JP2010220608A - Taste improved meat and meat taste improver - Google Patents

Taste improved meat and meat taste improver Download PDF

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JP2010220608A
JP2010220608A JP2010033462A JP2010033462A JP2010220608A JP 2010220608 A JP2010220608 A JP 2010220608A JP 2010033462 A JP2010033462 A JP 2010033462A JP 2010033462 A JP2010033462 A JP 2010033462A JP 2010220608 A JP2010220608 A JP 2010220608A
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Hiroe Ogawa
博衛 小川
Akihiro Ogawa
明宏 小川
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a taste improver preventing deterioration of taste quality after heating, refrigeration or freezing of meat and improving soft food feeling and taste, and to provide taste-improved meat added therewith. <P>SOLUTION: A meat taste-improver provided by uniformly adding glycerol mono fatty acid ester or polyglycerol fatty acid ester to sodium lactate makes meat soft, improves elasticity, juicy feeling, soft feeling and body feeling, makes taste better, and improves crispy feeling. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は風味を向上させた食肉、食肉風味向上剤およびその製造法に関する。   The present invention relates to a meat with improved flavor, a meat flavor improver, and a method for producing the same.

従来食肉の品質改良剤は多く提案がなされている。例えば食肉の歩留り食感を向上させる方法として食肉を加工するにあたり有機酸、繊維性の食品素材またはこれ等を調味液又は水に溶解させたものを混合又は注入して製品の歩留りを向上する方法(特許文献1)、ヒドロキシカルボン酸又はその塩と脂肪酸とのエステル(たとえばステアロイル乳酸ナトリウム又はステアロイル乳酸カルシウム)を肉に含有させてジューシーな肉質にする肉の改良剤(特許文献2)、乳酸ナトリウム、酢酸ナトリウム、クエン酸ナトリウムを食肉に含有させる風味食感日持が改良された食肉加工品(特許文献3)、食肉に乳酸塩又は乳酸塩と乳酸を含む溶液を塗布する食肉の変色防止法(特許文献4)、ステアロイル乳酸ナトリウムおよび又はポリオキシエチレン(20)ソルビタン脂肪酸エステルをそのまま又は水や油に溶解ないし分散あるいは乳化して肉に加え加熱工程を経ても肉が硬く締まり肉汁が流出しない方法(特許文献5)、生ハムを製造するに際し食塩の代替として乳酸ナトリウムや乳酸カリウムを使用して塩漬し水分活性により生ハムの保存性を高める方法(特許文献6)、畜肉トリ肉魚肉の肉片にモノグリセリドあるいはジグリセリドとポリカルボン酸とのエステルを使用し肉質を柔らかくする方法(特許文献7)、モノグリセリドあるいはジグリセリドとポリカルボン酸とのエステルを含有する挽き肉を主成分とする成型物のジューシー感をよくする方法(特許文献8)等が知られているが、いずれもジューシー感やソフト感に乏しく、肉類軟化酵素を併用しても充分な風味向上効果が得られなかった。   Many proposals have been made on meat quality improving agents. For example, a method for improving the yield of products by mixing or injecting an organic acid, a fibrous food material, or a solution obtained by dissolving these in a seasoning liquid or water when processing the meat as a method for improving the yield texture of the meat (Patent Document 1), Meat improver (Patent Document 2), Sodium lactate containing hydroxycarboxylic acid or its salt and fatty acid ester (for example, sodium stearoyl lactate or calcium stearoyl lactate) to make meat juicy , Meat Processing Product (Patent Document 3) with Improved Flavor, Feeling and Durability, Containing Sodium Acetate and Sodium Citrate in Meat, and Meat Discoloration Prevention Method by Applying Lactate or Lactate and Lactic Acid Solution to Meat (Patent Document 4), sodium stearoyl lactate and / or polyoxyethylene (20) sorbitan fatty acid ester Alternatively, a method in which meat is hardened and meat juice does not flow out even if heated or heated after being dissolved, dispersed or emulsified in water or oil (Patent Document 5), sodium lactate or potassium lactate as an alternative to salt when producing raw ham A method of increasing the shelf life of raw ham by salting with water (Patent Document 6), a method of softening meat quality by using monoglyceride or diglyceride and polycarboxylic acid ester in meat pieces of livestock meat Patent Document 7), a method for improving the juiciness of a molded product mainly composed of minced meat containing monoglyceride or diglyceride and polycarboxylic acid (Patent Document 8), etc. are known. In addition, it was poor in softness, and even when meat softening enzyme was used in combination, a sufficient flavor improving effect could not be obtained.

特開平6−343423号公報JP-A-6-343423 特開平8−140630号公報JP-A-8-140630 特開平11−133号公報JP 11-133 A 特開平2000−253810号公報Japanese Unexamined Patent Publication No. 2000-253810 特開平2004−65214号公報Japanese Patent Laid-Open No. 2004-65214 特開昭59−17940号公報JP 59-17940 特開平7−170942号公報Japanese Patent Laid-Open No. 7-170942 特開平7−203903号公報JP-A-7-203903

本発明の課題は肉質の柔らかい弾力性とジューシー感ソフト感を強めしかも風味が良く歯切れの良い食肉特にミンチ、ペースト等の加工食肉、及びその食肉を得るための食肉風味向上剤を提供することにある。   It is an object of the present invention to provide meat with improved softness and juiciness, softness of meat quality, and flavorful and crisp meat, especially processed meat such as mince and paste, and a meat flavor improver for obtaining the meat. is there.

本発明者らは上記課題を解決する為に種々実験を重ねた結果、乳酸ナトリウムとグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルを食肉に添加すると、貯蔵、加工後もジューシーで肉質の柔らかい、歯切れの良い弾力と良好な風味を有する食肉となることを突き止めた。この効果は主として、食肉への適当量の乳酸ナトリウムの添加により、食肉の保存、加工、特に冷蔵、冷凍保存、加熱、微塵切り、摩砕、混練等の加工による肉組織からの水分や水溶性成分の分離流出が抑制され、グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルの添加により、肉組織からの油性成分の分離流出が抑制されて、その両者の効果が相乗的に奏せられる結果と考えられる。また、乳酸ナトリウム水溶液に、液状または溶融したグリセリンモノ脂肪酸エステル又はおよびポリグリセリン脂肪酸エステルを混合又は加熱混合して均一に混和して得られる食肉風味向上剤は簡単に食肉に添加することができ、ばらつきのない風味向上効果を発揮させることができるという知見を得て本発明を完成した。   As a result of repeating various experiments to solve the above-mentioned problems, the present inventors have added sodium lactate and glycerin monofatty acid ester or polyglycerin fatty acid ester to meat. It was found that the meat had good elasticity and good flavor. This effect is mainly due to the addition of an appropriate amount of sodium lactate to the meat, the preservation and processing of meat, especially water from the meat tissue and water solubility by processing such as refrigeration, frozen storage, heating, fine dusting, grinding, kneading, etc. It is thought that the separation and outflow of components are suppressed, and the addition of glycerin monofatty acid ester or polyglycerin fatty acid ester suppresses the separation and outflow of oily components from meat tissue, and the effects of both are produced synergistically. . In addition, a meat flavor enhancer obtained by mixing or heating and mixing a liquid or molten glycerin monofatty acid ester or polyglycerin fatty acid ester in a sodium lactate aqueous solution and mixing uniformly can be easily added to meat, The present invention was completed by obtaining the knowledge that a flavor improvement effect without variation can be exhibited.

