JP4321003B2 - Method for producing multilayer molded product - Google Patents

Method for producing multilayer molded product Download PDF

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Publication number
JP4321003B2
JP4321003B2 JP2002049323A JP2002049323A JP4321003B2 JP 4321003 B2 JP4321003 B2 JP 4321003B2 JP 2002049323 A JP2002049323 A JP 2002049323A JP 2002049323 A JP2002049323 A JP 2002049323A JP 4321003 B2 JP4321003 B2 JP 4321003B2
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skin material
mold
thermoplastic resin
cavity
male
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JP2003245934A5 (en
JP2003245934A (en
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由卓 小林
信裕 臼井
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Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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  • Instrument Panels (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)

Description

【0001】
【発明の属する技術分野】
本発明は熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に表皮材が部分的に貼合一体化され、かつ該表皮材貼合部が3次元形状を含む形状からなる多層成形品の製造方法に関する。
【0002】
【従来の技術】
熱可塑性樹脂からなる基材層に表皮材が貼合されてなる多層成形品は、その経済性、軽量性および良好な賦形性から、例えばドアトリムやインストルメントパネルなどの自動車内装部品や家電製品の内外装部品その他の広い分野で多く使用されている。
【0003】
このような多層成形品の代表例として、例えばドアトリムのように、熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に表皮材が部分的に貼合一体化され、かつ該表皮材貼合部が3次元形状を含む形状からなる多層成形品が知られているが、従来、このような多層成形品の製造方法としては表皮材貼合部と表皮材非貼合部とを別々に製造し、後工程で熱かしめなどの方法により両者を接合する方法が知られている。
【0004】
この方法は、表皮材貼合部と表皮材非貼合部との境界部が明瞭で製品外観に優れるという利点はあるが、工程数が多くなるうえに部分的な接合のために接合強度に劣るという問題があり、工業的な製造法として十分とはいえなかった。
【0005】
また、表皮材が部分的に貼合された多層成形品の他の製造方法として、開放状態にある金型間に表皮材を供給し、表皮材貼合部外周に相当する位置に設けた可動堰を型内に突出させた状態で、表皮材貼合部の基材部分に相当するだけの溶融状熱可塑性樹脂を供給してキャビティクリアランスが最終製品厚みになるまで型締めを行い、可動堰を型内に収容した後、キャビティクリアランスを保持しつつ残余の密閉状態のキャビティ空間に残余の溶融状熱可塑性樹脂を供給する方法が知られている。(特開平8−25407公報)。
【0006】
この方法は、表皮材貼合部分と非貼合部分との接合強度や非貼合部の外観に問題のない良好な成形品を低コストで得ることができるが、この方法を準用して例えばドアトリムのように縦壁部等の3次元形状を有する多層成形品を製造する場合には、表皮材の位置決めが困難であり、図1に示すように表皮材の位置ずれが生じて表皮材貼合部と表皮材非貼合部との境界部が不明瞭となって製品外観に劣るという問題がある。
【0007】
【発明が解決しようとする課題】
このようなことから、本発明者らは熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に表皮材が部分的に貼合一体化され、かつ該表皮材貼合部が3次元形状を含む形状からなる多層成形品を、表皮材貼合部と表皮材非貼合部との境界部が明瞭で製品外観に優れるとともに、機械的強度にも優れ、かつ低コストで工業的にも容易に製造するための方法を開発すべく検討を行なった結果、本発明に至った。
【0008】
【課題を解決するための手段】
すなわち本発明は、雌雄いずれか一方の金型のキャビティ内の表皮材貼合部と非貼合部の境界部に対応する位置に突出可能な可動堰を設けた雌雄一対の金型を使用して、熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に表皮材が部分的に貼合一体化され、かつ該表皮材貼合部が3次元形状を含む形状からなる多層成形品を製造する方法であって、
1)雌雄両金型を型締めした時に、キャビティ面の形状に沿った状態で、表皮材が基材表面の外周部の少なくとも一部を覆い、かつ該表皮材の基材内部に収まる端末部が基材表面における表皮材貼合部と非貼合部の境界部の形状と一致するような形状に表皮材を予め裁断する工程。
2)開放状態にある雌雄両金型間の所定の位置に前記表皮材を供給する工程。
3)雌雄両金型を型締めして、表皮材をキャビティ面の形状に沿わせる工程
4)可動堰をキャビティ内に突出させ、その先端部で表皮材の基材内部に収まる端末部を金型面に押さえつける工程。
5)表皮材を雌雄いずれかの一方の金型面に押さえつけた状態を維持しながら、最終製品厚みよりも大きいキャビティクリアランスとなるまで雌雄金型を開く工程。
6)表皮材と非表皮材側の金型面との間のキャビティに、全溶融状熱可塑性樹脂量のうち、表皮材が貼合される基材部を形成するに必要な樹脂量の溶融状熱可塑性樹脂を供給する工程。
7)前記溶融状熱可塑性樹脂を供給後あるいは供給しながら最終製品厚みとなるまで型締めする工程。
8)金型内で熱可塑性樹脂を1次冷却する工程。
9)可動堰を金型内に収容する工程。
10)キャビティクリアランスを保持しつつ、残余のキャビティ内に残余の溶融状熱可塑性樹脂を供給する工程。
11)金型内で熱可塑性樹脂を2次冷却する工程。
12)金型を開放状態にして成形体を取り出す工程。
からなる多層成形品の製造方法を提供するものである。
【0009】
【発明の実施の形態】
以下、本発明を図面に基づいて詳細に説明する。
尚、以下の説明は本発明の一例であり、本発明がこの例に限定されるものではないことはいうまでもない。
【0010】
図2は本発明の方法により製造される多層成形品の一例であるドアトリム(1)を平面図で示したものであり、熱可塑性樹脂からなる基材(2)の表面の外周部(13)の一部(図面では上端側の全部)に表皮材(3)が部分的に貼合一体化されており、他の部分は熱可塑性樹脂からなる基材(2)の表面がそのまま意匠面となっている。
図3は本発明の方法により製造される他のドアトリムの例を示している。
この例においては、熱可塑性樹脂からなる基材(2)の表面の外周部(13)の一部に表皮材(3)が部分的に貼合一体化されている。
これらの例において、図示するドアトリムの表皮材が貼合された外周部(図では上端側)は、図面では明確に示されていないが、その立体的意匠のために3次元構造となっている。
【0011】
このように、本発明の製造方法は、表皮材が熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に部分的に貼合一体化され、かつ、該表皮材貼合部が3次元形状を含む形状からなる多層成形品をその対象とするが、表皮材の貼合部位としては基材の外周部のみに限られず、表皮材(3)が熱可塑性樹脂からなる基材(2)表面の外周部(13)の少なくとも一部を含んで貼合一体化されているとともに、別の表皮材(3’)が基材(2)の外周部とは別の位置に貼合一体化されていてもよく、例えば、他の表皮材(3’)が図4のように外周部(13)の一部を含んで貼合一体化されている表皮材(3)と接していてもよいし、図5のように独立して貼合されていてもよい。
【0012】
