JP4449820B2 - Coated paper for printing - Google Patents

Description

  The present invention relates to a bulky coated coated paper with improved smoothness.

  In general, a coated paper for printing is produced by applying a coating liquid mainly composed of a pigment and an adhesive to at least one side of a base paper and drying it. The coated paper for printing is classified into cast coated paper, art paper, coated paper, fine coated paper, and the like according to the coating amount of the coating liquid and the finishing method of the coated paper. These coated papers are subjected to multicolor printing or single color printing, and are widely used as commercial printed materials such as flyers, brochures and posters, or as publications such as books and magazines.

  In recent years, with the progress of visualization and colorization of printed matter, there is an increasing demand for high quality coated paper for printing. Specifically, the glossiness, smoothness, and whiteness of the coated coated paper itself determine the quality of the printed finish.

  As a technique for improving the smoothness of the coated paper for printing, it has been proposed to blend delaminated kaolin (hereinafter abbreviated as delaminated kaolin) in the coating layer (see Patent Documents 1 to 3). Deramikaolin is a hexagonal thin flat clay mineral pigment, and since the shape is flat, the pigment is lined up so as to cover the surface of the coating layer widely. Have. The degree of flatness (flatness) of the delaminated kaolin is generally expressed using an aspect ratio (size of pigment diameter / pigment thickness), and the higher the aspect ratio, the thinner the pigment particle shape, This indicates that the pigment shape has a large flat plate shape (high flatness). As a specific numerical value of aspect ratio, it is about 15 to 20 for general deramikaolin, but has a high flatness of about 30 to 60 for special deramikaolin. Special deramikaolin with extremely high flatness such as 100 has appeared.

As a technique for improving the smoothness of the coated paper for printing, it has been proposed to further add satin white to the coating layer (see Patent Documents 4 to 7). Satin white is, for example, a white pigment of acicular crystals generated by a reaction between calcium hydroxide and aluminum sulfate, and its official name is calcium trisulfoaluminate. Satin white is an inorganic complex compound represented by the following general formula (1), and the coating layer surface in which this is blended usually exhibits excellent smoothness.
3CaO · Al ₂ O ₃ · 3CaSO ₄ · 31 to 32H ₂ O (1)

  However, any of the prior art documents merely teaches that deramikaolin and satin white are blended in the coating layer of the coated paper that controls ink reception. Some conventional printing coated papers have a single undercoating layer provided on the lower side of a coating layer that controls ink reception (hereinafter referred to as an overcoating layer). In many cases, the installation of the undercoat coating layer is one way to improve the smoothness of the topcoat coating layer. In spite of this, the prior art gives the effect of the undercoat layer on the smoothness of the topcoat layer.

  By the way, in the conventional printing coated paper provided with an undercoat coating layer, there are examples in which kaolin is blended in the pigment of the undercoat coating layer (see Patent Documents 8 to 10) and a few examples in which satin white is blended. However, in many cases, relatively inexpensive pigments are used, and relatively inexpensive starch is also used as an adhesive.

  The kaolin is a so-called “kaolin within a general particle shape range” in which “the size of the pigment” is specified by the particle diameter or particle size distribution, and has a high aspect ratio as described above. This is different from special deramikaolin, which greatly improved the property (flatness).

  However, when an undercoat coating layer is provided, the surface smoothness of the layer typically affects the smoothness of the overcoat layer (ink receiving layer) provided on the undercoat layer, The smoothness of the topcoat layer that governs ink acceptance affects the glossiness of that layer. Therefore, in order to obtain a coated paper for printing excellent in glossiness, smoothness and whiteness, not only the topcoat coating layer (= ink receiving layer) of the coated paper but also the constitution of the undercoat coating layer. It must be devised.

  Moreover, in addition to the requirement for excellent glossiness, smoothness and whiteness, the coated paper for printing has recently increased the touch feeling (paper waist) and apparent specific volume of each coated paper. There is a tendency to pay attention. In particular, a recent trend is that coated paper for publications is respected for being bulkier.

  In order to increase the bulk of the coated paper for printing, a method of making the base paper itself bulky by adding a bulking agent (see Patent Documents 12 to 13), or a coating layer applied on the base paper is treated with a thermal soft calender or the like. Conventionally, a method (see Patent Documents 14 to 16), a method using a hollow plastic pigment as a pigment to be blended in a coating layer (see Patent Documents 17 to 18), and the like have been proposed.

  In other words, the conventional proposal for increasing the bulk is to use a relatively bulky base paper as a base paper for printing, and to apply a calendar treatment to the coated paper obtained by applying the coating liquid onto the base paper. It is to reduce the pressing force applied to the base paper and the coating layer as much as possible. However, the reduction of the pressing force at the time of the calendar process tends to be smaller than the case where the smoothing action of the coating layer by the calendar process is not reduced.

  Therefore, in order to obtain an excellent smoothness, more specifically, the smoothness of the top coat layer and the bulky coated paper, the top coat before the calendar treatment is performed under mild conditions. It is important that the layer has a certain level of smoothness.

  One of the prior arts for obtaining coated paper with excellent smoothness even with mild calendering is considered to contribute to the smoothing of the coating layer as a pigment of the top coating layer as described above. However, it is a method of using a white pigment (for example, satin white or deramikaolin) whose crystal shape is needle or flat. The other is a method of increasing the thickness of the top coat layer and camouflaging irregularities on the surface with which the top coat layer is in contact with the top coat layer.

  However, since the coated paper has a predetermined basis weight, not only cannot the thickness of the topcoat layer be increased, but also the increase in the thickness of the topcoat layer is inevitably increased. Increase the density of the coated paper. Therefore, when the former method is adopted, it is difficult to obtain a bulky coated paper.

In general, a coated paper for printing that does not exhibit “bulkyness” generally has a tenacity in the range of 1.15 to 1.25 g / cm ³ . Thus, "bulky coated paper for printing" used in this specification, bulk density is 1.10 g / cm ³ or less, and typically refers to a coated paper is 1.05 g / cm ³ or less. In addition, the measurement of the tension was performed according to the provisions of ISO 534: 1988.

