JP4384486B2 - Deodorant, deodorant body and method using the same - Google Patents
Deodorant, deodorant body and method using the same Download PDFInfo
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Description
本発明は、消臭剤及びそれを用いた消臭体並びに消臭方法に関するものである。 The present invention relates to a deodorizing agent, a deodorizing body using the same, and a deodorizing method.
従来より、生ゴミや食品工場等の廃棄物，汚泥，ペット等動物の糞尿，カビ等の悪臭源から発生する臭気を除去するために種々の消臭剤が開発されている。消臭剤のなかには、生物的作用によって悪臭源を分解し変質させることにより消臭するものがある。
このような生物的作用を利用した消臭剤として、例えば、（特許文献１）に「バチルス・サブチリス・クボタを水に含有させた消臭剤」が開示されている。
As a deodorant using such a biological action, for example, (Patent Document 1) discloses a “deodorant containing Bacillus subtilis kubota in water”.
しかしながら上記従来の技術においては、以下のような課題を有していた。
（１）（特許文献１）に開示の技術は、バチルス・サブチリスに属する特定の菌を水に含有させて消臭剤として用いるものであり、菌が悪臭源を分解して消臭効果を得るものなので、消臭効果の持続性には優れているものの即効性がなく、使用直後に良好な消臭効果が得られないという課題を有していた。
（２）このように消臭作用において、即効性と持続性を同時に満足する消臭剤が得られないという課題を有していた。
（３）消臭剤の保存中に、バチルス・サブチリスに属する菌が発芽し増殖してしまうことがあり、この場合は消臭剤が悪臭源と接触しても悪臭源を分解したり変質させたりする作用が小さく、保存性に欠けるという課題を有していた。
However, the above conventional techniques have the following problems.
(1) The technology disclosed in (Patent Document 1) uses a specific bacterium belonging to Bacillus subtilis in water and uses it as a deodorant, and the bacterium decomposes malodor sources to obtain a deodorizing effect. However, although it has an excellent deodorizing effect, it has no immediate effect and has a problem that a good deodorizing effect cannot be obtained immediately after use.
(2) Thus, in the deodorizing action, there was a problem that a deodorant satisfying both immediate effect and sustainability could not be obtained.
(3) During storage of the deodorant, bacteria belonging to Bacillus subtilis may germinate and grow. In this case, even if the deodorant comes in contact with the malodorous source, the malodorous source is decomposed or altered. It has a problem that it has a small action and lacks storage stability.
本発明は上記従来の課題を解決するもので、悪臭源と接触した際に、硫黄系臭気成分等と素早く反応し分解し即効性に優れるとともに悪臭源を分解したり変質させて消臭効果の持続性に優れ、さらに保存性に優れるとともに環境保全性にも優れた消臭剤を提供することを目的とする。
また、本発明は、悪臭の発生を最小限にして長期間に渡り抑制することができる持続性に優れた消臭体を提供することを目的とする。
また、本発明は、消臭剤を悪臭源に接触させることで高い消臭効果を得ることができるとともに、悪臭源の状態に応じて適宜の手段を選択して用いることができ汎用性に優れた消臭方法を提供することを目的とする。
The present invention solves the above-mentioned conventional problems, and when it comes into contact with a malodorous source, it reacts quickly with a sulfur-based odorous component and decomposes and is excellent in immediate effect, and also has a deodorizing effect by decomposing or altering the malodorous source. An object of the present invention is to provide a deodorant that is excellent in sustainability, in addition to excellent storage stability and environmental conservation.
Another object of the present invention is to provide a deodorant excellent in sustainability that can suppress the generation of malodors for a long period of time.
In addition, the present invention can obtain a high deodorizing effect by bringing the deodorant into contact with a malodorous source, and can be used by selecting an appropriate means depending on the state of the malodorous source and is excellent in versatility. The purpose is to provide a deodorizing method.
上記従来の課題を解決するために本発明の消臭剤及びそれを用いた消臭体並びに消臭方法は、以下の構成を有している。
本発明の請求項１に記載の消臭剤は、過酸化水素及び／又はオゾンを溶解させた水性溶媒と、前記水性溶媒に分散された枯草菌及び／又は納豆菌と、苦汁と、を含有し、前記水性溶媒中のアルコール類の含有量が２０〜５０重量％である構成を有している。
この構成により、以下のような作用が得られる。
（１）水性溶媒に枯草菌や納豆菌とともに過酸化水素やオゾンを含有させているので、消臭剤を悪臭源に接触させた際に、過酸化水素等の作用で硫化水素，チオール類等の硫黄系臭気成分等と素早く反応しこれらを分解するので即効性に優れる。
（２）悪臭源と接触した枯草菌や納豆菌が、発芽し増殖する際に悪臭源を分解したり変質させるので消臭効果の持続性にも優れる。
（３）グラム陽性菌であり芽胞菌である枯草菌や納豆菌を用いているので、過酸化水素やオゾンが枯草菌や納豆菌へ作用する殺菌力が弱いため、水性溶媒中でこれらを死滅させることがなく、しかも枯草菌等を休眠状態に保つことができるので保存性に優れる。なお、悪臭源に接触した際には水性溶媒中の過酸化水素やオゾンは分解されるため、枯草菌や納豆菌の発芽や増殖を妨げることなく消臭効果を高めることができる。
（４）枯草菌や納豆菌、過酸化水素やオゾンを用いているので、環境が破壊される等の悪影響が生じることがなく環境保全性に優れるとともに、食品工場等においても用いることができ汎用性に優れる。
（５）枯草菌や納豆菌は水質浄化作用を有するため、工場等で用いられる浄化槽等に添加して消臭と同時に水質を浄化させることもでき応用性に優れる。
（６）Ｍｇ 2+ ，Ｋ + 等を含有する苦汁を含有しているので、消臭剤が悪臭源に接触した際には、枯草菌や納豆菌が悪臭源に含まれる糖類やアミノ酸等の代謝可能な物質によって生理的発芽をして増殖していくとともに、水性溶媒に含有された非代謝物質であるＣａ 2+ ，Ｍｇ 2+ ，Ｋ + の金属イオンによって化学的発芽を引き起こさせて増殖させることができ、悪臭源に含まれる代謝物質と水性溶媒に含まれる非代謝物質との相乗効果によって、枯草菌等を飛躍的に増殖させ高い消臭効果を得ることができる。
（７）水性溶媒がＣａ 2+ ，Ｍｇ 2+ ，Ｋ + の金属イオンの１種以上を０．５〜１００ｐｐｍの所定量含有しているので、保存中にオゾンや過酸化水素の一部が還元され酸化力がわずかに失われるため、オゾンや過酸化水素による枯草菌や納豆菌の生菌に対する殺菌力が低下し枯草菌や納豆菌を生菌の状態で長期間維持することができ保存性に優れる。
（８）水性溶媒が所定量のアルコール類を含有しているので、悪臭源の内の枯草菌や納豆菌が未分解の残留タンパク質をアルコール類が凝固するとともにカビ類等を殺菌し高い消臭効果を得ることができる。
（９）芽胞菌である枯草菌や納豆菌を用いているので、アルコール類が枯草菌や納豆菌へ作用する殺菌力が弱いため、水性溶媒中でこれらを死滅させることがなく、しかも枯草菌等を休眠状態に保つことができるので保存性に優れる。また、悪臭源の残留タンパク質の凝固に用いられなかった過剰なアルコール類は揮発するので、枯草菌や納豆菌の発芽や増殖を妨げることなく消臭効果を高めることができる。
In order to solve the above conventional problems, the deodorant of the present invention, the deodorant using the same, and the deodorization method have the following configurations.