図6は本発明の方法で使用する金型例の概略断面図であり、雄型(4)および雌型(5)の雌雄一対からなり、雌雄いずれか一方の金型、この例では、製品の非意匠面に対応する雄型(4)の表皮材貼合部と非貼合部の境界部に相当する位置に可動堰(8)が設けられており、この可動堰(8)は油圧シリンダー等(9)により金型開閉方向に突出、収容可能な構造となっている。
【0013】
また、雄型(4)の成形面には溶融状熱可塑性樹脂を供給するための溶融樹脂供給口(7A、7B)が設けられており、溶融樹脂供給通路(6)を通じてキャビティ内に溶融状熱可塑性樹脂が供給される。
この溶融樹脂供給口(7A、7B)の設置場所は製品形状や大きさにより適宜決定されるが、表皮材が貼合される場所に対応する金型部分と表皮材が貼合されない金型部分のそれぞれに少なくとも1ヶ所ずつ設けることが必要であり、その数はそれぞれ1つでも複数でもよい。
【0014】
また、この例では、表皮材が貼合される場所に対応する金型部分に供給される熱可塑性樹脂と表皮材が貼合されない金型部分に供給される熱可塑性樹脂溶融が同一である場合を示しているために、一つの溶融樹脂通路がそれぞれの溶融樹脂供給口(7A、7B)に分岐する構造となっているが、供給する熱可塑性樹脂が表皮材貼合部と非貼合部とで異なる場合には、それぞれの溶融樹脂供給口に対応して独立した溶融樹脂通路を設ければよい。
【0015】
尚、本発明の方法を有効に実施するためには、表皮材を金型にセットしたのち型締めを行う際に、表皮材に適度なテンションが加わる状態として、しわが入ることなく金型キャビティ形状に沿わせることが必要となるが、そのために、この例では、雄型(4)の金型外周部に表皮材端部をクランプするためのクランプ枠(10)が設けられている。
【0016】
かかるクランプ枠により、表皮材を雌雄金型間に供給する際にその端部を固定し、また、型締め時には表皮材を雄型(4)と雌型(5)との間に挟み込み、表皮材に適度な張力を加えることができる。
この表皮材クランプ枠(10)はエアーシリンダー等(11)に連結され、雌雄金型の型締め時に雌型(5)の位置と連動して型締め方向に動作するようになっている。
【0017】
図7は、表皮材クランプ枠(10)の設置状況を示すための、図6の金型から雌型部分を除いた金型部分の平面概略図であり、雄型(4)の成形面の金型外周部の一部に表皮材クランプ枠(10)が設けられている。
この表皮材クランプ枠(10)は、表皮材貼合部に対応する金型外周部に沿って、表皮材端部が固定されるように設けられる。
【0018】
尚、上記で説明した金型は、雌雄両金型が上下方向(縦方向)に開閉するいわゆる縦型の例を示したが、金型の開閉方向は何ら上下方向に限定されず、水平方向(横方向)に開閉するいわゆる横型であっても何ら差し支えない。
【0019】
以下、この金型を用いて、多層成形品の具体的な製造例を説明する。
図8は、図2に示す形状の多層成形品を製造する例において、雌雄金型間に表皮材(3)を供給したところの金型断面概略図を、図9は図7に対応してそのときの表皮材の供給状態を平面概略図で示したものである。
【0020】
表皮材(3)は雄型(4)の表皮材貼合部に相当する部分に対応するように載置され、その外周端部は雄型(4)の外周部に設けたクランプ枠(10)にかかるように載置してピン等(図示せず)により位置決めし、固定される。
【0021】
この時、供給する表皮材(3)は、表皮材の外周端部をクランプ枠等で固定した状態で雌雄両金型を型締めした時に、キャビティ面の形状に沿った状態で、表皮材が基材表面の外周部の少なくとも一部を覆い、かつ該表皮材の基材内部側端部(基材内部に収まる端部)(14)が基材表面における表皮材貼合部と非貼合部の境界部の形状と一致するような形状に、型締め時の表皮材の引き込まれ量を予め見込んだ状態で裁断しておいたものを供給することが重要であり、この裁断が不十分であると外観の良好な多層成形品が得られない。
この際、表皮材の種類によっては供給に先立って予備加熱を行い、型締め時に金型キャビティ形状に沿い易いようにしておいてもよい。
【0022】
上記のように、予め裁断した表皮材を開放状態にある雌雄両金型間の所定の位置に供給した後、雌雄両金型を型締めする。(図10)
型締めにより表皮材(3)は金型キャビティ面の形状に沿った状態となり、固定を行なっていない表皮材の基材内部側端部(14)は基材の3次元形状に対応する金型成形面の形状に沿いながら、その表皮材外周端部が固定されている金型外周部側に引込まれ、成形後の貼合部/非貼合部の境界部に相当する位置に移動する。
【0023】
この時の型締め量は通常、表皮材が雌雄両金型の成形面に接触する位置まで行なえばよい。
尚、図10は上記の型締め終了後の状態をわかり易くするために、型締め後に若干金型をその後に開いた状態で示している。
【0024】
型締めにより、表皮材を金型キャビティ面の形状に沿わせた状態で可動堰(8)を油圧シリンダー(9)によりキャビティ内に突出させ、可動堰の先端部で表皮材の基材内部側端部(14)を雌型(5)成形面との間に押し付けて固定する(図11)。
この可動堰は金型の開閉方向に自在に動作し、かつ金型の開閉方向と連動することが可能な構造となっている。
【0025】
ついで、表皮材の基材内部側端部を可動堰(8)と雌型(5)成形面との間に押し付けて固定した状態を保持しながら雄雌金型を開く。(図12)
これにより、キャビティ空間を形成しながら表皮材が金型キャビティ形状に概略沿った状態で配置される。
【0026】
この時の型開きは最終製品厚みよりも大きいキャビティクリアランスまで開放されるが、具体的には使用する表皮材の種類や厚み、その後に供給される熱可塑性樹脂の種類や性質などの応じて適宜決定される。
【0027】
次いで、表皮材が貼合される場所に相当するキャビティすなわち表皮材と非表皮材の金型面との間のキャビティに、溶融樹脂供給口(7A)から溶融樹脂供給通路(6)を通じ、全溶融状熱可塑性樹脂量の内の表皮材が貼合される基材部を形成するに必要な樹脂量の溶融状熱可塑性樹脂(12)を供給する(図13)。
【0028】
その後、キャビティクリアランスが最終製品厚みとなるまで型締めし、キャビティ内に充填する(図14)。
このとき、可動堰(8)は表皮材の基材内部側端部(14)を介して雌型(5)に突き当てた状態であるため、該可動堰が仕切り壁となって、型締めを行なっても供給された溶融状熱可塑性樹脂(12)は表皮材貼合部に相当するキャビティ内のみを流動し、表皮材の貼合されない基材部に対応する隣接のキャビティ内に樹脂がはみ出すことはない。
【0029】
前記溶融状熱可塑性樹脂(12)の供給および型締めのタイミングは、使用する表皮材の種類や厚み、熱可塑性樹脂の種類、樹脂温度等の成形条件に応じて適宜決定され、例えば樹脂供給開始のタイミングは図12の型開き後に樹脂供給開始してもよいし、型開き完了前に樹脂供給を開始してもよい。また、型締め開始のタイミングも樹脂供給の完了後に型締めを開始してもよいし、樹脂供給完了前に型締めを開始してもよい。
【0030】
型締め完了後、キャビティクリアランスを維持しつつ、表皮材貼合部に相当するキャビティ内に供給、充填された熱可塑性樹脂を冷却、固化させる。
この冷却は、供給した溶融状熱可塑性樹脂の温度よりも低く、通常30〜80℃程度に設定、保持された金型温度との差を利用し、所定時間型締め状態を維持することにより行われる。
【0031】
前記熱可塑性樹脂が冷却、固化した後、可動堰(8)を雄型(4)内に収容する(図15)。
可動堰(8)を雄型(4)内に収容するタイミングは前記熱可塑性樹脂が冷却、固化した後に収容することが必要であるが、熱可塑性樹脂全体が完全に固化している必要はなく、可動堰を収容した際に前記熱可塑性樹脂が表皮材を貼合していない側のキャビティ空間にはみ出さない程度に表面のみが固化している状態であってもよい。
【0032】
可動堰(8)を金型内に収納後、キャビティクリアランスを維持しながら、表皮材が貼合されない残余の閉鎖されたキャビティ空間に溶融状熱可塑性樹脂(12)を樹脂供給口(7B)より供給する(図16)
このとき、キャビティクリアランスは最終製品厚みに保たれた状態で供給を行なうことが必要であるが、供給した溶融状熱可塑性樹脂(12)が表皮材を貼合した側の製品表面にはみ出さない限り、溶融樹脂供給圧力によって雌雄両金型のクリアランスが若干開いて広くなっても構わない。
この表皮材が貼合されていない側のキャビティ内に供給する熱可塑性樹脂は、通常表皮材を貼合する部位に供給した熱可塑性樹脂と同一であるが、別の異なった溶融状熱可塑性樹脂であってもよい。
【0033】
熱可塑性樹脂の供給が完了し、キャビティ内に充填されると、充填した溶融状熱可塑性樹脂を冷却(2次冷却)し、固化させる。(図17)
その後、雌雄金型を開放し、製品を金型から取り出すことにより、表皮材が貼合された熱可塑性樹脂基材部と表皮材が貼合されない熱可塑性樹脂基材部とが基材部の端面同士で強固に融着一体化し、しかも部分的に貼合された表皮材の基材内部側端部が所定の位置に収まった、表皮材端縁の位置ずれのない外観の良好な多層成形品を得ることができる。
