの紙層内への漉き込み方法を示す概略図である。It is the schematic which shows the winding method in the paper layer of the non-contact-type IC tag by a circular net type | mold wire and this wire.

符合の説明Explanation of sign

1,非接触型ICタグ
2,非接触型ICタグが湿紙に漉き込まれる時の状態の湿紙
3,非接触型ICタグが漉き込まれた成紙
4,インレット
5,ワイヤー
6,ポンド
7,サクションボックス
8,紙料マット
9,非接触型ICタグ導入管
10,非接触型ICタグ、又は非接触型ICタグを貼り付けたテープ
11,毛布
12,オーバーフロー口
13,13a,13b,13c,紙層
I,円網型バット(I)
II,円網型バット(II)
III,円網型バット(III)
1. Non-contact type IC tag 2. Wet paper in the state when the non-contact type IC tag is put into the wet paper 3. Adult paper in which the non-contact type IC tag is put in. 4, Inlet 5, Wire 6, Pound 7, suction box 8, paper mat 9, non-contact type IC tag introduction tube 10, non-contact type IC tag, or tape 11 with a non-contact type IC tag attached, blanket 12, overflow port 13, 13a, 13b, 13c, paper layer I, circular net bat (I)
II, round net type bat (II)
III, circular net type bat (III)

Claims (5)

原料パルプ繊維としてECF漂白化学パルプを用いた中性抄紙紙料を使用し、用紙基材又は多層用紙基材のJIS P 8122:2004で規定されるステキヒト法によるサイズ度が0.0093×(坪量)^2.00秒以上となる量のサイズ剤を前記紙料に添加する工程と、
抄紙機のワイヤーパートのワイヤー上で形成途中の紙料マットの中に非接触型ICタグを漉き込む工程と、
一層からなる用紙基材又は二層以上からなる多層用紙基材の湿紙を得る工程と、
前記抄紙機の各加圧装置の加圧を線圧0kgf/cmを超えて45kgf/cm以下としてプレスする工程と、を有することを特徴とする非接触型ICタグが漉き込まれた用紙の製造方法。
A neutral papermaking material using ECF bleached chemical pulp is used as the raw pulp fiber, and the degree of sizing according to the Steecht method defined in JIS P 8122: 2004 is 0.0093 × (tsubo Amount) Step of adding a sizing agent in an amount of ^ 2.00 seconds or more to the stock;
A step of inserting a non-contact type IC tag into a paper mat that is being formed on the wire of the wire part of a paper machine;
Obtaining a wet paper of a paper substrate consisting of one layer or a multilayer paper substrate consisting of two or more layers;
And pressing the pressure of each pressurizing device of the paper machine to a pressure exceeding 0 kgf / cm to 45 kgf / cm or less, and manufacturing a paper in which a non-contact type IC tag is inserted Method.
前記非接触型ICタグを漉き込む工程は、細長状の連続テープに所定間隔をおいて貼着された前記非接触型ICタグを該連続テープと共に、前記形成途中の紙料マットの中に漉き込む工程であることを特徴とする請求項記載の非接触型ICタグが漉き込まれた用紙の製造方法。 The step of inserting the non-contact type IC tag is performed by spreading the non-contact type IC tag attached to a long continuous tape at a predetermined interval together with the continuous tape in the paper mat that is being formed. 2. The method for producing a paper in which the non-contact type IC tag is inserted, according to claim 1, wherein 前記非接触型ICタグを漉き込む工程は、非接触型ICタグ導入管の先端を前記形成途中の紙料マットの中に配置し、水若しくは希釈紙料をキャリアとして所定間隔ごとに前記非接触型ICタグを漉き込む工程であることを特徴とする請求項記載の非接触型ICタグが漉き込まれた用紙の製造方法。 The step of inserting the non-contact type IC tag includes the step of disposing the tip of the non-contact type IC tag introduction tube in the paper mat in the process of formation, and the non-contact type at a predetermined interval using water or diluted paper as a carrier. method for producing a paper non-contact IC tag according to claim 1, wherein the plowed, characterized in that the step Komu plow type IC tag. 前記抄紙機は多層抄き抄紙機であり、且つ、前記非接触型ICタグを漉き込む工程は、紙幅方向で相隣り合う前記非接触型ICタグを異なる紙層内に漉き込む工程であることを特徴とする請求項1、2又は3記載の非接触型ICタグが漉き込まれた用紙の製造方法。 The paper machine is a multilayer paper machine, and the step of inserting the non-contact type IC tag is a step of inserting the non-contact type IC tags adjacent in the paper width direction into different paper layers. A method of manufacturing a paper in which the non-contact type IC tag according to claim 1, 2 or 3 is inserted. 主に顔料と接着剤からなる塗被組成物を用紙の片面及び/又は両面に片面塗被量5〜15g/mA coating composition mainly composed of a pigment and an adhesive is coated on one side and / or both sides of a sheet with a coating amount of 5 to 15 g / m on one side. 2 で塗被する工程を更に有していることを特徴とする請求項1、2、3又は4記載の非接触型ICタグが漉き込まれた用紙の製造方法。5. The method for producing a paper in which the non-contact type IC tag according to claim 1, 2, 3 or 4 is further provided.
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