JP6815802B2 - Quality improver for prepared foods - Google Patents

Quality improver for prepared foods Download PDF

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JP6815802B2
JP6815802B2 JP2016185011A JP2016185011A JP6815802B2 JP 6815802 B2 JP6815802 B2 JP 6815802B2 JP 2016185011 A JP2016185011 A JP 2016185011A JP 2016185011 A JP2016185011 A JP 2016185011A JP 6815802 B2 JP6815802 B2 JP 6815802B2
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祐輔 中西
祐輔 中西
隆一 吉川
隆一 吉川
秀征 和泉
秀征 和泉
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Riken Vitamin Co Ltd
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本発明は、畜肉類及び/又は魚介類を主成分とする成形品である惣菜食品のジューシー感を改善する惣菜食品用品質改良剤に関する。 The present invention relates to a quality improver for prepared foods, which improves the juiciness of prepared foods, which are molded products mainly composed of livestock meat and / or seafood.

従来、牛肉、豚肉、鶏肉をはじめとする畜肉類、及び魚、海老、貝等をはじめとする魚介類を用いた惣菜食品、例えばハンバーグ、肉だんご、メンチカツ、から揚げ、さつま揚げ、しんじょ、つみれ等は、畜肉類や魚介類がもつ繊維感や食感を有しつつもジューシー感があるものが好まれるが、加熱調理することによって肉汁等が流出し、脂っぽさのあるジューシー感が損なわれるという問題があった。 Conventionally, prepared foods using livestock meat such as beef, pork, chicken, and seafood such as fish, shrimp, shellfish, etc., such as hamburger, meat dango, menchi cutlet, fried chicken, fried chicken, shinjo, tsumire For example, those that have the fibrous and texture of livestock meat and seafood but have a juicy feel are preferred, but when cooked, the meat juice etc. will flow out, giving a greasy juicy feel. There was a problem of being damaged.

惣菜食品の品質を改善する従来技術としては、食用油脂とポリグリセリン縮合リシノレイン酸エステル、澱粉および/または水溶性多糖類を含有する食肉加工用油中水型乳化油脂組成物(特許文献1)、ポリグリセリン脂肪酸エステルの粉末を含有する食肉加工品食感改良剤(特許文献2)、可溶性澱粉と固形脂を含有する畜肉加工用の乳化組成物(特許文献3)、アルギン酸エステルを含有する畜肉および魚肉加工品用の食感改良剤(特許文献4)、カラメルを含有する砂糖を含有し、水に溶解した場合にpH8〜11となる畜肉又は魚肉の軟化剤(特許文献5)等が開示されている。しかし、これらの従来技術では一長一短があり、必ずしも満足できないのが現状である。 Conventional techniques for improving the quality of prepared foods include water-in-water emulsified fat and oil compositions for meat processing containing edible fats and oils, polyglycerin-condensed ricinoleic acid ester, starch and / or water-soluble polysaccharides (Patent Document 1). Processed meat texture improver containing polyglycerin fatty acid ester powder (Patent Document 2), emulsified composition for livestock processing containing soluble starch and solid fat (Patent Document 3), livestock meat containing alginate ester, and Disclosed are a texture improving agent for processed fish meat (Patent Document 4), a softening agent for livestock meat or fish meat (Patent Document 5) containing sugar containing caramel and having a pH of 8 to 11 when dissolved in water. ing. However, these conventional techniques have advantages and disadvantages, and the current situation is that they are not always satisfactory.

特開2005−087070号公報Japanese Unexamined Patent Publication No. 2005-087070 特開2013−183697号公報Japanese Unexamined Patent Publication No. 2013-183697 特開2008−043288号公報Japanese Unexamined Patent Publication No. 2008-043288 特開2002−281942号公報JP-A-2002-281942 特開2013−247896号公報Japanese Unexamined Patent Publication No. 2013-247896

本発明の目的は、畜肉類及び/又は魚介類を主成分とする成形した惣菜食品のジューシー感を改善する惣菜食品用品質改良剤を提供することである。 An object of the present invention is to provide a quality improver for prepared foods, which improves the juiciness of molded prepared foods containing livestock meat and / or seafood as a main component.

本発明者らは、上記課題を解決する為に鋭意研究を重ねた結果、惣菜食品を製造する際に、特定の乳化剤を含有する油脂組成物が、上記課題を解決することを見出した。本発明者らは、これらの知見に基づきさらに研究を重ね、本発明を完成するに至った。
すなわち、本発明は、プロピレングリコール脂肪酸エステル、モノグリセリン脂肪酸エステル、ジグリセリン脂肪酸エステル及び油脂を含有することを特徴とする惣菜食品用品質改良剤、からなっている。
As a result of diligent research to solve the above-mentioned problems, the present inventors have found that an oil / fat composition containing a specific emulsifier solves the above-mentioned problems when producing a prepared food. Based on these findings, the present inventors have further studied and completed the present invention.
That is, the present invention comprises a quality improver for prepared foods, which comprises a propylene glycol fatty acid ester, a monoglycerin fatty acid ester, a diglycerin fatty acid ester, and an oil and fat.

本発明の惣菜食品用品質改良剤は、畜肉類及び/又は魚介類を主成分とする成形した惣菜食品に配合することにより、ジューシー感、具体的には脂っぽさのあるジューシー感を改善するという効果を奏する。 The quality improver for prepared foods of the present invention improves a juicy feeling, specifically, a greasy juicy feeling by blending it with a molded prepared food containing livestock meat and / or seafood as a main component. It has the effect of doing.

本発明で用いられるプロピレングリコール脂肪酸エステルは、プロピレングリコールと脂肪酸とのエステルであり、エステル化反応、エステル交換反応等自体公知の方法で製造される。該エステルはモノエステル体であってもジエステル体であってもよいし、あるいはそれらの混合物であってもよい。好ましくはモノエステルであり、混合物であればモノエステルを約90%以上含むものがよい。 The propylene glycol fatty acid ester used in the present invention is an ester of propylene glycol and a fatty acid, and is produced by a method known per se, such as an esterification reaction and a transesterification reaction. The ester may be a monoester, a diester, or a mixture thereof. It is preferably a monoester, and if it is a mixture, it preferably contains about 90% or more of the monoester.

