JP4555178B2 - Meat processing product improver, method for modifying meat processed product using the improver, and meat processed product - Google Patents

Meat processing product improver, method for modifying meat processed product using the improver, and meat processed product Download PDF

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JP4555178B2
JP4555178B2 JP2005199412A JP2005199412A JP4555178B2 JP 4555178 B2 JP4555178 B2 JP 4555178B2 JP 2005199412 A JP2005199412 A JP 2005199412A JP 2005199412 A JP2005199412 A JP 2005199412A JP 4555178 B2 JP4555178 B2 JP 4555178B2
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俊久 田口
富美 影嶋
邦夫 岡田
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Nihon Shokuhin Kako Co Ltd
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Description

本発明は、肉類の加工、加熱調理後の歩留と風味、食感に優れ、更には加熱調理後、冷凍やチルド状態での保存を経た後の、電子レンジ加熱などの再加熱の後でも良好な風味と食感を損なうことがなく、安価に提供できる肉類加工品用改良剤、該改良剤を用いた肉類加工品の改質方法及び肉類加工品に関する。   The present invention is excellent in meat processing, yield and flavor after cooking, and texture, and further after cooking and after reheating such as microwave heating after storage in a frozen or chilled state. The present invention relates to an improving agent for processed meat products that can be provided at low cost without impairing good flavor and texture, a method for modifying processed meat products using the improving agent, and processed meat products.

牛肉、豚肉、鶏肉をはじめとする肉類と、魚などを始めとする魚介の肉類、更に、それを用いた加工食品は、肉本来の繊維感や噛み応えなどの食感を有しつつもソフトであり、パサつきが少なくジューシー、かつ肉本来の風味を有するものが好まれる。   Beef, pork, chicken and other meats, fish and other seafood meats, and processed foods that use them are soft while having the texture of meat, such as fiber texture and chewing response. It is preferred that it is succulent and has the original flavor of meat.

近年ではBSE問題、鶏インフルエンザ問題などに起因する原料供給不安も広がり、安価で安定した品質の原料肉も、以前より入手が困難になりつつある。   In recent years, the supply of raw materials due to the BSE problem, the chicken influenza problem, etc. has spread, and cheap and stable quality raw material meat is becoming difficult to obtain.

このような中、老廃家畜、経産家畜、乳牛種や、海外より輸入の冷凍魚介から得られる肉は、安価ではあるものの、加熱調理のあとは、歩留が低くなる、パサついてジューシーさが乏しくなる、硬くて噛み切り難い、独特の臭みがあるなどの問題があり、おいしく喫食することは難しい。このような原料肉を用いて加工品を製造する場合、これまでに様々な改良方法が考案されてきた。   Under such circumstances, meat obtained from obsolete livestock, cross-breed livestock, dairy cattle, and frozen seafood imported from overseas are inexpensive, but after cooking, the yield is low, and the succulentness of pas It is difficult to eat deliciously because there are problems such as being scarce, hard and difficult to bite, and a unique smell. When manufacturing a processed product using such raw material meat, various improvement methods have been devised so far.

例えば、下記特許文献1、2、3、4、5、6では、澱粉や澱粉加水分解物を利用した肉類の製造方法、改質剤、改質方法等を開示している。しかしながら、これらの技術で得た肉類もしくは肉類加工品は、加熱調理すると、肉本来の食感の弱い、均一な、食感となってしまい、肉類本来の、繊維感のある、ソフトでジューシーな食感は十分に得られない。   For example, the following Patent Documents 1, 2, 3, 4, 5, and 6 disclose meat production methods, modifiers, modification methods, and the like using starch and starch hydrolysates. However, meat or processed meat products obtained by these techniques, when cooked, become a weak, uniform texture that is inherent to the meat, and is soft and juicy with the original texture of meat. A sufficient texture cannot be obtained.

また、下記特許文献7では、油脂、及びモノグリセリドとポリカルボン酸とのエステル及び/又はジグリセリドと、ポリカルボン酸とのエステルを含む組成物を肉類に添加している。しかしながら、この技術では、効果を十分に引き出すためには多量の上記組成物を添加することが必要となり、肉類本来の風味を損うことがあり、また、安定した、十分な効果が得られていないのが現状であった。   Moreover, in the following patent document 7, the composition containing fats and oils, ester of monoglyceride and polycarboxylic acid, and / or diglyceride, and ester of polycarboxylic acid is added to meat. However, with this technique, it is necessary to add a large amount of the above-described composition in order to fully obtain the effect, which may impair the original flavor of meat, and a stable and sufficient effect is obtained. There was no current situation.

また、下記特許文献8、9、10、11では、有機酸またはその塩類を、複数種類組み合わせて肉類に添加したり、それ以外の素材と組み合わせて肉類に添加している。しかしながら、これらの技術では、安定した効果を得ることが難しく、有機酸またはその塩類特有の欠点が肉類またはその加工品に呈してしまうことがあるため、満足のいく効果が得られていないのが現状であった。   In the following Patent Documents 8, 9, 10, and 11, a plurality of organic acids or salts thereof are added to meat in combination, or added to meat in combination with other ingredients. However, in these techniques, it is difficult to obtain a stable effect, and a defect peculiar to an organic acid or a salt thereof may be exhibited in meat or a processed product thereof. Therefore, a satisfactory effect is not obtained. It was the current situation.

また、下記特許文献12では、魚肉及び/又は畜肉を冷凍、凍結乾燥する際のタンパク質の変性を抑制するため、原料肉に対し、マルトテトラオース及び/又はその還元物を主成分とする糖質、マルトトリオース及び/又はその還元物を主成分とする糖質、又はサイクロデキストリン及び重合度3〜10のオリゴ糖を主成分とする糖質を添加している。しかしながら、これも、安定した効果が得られるとはいえず、改善の余地があった。
特開平9−308461号公報 特開平10−99051号公報 特開平11−266835号公報 特許第3180148号公報 特開平9−308462号公報 特開2000−157218号公報 特開平7−313105号公報 特開平6−343423号公報 特開2003−304836号公報 特開2000−79号公報 特開平11−133号公報 特公平7−75515号公報
Moreover, in the following patent document 12, in order to suppress protein denaturation when freezing and freeze-drying fish meat and / or livestock meat, a carbohydrate mainly composed of maltotetraose and / or a reduced product thereof is used as a raw material meat. , A saccharide mainly composed of maltotriose and / or a reduced product thereof, or a saccharide mainly composed of cyclodextrin and an oligosaccharide having a polymerization degree of 3 to 10 is added. However, it cannot be said that a stable effect is obtained, and there is room for improvement.
JP-A-9-308461 Japanese Patent Laid-Open No. 10-99051 JP-A-11-266835 Japanese Patent No. 3180148 JP-A-9-308462 JP 2000-157218 A JP-A-7-313105 JP-A-6-343423 JP 2003-304836 A Japanese Unexamined Patent Publication No. 2000-79 JP 11-133 A Japanese Patent Publication No. 7-75515

前述のように肉類の加工方法についてはこれまでに様々な研究がなされているが満足のできる結果は得られてはいないのが実情であった。   As described above, various studies have been conducted on meat processing methods so far, but satisfactory results have not been obtained.

よって、本発明は、肉類の加工、加熱調理後の歩留と風味、食感に優れ、更には加熱調理後、冷凍やチルド状態での保存を経た後の、電子レンジ加熱などの再加熱の後でも良好な風味と食感を損なうことがなく、安価に提供できる肉類加工品用改良剤、該改良剤を用いた肉類加工品の改質方法及び肉類加工品を提供することを目的とする。   Therefore, the present invention is excellent in the processing of meat, the yield and flavor after cooking, and the texture, and after cooking, after being frozen and stored in a chilled state, reheating such as microwave heating An object of the present invention is to provide an improved agent for processed meat products that can be provided at a low cost without losing good flavor and texture even afterwards, an improved method for processed meat products using the improved agent, and processed meat products. .

本発明者らは、上記目的を達成すべく鋭意検討した結果、オリゴ糖と澱粉質原料を原料となる肉類に同時に添加することで、それぞれが持つ機能を効果的に発揮し、更には、オリゴ糖、又は澱粉質原料を単独で添加した際には得られない、新たな効果が得られるということを見出した。   As a result of intensive studies to achieve the above object, the present inventors have demonstrated that each of the oligosaccharides and starchy raw materials are added to the raw meat at the same time, thereby effectively exerting their respective functions. It has been found that new effects can be obtained that cannot be obtained when a sugar or starchy raw material is added alone.

すなわち、本発明の肉類加工品用改良剤は、(A)オリゴ糖と、(B)澱粉質原料を含むことを特徴とする。   That is, the improving agent for processed meat products of the present invention is characterized by containing (A) an oligosaccharide and (B) a starchy raw material.