The deodorant according to claim 1 of the present invention contains an aqueous solvent in which hydrogen peroxide and / or ozone are dissolved, Bacillus subtilis and / or Bacillus natto dispersed in the aqueous solvent, and bitter juice. In addition , the content of the alcohol in the aqueous solvent is 20 to 50% by weight .
With this configuration, the following effects can be obtained.
(1) Since hydrogen peroxide and ozone are contained in an aqueous solvent together with Bacillus subtilis and Bacillus natto, hydrogen sulfide, thiols, etc. by the action of hydrogen peroxide, etc. when deodorant is brought into contact with a malodorous source It reacts quickly with sulfur-based odor components and decomposes them, so it has excellent immediate effect.
(2) Since Bacillus subtilis and Bacillus natto in contact with a malodorous source germinate and proliferate, the malodorous source is decomposed and altered, so that the deodorizing effect is excellent.
(3) Gram-positive bacteria and spore bacteria Bacillus subtilis and Bacillus natto are used, so hydrogen peroxide and ozone are weak in the bactericidal activity acting on Bacillus subtilis and Bacillus natto. In addition, Bacillus subtilis and the like can be kept dormant, so that the storage stability is excellent. Since the hydrogen peroxide and ozone in the aqueous solvent are decomposed when coming into contact with a malodorous source, the deodorizing effect can be enhanced without hindering germination and growth of Bacillus subtilis and Bacillus natto.
(4) Since Bacillus subtilis, Bacillus natto, hydrogen peroxide, and ozone are used, there is no adverse effect such as destruction of the environment, it is excellent in environmental conservation, and it can be used in food factories etc. Excellent in properties.
(5) Since Bacillus subtilis and Bacillus natto have a water purification effect, they can be added to septic tanks used in factories and the like to purify water simultaneously with deodorization and have excellent applicability.
(6) Since it contains bitter juice containing Mg 2+ , K +, etc., when the deodorant comes in contact with the malodorous source, Bacillus subtilis or Bacillus natto, such as sugars and amino acids contained in the malodorous source Proliferates through physiological germination with metabolizable substances, and causes chemical germination by metal ions of Ca 2+ , Mg 2+ , K + , which are non-metabolites contained in an aqueous solvent. Due to the synergistic effect of the metabolite contained in the malodorous source and the non-metabolite contained in the aqueous solvent, Bacillus subtilis etc. can be drastically grown and a high deodorizing effect can be obtained.
(7) Since the aqueous solvent contains one or more of Ca 2+ , Mg 2+ , and K + metal ions in a predetermined amount of 0.5 to 100 ppm, ozone or hydrogen peroxide is partially stored during storage. Because it is reduced and its oxidizing power is slightly lost, the bactericidal power of Bacillus subtilis and Bacillus natto by virtue of ozone and hydrogen peroxide is reduced, and Bacillus subtilis and Bacillus natto can be maintained in the state of viable bacteria for long periods of storage Excellent in properties.
(8) Since the aqueous solvent contains a predetermined amount of alcohols, Bacillus subtilis and Bacillus natto, among the malodorous sources, coagulate residual proteins that are not decomposed, while alcohols sterilize molds and have high deodorization An effect can be obtained.
(9) Since Bacillus subtilis and Bacillus natto, which are spores, are used, the bactericidal power of alcohols acting on Bacillus subtilis and Bacillus natto is weak, so these are not killed in an aqueous solvent, and Bacillus subtilis Etc. can be kept in a dormant state. Moreover, since excess alcohol which was not used for coagulation | solidification of the residual protein of a malodor source volatilizes, a deodorizing effect can be heightened, without preventing germination and proliferation of Bacillus subtilis and Bacillus natto.
ここで、水性溶媒としては、イオン交換水、水道水、井戸水、純水等を用いることができる。 Here, ion exchange water, tap water, well water, pure water, or the like can be used as the aqueous solvent.
過酸化水素は、殺菌作用を示すとともに、硫化水素，チオール類，硫化ジメチル，二硫化ジメチル等の硫黄系臭気成分と素早く反応して臭気を減少させることができる。但し、食品に使用する場合は、最終食品の完成前に分解又は除去することが定められているため、使用が制限される。
オゾンは、悪臭源に存在するほとんどのグラム陰性菌等に作用し強力な殺菌作用と消臭作用を示すとともに、経時的に酸素に分解されるため低濃度であれば食品にも使用することができ汎用性に優れる。但し、経時的に分解し易く保存性に欠けるため、使用する都度、溶存させるのが好ましい。
Hydrogen peroxide exhibits a bactericidal action, and can quickly react with sulfur-based odor components such as hydrogen sulfide, thiols, dimethyl sulfide, dimethyl disulfide and the like to reduce odor. However, when it is used for food, it is specified that it is decomposed or removed before the final food is completed.
Ozone acts on most gram-negative bacteria present in malodorous sources and has a strong bactericidal and deodorizing action. It decomposes into oxygen over time, so it can be used in foods at low concentrations. Can be versatile. However, it is preferable to dissolve each time it is used because it is easily decomposed over time and lacks storage stability.
過酸化水素の水性溶媒に対する濃度としては、３〜３０重量％好ましくは５〜１０重量％が用いられる。過酸化水素の濃度が５重量％より小さくなるにつれ消臭効果や殺菌効果が低下する傾向がみられ、１０重量％より大きくなるにつれ保存中に過酸化水素の殺菌力により枯草菌や納豆菌の生菌の一部が死んでしまい、これらの生菌による消臭効果が低下するとともに過酸化水素による反応性が増し取扱性が低下する傾向がみられる。特に、３重量％より小さくなるか３０重量％より大きくなると、これらの傾向が著しいため、いずれも好ましくない。 The concentration of hydrogen peroxide in the aqueous solvent is 3 to 30% by weight, preferably 5 to 10% by weight. As the concentration of hydrogen peroxide becomes smaller than 5% by weight, the deodorizing effect and sterilizing effect tend to decrease. As the concentration becomes higher than 10% by weight, the sterilizing power of hydrogen peroxide during storage can cause Some of the live bacteria die, and the deodorizing effect by these live bacteria decreases, and the reactivity by hydrogen peroxide increases and the handling property tends to decrease. In particular, when the content is smaller than 3% by weight or larger than 30% by weight, these tendencies are remarkable, so that neither is preferable.
