JP4472645B2 - Spring roll skin oil composition - Google Patents
Spring roll skin oil composition Download PDFInfo
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- JP4472645B2 JP4472645B2 JP2006029575A JP2006029575A JP4472645B2 JP 4472645 B2 JP4472645 B2 JP 4472645B2 JP 2006029575 A JP2006029575 A JP 2006029575A JP 2006029575 A JP2006029575 A JP 2006029575A JP 4472645 B2 JP4472645 B2 JP 4472645B2
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- 239000003925 fat Substances 0.000 claims description 67
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Landscapes
- Edible Oils And Fats (AREA)
- Seeds, Soups, And Other Foods (AREA)
Description
本発明は、春巻の皮に塗布または噴霧して用いられる油脂組成物に関する。 The present invention relates to an oil and fat composition used by applying or spraying to spring roll skin.
揚げ春巻は、春巻の皮のクリスピーなパリパリとした食感と、春巻の皮に巻かれた具材のソフトな食感との両方が同時に味わえることが望まれており、食用油脂で揚げた直後の春巻においてはこのような食感が得られる。しかし、該春巻は通常時間の経過と共にパリパリとした食感を失う。また上記加熱処理した春巻を凍結保存した冷凍春巻を、電子レンジやオーブントースターで再加熱するとこのような食感が著しく損なわれ、従来問題となっていた。 Deep-fried spring rolls are desired to be able to taste both the crispy and crispy texture of spring rolls and the soft texture of ingredients wrapped around spring rolls. In the spring roll immediately after fried, such a texture is obtained. However, the spring roll usually loses its crispy texture over time. In addition, when a frozen spring roll obtained by freezing the heat-treated spring roll is reheated with a microwave oven or an oven toaster, such a texture is remarkably impaired, which has been a conventional problem.
この問題を解決するための手段の一つに、春巻の皮に油脂または油脂組成物を塗布または噴霧する方法があり、該油脂または油脂組成物として、融点35℃以下の油脂100重量部に対して、乳化剤を0.5重量部以上5重量部以下で含有し、前記乳化剤は、少なくとも2種のグリセリン脂肪酸エステルからなることを特徴とする春巻皮改質用油脂組成物(特許文献1参照)、融点30〜50℃、結晶の平均粒径20〜100μの油脂(特許文献2参照)、水分含量10〜20重量%の固形状または半固形状の油脂(特許文献3参照)、固形脂またはホイッピングした油脂(特許文献4参照)、油脂および地下でんぷん類を含む穀物微粉砕物を主成分とし、油脂と穀物微粉砕物の比が50〜90重量部対50〜10重量部である非水系乳化分散物(特許文献5参照)、などが提案されている。 One of the means for solving this problem is a method of applying or spraying oil or fat composition to the spring roll skin. As the oil or fat composition, 100 parts by weight of oil having a melting point of 35 ° C. or less. On the other hand, it contains an emulsifier in an amount of 0.5 parts by weight or more and 5 parts by weight or less, and the emulsifier is composed of at least two glycerin fatty acid esters (Patent Document 1). Reference), melting point of 30 to 50 ° C., fat and oil having an average crystal grain size of 20 to 100 μm (see Patent Document 2), solid or semi-solid oil and fat having a water content of 10 to 20% by weight (see Patent Document 3), solid Fat or whipped fat and oil (see Patent Document 4), finely pulverized cereals containing fats and fats and underground starches are the main components, and the ratio of fats and fats and finely pulverized cereals is 50 to 90 parts by weight to 50 to 10 parts by weight. Non-aqueous emulsion Object (see Patent Document 5), have been proposed.
しかし、前述の油脂または油脂組成物では十分な効果が得られていないのが実状である。
本発明は、春巻の皮に塗布または噴霧することにより、食用油脂で揚げた直後のパリパリとした食感が長時間保たれ、また前記加熱処理した春巻を凍結保存した冷凍春巻を、電子レンジやオーブントースターで再加熱してもパリパリとした食感が維持される、油脂組成物を提供することを目的とする。 By applying or spraying on the spring roll skin, the present invention maintains a crispy texture immediately after fried in edible oils and fats, and the frozen spring roll obtained by freezing and storing the heat-treated spring roll, An object of the present invention is to provide an oil and fat composition that maintains a crispy texture even when reheated in a microwave oven or oven toaster.
本発明者らは、上記課題を解決するため鋭意検討した結果、常温で液状の植物油脂と、上昇融点が50〜90℃の油脂と、ポリグリセリン不飽和脂肪酸エステルおよび/またはプロピレングリコール不飽和脂肪酸エステルとを3つの必須構成成分として含有する油脂組成物を創製し、該油脂組成物を春巻の皮に塗布または噴霧した後常法により揚げ春巻を調理することにより上記した課題で示した効果を奏する春巻きが製造されることを見いだし、この知見に基づいて本発明をなすに至った。 As a result of intensive studies to solve the above-mentioned problems, the present inventors have found that vegetable oils and fats that are liquid at room temperature, oils and fats with rising melting points of 50 to 90 ° C., polyglycerol unsaturated fatty acid esters and / or propylene glycol unsaturated fatty acids. An oil and fat composition containing esters as three essential components was created, and the oil and fat composition was applied to or sprayed on the spring roll skin, and then fried spring rolls were cooked in a conventional manner to show the above-mentioned problems. It has been found that spring rolls having an effect are produced, and the present invention has been made based on this finding.
すなわち、本発明は、
(イ)常温で液状の植物油脂、(ロ)上昇融点が50〜90℃の油脂および(ハ)ポリグリセリン不飽和脂肪酸エステルおよび/またはプロピレングリコール不飽和脂肪酸エステルを含有し、春巻の皮に塗布または噴霧して用いられることを特徴とする油脂組成物、
(2)前記(1)に記載の油脂組成物を塗布または噴霧してなる春巻の皮、
(3)前記(2)に記載の春巻の皮を用いて調理されたことを特徴とする揚げ春巻、
(4)前記(3)に記載の揚げ春巻を凍結して得られる冷凍春巻、
からなっている。
That is, the present invention
(B) Contains vegetable oils and fats that are liquid at room temperature, (b) oils and fats having an elevated melting point of 50 to 90 ° C., and (c) polyglycerin unsaturated fatty acid esters and / or propylene glycol unsaturated fatty acid esters, An oil or fat composition characterized by being applied or sprayed;
(2) Spring roll skin formed by applying or spraying the oil and fat composition according to (1) above,
(3) Fried spring rolls characterized by being cooked using the spring roll skin as described in (2) above,
(4) A frozen spring roll obtained by freezing the fried spring roll according to (3),
It is made up of.