オリゴ糖と澱粉質原料を肉類に添加することで、それぞれが持つ機能を効果的に発揮し、加熱調理後の歩留と食感に優れ、更には加熱調理後、冷凍やチルド状態での保存を経た後、電子レンジ加熱などの再加熱によっても良好な風味と食感を損なうことがない肉類加工品とすることができる。   By adding oligosaccharides and starchy raw materials to meat, each of them effectively demonstrates their functions, has excellent yield and texture after cooking, and is also stored in a frozen or chilled state after cooking. After passing through, it can be set as the processed meat product which does not impair favorable flavor and food texture by reheating, such as microwave heating.

また、本発明の肉類加工品用改良剤は、(C)有機酸の可溶性塩、(D)アルカリ剤、(E)高分子多糖類を更に含むことを特徴とする。それによって前記のオリゴ糖と澱粉を併用したときに得られる前記の効果を、更に効果的に引き出すことができる。 Also, meat processed products for improving agent of the present invention is characterized with a soluble salt of (C) an organic acid, and (D) an alkali agent, a further including Mukoto and (E) high molecular polysaccharides. Thereby, the effect obtained when the oligosaccharide and starch are used in combination can be more effectively brought out.

そして、(A)成分は、マルトオリゴ糖、ニゲロオリゴ糖から選ばれた1種以上を主成分とする重合度3〜7のマルトオリゴ糖が主成分糖であることがより好ましい。 Then, (A) component, the main component at least one selected maltooligosaccharides two Geroorigo sugar or al. It is more preferable that the maltooligosaccharide having a polymerization degree of 3 to 7 is a main component sugar.

(B)成分は、酸処理、エステル化処理、エーテル化処理、架橋処理、油脂加工処理、湿熱処理から選ばれた1種又は2種以上の処理方法で加工した澱粉誘導体であることが好ましい。   The component (B) is preferably a starch derivative processed by one or more processing methods selected from an acid treatment, an esterification treatment, an etherification treatment, a crosslinking treatment, an oil and fat processing treatment, and a wet heat treatment.

(C)成分は、乳酸、クエン酸、リンゴ酸、コハク酸から選ばれた1種又は2種以上とするComponent (C), milk acid and citric acid, malic acid, and one or more selected or co Haq acid et al.

(D)成分は、炭酸ナトリウム、炭酸水素ナトリウム、ピロリン酸ナトリウム、ポリリン酸ナトリウムから選ばれた1種又は2種以上とするComponent (D) is sodium carbonate, sodium hydrogen carbonate, sodium pin pyrophosphate, with one or more selected ports Yi Lin acid sodium or al.

(E)成分は、キサンタンガム、コーンファイバー、カラギナンから選ばれた1種又は2種以上とするComponent (E), key Santangamu, and co over emission fiber, one or more selected from carrageenan.

そして、本発明の肉類加工品用改良剤では、肉類加工品用改良剤の固形分全量中における(A)成分と(B)成分は、質量比で(A)成分:(B)成分=1:9〜9:1であることが好ましい。   And in the improving agent for processed meat products of this invention, (A) component and (B) component in solid content whole quantity of the improved meat processing product component are (A) component: (B) component = 1 by mass ratio. : It is preferable that it is 9-9: 1.

また、肉類加工品用改良剤の(A)成分と(B)成分の固形分合計量を100質量部とした時、(C)成分の含有量は1〜50質量部、(D)成分の含有量は1〜40質量部、(E)成分の含有量は0.5〜30質量部であることが好ましい。   Moreover, when the solid content total amount of the (A) component and the (B) component of the improver for processed meat products is 100 parts by mass, the content of the (C) component is 1 to 50 parts by mass of the (D) component. The content is preferably 1 to 40 parts by mass, and the content of the component (E) is preferably 0.5 to 30 parts by mass.

本発明の肉類加工品の改質方法は、上記改良剤を肉類に添加することを特徴としており、肉類100質量部に対し、(A)成分0.05〜10質量部、及び(B)成分を0.05〜10質量部添加することが好ましい。   The method for modifying processed meat products of the present invention is characterized in that the above-mentioned improving agent is added to meat, and 0.05 parts by mass of component (A) and 10 parts by mass of component (B) with respect to 100 parts by mass of meat. It is preferable to add 0.05-10 mass parts.

更に、肉類100質量部に対し、(C)成分は0.01〜3質量部添加することが好ましく、(D)成分は0.005〜3質量部添加することが好ましく、(E)成分は0.005〜3質量部添加することが好ましい。   Furthermore, it is preferable to add 0.01-3 mass parts of (C) component with respect to 100 mass parts of meat, It is preferable to add 0.005-3 mass parts of (D) component, (E) component is It is preferable to add 0.005-3 mass parts.

そして、本発明の肉類加工品は、上記改質方法で得られた肉類加工品である。   The processed meat product of the present invention is a processed meat product obtained by the above modification method.

本発明の肉類加工品用改良剤は、(A)オリゴ糖としてマルトオリゴ糖、ニゲロオリゴ糖から選ばれた1種以上と、(B)澱粉質原料、(C)有機酸の可溶性塩として乳酸、クエン酸、リンゴ酸、コハク酸から選ばれた1種又は2種以上と、(D)アルカリ剤として炭酸ナトリウム、炭酸水素ナトリウム、ピロリン酸ナトリウム、ポリリン酸ナトリウムから選ばれた1種又は2種以上と、(E)高分子多糖類としてキサンタンガム、コーンファイバー、カラギナンから選ばれた1種又は2種以上とを含むものであり、該改良剤を原料となる肉類に添加することにより、個々の成分の相乗作用によって、加熱調理後の歩留と風味、食感に優れ、更には加熱調理後、冷凍やチルド状態での保存を経た後の、電子レンジ加熱などの再加熱の後でも良好な風味と食感を損なうことがない肉類加工品を提供することが出来る。 The improving agent for processed meat products of the present invention comprises: (A) at least one selected from malto-oligosaccharides and nigerooligosaccharides as oligosaccharides; (B) starchy raw materials ; and (C) lactic acid, citric acid as soluble salts of organic acids. One or more selected from acids, malic acid, and succinic acid, and (D) one or more selected from sodium carbonate, sodium bicarbonate, sodium pyrophosphate, and sodium polyphosphate as an alkaline agent , (E) one or more selected from xanthan gum, corn fiber, and carrageenan as the polymer polysaccharide , and by adding the improver to meat as a raw material, Due to the synergistic effect, it is excellent in yield, flavor and texture after cooking, and even after reheating such as microwave heating after cooking and storage in frozen or chilled state It is possible to provide a good that there is no compromising the flavor and texture of meat processed products.

そして、更に、発酵調味料を含む改良剤を用いることで、より良い食感と、風味を備えた肉類加工品を提供することが出来る。 And further, by using a modifier comprising originating酵調seasonings, and better texture, it is possible to provide a meat processed product having a flavor.

本発明の肉類加工品用改良剤は、オリゴ糖及び澱粉質原料を含むものである。   The improver for processed meat products according to the present invention includes an oligosaccharide and a starch raw material.

そして、本発明において使用可能な肉類とは、牛肉、豚肉、羊肉、山羊肉、馬肉、家兎肉、鹿肉などの畜肉、鶏肉、アヒル肉、ガチョウ肉、七面鳥肉などの家禽肉など、魚、イカ、タコ、カニ、エビなどの魚介肉などであり、加熱などの処理が施されていない肉類を総称し、冷凍肉、チルド肉、生鮮肉なども含む。また、使用する部位については、特に限定しない。更に、使用する肉類の形状は、比較的大きな肉塊であっても、チョッパー等を用いて挽肉にされていても、フードカッター等を用いてカッティングしてもよい。   The meats that can be used in the present invention include beef, pork, lamb, goat, horse meat, rabbit meat, venison and other livestock meat, chicken, duck meat, goose meat, turkey meat and other poultry meat, , Squid, octopus, crab, seafood such as shrimp, etc., and is a generic term for meats that have not been treated such as heating, including frozen meat, chilled meat, and fresh meat. Moreover, it does not specifically limit about the site | part to be used. Furthermore, the shape of the meat to be used may be a relatively large meat block, ground meat using a chopper or the like, or cutting using a food cutter or the like.