JP 2002-27443 A Japanese Patent Laid-Open No. 2002-22095 JP-A-11-302998 JP-A-11-247097 JP 09-256295 A JP 09-67794 A Japanese Patent Laid-Open No. 02-14098 JP 2003-268695 A JP 2002-69894 A Japanese Patent Laid-Open No. 08-12069 JP 07-238495 A JP 2002-155494 A JP 2003-171893 A Japanese Patent No. 3249212 JP 09-228298 A Japanese Patent Laid-Open No. 06-294100 Japanese Patent Laid-Open No. 2002-22095 JP 09-1119090 A

The present invention is a coated paper for printing in which two coating layers mainly composed of a white pigment and an adhesive are provided on at least one side of a base paper. The coated paper has excellent smoothness and a tension of 1. An object of the present invention is to provide a bulky printing coated paper having a size of 05 g / cm ³ or less.

Therefore, the coated paper for printing according to the present invention has a tension of 1. which is provided with two coating layers mainly composed of a pigment and an adhesive on at least one side of a base paper having a tension of 0.75 g / cm ³ or less. A white pigment having an average particle diameter in the range of 0.1 to 1.3 μm as measured by a sedimentation method for the pigment component of the undercoat layer in contact with the topcoat layer in a printing coated paper of 05 g / cm ³ or less The delaminated kaolin satisfying the following conditions is contained in an amount of 50% by mass or more of the total pigment in the undercoat layer, and is an adhesive component of the undercoat layer. Is in the range of 10 to 20 parts by mass per 100 parts by mass of the pigment component.
Delaminated kaolin: Yes Average particle size d50 ₁ as measured by light scattering method in the range of 2.0～5.0Myuemu, average particle diameter d50 ₂ in the range of 0.30~0.55μm measured by sedimentation method located within, moreover, the average particle size d50 ₁ and an average particle diameter d50 ₂ ratio _(d50 1 / d50 ₂₎ is delaminated kaolin is 4 or more.
It is preferable that 1-30 mass% of the white pigment contained in the undercoat coating layer is satin white.
For the adhesive component of the undercoat coating layer, it is preferable to use a dispersion-type adhesive having a dispersed particle size of 50 to 120 nm, particularly 50 to 100 nm, and when using a water-soluble adhesive in combination, The amount is preferably 7 parts by mass or less per 100 parts by mass of the pigment component.

  In a printing coated paper in which two coating layers mainly composed of a pigment and an adhesive are provided on at least one side of the base paper, the undercoating layer in contact with the top coating layer is a primer coating of the prior art described above. Corresponds to the layer. In the present invention, since the average particle diameter of the pigment component is measured by the sedimentation method, the average particle diameter described below with respect to the pigment component means the average particle diameter measured by the precipitation method.

In the coated paper for printing according to the present invention, the pigment component of the topcoat layer is composed of a white pigment having an average particle diameter in the range of 0.1 to 1.3 μm, and the adhesive component of the topcoat layer Is preferably in the range of 10 to 20 parts by mass per 100 parts by mass of the pigment component of the top coat layer.
It is preferable that 1-30 mass% of the pigment component of the top coat layer is satin white.
The pigment component of the top coat layer is preferably 1 to 30% by mass of a plastic pigment.
For the adhesive component of the top coat layer, it is preferable to use a dispersion-type adhesive having a dispersed particle size of 50 to 120 nm, particularly 50 to 100 nm. When a water-soluble adhesive is used in combination, The amount is preferably 4 parts by mass or less per 100 parts by mass of the pigment component.

Since the coated paper for printing according to the present invention has a bulkiness of 1.05 g / cm ³ or less and is excellent in smoothness, a printed paper having a good appearance can be obtained by printing on the coated paper. Can do.

Generally speaking, a coated paper for printing is produced by forming a coating layer composed mainly of a white raw material and an adhesive as a single layer or multiple layers on at least one side of a base paper. In the present invention, since the aim is to provide a coated paper having a tenacity of 1.05 g / cm ³ or less, the base paper used in the present invention has a tenacity (density) of 0.75 g / cm 3. It is a unique condition that it is ³ or less, and as long as this condition is satisfied, there is no limitation on the type of raw material pulp and the papermaking conditions at the time of producing the base paper itself. It does not matter whether the base paper is size-pressed.

The coated paper of the present invention can be produced by forming an undercoat coating layer and an overcoat coating layer in this order on at least one side of a base paper having an intensity of 0.75 g / cm ³ or less. Both the undercoat coating layer and the topcoat coating layer are mainly composed of a pigment component and an adhesive component.
In the coated paper for printing according to the present invention, the pigment component constituting the undercoat coated layer has an average particle diameter in the range of 0.1 to 1.3 μm, preferably 0. It is in the range of 3 to 1.0 μm. When the average particle diameter of the pigment component constituting the undercoat layer exceeds 1.3 μm, it is difficult to impart excellent smoothness to the undercoat layer itself, and when it is less than 0.1 μm, the smoothness However, since a relatively large amount of adhesive is required to form the undercoat coating layer, it is disadvantageous in terms of economy.

  The pigment component of the undercoat coating layer contains 50% by mass or more, preferably 70 to 95% by mass of deramikaolin. Including deramikaolin in the undercoat coating layer, combined with the fact that the average particle size of the pigment component is specified as described above, is official in providing excellent smoothness to the undercoat coating layer itself. The present inventors have found that this is the case. When the amount of deramikaolin is less than 50% by mass of the pigment component of the undercoat layer, it is difficult to impart excellent smoothness to the undercoat layer itself.

  For pigment particles, the general definition of what is meant by the term aspect ratio (aspect ratio) is the ratio of the average long dimension to the average short dimension when comparing the size of each dimension of the pigment particle, Appropriate average values of the long and short dimensions of the pigment particles described above vary depending on the type of pigment particles.