オゾンの水性溶媒中への溶存量としては、０．１〜２０ｐｐｍ好ましくは０．４〜１２ｐｐｍが好適に用いられる。オゾンの溶存量が０．４ｐｐｍより少なくなるにつれ消臭効果や殺菌効果が低下する傾向がみられ、１２ｐｐｍより多くなるにつれ強力な酸化力により安全性が低下するとともに食品への使用が制限され、さらに保存中にオゾンの殺菌力により枯草菌や納豆菌の生菌の一部が死んでしまい、これらの生菌による消臭効果が低下する傾向がみられる。特に、０．１ｐｐｍより少なくなるか、２０ｐｐｍより多くなると、これらの傾向が著しいため、いずれも好ましくない。 As the dissolved amount of ozone in the aqueous solvent, 0.1 to 20 ppm, preferably 0.4 to 12 ppm is suitably used. As the dissolved amount of ozone is less than 0.4 ppm, the deodorizing effect and the bactericidal effect tend to decrease, and as it exceeds 12 ppm, safety is reduced due to its strong oxidizing power and its use in food is restricted. Further, during storage, some of the viable bacteria of Bacillus subtilis and Bacillus natto die due to the sterilizing power of ozone, and the deodorizing effect due to these live bacteria tends to decrease. In particular, when the content is less than 0.1 ppm or more than 20 ppm, these tendencies are remarkable, so that neither is preferable.
枯草菌や納豆菌の水性溶媒への分散量としては、枯草菌と納豆菌の合計の菌数が１×１０2〜１×１０13個／ｍＬ好ましくは１×１０3〜１×１０10個／ｍＬが用いられる。枯草菌や納豆菌の菌数が１×１０3個／ｍＬより少なくなるにつれ枯草菌等の活動が少ないため十分な消臭効果が得られ難くなる傾向がみられ、１×１０10個／ｍＬより多くなるにつれ菌が飽和状態に近づき菌の分裂能や増殖能が低下し悪臭源を分解や変質させる能力が低下し十分な消臭効果が得られ難くなる傾向がみられる。特に、菌数が１×１０2個／ｍＬより少なくなるか１×１０13個／ｍＬより多くなると、これらの傾向が著しくなるため、いずれも好ましくない。
アルコール類としては、メタノール，エタノール，プロパノール等の炭素原子数が１〜３の低級脂肪族アルコールの１種若しくは複数種を混合したものが用いられる。なかでも、エタノール，イソプロピルアルコールが好適に用いられる。消毒液としても用いられており人体に対する影響も少なく安全性に優れるとともに、タンパク質の凝固作用が高いため安定した消臭効果が得られるからである。
水性溶媒中のアルコール類の含有量が２０重量％より少なくなるにつれ、残留タンパク質の凝固量が少なくなるとともにカビ類等の殺菌力も低下し消臭効果が低下する傾向がみられ、５０重量％より多くなるにつれ引火性が増すとともに保存中に枯草菌や納豆菌の中に殺菌されるものが現れ消臭効果が低下する傾向がみられるため、いずれも好ましくない。
The amount of Bacillus subtilis or Bacillus natto dispersed in an aqueous solvent is such that the total number of Bacillus subtilis and Bacillus natto is 1 × 10 2 to 1 × 10 13 cells / mL, preferably 1 × 10 3 to 1 × 10 10. / ML is used. As the number of Bacillus subtilis and Bacillus natto is less than 1 × 10 3 cells / mL, there is a tendency that it is difficult to obtain a sufficient deodorizing effect due to less activity of Bacillus subtilis, etc. 1 × 10 10 cells / mL As more and more bacteria are brought into saturation, there is a tendency that the ability to break down or proliferate the bacteria decreases, the ability to decompose or alter malodorous sources, and it becomes difficult to obtain a sufficient deodorizing effect. In particular, when the number of bacteria is less than 1 × 10 2 cells / mL or more than 1 × 10 13 cells / mL, these tendencies tend to be remarkable, and neither is preferable.
As the alcohol, a mixture of one or more kinds of lower aliphatic alcohols having 1 to 3 carbon atoms such as methanol, ethanol, and propanol is used. Of these, ethanol and isopropyl alcohol are preferably used. This is because it is also used as a disinfecting solution, has little influence on the human body, is excellent in safety, and has a high protein coagulation action, so that a stable deodorizing effect can be obtained.
As the content of alcohols in the aqueous solvent is less than 20% by weight, the amount of residual protein coagulated decreases, and the sterilizing power of molds and the like also tends to decrease and the deodorizing effect tends to decrease. As the amount increases, flammability increases, and sterilized Bacillus subtilis or Bacillus natto during storage tends to appear and the deodorizing effect tends to decrease.
ここで、Ｃａ２＋，Ｍｇ２＋，Ｋ＋を水性溶媒に含有させる手段としては、予め所定量のＣａ２＋，Ｍｇ２＋，Ｋ＋が溶存している井戸水等の水性溶媒を用いたり、イオン交換水や純水等に海水から食塩を製造するときに副生されたＭｇ２＋，Ｋ＋等を含有する苦汁を加えて水性溶媒とする等の種々の手段を用いることができる。 Here, Ca 2+, Mg 2+, as a means for containing the K + in an aqueous solvent, in advance a predetermined amount of Ca 2+, Mg 2+, or with an aqueous solvent such as well water K + is dissolved, ion-exchanged water Various means can be used, such as adding bitter juice containing Mg 2+ , K +, etc. produced as a by-product when producing salt from seawater to pure water or the like to form an aqueous solvent.
Ｃａ２＋，Ｍｇ２＋，Ｋ＋の１種以上の水性溶媒中の含有量が１ｐｐｍより少なくなるにつれ、枯草菌等が悪臭源と接触した際に化学的発芽が起こり難く枯草菌等の増殖速度が小さく高い消臭効果が得られ難くなる傾向がみられ、８０ｐｐｍより多くなるにつれ保存中に枯草菌等と接触することで枯草菌等が化学的発芽を起こし易く、このためオゾンや過酸化水素の作用を受け易く枯草菌等の生菌が少なくなり消臭効果が低下するとともに、還元されるオゾンや過酸化水素の量が増加しオゾンや過酸化水素による即効性の消臭効果が低下する傾向が見られる。特に、０．５ｐｐｍより少なくなるか１００ｐｐｍより多くなるとこれらの傾向が著しくなるため、いずれも好ましくない。 As the content of Ca 2+ , Mg 2+ , and K + in one or more aqueous solvents is less than 1 ppm, chemical germination hardly occurs when Bacillus subtilis or the like comes into contact with a malodorous source, and the growth rate of Bacillus subtilis or the like increases. Small and high deodorizing effect tends to be difficult to obtain. As the concentration exceeds 80 ppm, Bacillus subtilis and the like are liable to chemically germinate by contact with Bacillus subtilis during storage. It is easy to be affected, and there are fewer viable bacteria such as Bacillus subtilis and the deodorizing effect is reduced, and the amount of ozone and hydrogen peroxide to be reduced is increased and the immediate deodorizing effect due to ozone and hydrogen peroxide is reduced. Is seen. In particular, when the content is less than 0.5 ppm or more than 100 ppm, these tendencies become remarkable, and therefore, neither is preferable.