本発明の肉類加工用改良剤で用いるオリゴ糖としては、マルトオリゴ糖及び/又はニゲロオリゴ糖を使用する。マルトオリゴ糖を主成分糖とするものが好ましい。マルトオリゴ糖としては、重合度2〜10のマルトオリゴ糖がより好ましく、重合度3〜7である、マルトトリオース、マルトテトラオース、マルトペンタオース、マルトヘキサオース、マルトヘクタオースから選ばれたマルトオリゴ糖が最も好ましい。更には、上記オリゴ糖は単独で用いても、重合度の異なるオリゴ糖の混合物として用いても良い。 The oligosaccharide used in the meat processing improving agent of the present invention, a Ma Rutoorigo sugar and / or nigerooligosaccharides. Those having malto-oligosaccharide as the main sugar are preferred. As the maltooligosaccharide, a maltooligosaccharide having a polymerization degree of 2 to 10 is more preferable, and a maltooligosaccharide having a polymerization degree of 3 to 7 and selected from maltotriose, maltotetraose, maltopentaose, maltohexaose and maltohectorose. Is most preferred. Furthermore, the above oligosaccharides may be used alone or as a mixture of oligosaccharides having different degrees of polymerization.

本発明において、オリゴ糖は、シロップ状でも、スプレードライなど公知の方法で粉末状に乾燥したものでもよく、シロップ状のオリゴ糖の場合は、全固形分の合計が50%以上の濃度であることが好ましい。   In the present invention, the oligosaccharide may be syrup-like or dried in a powder form by a known method such as spray drying. In the case of syrup-like oligosaccharide, the total solid content has a concentration of 50% or more. It is preferable.

本発明の肉類加工用改良剤で用いる澱粉質原料は、特に限定はなく、例えば、コーンスターチ、ワキシーコーンスターチ、ハイアミロースコーンスターチ、タピオカ澱粉、馬鈴薯澱粉、小麦澱粉、粳米澱粉、餅米澱粉、サゴ澱粉、甘藷澱粉など通常市販されているものを好適に使用することができる。   The starchy raw material used in the meat processing improver of the present invention is not particularly limited, for example, corn starch, waxy corn starch, high amylose corn starch, tapioca starch, potato starch, wheat starch, glutinous rice starch, glutinous rice starch, sago starch, A commercially available product such as sweet potato starch can be preferably used.

また、澱粉質原料は未加工品であってもよいが、好ましくは、化学的又は/及び物理的に処理された加工品である。   The starchy raw material may be an unprocessed product, but is preferably a processed product that has been chemically or / and physically treated.

澱粉質原料の加工方法は、例えば、酸処理、エステル化処理、エーテル化処理、架橋処理、油脂加工処理、湿熱処理等が挙げられ、これら加工方法を1種または2種以上を選択して組み合わせて用いてもよい。   Examples of processing methods for starch raw materials include acid treatment, esterification treatment, etherification treatment, cross-linking treatment, fat and oil processing, wet heat treatment and the like, and these processing methods are selected by combining one or more kinds. May be used.

酸処理に用いる酸処理剤としては、例えば、次亜塩素酸ナトリウム、過酸化水素等から選ばれた一種以上が好ましく用いられる。   As the acid treatment agent used for the acid treatment, for example, one or more selected from sodium hypochlorite, hydrogen peroxide and the like are preferably used.

架橋処理に用いる架橋剤としては、例えば、オキシ塩化リン、ポリリン酸塩、メタリン酸塩、アジピン酸、アクロレイン、エピクロロヒドリン等から選ばれた一種以上が好ましく用いられる。   As the crosslinking agent used for the crosslinking treatment, for example, one or more selected from phosphorus oxychloride, polyphosphate, metaphosphate, adipic acid, acrolein, epichlorohydrin and the like are preferably used.

エステル化処理に用いるエステル化剤としては、例えば、無水酢酸、酢酸ビニル、無水マレイン酸、無水コハク酸、1−オクテニルコハク酸、オルトリン酸、ポリリン酸、メタリン酸等から選ばれた一種以上が好ましく用いられる。   As the esterifying agent used for the esterification treatment, for example, one or more selected from acetic anhydride, vinyl acetate, maleic anhydride, succinic anhydride, 1-octenyl succinic acid, orthophosphoric acid, polyphosphoric acid, metaphosphoric acid and the like are preferably used. It is done.

エーテル化処理に用いるエーテル化剤としては、例えば、エチレンオキシド、プロピレンオキシド等のアルキレンオキシドや、モノクロロ酢酸等が好ましく用いられる。   As the etherifying agent used for the etherification treatment, for example, alkylene oxides such as ethylene oxide and propylene oxide, monochloroacetic acid and the like are preferably used.

油脂加工処理とは、澱粉に食用油脂およびその類縁物などを添加し、均一になるまで混合した後、必要に応じて乾燥し、更に加熱処理する処理方法である。   Oil processing is a processing method in which edible oils and their analogs and the like are added to starch, mixed until uniform, then dried if necessary, and further heat-treated.

湿熱処理とは、澱粉を糊化するには不十分な水分の存在下で加熱処理することを意味し、例えば特開平4−130102号に示されるように、減圧ラインと加圧蒸気ラインの両方を敷設し、内圧、外圧共に耐圧性の密封できる容器内に澱粉を入れ、減圧した後、蒸気導入による加圧加熱を行ない、あるいはこの操作を繰り返すことにより、澱粉を所定時間加熱した後、冷却する方法が好ましく採用される。   The wet heat treatment means heat treatment in the presence of insufficient moisture to gelatinize the starch. For example, as shown in JP-A-4-130102, both a decompression line and a pressurized steam line are used. After placing the starch in a container that can seal both the internal and external pressures, and reducing the pressure, heat the starch by introducing steam, or repeat this operation to heat the starch for a specified time, and then cool it. The method is preferably employed.

そして、肉類加工用改良剤に含まれるオリゴ糖と澱粉質原料の含有量は、質量比でオリゴ糖:澱粉質原料=1:9〜9:1であることが好ましく、より好ましくは3:7〜7:3である。   The content of the oligosaccharide and the starch raw material contained in the meat processing improver is preferably oligosaccharide: starch raw material = 1: 9 to 9: 1 by mass ratio, more preferably 3: 7. ~ 7: 3.

更に、オリゴ糖の肉類加工品への添加量は、原料肉類100質量部に対し0.05〜10質量部とすることが好ましく、より好ましくは0.1〜6質量部である。添加量が0.05質量部未満であると、本発明で期待する効果を十分に得ることができず、また、10質量部より多いと、肉類加工品の加熱調理時に、オリゴ糖の流出量が多くなってしまうため好ましくない。   Furthermore, the addition amount of the oligosaccharide to the processed meat product is preferably 0.05 to 10 parts by mass, more preferably 0.1 to 6 parts by mass with respect to 100 parts by mass of the raw meat. If the addition amount is less than 0.05 parts by mass, the effect expected in the present invention cannot be sufficiently obtained. If the addition amount is more than 10 parts by mass, the amount of oligosaccharide efflux during cooking of processed meat products Is unfavorable because of an increase in the amount of.

更に、澱粉質原料の肉類加工品への添加量は、原料肉類100質量部に対し、0.05〜10質量部とすることが好ましく、より好ましくは0.1〜6質量部である。添加量が0.05質量部未満であると肉類のソフト化、歩留の向上などの効果はほとんど得られず、10質量部より多いと、肉類加工品のジューシーさ、ソフトさが薄れてしまうため好ましくない。   Furthermore, the addition amount of the starchy raw material to the processed meat product is preferably 0.05 to 10 parts by mass, more preferably 0.1 to 6 parts by mass with respect to 100 parts by mass of the raw meat. If the added amount is less than 0.05 parts by mass, effects such as softening meat and improving yield are hardly obtained, and if it is more than 10 parts by mass, the juiciness and softness of processed meat products will be reduced. Therefore, it is not preferable.

オリゴ糖は、前記の通りに原料肉類に配合することで、その効果を引き出すことが可能であるが、肉類加工品は加熱調理の際に焼き縮みを起こし、配合したオリゴ糖の一部、又は大部分が流出してしまうため、十分な効果が得られなかった。   The oligosaccharide can be extracted from the raw meat as described above to bring about its effect. However, the processed meat product is baked and shrunk during cooking, and a part of the mixed oligosaccharide, or Since most of the spilled out, sufficient effects could not be obtained.

また、澱粉質原料を原料肉類に配合することで、加熱調理時に肉汁の流出を抑制し、その歩留を向上させることは可能であるが、特に畜肉類の加工品においては、食感が均一で噛み応えが弱く、ジューシーさに乏しいものになりがちで、肉本来の食感が薄れてしまう欠点があった。   In addition, it is possible to improve the yield by suppressing the outflow of gravy during cooking by mixing the starchy raw material with raw material meat, but the texture is uniform especially in processed meat products However, there is a drawback that the chewing response is weak and the juiciness tends to be poor, and the original texture of the meat is diminished.

しかしながら、オリゴ糖と澱粉質原料を同時に配合することで、加熱調理の際の肉汁の流出を抑えつつ、肉本来の繊維感のある、ソフトでジューシーな食感を付与することができる。   However, by blending the oligosaccharide and the starchy raw material at the same time, it is possible to impart a soft and juicy texture with the original fiber feeling while suppressing the outflow of meat juice during cooking.