プロピレングリコール脂肪酸エステルの原料として用いられる脂肪酸は、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はないが、例えば、炭素数8〜24の飽和脂肪酸(例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、リグノセリン酸等)、又は炭素数8〜24の不飽和脂肪酸(例えば、パルミトレイン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸、エルカ酸等)が挙げられ、好ましくは炭素数16〜18の飽和脂肪酸(例えば、パルミチン酸、ステアリン酸等)である。尚これらの脂肪酸は、1種又は2種以上の脂肪酸の混合物であってもよい。 The fatty acid used as a raw material for the propylene glycol fatty acid ester is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and for example, saturated fatty acids having 8 to 24 carbon atoms (for example, capric acid, capric acid, etc.). Lauric acid, myristic acid, palmitic acid, stearic acid, bechenic acid, lignoceric acid, etc., or unsaturated fatty acids with 8 to 24 carbon atoms (eg, palmitic acid, oleic acid, ellaic acid, linoleic acid, linolenic acid, erucic acid) Etc.), preferably saturated fatty acids having 16 to 18 carbon atoms (for example, palmitic acid, stearic acid, etc.). These fatty acids may be one or a mixture of two or more fatty acids.

プロピレングリコール脂肪酸エステルとしては、例えば、リケマールPS−100(製品名;プロピレングリコールステアリン酸エステル;モノエステル含有量90%以上;理研ビタミン社製)、リケマールPP−100(製品名;プロピレングリコールパルミチン酸エステル;モノエステル含有量90%以上;理研ビタミン社製)、リケマールPB−100(商品名;プロピレングリコールベヘニン酸エステル;モノエステル含有量90%以上;理研ビタミン社製)等が商業的に製造及び販売されており、本発明ではこれらを用いることができる。 Examples of the propylene glycol fatty acid ester include Riquemar PS-100 (product name; propylene glycol stearate ester; monoester content of 90% or more; manufactured by RIKEN Vitamin Co., Ltd.) and Rikemar PP-100 (product name; propylene glycol palmitate). Commercially manufactured monoester content of 90% or more; Riken Vitamin Co., Ltd.), Rikemar PB-100 (trade name; propylene glycol behenic acid ester; monoester content of 90% or more; manufactured by Riken Vitamin Co., Ltd.), etc. And sold, and these can be used in the present invention.

本発明で用いられるモノグリセリン脂肪酸エステルは、グリセリンと脂肪酸とのエステルであり、エステル化反応、エステル交換反応等自体公知の方法で製造できる。該エステルはモノエステル体(モノグリセリド)、ジエステル体(ジグリセリド)のいずれであってもよく、あるいはそれらの混合物であってもよい。好ましくはモノエステル体であり、混合物であれば好ましくはモノエステルを約50%以上含、より好ましくは約70%以上含むものがよい。 The monoglycerin fatty acid ester used in the present invention is an ester of glycerin and a fatty acid, and can be produced by a method known per se such as an esterification reaction and a transesterification reaction. The ester may be either a monoester (monoglyceride) or a diester (diglyceride), or a mixture thereof. It is preferably a monoester, and if it is a mixture, it preferably contains about 50% or more of monoester, and more preferably about 70% or more.

モノグリセリン脂肪酸エステルの原料として用いられる脂肪酸は、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はないが、例えば、炭素数8〜24の飽和脂肪酸(例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、リグノセリン酸等)、又は炭素数8〜24の不飽和脂肪酸(例えば、パルミトレイン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸、エルカ酸等)が挙げられ、好ましくは炭素数16〜18の飽和脂肪酸(例えば、パルミチン酸、ステアリン酸等)である。尚これらの脂肪酸は、1種又は2種以上の脂肪酸の混合物であってもよい。 The fatty acid used as a raw material for the monoglycerin fatty acid ester is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and is, for example, a saturated fatty acid having 8 to 24 carbon atoms (for example, capric acid, capric acid, etc.). Lauric acid, myristic acid, palmitic acid, stearic acid, bechenic acid, lignoseric acid, etc.) or unsaturated fatty acids with 8 to 24 carbon atoms (eg, palmitreic acid, oleic acid, ellaic acid, linoleic acid, linolenic acid, erucic acid) Etc.), preferably saturated fatty acids having 16 to 18 carbon atoms (for example, palmitic acid, stearic acid, etc.). These fatty acids may be one or a mixture of two or more fatty acids.

上記モノグリセリン脂肪酸エステルは、通常、油脂とグリセリンの混合物にアルカリ( 例えば水酸化カリウム、水酸化ナトリウム、炭酸カリウム、炭酸ナトリウム等)を触媒として添加し、窒素又は二酸化炭素等の任意の不活性ガス雰囲気下、例えば、約180〜260℃ の範囲、好ましくは約200〜250℃で約0.5〜5時間、好ましくは、約1〜3時間加熱してエステル交換反応するか、又は脂肪酸とグリセリンの混合物に酸又はアルカリを触媒として添加し、窒素又は二酸化炭素等の任意の不活性ガス雰囲気下で、例えば約180〜260℃ の範囲、好ましくは約200〜250℃で約0.5〜5時間、好ましくは約1〜3時間加熱してエステル化反応を行い、反応終了後触媒を中和し、得られた反応混合物から未反応のグリセリン、ジグリセライド及びトリグリセライドを可及的に除去することにより得ることができる。前記未反応のグリセリン、ジグリセライド及びトリグリセライドを除去する方法としては、例えば減圧蒸留、分子蒸留、カラムクロマトグラフィー又は液液抽出等自体公知の方法が挙げられる。グリセリン、ジグリセライド及びトリグリセライド除去後、所望により脱色、脱臭等の処理を行ってよい。 The monoglycerin fatty acid ester is usually prepared by adding an alkali (for example, potassium hydroxide, sodium hydroxide, potassium carbonate, sodium carbonate, etc.) to a mixture of fat and oil and glycerin as a catalyst, and any inert gas such as nitrogen or carbon dioxide. In an atmosphere, for example, a transesterification reaction by heating in the range of about 180 to 260 ° C., preferably about 200 to 250 ° C. for about 0.5 to 5 hours, preferably about 1 to 3 hours, or fatty acid and glycerin. Acid or alkali is added as a catalyst to the mixture of, and under an atmosphere of an arbitrary inert gas such as nitrogen or carbon dioxide, for example, in the range of about 180 to 260 ° C., preferably about 200 to 250 ° C., about 0.5 to 5 By heating for hours, preferably about 1 to 3 hours, the transesterification reaction is carried out, the catalyst is neutralized after the reaction is completed, and unreacted glycerin, diglyceride and triglyceride are removed as much as possible from the obtained reaction mixture. Obtainable. Examples of the method for removing the unreacted glycerin, diglyceride and triglyceride include methods known per se, such as vacuum distillation, molecular distillation, column chromatography and liquid-liquid extraction. After removing glycerin, diglyceride and triglyceride, treatments such as decolorization and deodorization may be performed if desired.