本発明の請求項２に記載の発明は、請求項１に記載の消臭剤であって、前記水性溶媒が、ニトロソモナス属、ニトロバクター属、シュードモナス属の内のいずれか１種以上の微生物を含有した構成を有している。
この構成により、請求項１で得られる作用に加え、以下のような作用が得られる。
（１）ニトロソモナス属、ニトロバクター属、シュードモナス属の微生物は、悪臭源から発生するアンモニア等の窒素系臭気成分の分解に寄与するので、種々の種類の臭気を効果的に除去することができる。即ち、ニトロソモナス属の微生物はアンモニアをＮＯ2に、ニトロバクター属の微生物はＮＯ2をＮＯ3に、シュードモナス属の微生物はＮＯ3をＮ2に変換するといわれており、これらの相互作用によって消臭できるのである。
The invention according to claim 2 of the present invention is the deodorant according to claim 1 , wherein the aqueous solvent is one or more microorganisms of the genus Nitrosomonas, Nitrobacter, and Pseudomonas. It has the structure containing.
With this configuration, in addition to the operation obtained in the first aspect , the following operation can be obtained.
(1) Nitrosomonas spp., Nitrobacter spp., Pseudomonas spp. Microorganisms contribute to the decomposition of nitrogenous odorous components such as ammonia generated from malodorous sources, so that various types of odors can be effectively removed. . In other words, it is said that microorganisms belonging to the genus Nitrosomonas convert ammonia to NO 2 , microorganisms belonging to the genus Nitrobacter convert NO 2 to NO 3 , and microorganisms belonging to the genus Pseudomonas convert NO 3 to N 2. It can smell.
ここで、ニトロソモナス属の微生物としては、ニトロソモナス・ユーロパエア等を用いることができる。
ニトロバクター属の微生物としては、ニトロバクター・アギリス等を用いることができる。
シュードモナス属の微生物としては、シュードモナス・キャリオフィリ、シュードモナス・スタッチェリ等を用いることができる。
Here, as microorganisms belonging to the genus Nitrosomonas, nitrosomonas europaea and the like can be used.
As a microorganism belonging to the genus Nitrobacter, Nitrobacter aguiris can be used.
As a microorganism belonging to the genus Pseudomonas, Pseudomonas caryophili, Pseudomonas staccelli, or the like can be used.
枯草菌や納豆菌と、ニトロソモナス属、ニトロバクター属、シュードモナス属の内のいずれか１種以上の微生物とは、種々の割合で混合して用いることができるが、特に、枯草菌や納豆菌の合計１００重量部に対し、ニトロソモナス属等の微生物の合計の重量が、３０〜７０重量部の割合で混合して用いるのが好ましい。なお、枯草菌や納豆菌の合計１００重量部に対するニトロソモナス属等の微生物の合計の重量が、３０重量部より少なくなるにつれ窒素系の臭気が残留し易く、７０重量部より多くなるにつれタンパク質の腐敗臭等の臭気が残留し易くなる傾向がみられる。 Bacillus subtilis and Bacillus natto and any one or more microorganisms of the genus Nitrosomonas, Nitrobacter, and Pseudomonas can be used in a mixture at various ratios. It is preferable that the total weight of microorganisms such as nitrosomonas is mixed and used at a ratio of 30 to 70 parts by weight with respect to 100 parts by weight in total. As the total weight of microorganisms such as nitrosomonas relative to 100 parts by weight of Bacillus subtilis and Bacillus natto is less than 30 parts by weight, a nitrogenous odor tends to remain, and as the total weight of the microorganisms exceeds 70 parts by weight, There is a tendency for odors such as spoilage odor to remain.
本発明の請求項３に記載の発明は、請求項２に記載の消臭剤であって、前記枯草菌及び／又は納豆菌の合計量１００重量部に対し、前記微生物の合計量が３０〜７０重量部である構成を有している。
この構成により、請求項２で得られる作用に加え、以下のような作用が得られる。
（１）枯草菌や納豆菌の合計１００重量部に対するニトロソモナス属等の微生物の合計の重量が、３０重量部より少なくなるにつれ窒素系の臭気が残留し易く、７０重量部より多くなるにつれタンパク質の腐敗臭等の臭気が残留し易くなる傾向がみられるので、それを防ぐことができる。
Invention of Claim 3 of this invention is a deodorizer of Claim 2 , Comprising: The total amount of the said microorganisms is 30 to 30 weight part with respect to the total amount of said Bacillus subtilis and / or Bacillus natto. The structure is 70 parts by weight .
With this configuration, in addition to the operation obtained in the second aspect , the following operation can be obtained.
(1) As the total weight of microorganisms such as nitrosomonas relative to 100 parts by weight of Bacillus subtilis and Bacillus natto is less than 30 parts by weight, a nitrogenous odor tends to remain, and as it exceeds 70 parts by weight, protein There is a tendency that odors such as rotting odor remain, which can be prevented.
上記消臭剤を担持した担持部材を室内や建屋内等の悪臭源の近くの所定の空間や箇所に配置したり、担持部材で室内や建屋内等の悪臭が発生した所定の箇所を拭き取ることにより、悪臭の発生を抑制することができる。
また、上記担持部材を悪臭源の近くに配置しておくことにより、悪臭の発生を長期間防止することができる。
Or to place carrying member carrying the deodorant in the vicinity of a predetermined space and location of room or building in such offensive odor source, wiping the predetermined portion of malodor room or building in or the like occurs in the bearing member Therefore, generation of bad odor can be suppressed.
Further, by disposing the support member near the odor source, generation of odor can be prevented for a long time.
ここで、担持部材としては、木炭，竹炭，ゼオライト，発泡ウレタン等の多孔質体、紙，布等の繊維状体等が用いられる。これらの担持部材に消臭剤を含浸させて担持させ、用いることができる。 Here, as the support member, a porous body such as charcoal, bamboo charcoal, zeolite, and urethane foam, or a fibrous body such as paper or cloth is used. These supporting members can be used by impregnating them with a deodorant.
上記消臭剤を散布、塗布、噴霧等の手段によって悪臭源に接触させることにより、消臭剤を悪臭源に接触させることで高い消臭効果を得ることができるとともに、悪臭源の状態に応じて適宜の手段を選択して用いることができ汎用性に優れる。
また、枯草菌や納豆菌は水質浄化作用を有するため、浄化槽等に流れる水に接触させることにより水質浄化も行うことができ応用性に優れる。
By bringing the deodorant into contact with a malodorous source by means of spraying, coating, spraying, etc., a high deodorizing effect can be obtained by bringing the deodorant into contact with the malodorous source and depending on the state of the malodorous source. Therefore, an appropriate means can be selected and used, and the versatility is excellent.
In addition, Bacillus subtilis and Bacillus natto have a water purification effect, so that the water quality can be purified by bringing them into contact with the water flowing in the septic tank or the like, which is excellent in applicability.