For example, in the case of flat pigments such as kaolin, mica (mica) and talc (talc), the long dimension is the diameter of a circle with an area corresponding to the grain surface, while the short dimension is the thickness of the grain. In the case of pigment particles with a needle-like (rod-like) structure such as light calcium carbonate and satin white, the long dimension is the length of the particle, the short dimension is the average diameter of the particle, and even if it is a flat pigment, Even in the case of a pigment, if the long dimension and short dimension of the pigment particles are the same, the result is that the aspect ratio is the same by definition.
In addition, the aspect ratio measurement has a problem of high technical difficulty and cost and time. (See Patent Document 19)

Japanese Patent No. 2896250

  In addition, flat pigments have a very large particle area compared to needle pigments, and the shape characteristics of these pigment particles exhibit excellent properties such as improved smoothness compared to coated paper for printing. It is considered that it is inaccurate and insufficient to express the shape characteristics of the particles by the aspect ratio.

In contrast, the inventors examined a method for measuring the particle shape of a tabular pigment such as kaolin easily and in a short time, and obtained an average particle size d50 ₁ by a light scattering method, an average particle size by a precipitation method. d50 _2, and devised a method of representing the shape properties of the plate-shaped pigments the average particle size d50 ₂ ratio by an average particle size d50 ₁ and sedimentation method using a light scattering method _(d50 1 / d50 _2).

That is, in the measurement of the average particle size d50 ₁ by light scattering method, while its diameter is measured, in the measurement of the average particle diameter d50 ₂ by settling method is considered all individual particles to spherical particles, the particles Since the shape influences the sedimentation property, particles having a flat shape and slower sedimentation are measured as particles having a smaller apparent diameter. Therefore, as the particle aspect ratio of the large average particle diameter d50 ₁ and the ratio of the average particle diameter d50 ₂ by sedimentation method using a light scattering method _(d50 1 / d50 ₂₎ it is considered to increase.

Therefore, the particulate properties of delaminated kaolin in the present invention, rather than the aspect ratio, average particle size d50 ₁ by light scattering method, was defined by the average particle diameter d50 _2, and _d50 1 / d50 ₂ by sedimentation method.

  In the present invention, a laser diffraction particle size distribution analyzer SALD-2000 (manufactured by Shimadzu Corporation) is used as a method for measuring the average particle size by the light scattering method, and Cedigraph 5100 (as a method for measuring the average particle size by the sedimentation method). US Micromeritics) was used.

And in the present invention, as delaminated kaolin to be contained in the undercoat coating layer, the range of the average particle size d50 ₁ as measured by light scattering method 2.0～5.0Myuemu, ranges preferably from 2.2~4.7μm to have an average particle diameter d50 ₂ is 0.30~0.55μm measured by sedimentation method, preferably in the range of 0.35～0.50Myuemu, average particle size d50 ₁ and an average particle diameter d50 ₂ ratio, A delaminated kaolin having a d50 ₁ / d50 ₂ of 4 or more, preferably 5 or more is used.

By the way, when d50 ₁ and d50 ₂ of deramikaolin contained in the undercoat coating layer are less than 2.0 μm and less than 0.30 μm, respectively, delamikaolin in the coating solution penetrates excessively into the base paper. Therefore, it becomes difficult to form a coating layer with high smoothness. Further, d50 ₁ and d50 ₂ is also when each exceeds 5.0μm and 0.55 .mu.m, it is difficult to form a highly smooth coating layer. Even when d50 ₁ / d50 ₂ is less than 4, since the flatness (flatness) of the pigment is low, it is excessively permeated into the base paper and it becomes difficult to form a coating layer with high smoothness. For this reason, it is difficult to obtain the coated paper for printing of the present invention.

  The pigment component of the undercoat coating layer preferably further contains 1 to 30% by mass, preferably 3 to 20% by mass of satin white. Incorporation of satin white in the undercoat coating layer, in combination with the fact that the average particle diameter of the pigment component is specified as described above, is public in order to impart excellent smoothness to the undercoat coating layer itself. The present inventors have found that this is the case. When the amount of satin white is less than 1% by mass of the pigment component of the undercoat coating layer, the effect of imparting excellent smoothness to the undercoat layer itself is small. On the other hand, if the amount of satin white exceeds 30% by mass of the pigment component of the undercoat layer, the smoothness of the undercoat layer itself is improved, but a relatively large amount of adhesive is required to form the undercoat layer. Therefore, there is a disadvantage in economic efficiency.

  Other white pigments used in combination with delaminated kaolin and satin white as the pigment component of the undercoat coating layer include calcium carbonate, kaolin, calcined kaolin, engineered kaolin, talc, calcium sulfate, barium sulfate, aluminum hydroxide, Inorganic pigments such as titanium oxide, zinc oxide, alumina, magnesium carbonate, magnesium oxide, silica, magnesium aluminosilicate, calcium silicate bentonite, zeolite, sericite, smectite, solid type, hollow type, through-hole type plastic pigments, etc. And one or more of these can be used in combination with deramikaolin and satin white.

As the adhesive component of the undercoat coating layer, a dispersion type adhesive is usually used. Dispersion type adhesives include conjugated diene polymer latexes such as styrene-butadiene copolymers and methyl methacrylate-butadiene copolymers, acrylic polymer latexes, and vinyl polymer latexes such as ethylene-vinyl acetate copolymers. Etc. can be illustrated. One or two or more of the above-described dispersed adhesives can be used. Even when any of the dispersed adhesives is used, the particle diameter of the dispersed adhesive particles is 50 to 120 nm, particularly 50 to A range of 100 nm is preferable.
A small amount of water-soluble adhesive can be used in combination with the above-described dispersion type adhesive. Examples of water-soluble adhesives include various starches such as oxidized starch, esterified starch and cold water soluble starch, proteins such as casein, soy protein and synthetic protein, cellulose derivatives such as carboxymethylcellulose and methylcellulose, polyvinyl alcohol and modified products thereof. Etc. can be exemplified.