モノグリセリン脂肪酸エステルとしては、例えば、エマルジーMH(商品名;構成脂肪酸のステアリン酸含有量約85%、モノエステル含有量95%以上;理研ビタミン社製)、エマルジーMS(商品名;構成脂肪酸のステアリン酸含有量約68%、モノエステル含有量95%以上;理研ビタミン社製)、エマルジーP−100(商品名;主構成脂肪酸の炭素数16〜18、モノエステル含有量95%以上;理研ビタミン社製)等が商業的に製造及び販売されており、本発明ではこれらを用いることができる。 Examples of the monoglycerin fatty acid ester include Emargy MH (trade name; stearic acid content of constituent fatty acids of about 85%, monoester content of 95% or more; manufactured by RIKEN Vitamin Co., Ltd.), Emargy MS (trade name; stearic acid of constituent fatty acids). Acid content of about 68%, monoester content of 95% or more; manufactured by RIKEN Vitamin Co., Ltd.), Emulgy P-100 (trade name; main constituent fatty acids having 16 to 18 carbon atoms, monoester content of 95% or more; RIKEN Vitamin Co., Ltd. Et al. Are commercially manufactured and sold, and these can be used in the present invention.

本発明で用いられるジグリセリン脂肪酸エステルとは、ジグリセリンと脂肪酸とのエステル化反応生成物であり、エステル化反応等自体公知の方法で製造される。 The diglycerin fatty acid ester used in the present invention is an esterification reaction product of diglycerin and a fatty acid, and is produced by a method known per se such as an esterification reaction.

ジグリセリン脂肪酸エステルを構成するジグリセリンとしては、通常グリセリンに少量の酸又はアルカリを触媒として添加し、窒素又は二酸化炭素等の任意の不活性ガス雰囲気下で、例えば180℃以上の温度で加熱し、重縮合反応させて得られるグリセリンの平均重合度が1.5〜2.4、好ましくは平均重合度が2.0のジグリセリン混合物が挙げられる。また、ジグリセリンはグリシドール又はエピクロルヒドリン等を原料として得られるものであっても良い。反応終了後、必要であれば中和、脱塩、脱色等の処理を行っても良い。 As the diglycerin constituting the diglycerin fatty acid ester, a small amount of acid or alkali is usually added to glycerin as a catalyst and heated in an atmosphere of an arbitrary inert gas such as nitrogen or carbon dioxide at a temperature of, for example, 180 ° C. or higher. , A diglycerin mixture having an average degree of polymerization of 1.5 to 2.4, preferably 2.0, of glycerin obtained by a polycondensation reaction can be mentioned. Further, the diglycerin may be obtained from glycidol, epichlorohydrin or the like as a raw material. After completion of the reaction, if necessary, treatments such as neutralization, desalting, and decolorization may be performed.

本発明においては、上記ジグリセリン混合物を、例えば蒸留又はカラムクロマトグラフィー等自体公知の方法を用いて精製し、グリセリン2分子からなるジグリセリンを50質量%以上、好ましくは85質量%以上に高濃度化した高純度ジグリセリンが、好ましく用いられる。 In the present invention, the above diglycerin mixture is purified by a method known per se, for example, distillation or column chromatography, and the concentration of diglycerin composed of two glycerin molecules is as high as 50% by mass or more, preferably 85% by mass or more. High-purity diglycerin is preferably used.

ジグリセリン脂肪酸エステルを構成する脂肪酸としては、食用可能な動植物油脂を起源とする脂肪酸であれば特に制限はないが、例えば、炭素数8〜24の飽和脂肪酸(例えば、カプリル酸、カプリン酸、ラウリン酸、ミリスチン酸、パルミチン酸、ステアリン酸、ベヘン酸、リグノセリン酸等)、又は炭素数8〜24の不飽和脂肪酸(例えば、パルミトレイン酸、オレイン酸、エライジン酸、リノール酸、リノレン酸、エルカ酸等)が挙げられ、好ましくは炭素数16〜18の飽和脂肪酸(例えば、パルミチン酸、ステアリン酸等)、炭素数16〜18の不飽和脂肪酸(例えば、オレイン酸等)である。尚これらの脂肪酸は、1種又は2種以上の脂肪酸の混合物であってもよい。 The fatty acid constituting the diglycerin fatty acid ester is not particularly limited as long as it is a fatty acid derived from edible animal and vegetable fats and oils, and is, for example, a saturated fatty acid having 8 to 24 carbon atoms (for example, capric acid, capric acid, laurin). Acids, myristic acid, palmitic acid, stearic acid, behenic acid, lignoseric acid, etc., or unsaturated fatty acids with 8 to 24 carbon atoms (eg, palmitreic acid, oleic acid, ellagic acid, linoleic acid, linolenic acid, erucic acid, etc.) ), And preferably saturated fatty acids having 16 to 18 carbon atoms (for example, palmitic acid, stearic acid, etc.) and unsaturated fatty acids having 16 to 18 carbon atoms (for example, oleic acid, etc.). These fatty acids may be one or a mixture of two or more fatty acids.

本発明で用いられるジグリセリン脂肪酸エステルの好ましい製造方法の概略は次のとおりである。例えば、撹拌機、加熱用のジャケット、邪魔板等を備えた通常の反応容器に、ジグリセリンと脂肪酸とをモル比で約1:0.8〜1:1.6、好ましくは約1:1で仕込み、触媒として水酸化ナトリウムを加えて撹拌混合し、窒素ガス雰囲気下で、エステル化反応により生成する水を系外に除去しながら、所定温度で加熱する。反応温度は通常、180〜260℃の範囲、好ましくは200〜250℃の範囲である。また、反応圧力条件は減圧下又は常圧下で、反応時間は0.5〜15時間、好ましくは1〜3時間である。反応の終点は、通常反応混合物の酸価を測定し、酸価12以下を目安に決められる。
得られた反応液は、未反応の脂肪酸、未反応のジグリセリン、ジグリセリンモノ脂肪酸エステル、ジグリセリンジ脂肪酸エステル、ジグリセリントリ脂肪酸エステル、ジグリセリンテトラ脂肪酸エステル等を含む混合物である。反応終了後、得られた反応液を120℃以上180℃未満、好ましくは130〜150℃に冷却し、次いで酸を加えて触媒を中和し、好ましくは15分間〜1時間放置し、未反応のジグリセリンを含むポリオールが下層に分離した場合はそれを除去し、ジグリセリン脂肪酸エステルが得られる。
The outline of the preferable production method of the diglycerin fatty acid ester used in the present invention is as follows. For example, in a normal reaction vessel equipped with a stirrer, a jacket for heating, a baffle plate, etc., diglycerin and fatty acid are mixed in a molar ratio of about 1: 0.8 to 1: 1.6, preferably about 1: 1. Sodium hydroxide is added as a catalyst, and the mixture is stirred and mixed. In a nitrogen gas atmosphere, water produced by the esterification reaction is removed from the system and heated at a predetermined temperature. The reaction temperature is usually in the range of 180-260 ° C, preferably in the range of 200-250 ° C. The reaction pressure condition is reduced pressure or normal pressure, and the reaction time is 0.5 to 15 hours, preferably 1 to 3 hours. The end point of the reaction is usually determined by measuring the acid value of the reaction mixture and using an acid value of 12 or less as a guide.
The obtained reaction solution is a mixture containing unreacted fatty acid, unreacted diglycerin, diglycerin monofatty acid ester, diglycerin difatty acid ester, diglycerin trifatty acid ester, diglycerin tetra fatty acid ester and the like. After completion of the reaction, the obtained reaction solution is cooled to 120 ° C. or higher and lower than 180 ° C., preferably 130 to 150 ° C., and then an acid is added to neutralize the catalyst, preferably left for 15 minutes to 1 hour, and unreacted. If the polyol containing diglycerin is separated into the lower layer, it is removed to obtain a diglycerin fatty acid ester.