ここで、消臭剤を悪臭源に接触させる手段としては、特に限定されるものではなく、例えば、スプレー等の散布装置や噴霧装置を用いて悪臭源に、若しくは悪臭源が存在すると考えられる場所に散布若しくは噴霧する手段、悪臭源に消臭剤を直接振りかける手段、消臭剤を担持した担持部材を悪臭源の近くの所定の空間や箇所に配置する手段、消臭剤を担持した担持部材で悪臭源を拭き取る手段等を用いることができる。 Here, the means for bringing the deodorant into contact with the malodorous source is not particularly limited. For example, a place where the malodorous source is present in the malodorous source using a spraying device such as a spray or a spraying device. Means for spraying or spraying on the odor, means for sprinkling the deodorant directly on the odor source, means for disposing the carrying member carrying the deodorant in a predetermined space or location near the odor source, carrying member carrying the deodorant A means for wiping off malodorous sources can be used.
悪臭源としては、特に限定する必要がなく多様な箇所で用いることができるが、例えば、生ゴミや食品工場等の廃棄物、魚介類等を扱う食品加工工場や商店、汚泥、ペット等動物の糞尿、動物の飼育場、トイレ、エアコン等に用いることができる。また、浄化槽等の水と接触する箇所に用いることにより、消臭と同時に水質浄化も行うことができる。 The odor source is not particularly limited and can be used in various places. For example, food processing factories and stores that handle food waste, seafood, etc. It can be used for manure, animal breeding grounds, toilets, air conditioners, etc. Moreover, water quality purification | cleaning can be performed simultaneously with deodorizing by using for the location which contacts water, such as a septic tank.
以上のように、本発明の消臭剤及びそれを用いた消臭体並びに消臭方法によれば、以下のような有利な効果が得られる。
請求項１に記載の発明によれば、
（１）水性溶媒に枯草菌や納豆菌とともに過酸化水素やオゾンを含有させているので、消臭剤を悪臭源に接触させた際に、過酸化水素等の作用で硫化水素，チオール類等の硫黄系臭気成分等と素早く反応しこれらを分解するので即効性に優れた消臭剤を提供することができる。
（２）悪臭源と接触した枯草菌や納豆菌が、発芽し増殖する際に悪臭源を分解したり変質させるので消臭効果の持続性にも優れた消臭剤を提供することができる。
（３）グラム陽性菌であり芽胞菌である枯草菌や納豆菌を用いているので、過酸化水素やオゾンが枯草菌や納豆菌へ作用する殺菌力が弱いため、水性溶媒中でこれらを死滅させることがなく、しかも枯草菌等を休眠状態に保つことができるので保存性に優れた消臭剤を提供することができる。
（４）枯草菌や納豆菌、過酸化水素やオゾンを用いているので、環境が破壊される等の悪影響が生じることがなく環境保全性に優れるとともに、食品工場等においても用いることができ汎用性に優れた消臭剤を提供することができる。
（５）枯草菌や納豆菌は水質浄化作用を有するため、工場等で用いられる浄化槽等に添加して消臭と同時に水質を浄化させることもでき応用性に優れた消臭剤を提供することができる。
（６）Ｍｇ 2+ ，Ｋ + 等を含有する苦汁を含有しているので、消臭剤が悪臭源に接触した際には、枯草菌や納豆菌が悪臭源に含まれる糖類やアミノ酸等の代謝可能な物質によって生理的発芽をして増殖していくとともに、水性溶媒に含有された非代謝物質であるＣａ 2+ ，Ｍｇ 2+ ，Ｋ + の金属イオンによって化学的発芽を引き起こさせて増殖させることができ、悪臭源に含まれる代謝物質と水性溶媒に含まれる非代謝物質との相乗効果によって、枯草菌等を飛躍的に増殖させ高い消臭効果を得ることができる消臭剤を提供することができる。
（７）水性溶媒がＣａ 2+ ，Ｍｇ 2+ ，Ｋ + の金属イオンの１種以上を０．５〜１００ｐｐｍの所定量含有しているので、保存中にオゾンや過酸化水素の一部が還元され酸化力がわずかに失われるため、オゾンや過酸化水素による枯草菌や納豆菌の生菌に対する殺菌力が低下し枯草菌や納豆菌を生菌の状態で長期間維持することができ保存性に優れた消臭剤を提供することができる。
（８）水性溶媒が所定量のアルコール類を含有しているので、悪臭源の内の枯草菌や納豆菌が未分解の残留タンパク質をアルコール類が凝固するとともにカビ類等を殺菌し消臭効果に優れた消臭剤を提供することができる。
（９）芽胞菌である枯草菌や納豆菌を用いているので、アルコール類が枯草菌や納豆菌へ作用する殺菌力が弱いため、水性溶媒中でこれらを死滅させることがなく、しかも枯草菌等を休眠状態に保つことができるので保存性に優れた消臭剤を提供することができる。
As described above, according to the deodorant of the present invention, the deodorant using the same, and the deodorization method, the following advantageous effects can be obtained.
According to the invention of claim 1,
(1) Since hydrogen peroxide and ozone are contained in an aqueous solvent together with Bacillus subtilis and Bacillus natto, hydrogen sulfide, thiols, etc. by the action of hydrogen peroxide, etc. when deodorant is brought into contact with a malodorous source Since it reacts quickly with the sulfur-based odor components of the product and decomposes them, it is possible to provide a deodorant excellent in immediate effect.
(2) Since Bacillus subtilis and Bacillus natto in contact with the malodorous source germinate and proliferate, the malodorous source is decomposed or altered, so that it is possible to provide a deodorant with excellent deodorizing effect.
(3) Gram-positive bacteria and spore bacteria Bacillus subtilis and Bacillus natto are used, so hydrogen peroxide and ozone are weak in the bactericidal activity acting on Bacillus subtilis and Bacillus natto. In addition, since Bacillus subtilis and the like can be kept dormant, a deodorant excellent in preservability can be provided.
(4) Since Bacillus subtilis, Bacillus natto, hydrogen peroxide, and ozone are used, there is no adverse effect such as destruction of the environment, it is excellent in environmental conservation, and it can be used in food factories etc. It is possible to provide a deodorant excellent in properties.
(5) Since Bacillus subtilis and Bacillus natto have a water purification effect, they can be added to septic tanks used in factories and the like to purify water simultaneously with deodorization and provide a deodorant with excellent applicability. Can do.
(6) Since it contains bitter juice containing Mg 2+ , K +, etc., when the deodorant comes in contact with the malodorous source, Bacillus subtilis or Bacillus natto, such as sugars and amino acids contained in the malodorous source Proliferates through physiological germination with metabolizable substances, and causes chemical germination by metal ions of Ca 2+ , Mg 2+ , K + , which are non-metabolites contained in an aqueous solvent. A deodorant that can dramatically increase the growth of Bacillus subtilis, etc., and achieve a high deodorizing effect by the synergistic effect of the metabolite contained in the malodorous source and the non-metabolite contained in the aqueous solvent. can do.
(7) Since the aqueous solvent contains one or more of Ca 2+ , Mg 2+ , and K + metal ions in a predetermined amount of 0.5 to 100 ppm, ozone or hydrogen peroxide is partially stored during storage. Because it is reduced and its oxidizing power is slightly lost, the bactericidal power of Bacillus subtilis and Bacillus natto by virtue of ozone and hydrogen peroxide is reduced, and Bacillus subtilis and Bacillus natto can be maintained in the state of viable bacteria for long periods of storage It is possible to provide a deodorant excellent in properties.