即ち本発明は、
(1)乳酸ナトリウム(a)とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を添加して風味を向上させた食肉、
(2)食肉に対して乳酸ナトリウム(a)を0.08〜4.0重量%とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を0.005〜2.0重量%添加して風味を向上させた(1)記載の食肉、
(3)さらに酸類、塩類又はアルカリ剤を添加して風味を向上させた(1)又は(2)記載の食肉、
(4)グリセリンモノ脂肪酸エステルを構成する脂肪酸が炭素数8〜18のものであり、ポリグリセリン脂肪酸エステルのグリセリンの重合度が2〜10、エステル結合している脂肪酸の数が1〜4で構成する脂肪酸が炭素数8〜18のものである(1)〜(3)のいずれかに記載の食肉、
(5)乳酸ナトリウム(a)1重量部に対して、グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を0.003〜1.000重量部配合した食肉風味向上剤、
(6)乳酸ナトリウムの水溶液に溶融したグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪エステルを均一に混和する食肉風味向上剤の製造法、
(7)食肉に対して乳酸ナトリウム(a)を0.08〜4.0重量%とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を0.005〜2.0重量%添加する食肉の風味向上法、
である。
That is, the present invention
(1) Meat whose flavor is improved by adding sodium lactate (a) and glycerin monofatty acid ester or polyglycerin fatty acid ester (b),
(2) 0.08 to 4.0% by weight of sodium lactate (a) and 0.005 to 2.0% by weight of glycerin monofatty acid ester or polyglycerin fatty acid ester (b) are added to the meat to give a flavor. Improved meat according to (1),
(3) The meat according to (1) or (2), wherein the flavor is further improved by adding acids, salts or alkaline agents,
(4) The fatty acid constituting the glycerin monofatty acid ester is one having 8 to 18 carbon atoms, the degree of polymerization of glycerin of the polyglycerin fatty acid ester is 2 to 10, and the number of ester-bonded fatty acids is 1 to 4 The meat according to any one of (1) to (3), wherein the fatty acid is one having 8 to 18 carbon atoms,
(5) A meat flavor improver containing 0.003 to 1.000 parts by weight of glycerin monofatty acid ester or polyglycerin fatty acid ester (b) with respect to 1 part by weight of sodium lactate (a),
(6) A method for producing a meat flavor improver, wherein glycerin monofatty acid ester or polyglycerin fatty ester melted in an aqueous solution of sodium lactate is uniformly mixed,
(7) Meat flavor in which 0.08 to 4.0% by weight of sodium lactate (a) and 0.005 to 2.0% by weight of glycerol mono-fatty acid ester or polyglycerol fatty acid ester (b) are added to meat. Improvement method,
It is.

本発明においては、乳酸ナトリウム(a)は食肉に対し、0.08〜4.0重量%、好ましくは0.15〜3.5重量%、さらに好ましくは0.20〜3.0重量%添加する。グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)は食肉に対して0.005〜2.0重量%、好ましくは0.01〜1.5重量%、さらに好ましくは0.02〜1.0重量%添加する。更に必要に応じ、さらに酸類、塩類及びアルカリ剤をそれぞれ単独または混合して使用することができる。   In the present invention, sodium lactate (a) is added in an amount of 0.08 to 4.0% by weight, preferably 0.15 to 3.5% by weight, more preferably 0.20 to 3.0% by weight based on meat. To do. The glycerin monofatty acid ester or polyglycerin fatty acid ester (b) is 0.005 to 2.0% by weight, preferably 0.01 to 1.5% by weight, more preferably 0.02 to 1.0% by weight based on meat. %Added. Further, if necessary, acids, salts and alkali agents can be used alone or in combination.

本発明の食肉風味向上剤は、撹拌下乳酸ナトリウム(a)の水溶液に溶融状のグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を均一に混和することにより調製することができる。その過程で、必要により更に酸類、塩類またはアルカリ剤を加えて、より風味向上効果の高い食肉風味向上剤とすることもできる。   The meat flavor improving agent of the present invention can be prepared by uniformly mixing a molten glycerin monofatty acid ester or polyglycerin fatty acid ester (b) into an aqueous solution of sodium lactate (a) with stirring. In the process, if necessary, an acid, salt or alkali agent may be added to obtain a meat flavor improving agent having a higher flavor improving effect.

本発明の風味が向上された食肉及び食肉風味向上剤の調製に用いられる一成分である乳酸ナトリウム(a)は、食品衛生上安全なものが用いられる。通常50〜60重量%の水溶液や100%に近い粉末状のものが市販されているが、製剤化には高濃度のものが望ましい。これらはそのままもしくは水やその他溶媒で希釈して用いることもできる。   As the sodium lactate (a), which is one component used for the preparation of the meat having improved flavor and the meat flavor improving agent of the present invention, food safety is used. Usually, a 50 to 60% by weight aqueous solution or a powdery product close to 100% is commercially available, but a high concentration is desirable for formulation. These can be used as they are or diluted with water or other solvents.

本発明の風味が向上された食肉及び食肉風味向上剤の製造に用いられるもう一つの成分は、グリセリンモノ脂肪酸エステル又は、ポリグリセリン脂肪酸エステルである。
グリセリンモノ脂肪酸エステルを構成する脂肪酸は、例えばカプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミン酸、ステアリン酸、オレイン酸などの炭素数C8〜C18のものであるが、好ましくはCl0〜C16、さらに好ましくはC12〜C14のものである。このグリセリンモノ脂肪酸エステルは、グリセリンモノ脂肪酸エステルが50重量%以上、好ましくは70重量%以上含有するグリセリン脂肪酸エステルの混合物として使用することができる。
Another component used in the production of the meat with improved flavor and the meat flavor enhancer of the present invention is a glycerin monofatty acid ester or a polyglycerin fatty acid ester.
The fatty acid constituting the glycerin monofatty acid ester is, for example, one having C8 to C18 carbon atoms such as caprylic acid, capric acid, lauric acid, myristic acid, palmic acid, stearic acid, oleic acid, etc., preferably Cl0 to C16, More preferably, it is C12-C14. This glycerin monofatty acid ester can be used as a mixture of glycerin fatty acid esters containing 50% by weight or more, preferably 70% by weight or more of glycerin monofatty acid ester.

ポリグリセリン脂肪酸エステルは複数のグリセリンが重合し、残った遊離水酸基(OH基)に脂肪酸がエステル結合したものである。ポリグリセリンの重合度は2〜10で、好ましくは2〜6、さらに好ましくは2〜4である。ポリグリセリンにエステル結合している脂肪酸の数は通常1〜4個程度であるが、ポリグリセリン脂肪酸エステルとしてはジグリセリンモノ脂肪酸エステルが特に好ましい。
ポリグリセリン脂肪酸エステルのエステルを構成する脂肪酸はカプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミン酸、ステアリン酸、オレイン酸などの炭素数C8〜C18のものであるが、好ましくはCl0〜C16、さらに好ましくはC12〜C14のものである。
これらのグリセリンモノ脂肪酸エステルまたはポリグリセリン脂肪酸エステルは、食肉に対して0.005〜2.0重量%、好ましくは0.01〜1.5重量%、さらに好ましくは0.02〜1.0重量%程度含ませるのが望ましい。
The polyglycerin fatty acid ester is a polymer in which a plurality of glycerins are polymerized and a fatty acid is ester-bonded to the remaining free hydroxyl group (OH group). The polymerization degree of polyglycerol is 2 to 10, preferably 2 to 6, and more preferably 2 to 4. The number of fatty acids ester-bonded to polyglycerol is usually about 1 to 4, but diglycerol mono-fatty acid ester is particularly preferable as the polyglycerol fatty acid ester.
The fatty acid constituting the ester of polyglycerin fatty acid ester is a C8-C18 carbon such as caprylic acid, capric acid, lauric acid, myristic acid, palmic acid, stearic acid, oleic acid, etc., preferably Cl0-C16, More preferably, it is C12-C14.
These glycerin monofatty acid ester or polyglycerin fatty acid ester is 0.005 to 2.0% by weight, preferably 0.01 to 1.5% by weight, more preferably 0.02 to 1.0% by weight based on meat. It is desirable to include about%.

本発明の食肉風味向上剤における乳酸ナトリウム(a)とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)の混合割合は、重量比で、1:0.003〜1.000、好ましくは1:0.007〜0.800、さらに好ましくは1:0.017〜0.650である。   The mixing ratio of sodium lactate (a) and glycerol mono fatty acid ester or polyglycerol fatty acid ester (b) in the meat flavor improving agent of the present invention is 1: 0.003 to 1.000, preferably 1: 0, in weight ratio. 0.007 to 0.800, more preferably 1: 0.017 to 0.650.

本発明にいう酸類、塩類、アルカリ剤は食品衛生法に適合する酸類、塩類およびアルカリ剤であれば、特に制限はない。   The acids, salts, and alkali agents referred to in the present invention are not particularly limited as long as they are acids, salts, and alkali agents compatible with the Food Sanitation Law.