本発明の油脂組成物を塗布または噴霧した春巻の皮を用いることにより、食用油脂で揚げた直後のパリパリとした食感を長時間失わない揚げ春巻が得られる。
本発明の春巻の皮を用いて調理した揚げ春巻を凍結保存した冷凍春巻を、電子レンジやオーブントースターで再加熱してもパリパリとした食感が維持される。
By using the spring roll skin coated or sprayed with the oil and fat composition of the present invention, a deep-fried spring roll that does not lose the crispy texture immediately after being fried with edible oil and fat is obtained.
Even when the frozen spring roll prepared by freezing the fried spring roll cooked using the spring roll skin of the present invention is reheated with a microwave oven or an oven toaster, the crispy texture is maintained.
本発明で用いられる常温(約15〜25℃)で液状の植物油脂としては、食用に適するよう処理されたものであって該要件を満たすものであれば特に制限はなく、例えばオリーブ油、キャノーラ油、ごま油、米ぬか油、サフラワー油、ハイオレイックサフラワー油、大豆油、コーン油、パームオレイン、なたね油、ひまわり油、ハイオレイックひまわり油、綿実油などが挙げられる。これらの油脂は、一種類で用いても良いし、二種類以上を任意に組み合わせて用いても良い。 The vegetable oil and fat that is liquid at normal temperature (about 15 to 25 ° C.) used in the present invention is not particularly limited as long as it is processed to be edible and satisfies the requirements. For example, olive oil, canola oil Sesame oil, rice bran oil, safflower oil, high oleic safflower oil, soybean oil, corn oil, palm olein, rapeseed oil, sunflower oil, high oleic sunflower oil, cottonseed oil and the like. These fats and oils may be used alone or in any combination of two or more.
本発明で用いられる上昇融点が約50〜90℃の油脂(以下「高融点油脂」という)としては、食用に適するよう処理されたものであって該要件を満たすものであれば特に制限はなく、例えばオリーブ油、キャノーラ油、米ぬか油、サフラワー油、大豆油、コーン油、パーム油、パーム核油、なたね油、ひまわり油、綿実油、やし油、落花生油、牛脂、豚脂、魚油および乳脂などの動植物油脂を分別処理したもの、水素添加処理したもの(例えば、大豆極度硬化油、なたね極度硬化油等)、さらにこれらの動植物油脂単独または二種類以上を任意に組み合わせてエステル交換処理したものなどが挙げられる。これらの油脂は、一種類で用いても良いし、二種類以上を任意に組み合わせて用いても良い。上記の上昇融点は、「基準油脂分析試験法 2003年版」(社団法人 日本油化学会編)の[2.2.4.2−1996 融点(上昇融点)]に準じて測定される。 As fats and oils having an ascending melting point of about 50 to 90 ° C. used in the present invention (hereinafter referred to as “high melting point fats and oils”), there is no particular limitation as long as they are processed to be edible and satisfy the requirements. For example, olive oil, canola oil, rice bran oil, safflower oil, soybean oil, corn oil, palm oil, palm kernel oil, rapeseed oil, sunflower oil, cottonseed oil, palm oil, peanut oil, beef tallow, lard, fish oil and milk fat Oil and vegetable oils and fats that have been separated, hydrogenated (for example, soybean hardened oil, rapeseed extremely hardened oil, etc.), and those that have been transesterified in any combination of these animal and vegetable fats and fats. Etc. These fats and oils may be used alone or in any combination of two or more. The above-mentioned increase in the melting point of the is measured according to the "reference oil and fat analytical test method 2003 version" [2.2.4.2 -1996 melting point (rising melting point)] of (Japan Yuka Society of Japan).
本発明で用いられるポリグリセリン不飽和脂肪酸エステルの原料として用いられるポリグリセリンとしては、通常グリセリンに少量の酸またはアルカリを触媒として添加し、窒素または二酸化炭素などの任意の不活性ガス雰囲気下で、例えば約180℃以上の温度で加熱し、重縮合反応させて得られる重合度の異なるポリグリセリンの混合物が挙げられる。また、ポリグリセリンは、グリシドールまたはエピクロルヒドリンなどを原料として得られるものであっても良い。反応終了後、必要であれば中和、脱塩または脱色などの処理を行って良い。該ポリグリセリンとしては、グリセリンの平均重合度が通常約2〜20、好ましくは約2〜10のポリグリセリンが挙げられる。具体的には、例えばジグリセリン(平均重合度:約2.0)、トリグリセリン(平均重合度:約3.0)、テトラグリセリン(平均重合度:約4.0)、ヘキサグリセリン(平均重合度:約6.0)、オクタグリセリン(平均重合度:約8.0)およびデカグリセリン(平均重合度:約10.0)などが挙げられ、特にジグリセリンまたはトリグリセリンが好ましい。 As polyglycerin used as a raw material of polyglycerin unsaturated fatty acid ester used in the present invention, a small amount of acid or alkali is usually added to glycerin as a catalyst, and under any inert gas atmosphere such as nitrogen or carbon dioxide, For example, a mixture of polyglycerols having different degrees of polymerization obtained by heating at a temperature of about 180 ° C. or more and causing a polycondensation reaction can be mentioned. Polyglycerin may be obtained using glycidol or epichlorohydrin as a raw material. After completion of the reaction, a treatment such as neutralization, desalting or decolorization may be performed if necessary. Examples of the polyglycerin include polyglycerin having an average degree of polymerization of glycerin of usually about 2 to 20, preferably about 2 to 10. Specifically, for example, diglycerin (average polymerization degree: about 2.0), triglycerin (average polymerization degree: about 3.0), tetraglycerin (average polymerization degree: about 4.0), hexaglycerin (average polymerization) Degree: about 6.0), octaglycerin (average degree of polymerization: about 8.0), decaglycerin (average degree of polymerization: about 10.0) and the like, and diglycerin or triglycerin is particularly preferable.