【0034】
以上、基材部が発泡していない多層成形品の製造法について述べたが、表皮材を貼合する部分の基材部が発泡した部分発泡の多層成形品についても先に述べたと基本的に同様の方法により製造することもできる。
【0035】
以下、このような表皮材を貼合する部分の基材部が発泡した部分発泡の多層成形品を製造する方法について説明する。
この場合には、表皮材貼合部の基材部を形成させるための熱可塑性樹脂として、発泡剤含有の熱可塑性樹脂を使用すること以外は、前記説明における図8〜図14までの工程と基本的に同一である。従って、図14に示す溶融状熱可塑性樹脂がキャビティ内に充填された状態において、充填された溶融状熱可塑性樹脂は発泡剤を含有している状態にある。
【0036】
発泡剤を含有する溶融状熱可塑性樹脂を表皮材貼合部の発泡基材部に対応するキャビティ内に供給し、型締めにより該キャビティ内に発泡剤含有の溶融状熱可塑性樹脂が充填された図14の状態で一次冷却を行い、金型キャビティ面に接する溶融状熱可塑性樹脂にスキン層を形成させる。
この時の一次冷却時間は金型温度や溶融状熱可塑性樹脂の温度、特性等の条件により異なるが、通常0.1から5秒程度である。
冷却時間が長すぎるとスキン層が肥大し、キャビティ内の溶融状熱可塑性樹脂が固化しすぎて、次工程における発泡が十分に行われない。
【0037】
所定のスキン層が形成された後、金型キャビティを成形体の厚み方向に拡大すると、キャビティ内に充填されていた溶融状熱可塑性樹脂の未固化部分に閉じ込められていた発泡剤の分解により発生した発泡ガスが膨張し、成形体の厚み方向に発泡層を形成しながら厚みを増す。
キャビティクリアランスが発泡後の製品厚みになった時点で金型の拡大動作を停止し、キャビティクリアランスを保持しつつ冷却を行なう。(図18)
【0038】
このときの冷却時間は、金型温度や溶融状熱可塑性樹脂の温度、特性等の条件により適宜決定されるが、短過ぎると十分に固化していないため、その後の工程において、隣接するキャビティ内に供給される発泡剤非含有の溶融状熱可塑性樹脂が発泡層内に入り込んだり、表皮材の基材内部側端部の位置ズレ等を生じ、外観不良となる虞がある。
また、冷却時間が長すぎると発泡層側の温度低下が大きくなり、この後供給される溶融状熱可塑性樹脂との接着強度が不十分となる虞がある。このため通常は3〜30秒程度、好ましくは5〜20秒程度である。
【0039】
発泡、冷却工程終了後、金型キャビティ内に突出していた可動堰(8)を雄型内に収容し、表皮材が貼合されない基材部に対応する残余のキャビティ空間に溶融状熱可塑性樹脂(12)を射出、供給し、キャビティ内に充填する。(図19)
このとき、キャビティクリアランスは最終製品厚みに保たれた状態で供給を行なうことが必要であるが、供給した溶融状熱可塑性樹脂(12)が表皮材を貼合した側の表皮材表面にはみ出さない限り、溶融樹脂の供給圧力によって雌雄金型のクリアランスが若干開いて広くなっても構わない。
【0040】
この表皮材が貼合されない基材部に対応する残余のキャビティ空間に供給する熱可塑性樹脂は、表皮材を貼合する基材部に対応するキャビティに先に供給した発泡剤を含有した熱可塑性樹脂と同一であっても構わないが、通常は、発泡剤を含有しない溶融状熱可塑性樹脂が供給される。
【0041】
熱可塑性樹脂の供給が完了し、キャビティ内に充填されると、充填した溶融状熱可塑性樹脂を冷却(2次冷却)し、固化させる。(図20)
その後、雌雄金型を開放し、製品を金型から取り出すことにより、表皮材が貼合された発泡した熱可塑性樹脂基材部と表皮材が貼合されない熱可塑性樹脂基材部とが基材部の端面同士で強固に融着一体化し、しかも部分的に貼合された表皮材の基材内部側端部が所定の位置に収まった、表皮材端縁の位置ずれのない外観の良好な、表皮材が貼合された基材部が部分的に発泡した多層成形品を得ることができる。
【0042】
このような方法により得られる多層成形品において、表皮材を貼合した基材部と表皮材を貼合しない基材部分の境界部の形状は図21(a)に示すような平面状であってもよいが、図21(b)のA部に示すような凹形状にすることで境界部の外観をより好ましくすることができる。
【0043】
このような凹形状にするためには、上記雌型成形面の境界部に対応する位置に凹部の形状に対応する突起物を設け、可動堰(8)の先端部を表皮材の最先端部を巻き込んで該突起物と嵌合するような形状にしておけばよい。
【0044】
本発明の方法に適用される熱可塑性樹脂としては、圧縮成形、射出成形、押出成形などで通常使用される樹脂がそのまま適用され。特に限定されないが、このような樹脂としては、たとえばポリプロピレン、ポリエチレン、アクリロニトリルースチレンーブタジエンブロック共重合体、ポリスチレン、ナイロンなどのポリアミド、ポリ塩化ビニル、ポリカーボネート、アクリル樹脂、スチレンーブタジエンブロック共重合体などの一般的な熱可塑性樹脂、EPMやEPDMなどの熱可塑性エラストマー、これらの混合物、あるいはこれらを用いたポリマーアロイ等があげられ、本発明においてはこれらを総称して熱可塑性樹脂という。
【0045】
また、これらの熱可塑性樹脂には必要に応じて、通常使用されるガラス繊維などの強化繊維や各種の無機もしくは有機フィラーなどの充填材が含有されていてもよく、もちろん通常使用される各種の顔料、滑材、帯電防止剤、安定剤などの各種添加材が配合されていてもよい。
【0046】
また、表皮材が貼合される基材部を発泡した基材部とするために、熱可塑性樹脂中に配合される発泡剤としては、熱可塑性樹脂の発泡体を製造する際に使用されている公知の化学発泡剤を使用することができる。具体的には、重炭酸ナトリウム、重炭酸アンモニウム、炭酸アンモニウム等の無機系発泡剤、N,N’−ジニトロソペンタメチレンテトラミン等のニトロソ化合物、アゾジカルボンアミド、アゾビスイソブチロニトリル等のアゾ化合物、ベンゼンスルホニルヒドラジド、トルエンスルホニルヒドラジド、ジフェニルスルホン−3,3’−ジスルホニルヒドラジド等のスルホニルヒドラジド類、p−トルエンスルホニルセミカルバジド等の発泡剤が例示され、必要に応じてサリチル酸、尿素ならびにこれらを含む発泡助剤を添加することは好適な態様である。
【0047】
発泡剤の種類は使用する熱可塑性樹脂の溶融温度や目的とする発泡倍率等を考慮して選択される。またその添加量は、目的とする成形品の強度、密度等を考慮して調整されるが、一般的に樹脂100重量部に対して0.1〜5重量部である。また、化学発泡剤に代えて液状またはガス状の二酸化炭素および/または窒素等を直接溶融樹脂中に圧入してもよく、場合によってはこれらを併用してもよい。
【0048】
また、本発明の方法に適用される表皮材も特に限定されず、モケットやトリコット等の織物や編み物、ニードルパンチカーペット等の不織布、金属フォイル、熱可塑性樹脂や熱可塑性エラストマーのシートまたはフィルムがあげられる。
【0049】
これらの表皮材は必要に応じて発泡層や裏打ち層が適宜積層された2層あるいは3層以上とした積層表皮材であってもよく、特に発泡層を積層した表皮材が好ましく適用できる。
発泡層が積層された表皮材を使用する場合、その発泡層としてはポリプロピレンやポリエチレンなどのポリオレフィンの発泡体や、ポリ塩化ビニル発泡体、軟質あるいは半硬質のポリウレタン発泡体が用いられる。
【0050】
また、裏打ち層としては、不織布や合成樹脂シートやフィルムなどが用いられ、不織布を構成する繊維としては、綿、毛、絹、麻等の天然繊維あるいはポリアミド、ポリエステル、ナイロン等の合成繊維が使用でき、これらを単独であるいは混紡して種々の方法により不織布としたものが用いられる。例えばニードルパンチ式、サーマルボンド式、スパンボンド式、メルトブロー式、スパンレース式等の不織布があげられる。
【0051】
尚、これらの積層表皮材を使用する場合、基材部と接触する表皮材裏面は、該表皮材が積層される基材部を形成する熱可塑性樹脂と熱融着可能なもの、あるいは表皮材裏面に該熱可塑性樹脂が含浸して基材樹脂部分と接着可能なものであることが必要である。
【0052】
【発明の効果】
本発明の製造方法によれば、熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に表皮材が部分的に貼合一体化され、かつ該表皮材貼合部が3次元形状を含む形状からなる多層成形品を、表皮材貼合部と表皮材非貼合部との境界部が明瞭で製品外観に優れるとともに、機械的強度にも優れ、かつ低コストで工業的にも容易に製造することができる。
【図面の簡単な説明】
【図1】従来法により製造された多層成形品の一例を平面図で示したものである。
【図2】本発明の方法により製造された多層成形品の一例を平面図で示したものである。