酸類には、有機酸と無機酸があり、有機酸としては、例えば酢酸、醸造酢、フマル酸、クエン酸、リンゴ酸、酒石酸、アジピン酸、乳酸、アスコルビン酸、フイチン酸、グルコン酸等が、無機酸としては、例えばリン酸一、リン酸二、リン酸三等の燐酸およびピロ、メタ、ポリ燐酸等の重合リン酸等があげられる。
塩類としては、たとえば前記酸類の塩、例えばナトリウム、カリウム等のアルカリ金属の塩、カルシウム、マグネシウムなどのアルカリ土類金属塩が挙げられる。なお、乳酸ナトリウム塩は本発明に使用する必須成分であり、この範疇からは除く。
アルカリ剤としては、食品への添加が許可されており、且つその水溶液がアルカリ性を呈するものをいい、たとえば炭酸ナトリウム、炭酸水素ナトリウム等炭酸のアルカリ金属塩、カルシウム、マグネシウム等のアルカリ土類金属塩や、焼成カルシウム、酸化カルシウム等のアルカリ土類金属の酸化物等が挙げられる。
また、これらの酸類、塩類、アルカリ剤を配合した製剤及び保存料(例えばポリリジン、プロタミン、リゾチーム、ナイシン、その他バクテリオシン)、日持向上剤、pH調整剤、調味料等を適宜の量用いても良い。
Acids include organic acids and inorganic acids. Examples of organic acids include acetic acid, brewed vinegar, fumaric acid, citric acid, malic acid, tartaric acid, adipic acid, lactic acid, ascorbic acid, phytic acid, and gluconic acid. Examples of the inorganic acid include phosphoric acid such as phosphoric acid 1, phosphoric acid 2, and phosphoric acid 3, and polymerized phosphoric acid such as pyro, meta, and polyphosphoric acid.
Examples of the salts include salts of the aforementioned acids, for example, alkali metal salts such as sodium and potassium, and alkaline earth metal salts such as calcium and magnesium. In addition, sodium lactate is an essential component used in the present invention, and is excluded from this category.
Alkaline agents are those that are permitted to be added to food and whose aqueous solution is alkaline, such as alkali metal salts of carbonates such as sodium carbonate and sodium bicarbonate, alkaline earth metal salts such as calcium and magnesium And alkaline earth metal oxides such as calcined calcium and calcium oxide.
In addition, preparations and preservatives (for example, polylysine, protamine, lysozyme, nisin, and other bacteriocins) containing these acids, salts, and alkali agents, a shelf life improver, a pH adjuster, a seasoning, etc. are used in appropriate amounts. Also good.

本発明の食肉風味向上剤は、前述の通り乳酸ナトリウムの水溶液とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルを溶融させたものを均一に混和するか、加温撹拌混和し更に必要に応じ酸類又はその塩類、アルカリ剤その他の添加剤を混合使用又はそれぞれ単独を併用することにより製造することができる。
グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルは常温で液状である場合はそのまま乳酸ナトリウム水溶液と混合することが出来るが、その場合も充分に撹拌混合することが望ましい。
The meat flavor improver of the present invention is, as described above, uniformly mixed with an aqueous solution of sodium lactate and a molten glycerin monofatty acid ester or polyglycerin fatty acid ester, or mixed with heating and stirring, and if necessary, acids or its It can be produced by using a mixture of salts, alkali agents and other additives, or by using each alone in combination.
Glycerin monofatty acid ester or polyglycerin fatty acid ester can be mixed with an aqueous sodium lactate solution as it is when it is in a liquid state at normal temperature, but in that case, it is desirable to sufficiently stir and mix.

常温でペースト状又は固体であるグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルは、適当な温度、例えば50℃以上、好ましくは60〜100℃に加熱して溶融し乳酸ナトリウム水溶液と均一に混和することができる。
本発明の効果は乳酸ナトリウム(a)、グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を食肉にそれぞれ単品使用又は併用した場合に比べて食肉のジューシー感、風味向上効果に優れ、均一で安定化した効果が奏せられる。
本発明の食肉風味向上剤における乳酸ナトリウムの配合割合は、食肉用風味向上剤の製剤全体に対して、15〜80重量%、好ましくは18〜70重量%、より好ましくは24〜60重量%程度である。
Glycerin monofatty acid ester or polyglycerin fatty acid ester that is pasty or solid at room temperature can be melted by heating to an appropriate temperature, for example, 50 ° C. or higher, preferably 60 to 100 ° C., and mixed uniformly with an aqueous sodium lactate solution. it can.
The effect of the present invention is superior to the effect of improving the juiciness and flavor of meat compared to the case where sodium lactate (a), glycerin monofatty acid ester or polyglycerin fatty acid ester (b) is used individually or in combination, and uniform and stable. The effect that was made.
The mixing ratio of sodium lactate in the meat flavor improving agent of the present invention is 15 to 80% by weight, preferably 18 to 70% by weight, more preferably about 24 to 60% by weight, with respect to the whole preparation of the meat flavor improving agent. It is.

本発明の食肉風味向上剤におけるグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルは、製剤全体に対して、0.2〜35重量%、好ましくは0.5〜25重量%、より好ましくは1〜20重量%程度である。   The glycerin monofatty acid ester or polyglycerin fatty acid ester in the meat flavor improving agent of the present invention is 0.2 to 35% by weight, preferably 0.5 to 25% by weight, more preferably 1 to 20% by weight, based on the whole preparation. %.

また食肉風味向上のために酸類、塩類、アルカリ剤を使用する場合は、食肉類に対し0.02〜5重量%程度、好ましくは0.03〜4重量%程度、より好ましくは0.05〜3重量%程度添加するのが良い。   Moreover, when using acids, salt, and an alkali agent for meat flavor improvement, it is about 0.02-5 weight% with respect to meat, Preferably it is about 0.03-4 weight%, More preferably, it is 0.05- It is good to add about 3% by weight.

製剤又は酸類、塩類、アルカリ剤を含む製剤のpHは4.0〜12、好ましくは4.2〜11、より好ましくは4.5〜10程度である。   The pH of the preparation or the preparation containing acids, salts and alkaline agent is 4.0 to 12, preferably 4.2 to 11, more preferably about 4.5 to 10.

本発明の食肉には、畜肉類、鳥肉類、魚介類があげられる。畜肉類としては例えば牛、豚、馬、羊、カンガルーなどの獣肉、鳥肉類としては鶏、鴨、鳩、アヒル、七面鳥、ガチョウなどの家禽の肉類等があげられる。魚介類の肉としては、例えば鯛、ひらめ、たら等の白身魚やマグロ、等の赤身魚、サバ、アジ、ブリ等の青物、鯰やうなぎ等の魚肉、ハマグリ、アサリ等の貝類、エビ、カニ等の甲殻類、いか、たこ等の軟体動物の肉や鯨肉等があげられる。これ等の処理加工品としては例えばハンバーグ、ハム、ソーセージ、ミートローフ、ミンチカツ、ミンチボール、肉まん、シウマイ、ギョウザ、蒲鉾、竹輪、さつま揚げ等の魚、畜肉、鳥肉の煉製品や焼物、煮物、揚げ物等および塩辛、味噌漬、調味漬、カス漬等があげられこれ等の処理、加工品の冷蔵、冷凍品があげられる。また、製剤が容易に均一分散させることができるため、魚蓄肉等の練り製品が特に適している。   Examples of the meat of the present invention include livestock meat, poultry, and seafood. Examples of livestock meat include beef such as cattle, pigs, horses, sheep and kangaroos, and examples of poultry include poultry such as chickens, duck, pigeons, ducks, turkeys and geese. Examples of seafood include white fish such as sea bream, sea bream, and tuna, red fish such as tuna, fish such as mackerel, horse mackerel, and yellowtail, fish such as sea bream and eel, shellfish such as clams and clams, shrimp, and crabs. Crustaceans such as squid, mollusks such as squid and octopus, and whale meat. Examples of such processed products include hamburger, ham, sausage, meatloaf, minced cutlet, minced ball, meat bun, siamese, gyoza, salmon, bamboo rings, fried fish, livestock meat, poultry bricks, grilled food, boiled food, fried food And salted spices, miso pickles, seasoning pickles, pickled pickles, etc., and processing, refrigeration of processed products, and frozen products. In addition, since the preparation can be easily and uniformly dispersed, kneaded products such as fish stock are particularly suitable.