(8) Since the aqueous solvent contains a predetermined amount of alcohols, the alcohols coagulate the undegraded residual protein of Bacillus subtilis and Bacillus natto among the malodorous sources and sterilize the molds and deodorize them. It is possible to provide an excellent deodorant.
(9) Since Bacillus subtilis and Bacillus natto, which are spores, are used, the bactericidal power of alcohols acting on Bacillus subtilis and Bacillus natto is weak, so they are not killed in an aqueous solvent, and Bacillus subtilis Etc. can be kept in a dormant state, and thus a deodorant excellent in storage stability can be provided.
請求項２に記載の発明によれば、請求項１の効果に加え、
（１）ニトロソモナス属、ニトロバクター属、シュードモナス属の微生物は、悪臭源から発生するアンモニア等の窒素系臭気成分の分解に寄与するので、種々の種類の臭気を効果的に除去することができる消臭剤を提供することができる。
According to invention of Claim 2 , in addition to the effect of Claim 1 ,
(1) Nitrosomonas spp., Nitrobacter spp., Pseudomonas spp. Microorganisms contribute to the decomposition of nitrogenous odorous components such as ammonia generated from malodorous sources, so that various types of odors can be effectively removed. A deodorant can be provided.
請求項３に記載の発明によれば、請求項２の効果に加え、
（１）枯草菌や納豆菌の合計１００重量部に対するニトロソモナス属等の微生物の合計の重量が、３０重量部より少なくなるにつれ窒素系の臭気が残留し易く、７０重量部より多くなるにつれタンパク質の腐敗臭等の臭気が残留し易くなる傾向がみられるので、それを防ぐことができる。
According to invention of Claim 3 , in addition to the effect of Claim 2 ,
(1) As the total weight of microorganisms such as nitrosomonas relative to 100 parts by weight of Bacillus subtilis and Bacillus natto is less than 30 parts by weight, a nitrogenous odor tends to remain, and as it exceeds 70 parts by weight, protein There is a tendency that odors such as rotting odor remain, which can be prevented.
以下、本発明を実施例により具体的に説明する。なお、本発明はこれらの実施例に限定されるものではない。
（実施例１）
本実施例では、実験例１〜２２の消臭剤を調製し、これらの消臭剤について使用した直後の魚の餌箱（魚釣り用の餌を入れていた餌箱）に対する消臭効果を調べた。
消臭剤は、イオン交換水及びイソプロピルアルコール（日本薬局方）（以下、ＩＰＡという）を所定の割合で配合したものに、Ｃａ２＋，Ｍｇ２＋，Ｋ＋源としての苦汁と、枯草菌又は納豆菌が１×１０１５個／ｍＬの割合で水に含有された枯草菌液又は納豆菌液とを加え、これに所定量のオゾンを溶存させる又は過酸化水素を溶解させることで調製した。必要に応じて、ニトロソモナス属、ニトロバクター属、シュードモナス属の微生物が各々１×１０１５個／ｍＬの割合で水に含有されたニトロソモナス属微生物液（以下、Ｎ微生物液という）、ニトロバクター属微生物液（以下、Ｂ微生物液という）、シュードモナス属微生物液（以下、Ｓ微生物液という）も配合した。
なお、本実施例で用いた苦汁を消臭剤の全量１００重量部に対して０．１重量部配合した場合のＣａ２＋，Ｍｇ２＋，Ｋ＋の合計量は、分析の結果、９．１ｐｐｍであった。
実験例１〜２２の消臭剤について、各々の配合量（重量部）及びオゾンの溶存量（ｐｐｍ）を（表１）〜（表３）に示す。
Hereinafter, the present invention will be specifically described by way of examples. The present invention is not limited to these examples.
Example 1
In this example, the deodorizers of Experimental Examples 1 to 22 were prepared, and the deodorizing effect on the fish food box immediately after the use of these deodorizers (the bait box containing the fishing bait) was examined. .
The deodorant is a mixture of ion-exchanged water and isopropyl alcohol (Japanese Pharmacopoeia) (hereinafter referred to as IPA) in a predetermined ratio, bitter juice as a source of Ca 2+ , Mg 2+ , K + , Bacillus subtilis or natto It was prepared by adding a Bacillus subtilis solution or natto solution contained in water at a rate of 1 × 10 15 bacteria / mL, and dissolving a predetermined amount of ozone or dissolving hydrogen peroxide therein. Nitrosomonas genus liquid (hereinafter referred to as N microbial liquid), nitrosomonas genus, nitrobacter genus, Pseudomonas genus microorganisms contained in water at a rate of 1 × 10 15 / mL each, A genus microbial fluid (hereinafter referred to as B microbial fluid) and a Pseudomonas microbial fluid (hereinafter referred to as S microbial fluid) were also blended.
In addition, the total amount of Ca 2+ , Mg 2+ , and K + when 0.1 parts by weight of the bitter juice used in this example is blended with respect to 100 parts by weight of the deodorant is 9.1 ppm as a result of analysis. Met.
About the deodorizer of Experimental Examples 1-22, each compounding quantity (weight part) and the dissolved amount (ppm) of ozone are shown to (Table 1)-(Table 3).
（表１）〜（表３）のように配合された実験例１〜２２の消臭剤の１．２ｍＬを別々の魚の餌箱に噴霧し、臭気の強度を人による官能検査で調べた。この検査では、噴霧してから１０秒後、１分後、１０分後における臭気の強度を評価した。
その結果を（表４）〜（表６）に示す。なお、（表４）〜（表６）に示す臭気の強度は、以下のとおりである。「０」：無臭、「１」：やっと感知できる臭い、「２」：臭いの種類を判定できる程度、「３」：よく感知できる臭い、「４」：強い臭い、「５」：強烈な臭い。
なお、消臭剤を噴霧しなかった魚の餌箱の臭気の強度は、１０分後も「５」：強烈な臭いであった。
1.2 mL of the deodorizers of Experimental Examples 1 to 22 blended as shown in (Table 1) to (Table 3) were sprayed on separate fish food boxes, and the odor intensity was examined by human sensory test. In this test, the intensity of odor was evaluated 10 seconds, 1 minute and 10 minutes after spraying.
The results are shown in (Table 4) to (Table 6). In addition, the intensity | strength of the odor shown to (Table 4)-(Table 6) is as follows. “0”: no odor, “1”: odor that can be finally detected, “2”: odor can be judged, “3”: odor that can be detected well, “4”: strong odor, “5”: intense odor .
The odor intensity of the fish food box that was not sprayed with the deodorant was “5”: a strong odor even after 10 minutes.