【図3】本発明の方法により製造された多層成形品の他の一例を平面図で示したものである。
【図4】本発明の方法により製造された多層成形品の他の一例を平面図で示したものである。
【図5】本発明の方法により製造された多層成形品の他の一例を平面図で示したものである。
【図6】本発明の方法に使用する金型の一例を概略断面図で示したものである。
【図7】図6の金型において、雄型成形面およびクランプ枠の配置状況を平面概略図で示したものである。
【図8】本発明の製造工程において、予め裁断された表皮材を金型間に供給した状態を金型の断面概略図で示したものである。
【図9】図8における表皮材の供給状態を平面概略図で示したものである。
【図10】本発明の製造工程を金型の断面概略図で示したものである。
【図11】本発明の製造工程を金型の断面概略図で示したものである。
【図12】本発明の製造工程を金型の断面概略図で示したものである。
【図13】本発明の製造工程を金型の断面概略図で示したものである。
【図14】本発明の製造工程を金型の断面概略図で示したものである。
【図15】本発明の製造工程を金型の断面概略図で示したものである。
【図16】本発明の製造工程を金型の断面概略図で示したものである。
【図17】本発明の製造工程を金型の断面概略図で示したものである。
【図18】本発明の製造工程を金型の断面概略図で示したものである。
【図19】本発明の製造工程を金型の断面概略図で示したものである。
【図20】本発明の製造工程を金型の断面概略図で示したものである。
【図21】本発明の方法により製造された多層成形品の表皮材貼合部と非貼合部の境界部付近の断面例を示したものである。
【符号の説明】
1:多層成形品
2:熱可塑性樹脂
3:表皮材
4:雄型
5:雌型
6:溶融樹脂供給通路
7:溶融樹脂供給口
8:可動堰
9:油圧シリンダー
10:表皮材クランプ枠
11:エアーシリンダー
12:溶融状熱可塑性樹脂
13:基材外周部
14:表皮材の基材内部側端部
[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a multilayer molded article in which a skin material is partially bonded and integrated to at least a part of the outer peripheral portion of a base material surface made of a thermoplastic resin, and the skin material bonded portion has a shape including a three-dimensional shape. It relates to the manufacturing method.
[0002]
[Prior art]
Multi-layer molded products in which a skin material is bonded to a base material layer made of a thermoplastic resin are used for automobile interior parts such as door trims and instrument panels, and home appliances because of their economical efficiency, light weight, and good formability. Is widely used in a wide range of other interior and exterior parts.
[0003]
As a typical example of such a multilayer molded article, a skin material is partially bonded and integrated to at least a part of the outer peripheral portion of a base material surface made of a thermoplastic resin, such as a door trim. A multilayer molded article having a shape including a three-dimensional shape is known. Conventionally, as a method for producing such a multilayer molded article, a skin material bonding part and a skin material non-bonding part are separately provided. A method of manufacturing and joining them by a method such as heat caulking in a subsequent process is known.
[0004]
This method has the advantage that the boundary between the skin material bonding part and the skin material non-bonding part is clear and excellent in the appearance of the product, but the number of processes is increased and the bonding strength is increased due to partial bonding. There was a problem of being inferior, and it was not sufficient as an industrial production method.
[0005]
In addition, as another method for producing a multilayer molded article in which the skin material is partially bonded, the skin material is supplied between molds in an open state, and the movable material provided at a position corresponding to the outer periphery of the skin material bonding portion With the weir protruding into the mold, supply molten thermoplastic resin equivalent to the base material part of the skin material bonding part, and mold clamping until the cavity clearance reaches the final product thickness. A method of supplying the remaining molten thermoplastic resin to the remaining sealed cavity space while holding the cavity clearance is known. (JP-A-8-25407).
[0006]
This method can obtain a good molded product having no problem in the bonding strength between the skin material bonding part and the non-bonding part and the appearance of the non-bonding part at low cost. When manufacturing a multilayer molded product having a three-dimensional shape such as a vertical wall portion such as a door trim, it is difficult to position the skin material, and as shown in FIG. There is a problem that the boundary portion between the joint portion and the non-sealable portion is unclear and the product appearance is inferior.