さらに上記食肉の瓶詰、缶詰、レトルトパウチ各種プラスチックフィルム(例セロハン、ポリエチレン、塩酸ゴム、塩化ビニリデン、ポリエステル、ポリプロピレン、複合加工紙等)によりケーシング、チルドまたはレトルトした密封包装食品が挙げられる。
これ等の食肉への本発明製剤の添加量は、通常0.2〜6.5重量%、好ましくは0.3〜5.0重量%、より好ましくは0.5〜4.0重量%程度である。
Furthermore, the above-mentioned meat bottling, canning, and retort pouch plastic film (for example, cellophane, polyethylene, hydrochloric acid rubber, vinylidene chloride, polyester, polypropylene, composite processed paper, etc.), sealed packaged foods that are casing, chilled or retorted.
The amount of the preparation of the present invention added to these meats is usually 0.2 to 6.5% by weight, preferably 0.3 to 5.0% by weight, more preferably about 0.5 to 4.0% by weight. It is.

本発明における乳酸ナトリウム、グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル、さらには酸類、塩類又はアルカリ剤の食肉への添加は、常圧又は陰圧下でそれぞれの成分を単独または混合して、必要により冷却、加温などの温度調節を行った食肉又は食肉を含む食品素材に混合、煉合したり、それらを含む浸漬液やタレ調味液に浸漬する、漬け込む、まぶす、塗布する方法や、タンブラー等でタンプリングやインジェクトで調製液を浸入させる方法又は煉製品の製造工程でねり込む等して食肉に、なるべく均一に浸透させることにより行われる。最も典型的なものは獣肉のミンチや魚肉のペーストに液状の本製剤を均一に混合する方法である。また目的に応じ各種の添加物、例えば甘味料、糖アルコールやその他多価アルコール、調味料、糊料(例えばグルコマンナン、アルギン酸塩、ペクチン等の糊料)油脂、香辛料及びその抽出物、ポリリジン、プロタミン、ナイシン、リゾチーム等の抗菌剤や酸化防止剤を製剤に加えてもよいし、製剤と併用してもよい。   In the present invention, sodium lactate, glycerin monofatty acid ester or polyglycerin fatty acid ester, and further addition of acids, salts or alkaline agents to meat are carried out by mixing each component alone or under normal pressure or negative pressure, and cooling if necessary. , Mixed with food materials containing meat that has undergone temperature adjustment such as warming, or meat, soaked in immersion liquid or sauce seasoning containing it, soaked, dusted, applied, or tumbler It is carried out by infiltrating the meat as uniformly as possible by immersing the preparation liquid by tamping or injection or by squeezing it in the manufacturing process of the brick product. The most typical method is to uniformly mix the liquid preparation with animal mince or fish paste. Depending on the purpose, various additives such as sweeteners, sugar alcohols and other polyhydric alcohols, seasonings, pastes (eg pastes such as glucomannan, alginate, pectin), fats and oils, spices and extracts thereof, polylysine, Antibacterial agents and antioxidants such as protamine, nisin and lysozyme may be added to the preparation or may be used in combination with the preparation.

本発明は、食肉に一定量の乳酸ナトリウムとグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステルを添加することにより、冷蔵又は冷凍貯蔵後もジューシーで肉質の柔らかい、歯切れの良い弾力と良好な風味の食肉とすることができる。また、液状乳酸ナトリウムに溶解したグリセリンモノ脂肪酸エステル又はおよびポリグリセリン脂肪酸エステルを混合又は加熱混合して均一に混和して得られる食肉風味向上剤を食肉に添加すると、簡単で、ばらつきのない効果を発揮させることができる。   By adding a certain amount of sodium lactate and glycerin monofatty acid ester or polyglycerin fatty acid ester to meat, the present invention provides meat that is juicy, soft and crisp with good crispness and good flavor even after refrigerated or frozen storage. can do. In addition, when a meat flavor improver obtained by mixing or heating and mixing glycerin monofatty acid ester or polyglycerin fatty acid ester dissolved in liquid sodium lactate and mixing uniformly is added to the meat, it has a simple and consistent effect. It can be demonstrated.

以下に実施例、比較例を挙げて本発明を具体的に説明する。なお、部、%は、断りのない限り重量部、重量%を意味するものとする。   Hereinafter, the present invention will be specifically described with reference to Examples and Comparative Examples. Note that parts and% mean parts by weight and% by weight unless otherwise specified.