本発明において、上記ポリグリセリンを、例えば蒸留またはカラムクロマトグラフィーなど自体公知の方法を用いて精製し、単一成分の含量を高濃度化した高純度ポリグリセリンが好ましく用いられる。そのような例としては、例えばグリセリン2分子からなるジグリセリンの含有量が約50質量%以上、好ましくは約85質量%以上である高純度ジグリセリン、およびグリセリン3分子からなるトリグリセリンの含有量が約50質量%以上、好ましくは約85質量%以上である高純度トリグリセリンなどが挙げられる。 In the present invention, high-purity polyglycerin obtained by purifying the polyglycerin using a method known per se, such as distillation or column chromatography, and increasing the concentration of a single component is preferably used. As such an example, for example, the content of diglycerin composed of 2 molecules of glycerin is about 50% by mass or more, preferably about 85% by mass or more, and the content of triglycerin composed of 3 molecules of glycerin. Is high purity triglycerin and the like, which is about 50% by mass or more, preferably about 85% by mass or more.
上記ポリグリセリン不飽和脂肪酸エステルの原料として用いられる脂肪酸としては、食用可能な動植物油脂を起源とし、炭素原子間の結合に二重結合を含む脂肪酸であれば特に制限はなく、例えばパルミトオレイン酸、オレイン酸、エライジン酸、リノール酸、γ−リノレン酸、α−リノレン酸、アラキドン酸、リシノール酸、縮合リシノール酸などが挙げられる。これら不飽和脂肪酸は一種類で用いても良いし、二種類以上を任意に組み合わせて用いても良い。また、上記原料として用いられる脂肪酸は不飽和脂肪酸を主体とし飽和脂肪酸を含む混合脂肪酸であってよく、その場合、不飽和脂肪酸の含有量は通常約50%以上、好ましくは約80%以上である。 The fatty acid used as a raw material for the polyglycerin unsaturated fatty acid ester is not particularly limited as long as it is a fatty acid that originates from edible animal and vegetable oils and contains a double bond in the bond between carbon atoms. For example, palmitooleic acid Oleic acid, elaidic acid, linoleic acid, γ-linolenic acid, α-linolenic acid, arachidonic acid, ricinoleic acid, condensed ricinoleic acid and the like. These unsaturated fatty acids may be used alone or in any combination of two or more. The fatty acid used as the raw material may be a mixed fatty acid mainly composed of unsaturated fatty acids and containing saturated fatty acids. In this case, the content of unsaturated fatty acids is usually about 50% or more, preferably about 80% or more. .
本発明で用いられるポリグリセリン不飽和脂肪酸エステルの好ましい例として、モノエステル体の含有量が約50質量%以上、好ましくは約70質量%以上であるジグリセリン不飽和脂肪酸エステルが挙げられる。このような組成のジグリセリン不飽和脂肪酸エステルの好ましい製法の概略は以下の通りである。即ち、高純度ジグリセリンと不飽和脂肪酸を原料として常法によりエステル化反応を行い、反応終了後、反応混合物中に残存する触媒を中和する。中和後、反応混合物を、所望により冷却して、約100℃〜180℃、好ましくは約130℃〜150℃に保ち、好ましくは約0.5時間以上、更に好ましくは約1〜10時間放置する。未反応のポリオールが下層に分離した場合はそれを除去する。上記処理後、得られたジグリセリン不飽和脂肪酸エステルを、好ましくは、更に減圧下で蒸留して残存する未反応のポリオールを留去し、続いて、例えば流下薄膜式分子蒸留装置または遠心式分子蒸留装置などを用いて分子蒸留するか、またはカラムクロマトグラフィーもしくは液液抽出など自体公知の方法を用いて精製することにより、モノエステル体を約50質量%以上、好ましくは約70質量%以上含むジグリセリン不飽和脂肪酸エステルを得る。 A preferred example of the polyglycerin unsaturated fatty acid ester used in the present invention is a diglycerin unsaturated fatty acid ester having a monoester content of about 50% by mass or more, preferably about 70% by mass or more. The outline of the preferable manufacturing method of the diglycerin unsaturated fatty acid ester of such a composition is as follows. That is, an esterification reaction is performed by a conventional method using high-purity diglycerin and an unsaturated fatty acid as raw materials, and after the reaction, the catalyst remaining in the reaction mixture is neutralized. After neutralization, the reaction mixture is optionally cooled and maintained at about 100 ° C. to 180 ° C., preferably about 130 ° C. to 150 ° C., preferably about 0.5 hours or longer, more preferably about 1 to 10 hours. To do. If unreacted polyol is separated into the lower layer, it is removed. After the above treatment, the diglycerin unsaturated fatty acid ester obtained is preferably further distilled under reduced pressure to distill off the remaining unreacted polyol, followed by, for example, a falling film type molecular distillation apparatus or a centrifugal molecule. The monoester is contained in an amount of about 50% by mass or more, preferably about 70% by mass or more by molecular distillation using a distillation apparatus or the like, or by purification using a method known per se such as column chromatography or liquid-liquid extraction. Diglycerin unsaturated fatty acid ester is obtained.
本発明で用いられるプロピレングリコール不飽和脂肪酸エステルは、プロピレングリコールと不飽和脂肪酸とのエステル化反応生成物であり、エステル化反応など自体公知の方法で製造される。該プロピレングリコール不飽和脂肪酸エステルの原料として用いられる脂肪酸としては、食用可能な動植物油脂を起源とし、炭素原子間の結合に二重結合を含む脂肪酸であれば特に制限はなく、例えばパルミトオレイン酸、オレイン酸、エライジン酸、リノール酸、γ−リノレン酸、α−リノレン酸、アラキドン酸、リシノール酸、縮合リシノール酸などが挙げられる。これら不飽和脂肪酸は一種類で用いても良いし、二種類以上を任意に組み合わせて用いても良い。また、上記原料として用いられる脂肪酸は不飽和脂肪酸を主体とし飽和脂肪酸を含む混合脂肪酸であってよく、その場合、不飽和脂肪酸の含有量は通常約50%以上、好ましくは約80%以上である。 The propylene glycol unsaturated fatty acid ester used in the present invention is an esterification reaction product of propylene glycol and an unsaturated fatty acid, and is produced by a method known per se such as an esterification reaction. The fatty acid used as a raw material for the propylene glycol unsaturated fatty acid ester is not particularly limited as long as it is a fatty acid that originates from edible animal and vegetable oils and contains a double bond between carbon atoms. For example, palmitooleic acid Oleic acid, elaidic acid, linoleic acid, γ-linolenic acid, α-linolenic acid, arachidonic acid, ricinoleic acid, condensed ricinoleic acid and the like. These unsaturated fatty acids may be used alone or in any combination of two or more. The fatty acid used as the raw material may be a mixed fatty acid mainly composed of unsaturated fatty acids and containing saturated fatty acids. In this case, the content of unsaturated fatty acids is usually about 50% or more, preferably about 80% or more. .