そして、本発明の肉類加工用改良剤は、オリゴ糖と澱粉質原料の他に、更に有機酸の可溶性塩、アルカリ剤、水溶性高分子多糖類を含む。これにより、肉類加工品の食感、風味をより好ましく、そして効果的に改良することが可能である。また、更に発酵調味料を含むものであることが好ましい。 The meat processing improver of the present invention further contains a soluble salt of an organic acid, an alkali agent, and a water-soluble polymeric polysaccharide in addition to the oligosaccharide and the starchy raw material . Thus, the texture of meat such processed products, it is possible to more preferably the flavor and effectively improved. Moreover, it is preferable that a fermented seasoning is included.

本発明の肉類加工用改良剤で用いることのできる有機酸の可溶性塩とは、乳酸、クエン酸、リンゴ酸、コハク酸の塩の中から選ばれた1種又は2種以上である。 The soluble salts of organic acids which can be used in meat processing improving agent of the present invention, milk acid, citric acid, malic acid, is one or more selected from among salts of co Haku acid.

そして、肉類加工用改良剤中のオリゴ糖と澱粉質原料の固形分合計量を100質量部とした時、有機酸の可溶性塩の含有量は、1〜50質量部であることが好ましく、より好ましくは2〜25質量部である。   And, when the total solid content of the oligosaccharide and starchy raw material in the meat processing improver is 100 parts by mass, the content of the soluble salt of the organic acid is preferably 1 to 50 parts by mass, more Preferably it is 2-25 mass parts.

更に、有機酸の可溶性塩の肉類加工品への添加量は、原料肉類100質量部に対し、0.01〜3質量部とすることが好ましく、より好ましくは0.1〜2質量部である。添加量が0.01質量部より少ないと、有機酸塩の効果をほとんど得ることができず、添加量が5質量部より多いと、有機酸独特の風味が肉類加工品に出てしまうなど、好ましくない影響が出てしまう。   Furthermore, the addition amount of the organic acid soluble salt to the processed meat product is preferably 0.01 to 3 parts by mass, more preferably 0.1 to 2 parts by mass with respect to 100 parts by mass of the raw meat. . When the addition amount is less than 0.01 parts by mass, the effect of the organic acid salt can hardly be obtained, and when the addition amount is more than 5 parts by mass, the flavor unique to organic acids appears in processed meat products, Undesirable effects will occur.

本発明の肉類加工用改良剤で用いることのできるアルカリ剤とは、炭酸ナトリウム、炭酸水素ナトリウム、ピロリン酸ナトリウム、ポリリン酸ナトリウムが挙げられるThe alkali agent can be used in meat processing improving agent of the present invention, sodium carbonate, sodium hydrogen carbonate, sodium pin pyrophosphate, sodium Po Yi Lin acid.

本発明では、上記のアルカリ剤の中から1種以上を選択して用いるが、市販されている製剤化されたアルカリ剤を使用することも可能である。 In the present invention, Ru used by selecting one or more of the above alkali agents, it is also possible to use formulated alkali agents are city sales.

そして、肉類加工用改良剤中のオリゴ糖と澱粉質原料の固形分合計量を100質量部とした時、アルカリ剤の含有量は、1〜40質量部であることが好ましく、より好ましくは2〜25質量部である。   When the total solid content of the oligosaccharide and starch raw material in the meat processing improver is 100 parts by mass, the content of the alkaline agent is preferably 1 to 40 parts by mass, more preferably 2 ˜25 parts by mass.

更に、アルカリ剤の肉類加工品への添加量は、原料肉類100質量部に対し0.005〜3質量部とすることが好ましく、より好ましくは0.01〜2質量部である。アルカリ剤の含有量が0.005質量部より少ないと、アルカリ剤の効果をほとんど得ることができず、3質量部より多いと、使用したアルカリ剤独特の風味など、アルカリ剤の持つ欠点が肉類加工品に出てしまうため好ましくない。   Furthermore, the addition amount of the alkaline agent to the processed meat product is preferably 0.005 to 3 parts by mass, more preferably 0.01 to 2 parts by mass with respect to 100 parts by mass of the raw meat. If the content of the alkali agent is less than 0.005 parts by mass, the effect of the alkali agent can hardly be obtained, and if it is more than 3 parts by mass, the disadvantages of the alkali agent such as the flavor unique to the alkali agent used are meats. Since it will appear in a processed product, it is not preferable.

本発明の肉類加工用改良剤で用いる高分子多糖類としては、カラギナン、キサンタンガム、コーンファイバーの中から1種以上を選択して用いる。
The polymer polysaccharides used in the meat processing improving agent of the present invention, mosquitoes Raginan, key Santangamu, selected and used one or more of the co-chromatography emission fiber.

そして、肉類加工用改良剤中のオリゴ糖と澱粉質原料の固形分合計量を100質量部とした時、高分子多糖類の含有量は、0.5〜30質量部であることが好ましく、より好ましくは1.5〜15質量部である。   And when the total solid content of the oligosaccharide and starch raw material in the meat processing improver is 100 parts by mass, the content of the high molecular polysaccharide is preferably 0.5 to 30 parts by mass, More preferably, it is 1.5-15 mass parts.

更に、高分子多糖類の肉類加工品への添加量は、原料肉類100質量部に対し0.005〜3質量部とすることが好ましく、より好ましくは0.01〜1質量部である。高分子多糖類の含有量が0.005質量部より少ないと、高分子多糖類の効果をほとんど得ることができず、3質量部より多いと、ジューシーさが弱まるなど、食感に悪影響を及ぼしてしまう。   Furthermore, the addition amount of the polymer polysaccharide to the processed meat product is preferably 0.005 to 3 parts by mass, more preferably 0.01 to 1 part by mass with respect to 100 parts by mass of the raw meat. If the content of the polymer polysaccharide is less than 0.005 parts by mass, the effect of the polymer polysaccharide can hardly be obtained, and if it is more than 3 parts by mass, the juiciness will be weakened and the texture will be adversely affected. End up.

その他に副成分として、醤油、味噌、食酢、みりんや清酒タイプ発酵調味料、ワインタイプ発酵調味料などの発酵調味料類、ビーフエキス、ポークエキス、チキンエキスなどの畜肉エキス類、かつおエキス、帆立貝エキス、蛎エキス、昆布エキスなどの魚介エキス類、グルタミン酸ナトリウム、イノシン酸ナトリウムなどの単一化学調味料類などの各種調味料、食塩、植物性タンパク質、動物性タンパク質、ならびにこれらを加水分解したもの、発色剤、香辛料等を更に用いてもよい。   In addition, fermented seasonings such as soy sauce, miso, vinegar, mirin and sake type fermented seasoning, wine type fermented seasoning, livestock meat extracts such as beef extract, pork extract, chicken extract, bonito extract, scallop extract , Seafood extracts such as salmon extract and kelp extract, various seasonings such as single chemical seasonings such as sodium glutamate and sodium inosinate, salt, vegetable protein, animal protein, and hydrolyzed products thereof, Coloring agents, spices and the like may be further used.

本発明の肉類加工品用改良剤は、オリゴ糖及び澱粉質原料を必須とする上記原料を、含むものであれば良く、その製品形態としては特に限定されないが、好ましい形態としては、例えば粉末状または混合液状に製剤化したもの、各原料の性状により、粉末状と液体状を別々に製剤化したもの、用途や使用方法に応じて幾つかに分けて製剤化したしたものなどがある。   The improver for processed meat products of the present invention is not particularly limited as a product form as long as it contains the above-mentioned raw materials essential for oligosaccharides and starchy raw materials. Alternatively, there are those formulated into mixed liquids, powders and liquids separately formulated according to the properties of each raw material, and those divided into several according to applications and usage methods.

次に、本発明の肉類加工品の改質方法について説明する。
本発明の肉類加工品の改質方法とは、加熱又は未加熱の原料肉類に対し、上記肉類加工品用改良剤を添加する処理方法である。
Next, a method for modifying processed meat products according to the present invention will be described.
The method for modifying processed meat products according to the present invention is a processing method in which the improving agent for processed meat products is added to raw or unheated raw meat.

原料肉類への添加方法としては特に限定はなく、上記改良剤をピックル液とし、これをインジェクション、タンブリング、カッティングする方法、上記改良剤を原料肉類に直接添加し、サイレントカッターなどでこれをカッティングする方法、上記改良剤と原料肉類を練り込む方法などが挙げられるが、この限りではない。   There is no particular limitation on the method of adding to the raw meat, the above improving agent is used as a pickle liquid, this is a method of injection, tumbling and cutting, the above improving agent is directly added to the raw meat, and this is cut with a silent cutter or the like. Examples thereof include a method, a method of kneading the improver and raw meats, but are not limited thereto.