食肉風味向上剤(製剤)の調製
(A)80℃で加温溶融したグリセリンモノカプリル酸エステル(C8)0.5重量部とジグリセリンモノミリスチン酸エステル(C14)4.5重量部を撹拌混合し、70℃で加温した60重量%乳酸ナトリウム水溶液95重量部を添加し、70℃で加温撹拌混合して製剤Aとした。
(B)80℃で加温溶融したグリセリンモノカプリン酸エステル(C10)5重量部とジグリセリンモノミリスチン酸エステル(C14)20重量部を撹拌混合し、70℃で加温した60重量%乳酸ナトリウム水溶液75重量部を添加し、70℃で加温撹拌混合して製剤Bとした。
(C)80℃で加温溶融したグリセリンモノラウリン酸エステル(C12)2重量部とジグリセリンモノミリスチン酸エステル(C14)18重量部を撹拌混合し、70℃で加温した60重量%乳酸ナトリウム水溶液80重量部を添加し、70℃で加温撹拌混合して製剤Cとした。
(D)70℃で加温した60重量%乳酸ナトリウム水溶液95重量部に80℃で加温溶融したジグリセリンモノミリスチン酸エステル(C14)5重量部を添加し、70℃で加温撹拌混合して製剤Dとした。
(E)80℃で加温溶融したモノグリセリンモノパルミチン酸エステル(C16)15重量部とジグリセリンモノミリスチン酸エステル(C14)10重量部を撹拌混合し、70℃で加温した60重量%乳酸ナトリウム水溶液75重量部を添加し、70℃で加温撹拌混合して製剤Eとした。
(F)70℃で加温した60重量%乳酸ナトリウム水溶液90重量部に80℃で加温溶融したジグリセリンモノミリスチン酸エステル(C14)を10重量部添加し70℃で加温撹拌混合して製剤Fとした。
(G)70℃で加温した60重量%乳酸ナトリウム水溶液80重量部に80℃で加温溶融したジグリセリンモノミリスチン酸エステ(C14)を20重量部添加し、70℃で加温撹拌混合して製剤Gとした。
(H)60重量%乳酸ナトリウム水溶液85重量部に50重量%乳酸水溶液5重量部を加え70℃で加温混合しながら80℃で加温溶融したジグリセリンモノミリスチン酸エステル(C14)を10重量部添加混合して製剤Hとした。
(I)70℃で加温した60重量%乳酸ナトリウム水溶液70重量部に80℃で加温溶融したデカグリセリンモノミリスチン酸エステル(C14)を30重量部添加し、70℃で加温撹拌混合して製剤Iとした。
(J)70℃で加温した60重量%乳酸ナトリウム水溶液66.7重量部と水29.3重量部を混合し80℃で加温溶融したジグリセリンモノミリスチン酸エステル(C14)4重量部を添加し、70℃で加温撹拌混合して製剤Jとした。
(K)70℃で加温した60重量%乳酸ナトリウム水溶液99重量部にジグリセリンモノミリスチン酸エステル(C14)1重量部を添加し、撹拌混合して製剤Kとした。
(L)70℃で加温した60重量%乳酸ナトリウム水溶液75重量部に80℃で加温溶融したジグリセリンモノミリスチン酸エステル(C14)25重量部を添加し、撹拌混合して製剤Lとした。
(M)50℃で加温した60重量%乳酸ナトリウム水溶液95重量部に90℃で加温溶融したモノグリセリンモノパルミチン酸エステル(C16)5重量部を添加し、撹拌混合して製剤Mとした。
(N)70℃で加温した60重量%乳酸ナトリウム水溶液47.9重量部に98重量%乳酸ナトリウム42.1重量部を添加し、攪拌溶解後80℃で加温溶融したジグリセリンモノミリスチン酸エステル(C14)10重量部を添加し、70℃で加温撹拌混合して製剤Nとした。
(O)70℃で加温した60重量%乳酸ナトリウム水溶液25.0重量部に98重量%乳酸ナトリウム51.0重量部を添加し、加温攪拌溶解後80℃で加温溶融したテトラグリセリンモノミリスチン酸エステル(C14)24.0重量部を添加し、70℃で加温撹拌混合して製剤Oとした。
(P)70℃で加温した60重量%乳酸ナトリウム水溶液59.6重量部に98重量%乳酸ナトリウム7.4重量部を添加し、加温攪拌溶解後80℃で加温溶融したテトラグリセリンモノミリスチン酸エステル(C14)33.0重量部を添加し、70℃で加温撹拌混合して製剤Pとした。
(Q)60重量%乳酸ナトリウム水溶液30.7重量部に水65.3重量部を加え攪拌し、70℃に加温する。これにテトラグリセリンモノラウリン酸エステル(C12)4.0重量部を添加し、70℃で攪拌混合して製剤Qとした。
(R)60重量%乳酸ナトリウム水溶液74.5重量部に水24.5重量部を加え攪拌する。これにテトラグリセリンモノラウリン酸エステル(C12)1.0重量部を添加し、70℃で攪拌混合して製剤Rとした。
Preparation of meat flavor improver (formulation) (A) 0.5 parts by weight of glycerol monocaprylate (C8) heated and melted at 80 ° C. and 4.5 parts by weight of diglycerol monomyristate (C14) Then, 95 parts by weight of a 60% by weight aqueous sodium lactate solution heated at 70 ° C. was added, and the mixture was heated and stirred at 70 ° C. to obtain Formulation A.
(B) 60 wt% sodium lactate obtained by stirring and mixing 5 parts by weight of glycerin monocapric acid ester (C10) and 20 parts by weight of diglycerin monomyristic acid ester (C14) heated and melted at 80 ° C. 75 parts by weight of an aqueous solution was added, and the mixture was heated and stirred at 70 ° C. to prepare Formulation B.
(C) 2 parts by weight of glycerol monolaurate (C12) heated and melted at 80 ° C. and 18 parts by weight of diglycerol monomyristate (C14) were stirred and mixed, and heated at 70 ° C., 60% by weight sodium lactate aqueous solution 80 parts by weight was added, and the mixture was heated and stirred at 70 ° C. to obtain Formulation C.
(D) 5 parts by weight of diglycerin monomyristic acid ester (C14) heated and melted at 80 ° C. is added to 95 parts by weight of 60% by weight sodium lactate aqueous solution heated at 70 ° C., and the mixture is heated and stirred at 70 ° C. Thus, preparation D was obtained.
(E) 15% by weight of monoglycerol monopalmitate (C16) heated and melted at 80 ° C. and 10 parts by weight of diglycerol monomyristate (C14) were stirred and mixed, and 60% by weight lactic acid heated at 70 ° C. 75 parts by weight of an aqueous sodium solution was added, and the mixture was heated and stirred at 70 ° C. to prepare Formulation E.
(F) 10 parts by weight of diglycerin monomyristate ester (C14) heated and melted at 80 ° C. was added to 90 parts by weight of a 60% by weight aqueous sodium lactate solution heated at 70 ° C., and the mixture was heated and stirred at 70 ° C. Formulation F was designated.
(G) 20 parts by weight of diglycerin monomyristic acid ester (C14) melted by heating at 80 ° C. is added to 80 parts by weight of 60% by weight sodium lactate aqueous solution heated at 70 ° C., and the mixture is heated and stirred at 70 ° C. Thus, preparation G was obtained.
(H) 10 parts by weight of diglycerin monomyristic acid ester (C14) melted by heating at 80 ° C. while adding 5 parts by weight of 50% by weight aqueous solution to 85 parts by weight of 60% by weight sodium lactate aqueous solution and heating and mixing at 70 ° C. Partly added and mixed to make Formulation H.
(I) 30 parts by weight of decaglycerin monomyristic acid ester (C14) heated and melted at 80 ° C. was added to 70 parts by weight of a 60% by weight aqueous sodium lactate solution heated at 70 ° C., and the mixture was heated and stirred at 70 ° C. This was designated as Formulation I.
(J) 6 parts by weight of a 60% by weight aqueous sodium lactate solution heated at 70 ° C. and 29.3 parts by weight of water, and 4 parts by weight of diglycerin monomyristate ester (C14) melted by heating at 80 ° C. Then, the mixture was heated and stirred at 70 ° C. to prepare Formulation J.
(K) 1 part by weight of diglycerin monomyristic acid ester (C14) was added to 99 parts by weight of an aqueous 60% by weight sodium lactate solution heated at 70 ° C., and the mixture was stirred and mixed to prepare formulation K.
(L) 25 parts by weight of diglycerin monomyristic acid ester (C14) heated and melted at 80 ° C. was added to 75 parts by weight of a 60% by weight sodium lactate aqueous solution heated at 70 ° C. .
(M) 5 parts by weight of a monoglycerin monopalmitate (C16) melted by heating at 90 ° C. was added to 95 parts by weight of an aqueous 60% by weight sodium lactate solution heated at 50 ° C., and mixed to obtain a preparation M. .
(N) Diglycerin monomyristic acid obtained by adding 42.1 parts by weight of 98% by weight sodium lactate to 47.9 parts by weight of 60% by weight sodium lactate aqueous solution heated at 70 ° C., and stirring and dissolving, followed by heating and melting at 80 ° C. 10 parts by weight of ester (C14) was added, and the mixture was heated and stirred at 70 ° C. to obtain Formulation N.
(O) 51.0 parts by weight of 98% by weight sodium lactate was added to 25.0 parts by weight of a 60% by weight sodium lactate aqueous solution heated at 70 ° C. 24.0 parts by weight of myristic acid ester (C14) was added, and the mixture was heated and stirred at 70 ° C. to prepare Formulation O.
(P) Tetraglycerin monohydrate was added to 59.6 parts by weight of a 60% by weight sodium lactate aqueous solution heated at 70 ° C., and 7.4 parts by weight of 98% by weight sodium lactate was dissolved by heating and stirring, followed by heating and melting at 80 ° C. 33.0 parts by weight of myristic acid ester (C14) was added, and the mixture was heated and stirred at 70 ° C. to obtain a preparation P.
(Q) Add 65.3 parts by weight of water to 30.7 parts by weight of a 60% by weight aqueous sodium lactate solution, stir and warm to 70 ° C. To this, 4.0 parts by weight of tetraglycerin monolaurate (C12) was added, and the mixture was stirred and mixed at 70 ° C. to prepare Formulation Q.
(R) 24.5 parts by weight of water is added to 74.5 parts by weight of a 60% by weight aqueous sodium lactate solution and stirred. To this was added 1.0 part by weight of tetraglycerin monolaurate (C12), and the mixture was stirred and mixed at 70 ° C. to prepare Formulation R.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存後、再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)比較例 60%乳酸ナトリウム水溶液 0.8重量%
(3)本発明 実施例1の製剤(A) 0.8重量%
製造後の観察
(1)比較対照
(2)(1)とほぼ同等の食感
(3)(2)よりジューシー感とコクがあり美味
冷蔵庫に一週間保存後の観察は(1)、(2)は共に風味が更に低下したが(3)は食感、風味共に良好であるとの評価で、(3)が10その他は0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, and further stored for 1 week in a refrigerator, and then reheated to observe the flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Addition amount of additive (1) No addition (2) Comparative example 60% sodium lactate aqueous solution 0.8% by weight
(3) Invention Formulation (A) of Example 1 0.8% by weight
Observations after production (1) Comparison (2) (1) Almost the same texture as (1) (3) (2) More juicy and richer The observation after storage in the refrigerator for one week is (1), (2 ) Was further reduced in flavor, but (3) was evaluated as having good texture and flavor, and (3) was rated as 10 for others and 0.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存後、再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)比較例 60%乳酸ナトリウム水溶液 0.3重量%
(3)本発明 実施例1の製剤(B) 0.3重量%
製造後の観察
(1)対照
(2)(1)とほぼ同等の食感
(3)(1)、(2)よりジューシー感とコクがあり美味
冷蔵庫に一週間保存後の観察は(1)、(2)共に香味が更に低下したが(3)は食感、風味共に良好であるとの評価で(3)が10その他は0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, and further stored for 1 week in a refrigerator, and then reheated to observe the flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Addition amount of additive (1) No addition (2) Comparative example 60% sodium lactate aqueous solution 0.3% by weight
(3) Invention Formulation (B) of Example 1 0.3% by weight
Observation after production (1) Texture (3) (1), (2), almost the same as the control (2) (1) (2) The flavor was further reduced, but (3) was evaluated as having good texture and flavor, and (3) was rated as 10 for others and 0.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存後、再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)本発明実施例1の製剤(I) 0.7重量%
(2)比較例 ステアロイル乳酸ナトリウム 0.7重量%
(3)比較例 ステアロイル乳酸カルシウム 0.7重量%
(4)比較例 60%乳酸ナトリウム水溶液 0.7重量%