[0007]
[Problems to be solved by the invention]
For these reasons, the present inventors have integrated and integrated the skin material partially on at least a part of the outer peripheral portion of the base material surface made of thermoplastic resin, and the skin material bonding portion has a three-dimensional shape. Multi-layer molded products with a shape that includes a clear boundary between the skin material bonding part and the skin material non-bonding part, excellent product appearance, excellent mechanical strength, and low cost As a result of studies to develop a method for easy production, the present invention has been achieved.
[0008]
[Means for Solving the Problems]
That is, the present invention uses a pair of male and female molds provided with movable weirs that can project at positions corresponding to the boundary portions between the skin material bonding part and the non-bonding part in the cavity of one of the male and female molds. A multilayer molded article in which the skin material is partially bonded and integrated with at least a part of the outer peripheral portion of the surface of the base material made of thermoplastic resin, and the skin material bonded portion has a shape including a three-dimensional shape. A method of manufacturing comprising:
1) A terminal portion in which the skin material covers at least a part of the outer peripheral portion of the surface of the base material and fits inside the base material of the skin material in a state along the shape of the cavity surface when both the male and female molds are clamped Cutting the skin material in advance into a shape that matches the shape of the boundary portion between the skin material bonding portion and the non-bonding portion on the substrate surface.
2) A step of supplying the skin material to a predetermined position between the male and female molds in the open state.
3) Clamping both male and female molds to make the skin material conform to the shape of the cavity surface
4) A step of causing the movable weir to protrude into the cavity and pressing the end portion of the movable dam inside the base material of the skin material against the mold surface.
5) A step of opening the male and female molds until the cavity clearance is larger than the final product thickness while maintaining the state in which the skin material is pressed against one of the male and female mold surfaces.
6) Melting of the amount of resin necessary to form the base material portion to which the skin material is bonded, out of the total molten thermoplastic resin amount, in the cavity between the skin material and the non-skin material side mold surface Supplying a thermoplastic resin.
7) A step of clamping the mold until the final product thickness is obtained after or while supplying the molten thermoplastic resin.
8) A step of primarily cooling the thermoplastic resin in the mold.
9) The process of accommodating a movable weir in a metal mold | die.
10) A step of supplying the remaining molten thermoplastic resin into the remaining cavity while maintaining the cavity clearance.
11) A step of secondary cooling of the thermoplastic resin in the mold.
12) A step of removing the molded body with the mold open.
The manufacturing method of the multilayer molded article which consists of is provided.
[0009]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, the present invention will be described in detail with reference to the drawings.
In addition, the following description is an example of this invention, and it cannot be overemphasized that this invention is not limited to this example.
[0010]
FIG. 2 is a plan view showing a door trim (1) which is an example of a multilayer molded article manufactured by the method of the present invention. The outer peripheral portion (13) on the surface of a base material (2) made of a thermoplastic resin. Part (all on the upper end side in the drawing) is partially bonded and integrated with the surface material (3), and the surface of the base material (2) made of thermoplastic resin is the design surface. It has become.
FIG. 3 shows an example of another door trim manufactured by the method of the present invention.
In this example, the skin material (3) is partially bonded and integrated to a part of the outer peripheral portion (13) on the surface of the base material (2) made of a thermoplastic resin.
In these examples, the outer peripheral portion (upper end side in the drawing) to which the cover material of the door trim shown in the figure is bonded is not clearly shown in the drawing, but has a three-dimensional structure for its three-dimensional design. .
[0011]
Thus, in the production method of the present invention, the skin material is partially bonded and integrated to at least a part of the outer peripheral portion of the substrate surface made of the thermoplastic resin, and the skin material bonding portion is three-dimensional. The target is a multilayer molded article having a shape including a shape, but the skin material is not limited to the outer peripheral portion of the base material, and the base material (2) is made of the thermoplastic material (3). It is bonded and integrated including at least a part of the outer peripheral part (13) of the surface, and another skin material (3 ′) is bonded and integrated at a position different from the outer peripheral part of the base material (2). For example, even if another skin material (3 ′) is in contact with the skin material (3) bonded and integrated including part of the outer peripheral portion (13) as shown in FIG. Alternatively, they may be bonded independently as shown in FIG.
[0012]
FIG. 6 is a schematic cross-sectional view of an example of a mold used in the method of the present invention, which is composed of a male and female pair of male mold (4) and female mold (5). A movable weir (8) is provided at a position corresponding to the boundary between the skin material bonding portion and the non-bonding portion of the male mold (4) corresponding to the non-design surface. It has a structure that can be projected and housed in the mold opening and closing direction by a cylinder or the like (9).
[0013]
Further, the molding surface of the male mold (4) is provided with molten resin supply ports (7A, 7B) for supplying molten thermoplastic resin, and is melted into the cavity through the molten resin supply passage (6). A thermoplastic resin is supplied.
The location of the molten resin supply port (7A, 7B) is appropriately determined depending on the product shape and size, but the mold portion corresponding to the location where the skin material is pasted and the mold portion where the skin material is not pasted It is necessary to provide at least one place for each of the two, and the number thereof may be one or more.
[0014]
Also, in this example, when the thermoplastic resin supplied to the mold part corresponding to the place where the skin material is bonded and the thermoplastic resin melt supplied to the mold part where the skin material is not bonded are the same In order to show the structure, one molten resin passage has a structure branched to each molten resin supply port (7A, 7B), but the thermoplastic resin to be supplied is a skin material bonding portion and a non-bonding portion. If different from each other, an independent molten resin passage may be provided corresponding to each molten resin supply port.
[0015]
In order to effectively carry out the method of the present invention, when the skin material is set in a mold and then clamped, a mold cavity is formed without wrinkles so that an appropriate tension is applied to the skin material. For this purpose, a clamp frame (10) for clamping the end of the skin material is provided on the outer periphery of the mold of the male mold (4).
[0016]
With such a clamp frame, the end portion is fixed when the skin material is supplied between the male and female molds, and the skin material is sandwiched between the male mold (4) and the female mold (5) when clamping the mold. Appropriate tension can be applied to the material.
The skin material clamp frame (10) is connected to an air cylinder or the like (11) and operates in the mold clamping direction in conjunction with the position of the female mold (5) when the male and female molds are clamped.
[0017]
FIG. 7 is a schematic plan view of a mold part obtained by removing the female part from the mold of FIG. 6 to show the installation state of the skin material clamp frame (10), and shows the molding surface of the male mold (4). A skin material clamp frame (10) is provided on a part of the outer periphery of the mold.
The skin material clamp frame (10) is provided so that the skin material end is fixed along the outer periphery of the mold corresponding to the skin material bonding portion.
[0018]
In addition, although the metal mold | die demonstrated above showed the example of what is called a vertical type in which both male and female metal molds open and close (vertical direction), the opening and closing direction of a metal mold | die is not limited to an up-down direction at all, and a horizontal direction There is no problem even if it is a so-called horizontal type that opens and closes in the (horizontal direction).
[0019]
Hereinafter, a specific production example of a multilayer molded product will be described using this mold.
FIG. 8 is a schematic cross-sectional view of a mold where the skin material (3) is supplied between the male and female molds in the example of manufacturing the multilayer molded article having the shape shown in FIG. 2, and FIG. 9 corresponds to FIG. The supply state of the skin material at that time is shown by a schematic plan view.