なお、本発明の肉類加工品の改質方法では、上記原料を改良剤として調合して用いなくてもよく、改良剤の各原料を原料となる肉類にそれぞれ添加してもよい。改良剤の各原料の好ましい添加量は、前述した通りである。   In the method for modifying processed meat products according to the present invention, the raw materials may not be prepared and used as an improving agent, and each raw material of the improving agent may be added to meat as a raw material. The preferable addition amount of each raw material of the improving agent is as described above.

上記改質方法により得られた肉類加工品は、風味、食感に優れたものであり、例えば、ステーキ、焼肉、焼鳥、角煮、焼豚、ハム類、ベーコン類、ローストビーフ、カツ、生姜焼き、唐揚げなど、比較的大きな肉塊を用いて加工、調理するものや、ソーセージ類、ハンバーグ、ハンバーグパティ、ナゲット、つくね、肉団子、メンチカツ、コロッケ、中華まんの具材など、挽肉や細かいブロックを他の素材と一緒に練ることで得るものや、カッティングして加工するものなどにも適用できる。また、シチュー、カレー、筑前煮、肉じゃがなどの煮込み食品の具材や、肉野菜炒め、八宝菜、チンジャオロースなど、炒め物の具材などにも用いることができる。カマボコ、ハンペン、ちくわ、魚肉ソーセージ等の魚介類すり身を用いた加工品、魚肉フライ、魚肉ソテー等の加工品にも利用できる。また、肉類加工品としては、加熱調理前の状態で上記改良剤を添加した後加熱調理したもの、加熱調理をしないもの、半調理の状態のもので、チルドもしくは冷凍で流通させるものがあるが、特にこれらに限定しない。   The processed meat product obtained by the above modification method is excellent in flavor and texture, such as steak, yakiniku, yakitori, kaku boiled, grilled pork, ham, bacon, roast beef, cutlet, grilled ginger, Minced meat and fine blocks such as fried chicken, processed and cooked using relatively large chunks of meat, sausages, hamburger, hamburger patties, nuggets, meatballs, meatballs, croquettes, Chinese bun ingredients, etc. It can also be applied to materials obtained by kneading together with other materials and materials processed by cutting. It can also be used for ingredients for stewed food such as stew, curry, boiled Chikuzen, and meat potato, and ingredients for stir-fried foods such as stir-fried meat and vegetables, Happo vegetables and tinjaoulose. It can also be used for processed products using fishery products such as sea bream, hampen, chikuwa, and fish sausage, and processed products such as fried fish and sauteed fish. In addition, as processed meat products, there are those that are cooked after adding the above-mentioned improver in the state before cooking, those that are not cooked, those that are half-cooked, and those that are circulated by chilled or frozen However, it is not particularly limited to these.

以下に実施例を挙げて本発明を具体的に説明するが、本発明はこれらにより限定されるものではない。   EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited thereto.

<試験例1>
表1に示す原料及び調合量で製造例1〜8のピックル液を調製した。ピックル液は、冷水に表1に記載の各成分を添加して混合液にした後、高圧ホモゲナイザーで、70barで加圧して均質化した。なお、表1に示す各原料の配合量は質量%で表す。
<Test Example 1>
The pickle liquids of Production Examples 1 to 8 were prepared using the raw materials and blending amounts shown in Table 1. The pickle solution was homogenized by adding each component shown in Table 1 to cold water to make a mixed solution, and then applying pressure at 70 bar with a high-pressure homogenizer. In addition, the compounding quantity of each raw material shown in Table 1 is represented by the mass%.

なお、調味料として、食塩及びグルタミン酸ナトリウムを、オリゴ糖として、マルトトリオースが主成分糖で、固形分換算で60%以上含有する、固形分70%のオリゴ糖シラップ(以下よりオリゴ糖Aと記す)を、澱粉質原料として、酢酸エステル化処理をしたタピオカ澱粉(以下より澱粉Aと記す)を、有機酸の可溶性塩として、50%乳酸ナトリウム水溶液を、アルカリ剤として炭酸ナトリウムを、高分子多糖類としてキサンタンガムを用いた。   In addition, as a seasoning, sodium sugar and glutamate are used as oligosaccharides, and maltotriose is a main component sugar and contains 60% or more in terms of solid content, an oligosaccharide syrup having a solid content of 70% (hereinafter referred to as oligosaccharide A and ) As a starchy raw material, tapioca starch (hereinafter referred to as starch A) treated with acetic acid ester, as a soluble salt of organic acid, 50% sodium lactate aqueous solution, sodium carbonate as alkaline agent, polymer Xanthan gum was used as the polysaccharide.

また、原料肉類として、市販の冷凍牛肉ブロックを、冷蔵庫中で解凍したものを用いた。   Moreover, what thawed | compressed the commercially available frozen beef block in the refrigerator was used as raw material meat.

Figure 0004555178
Figure 0004555178

原料肉類100質量部に、製造例1〜8のピックル液を20質量部インジェクションした後、凍結して保存した。その後、この肉塊を冷蔵庫中で解凍した。   20 parts by mass of the pickle liquids of Production Examples 1 to 8 were injected into 100 parts by mass of raw meat, and then frozen and stored. Then, this meat chunk was thawed in the refrigerator.

解凍した肉塊を、1cm厚にスライスしてステーキ肉原料とし、一枚ごとの重量を測定した。このスライス肉を、約200℃に熱したホットプレートで中心温度が80℃になるまで焼成し、ステーキを作製した。このステーキの重量を測定し、次の方法によって焼成歩留を算出した。
「焼成歩留」=焼成後肉重量÷焼成前原料肉重量×100
The thawed meat chunk was sliced to a thickness of 1 cm to make a steak meat material, and the weight of each piece was measured. The sliced meat was baked with a hot plate heated to about 200 ° C. until the center temperature reached 80 ° C., to prepare steak. The weight of this steak was measured, and the firing yield was calculated by the following method.
“Baking Yield” = Meat weight after baking ÷ Raw meat weight before baking × 100

また、焼成直後のステーキ肉を試食し、「ソフトさ」、「ジューシーさ」、「肉の繊維感」、「風味」を10名の熟練パネラーにより官能検査を実施し、「5点」;良い、「4点」;やや良い、「3点」;普通、「2点」;やや悪い、「1点」;悪い、の5段階で評価した。更に、前記4項目を含めた、ステーキ肉のおいしさを総合的に評価し、これを「総合評価」とした。評価の結果は、各パネラーの点数を平均し、表2に結果を示す。





































In addition, the steak meat immediately after baking was sampled, and "softness", "juiciness", "meat fiber feeling", and "flavor" were subjected to a sensory test by 10 skilled panelists, "5 points"; , “4 points”; Slightly good, “3 points”; Normal, “2 points”; Slightly bad, “1 point”; Furthermore, the deliciousness of the steak meat including the above four items was comprehensively evaluated, and this was designated as “total evaluation”. The result of evaluation is the average of the scores of each panel, and the results are shown in Table 2.





































Figure 0004555178
Figure 0004555178

比較例1は、原料肉にインジェクション処理を施さず、そのままスライスして焼成し、評価を実施したものである。比較例1の肉類加工品は、硬く、ジューシー感に欠けており、牛肉独特の臭みが強かったため、総合評価も低くなった。比較例2の肉類加工品は、オリゴ糖を添加したことで焼成歩留、ソフトさ、ジューシーさ、風味は、比較例1より向上したものの、好ましいものではなかった。また、比較例3の肉類加工品は、砂糖と澱粉質原料とを併用したものであるが、焼成歩留は高くなったものの、ステーキには不自然な甘味が強く感じられた。比較例4の肉類加工品は澱粉質原料を添加したことで、ソフトさは向上したものの、その他の項目は十分でなく、総合評価も低くなった。比較例5の肉類加工品は有機酸の可溶性塩を添加したことで風味の改善に効果が見られたが、その他の項目では顕著な効果は見られなかった。   In Comparative Example 1, the raw meat was not subjected to the injection treatment, and was sliced and baked as it was and evaluated. The processed meat product of Comparative Example 1 was hard, lacking a juicy feeling, and had a strong beef-specific odor, resulting in a low overall evaluation. The processed meat product of Comparative Example 2 was not preferable although the baking yield, softness, juiciness, and flavor were improved as compared with Comparative Example 1 by adding oligosaccharides. In addition, the processed meat product of Comparative Example 3 was a combination of sugar and starchy raw material, but although the baking yield was high, unnatural sweetness was strongly felt in the steak. In the processed meat product of Comparative Example 4, although the softness was improved by adding the starchy raw material, other items were not sufficient, and the overall evaluation was also low. The processed meat product of Comparative Example 5 was effective in improving the flavor by adding a soluble salt of an organic acid, but no significant effect was observed in other items.