該ジグリセリン脂肪酸エステルは、モノエステル体の含有量が通常30質量%以上50質量%未満のものであるが、所望により、該ジグリセリン脂肪酸エステルを、例えば流下薄膜式分子蒸留装置又は遠心式分子蒸留装置等を用いて分子蒸留するか、又はカラムクロマトグラフィー若しくは液液抽出等自体公知の方法を用いて精製することにより、全体に対してモノエステル体を50質量%以上、好ましくは70質量%以上含むジグリセリン脂肪酸エステルを得ることができる。 The content of the monoester is usually 30% by mass or more and less than 50% by mass in the diglycerin fatty acid ester, but if desired, the diglycerin fatty acid ester can be subjected to, for example, a flow-down thin-film molecular distillation apparatus or a centrifugal molecule. By molecular distillation using a distillation apparatus or the like, or by purifying using a method known per se such as column chromatography or liquid-liquid extraction, the monoester is 50% by mass or more, preferably 70% by mass, based on the whole. A diglycerin fatty acid ester containing the above can be obtained.

ジグリセリン脂肪酸エステルとしては、例えば、ポエムJ−2081V(商品名;ジグリセリンステアリン酸エステル、モノエステル含有量約35%;理研ビタミン社製)、ポエムDO−100V(商品名;ジグリセリンオレイン酸エステル、モノエステル含有量80%以上;理研ビタミン社製)、ポエムDS−100A(商品名;ジグリセリンステアリン酸エステル、モノエステル含有量約80%;理研ビタミン社製)、ポエムDP−100A(商品名;ジグリセリンパルミチン酸エステル;モノエステル含有量80%以上;理研ビタミン社製)等が商業的に製造及び販売されており、本発明ではこれを用いることができる。 Examples of the diglycerin fatty acid ester include Poem J-2081V (trade name; diglycerin stearate, monoester content of about 35%; manufactured by RIKEN Vitamin Co., Ltd.), Poem DO-100V (trade name; diglycerin oleate). , Monoester content 80% or more; Riken Vitamin Co., Ltd.), Poem DS-100A (trade name; diglycerin stearate, monoester content about 80%; Riken Vitamin Co., Ltd.), Poem DP-100A (trade name) Diglycerin luminic acid ester; monoester content 80% or more; manufactured by RIKEN Vitamin Co., Ltd.) and the like are commercially manufactured and sold, and this can be used in the present invention.

ここで、本発明で用いられるプロピレングリコール脂肪酸エステル、モノグリセリン脂肪酸エステル及びジグリセリン脂肪酸エステルのモノエステル体の含有量は、下記分析条件にてHPLCを用いて分析することにより求められる。具体的には、プロピレングリコール脂肪酸エステル、モノグリセリン脂肪酸エステル又はジグリセリン脂肪酸エステルを下記HPLC分析条件で分析後、データ処理装置によりクロマトグラム上に記録された被検試料の各成分に対応するピークについて、積分計を用いてピーク面積を測定し、測定されたピーク面積に基づいて、面積百分率としてモノエステル体の含有量を求めることができる。 Here, the content of the monoesters of the propylene glycol fatty acid ester, the monoglycerin fatty acid ester and the diglycerin fatty acid ester used in the present invention can be determined by analyzing using HPLC under the following analytical conditions. Specifically, after analyzing the propylene glycol fatty acid ester, monoglycerin fatty acid ester, or diglycerin fatty acid ester under the following HPLC analysis conditions, the peaks corresponding to each component of the test sample recorded on the chromatogram by the data processing apparatus. , The peak area can be measured using an integrator, and the content of the monoester can be determined as an area percentage based on the measured peak area.

[HPLC分析条件]
装置 高速液体クロマトグラフ(型式:LC−10AS;島津製作所社製)
検出器 RI検出器(型式:RID−6A、島津製作所社製)
カラム GPCカラム(型式:SHODEX KF−802;昭和電工社製)
2本連結
温度 40℃
移動相 THF
流量 1.0mL/min
検液注入量 15μL
[HPLC analysis conditions]
Equipment High Performance Liquid Chromatograph (Model: LC-10AS; manufactured by Shimadzu Corporation)
Detector RI detector (model: RID-6A, manufactured by Shimadzu Corporation)
Column GPC column (Model: SHODEX KF-802; manufactured by Showa Denko KK)
Two connection temperature 40 ℃
Mobile phase THF
Flow rate 1.0 mL / min
Test solution injection volume 15 μL

本発明で用いられる油脂は、食用可能な油脂であれば特に制限はなく、例えば菜種油、サフラワー油、大豆油、ヒマワリ油、コーン油、綿実油、米糠油、椰子油、パーム油、パーム核油、カポック油、落花生油、オリーブ油、ハイオレイック菜種油、ハイオレイックサフラワー油、ハイオレイックコーン油及びハイオレイックヒマワリ油等の植物油脂、牛脂、ラード、魚油及び乳脂等の動物油脂、さらにこれら動植物油脂を分別、水素添加又はエステル交換したもの、並びに中鎖脂肪酸トリグリセリド(MCT)等が挙げられる。好ましくは、常温で液体状の油脂である菜種油、サフラワー油、大豆油、ヒマワリ油又はコーン油等である。 The fats and oils used in the present invention are not particularly limited as long as they are edible fats and oils. For example, rapeseed oil, safflower oil, soybean oil, sunflower oil, corn oil, cottonseed oil, rice bran oil, coconut oil, palm oil, palm kernel oil. , Capoc oil, peanut oil, olive oil, high oleic rapeseed oil, high oleic safflower oil, high oleic corn oil and high oleic sunflower oil and other vegetable oils, beef fat, lard, fish oil and milk fat and other animal oils and plants. Examples thereof include fats and oils separated, hydrogenated or ester-exchanged, and medium-chain fatty acid triglyceride (MCT). Rapeseed oil, safflower oil, soybean oil, sunflower oil, corn oil and the like, which are liquid fats and oils at room temperature, are preferable.