製造後の観察
(1)ジューシー感ソフト感共に最も良好であった。
(2)ジューシー感ソフト感は(1)より劣り脂っぽい味で風味が低下し、(4)よりやや良好。
(3)ジューシー感はなく、パサついた食感でしぶみがあり最も悪かった。
(4)ジューシー感ソフト感は(2)よりやや劣るが、(3)より良好。
冷蔵庫に一週間保存後の観察は(2)、(3)、(4)共に風味が更に低下したが(1)は食感、風味共に極めて良好であるとの評価で(1)が10その他は0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, and further stored for 1 week in a refrigerator, and then reheated to observe the flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Addition amount of additive (1) Formulation (I) of Example 1 of the present invention 0.7% by weight
(2) Comparative Example Sodium stearoyl lactate 0.7% by weight
(3) Comparative Example Calcium stearoyl lactate 0.7% by weight
(4) Comparative Example 60% sodium lactate aqueous solution 0.7% by weight

Observation after production (1) The succulent soft feeling was the best.
(2) Juicy soft feeling is inferior to (1) and has a greasy taste and lower flavor, and slightly better than (4).
(3) There was no succulent feeling, the texture was crunchy, and it was the worst.
(4) Juicy soft feeling is slightly inferior to (2) but better than (3).
The observation after storage in the refrigerator for one week (2), (3), (4) was further reduced in flavor, but (1) is an evaluation that the texture and flavor are very good (1) is 10 and others Was rated 0.

蒸しギョウザレシピ
合挽肉(牛:豚=1:1) 350部
白菜 100部
食塩 5部
醤油 10部
ゴマ油 10部

上記素材からなるギョウザの具に実施例1の製剤(D)を1.0重量%煉り込んだものと無添加品をそれぞれ市販のギョウザの皮に包み90℃で20分間蒸した後試食した結果、発明区はジューシー感ソフト感風味共に良好であったが対照区は固さと「パサつき」があり食感風味が低下した。
又それぞれを1週間冷凍し解凍後再加熱して試食した結果も同様で習熟したパネラー10人のパネル結果は10:0であった。
Steamed gyoza recipe Ground meat (cow: pork = 1: 1) 350 parts Chinese cabbage 100 parts Salt 5 parts Soy sauce 10 parts Sesame oil 10 parts

Result of tasting after 10% of the formulation (D) of Example 1 embedded in gyoza ingredient made of the above materials and additive-free product wrapped in commercially available gyoza skin and steamed at 90 ° C for 20 minutes. The invention group had good succulent and soft feeling, while the control group had hardness and “passy” and the texture was lowered.
The result of freezing each sample for one week, thawing, reheating, and tasting was the same, and the panel result of 10 trained panelists was 10: 0.

ソーセージ
表1に示した通り、それぞれの素材および実施例1の製剤(F)およびアルカリ剤を併用煉合し、常法によりソーセージを製造した。
Sausage As shown in Table 1, each raw material, the preparation (F) of Example 1 and an alkali agent were combined and sausage was produced by a conventional method.

アルカリ剤
成分
DL−アラニン 5%
L−グルタミン酸ナトリウム 3%
クエン酸三ナトリウム 26%
塩化カリウム 5.5%
炭酸ナトリウム 25%
デキストリン 35.5%
Alkaline agent component DL-alanine 5%
Sodium L-glutamate 3%
Trisodium citrate 26%
Potassium chloride 5.5%
Sodium carbonate 25%
Dextrin 35.5%

得られたソーセージにつき習熟したパネラー10名により風味品質を官能試験により判定した。発明区1はジューシー感ソフト感風味が最も優れ、次いで発明区2がよく、対照区3はジューシー感ソフト感がなく食感風味共に10:0で発明区より劣るとの評価であった。   The taste quality was judged by a sensory test by 10 panelists who were familiar with the obtained sausage. Invention Group 1 was most excellent in juicy soft taste, followed by Invention Group 2, and Control Group 3 was evaluated as having no juicy soft feeling and having a texture of 10: 0, both inferior to the invention group.

ソーセージ
表2に示した通り、それぞれの素材および実施例1の製剤(G)を煉合し、常法によりソーセージを製造した。
Sausage As shown in Table 2, each raw material and the preparation (G) of Example 1 were refined and sausages were produced by a conventional method.

得られたソーセージにつき習熟したパネラー10名により風味品質を官能試験により判定した。発明区1はジューシー感ソフト感風味共に優れ、対照区2はジューシー感ソフト感がなく食感風味共に発明区より劣り発明区:対照区=10:0の評価であった。   The taste quality was judged by a sensory test by 10 panelists who were familiar with the obtained sausage. Invention Group 1 was superior in both juicy and soft feeling, and Control Group 2 had no juicy and soft feeling and was inferior in texture to the Invention Group. Invention Group: Control Group = 10: 0.

蒸しギョウザレシピ
合挽肉(牛:豚=1:1) 350部
白菜 100部
食塩 5部
醤油 10部
ゴマ油 10部

上記素材からなるギョウザの具に実施例1の製剤(H)を5部煉り込んだものと無添加品をそれぞれ市販のギョウザの皮に包み90℃で20分間蒸した後試食した結果、発明区はジューシー感としっかりとした食感があり、風味共に良好であったが、対照区は固さと「パサつき」があり、食感風味が低下した。
又それぞれを1週間冷凍し解凍後再加熱して試食した結果も同様で習熟したパネラー10人のパネル結果は10:0であった。
Steamed gyoza recipe Ground meat (cow: pork = 1: 1) 350 parts Chinese cabbage 100 parts Salt 5 parts Soy sauce 10 parts Sesame oil 10 parts

As a result of tasting after wrapping 5 parts of the preparation (H) of Example 1 in the gyoza made of the above materials and additive-free products in a commercially available gyoza skin and steaming at 90 ° C. for 20 minutes. Had a succulent and firm texture and good flavor, but the control group had a firmness and a “passy” texture, and the texture was reduced.
The result of freezing each sample for one week, thawing, reheating, and tasting was the same, and the panel result of 10 trained panelists was 10: 0.

蒸し蒲鉾
下記材料及び製剤を練合、成型後85〜90℃で30分間蒸す。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存し風味品質を観察した。
蒸し蒲鉾レシピ
すり身 206部
食塩 6.3部
水 34.3部
調味液 53.4部
(調味液レシピ)
上白糖 4.4部
MSG 2.2部
片栗粉 10.8部
水 36部
添加剤の添加量
(1)無添加(対照)
(2)実施例1の製剤(E) 1.8重量部添加(対すり上がり全量)

製造後の観察
製造直後(2)はソフトでジューシー感があり風味も良好であったが(1)は固くザラついた食感で風味が低下した。冷蔵1週間後の観察も同様であった。パネラー10人の評価は、製造直後、冷蔵1週間後共に(2)が良好で(2)が10、(1)は0の評価であった。
Steamed rice cake The following ingredients and preparations are kneaded and steamed at 85 to 90 ° C. for 30 minutes after molding. The flavor quality was observed by 10 panelists who were trained after cooling, and further stored in the refrigerator for 1 week to observe the flavor quality.
Steamed crab recipe Surimi 206 parts Salt 6.3 parts Water 34.3 parts Seasoning liquid 53.4 parts (Seasoning liquid recipe)
Upper white sugar 4.4 parts MSG 2.2 parts Starch flour 10.8 parts Water 36 parts Addition amount of additive (1) No addition (control)
(2) Preparation of Example 1 (E) 1.8 parts by weight added (overall amount)

Observation after production Immediately after production (2) was soft and succulent and good in flavor, but (1) had a hard and rough texture and the flavor was lowered. The observation after 1 week of refrigeration was the same. As for the evaluation of 10 panelists, (2) was good, (2) was 10, and (1) was 0, both immediately after manufacture and after 1 week of refrigeration.