一方、原料肉類にオリゴ糖と澱粉質原料を添加した実施例1の肉類加工品では、ソフトさ、ジューシーさ、繊維感のいずれも向上し、風味についても、牛肉独特の臭みが改善され、好ましい結果となった。実施例2の肉類加工品は、ソフトさ、ジューシーさが共に実施例1よりも向上し、繊維感も好ましく、総合評価も高い評点となった。更に、有機酸の可溶性塩、アルカリ剤、及び高分子多糖類の1種以上を含む実施例3〜4の肉類加工品はより食感、風味、焼成歩留の良いものであり、牛肉独特の臭みもを殆ど感じず、旨味のある、ステーキとして好ましい風味となった。なかでも、有機酸の可溶性塩、アルカリ剤、高分子多糖類の全て含んだ実施例4の肉類加工品は特に優れた評価が得られ、締まった食感になりつつも、ソフトさ、ジューシーさ、肉の繊維感、風味がいずれも好ましい評価となった。   On the other hand, the processed meat product of Example 1 in which oligosaccharides and starchy raw materials are added to the raw meat is improved in all of the softness, juiciness, and fiber feeling, and the flavor of the beef is improved, which is preferable. As a result. The processed meat product of Example 2 was improved in both softness and juiciness as compared with Example 1, the fiber feeling was preferable, and the overall evaluation was high. Furthermore, the processed meat products of Examples 3 to 4 containing one or more of a soluble salt of an organic acid, an alkaline agent, and a high molecular weight polysaccharide have a better texture, flavor, and baking yield. Almost no odor was felt, and the flavor became delicious and delicious as a steak. Among them, the processed meat product of Example 4 containing all of the soluble salts of organic acids, alkali agents, and high molecular polysaccharides was particularly excellent in evaluation, and although it had a tight texture, it was soft and juicy. In addition, the fiber feeling and flavor of the meat were all favorable evaluations.

<試験例2>
表3に示す原料及び調合量で製造例9〜12のピックル液を調製した。ピックル液は、冷水に表3に記載の各成分を添加して混合液にした後、高圧ホモゲナイザーで、70barで加圧して均質化した。なお、表3に示す各原料の配合量は質量%で表す。
<Test Example 2>
Pickle liquids of Production Examples 9 to 12 were prepared using the raw materials and blending amounts shown in Table 3. The pickle solution was made into a mixed solution by adding each component shown in Table 3 to cold water, and then homogenized by pressurizing at 70 bar with a high-pressure homogenizer. In addition, the compounding quantity of each raw material shown in Table 3 is represented by the mass%.

なお、調味料として、食塩及びグルタミン酸ナトリウムを、オリゴ糖として、マルトヘキサオースとマルトヘプタオースが主成分糖で、固形分換算で40%以上を含有する、固形分が70%のオリゴ糖シロップ(以下よりオリゴ糖Bと記す)を、澱粉質原料として、リン酸架橋したコーンスターチ(以下より澱粉Bと記す)を、有機酸の可溶性塩として、コハク酸ナトリウムを、アルカリ剤として、ポリリン酸ナトリウムを、高分子多糖類として、キサンタンガムを用いた。   In addition, as a seasoning, salt and sodium glutamate are used as oligosaccharides, maltohexaose and maltoheptaose are main component sugars, and contain 40% or more in terms of solid content, and an oligosaccharide syrup having a solid content of 70% ( Hereinafter, oligosaccharide B) is used as a starch raw material, phosphoric acid-crosslinked corn starch (hereinafter referred to as starch B) is used as a soluble salt of an organic acid, sodium succinate is used as an alkaline agent, and sodium polyphosphate is used. Xanthan gum was used as the polymer polysaccharide.

また、原料肉類として市販の冷凍豚肉を冷蔵庫中で解凍したものを用いた。
















Moreover, what thawed commercially available frozen pork in a refrigerator was used as raw material meat.
















Figure 0004555178
Figure 0004555178

原料肉類100質量部に、製造例9〜12のピックル液30質量部をインジェクションした後、凍結して保存した。その後、この肉塊を冷蔵庫中で解凍した。   After injecting 30 parts by mass of the pickle liquids of Production Examples 9 to 12 into 100 parts by mass of the raw meat, the meat was frozen and stored. Then, this meat chunk was thawed in the refrigerator.

解凍した肉塊は、1cm厚にスライスしてトンカツ用肉とした。油脂加工コーンスターチを100質量部に対し、冷水160質量部を添加して均一なスラリーとして、トンカツ用肉100質量部に対してバッタースラリー30質量部を、肉の表面に均一に付け、更にその上からパン粉を均一にまぶし、約180℃で油ちょうしてトンカツを作製した。   The thawed meat chunk was sliced to a thickness of 1 cm to obtain meat for tonkatsu. Add 100 parts by mass of cold water to 100 parts by mass of the oil and fat processed corn starch, add 30 parts by mass of batter slurry to 100 parts by mass of meat for tonkatsu, and uniformly apply to the meat surface. The bread crumbs were uniformly sprinkled and oiled at about 180 ° C. to prepare tonkatsu.

この揚げたて直後のトンカツを試食し、「ソフトさ」、「ジューシーさ」、「肉の繊維感」、「風味」を10名の熟練パネラーにより官能検査を実施し、「5点」;良い、「4点」;やや良い、「3点」;普通、「2点」;やや悪い、「1点」;悪い、の5段階で評価した。更に、前記4項目を含めた、ステーキ肉のおいしさを総合的に評価し、これを「総合評価」とした。評価の結果は、各パネラーの点数を平均し、表4に結果を示す。   The freshly-cut fried tonkatsu was tasted, and "softness", "juiciness", "texture of meat", and "flavor" were subjected to sensory inspections by 10 skilled panelists. "5 points"; Evaluation was made in five stages: “4 points”; somewhat good, “3 points”; normal, “2 points”; somewhat bad, “1 point”; Furthermore, the deliciousness of the steak meat including the above four items was comprehensively evaluated, and this was designated as “total evaluation”. The result of evaluation is the average of the scores of each panel, and the results are shown in Table 4.

Figure 0004555178
Figure 0004555178

比較例6の肉類加工品は、ピックル液をインジェクションしていない無処理の原料肉を用い、前述の方法でトンカツを調製したものである。肉質が硬く、繊維感はあるものの、硬さの方が勝ったため、繊維感についても良い評価にはならなかった。また、ジューシーさもなく、パサパサとした食感を強く感じたため、総合評価も著しく低くなった。比較例7の肉類加工品は、オリゴ糖が配合されていないため、ソフトさを強く感じるものの、ジューシーさ、繊維感、風味の評価は低く、総合評価も低くなった。   The processed meat product of Comparative Example 6 is prepared by using the untreated raw material meat that has not been injected with the pickle liquid and preparing tonkatsu by the method described above. Although the flesh was hard and there was a feeling of fiber, since the hardness was superior, the fiber feeling was not evaluated well. Moreover, since there was no succulent feeling and the texture was crisp, the overall evaluation was significantly lower. Although the processed meat product of Comparative Example 7 did not contain oligosaccharides, the softness felt strongly, but the evaluation of juiciness, fiber feeling and flavor was low, and the overall evaluation was also low.

一方、原料肉類にオリゴ糖、澱粉質原料及び高分子多糖類を添加した実施例5の肉類加工品は、ソフトさとジューシーさが著しく改善され、更に有機酸塩を添加した実施例6の肉類加工品は、風味も旨味が増しており、臭みのないものであり、有機酸の可溶性塩とアルカリ剤とを添加した実施例7は、ソフトさとジューシーさに優れ、繊維感と風味が好ましく、とんかつとして好ましいものであった。   On the other hand, the processed meat product of Example 5 in which oligosaccharides, starchy raw materials and high molecular weight polysaccharides were added to the raw meat was significantly improved in softness and juiciness, and the meat processing of Example 6 in which an organic acid salt was further added. The product has an increased flavor and umami, and has no odor, and Example 7 to which a soluble salt of an organic acid and an alkaline agent are added is excellent in softness and juiciness, and a fiber feeling and flavor are preferable. As preferred.

<試験例3>
表5に示す原料及び調合量で製造例13〜17のピックル液を調製した。ピックル液は、冷水に表5に記載の各成分を添加して混合液にした後、高圧ホモゲナイザーで、70barで加圧して均質化した。なお、表5に示す各原料の配合量は質量%で表す。
<Test Example 3>
Pickle liquids of Production Examples 13 to 17 were prepared using the raw materials and blending amounts shown in Table 5. The pickle solution was homogenized by adding each component shown in Table 5 to cold water to make a mixed solution, and then pressurizing with a high-pressure homogenizer at 70 bar. In addition, the compounding quantity of each raw material shown in Table 5 is represented by the mass%.