（表１）及び（表４）に示すように、実験例１の消臭剤は、臭気の強度「５」のものが噴霧１０秒後に臭気の強度が「２」、１分後には「１」になったことから、非常に優れた消臭効果を有していることが明らかになった。実験例２の消臭剤は、１分後の臭気の強度が「２」であったが１０分後には「１」になった。実験例１に比べて苦汁の量が少ないため、枯草菌の増殖速度が緩慢だったため即効性が若干劣ったのではないかと推察している。
実験例３の消臭剤は、１０秒後の臭気の強度が「３」、１分後が「２」であったが１０分後には「１」になった。実験例１に比べて苦汁の量が多いため、オゾンの強力な酸化力が若干低下し即効性が若干劣ったのではないかと推察している。
実験例４の消臭剤は、１０秒後の臭気の強度が「３」、１分後が「２」であったが１０分後には「１」になった。実験例１に比べてオゾンの溶存量が少ないため、オゾンの強力な酸化力が小さく即効性が若干劣ったのではないかと推察している。
実験例５の消臭剤は、１０秒後の臭気の強度が「３」、１分後が「２」、１０分後も「２」であった。実験例１に比べてオゾンの量が多いため、オゾンの強力な酸化力により枯草菌の作用が低下し持続性が若干劣ったのではないかと推察している。
実験例６〜８の消臭剤は、臭気の強度が１０分後には「０」になった。実験例１の配合に加えニトロバクター属等の微生物が配合されているので、オゾンと枯草菌だけでは除去できなかった残臭を除去することができたのではないかと推察している。
As shown in (Table 1) and (Table 4), the deodorant of Experimental Example 1 has an odor intensity of “5”, the odor intensity is “2” after 10 seconds of spraying, and “1” after 1 minute. It became clear that it has a very excellent deodorizing effect. The deodorizer of Experimental Example 2 had an odor intensity of “2” after 1 minute, but became “1” after 10 minutes. Since the amount of bitter juice is small compared to Experimental Example 1, it is speculated that the immediate effect may be slightly inferior because the growth rate of Bacillus subtilis was slow.
The deodorizer of Experimental Example 3 had an odor intensity of “3” after 10 seconds and “2” after 1 minute, but became “1” after 10 minutes. Since the amount of bitter juice is larger than that of Experimental Example 1, it is presumed that the strong oxidizing power of ozone is slightly lowered and the immediate effect is slightly inferior.
The deodorant of Experimental Example 4 had an odor intensity of “3” after 10 seconds and “2” after 1 minute, but became “1” after 10 minutes. Since the dissolved amount of ozone is smaller than that of Experimental Example 1, it is presumed that the strong oxidizing power of ozone is small and the immediate effect is slightly inferior.
The deodorant of Experimental Example 5 had an odor intensity of “3” after 10 seconds, “2” after 1 minute, and “2” after 10 minutes. Since the amount of ozone is larger than that of Experimental Example 1, it is presumed that the action of Bacillus subtilis is reduced by the strong oxidizing power of ozone and the sustainability is slightly inferior.
In the deodorizers of Experimental Examples 6 to 8, the odor intensity became “0” after 10 minutes. Since microorganisms such as Nitrobacter are blended in addition to the blend of Experimental Example 1, it is presumed that the residual odor that could not be removed only by ozone and Bacillus subtilis could be removed.
（表２）及び（表５）に示すように、実験例９の消臭剤は、オゾンの代わりに過酸化水素を加えたものであるが、実験例１と同様の消臭効果が得られた。
実験例１０の消臭剤は、１０秒後の臭気の強度が「３」、１分後が「２」であったが１０分後には「１」になった。実験例９に比べて過酸化水素の量が少ないため、過酸化水素による酸化力が若干低下し即効性が若干劣ったのではないかと推察している。
実験例１１の消臭剤は、１０秒後の臭気の強度が「３」、１分後が「２」、１０分後も「２」であった。実験例９に比べて過酸化水素の量が多いため、過酸化水素の酸化力により枯草菌の作用が低下し持続性が若干劣ったのではないかと推察している。
実験例１２の消臭剤は、オゾンと過酸化水素を両方加えたものであるが、実験例１、実験例９と同様の消臭効果が得られた。
実験例１３、実験例１４の消臭剤は、枯草菌の代わりに納豆菌を加えたものであるが、実験例１、実験例９と同様の消臭効果が得られた。
As shown in (Table 2) and (Table 5), the deodorant of Experimental Example 9 is obtained by adding hydrogen peroxide instead of ozone, but the same deodorizing effect as in Experimental Example 1 is obtained. It was.
The deodorant of Experimental Example 10 had an odor intensity of “3” after 10 seconds and “2” after 1 minute, but became “1” after 10 minutes. Since the amount of hydrogen peroxide is smaller than that in Experimental Example 9, it is presumed that the oxidizing power by hydrogen peroxide is slightly lowered and the immediate effect is slightly inferior.
The deodorant of Experimental Example 11 had an odor intensity of “3” after 10 seconds, “2” after 1 minute, and “2” after 10 minutes. Since the amount of hydrogen peroxide is larger than that in Experimental Example 9, it is presumed that the action of Bacillus subtilis is reduced by the oxidizing power of hydrogen peroxide and the sustainability is slightly inferior.
Although the deodorizer of Experimental Example 12 was obtained by adding both ozone and hydrogen peroxide, the same deodorizing effect as in Experimental Example 1 and Experimental Example 9 was obtained.
The deodorizers of Experimental Examples 13 and 14 were obtained by adding Bacillus natto instead of Bacillus subtilis, but the same deodorizing effect as Experimental Examples 1 and 9 was obtained.
（表３）及び（表６）に示すように、実験例１５〜１８の消臭剤は、１０秒後の臭気の強度が「４」又は「３」であり、１０分後も「３」であった。実験例１５の消臭剤は実験例１に比べ苦汁の量が多くオゾンの強力な酸化力が低下し消臭効果が劣ったのではないかと推察している。実験例１６の消臭剤は実験例１に比べＩＰＡの量が少ないためタンパク質の凝固作用が小さく消臭効果が劣ったのではないかと推察している。実験例１７の消臭剤は実験例１に比べＩＰＡの量が多いためアルコール臭が強く、また枯草菌の増殖も緩慢だからであると推察している。実験例１８の消臭剤はオゾンの溶存量が多いため枯草菌の増殖に影響を与えたのではないかと推察している。
実験例１９の消臭剤は、１０秒後の臭気の強度が「４」であり、１０分後も「３」であった。実験例１０の消臭剤に比べさらに過酸化水素の量が少なく、過酸化水素による酸化力が低下し即効性が劣り、それに伴って枯草菌による消臭効果も目立たなかったのではないかと推察している。
実験例２０の消臭剤は、１０秒後の臭気の強度が「３」であり、１０分後もそのままであった。過酸化水素の量が多いため枯草菌の増殖に影響を与えたのではないかと推察している。
実験例２１の消臭剤は、オゾンも過酸化水素も加えていないため、オゾンや過酸化水素による酸化分解作用が得られず即効性が劣り、それに伴って枯草菌による消臭効果も目立たなかったのではないかと推察している。
実験例２２の消臭剤は、苦汁を加えていないため、オゾンによる即効性はみられたが、枯草菌の増殖速度が緩慢で消臭効果が劣ったのではないかと推察している。
以上のように本実施例によれば、本発明の消臭剤は、非常に優れた消臭効果を有していることが明らかになった。
As shown in (Table 3) and (Table 6), in the deodorizers of Experimental Examples 15 to 18, the odor intensity after 10 seconds is “4” or “3”, and “3” after 10 minutes. Met. It is speculated that the deodorant of Experimental Example 15 has a larger amount of bitter juice than that of Experimental Example 1 and the strong oxidative power of ozone is reduced, resulting in inferior deodorizing effect. It is speculated that the deodorant of Experimental Example 16 has a smaller amount of IPA than that of Experimental Example 1, and thus the protein coagulation action is small and the deodorizing effect is inferior. The deodorant of Experimental Example 17 is presumed to be because the amount of IPA is larger than that of Experimental Example 1, so that the alcohol odor is strong and the growth of Bacillus subtilis is also slow. The deodorant of Experimental Example 18 is presumed to have influenced the growth of Bacillus subtilis because of the large amount of dissolved ozone.