[0020]
The skin material (3) is placed so as to correspond to the portion corresponding to the skin material bonding portion of the male mold (4), and its outer peripheral end is a clamp frame (10 provided on the outer peripheral portion of the male mold (4). ) And is positioned and fixed by pins or the like (not shown).
[0021]
At this time, the skin material (3) to be supplied is in a state in which the skin material conforms to the shape of the cavity surface when the male and female molds are clamped with the outer peripheral edge of the skin material fixed with a clamp frame or the like. Covers at least a part of the outer peripheral portion of the surface of the base material, and the end portion on the inner side of the base material (end that fits inside the base material) (14) is not bonded to the skin material bonding portion on the base material surface It is important to supply the shape that matches the shape of the boundary part of the part, with the cut material being cut in advance with the expected amount of skin material being clamped. If it is, a multilayer molded article having a good appearance cannot be obtained.
At this time, depending on the type of the skin material, preheating may be performed prior to supply so that the mold cavity shape can be easily aligned during mold clamping.
[0022]
As described above, after the skin material cut in advance is supplied to a predetermined position between the male and female molds in an open state, the male and female molds are clamped. (Fig. 10)
By the mold clamping, the skin material (3) is in a state along the shape of the mold cavity surface, and the base material inner side end portion (14) of the skin material not fixed is a mold corresponding to the three-dimensional shape of the base material. While being along the shape of the molding surface, the outer peripheral edge of the skin material is drawn into the outer peripheral part of the mold, and moves to a position corresponding to the boundary between the bonded part / non-bonded part after molding.
[0023]
The mold clamping amount at this time may be usually performed up to a position where the skin material contacts the molding surface of both the male and female molds.
Note that FIG. 10 shows a state where the mold is slightly opened after the mold clamping in order to make it easy to understand the condition after the mold clamping is completed.
[0024]
By clamping the mold, the movable weir (8) is protruded into the cavity by the hydraulic cylinder (9) with the skin material conforming to the shape of the mold cavity surface. The end (14) is pressed and fixed between the female mold (5) and the molding surface (FIG. 11).
This movable weir has a structure that can freely move in the opening and closing direction of the mold and interlock with the opening and closing direction of the mold.
[0025]
Next, the male and female molds are opened while maintaining the state in which the inner end of the base material of the skin material is pressed and fixed between the movable weir (8) and the female mold (5) molding surface. (Fig. 12)
Thereby, the skin material is arranged in a state substantially along the shape of the mold cavity while forming the cavity space.
[0026]
The mold opening at this time is opened up to a cavity clearance larger than the final product thickness, but specifically, depending on the type and thickness of the skin material to be used, the type and properties of the thermoplastic resin supplied thereafter, etc. It is determined.
[0027]
Next, through the molten resin supply passage (6) from the molten resin supply port (7A) to the cavity corresponding to the place where the skin material is bonded, that is, the cavity between the skin material and the non-skin material mold surface, A molten thermoplastic resin (12) having a resin amount necessary for forming a base material portion to which the skin material of the molten thermoplastic resin amount is bonded is supplied (FIG. 13).
[0028]
Thereafter, the mold is clamped until the cavity clearance reaches the final product thickness, and the cavity is filled (FIG. 14).
At this time, since the movable weir (8) is in contact with the female mold (5) via the inner end (14) of the base material of the skin material, the movable weir becomes a partition wall, and the mold is clamped. The molten thermoplastic resin (12) that is supplied flows only in the cavity corresponding to the skin material bonding portion, and the resin is placed in the adjacent cavity corresponding to the base material portion to which the skin material is not bonded. It does not protrude.
[0029]
The supply timing and mold clamping timing of the molten thermoplastic resin (12) are appropriately determined according to the molding conditions such as the type and thickness of the skin material to be used, the type of the thermoplastic resin, the resin temperature, etc. In this timing, the resin supply may be started after the mold opening shown in FIG. 12, or the resin supply may be started before the mold opening is completed. In addition, the mold clamping may be started after the resin supply is completed, or the mold clamping may be started before the resin supply is completed.
[0030]
After completion of mold clamping, the thermoplastic resin supplied and filled in the cavity corresponding to the skin material bonding portion is cooled and solidified while maintaining the cavity clearance.
This cooling is performed by maintaining the mold clamping state for a predetermined time by using the difference from the mold temperature which is lower than the temperature of the supplied molten thermoplastic resin and is usually set to about 30 to 80 ° C. and held. Is called.
[0031]
After the thermoplastic resin is cooled and solidified, the movable weir (8) is accommodated in the male mold (4) (FIG. 15).
The timing of accommodating the movable weir (8) in the male mold (4) needs to be accommodated after the thermoplastic resin has cooled and solidified, but the entire thermoplastic resin need not be completely solidified. When the movable weir is accommodated, only the surface may be solidified so that the thermoplastic resin does not protrude into the cavity space on the side where the skin material is not bonded.
[0032]
After the movable weir (8) is stored in the mold, the molten thermoplastic resin (12) is fed from the resin supply port (7B) into the remaining closed cavity space where the skin material is not bonded while maintaining the cavity clearance. Supply (Fig. 16)
At this time, it is necessary to supply the cavity clearance while maintaining the final product thickness, but the supplied molten thermoplastic resin (12) does not protrude from the surface of the product on which the skin material is bonded. As long as the molten resin supply pressure is used, the clearance between the male and female dies may be slightly widened and widened.
The thermoplastic resin supplied into the cavity on the side where the skin material is not bonded is the same as the thermoplastic resin supplied to the portion where the skin material is normally bonded, but another different molten thermoplastic resin. It may be.
[0033]
When the supply of the thermoplastic resin is completed and the cavity is filled, the filled molten thermoplastic resin is cooled (secondary cooling) and solidified. (Fig. 17)
Thereafter, the male and female molds are opened, and the product is removed from the mold, so that the thermoplastic resin base material portion to which the skin material is bonded and the thermoplastic resin base material portion to which the skin material is not bonded are the base material portions. Multi-layer molding with excellent appearance with no misalignment of the edge of the skin material, which is firmly fused and integrated between the end faces, and the inner end of the base material of the skin material that has been partially bonded is in place. Goods can be obtained.
[0034]
As mentioned above, although the manufacturing method of the multilayer molded product in which the base material portion is not foamed has been described, it is basically said that the partially foamed multilayer molded product in which the base material portion of the portion to which the skin material is bonded is foamed is also described above. It can also be produced by a similar method.
[0035]
Hereinafter, a method for producing a partially-foamed multilayer molded product in which the base material portion of the portion to which the skin material is bonded is foamed will be described.
In this case, as the thermoplastic resin for forming the base material portion of the skin material bonding portion, the steps from FIG. 8 to FIG. 14 in the above description, except that a foaming agent-containing thermoplastic resin is used. Basically the same. Therefore, in the state in which the molten thermoplastic resin shown in FIG. 14 is filled in the cavity, the filled molten thermoplastic resin is in a state containing a foaming agent.
[0036]
The molten thermoplastic resin containing the foaming agent was supplied into the cavity corresponding to the foam base material part of the skin material bonding part, and the melted thermoplastic resin containing the foaming agent was filled into the cavity by mold clamping In the state of FIG. 14, primary cooling is performed to form a skin layer on the molten thermoplastic resin in contact with the mold cavity surface.
The primary cooling time at this time varies depending on conditions such as the mold temperature, the temperature of the molten thermoplastic resin, and characteristics, but is usually about 0.1 to 5 seconds.