The amount of the adhesive component contained in the undercoat layer is 10 to 20 parts by mass, particularly 10 per 100 parts by mass of the pigment component contained in the undercoat layer, regardless of whether or not a water-soluble adhesive is used in combination. It is selected in the range of ˜18 parts by mass. When the content of the adhesive component is less than 10 parts by mass, the binding power is insufficient, and when it exceeds 20 parts by mass, the smoothness of the undercoat layer may be impaired.
When a water-soluble adhesive is used in combination, the content is preferably 7 parts by mass or less, particularly 4 parts by mass or less per 100 parts by mass of the pigment component. If it exceeds 7 parts by mass, the smoothness of the undercoat coating layer is inferior, which is not preferable. Use of a small amount of a water-soluble adhesive in combination with a dispersion-type adhesive is effective for increasing the viscosity of a coating mixture (coating mixture) for forming an undercoat coating layer and retaining water.

The undercoat layer of the coated paper for printing according to the present invention is composed of a white pigment having an average particle diameter in the range of 0.1 to 1.3 μm and 50% by mass or more of deramikaolin satisfying specific conditions. The first coating liquid containing 10 to 20 parts by mass of the pigment component and 100 to 100 parts by mass of the pigment component is coated on one side or both sides of the base paper and dried. The For coating, roll coating, air knife coating, bar coating, blade coating, etc. can be adopted, but blade coating is preferred. The coating amount of the first coating solution is selected in the range of 10 to ²⁰ g / m ² per one side of the base paper, in total with the coating amount of the second coating solution used for forming the top coating layer described later. It is.

  The PPS smoothness of the undercoat layer obtained from the first coating liquid is preferably adjusted to a range of 2.0 to 3.5 μm, particularly 2.6 to 3.2 μm. The PPS smoothness of the undercoat coating layer obtained by blade-coating the first coating solution having the above composition on the base paper is usually in the range specified above.

  As a precaution, when forming the top coat layer from the second coating liquid described in detail later, when adopting blade coating, the PPS smoothness of the undercoat coat layer is less than 2.0 μm. In some cases, streak or scratch may occur in the overcoat layer. However, if the PPS smoothness of the undercoat coating layer is 2.6 μm or more, the occurrence of streaks or scratches can be completely prevented.

The topcoat layer of the coated paper for printing according to the present invention has a white pigment having an average particle diameter in the range of 0.1 to 1.3 μm, preferably in the range of 0.3 to 1.0 μm, and the white pigment 100 It is formed by applying a second coating mixture containing 10 to 20 parts by mass of adhesive per part by mass to the surface of the undercoat coating layer formed on the base paper and drying it. . For coating, roll coating, air knife coating, bar coating, blade coating, etc. can be adopted, but blade coating is preferred. The coating amount of the second coating liquid is a total of the coating amount of the first coating liquid used for forming the above-described undercoat coating layer, and is selected in the range of 10 to ²⁰ g / m ² per one side of the base paper. It is.

  The reason why the average particle size of the white pigment contained in the topcoat layer is defined as described above is substantially the same as that for the undercoat layer. The white pigment which is one of the main components of the top coat layer preferably contains satin white and / or plastic pigment in an amount corresponding to 1 to 30% by mass, particularly 3 to 20% by mass of the total amount. . The reason is substantially the same as in the case of the undercoat coating layer described above.

  Examples of white pigments other than satin white and plastic pigment that can be used in the top coat layer include, for example, calcium carbonate, calcined kaolin, engineered kaolin, deramikaolin, talc, calcium sulfate, barium sulfate, aluminum hydroxide, titanium dioxide, Examples thereof include inorganic pigments such as zinc oxide, alumina, magnesium carbonate, magnesium oxide, silica, magnesium aluminosilicate, calcium silicate bentonite, zeolite, sericite, and smectite. One or more of these white pigments can be used in the present invention.

  As the adhesive component of the top coat layer, a dispersion type adhesive is usually used as in the case of the above-described undercoat layer. Dispersion type adhesives include conjugated diene polymer latexes such as styrene-butadiene copolymers and methyl methacrylate-butadiene copolymers, acrylic polymer latexes, and vinyl polymer latexes such as ethylene-vinyl acetate copolymers. Etc., and one or more of these can be used as the adhesive component of the outermost coating layer.

The dispersion-type adhesive used for forming the top coat layer preferably contains 10 to 35% by mass, particularly 20 to 30% by mass, of acrylonitrile as a monomer for polymerization. If the acrylonitrile content of the dispersion-type adhesive is less than 10% by mass, the ink solvent absorbability of the formed topcoat layer cannot be satisfactorily lowered, resulting in a loss of printing gloss. I am worried. On the other hand, when the acrylonitrile content of the dispersion-type adhesive exceeds 35% by mass, emulsion polymerization becomes difficult, and satisfactory binding power cannot be expected.
Regardless of which dispersion type adhesive is used as the adhesive component of the top coat layer, the dispersed adhesive particles preferably have a particle size in the range of 50 to 120 nm, particularly 50 to 90 nm.

  A small amount of water-soluble adhesive can be used in combination with the above-described dispersion type adhesive. Examples of water-soluble adhesives include various starches such as oxidized starch, esterified starch and cold water soluble starch, proteins such as casein, soy protein and synthetic protein, cellulose derivatives such as carboxymethylcellulose and methylcellulose, polyvinyl alcohol and modified products thereof. Etc. can be exemplified.

The amount of the adhesive component contained in the top coat layer is 10 to 20 parts by weight, particularly 10 parts per 100 parts by weight of the pigment component contained in the top coat layer regardless of whether or not a water-soluble adhesive is used in combination. It is selected in the range of ˜18 parts by mass. When the content of the adhesive component is less than 10 parts by mass, the binding power is insufficient, and when it exceeds 20 parts by mass, the smoothness of the overcoat layer may be impaired.
When a water-soluble adhesive is used in combination, the content is preferably 4 parts by mass or less per 100 parts by mass of the pigment component. If it exceeds 4 parts by mass, the smoothness of the top coat layer is inferior, which is not preferable. Use of a small amount of a water-soluble adhesive together with a dispersion-type adhesive is effective for increasing the viscosity of a coating mixture (coating mixture) for forming an overcoat coating layer and retaining water.