本発明で用いられるプロピレングリコール不飽和脂肪酸エステルの好ましい例として、モノエステル体の含有量が約50質量%以上、好ましくは約90質量%以上であるプロピレングリコール不飽和脂肪酸エステルが挙げられる。このような組成のプロピレングリコール不飽和脂肪酸エステルの製法の概略は以下の通りである。即ち、プロピレングリコールと不飽和脂肪酸を原料として常法によりエステル化反応を行い、反応終了後、反応混合物中に残存する触媒を中和する。中和後、反応混合物を、減圧下で蒸留して未反応のプロピレングリコールを留去し、続いて、例えば流下薄膜式分子蒸留装置または遠心式分子蒸留装置などを用いて分子蒸留するか、またはカラムクロマトグラフィーもしくは液液抽出など自体公知の方法を用いて精製することにより、モノエステル体を約50質量%以上、好ましくは約90質量%以上含むプロピレングリコール不飽和脂肪酸エステルを得る。 Preferable examples of the propylene glycol unsaturated fatty acid ester used in the present invention include a propylene glycol unsaturated fatty acid ester having a monoester content of about 50% by mass or more, preferably about 90% by mass or more. The outline of the production method of the propylene glycol unsaturated fatty acid ester having such a composition is as follows. That is, an esterification reaction is carried out by a conventional method using propylene glycol and an unsaturated fatty acid as raw materials, and after completion of the reaction, the catalyst remaining in the reaction mixture is neutralized. After neutralization, the reaction mixture is distilled under reduced pressure to distill off unreacted propylene glycol, followed by molecular distillation using, for example, a falling film molecular distillation device or a centrifugal molecular distillation device, or By purifying using a method known per se such as column chromatography or liquid-liquid extraction, a propylene glycol unsaturated fatty acid ester containing about 50% by mass or more, preferably about 90% by mass or more of the monoester is obtained.
ポリグリセリン不飽和脂肪酸エステルおよびプロピレングリコール不飽和脂肪酸エステルは水分を取り込み、包水ゲルを形成する作用を有することから、本発明の油脂組成物を春巻の皮の内側に塗布または散布することにより、具材から皮への水の移行を抑制することができる。 Since polyglycerin unsaturated fatty acid ester and propylene glycol unsaturated fatty acid ester have the action of taking up moisture and forming a water-containing gel, by applying or spraying the oil and fat composition of the present invention to the inside of spring roll skin It is possible to suppress the transfer of water from the ingredients to the skin.
本発明の油脂組成物100質量%中における各成分の含有量は、常温で液状の植物油脂が通常約70〜97質量%、好ましくは約75〜95質量%、高融点油脂が通常約1〜20質量%、好ましくは約3〜15質量%並びにポリグリセリン不飽和脂肪酸エステルおよび/またはプロピレングリコール不飽和脂肪酸エステルが通常約0.5〜15質量%、好ましくは約1〜10質量%である。本発明の油脂組成物には、更に、高融点油脂の結晶調整剤として、グリセリン脂肪酸エステルまたはソルビタン脂肪酸エステルを油脂組成物100質量部に対して約0.05〜3質量部程度添加してもよい。 The content of each component in 100% by mass of the oil and fat composition of the present invention is generally about 70 to 97% by mass, preferably about 75 to 95% by mass of vegetable oils and fats that are liquid at room temperature, and usually about 1 to about 1 to 75% by mass of high melting point oils and fats. 20% by mass, preferably about 3 to 15% by mass, and polyglycerol unsaturated fatty acid ester and / or propylene glycol unsaturated fatty acid ester are usually about 0.5 to 15% by mass, preferably about 1 to 10% by mass. Even if about 0.05 to 3 parts by mass of glycerin fatty acid ester or sorbitan fatty acid ester is added to 100 parts by mass of the oil / fat composition as a high-melting point oil / fat crystallization regulator in the oil / fat composition of the present invention. Good.
本発明の油脂組成物の製造方法は特に制限されず、自体公知の方法を用いることができる。以下に、好ましい油脂組成物の製造方法を例示する。例えば、攪拌機、加熱用のジャケット、邪魔板などを備えた通常の攪拌・混合槽に、3つの必須成分である(イ)常温で液状の植物油脂、(ロ)高融点油脂、および(ハ)ポリグリセリン不飽和脂肪酸エステルおよび/またはプロピレングリコール不飽和脂肪酸エステルを入れて混合し、約65〜90℃程度に加熱し溶解する。攪拌機に装備する攪拌翼の形状はプロペラ型、かい十字型、フラットタービン型、ディスクタービン型またはいかり型のいずれでも良いが、好ましくはプロペラ型またはフラットタービン型である。 The production method of the oil and fat composition of the present invention is not particularly limited, and a method known per se can be used. Below, the manufacturing method of a preferable oil-fat composition is illustrated. For example, in a normal stirring / mixing tank equipped with a stirrer, a heating jacket, a baffle plate, etc., there are three essential components (a) vegetable oil and fat that are liquid at room temperature, (b) high melting point oil and fat, and (c) Polyglycerin unsaturated fatty acid ester and / or propylene glycol unsaturated fatty acid ester are mixed and heated to about 65 to 90 ° C. to dissolve. The shape of the stirring blades equipped in the stirrer may be any of a propeller type, a cross shape, a flat turbine type, a disc turbine type, or an anchor type, but is preferably a propeller type or a flat turbine type.