本発明の惣菜食品用品質改良剤100質量%中のプロピレングリコール脂肪酸エステル含量は2.0〜24.0質量%、好ましくは6.0〜18.0質量%、モノグリセリン脂肪酸エステル含量は1.0〜11.0質量%、好ましくは3.0〜9.0質量%、ジグリセリン脂肪酸エステル含量は0.1〜3.0質量%、好ましくは0.5〜1.5質量%、油脂含量は74.9〜84.0質量%、好ましくは78.5〜83.5質量%である。 The content of propylene glycol fatty acid ester in 100% by mass of the quality improver for prepared foods of the present invention is 2.0 to 24.0% by mass, preferably 6.0 to 18.0% by mass, and the content of monoglycerin fatty acid ester is 1. 0 to 11.0% by mass, preferably 3.0 to 9.0% by mass, diglycerin fatty acid ester content of 0.1 to 3.0% by mass, preferably 0.5 to 1.5% by mass, fat content Is 74.9 to 84.0% by mass, preferably 78.5 to 83.5% by mass.

本発明の惣菜食品用品質改良剤には、本発明の目的を阻害しない範囲で他の任意の成分が含まれても良く、例えば、食品用乳化剤(但し、本発明で用いられる食品用乳化剤を除く)、pH調整剤、酸化防止剤等が挙げられる。 The prepared food quality improver of the present invention may contain any other component as long as the object of the present invention is not impaired. For example, a food emulsifier (provided that the food emulsifier used in the present invention is used). Excludes), pH adjusters, antioxidants, etc.

上記食品用乳化剤としては、ソルビタン脂肪酸エステル、ポリグリセリン縮合リシノール酸エステル、ショ糖脂肪酸エステル、レシチン等が挙げられる。ここでレシチンには、分別レシチン、酵素分解レシチン、酵素処理レシチン等が含まれる。 Examples of the food emulsifier include sorbitan fatty acid ester, polyglycerin condensed ricinoleic acid ester, sucrose fatty acid ester, and lecithin. Here, lecithin includes fractionated lecithin, enzymatically decomposed lecithin, enzyme-treated lecithin and the like.

本発明の惣菜食品用品質改良剤は、実質的に水分を含まず、油脂、プロピレングリコール脂肪酸エステル、モノグリセリン脂肪酸エステル及びジグリセリン脂肪酸エステル等を配合した油脂組成物である。該品質改良剤の形態に特に制限はないが、惣菜食品に添加することを考慮した場合、常温で流動性を有することが好ましい。
ここで、前記「実質的に水分を含まず」とは、水を全く含有しない、あるいは水が十分に少ないことを意味する。より具体的には、惣菜食品用品質改良剤中の水分が、通常1.0質量%以下、より好ましくは0.5質量%以下であることを意味する。
The quality improver for prepared foods of the present invention is a fat and oil composition containing fats and oils, propylene glycol fatty acid ester, monoglycerin fatty acid ester, diglycerin fatty acid ester and the like, which is substantially free of water. The form of the quality improving agent is not particularly limited, but it is preferable that the quality improving agent has fluidity at room temperature when it is considered to be added to a prepared food.
Here, the above-mentioned "substantially water-free" means that the water is not contained at all or the amount of water is sufficiently small. More specifically, it means that the water content in the quality improver for prepared foods is usually 1.0% by mass or less, more preferably 0.5% by mass or less.

本発明の惣菜食品用品質改良剤の製造方法は特に限定されず、自体公知の方法を用いることができる。以下に惣菜食品用品質改良剤の製造方法を例示する。原材料を70〜80℃で混合溶解し、得られた油脂組成物を攪拌しながら急冷し、その後、必要であればテンパリング操作を行い、本発明の惣菜食品用品質改良剤を得る。 The method for producing the quality improver for prepared foods of the present invention is not particularly limited, and a method known per se can be used. The manufacturing method of the quality improver for prepared foods is illustrated below. The raw materials are mixed and dissolved at 70 to 80 ° C., the obtained oil and fat composition is rapidly cooled with stirring, and then a tempering operation is performed if necessary to obtain the quality improver for prepared foods of the present invention.

本発明の惣菜食品用品質改良剤は、惣菜食品の中だねや具(生地)に添加して用いることができる。ここで惣菜食品とは、畜肉及び/又は魚介類(すり身を含む)を主成分とする成形品、又は畜肉及び/又は魚介類(すり身を含む)と副原料とを含有する成形品、あるいは前記した成形品を皮や衣で包んだものであり、例えばハンバーグ、肉だんご、さつま揚げ、つみれ、しんじょ等や、餃子、焼売、ワンタン、春巻き、中華まん、ピロシキ、コロッケ、メンチカツ、から揚げ等が挙げられる。 The quality improver for prepared foods of the present invention can be used by adding it to a side dish or an ingredient (dough) in a prepared food. Here, the prepared food is a molded product containing livestock meat and / or seafood (including ground meat) as a main component, or a molded product containing livestock meat and / or seafood (including ground meat) and an auxiliary raw material, or the above-mentioned. The molded product is wrapped in leather or clothing, such as hamburger, meat dumplings, fried fish balls, fish balls, shinjo, dumplings, grilled food, wontons, spring rolls, Chinese buns, piroshiki, croquettes, fried chicken, etc. Be done.

上記に用いられる畜肉類としては、例えば牛、豚、羊、鶏、七面鳥、カモ、ガチョウ等が挙げられ、魚介類(すり身を含む)としては、例えばタラ、イトヨリダイ、エソ、ヒラメ、アジ、サケ、海老、帆立等が挙げられる。 Examples of the livestock meat used above include cows, pigs, sheep, chickens, turkeys, ducks, geese and the like, and examples of seafood (including surimi) include cod, Itoyoridai, lizardfish, flounder, hydrangea and salmon. , Shrimp, salmon, etc.

本発明の惣菜食品用品質改良剤の惣菜食品への添加方法は、特に限定されず、例えば、畜肉及び/又は魚介類(すり身を含む)、又は畜肉及び/又は魚介類(すり身を含む)と副原料に添加することができる。惣菜食品用品質改良剤と畜肉及び/又は魚介類(すり身を含む)、又は畜肉及び/又は魚介類(すり身を含む)と副原料は、混合して練合せて用いることが好ましい。
上記副原料としては、惣菜食品用食品に適したものであれば特に制限はなく、例えば、野菜類、パン粉、卵、調味料類等が挙げられる。
The method for adding the quality improver for prepared foods of the present invention to prepared foods is not particularly limited, and for example, with livestock meat and / or seafood (including surimi), or livestock meat and / or seafood (including surimi). It can be added to auxiliary raw materials. It is preferable that the quality improver for prepared foods and livestock meat and / or seafood (including surimi), or livestock meat and / or seafood (including surimi) and auxiliary raw materials are mixed and kneaded.
The auxiliary raw material is not particularly limited as long as it is suitable for prepared foods, and examples thereof include vegetables, bread crumbs, eggs, and seasonings.