  For the first coating liquid used for forming the undercoat coating layer and the second coating liquid used for forming the topcoat coating layer, blue or purple dyes, colored pigments, fluorescent light are used as necessary. Various auxiliary agents such as dyes, thickening water retention agents, antioxidants, anti-aging agents, conductivity-inducing agents, antifoaming agents, UV absorbers, dispersants, pH adjusters, mold release agents, water-resistant agents, water-repellent agents, etc. Can be appropriately blended.

The coated paper coated with the second coating liquid to form the top coat layer is subjected to a finishing process, and in this process, for example, a super calendar, a gloss calendar, a soft calendar, or the like can be used. However, among these, it is preferable to employ a calendar provided with a hard resin roll.
In the present invention, the average particle diameter of the pigment component contained in each of the undercoat coating layer and the topcoat coating layer is specified, and the undercoat coating layer and the topcoat coating layer are formed on one side of a base paper having relatively low tension or Since it is provided on both sides, unless a particularly high pressing force is applied to the calendar, it is possible to obtain a coated paper having a tension of 1.05 g / cm ³ or less by calender finishing commonly used in the industry. it can.

  EXAMPLES The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples. In addition, unless otherwise indicated, the part and% in an example show a mass part and the mass%, respectively. Moreover, the average particle diameter of the pigment used by the Example and the comparative example was measured with the following method.

・ Measurement of average particle size of pigment by light scattering method The particle size distribution of pigment is measured using a laser diffraction particle size distribution analyzer SALD-2000 manufactured by Shimadzu Corporation, and the average particle size corresponding to 50 cumulative mass%. The diameter (d50 ₁ ) was measured. The pigment dispersion used for the measurement was obtained by adding 0.05% of a dispersant (sodium polyacrylate) to the pigment and diluting the pigment to a solid content concentration of 1%. Furthermore, it diluted to the area | region which can be measured with the said measuring apparatus as needed.

・ Measurement of average particle size of pigment by sedimentation method The particle size distribution of pigment is measured using a Sedigraph 5100 manufactured by Micromeritics, USA, and the average particle size (d50 ₂ ) corresponding to 50 cumulative mass% is obtained. It was. The pigment dispersion used for the measurement was prepared by adding a pigment slurry prepared by adding 0.05% of a dispersant (sodium polyacrylate) to a pigment with a 0.1% aqueous solution of a phosphate dispersant (nancarin). The pigment solid content concentration was diluted to about 5%.

・ Average particle diameter of copolymer latex Samples containing copolymer latex were photographed with a transmission electron microscope at a magnification of 50,000 times, and the copolymer latex particles were measured from the obtained micrograph, and the number average was obtained. I asked for it.

Example 1
-Preparation of the first coating solution Deramikaolin (trade name: Contour 1160, d50 ₁ : 2.7 µm) was added to an aqueous solution in which 0.1 part of sodium polyacrylate was added as a dispersant to the dispersed deramikaolin. d50 ₂ : 0.38 μm, d50 ₁ / d50 ₂ : 7.1, manufactured by Imeris Co., Ltd.) 90 parts, heavy calcium carbonate (trade name: Hydrocurve 60, d50 ₂ : 1.3 μm, manufactured by Bihoku Powdered Industries Co., Ltd.) 10 parts were added sequentially and dispersed with a Coreless disperser to prepare a pigment slurry. To this slurry, 4.0 parts of oxidized starch (trade name: Ace B, manufactured by Oji Cornstarch Co., Ltd.), styrene-butadiene copolymer latex (trade name: SMARTEX PA2182-2, particle size: 100 parts of pigment) 10 parts (100 nm, manufactured by Nippon A & L Co., Ltd.) (both in terms of solid content), an antifoaming agent and a dye were added as auxiliaries, and finally a first coating solution having a solid content concentration of 54% was prepared.

-Preparation of the second coating solution To the aqueous solution obtained by adding 0.1 parts of sodium polyacrylate as a dispersant to the pigment to be dispersed, fine kaolin (trade name: kao gloss, d50 ₂ : 0.4 μm, 80 parts by Huber (USA) and 20 parts by weight of heavy calcium carbonate (trade name: Hydrocurve 90, d50 ₂ : 0.8 μm, manufactured by Bihoku Powder Chemical Co., Ltd.) were added in order, and dispersed with a Coreless disperser. A pigment slurry was prepared. To this slurry, 2 parts of oxidized starch (trade name: Oji Ace B, supra), styrene-butadiene copolymer latex (trade name: SMARTEX PA2323, acrylonitrile monomer content: 21% by mass with respect to 100 parts of pigment. , Particle size: 89 nm, manufactured by Nippon A & L Co., Ltd.) 12 parts (both solid content conversion), and an antifoaming agent and a dye are added as auxiliary agents, and finally the second coating having a solid content concentration of 59% A liquid was prepared.

-Production of coated paper for printing The first coating liquid was applied on both sides of a high-quality base paper (72.5 g / m ² ) having a tenacity of 0.73 g / cm ³ , and the dry weight per side was 6 g / Coating was performed using a blade coater so as to be m ^2, and this was dried to provide an undercoat coating layer. Next, the second coating liquid is applied onto each undercoat coating layer using a blade coater so that the dry weight per side is 9 g / m ^2, and this is dried to form an overcoat coating layer. Provided. The coated paper thus obtained was passed through a super calender at a temperature of 35 ° C. and a linear pressure of 80 KN / m to obtain a coated paper for printing having a tenacity of 1.03 g / cm ³ .