次に、得られた溶液を攪拌しながら急冷し、スラリー状の油脂組成物を得る。前記溶液の冷却は、前記加熱用のジャケットに水または冷媒を通すことにより行われてもよいが、工業的には、攪拌・混合槽より溶液を抜き出し、ボテーター(ケメトロン社)、オンレーター(桜製作所社)またはコンサーム(アルファ・ラバル社)などの掻きとり式の急冷混捏装置を用いて行われるのが好ましい。 Next, the obtained solution is rapidly cooled with stirring to obtain a slurry-like oil and fat composition. The solution may be cooled by passing water or a refrigerant through the heating jacket, but industrially, the solution is extracted from a stirring / mixing tank, and a botator (Chemtron Co.), an onrator (Sakura) It is preferable to use a scraping-type quenching and kneading apparatus such as a manufacturing company) or a concerm (Alfa Laval).
得られた油脂組成物は、更にテンパリング処理されるのが好ましい。テンパリングの温度は、配合した高融点油脂の種類により異なり一様ではないが、通常組成物の上昇融点より約5〜10℃低い温度が好ましい。テンパリングの時間は、通常約1〜10日間、好ましくは約2〜3日間である。テンパリング処理により組成物中の高融点油脂の結晶は安定なβ−プライム型に変化し、微細結晶となり得る。油脂結晶の大きさは、通常、光学顕微鏡を用いて測定される。本発明の油脂組成物中における高融点油脂の結晶の大きさは、結晶の平均長が通常約100μm以下、好ましくは約1〜50μmである。 The obtained oil and fat composition is preferably further tempered. The temperature of tempering varies depending on the type of the high melting point oil / fat blended and is not uniform, but is usually preferably about 5-10 ° C. lower than the rising melting point of the composition. The tempering time is usually about 1 to 10 days, preferably about 2 to 3 days. Due to the tempering treatment, the crystals of the high melting point oil or fat in the composition can be changed into a stable β-prime type and become fine crystals. The size of the fat and oil crystals is usually measured using an optical microscope. As for the size of the high melting point fat and oil crystals in the oil and fat composition of the present invention, the average length of the crystals is usually about 100 μm or less, preferably about 1 to 50 μm.
本発明の油脂組成物の粘度は、通常約100〜6000ミリパスカル秒、好ましくは約200〜3000ミリパスカル秒である。粘度が100ミリパスカル秒未満では、油脂が春巻の皮の内部にまで過度に浸透し、皮の表面に薄い油脂層が形成されない恐れがある。一方、6000ミリパスカル秒を越えると刷毛塗りが困難となり、また噴霧器を用いた作業も不能となる恐れがある。 The viscosity of the oil and fat composition of the present invention is usually about 100 to 6000 millipascal seconds, preferably about 200 to 3000 millipascal seconds. If the viscosity is less than 100 millipascal seconds, the oil or fat may excessively penetrate into the spring roll skin and a thin oil or fat layer may not be formed on the skin surface. On the other hand, if it exceeds 6000 millipascal seconds, it is difficult to apply the brush, and there is a possibility that the operation using the sprayer becomes impossible.
上記の粘度は、第7版食品添加物公定書記載「28. 粘度測定法」の「第2法 回転粘度計法」に基づいて測定される。具体的な測定方法および操作条件を以下に示す。なおローターおよび回転数は想定される粘度に応じて適宜選択される。
[粘度測定方法]
試料を入れた容器中にローターとガードを静かに入れ、試料の液面をローターの液浸マークに一致させる。スイッチを入れてから60秒経過後の指針の示す目盛を読み取り、この指示値に、使用したローターの種類および回転数によって定まる換算乗数を乗じて、試料の粘度を算出する。
[操作条件]
測定装置:ブルックフィールド型粘度計
ローター:2号または3号
回転数 :60、30、12または6回転/分
測定温度:25℃
The above viscosity is measured based on “Second Method Rotational Viscometer Method” in “28. Viscosity Measurement Method” described in the 7th edition Food Additives Official Specification. Specific measurement methods and operating conditions are shown below. The rotor and the number of rotations are appropriately selected according to the assumed viscosity.
[Viscosity measurement method]
Gently place the rotor and guard into the container containing the sample, and align the liquid level of the sample with the immersion mark on the rotor. The scale indicated by the pointer 60 seconds after the switch is turned on is read, and the viscosity of the sample is calculated by multiplying this indicated value by a conversion multiplier determined by the type of rotor used and the number of rotations.
[Operation conditions]
Measuring device: Brookfield viscometer Rotor: No. 2 or 3 Number of revolutions: 60, 30, 12 or 6 revolutions / minute Measuring temperature: 25 ° C.
本発明の油脂組成物を塗布または噴霧する春巻の皮に特に制限はなく、自体公知の方法に準じて作られた春巻の皮を用いることができる。例えば、ミキサーに穀粉、食塩水を加えて混練りして生地を得る。該穀粉としては、小麦粉、米粉、コーンスターチなどが挙げられ、通常小麦粉単独で、所望により小麦粉に米粉、コーンスターチなどを適宜配合して用いられる。該生地を薄く伸ばして焼成するには、通常春巻皮成形機(大英技研社製)が用いられる。該機械はホッパーにペースト状の生地を投入することにより、約100〜200℃に温度制御された加熱ドラムを経て、連続的に帯状の薄皮が焼成されてできてくる機械であり、これを任意の長さに切断することにより、均一な厚さの春巻の皮が得られる。 There is no particular limitation on the spring roll skin to which the oil or fat composition of the present invention is applied or sprayed, and spring roll skin made according to a method known per se can be used. For example, flour and saline are added to a mixer and kneaded to obtain a dough. Examples of the flour include wheat flour, rice flour, corn starch and the like. Usually, wheat flour alone is used, and rice flour, corn starch and the like are appropriately blended with wheat flour as desired. To roll the dough thinly and fire it, a spring roll forming machine (manufactured by Daiei Giken Co., Ltd.) is usually used. This machine is a machine in which a strip-shaped thin skin is continuously fired by putting a paste-like dough into a hopper and passing through a heating drum whose temperature is controlled at about 100 to 200 ° C. A spring roll with a uniform thickness can be obtained by cutting to a length of.
本発明の油脂組成物は、スラリー状のまま、通常春巻の皮の片側で、具材が巻き込まれる内側に塗布または噴霧されるのが好ましい。春巻の皮に塗布または噴霧される油脂組成物の量は、春巻の皮一枚(約16cm×16cm〜20cm×20cm)当たり約1〜2gであるのが好ましい。春巻の皮に塗布または噴霧する方法に特に制限はなく、自体公知の方法で行ってよい。 The oil and fat composition of the present invention is preferably applied or sprayed in the form of a slurry, usually on one side of the spring roll skin, inside the ingredients. The amount of the oil or fat composition applied or sprayed onto the spring roll skin is preferably about 1 to 2 g per spring roll skin (about 16 cm × 16 cm to 20 cm × 20 cm). There is no particular limitation on the method of applying or spraying the spring roll skin, and it may be carried out by a method known per se.