ミンチボール
下記材料及び製剤を混合し、それぞれ1個約17gに成型する。打ち粉を付けて160〜165℃の油で4分間揚げる。
冷却後習熟したパネラー10名により風味品質を観察する。更に冷凍1ケ月後電子レンジで再加熱して風味品質を観察する。
ミンチボールレシピ
合挽肉(牛:豚=1:1) 400部
みじん切り玉葱 150部
卵 50部
片栗粉 24部
上白糖 3部
食塩 5部
コショウ 0.5部
打ち粉:片栗粉使用

添加剤の添加量
(1)無添加
(2)60%乳酸ナトリウム水溶液 0.95重量%
(3)ジグリセリンモノミリスチン酸エステル 0.05重量%
(4)60%乳酸ナトリウム水溶液 0.95重量%
及びジグリセリンモノミリスチン酸エステル 0.05重量%(別々に添加)
(5)実施例1の製剤(C) 1.0重量%
※添加量は対ミートボール全量
製造後の観察
(1)、(2)、(3)は殆んどジューシー感はなく風味、食感を比較すると僅
差で(3)>(2)>(1)の順で良好であった。(4)、(5)は(1)、(2)、(3)よりジューシー感、歯切れ、風味、食感共に良好であった。(4)、(5)の比較ではさらに(5)の方がジューシー感、風味、食感がよく、むらなく安定していた。
Mince balls The following ingredients and preparations are mixed and molded into about 17 g each. Apply flour and fry in oil at 160-165 ° C for 4 minutes.
The flavor quality is observed by 10 panelists who have mastered after cooling. Further, after 1 month of freezing, reheat in a microwave and observe the flavor quality.
Mince ball recipe Ground meat (cow: pork = 1: 1) 400 parts minced onion 150 parts egg 50 parts potato starch 24 parts white saccharose 3 parts salt 5 parts pepper 0.5 parts dusting powder: using potato starch

Addition amount of additive (1) No addition (2) 60% sodium lactate aqueous solution 0.95% by weight
(3) Diglycerin monomyristic acid ester 0.05% by weight
(4) 60% sodium lactate aqueous solution 0.95% by weight
And diglycerin monomyristic acid ester 0.05% by weight (added separately)
(5) Formulation (C) of Example 1 1.0% by weight
* The amount added is the observation after production of the whole meatballs (1), (2), (3) is almost succulent and there is little difference when comparing flavor and texture (3)>(2)> (1 ) In order. In (4) and (5), juiciness, crispness, flavor and texture were better than those in (1), (2) and (3). In comparison between (4) and (5), (5) was more succulent, flavored and textured and evenly stable.

※各パネラーが(1)〜(5)のミンチボールを試食し、最高10点〜最低1点の範囲で採点する。検体ごとにその平均点を表3に示した。 * Each panelist will try the minced balls from (1) to (5) and score in the range of 10 points to 1 point. The average score for each specimen is shown in Table 3.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存後、再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)本発明 実施例1の製剤(J) 2.5重量%
製造後の観察
(1)対照
(2)(1)よりかなりジューシー感とコクがあり美味
冷蔵庫に一週間保存後の観察は(1)は共に風味が更に低下したが(2)は食感、風味共に良好であるとの評価で、(2)が10、(1)は0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, and further stored for 1 week in a refrigerator, and then reheated to observe the flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Addition amount of additive (1) No addition (2) Invention formulation (J) of Example 1 2.5% by weight
Observation after production (1) The control (2) (1) is considerably juicy and richer than the (1), and the taste after storage for one week in the refrigerator (1) was further reduced in flavor, but (2) was texture, In the evaluation that both flavors were good, (2) was 10, and (1) was 0.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存後、再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)本発明 実施例1の製剤(K) 1.0重量%
製造後の観察
(1)対照
(2)(1)よりややジューシー感とコクがある。
冷蔵庫に一週間保存後の観察は(1)の香味が更に低下したが(2)は食感、風味共に良好であるとの評価で(2)が10、(1)は0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, and further stored for 1 week in a refrigerator, and then reheated to observe the flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Addition amount of additives (1) No addition (2) Invention formulation (K) of Example 1 1.0% by weight
Observation after production (1) Slightly juicy and richer than controls (2) and (1).
Observation after storage in the refrigerator for one week showed that the flavor of (1) was further reduced, but (2) was evaluated as good in texture and flavor, (2) was 10, and (1) was rated 0. It was.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷凍し、1週間保存後、解凍後再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)本発明 実施例1の製剤(L) 0.25重量%
(3)本発明 実施例1の製剤(Q) 0.25重量%
(4)本発明 実施例1の製剤(R) 0.25重量%
製造後の観察
(1)対照
(2)(1)よりややジューシー感とコクがある。
(3)(1)と同程度で効果が見られない。(食肉に対して乳酸ナトリウムの量が少ない。)
(4)(1)と同程度で効果が見られない。(食肉に対してグリセリン脂肪酸エステルの量が少ない。)
冷蔵庫に一週間保存後の観察は、(1)、(3)、(4)の香味が更に低下したが(2)は食感、風味共にやや良好であるとの評価で(2)が10、(1)、(3)、(4)は0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, further frozen, stored for 1 week, reheated after thawing, and observed for flavor flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Additive amount of additive (1) No addition (2) Invention Formulation (L) of Example 1 0.25 wt%
(3) Invention Formulation (Q) of Example 1 0.25% by weight
(4) Invention Formulation (R) of Example 1 0.25% by weight
Observation after production (1) Slightly juicy and richer than controls (2) and (1).
(3) No effect is seen at the same level as (1). (The amount of sodium lactate is less than meat.)
(4) No effect is seen at the same level as (1). (The amount of glycerin fatty acid ester is small relative to meat.)
Observation after storage in the refrigerator for one week showed that the flavors of (1), (3), and (4) were further reduced, but (2) was evaluated as slightly satisfactory in both texture and flavor. , (1), (3), (4) were rated 0.

ハンバーグ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により風味品質を観察し、更に冷蔵庫に1週間保存後冷凍し、更に一週間保存後解凍し、再加熱して香味風味を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
みじん切玉葱 100部
卵 50部
水 30部
パン粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)本発明 実施例1の製剤(L) 2.0重量%
(3)本発明 実施例1の製剤(L) 4.0重量%
(4)本発明 実施例1の製剤(O) 3.5重量%
(5)本発明 実施例1の製剤(O) 4.2重量%
(6)本発明 実施例1の製剤(P) 4.2重量%
製造後の観察
(1)対照
(2)(1)よりかなりジューシー感とコクがあり、塩味がある。
(3)(2)よりさらに力強いコクとボディー感(食べ応え)があり、さらに塩味が増す。
(4)(3)よりコクとボディー感がやや薄いが、塩味はやや増している。
(5)塩味が強く、えぐ味、金属味を感じる。(食肉に対して乳酸ナトリウムの量が多い。)
(6)塩味があり、えぐ味、苦味を感じる。(食肉に対してグリセリン脂肪酸エステルの量が少ない。)
冷蔵庫に1週間保存後冷凍し、更に一週間保存後解凍し、再加熱後の観察は(1)の香味が更に低下したが(2)、(3)、(4)は食感、風味共に良好であるとの評価で(2)が9、(3)が5、(4)が4、(1)が0の評価であった。(5)、(6)は食感、風味の低下は見られなかったが、元々味が悪く、それぞれ0の評価であった。
Hamburg The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor quality was observed by 10 panelists who were trained after cooling, further stored in the refrigerator for 1 week, frozen, stored for another week, thawed, reheated and observed for flavor.
Recipe Minced meat (cow: pork = 1: 1) 400 parts Michin cut onion 100 parts Egg 50 parts Water 30 parts Bread crumbs 25 parts Salt 4.5 parts Pepper 0.5 parts

Additive amount of additive (1) No addition (2) Invention Formulation (L) of Example 1 2.0% by weight
(3) Invention Formulation (L) of Example 1 4.0% by weight
(4) Invention Formulation (O) of Example 1 3.5% by weight
(5) Invention Formulation (O) of Example 1 4.2 wt%
(6) Invention Formulation (P) of Example 1 4.2% by weight
Observation after production (1) The control (2) and (1) are much more juicy and richer and have a salty taste.
(3) There is a stronger body and body feeling (eating response) than (2), and the salty taste is further increased.
(4) The body feel is slightly lighter than (3), but the saltiness is slightly increased.
(5) It has a strong salty taste and feels gummy and metallic. (The amount of sodium lactate is larger than the meat.)
(6) It has a salty taste and feels sour and bitter. (The amount of glycerin fatty acid ester is small relative to meat.)
Refrigerate for 1 week after storage in the refrigerator, thaw after further storage for 1 week, and the observation after reheating has further decreased the flavor of (1) (2), (3), (4) are both texture and flavor In the evaluation that it was good, (2) was 9, (3) was 5, (4) was 4, and (1) was 0. In (5) and (6), although the texture and flavor did not deteriorate, the taste was originally bad and the evaluation was 0 respectively.