Example 2
The pigment component of the second coating solution used in Example 1 is composed of 80 parts of fine kaolin (trade name: kao gloss, supra) and 10 parts of heavy calcium carbonate (trade name: hydrocurve 90, supra), Except for changing to a pigment component consisting of 10 parts of Sachin White (trade name: Sachin White B, d50 ₂ : 1.0 μm, manufactured by Shiraishi Kogyo Co., Ltd.) and carrying out the coating solution with a final solid concentration of 54%. In the same manner as in Example 1, a coated paper for printing was obtained.

Example 3
The pigment component of the first coating solution used in Example 2 was delaminated kaolin (trade name: Contour 2070, d50 ₁ : 2.1 μm, d50 ₂ : 0.47 μm, d50 ₁ / d50 ₂ : 4.5, The pigment component was changed to 90 parts by imerys) and 10 parts by weight of heavy calcium carbonate (trade name: Hydrocurve 60, d50 ₂ : 1.3 μm, supra), and the final solid concentration was 54%. A coated paper for printing was obtained in the same manner as in Example 2 except that the liquid was used.

Example 4
The pigment component of the first coating liquid used in Example 2 was delaminated kaolin (trade name: Contour 2000, d50 ₁ : 3.6 μm, d50 ₂ : 0.47 μm, d50 ₁ / d50 ₂ : 7.7, Except for changing to a pigment component consisting of 90 parts of Imeris Co., Ltd. and 10 parts of heavy calcium carbonate (trade name: Hydrocurve 60, supra), and having a final solid concentration of 54%, In the same manner as in Example 2, a coated paper for printing was obtained.

Example 5
The pigment component of the first coating solution used in Example 2 is 60 parts deramikaolin (trade name: Contour 2070, supra) and 40 parts heavy calcium carbonate (trade name: Hydrocurve 60, supra). A coated paper for printing was obtained in the same manner as in Example 2, except that the pigment component was changed to a final coating liquid having a solid concentration of 54%.

Example 6
The pigment component of the first coating solution used in Example 2 is 90 parts of deramikaolin (trade name: Contour 1160, supra) and 10 parts of heavy calcium carbonate (trade name: hydrocurve 90, supra). A coated paper for printing was obtained in the same manner as in Example 2, except that the pigment component was changed to a final coating liquid having a solid concentration of 54%.

Example 7
The adhesive component of the first coating solution used in Example 2 was 0.1 parts of oxidized starch (trade name: Oji Ace B, supra), styrene-butadiene copolymer latex (trade name: SMARTEX PA2182- 2, supra) A coated paper for printing was obtained in the same manner as in Example 2 except that the coating liquid was changed to 12 parts (all in terms of solid content) and the final coating liquid had a solid concentration of 54%.

Example 8
The pigment component of the first coating solution used in Example 2 was 80 parts of deramikaolin (trade name: Contour 1160, supra) and 10 parts of heavy calcium carbonate (trade name: hydrocurve 60, supra). , For printing in the same manner as in Example 2 except that the pigment component was changed to 10 parts of Satin White (trade name: Satin White B, supra) and the final coating liquid had a solid concentration of 53%. Coated paper was obtained.

Example 9
The adhesive component of the second coating solution used in Example 8 was made of 2 parts of oxidized starch (trade name: Oji Ace B, supra), styrene-butadiene copolymer latex (trade name: T-2629M, acrylonitrile monomer). A coated paper for printing was obtained in the same manner as in Example 8, except that the content was changed to 12 parts (all in terms of solid content): 17% by mass, average particle size: 125 nm, manufactured by JSR Corporation.

Example 10
The pigment component of the second coating solution used in Example 8 is 80 parts fine kaolin (trade name: Kao gloss, supra), 10 parts heavy calcium carbonate (trade name: Hydrocurve 90, supra), and plastic. Except that it was changed to a pigment component consisting of 10 parts of pigment (trade name: AE851, d50 ₂ : 1.1 μm, porosity 50%, manufactured by JSR), and the final coating solution had a solid concentration of 54%. In the same manner as in Example 8, a coated paper for printing was obtained.

Example 11
The pigment component of the first coating solution used in Example 8 was 60 parts of deramikaolin (trade name: Contour 1160, supra) and 10 parts of heavy calcium carbonate (trade name: hydrocurve 60, supra). And printing with the same procedure as in Example 8 except that the pigment component is 30 parts of Satin White (trade name: Satin White B, supra) and the final coating liquid has a solid concentration of 44%. Coated paper was obtained.

Example 12
In the production of the coated paper for printing of Example 8, the coated paper for printing was prepared in the same manner as in Example 8 except that the coating amount (dry weight per side) of the undercoat coating layer was 9 g / m ^2. Got.

Example 13
The pigment component of the first coating liquid used in Example 2 was 80 parts deramikaolin (trade name: Contour 1160, supra) and 10 parts heavy calcium carbonate (trade name: Hydrocurve 90, supra). And a satin white (trade name: satin white B, supra) 10 parts pigment component, a final coating solution with a solid concentration of 53% is prepared, and then in the production of coated paper for printing A coated paper for printing was obtained in the same manner as in Example 2 except that a high-quality base paper (US basis weight 70.0 g / m ² ) having an intensity of 0.67 g / cm ³ was used as the base paper.

Comparative Example 1
The pigment component of the first coating liquid used in Example 2 was mixed with 90 parts of deramikaolin (trade name: Contour 1160, supra) and heavy calcium carbonate (trade name: B21, d50 ₂ : 2.1 μm, A coated paper for printing was obtained in the same manner as in Example 2 except that the pigment component was changed to 10 parts (manufactured by Oji Paper Yonago Factory) and the final coating liquid had a solid concentration of 54%.

Comparative Example 2
The pigment component of the first coating solution used in Example 2 was a delaminated kaolin (trade name: Capim) having d50 ₁ of 3.7 μm, d50 ₂ of 0.95 μm, and d50 ₁ / d50 ₂ of 3.9. 90 parts of NP, d50 ₁ : 3.7 μm, d50 ₂ : 0.95 μm, d50 ₁ / d50 ₂ : 3.9, manufactured by Imeris Co., Ltd., and heavy calcium carbonate (trade name: Hydrocurve 60, supra) 10 A coated paper for printing was obtained in the same manner as in Example 2 except that the pigment component was changed to a pigment component consisting of parts and the final coating liquid had a solid concentration of 54%.