If the cooling time is too long, the skin layer is enlarged, and the molten thermoplastic resin in the cavity is too solid, and foaming in the next step is not sufficiently performed.
[0037]
After the predetermined skin layer is formed, when the mold cavity is expanded in the thickness direction of the molded body, it is generated by decomposition of the foaming agent confined in the unsolidified portion of the molten thermoplastic resin filled in the cavity The foamed gas expands and increases the thickness while forming a foam layer in the thickness direction of the molded body.
When the cavity clearance reaches the product thickness after foaming, the die expansion operation is stopped, and cooling is performed while maintaining the cavity clearance. (Fig. 18)
[0038]
The cooling time at this time is appropriately determined depending on conditions such as the mold temperature, the temperature of the molten thermoplastic resin, and the characteristics, but if it is too short, it is not sufficiently solidified. There is a possibility that the molten thermoplastic resin containing no foaming agent supplied into the inside of the foam enters the foamed layer, or the positional deviation of the inner end of the base material of the skin material occurs, resulting in poor appearance.
On the other hand, if the cooling time is too long, the temperature drop on the foamed layer side becomes large, and the adhesive strength with the molten thermoplastic resin supplied thereafter may be insufficient. For this reason, it is usually about 3 to 30 seconds, preferably about 5 to 20 seconds.
[0039]
After completion of the foaming and cooling process, the movable weir (8) protruding into the mold cavity is accommodated in the male mold, and the molten thermoplastic resin is filled in the remaining cavity space corresponding to the base material portion to which the skin material is not bonded. (12) is injected, supplied, and filled into the cavity. (Fig. 19)
At this time, it is necessary to supply the cavity clearance while maintaining the final product thickness, but the supplied molten thermoplastic resin (12) does not protrude from the surface of the skin material on the side where the skin material is bonded. Unless otherwise, the clearance between the male and female molds may be slightly widened and widened by the supply pressure of the molten resin.
[0040]
The thermoplastic resin supplied to the remaining cavity space corresponding to the base material portion to which the skin material is not bonded is a thermoplastic resin containing the foaming agent previously supplied to the cavity corresponding to the base material portion to which the skin material is bonded. Although it may be the same as the resin, usually a molten thermoplastic resin containing no foaming agent is supplied.
[0041]
When the supply of the thermoplastic resin is completed and the cavity is filled, the filled molten thermoplastic resin is cooled (secondary cooling) and solidified. (Fig. 20)
Thereafter, the male and female molds are opened, and the product is taken out of the mold, whereby the foamed thermoplastic resin base material portion to which the skin material is bonded and the thermoplastic resin base material portion to which the skin material is not bonded are the base materials. The outer surface of the base material inside the base material of the skin material, which is firmly fused and integrated between the end faces of the parts, is located in a predetermined position, and the outer appearance of the outer edge of the skin material is good. A multilayer molded article in which the base material portion to which the skin material is bonded is partially foamed can be obtained.
[0042]
In the multilayer molded product obtained by such a method, the shape of the boundary portion between the base material portion bonded with the skin material and the base material portion not bonded with the skin material is a flat shape as shown in FIG. However, the appearance of the boundary portion can be made more preferable by forming a concave shape as shown in part A of FIG.
[0043]
In order to make such a concave shape, a protrusion corresponding to the shape of the concave portion is provided at a position corresponding to the boundary portion of the female molding surface, and the distal end portion of the movable weir (8) is the most advanced portion of the skin material. It is sufficient to make it so as to be fitted with the protrusions.
[0044]
As the thermoplastic resin applied to the method of the present invention, resins usually used in compression molding, injection molding, extrusion molding and the like are applied as they are. Although not particularly limited, examples of such resins include polypropylene, polyethylene, acrylonitrile-styrene-butadiene block copolymers, polyamides such as polystyrene and nylon, polyvinyl chloride, polycarbonate, acrylic resins, and styrene-butadiene block copolymers. General thermoplastic resins such as EPM, EPDM and other thermoplastic elastomers, mixtures thereof, polymer alloys using these, and the like are collectively referred to as thermoplastic resins in the present invention.
[0045]
In addition, these thermoplastic resins may contain reinforcing fibers such as glass fibers that are usually used and fillers such as various inorganic or organic fillers, if necessary. Various additives such as pigments, lubricants, antistatic agents and stabilizers may be blended.
[0046]
Moreover, in order to make the base material part to which a skin material is bonded into a foamed base material part, as a foaming agent blended in the thermoplastic resin, it is used when producing a thermoplastic resin foam. Known chemical blowing agents can be used. Specifically, inorganic foaming agents such as sodium bicarbonate, ammonium bicarbonate and ammonium carbonate, nitroso compounds such as N, N'-dinitrosopentamethylenetetramine, azodicarbonamide, azo such as azobisisobutyronitrile Compounds, benzenesulfonyl hydrazide, toluenesulfonyl hydrazide, sulfonyl hydrazides such as diphenylsulfone-3,3′-disulfonyl hydrazide, and blowing agents such as p-toluenesulfonyl semicarbazide are exemplified. If necessary, salicylic acid, urea and these It is a preferred embodiment to add a foaming aid containing.
[0047]
The type of the foaming agent is selected in consideration of the melting temperature of the thermoplastic resin to be used, the target foaming ratio, and the like. The amount added is adjusted in consideration of the strength, density and the like of the target molded product, but is generally 0.1 to 5 parts by weight with respect to 100 parts by weight of the resin. Further, in place of the chemical foaming agent, liquid or gaseous carbon dioxide and / or nitrogen may be directly injected into the molten resin, and in some cases, these may be used in combination.
[0048]
Further, the skin material applied to the method of the present invention is not particularly limited, and examples thereof include woven fabrics and knitted fabrics such as moquettes and tricots, nonwoven fabrics such as needle punch carpets, metal foils, sheets and films of thermoplastic resins and thermoplastic elastomers. It is done.
[0049]
These skin materials may be laminated skin materials having two layers or three or more layers in which foam layers and backing layers are appropriately laminated as required. Particularly, skin materials in which foam layers are laminated are preferably applied.
When a skin material in which a foam layer is laminated is used, a polyolefin foam such as polypropylene or polyethylene, a polyvinyl chloride foam, a soft or semi-rigid polyurethane foam is used as the foam layer.
[0050]
In addition, non-woven fabrics, synthetic resin sheets, and films are used as the backing layer, and natural fibers such as cotton, wool, silk, and linen, or synthetic fibers such as polyamide, polyester, and nylon are used as the fibers constituting the non-woven fabric. These can be used alone or in combination to produce nonwoven fabrics by various methods. For example, non-woven fabrics such as a needle punch type, a thermal bond type, a spun bond type, a melt blow type, and a spun lace type are listed.
[0051]
When these laminated skin materials are used, the back surface of the skin material that comes into contact with the base material portion can be heat-sealable with the thermoplastic resin that forms the base material portion on which the skin material is laminated, or the skin material. It is necessary that the thermoplastic resin is impregnated on the back surface and can be adhered to the base resin portion.
[0052]
【The invention's effect】
According to the manufacturing method of the present invention, the skin material is partially bonded and integrated to at least a part of the outer peripheral portion of the base material surface made of the thermoplastic resin, and the skin material bonding portion includes a three-dimensional shape. A multilayer molded product consisting of shapes has a clear boundary between the skin material bonding part and the skin material non-bonding part, excellent product appearance, excellent mechanical strength, and low cost and easy industrialization. Can be manufactured.