なお、調味料として、食塩及びグルタミン酸ナトリウムを、オリゴ糖として、ニゲロオリゴ糖が主成分糖で、固形分換算で50%以上を含有する、固形分が70%のオリゴ糖シロップ(以下よりオリゴ糖Cと記す)を、澱粉質原料として、リン酸架橋したワキシーコーンスターチ(以下より澱粉Cと記す)を、有機酸の可溶性塩として、リンゴ酸ナトリウムを、アルカリ剤として、炭酸水素ナトリウムを、高分子多糖類として、水溶性コーンファイバーを用いた。比較対照として、デキストリン(DE10)を使用した。   In addition, salt and sodium glutamate as seasonings, and oligosaccharide syrup (hereinafter referred to as Oligosaccharide C) containing 70% or more of solids in terms of solid content, with nigerooligosaccharide being the main component sugar and oligosaccharide. ) As a starch raw material, phosphoric acid-crosslinked waxy corn starch (hereinafter referred to as starch C), as a soluble salt of organic acid, sodium malate as an alkaline agent, sodium bicarbonate as a high molecular weight polymer. Water-soluble corn fiber was used as the saccharide. As a comparative control, dextrin (DE10) was used.

また、原料肉類として市販の冷凍鶏肉を、冷蔵庫中で解凍したものを用いた。



























Moreover, the thing which thawed | compressed commercially available frozen chicken in the refrigerator as raw material meat was used.



























Figure 0004555178
Figure 0004555178

原料肉類100質量部に、製造例13〜17のピックル液20質量部をタンブリング処理した後、凍結して保存した。次にこの肉塊を、冷蔵庫中で解凍した。解凍した肉塊は、3cm×3cm×3cmの立方体状に切り出し、唐揚げ用肉とした。   After 100 parts by mass of raw material meat was tumbled with 20 parts by mass of the pickle liquids of Production Examples 13 to 17, they were stored frozen. The meat mass was then thawed in the refrigerator. The thawed meat block was cut into a 3 cm × 3 cm × 3 cm cube and used as fried meat.

この唐揚げ用肉に、唐揚げ粉を均一にまぶし、約180℃で油ちょうして唐揚げを作製した。そして、揚げたて直後の唐揚げを試食し、「ソフトさ」、「ジューシーさ」、「肉の繊維感」、「風味」を10名の熟練パネラーにより官能検査を実施し、「5点」;良い、「4点」;やや良い、「3点」;普通、「2点」;やや悪い、「1点」;悪い、の5段階で評価した。更に、前記4項目を含めた、ステーキ肉のおいしさを総合的に評価し、これを「総合評価」とした。評価の結果は、各パネラーの点数を平均し、表6に結果を示す。












































To this deep-fried meat, deep-fried flour was evenly sprinkled and oiled at about 180 ° C. to prepare deep-fried chicken. Then, taste the fried chicken right after it is fried, and perform sensory tests with 10 skilled panelists on “softness”, “juiciness”, “meat fiber feeling”, and “flavor”, “5 points”; , “4 points”; Slightly good, “3 points”; Normal, “2 points”; Slightly bad, “1 point”; Furthermore, the deliciousness of the steak meat including the above four items was comprehensively evaluated, and this was designated as “total evaluation”. The result of evaluation is the average of the scores of each panel, and the results are shown in Table 6.












































Figure 0004555178
Figure 0004555178

比較例8の肉類加工品は、ピックル液を添加しない未処理の原料肉を用い、他は前記と同様に調製したものである。硬くてジューシーさが乏しく、鶏肉独特の臭みも強いため、総合評価も低くなった。また、オリゴ糖の代わりにDE10のデキストリンを用い、澱粉質原料と併用して添加した比較例9の肉類加工品は、加熱歩留は比較例8に比べ向上したが、ソフトさ、ジューシーさ、繊維感の改善効果は十分とは言えず、総合評価も悪くなった。   The processed meat product of Comparative Example 8 was prepared in the same manner as described above, using untreated raw material meat to which no pickle solution was added. It is hard and juicy, and the unique smell of chicken is strong, resulting in a low overall rating. The processed meat product of Comparative Example 9 using DE10 dextrin instead of oligosaccharide and added in combination with the starchy material improved the heating yield compared to Comparative Example 8, but the softness, juiciness, The fiber feeling improvement effect was not sufficient, and the overall evaluation also deteriorated.

一方、原料肉類にオリゴ糖、澱粉質原料及び高分子多糖類を添加した実施例8の肉類加工品は、肉の繊維感を感じつつも、ソフトさ、ジューシーさが向上し、臭みが殆ど無くなった。更に有機酸の可溶性塩又はアルカリ剤を添加した実施例9、10の肉類加工品は、更に風味が改善され、繊維の締まった食感になりつつも、ソフトさとジューシーさを併せもつ、旨味のある唐揚げとなり、有機酸の可溶性塩及びアルカリ剤を添加した実施例11の肉類加工品は、最も旨み、食感のよい唐揚げとすることができた。   On the other hand, the processed meat product of Example 8 in which oligosaccharides, starchy raw materials and high molecular weight polysaccharides were added to raw meats improved the softness and juiciness while feeling the fiber feel of the meat, and almost no odor. It was. Furthermore, the processed meat products of Examples 9 and 10 to which a soluble salt of an organic acid or an alkali agent was added further improved the flavor and the texture of the fibers was tight, while having a soft and juicy taste. A processed deep-fried meat product of Example 11 in which a soluble salt of an organic acid and an alkaline agent were added was able to be a deep-fried chicken with the best taste and texture.

<試験例4>
表7に示す原料及び調合量で牛豚合挽きハンバーグを調製した。なお、表7に示す各原料の配合量は原料肉類(牛豚合挽き肉)100質量部に対する質量部で表す。


































<Test Example 4>
A ground beef hamburger with the raw materials and blending amounts shown in Table 7 was prepared. In addition, the compounding quantity of each raw material shown in Table 7 is represented by the mass part with respect to 100 mass parts of raw material meat (cow pork ground meat).


































Figure 0004555178
Figure 0004555178

調味料として、食塩及びグルタミン酸ナトリウムを、香辛料として、白胡椒及びナツメグを、オリゴ糖として、オリゴ糖Aを、澱粉質原料として、油脂加工したコーンスターチ(以下より澱粉Dと記す)を、有機酸の可溶性塩として、クエン酸ナトリウムを、アルカリ剤としてピロリン酸ナトリウムを、高分子多糖類としてカラギナン(κ―タイプ)を用いた。なお、タマネギは、みじん切りにしたものを、卵は、全卵を使用した。   As seasonings, salt and sodium glutamate, spices, white pepper and nutmeg, oligosaccharides, oligosaccharide A, starchy raw material, corn starch (hereinafter referred to as starch D), and organic acid Sodium citrate was used as the soluble salt, sodium pyrophosphate as the alkaline agent, and carrageenan (κ-type) as the polymer polysaccharide. In addition, the onion used what was chopped, and the egg used the whole egg.

また、原料肉類は、市販の牛豚合挽き肉(牛:豚=7:3の質量比で混合されたもの)を使用した。   In addition, as raw material meat, commercially available ground beef pork (mixed in a mass ratio of beef: pig = 7: 3) was used.

表7の調合量で原料をこね合わせたハンバーグ生地を、1個あたり120g測りとって、小判型の生ハンバーグを作製した。この生ハンバーグを、約200℃に熱したホットプレートで、中心温度が約80℃になるまで焼成し、ハンバーグを作製した。このハンバーグの重量を測定し、次の方法によって焼成歩留を算出した。
「焼成歩留」=焼成後ハンバーグ重量÷焼成前生ハンバーグ重量×100
120 g of hamburger dough kneaded with the raw materials in the blending amounts shown in Table 7 was measured to produce a small-sized raw hamburger. This raw hamburger was baked with a hot plate heated to about 200 ° C. until the center temperature reached about 80 ° C. to produce a hamburger. The hamburger was weighed and the firing yield was calculated by the following method.
“Firing Yield” = hamburger weight after firing ÷ raw hamburger weight before firing × 100

そして、焼きたて直後のハンバーグを試食し、「ソフトさ」、「ジューシーさ」、「弾力」、「風味」を10名の熟練パネラーにより官能検査を実施し、「5点」;良い、「4点」;やや良い、「3点」;普通、「2点」;やや悪い、「1点」;悪い、の5段階で評価した。同様にして、焼成後に冷凍し、それを電子レンジで解凍、加温した後のハンバーグについても試食し、「ソフトさ」「ジューシーさ」「弾力」「風味」を評価し、これらを総合して「再加熱後のおいしさ」として評価した。そして、焼成直後、及び冷凍したハンバーグの電子レンジ後のおいしさを総合的に評価し、これを「総合評価」とした。評価の結果は、各パネラーの点数を平均し、表8に結果を示す。
































Then, the hamburger just after baking was sampled, and "softness", "juiciness", "elasticity", and "flavor" were subjected to a sensory test by 10 skilled panelists, "5 points"; Evaluation was made in five stages: “4 points”; somewhat good, “3 points”; normal, “2 points”; somewhat bad, “1 point”; In the same way, freeze it after baking, sample it with hamburger after thawing and heating it with microwave oven, evaluate "softness""juicy""elasticity""flavor", and combine these It was evaluated as “deliciousness after reheating”. And the deliciousness immediately after baking and the microwave oven of the frozen hamburger were evaluated comprehensively, and this was set as "total evaluation." The result of evaluation is the average of the scores of each panel, and the results are shown in Table 8.
