Comparative Example 3
The pigment component of the first coating liquid used in Example 2 was deramikaolin (trade name: Capim DG, d50 ₁ : 2.3 μm, d50 ₂ : 0.61 μm, d50 ₁ / d50 ₂ : 3.8, Imeris). Except for changing to a pigment component consisting of 90 parts by company) and 10 parts of heavy calcium carbonate (trade name: Hydrocurve 60, supra) and making the final coating solution with a solid concentration of 54%. In the same manner as in Example 2, a coated paper for printing was obtained.

Comparative Example 4
The pigment component of the first coating solution used in Example 2 was delaminated kaolin (trade name: New Surf, d50 ₁ : 5.6 μm, d50 ₂ : 2.1 μm, d50 ₁ / d50 ₂ : 2.7, Engel Except that it was changed to a pigment component consisting of 90 parts by HARD Co., Ltd. and 10 parts heavy calcium carbonate (trade name: Hydrocurve 60, supra), and the final coating solution had a solid concentration of 54%. In the same manner as in Example 2, a coated paper for printing was obtained.

Comparative Example 5
The pigment component of the 1st coating liquid used in Example 2 was made into fine kaolin (trade name: Milagros, d50 ₁ : 1.8 μm, d50 ₂ : 0.24 μm, d50 ₁ / d50 ₂ : 7.5, Engelhard. Except for changing to a pigment component consisting of 90 parts by company) and 10 parts of heavy calcium carbonate (trade name: Hydrocurve 60, supra) and making the final coating solution with a solid concentration of 54%. In the same manner as in Example 2, a coated paper for printing was obtained.

Comparative Example 6
The pigment component of the first coating solution used in Example 2 was engineered kaolin (trade name: Exilon, d50 ₁ of 2.4 μm, d50 ₂ of 0.61 μm, d50 ₁ / d50 ₂ of 3.9). d50 ₁ : 2.4 μm, d50 ₂ : 0.61 μm, d50 ₁ / d50 ₂ : 3.9, manufactured by Engelhard) 90 parts and heavy calcium carbonate (trade name: Hydrocurve 60, supra) 10 parts A coated paper for printing was obtained in the same manner as in Example 2, except that the pigment component was changed to a final coating liquid having a solid concentration of 54%.

Comparative Example 7
In 60 parts of deramikaolin (trade name: Contour 2070, supra) in the pigment component of the first coating solution used in Example 5, 30 parts were changed to fine kaolin (trade name: milagros, supra). Then, a coated paper for printing was obtained in the same manner as in Example 5 except that the final coating solution had a solid concentration of 54%.

Example 14
The adhesive component of the first coating liquid used in Example 2 was 8 parts of oxidized starch (trade name: Oji Ace B, supra), styrene-butadiene copolymer latex (trade name: Smartex PA2182-2, As mentioned above, a coated paper for printing was obtained in the same manner as in Example 2 except that the coating liquid was changed to 8 parts (all in terms of solid content) to obtain a final coating liquid having a solid concentration of 54%.

Comparative Example 8
・ Preparation of coarse-grained satin white pigment slurry 90 kg (90 liters) of water was placed in a reaction tank (coreless stirring tank) with a volume of 250 liters, and classification was not performed while stirring (particle diameter was 1 diameter). A lump of quick lime (CaO, manufactured by Adachi Lime Industry Co., Ltd.) having a size of ˜4 cm was mixed. Subsequently, it melt | dissolved, continuing stirring, the temperature of the liquid was raised, and it hold | maintained in the range of 85-95 degreeC for 1 hour, Then, it cooled to 30 degreeC. Next, 58.3 kg of an aqueous solution of a sulfuric acid band (25 kg of Al ₂ (SO ₄ ) ₃ · 18H ₂ O dissolved in 50 kg (50 liters) of water) of about 1 kg / min with vigorous stirring. The solution was gradually added in a liquid feeding amount to obtain a satin white suspension.
This suspension was squeezed with a filter press to obtain a cake-like satin white having a solid concentration of 32%. Next, after adding 3 parts of sodium polycarboxylate (trade name: Aron T-40, manufactured by Toa Gosei Co., Ltd.) and water to a solid content of 20% per 100 parts of the solid content of this satin white, it was passed through a sand grinder. A satin white dispersion was obtained, and the dispersion was further subjected to a 150 mesh screen mesh treatment to obtain a satin white pigment slurry having a solid content concentration of 20%. The average particle size of the satin white obtained from this pigment slurry by X-ray transmission type particle size distribution measurement was 3.0 μm.

  The pigment component of the first coating solution used in Example 2 is 80 parts deramikaolin (trade name: Contour 1160, supra) and 10 parts heavy calcium carbonate (trade name: Hydrocurve 60, supra). A coated paper for printing was prepared in the same manner as in Example 2 except that the pigment component consisting of 10 parts of the coarse-grained satin white obtained above was changed to a final coating liquid having a solid concentration of 53%. Obtained.

Example 15
The pigment component of the second coating solution used in Example 2 is 10 parts fine kaolin (trade name: Kao gloss, supra) and 80 parts of heavy calcium carbonate (trade name: Hydrocurve 90, supra), Coating for printing in the same manner as in Example 2 except that the pigment component was changed to 10 parts of Sachin White (trade name: Sachin White B, supra) and the final coating liquid had a solid concentration of 59%. A paper was obtained.

Example 16
The pigment component of the first coating solution used in Example 15 was 80 parts deramikaolin (trade name: Contour 1160, supra) and 10 parts heavy calcium carbonate (trade name: Hydrocurve 90, supra). And Sachin White (trade name: Sachin White B, supra) 10 parts, except that the pigment component is changed to a final coating liquid having a solid concentration of 59%. Coated paper was obtained.