The deodorizer of Experimental Example 19 had an odor intensity of “4” after 10 seconds and “3” after 10 minutes. It is presumed that the amount of hydrogen peroxide is smaller than that of the deodorant of Experimental Example 10, the oxidizing power due to hydrogen peroxide is reduced and the immediate effect is inferior, and the deodorizing effect due to Bacillus subtilis is not conspicuous accordingly. is doing.
The deodorizer of Experimental Example 20 had an odor intensity of “3” after 10 seconds and remained as it was after 10 minutes. The amount of hydrogen peroxide is presumed to have influenced the growth of Bacillus subtilis.
Since the deodorizer of Experimental Example 21 contains neither ozone nor hydrogen peroxide, the oxidative decomposition action by ozone or hydrogen peroxide cannot be obtained, and the immediate effect is inferior, and the deodorizing effect by Bacillus subtilis is not conspicuous accordingly. I guess that it was.
Since the deodorant of Experimental Example 22 did not add bitter juice, an immediate effect by ozone was observed, but it was speculated that the growth rate of Bacillus subtilis was slow and the deodorizing effect was inferior.
As mentioned above, according to the present Example, it became clear that the deodorizer of this invention has the very outstanding deodorizing effect.
（実施例２）
灰皿内でもみ消した直後の煙草の吸殻に、実施例１で説明した実験例１の消臭剤０．３ｍＬを噴霧したところ、臭気の強度「５」のものが、噴霧１０秒後には臭気の強度が「１」、１分後には「０」になったことから、非常に優れた消臭効果を有していることが明らかになった。
また、自動車の室内の煙草の臭いも実験例１の消臭剤０．６ｍＬを噴霧したところ、１０分後には臭気の強度が「０」になった。
(Example 2)
When 0.3 mL of the deodorant of Experimental Example 1 described in Example 1 was sprayed on the cigarette butts immediately after being extinguished in the ashtray, the odor intensity of “5” had an odor of 10 seconds after spraying. Since the strength was “1” and “0” after 1 minute, it was revealed that the product had a very excellent deodorizing effect.
Further, when 0.6 mL of the deodorant of Experimental Example 1 was sprayed on the odor of the cigarette in the automobile, the odor intensity became “0” after 10 minutes.
（実施例３）
中型の猫の一食分の猫用ドライフードに、実施例１で説明した実験例１の消臭剤０．４５ｍＬを噴霧したところ、臭気の強度「５」のものが、噴霧１０秒後には臭気の強度が「２」、１分後には「１」、１０分後には「０」になった。
これらの実施例に示すように、多種多様な臭気に対して、本発明の消臭剤は優れた消臭効果を示すことが明らかになった。
(Example 3)
When 0.45 mL of the deodorant of Experimental Example 1 described in Example 1 was sprayed on a cat dry food for a medium-sized cat, the odor intensity of “5” was 10 seconds after spraying. The intensity was “2”, “1” after 1 minute, and “0” after 10 minutes.
As shown in these Examples, it was revealed that the deodorizer of the present invention exhibits an excellent deodorizing effect against a wide variety of odors.
本発明は、消臭剤及びそれを用いた消臭体並びに消臭方法に関し、悪臭源と接触した際に、硫黄系臭気成分等と素早く反応し分解するので即効性に優れるとともに悪臭源を分解したり変質させて消臭効果の持続性に優れ、さらに保存性に優れるとともに環境保全性にも優れた消臭剤を提供することができ、また、悪臭の発生を最小限にして長期間に渡り抑制することができる持続性に優れた消臭体を提供することができ、さらに、消臭剤を悪臭源に接触させることで高い消臭効果を得ることができるとともに、悪臭源の状態に応じて適宜の手段を選択して用いることができ汎用性に優れた消臭方法を提供することができる。 The present invention relates to a deodorant, a deodorant using the same, and a deodorization method, and when it comes into contact with a malodorous source, it reacts quickly with a sulfur-based odor component and decomposes so that it has excellent immediate effect and decomposes the malodorous source. Or denatured to provide a deodorant with excellent deodorizing effect, excellent storage stability and environmental conservation, and minimizes the generation of bad odors over a long period of time. It is possible to provide a deodorant body with excellent sustainability that can be suppressed, and to obtain a high deodorizing effect by bringing the deodorant into contact with a malodor source, and to the state of the malodor source. Accordingly, an appropriate means can be selected and used, and a deodorizing method excellent in versatility can be provided.
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| JP2008013512A (en) * | 2006-07-07 | 2008-01-24 | Bio Iryo Joho:Kk | Method for producing deodorant sterilizer |
| DE102007029970A1 (en) * | 2007-06-15 | 2008-12-18 | Lubing Maschinenfabrik Ludwig Bening Gmbh & Co. Kg | Process for the treatment of waste air from agricultural animal husbandry |
| US8211477B2 (en) | 2007-10-17 | 2012-07-03 | Biova, L.L.C. | Solubilized protein composition obtained from eggshell membrane |
| US8197852B2 (en) | 2007-10-17 | 2012-06-12 | Biova, L.L.C. | Process for solubilizing protein from a proteinaceous material and compositions thereof |
| JP2009154076A (en) * | 2007-12-26 | 2009-07-16 | Sk Holdings:Kk | Sustained-release ozone water, and method and device for producing the same |
| JP5261569B2 (en) * | 2011-12-22 | 2013-08-14 | 株式会社 Ｓｋホールディングス | Ozone water and its production equipment |
| JP6141063B2 (en) * | 2013-03-19 | 2017-06-07 | 創研株式会社 | Deodorizer, deodorizing apparatus and deodorizing method |
| CN103484402A (en) * | 2013-09-06 | 2014-01-01 | 广西壮族自治区水牛研究所 | Bacillus subtilis X3 and application thereof for reducing generation of hydrogen sulfide in buffalo dung |
| ES2712163T3 (en) * | 2014-08-25 | 2019-05-09 | Japan Env Science Company | Composition, support, wastewater treatment system, wastewater treatment method, deodorization method and discontinuous wastewater treatment method |
| CN106967640A (en) * | 2017-04-11 | 2017-07-21 | 上海莱泰生物科技有限公司 | A kind of preparation method of deodorizing microorganism microbial inoculum |
| JP2019017445A (en) * | 2017-07-12 | 2019-02-07 | クリーンアップ株式会社 | Control system |
| JP7150351B2 (en) * | 2020-06-09 | 2022-10-11 | 株式会社リスクベネフィット | How to decontaminate facilities where the virus may remain and/or how to reduce the risk of virus infection in facilities |
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