ミンチボール
下記材料及び製剤を混合し、それぞれ1個約17gに成型する。打ち粉を付けて160〜165℃の油で4分間揚げる。
冷却後習熟したパネラー10名により風味品質を観察する。更に冷凍1ケ月後電子レンジで再加熱して風味品質を観察する。
ミンチボールレシピ
合挽肉(牛:豚=1:1) 400部
みじん切り玉葱 150部
卵 50部
片栗粉 24部
上白糖 3部
食塩 5部
コショウ 0.5部
打ち粉:片栗粉使用

添加剤の添加量
(1)無添加
(2)実施例1の製剤(M) 2.0重量%
※添加量は対ミートボール全量
製造後の観察
(1)殆んどジューシー感はなかった。
(2)ジューシー感、歯切れ、風味、食感共に良好でコクがあった。
味覚実験
※各パネラーが(1)、(2)のミンチボールを試食し、最高10点〜最低1点の範囲で採点する。検体ごとにその平均点を表4に示した。
Mince balls The following ingredients and preparations are mixed and molded into about 17 g each. Apply flour and fry in oil at 160-165 ° C for 4 minutes.
The flavor quality is observed by 10 panelists who have mastered after cooling. Further, after 1 month of freezing, reheat in a microwave and observe the flavor quality.
Mince ball recipe Ground meat (cow: pork = 1: 1) 400 parts minced onion 150 parts egg 50 parts potato starch 24 parts white saccharose 3 parts salt 5 parts pepper 0.5 parts dusting powder: using potato starch

Additive amount of additive (1) No addition (2) Formulation (M) of Example 1 2.0% by weight
* The amount added was observed after the production of all meatballs (1) There was almost no succulent feeling.
(2) The succulent feeling, crispness, flavor and texture were good and rich.
Taste experiment * Each panelist will taste the minced balls from (1) and (2) and score in the range of 10 points to 1 point. The average score for each specimen is shown in Table 4.

ハンバーグパテ
下記材料及び製剤を混合し夫々50g2個ずつ成型し、予熱した250℃のオーブンで10分間加熱した。冷却後習熟したパネラー10名により香味風味品質を観察した。
レシピ
合挽肉(牛:豚=1:1) 400部
卵 50部
水 30部
片栗粉 25部
塩 4.5部
コショウ 0.5部

添加剤の添加量
(1)無添加
(2)本発明 実施例1の製剤(F) 1.0重量%
製造後の観察
(1)対照
(2)(1)よりジューシー感とコクがある。
(1)は香味が低下し、硬く食感が悪い。(2)は食感、風味共に良好であるとの評価で(2)が10、(1)は0の評価であった。
Hamburg putty The following materials and preparations were mixed, 50 g each was molded, and heated in a preheated 250 ° C. oven for 10 minutes. The flavor flavor quality was observed by 10 panelists who were trained after cooling.
Recipe Minced meat (cow: pig = 1: 1) 400 parts Egg 50 parts Water 30 parts Starch flour 25 parts Salt 4.5 parts Pepper 0.5 parts

Additive amount of additive (1) No addition (2) Invention Formulation (F) of Example 1 1.0% by weight
Observation after production (1) There are more juicy and richer than the control (2) and (1).
(1) has a reduced flavor, is hard and has a poor texture. (2) is an evaluation that the texture and flavor are both good, (2) is 10, and (1) is 0.

本発明の食肉風味向上剤は、ハンバーグ、ハム、ソーセージ、ミンチボール、肉まん、シウマイ、ギョウザ、蒲鉾、竹輪等の畜肉、鳥肉、魚肉などの食肉に添加することにより、肉質の柔らかい弾力性とジューシー感を高め、しかも風味が良く歯切れの良い食肉を提供することができるので、これ等の処理、加工品の冷蔵、冷凍品に添加することができる。   The meat flavor improver of the present invention has a soft elasticity of meat quality by adding it to meat such as hamburger, ham, sausage, minced ball, meat bun, siamese, gyoza, salmon, bamboo rings, etc. Since it is possible to provide a succulent, crisp and crisp meat, it can be added to these treatments, refrigerated processed products, and frozen products.

Claims (7)

乳酸ナトリウム(a)とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を添加して風味を向上させた食肉。   Meat whose flavor is improved by adding sodium lactate (a) and glycerin monofatty acid ester or polyglycerin fatty acid ester (b). 食肉に対して乳酸ナトリウム(a)を0.08〜4.0重量%とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を0.005〜2.0%添加して風味を向上させた請求項1記載の食肉。   Claims for improving flavor by adding 0.08 to 4.0% by weight of sodium lactate (a) and 0.005 to 2.0% of glycerol mono-fatty acid ester or polyglycerol fatty acid ester (b) to meat Item 1. Meat according to Item 1. さらに酸類、塩類又はアルカリ剤を添加して風味を向上させた請求項1又は2記載の食肉。   Furthermore, the meat of Claim 1 or 2 which added acid, salt, or an alkaline agent, and improved the flavor. グリセリンモノ脂肪酸エステルを構成する脂肪酸が炭素数8〜18のものであり、ポリグリセリン脂肪酸エステルのグリセリンの重合度が2〜10、エステル結合している脂肪酸の数が1〜4、構成する脂肪酸が炭素数8〜18のものである請求項1〜3のいずれかに記載の食肉。   The fatty acid constituting the glycerin monofatty acid ester is one having 8 to 18 carbon atoms, the degree of polymerization of glycerin in the polyglycerin fatty acid ester is 2 to 10, the number of ester-bonded fatty acids is 1 to 4, and the constituting fatty acid is The meat according to any one of claims 1 to 3, which has 8 to 18 carbon atoms. 乳酸ナトリウム(a)1重量部に対して、グリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を0.003〜1.000重量部配合した食肉風味向上剤。   Meat flavor improver which mix | blended 0.003-1.000 weight part of glycerol mono-fatty acid ester or polyglycerol fatty acid ester (b) with respect to 1 weight part of sodium lactate (a). 乳酸ナトリウムの水溶液に溶融したグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪エステルを均一に混和する食肉風味向上剤の製造法。   A method for producing a meat flavor enhancer, wherein glycerin monofatty acid ester or polyglycerin fatty ester melted in an aqueous solution of sodium lactate is uniformly mixed. 食肉に対して乳酸ナトリウム(a)を0.08〜4.0重量%とグリセリンモノ脂肪酸エステル又はポリグリセリン脂肪酸エステル(b)を0.005〜2.0%添加する食肉の風味向上法。   A method for improving the flavor of meat, wherein 0.08 to 4.0% by weight of sodium lactate (a) and 0.005 to 2.0% of glycerin monofatty acid ester or polyglycerin fatty acid ester (b) are added to meat.
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JP2015057949A (en) * 2013-09-17 2015-03-30 理研ビタミン株式会社 Quality improver for meat processed foods and meat processed foods containing the quality improver
JP2015195781A (en) * 2014-04-03 2015-11-09 日清フーズ株式会社 Sprinkle type mix for deep-fried food
CN115460933A (en) * 2020-05-04 2022-12-09 西姆莱斯有限公司 Flavour composition for improving taste impression
WO2023188895A1 (en) * 2022-03-31 2023-10-05 不二製油グループ本社株式会社 Agent for improving quality of processed meat food product

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* Cited by examiner, † Cited by third party
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JP2015057949A (en) * 2013-09-17 2015-03-30 理研ビタミン株式会社 Quality improver for meat processed foods and meat processed foods containing the quality improver
JP2015195781A (en) * 2014-04-03 2015-11-09 日清フーズ株式会社 Sprinkle type mix for deep-fried food
CN115460933A (en) * 2020-05-04 2022-12-09 西姆莱斯有限公司 Flavour composition for improving taste impression
WO2023188895A1 (en) * 2022-03-31 2023-10-05 不二製油グループ本社株式会社 Agent for improving quality of processed meat food product

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