本発明の惣菜食品用品質改良剤の畜肉及び/又は魚介類(すり身を含む)、又は畜肉及び/又は魚介類(すり身を含む)と副原料への添加量は、畜肉及び/又は魚介類(すり身を含む)、又は畜肉及び/又は魚介類(すり身を含む)と副原料100質量部に対して0.2〜8.0質量部、好ましくは0.5〜5.0質量部である The amount of the quality improver for prepared foods of the present invention added to livestock meat and / or seafood (including ground meat), or livestock meat and / or seafood (including ground meat) and auxiliary raw materials is the amount of livestock meat and / or seafood (including ground meat). 0.2 to 8.0 parts by mass, preferably 0.5 to 5.0 parts by mass with respect to 100 parts by mass of (including ground meat) or livestock meat and / or seafood (including ground meat) and auxiliary ingredients.

惣菜食品用品質改良剤を添加した畜肉及び/又は魚介類(すり身を含む)、又は畜肉及び/又は魚介類(すり身を含む)と副原料は、練合せて惣菜食品に適した形状に成形し、所望により衣や皮等に包み惣菜食品が得られる。得られた惣菜食品は、そのまま加熱調理をおこなうことができるが、冷蔵保管、冷凍保管した後に加熱調理をおこなうこともできる。 Livestock meat and / or seafood (including surimi) to which a quality improver for prepared foods has been added, or livestock meat and / or seafood (including surimi) and auxiliary ingredients are kneaded and molded into a shape suitable for prepared foods. If desired, a prepared food can be obtained by wrapping it in clothes, skin, or the like. The obtained prepared food can be cooked as it is, but it can also be cooked after being refrigerated or frozen.

以下に本発明を実施例で説明するが、これは本発明を単に説明するだけのものであって、本発明を限定するものではない。 Hereinafter, the present invention will be described with reference to Examples, but this is merely a description of the present invention and does not limit the present invention.

[惣菜食品用品質改良剤の作製]
(1)原材料
プロピレングリコール脂肪酸エステル1(商品名:リケマールPS−100;理研ビタミン社製)
プロピレングリコール脂肪酸エステル2(商品名:リケマールPP−100;理研ビタミン社製)
モノグリセリン脂肪酸エステル(商品名:エマルジーMH;理研ビタミン社製)
ジグリセリン脂肪酸エステル(商品名:ポエムJ−2081V;理研ビタミン社製)
菜種油(商品名:ナタネ白絞油;辻製油社製)
[Production of quality improver for prepared foods]
(1) Raw material Propropylene glycol fatty acid ester 1 (trade name: Rikemar PS-100; manufactured by RIKEN Vitamin Co., Ltd.)
Propropylene glycol fatty acid ester 2 (trade name: Rikemar PP-100; manufactured by RIKEN Vitamin Co., Ltd.)
Monoglycerin fatty acid ester (trade name: Emarji MH; manufactured by RIKEN Vitamin Co., Ltd.)
Diglycerin fatty acid ester (trade name: Poem J-2081V; manufactured by RIKEN Vitamin Co., Ltd.)
Rapeseed oil (trade name: rapeseed white squeezed oil; manufactured by Tsuji Oil Co., Ltd.)

(2)配合
上記原材料を用いて作製した惣菜食品用品質改良剤(実施例品1〜3、比較例品1〜4、参考例品1〜4)の配合を表1に示した。
(2) Formulation Table 1 shows the composition of the quality improvers for prepared foods (Example products 1 to 3, Comparative example products 1 to 4, and Reference example products 1 to 4) prepared using the above raw materials.

Figure 0006815802
Figure 0006815802

(3)作製方法
作製する惣菜食品用品質改良剤の総量が各200gとなるように、表1に示した配合に基づいて各原材料を500mL容のステンレス製ジョッキに入れ、スパチュラで攪拌しながら約80℃に加熱して溶解した。得られた溶解液を約10℃の恒温水槽に漬け、約30℃まで冷却し、液状又はスラリー状混合物を得た。得られた液状又はスラリー状混合物を約40℃の恒温水槽に漬け、スリーワンモータ(型式:BL600;新東科学社製)で500rpmで攪拌しながら約1時間テンパリングした。テンパリング終了後室温まで放冷し、惣菜食品用品質改良剤(実施例品1〜3、比較例品1〜4、参考例品1〜3)を得た。参考例品4は、特に操作することなく菜種油を使用した。
(3) Preparation method Each raw material is placed in a 500 mL stainless steel mug based on the formulation shown in Table 1 so that the total amount of the quality improver for prepared foods to be prepared is 200 g, and the mixture is stirred with a spatula. It was melted by heating to 80 ° C. The obtained solution was immersed in a constant temperature water bath at about 10 ° C. and cooled to about 30 ° C. to obtain a liquid or slurry mixture. The obtained liquid or slurry-like mixture was immersed in a constant temperature water tank at about 40 ° C., and tempered for about 1 hour with stirring at 500 rpm with a three-one motor (model: BL600; manufactured by Shinto Kagaku Co., Ltd.). After the tempering was completed, the mixture was allowed to cool to room temperature to obtain quality improvers for prepared foods (Examples 1-3, Comparative Examples 1-4, Reference Examples 1-3). Reference example product 4 used rapeseed oil without any particular operation.