春巻の具材としては特に制限はなく、通常用いられる肉類、野菜類などを用いればよく、例えば、豚肉、むきえび、白菜、タケノコ、干しシイタケ、長ネギ、生姜などが挙げられる。春巻の具の調理方法は常法に準じてよく、例えば豚肉、むきえび、白菜、長ネギなどを細切りにして炒め、タケノコ、戻しシイタケ、生姜、調味料(例えば、中華スープ、日本酒、醤油、砂糖、食塩、オイスターソース、XO醤、胡椒、ゴマ油など)などを入れて焦げないように少し煮込み、水溶き片栗粉でトロミをつけてバットに移し、冷ますことにより春巻の具が得られる。具が冷めたら、前記春巻の皮に具を約20〜40g乗せて巻き、約160〜190℃の食用油脂で約2〜5分間揚げることにより、揚げ春巻が得られる。 There are no particular limitations on the ingredients for spring rolls, and it is sufficient to use commonly used meats, vegetables, and the like. Examples include pork, peeled shrimp, Chinese cabbage, bamboo shoots, dried shiitake mushrooms, long onions, and ginger. Spring rolls can be cooked in accordance with conventional methods, for example, pork, mung shrimp, Chinese cabbage, green onion, etc. Add sugar, salt, oyster sauce, XO sauce, pepper, sesame oil, etc.) and boil it a little to avoid scorching, transfer it to a bat with water-soluble starch powder, and cool it to obtain a spring roll. When the ingredients have cooled, the spring rolls are wrapped with about 20 to 40 g of the spring rolls and fried with edible oils and fats at about 160 to 190 ° C. for about 2 to 5 minutes to obtain fried spring rolls.
上記揚げ春巻を凍結することにより、好ましくは急速凍結することにより冷凍春巻が得られる。急速凍結とは、例えば、食品の品温が最大氷結晶生成帯である−1〜−5℃を通過するために費やされる時間が30分以内、あるいは食品の氷結前線が表面から内部へ進む速度(凍結界面前進速度)vが、v=5〜20cm/hの冷却速度で凍結させることを意味し、その具体的な方法としては、気体接触式凍結法(エアーブラスト凍結法)、固体接触式凍結法、液化ガス噴霧式凍結法および液体浸漬式凍結法などが挙げられる。得られた冷凍春巻は通常約−18℃以下に保存されるのが好ましい。 A frozen spring roll is obtained by freezing the fried spring roll, preferably by freezing it rapidly. Rapid freezing is, for example, the time spent for the food temperature to pass through the maximum ice crystal formation zone of -1 to -5 ° C within 30 minutes, or the speed at which the freezing front of the food advances from the surface to the inside. (Freezing interface advance speed) v means freezing at a cooling rate of v = 5 to 20 cm / h, and specific methods include gas contact freezing method (air blast freezing method), solid contact type A freezing method, a liquefied gas spray freezing method, a liquid immersion freezing method, etc. are mentioned. It is preferable that the obtained frozen spring roll is usually stored at about −18 ° C. or lower.
上記冷凍春巻は喫食時に電子レンジで再加熱される。加熱条件は冷凍春巻の大きさ、電子レンジの高周波出力により異なるが、例えば家庭用の電子レンジ(出力:500W)にて冷凍春巻1個(約50g)を加熱する時間は、約40〜60秒間であるのが好ましい。 The frozen spring roll is reheated in a microwave oven when eating. The heating conditions vary depending on the size of the frozen spring roll and the high-frequency output of the microwave oven. For example, the time for heating one frozen spring roll (about 50 g) in a household microwave oven (output: 500 W) is about 40 to Preferably it is 60 seconds.
以下に本発明を実施例および試験例に基づいて、より具体的に説明するが、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described more specifically based on examples and test examples, but the present invention is not limited to these examples.
2L容ステンレスビーカーになたね油(吉原製油社製;上記した常温で液状の植物油脂、以下同じ)880g、なたね極度硬化油(横関油脂工業社製;上記した高融点油脂、以下同じ)50g、ジグリセリンモノオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製,モノエステル体含量約80質量%)70gを入れ、約80℃に加熱し、溶解する。次に、溶解液をマーガリンプロセサー(研究開発用;パワーポイント・インターナショナル社製)にて20℃まで急冷し、得られたスラリー状混合物を25℃で2日間テンパリングし、油脂組成物(実施品1)を得た。 2L stainless beaker rapeseed oil (manufactured by Yoshiwara Seisakusho; vegetable oil and fat which is liquid at room temperature as described above) 880 g, rapeseed extremely hardened oil (manufactured by Yokoseki Oil & Fat Co., Ltd .; high melting point oil and fat as described above) 50 g 70 g of glycerin monooleate (trade name: Poem DO-100V; manufactured by Riken Vitamin Co., Ltd., monoester content: about 80% by mass) is added and heated to about 80 ° C. to dissolve. Next, the solution is rapidly cooled to 20 ° C. with a margarine processor (for research and development; manufactured by Powerpoint International Co., Ltd.), and the resulting slurry mixture is tempered at 25 ° C. for 2 days. Got.
2L容ステンレスビーカーになたね油(吉原製油社製)880g、なたね極度硬化油(横関油脂工業社製)50g、プロピレングリコールモノオレイン酸エステル(商品名:リケマールPO−100;理研ビタミン社製,モノエステル体含量90質量%以上)70gを入れ、約80℃に加熱し、溶解する。次に、溶解液を実施例1と同様に処理し、油脂組成物(実施品2)を得た。 2L stainless beaker, rapeseed oil (Yoshihara Seisakusho Co., Ltd.) 880 g, rapeseed extremely hardened oil (Yokoseki Yushi Kogyo Co., Ltd.) 50 g, propylene glycol monooleate (trade name: Riquemar PO-100; Riken Vitamin Co., monoester) 70g) (body content 90% by mass or more) is added, heated to about 80 ° C and dissolved. Next, the solution was treated in the same manner as in Example 1 to obtain an oil / fat composition (Example Product 2).