Figure 0004555178
Figure 0004555178

比較例10は、本発明のオリゴ糖と澱粉質原料を用いずに作製したハンバーグである。焼成後に肉汁が多く流出し、ジューシーさとソフトさが弱く、風味も特に優れなかった。また、冷凍後、電子レンジで再加熱すると、硬く、ジューシーさが弱くなり、風味も臭みが強く発したため、総合評価でも低い評点となった。比較例11は、オリゴ糖を使用せず、澱粉質原料のみを配合して作製した肉類加工品である。ソフトさ、弾力は比較例10にくらべ向上したものの、ジューシーさと風味は逆に低下した。また、電子レンジで再加熱すると、比較例10に近い、ジューシーさ、ソフトさ、弾力に乏しい食感で、臭みが強く発したため、総合評価も低くなった。   Comparative Example 10 is a hamburger prepared without using the oligosaccharide and starch material of the present invention. Much broth spilled after baking, juiciness and softness were weak, and flavor was not particularly excellent. Also, after freezing, when reheated in a microwave oven, it became hard, juicy, weak and smelly, and the overall rating was low. Comparative Example 11 is a processed meat product prepared by blending only starchy raw materials without using oligosaccharides. Although the softness and elasticity were improved as compared with Comparative Example 10, the juiciness and flavor were decreased. Moreover, when it reheated with the microwave oven, since the smell was strong in the food texture close | similar to the comparative example 10, and lacked in elasticity, the comprehensive evaluation also became low.

一方、オリゴ糖と澱粉質原料とを配合した実施例12の肉類加工品では、ソフトさ、ジューシーさ、再加熱後の食感と風味のいずれも改善された。また、有機酸の可溶性塩と高分子多糖類を添加した実施例13では、弾力と風味が更に改善され、再加熱後も、好ましい食感と風味がよく維持されていた。更には、有機酸の可溶性塩、アルカリ剤、高分子多糖類と発酵調味料を添加した実施例14では、ソフトで弾力に富み、ジューシーで、旨味の増した好ましい風味となり、再加熱後もその状態がよく維持されていた。   On the other hand, in the processed meat product of Example 12 in which the oligosaccharide and the starch material were blended, all of softness, juiciness, texture and flavor after reheating were improved. Moreover, in Example 13 which added the soluble salt of organic acid and polymeric polysaccharide, elasticity and flavor were further improved, and the preferable food texture and flavor were well maintained even after reheating. Furthermore, in Example 14 in which a soluble salt of an organic acid, an alkaline agent, a high molecular weight polysaccharide and a fermented seasoning were added, it became a soft, rich, juicy, savory flavor, and even after reheating The condition was well maintained.

本発明の肉類加工品用改良剤及びそれを用いた肉類加工品の改質方法によれば、加熱調理後の歩留と風味、食感に優れ、更には加熱調理後、冷凍やチルド状態での保存を経た後の電子レンジ加熱などの再加熱の後でも良好な風味と食感を損なうことがない肉類加工品を提供することができる。   According to the improving agent for processed meat products and the method for modifying processed meat products using the same according to the present invention, it is excellent in yield, flavor and texture after cooking, and further in a frozen or chilled state after cooking. It is possible to provide a processed meat product that does not impair good flavor and texture even after reheating such as microwave heating after storage.

Claims (11)

(A)オリゴ糖としてマルトオリゴ糖、ニゲロオリゴ糖から選ばれた1種以上と、(B)澱粉質原料と、(C)有機酸の可溶性塩として乳酸、クエン酸、リンゴ酸、コハク酸から選ばれた1種又は2種以上と、(D)アルカリ剤として炭酸ナトリウム、炭酸水素ナトリウム、ピロリン酸ナトリウム、ポリリン酸ナトリウムから選ばれた1種又は2種以上と、(E)高分子多糖類としてキサンタンガム、コーンファイバー、カラギナンから選ばれた1種又は2種以上とを含むことを特徴とする肉類加工品用改良剤。 (A) One or more kinds selected from malto-oligosaccharides and nigerooligosaccharides as oligosaccharides, (B) starchy raw materials, and (C) organic acid soluble salts selected from lactic acid, citric acid, malic acid, and succinic acid 1 type or 2 types or more, (D) 1 type or 2 types or more selected from sodium carbonate, sodium hydrogen carbonate, sodium pyrophosphate and sodium polyphosphate as alkaline agents, and (E) xanthan gum as a polymer polysaccharide 1 or 2 or more types chosen from corn fiber and carrageenan , The improvement agent for processed meat products characterized by the above-mentioned . 前記(A)成分は、重合度3〜7のマルトオリゴ糖が主成分である請求項に記載の肉類加工品用改良剤。 The improver for processed meat products according to claim 1 , wherein the component (A) is mainly composed of a maltooligosaccharide having a polymerization degree of 3 to 7. 前記(B)成分は、酸処理、エステル化処理、エーテル化処理、架橋処理、油脂加工処理、湿熱処理から選ばれた1種又は2種以上の処理方法で加工した澱粉誘導体である請求項1又は2に記載の肉類加工品用改良剤。 The component (B) is a starch derivative processed by one or more processing methods selected from an acid treatment, an esterification treatment, an etherification treatment, a crosslinking treatment, an oil processing treatment, and a wet heat treatment. Or the improving agent for processed meat products of 2 . 前記肉類加工品用改良剤の固形分全量中における、前記(A)成分と前記(B)成分は、質量比で、(A)成分:(B)成分=1:9〜9:1である請求項1〜のいずれか一つに記載の肉類加工品用改良剤。 In the total solid content of the improver for processed meat products, the component (A) and the component (B) are (A) component: (B) component = 1: 9 to 9: 1 in mass ratio. The improvement agent for processed meat products as described in any one of Claims 1-3 . 前記肉類加工品用改良剤の(A)成分と(B)成分の固形分合計量を100質量部とした時、前記(C)成分の含有量は1〜50質量部、前記(D)成分の含有量は1〜40質量部、前記(E)成分の含有量は0.5〜30質量部である請求項のいずれか一つに記載の肉類加工品用改良剤。 When the total amount of the solids of the component (A) and the component (B) of the improver for processed meat products is 100 parts by mass, the content of the component (C) is 1 to 50 parts by mass, the component (D) The improver for processed meat products according to any one of claims 1 to 4 , wherein the content of 1 to 40 parts by mass and the content of the component (E) is 0.5 to 30 parts by mass. 請求項1〜のいずれか一つに記載の肉類加工品用改良剤を、肉類に添加することを特徴とする肉類加工品の改質方法。 A method for modifying a processed meat product, comprising adding the improver for processed meat product according to any one of claims 1 to 5 to the meat product. 肉類100質量部に対し、前記(A)成分を0.05〜10質量部、及び前記(B)成分を0.05〜10質量部添加する請求項に記載の肉類加工品の改質方法。 The method for modifying a processed meat product according to claim 6 , wherein 0.05 to 10 parts by mass of the component (A) and 0.05 to 10 parts by mass of the component (B) are added to 100 parts by mass of the meat. . 肉類100質量部に対し、前記(C)成分を0.01〜3質量部添加する請求項又はに記載の肉類加工品の改質方法。 The method for modifying a processed meat product according to claim 6 or 7 , wherein 0.01 to 3 parts by mass of the component (C) is added to 100 parts by mass of the meat. 肉類100質量部に対し、前記(D)成分を0.005〜3質量部添加する請求項のいずれか一つに記載の肉類加工品の改質方法。 The method for modifying a processed meat product according to any one of claims 6 to 8 , wherein 0.005 to 3 parts by mass of the component (D) is added to 100 parts by mass of the meat. 肉類100質量部に対し、前記(E)成分を0.005〜3質量部添加する請求項のいずれか一つに記載の肉類加工品の改質方法。 The method for modifying a processed meat product according to any one of claims 6 to 9 , wherein 0.005 to 3 parts by mass of the component (E) is added to 100 parts by mass of the meat. 請求項10のいずれか一つに記載の改質方法で得られた肉類加工品。 Processed meat products obtained by the reforming method according to any one of claims 6 to 10 .
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