[惣菜食品用品質改良剤の評価1]
<鶏ソーセージでの評価>
(1)鶏ソーセージの作製
[試験区1〜12]
鶏胸肉(皮を取り除いたもの)300gを、ミートチョッパー(型式:M−22A;なんつね社製)を用いて挽き目3mmでチョッピングし、鶏挽き肉200gを得た。得られた挽き肉を急速冷凍機(型式:233FFB;大和冷機工業社製)を用いて−20℃で30分間保管し、保管後の鶏挽き肉200gを、フードプロセッサー(型式:MK−K48P;パナソニック社製)に加え、30秒間混合し、これに食塩6g、炭酸ナトリウム[商品名:食品添加物 炭酸ナトリウム・粉末;高杉製薬社製]0.6g、ピロリン酸ナトリウム[商品名:食品添加物 ピロリン酸四ナトリウム(無水);太平化学産業社製]0.4gを加え、さらに1分間混合した。最後に表2に記載した量の惣菜食品用品質改良剤(15.00g又は2.85g)、氷80gを加え、該フードプロセッサーを用いて生地の温度が10℃になるまで混合し、練り生地を得た。得られた練り生地を10gの円柱状の大きさに成型し、スチーマーボックス(型式:K−1DX;荒畑製作所社製)で85℃、8分間加熱し、その後−25℃の冷凍庫で1時間冷却し、鶏ソーセージ(試験区1〜12)を得た。
[Evaluation of quality improver for prepared foods 1]
<Evaluation with chicken sausage>
(1) Preparation of chicken sausage [Test groups 1-12]
300 g of chicken breast (without skin) was chopped with a meat chopper (model: M-22A; manufactured by Nantsune Co., Ltd.) with a grain size of 3 mm to obtain 200 g of minced chicken. The obtained ground meat is stored at -20 ° C for 30 minutes using a quick freezer (model: 233FFB; manufactured by Yamato Refrigerator Industry Co., Ltd.), and 200 g of the stored ground chicken meat is stored in a food processor (model: MK-K48P; Panasonic). In addition to (manufactured by), mix for 30 seconds, and add 6 g of salt, sodium carbonate [trade name: food additive sodium carbonate / powder; manufactured by Takasugi Pharmaceutical Co., Ltd.] 0.6 g, sodium pyrophosphate [trade name: food additive pyrophosphate Tetrasodium (anhydrous); manufactured by Taihei Kagaku Sangyo Co., Ltd.] 0.4 g was added, and the mixture was further mixed for 1 minute. Finally, the amounts of the quality improver for prepared foods (15.00 g or 2.85 g) and 80 g of ice shown in Table 2 are added, and the dough is mixed using the food processor until the temperature of the dough reaches 10 ° C. Got The obtained kneaded dough is molded into a columnar size of 10 g, heated in a steamer box (model: K-1DX; manufactured by Arahata Seisakusho) at 85 ° C for 8 minutes, and then cooled in a freezer at -25 ° C for 1 hour. Then, chicken sausages (test plots 1 to 12) were obtained.

Figure 0006815802
Figure 0006815802

(2)鶏ソーセージの評価
得られた鶏ソーセージを自然解凍(室温2時間静置)した後の食感(ジューシー感)についての官能評価を下記表3に示す評価基準に従い10名のパネラーでおこなった。結果はそれぞれ10名の評点の平均値として求め、下記基準にて記号化した。結果を表4に示す。
記号化
◎:平均値2.5以上
○:平均値1.5以上2.5未満
△:平均値0.5以上1.5未満
×:平均値0.5未満
(2) Evaluation of chicken sausage A sensory evaluation of the texture (juiciness) of the obtained chicken sausage after being naturally thawed (standing at room temperature for 2 hours) was performed by 10 panelists according to the evaluation criteria shown in Table 3 below. Chicken. The results were calculated as the average of the scores of 10 people, and symbolized according to the following criteria. The results are shown in Table 4.
Symbolization ⊚: Mean value 2.5 or more ○: Mean value 1.5 or more and less than 2.5 Δ: Mean value 0.5 or more and less than 1.5 ×: Mean value less than 0.5

Figure 0006815802
Figure 0006815802

Figure 0006815802
Figure 0006815802

表4の結果から明らかなように、実施例品を用いた試験区の鶏ソーセージの食感は、脂っぽさのあるジューシー感があった。一方、比較例品及び参考例品を用いた試験区の鶏ソーセージの食感は、脂っぽさのあるジューシー感は得られなかった。 As is clear from the results in Table 4, the texture of the chicken sausage in the test plot using the example product was greasy and juicy. On the other hand, the texture of the chicken sausages in the test plots using the comparative example product and the reference example product did not give a greasy and juicy feeling.

[惣菜食品用品質改良剤の評価2]
<鶏唐揚げでの評価>
(1)鶏唐揚げの作製
[試験区13〜24]
ステンレス製ボールに、食塩0.5g、肉質改良剤(商品名:ミートグッド300;理研ビタミン社製)3.0g、鶏油(商品名:チキンファットCO−1;理研ビタミン社製)2.0g、表5に記載した量の惣菜食品用品質改良剤(2.00g又は0.38g)及び全体が20gとなるように冷水(12.5g又は14.12g)を加え、スパチュラを用いてかき混ぜてピックル液を作製した。作製したピックル液と鶏胸肉(1個30〜35gにカットしたもの合計100g)とをタンブラー(型式:VT−5;竹内食品機械社製)に加え、真空タンブリング処理を15分間、12rpmでおこない処理肉を得た。得られた処理肉100gに対してから揚げ粉(商品名:から揚げ粉しょう油味;理研ビタミン社製)16g、水12gの割合となるようにステンレス製ボールに入れて練りこみ、唐揚げ液付けをした。唐揚げ液付けした処理肉を170℃で6分間油ちょうし、その後−25℃の冷凍庫で1時間冷却し、鶏唐揚げ(試験区13〜24)を得た。
[Evaluation of quality improver for prepared foods 2]
<Evaluation with fried chicken>
(1) Preparation of fried chicken [Test plots 13 to 24]
In a stainless steel bowl, 0.5 g of salt, meat quality improver (trade name: Meat Good 300; manufactured by RIKEN Vitamin) 3.0 g, chicken oil (trade name: Chicken Fat CO-1; manufactured by RIKEN Vitamin) 2.0 g , Add the amount of the quality improver for prepared foods (2.00 g or 0.38 g) shown in Table 5 and cold water (12.5 g or 14.12 g) so that the total amount is 20 g, and stir with a spatula. A pickle solution was prepared. The prepared pickle liquid and chicken breast (100 g in total cut into 30 to 35 g each) are added to a tumbler (model: VT-5; manufactured by Takeuchi Food Machinery Co., Ltd.), and vacuum tumbling treatment is performed for 15 minutes at 12 rpm. Obtained processed meat. Put 16g of karaage flour (trade name: karaage flour soy sauce flavor; manufactured by RIKEN Vitamin) and 12g of water in a stainless steel bowl, knead it, and add fried chicken liquid to 100g of the obtained processed meat. Did. The processed meat soaked in fried chicken was oiled at 170 ° C. for 6 minutes and then cooled in a freezer at -25 ° C. for 1 hour to obtain fried chicken (test plots 13 to 24).

Figure 0006815802
Figure 0006815802

(2)鶏唐揚げの評価
得られた鶏唐揚げを電子レンジで加熱した後の食感(ジューシー感)についての官能評価をおこなった。官能評価は、「惣菜食品用品質改良剤の評価1」の「(2)鶏ソーセージの評価」と同様な方法で行った。結果を表6に示す。
(2) Evaluation of fried chicken A sensory evaluation of the texture (juiciness) of the obtained fried chicken after heating in a microwave oven was performed. The sensory evaluation was carried out in the same manner as in "(2) Evaluation of chicken sausage" in "Evaluation 1 of quality improver for prepared foods". The results are shown in Table 6.

Figure 0006815802
Figure 0006815802

表6の結果から明らかなように、実施例品を用いた試験区の鶏唐揚げの食感は、脂っぽさのあるジューシー感があった。一方、比較例品及び参考例品を用いた試験区の鶏唐揚げの食感は、脂っぽさのあるジューシー感は得られなかった。 As is clear from the results in Table 6, the texture of the fried chicken in the test plot using the example product was greasy and juicy. On the other hand, the texture of fried chicken in the test plot using the comparative example product and the reference example product did not give a greasy and juicy feeling.