2L容ステンレスビーカーになたね油(吉原製油社製)900g、なたね極度硬化油(横関油脂工業社製)50g、ジグリセリンモノオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製,モノエステル体含量約80質量%)30g、プロピレングリコールモノオレイン酸エステル(商品名:リケマールPO−100;理研ビタミン社製,モノエステル体含量90質量%以上)20gを入れ、約80℃に加熱し、溶解する。次に、溶解液を実施例1と同様に処理し、油脂組成物(実施品3)を得た。 2L stainless beaker, rapeseed oil (Yoshihara Seisakusho) 900g, rapeseed extremely hardened oil (Yokoseki Yushi Kogyo Co., Ltd.) 50g, diglycerin monooleate (trade name: Poem DO-100V; manufactured by Riken Vitamin Co., monoester 30 g of body content of about 80% by mass) and 20 g of propylene glycol monooleate (trade name: Riquemar PO-100; manufactured by Riken Vitamin Co., Ltd., monoester content of 90% by mass or more) are heated to about 80 ° C. and dissolved. To do. Next, the solution was treated in the same manner as in Example 1 to obtain an oil and fat composition (Example Product 3).
2L容ステンレスビーカーになたね油(吉原製油社製)875g、なたね極度硬化油(横関油脂工業社製)90g、ジグリセリンモノオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製,モノエステル体含量約80質量%)20g、プロピレングリコールモノオレイン酸エステル(商品名:リケマールPO−100;理研ビタミン社製,モノエステル体含量90質量%以上)15g、ソルビタントリステアリン酸エステル(商品名:ポエムS−65V;理研ビタミン社製)2gを入れ、約80℃に加熱し、溶解する。次に、溶解液を実施例1と同様に処理し、油脂組成物(実施品4)を得た。 2L stainless beaker 875g rapeseed oil (produced by Yoshiwara Oil Co., Ltd.), rapeseed extremely hardened oil (produced by Yokoseki Oil & Fat Co., Ltd.) 90g, diglycerin monooleate (trade name: Poem DO-100V; manufactured by Riken Vitamin Co., monoester Body content about 80% by mass) 20 g, propylene glycol monooleate (trade name: Riquemar PO-100; manufactured by Riken Vitamin Co., Ltd., monoester content 90% by mass or more) 15 g, sorbitan tristearate (trade name: Poem) 2 g of S-65V (manufactured by Riken Vitamin Co., Ltd.) is added, heated to about 80 ° C. and dissolved. Next, the solution was treated in the same manner as in Example 1 to obtain an oil and fat composition (Example Product 4).
2L容ステンレスビーカーになたね油(吉原製油社製)845g、なたね極度硬化油(横関油脂工業社製)120g、ジグリセリンモノオレイン酸エステル(商品名:ポエムDO−100V;理研ビタミン社製,モノエステル体含量約80質量%)20g、プロピレングリコールモノオレイン酸エステル(商品名:リケマールPO−100;理研ビタミン社製,モノエステル体含量90質量%以上)15g、ソルビタントリステアリン酸エステル(商品名:ポエムS−65V;理研ビタミン社製)2gを入れ、約80℃に加熱し、溶解する。次に、溶解液を実施例1と同様に処理し、油脂組成物(実施品5)を得た。 2L stainless beaker 845g rapeseed oil (Yoshihara Seisakusho Co., Ltd.) 845g, rapeseed extremely hardened oil (Yokoseki Oil & Fats Co., Ltd.) 120g, diglycerin monooleate (trade name: Poem DO-100V; Riken Vitamin Co., monoester Body content about 80% by mass) 20 g, propylene glycol monooleate (trade name: Riquemar PO-100; manufactured by Riken Vitamin Co., Ltd., monoester content 90% by mass or more) 15 g, sorbitan tristearate (trade name: Poem) 2 g of S-65V (manufactured by Riken Vitamin Co., Ltd.) is added, heated to about 80 ° C. and dissolved. Next, the solution was treated in the same manner as in Example 1 to obtain an oil / fat composition (Example Product 5).
[比較例1]
2L容ステンレスビーカーになたね油(吉原製油社製)900g、なたね極度硬化油(横関油脂工業社製)100gを入れ、約80℃に加熱し、溶解する。次に、溶解液を実施例1と同様に処理し、油脂組成物(比較品1)を得た。
[Comparative Example 1]
In a 2 L stainless beaker, 900 g of rapeseed oil (manufactured by Yoshiwara Seisakusho) and 100 g of rapeseed extremely hardened oil (manufactured by Yokoseki Yushi Kogyo Co., Ltd.) are added, heated to about 80 ° C. and dissolved. Next, the solution was treated in the same manner as in Example 1 to obtain an oil / fat composition (Comparative Product 1).
[比較例2]
2L容ステンレスビーカーになたね油(吉原製油社製)950g、なたね極度硬化油(横関油脂工業社製)30g、ジグリセリンモノステアリン酸エステル(商品名:ポエムDS−100A;理研ビタミン社製,モノエステル体含量約80質量%)10g、プロピレングリコールモノステアリン酸エステル(商品名:リケマールPS−100;理研ビタミン社製,モノエステル体含量90質量%以上)10gを入れ、約80℃に加熱し、溶解する。次に、溶解液を実施例1と同様に処理し、油脂組成物(比較品2)を得た。
[Comparative Example 2]
2L stainless beaker 950g rapeseed oil (Yoshihara Seisakusho Co., Ltd.) 950g, rapeseed extremely hardened oil (Yokoseki Yushi Kogyo Co., Ltd.) 30g, diglycerin monostearate (trade name: Poem DS-100A; manufactured by Riken Vitamin Co., monoester 10 g of propylene glycol monostearate (trade name: Riquemar PS-100; manufactured by Riken Vitamin Co., Ltd., monoester content of 90 mass% or more) is added and heated to about 80 ° C. to dissolve. To do. Next, the solution was treated in the same manner as in Example 1 to obtain an oil and fat composition (Comparative product 2).