Comparative Example 9
The pigment component of the first coating solution used in Example 15 was 90 parts of deramikaolin (trade name: Capim NP, supra) and 10 parts of heavy calcium carbonate (trade name: Hydrocurve 60, supra). A coated paper for printing was obtained in the same manner as in Example 15 except that the pigment component was changed to a final coating liquid having a solid concentration of 54%.

Comparative Example 10
The pigment component of the first coating solution used in Example 15 is composed of 90 parts of fine kaolin (trade name: Milagros, supra) and 10 parts of heavy calcium carbonate (trade name: Hydrocurve 60, supra). A coated paper for printing was obtained in the same manner as in Example 15 except that the pigment component was changed to a final coating liquid having a solid concentration of 54%.

Quality evaluation of coated paper for printing The quality of each coated paper for printing obtained in Examples 1 to 16 and Comparative Examples 1 to 10 was evaluated by the following items. Evaluation was performed in an environment of 23 ° C. and 50 RH% unless otherwise specified. The results are shown in (Table 1) to (Table 4).

-PPS smoothness of coated paper Using a Parker Print Surf (PPS) surface smoothness tester (model name: MODEL M-569, manufactured by MESSMER BUCHEL, UK), backing disk: soft rubber, clamp pressure: 0. The smoothness was measured 5 times at 98 MPa, and the average was obtained. The smoothness was measured at three points after providing the undercoat coating layer, after providing the topcoat coating layer, and after calendar finishing.

-Surface smoothness The surface of the coating layer after the final calendar finish was observed with the naked eye, and the smoothness was evaluated in four stages.
A: Smoothness is particularly excellent.
○: Excellent smoothness.
Δ: The smoothness is slightly inferior.
X: Smoothness is inferior.

-Streaks on the surface of the coating layer The surface of the top coating layer of each coated paper that had been calendered was observed with the naked eye and examined for the presence of streaks.
○: No streak.
Δ: There is a streak.

・ Glossiness of white paper The glossiness of each coated paper before and after the calendar treatment was measured according to the TAPPI test method: T480 om-92 (TAPPI Test Method T480 om-92). Measured by Technical Research Institute Co., Ltd.).

・ Printability (ink fillability and print smoothness)
Using an RI printing machine, printing is performed on each coated paper using 0.1 cc of printing ink (trade name: Values-G black S type, manufactured by Dainippon Ink & Chemicals, Inc.), and ink transfer of the coated paper is performed. The surface was observed with the naked eye, and the printability of the coated paper was evaluated in four stages based on the transferred ink density (ink fillability) and density uniformity (print smoothness).
A: Printability is particularly excellent.
○: Printability is excellent.
Δ: Printability is slightly inferior.
X: Printability is inferior.

Printing gloss Printing was performed on each coated paper using 0.7 cc of printing ink (trade name: Values-G ink S type, manufactured by Dainippon Ink & Chemicals, Inc.), and the printed matter was left to dry for 24 hours. Thereafter, the 60 ° gloss of the printed surface of each coated paper was measured according to JIS Z8741-1997.

-Intensity The intensities of the coated paper for printing and the base paper after the calendar process were measured according to the regulations of ISO 534: 1988.

Claims (9)

In a coated paper for printing having a tenacity of 1.05 g / cm ³ or less, in which two coating layers mainly comprising a pigment and an adhesive are provided on at least one side of a base paper having a tenacity of 0.75 g / cm ³ or less, The pigment component of the undercoat layer in contact with the topcoat layer is composed of a white pigment having an average particle diameter measured by a precipitation method in the range of 0.1 to 1.3 μm, and the pigment component of the undercoat layer As one type, delaminated kaolin that satisfies the following conditions is contained in an amount of 50% by mass or more of the total pigment in the undercoat layer, and the amount of the adhesive component in the undercoat layer is 10 parts by mass per 100 parts by mass of the pigment component. A coated paper for printing, which is in the range of ˜20 parts by mass.
Delaminated kaolin: Yes Average particle size d50 ₁ as measured by light scattering method in the range of 2.0～5.0Myuemu, average particle diameter d50 ₂ in the range of 0.30~0.55μm measured by sedimentation method located within, moreover, the average particle size d50 ₁ and an average particle diameter d50 ₂ ratio _(d50 1 / d50 ₂₎ is delaminated kaolin is 4 or more.   The coated paper for printing according to claim 1, wherein 1 to 30% by mass of the white pigment contained in the undercoat coating layer is satin white.   The coated paper for printing according to claim 1, wherein the adhesive component of the undercoat coating layer contains a dispersed adhesive having a particle size of 50 to 120 nm.   The adhesive component of the undercoat coating layer comprises a water-soluble adhesive and a dispersion-type adhesive, and the amount of the water-soluble adhesive is 7 parts by mass or less per 100 parts by mass of the pigment component contained in the undercoat coating layer. The coated paper for printing according to claim 3.   The coated paper for printing as described in any one of Claim 1 to 4 whose PPS smoothness of the said undercoat coating layer surface is the range of 2.0-3.5 micrometers.   The pigment component of the top coat layer is a white pigment having an average particle diameter measured by a sedimentation method in the range of 0.1 to 1.3 μm, and the amount of the adhesive component of the top coat layer is white. The coated paper for printing according to claim 1, wherein the amount is in the range of 10 to 20 parts by mass per 100 parts by mass of the pigment.   The coated paper for printing according to claim 6, wherein 1 to 30% by mass of the white pigment contained in the top coat layer is satin white.   The coated paper for printing according to claim 6, wherein 1 to 30% by mass of the white pigment contained in the top coat layer is a plastic pigment.   The adhesive component of the top coat layer is composed of a water-soluble adhesive and a dispersion-type adhesive, and the amount of the water-soluble adhesive is 4 parts by mass or less per 100 parts by mass of the pigment component contained in the top coat layer. The coated paper for printing according to claim 1.