[惣菜食品用品質改良剤の評価3]
<メンチカツでの評価>
(1)メンチカツの作製
[試験区25〜36]
卓上ミキサー(型式:KSM150WH;エフ・エム・アイ社製)の容器内に粒状植物性たん白(商品名:フジニックエース100;不二製油社製)24g、水72g、たん白加水分解物(商品名:HAP−GL;理研ビタミン社製)2.4gを加え3分間放置して粒状植物性たん白に水分を吸水させた後、挽き肉[ミートチョッパー(型式:M−22A;なんつね社製)を用いて挽き目6mmでチョッピングして得られた豚腕肉(脂肪量20%)192g、鶏胸肉192g、牛トリミング(脂肪量30%)96g]480g、食塩2.4g、砂糖4.0g、香辛料2.4g、グルタミン酸ナトリウム(商品名:MSGペーパー;MCフードスペシャリティーズ社製)0.8gを加え、2分30秒間混合した。次にパン粉(商品名:P−900;富士パン粉工業社製)24g、水48g、玉ねぎみじん切り132g、表7に記載した量の惣菜食品用品質改良剤(8.00g又は1.52g)を加え、1分間混合した。最後に加工でん粉(商品名:日食MT01;日本食品化工社製)8.0gを加え、30秒間混合してメンチカツ中だね生地を作製した。得られたメンチカツ中だね生地を40gの大きさに成型して、バッター液[バッターミックス(商品名:U−869バッターミックス;理研ビタミン社製)100に対して水400の割合で混合したもの]を付けて、次にパン粉(商品名:VSカラー生ミックス12mm;ライオンフーズ社製)を付けて、その後−25℃の冷凍庫で1時間冷却し、メンチカツ(試験区25〜36)を得た。
[Evaluation of quality improver for prepared foods 3]
<Evaluation with Menchi-katsu>
(1) Preparation of Menchi-katsu [Test plots 25-36]
Granular vegetable protein (trade name: Fujinic Ace 100; manufactured by Fuji Oil Co., Ltd.) 24 g, water 72 g, protein hydrolyzate (trade name: Fujinic Ace 100; manufactured by Fuji Oil Co., Ltd.) in a container of a desktop mixer (model: KSM150WH; manufactured by FMI). Product name: HAP-GL; manufactured by RIKEN Vitamin) Add 2.4 g and leave for 3 minutes to allow the granular vegetable protein to absorb water, and then grind meat [meat chopper (model: M-22A; manufactured by Nantsune). 192 g of pork arm meat (20% fat content), 192 g of chicken breast, 96 g of beef trimming (30% fat content)] 480 g, 2.4 g of salt, and 4. sugar obtained by chopping with a grind of 6 mm using). 0 g, 2.4 g of spice, and 0.8 g of monosodium glutamate (trade name: MSG Paper; manufactured by MC Food Specialties) were added and mixed for 2 minutes and 30 seconds. Next, add 24 g of bread crumbs (trade name: P-900; manufactured by Fuji Panko Kogyo Co., Ltd.), 48 g of water, 132 g of chopped onions, and the amount of quality improver for prepared foods (8.00 g or 1.52 g) shown in Table 7. Mix for 1 minute. Finally, 8.0 g of modified starch (trade name: Nissho MT01; manufactured by Nihon Shokuhin Kako Co., Ltd.) was added and mixed for 30 seconds to prepare a dough for minced meat cutlet. The obtained Menchi-katsu dough is molded to a size of 40 g and mixed with 100 parts of batter liquid [batter mix (trade name: U-869 batter mix; manufactured by RIKEN Vitamin)) and 400 parts of water. ], Then bread crumbs (trade name: VS color raw mix 12 mm; manufactured by Lion Foods Co., Ltd.) were added, and then cooled in a freezer at -25 ° C for 1 hour to obtain Menchi-katsu (test plots 25-36). ..

Figure 0006815802
Figure 0006815802

(2)メンチカツの評価
得られたメンチカツを油ちょうした後の食感(ジューシー感)についての官能評価をおこなった。官能評価は、「惣菜食品用品質改良剤の評価1」の「(2)鶏ソーセージの評価」と同様な方法で行った。結果を表8に示す。
(2) Evaluation of Menchi-katsu A sensory evaluation was performed on the texture (juiciness) of the obtained minced meat cutlet after oiling. The sensory evaluation was carried out in the same manner as in "(2) Evaluation of chicken sausage" in "Evaluation 1 of quality improver for prepared foods". The results are shown in Table 8.

Figure 0006815802
表8の結果から明らかなように、実施例品を用いた試験区のメンチカツの食感は、脂っぽさのあるジューシー感があった。一方、比較例品及び参考例品を用いた試験区のメンチカツの食感は、脂っぽさのあるジューシー感は得られなかった。
Figure 0006815802
As is clear from the results in Table 8, the texture of the minced meat cutlet in the test plot using the example product was greasy and juicy. On the other hand, the texture of the minced meat cutlet in the test group using the comparative example product and the reference example product did not give a greasy and juicy feeling.

Claims (1)

構成脂肪酸が炭素数16〜18の飽和脂肪酸であるプロピレングリコール脂肪酸エステル6.0〜18.0質量%構成脂肪酸が炭素数16〜18の飽和脂肪酸でありモノエステル体を70質量%以上含有するモノグリセリン脂肪酸エステル3.0〜9.0質量%構成脂肪酸が炭素数16〜18の飽和脂肪酸でありモノエステル体を30質量%以上含有するジグリセリン脂肪酸エステル0.5〜1.5質量%及び油脂78.5〜83.5質量%を含有する油脂組成物であることを特徴とする畜肉類及び/又は魚介類を主成分とする成形した惣菜食品のジューシー感又は脂っぽさのあるジューシー感を改善する惣菜食品用品質改良剤。 The constituent fatty acid is a saturated fatty acid having 16 to 18 carbon atoms and contains propylene glycol fatty acid ester 6.0 to 18.0% by mass , and the constituent fatty acid is a saturated fatty acid having 16 to 18 carbon atoms and contains 70% by mass or more of a monoester compound. Monoglycerin fatty acid ester 3.0 to 9.0% by mass , diglycerin fatty acid ester 0.5 to 1.5% by mass containing 30% by mass or more of monoester, which is a saturated fatty acid having 16 to 18 carbon atoms as a constituent fatty acid. And , which is a fat and oil composition containing 78.5 to 83.5% by mass of fats and oils, has a juicy feeling or greasiness of a molded prepared food containing mainly livestock meat and / or seafood. A quality improver for prepared foods that improves the juiciness.
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