[試験例1]
実施例1〜5で得た油脂組成物(実施品1〜5)の粘度と油脂結晶の大きさを測定した。粘度の測定はブルックフィールド型粘度計を用いて行い、結晶の大きさの測定は光学顕微鏡(システム生物顕微鏡BX50;オリンパス社製)を用いて行った。結果を表1に示した。
[Test Example 1]
The viscosity of the oil and fat composition (Examples 1 to 5) obtained in Examples 1 to 5 and the size of the oil and fat crystals were measured. The viscosity was measured using a Brookfield viscometer, and the crystal size was measured using an optical microscope (system biological microscope BX50; manufactured by Olympus). The results are shown in Table 1.
5コート縦型ミキサー(型式:万能混合攪拌機5DMr;品川工業所社製)の中に小麦粉(商品名:花象鏡龍;千葉製粉社製)100質量部を入れ、食塩1質量部および乳化油脂(商品名:スーパーフレンジーM;理研ビタミン社製)1質量部を水道水100質量部に溶解した水溶液を加えて、低速で3分間、続いて高速で10分間攪拌し生地を得た。該生地を5℃で5時間寝かした後、春巻皮成形機(型式:HTR−15;大英技研社製)を用いて約130℃で25秒間焼成し、次に切断し、20cm×20cm、厚さ0.4mmの春巻の皮を得た。
得られた皮の片側(内側)に実施例1〜5で得た油脂組成物(実施品1〜5)および比較例1〜2で得た油脂組成物(比較品1〜2)をそれぞれ皮1枚につき1gずつ塗布し、次に、表2に示した配合に基づいて調理された具約20gを乗せて巻き、約180℃に加熱した調合こめ油(ボーソー油脂社製)中で4分間揚げ、揚げ春巻(試料1〜7)を得た。
In a 5 coat vertical mixer (model: universal mixing stirrer 5DMr; manufactured by Shinagawa Kogyo Co., Ltd.), 100 parts by weight of wheat flour (trade name: Hanazomi Kyoryu; manufactured by Chiba Flour Mills) is added, 1 part by weight of salt and emulsified oil (Product name: Super Frenzy M; manufactured by Riken Vitamin Co., Ltd.) An aqueous solution in which 1 part by mass was dissolved in 100 parts by mass of tap water was added and stirred at low speed for 3 minutes and then at high speed for 10 minutes to obtain a dough. After sleeping the dough at 5 ° C. for 5 hours, it was baked at about 130 ° C. for 25 seconds using a spring roll skin molding machine (model: HTR-15; manufactured by Daiei Giken Co., Ltd.), then cut, 20 cm × 20 cm, A spring roll skin having a thickness of 0.4 mm was obtained.
The oil and fat composition obtained in Examples 1 to 5 (Examples 1 to 5) and the oil and fat composition obtained in Comparative Examples 1 and 2 (Comparative products 1 and 2) are peeled on one side (inside) of the obtained leather Apply 1g per sheet, then roll with about 20g of cooked ingredients based on the formulation shown in Table 2 and heat to about 180 ° C for 4 minutes in blended koji oil (Bosso Yushi Co., Ltd.) Fried and fried spring rolls (samples 1 to 7) were obtained.
[揚げ春巻の評価]
(1)実施例6で得た揚げ春巻(試料1〜7)について、下記表3に示す評価基準に従い、揚げた直後の食感(パリパリ感)を評価した。官能試験は15名のパネラーで行い、結果は15名の評点の平均値として求め、以下の基準に従って記号化した。結果を表4に示した。
○:評点の平均値が2.5以上
△:評点の平均値が1.5以上、2.5未満
×:評点の平均値が1.5未満
(1) About the deep-fried spring roll (samples 1-7) obtained in Example 6, according to the evaluation criteria shown in the following Table 3, the food texture (crispiness) immediately after frying was evaluated. The sensory test was carried out by 15 panelists, and the results were obtained as the average value of the scores of 15 people and were symbolized according to the following criteria. The results are shown in Table 4.
○: Average score value is 2.5 or more Δ: Average score value is 1.5 or more and less than 2.5 ×: Average score value is less than 1.5
(2)実施例6で得た揚げ春巻(試料1〜7)について、前記表3に示す評価基準に従い、室温で6時間保存した後の食感(パリパリ感)を評価した。官能試験は15名のパネラーで行い、結果は15名の評点の平均値として求め、以下の基準に従って記号化した。結果を表4に示した。
○:評点の平均値が2.5以上
△:評点の平均値が1.5以上、2.5未満
×:評点の平均値が1.5未満
(2) About the deep-fried spring roll (samples 1-7) obtained in Example 6, according to the evaluation criteria shown in the said Table 3, the food texture (crispiness) after storing for 6 hours at room temperature was evaluated. The sensory test was carried out by 15 panelists, and the results were obtained as the average value of the scores of 15 people and were symbolized according to the following criteria. The results are shown in Table 4.
○: Average score value is 2.5 or more Δ: Average score value is 1.5 or more and less than 2.5 ×: Average score value is less than 1.5
実施例6で得た揚げ春巻(試料1〜7)を常法により急速凍結し、得られた冷凍春巻(試料8〜14)を−18℃に保存した。
[冷凍春巻の評価]
実施例7で得た冷凍春巻(試料8〜14)を冷凍開始から3日後に取り出し、家庭用電子レンジ(出力500W)で1個当り40秒間加熱し、前記表3に示す評価基準に従い、加熱直後の食感(パリパリ感)を評価した。官能試験は15名のパネラーで行い、結果は15名の評点の平均値として求め、以下の基準に従って記号化した。結果を表5に示した。
○:評点の平均値が2.5以上
△:評点の平均値が1.5以上、2.5未満
×:評点の平均値が1.5未満
The fried spring rolls (samples 1 to 7) obtained in Example 6 were rapidly frozen by a conventional method, and the obtained frozen spring rolls (samples 8 to 14) were stored at -18 ° C.
[Evaluation of frozen spring rolls]
The frozen spring rolls (samples 8 to 14) obtained in Example 7 were taken out 3 days after the start of freezing, heated in a home microwave oven (output 500 W) for 40 seconds, and according to the evaluation criteria shown in Table 3 above. The texture immediately after heating (crispiness) was evaluated. The sensory test was carried out by 15 panelists, and the results were obtained as the average value of the scores of 15 people and were symbolized according to the following criteria. The results are shown in Table 5.
○: Average score value is 2.5 or more Δ: Average score value is 1.5 or more and less than 2.5 ×: Average score value is less than 1.5
Claims (4)
A frozen spring roll obtained by freezing the fried spring roll according to claim 3.
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