[Brief description of the drawings]
FIG. 1 is a plan view showing an example of a multilayer molded product manufactured by a conventional method.
FIG. 2 is a plan view showing an example of a multilayer molded article produced by the method of the present invention.
FIG. 3 is a plan view showing another example of a multilayer molded article produced by the method of the present invention.
FIG. 4 is a plan view showing another example of a multilayer molded article produced by the method of the present invention.
FIG. 5 is a plan view showing another example of a multilayer molded article produced by the method of the present invention.
FIG. 6 is a schematic sectional view showing an example of a mold used in the method of the present invention.
FIG. 7 is a schematic plan view showing the arrangement of the male molding surface and the clamp frame in the mold of FIG. 6;
FIG. 8 is a schematic cross-sectional view of a mold showing a state in which a skin material cut in advance is supplied between molds in the manufacturing process of the present invention.
FIG. 9 is a schematic plan view showing a state of supplying the skin material in FIG.
FIG. 10 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 11 is a schematic cross-sectional view of a mold showing the manufacturing process of the present invention.
FIG. 12 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 13 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 14 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 15 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 16 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 17 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 18 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 19 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 20 is a schematic sectional view of a mold showing the manufacturing process of the present invention.
FIG. 21 shows an example of a cross section in the vicinity of a boundary portion between a skin material bonding portion and a non-bonding portion of a multilayer molded product manufactured by the method of the present invention.
[Explanation of symbols]
1: Multilayer molded product
2: Thermoplastic resin
3: Skin material
4: Male type
5: Female type
6: Molten resin supply passage
7: Molten resin supply port
8: Movable weir
9: Hydraulic cylinder
10: Skin material clamp frame
11: Air cylinder
12: Molten thermoplastic resin
13: Substrate outer periphery
14: End portion of inner side of skin material

Claims (4)

雌雄いずれか一方の金型のキャビティ内の表皮材貼合部と非貼合部の境界部に対応する位置に突出可能な可動堰を設けた雌雄一対の金型を使用して、熱可塑性樹脂からなる基材表面の外周部の少なくとも一部に表皮材が部分的に貼合一体化され、かつ該表皮材貼合部が3次元形状を含む形状からなる多層成形品を製造する方法であって、
1)前記金型を型締めした時に、キャビティ面の形状に沿った状態で、表皮材が基材表面の外周部の少なくとも一部を覆い、かつ該表皮材の基材内部に収まる端末部が基材表面における表皮材貼合部と非貼合部の境界部の形状と一致するような形状に表皮材を予め裁断する工程と、
2)開放状態にある前記金型間の所定の位置に前記表皮材を供給する工程と、
3)前記雌雄両金型を、前記表皮材が前記雌雄両金型の前記キャビティ面に接触する位置まで型締めして、前記表皮材をキャビティ面の形状に沿わせ、密着させる工程と、
4)前記可動堰をキャビティ内に突出させ、前記可動堰の先端部で前記表皮材の基材内部に収まる端末部を、雌雄いずれかの一方の金型のキャビティ面に押さえつける工程と、
5)前記表皮材を前記キャビティ面に押さえつけた状態を維持しながら、最終製品厚みよりも大きいキャビティクリアランスとなるまで前記金型を開く工程と、
6)前記表皮材と非表皮材側のキャビティ面との間に、全溶融状熱可塑性樹脂量のうち、表皮材が貼合される基材部を形成するに必要な樹脂量の溶融状熱可塑性樹脂を供給する工程と、
7)前記溶融状熱可塑性樹脂を供給後あるいは供給しながら最終製品厚みとなるまで型締めする工程と、
8)前記キャビティ内で熱可塑性樹脂を1次冷却する工程と、
9)前記可動堰を金型内に収容する工程と、
10)前記可動堰を金型内に収容後、キャビティクリアランスを保持しつつ、残余のキャビティ内に残余の溶融状熱可塑性樹脂を供給する工程と、
11)金型内で熱可塑性樹脂を2次冷却する工程と、
12)金型を開放状態にして成形体を取り出す工程と、
からなることを特徴とする多層成形品の製造方法。
Thermoplastic resin using a pair of male and female molds provided with a movable weir that can protrude at a position corresponding to the boundary between the skin material bonding part and the non-bonding part in the cavity of either mold The skin material is partially bonded and integrated with at least a part of the outer peripheral portion of the substrate surface, and the skin material bonded portion is a method for producing a multilayer molded article having a shape including a three-dimensional shape. And
1) When the mold is clamped, in a state along the shape of the cavity surface, the skin material covers at least a part of the outer peripheral portion of the surface of the base material, and a terminal portion that fits inside the base material of the skin material A step of cutting the skin material in advance into a shape that matches the shape of the boundary portion between the skin material bonding portion and the non-bonding portion on the substrate surface,
2) supplying the skin material to a predetermined position between the molds in an open state;
3) clamping the male and female molds to a position where the skin material comes into contact with the cavity surface of the male and female molds, causing the skin material to conform to the shape of the cavity surface, and closely contacting ;
4) projecting the movable weir into the cavity, and pressing the end portion of the movable weir at the tip of the inner surface of the skin material against the cavity surface of one of the male and female molds;
5) opening the mold until the cavity clearance is larger than the final product thickness while maintaining the state where the skin material is pressed against the cavity surface;
6) Between the skin material and the cavity surface on the non-skin material side, out of the total molten thermoplastic resin amount, the molten heat of the resin amount necessary to form the base material portion to which the skin material is bonded. Supplying a plastic resin;
7) A step of clamping until the final product thickness is reached after or while supplying the molten thermoplastic resin;
8) a step of primarily cooling the thermoplastic resin in the cavity;
9) accommodating the movable weir in a mold;
10) supplying the remaining molten thermoplastic resin into the remaining cavity while holding the cavity clearance after the movable weir is housed in the mold ;
11 ) secondary cooling of the thermoplastic resin in the mold;
12 ) taking out the molded body with the mold open,
A method for producing a multilayer molded article comprising the steps of:
前記表皮材として、発泡層を有する表皮材を用いることを特徴とする請求項1に記載の多層成形品の製造方法。  The method for producing a multilayer molded article according to claim 1, wherein a skin material having a foam layer is used as the skin material. 前記工程8)における一次冷却の後、前記雌雄両金型を僅かに開いて熱可塑性樹脂を発泡させる工程を含むことを特徴とする請求項1又は2に記載の多層成形品の製造方法。 3. The method for producing a multilayer molded article according to claim 1 , further comprising a step of foaming the thermoplastic resin by slightly opening both the male and female molds after the primary cooling in the step 8). 多層成形品が自動車内装部品であることを特徴とする請求項1からいずれかに記載の多層成形品の製造方法。The method for producing a multilayer molded article according to any one of claims 1 to 3, wherein the multilayer molded article is an automobile interior part.
JP2002049323A 2002-02-26 2002-02-26 Method for producing multilayer molded product Expired - Fee Related JP4321003B2 (en)

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KR20180118317A (en) * 2017-04-21 2018-10-31 (주)엘지하우시스 Method for manufacturing vehicle parts

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JP2007083898A (en) * 2005-09-22 2007-04-05 Kasai Kogyo Co Ltd Automobile interior component
JP6725832B2 (en) * 2016-03-07 2020-07-22 テイ・エス テック株式会社 Molding method

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20180118317A (en) * 2017-04-21 2018-10-31 (주)엘지하우시스 Method for manufacturing vehicle parts
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