JP4288927B2

JP4288927B2 - Multistage thermoelectric module

Info

Publication number: JP4288927B2
Application number: JP2002321876A
Authority: JP
Inventors: 敬久橘
Original assignee: Yamaha Corp
Current assignee: Yamaha Corp
Priority date: 2002-11-05
Filing date: 2002-11-05
Publication date: 2009-07-01
Anticipated expiration: 2022-11-05
Also published as: JP2004158582A

Description

【０００１】
【発明の属する技術分野】
本発明は、ペルチェ効果を持つ熱電素子対を絶縁基板間に配置した熱電モジュールを、熱流が一方向になるように多段に積み重ねて構成された多段熱電モジュールに関する。
【０００２】
【従来の技術】
熱エネルギーを電気エネルギーに変換したり、逆に電気エネルギーを供給することにより熱エネルギーを移動し冷却作用を及ぼしたりする熱電材料として、ＢｉＴｅ系の半導体が良好な熱電性能を有する熱電材料として利用されている。特に、この半導体の持つ熱電効果の１種であるペルチェ効果を利用した電子冷却素子及びゼーベック効果を利用した熱電素子は、構造が簡単で小型化及び軽量化が容易であること並びに無音及び無振動でメンテナンスも不要であることから、特殊な用途向けの小型冷蔵庫及び半導体レーザ等の半導体装置内部の温度調整器への適用等、広範囲に利用できる可能性がある。
【０００３】
このようなペルチェ効果を利用した電子冷却及びゼーベック効果を利用した熱電発電に用いる熱電モジュールは、多段型のモジュール構造に組み立てられて使用されるものがある。例えば、図５に示すような２段型熱電モジュール１００においては、第１段ｎ型熱電素子１０１ｎと第１段ｐ型熱電素子１０１ｐとが交互に隣り合わせて配置され、上部電極１０３ｄ及び下部電極１０３ｅを介して直列接続され、中段絶縁基板１０４ｍと下側絶縁基板１０４ｈとで挟まれて１段目熱電変換部１０５を形成している。同様に、第２段ｎ型熱電素子１０２ｎと第２段ｐ型熱電素子１０２ｐとが交互に隣り合わせて配置され、上部電極１０３ａ及び下部電極１０３ｂを介して直列接続され、上側絶縁基板１０４ｃと中段絶縁基板１０４ｍとで挟まれて２段目熱電変換部１０６を形成している。また、中段絶縁基板１０４ｍの一部には貫通孔１０７が形成されており、この貫通孔１０７の内周壁には導電性被膜１０８が塗布されている。この導電性被膜１０８は、１段目熱電変換部１０５における第１段ｎ型熱電素子１０１ｎに接合された上部電極１０３ｄと２段目熱電変換部１０６における第２段ｐ型熱電素子１０２ｐに接合された下部電極１０３ｂとに接続され、これらの１段目熱電変換部１０５の第１段ｎ型熱電素子１０１ｎと２段目熱電変換部１０６の第２段ｐ型熱電素子１０２ｐとを電気的に直列接続している。このようにして構成される従来の２段型熱電モジュール１００においては、これらの各段の熱電素子に通電することによって、各熱電素子が各段の吸熱側でペルチェ吸熱すると共に各段の放熱側でペルチェ放熱し、例えば、吸熱側の最外側となる上側絶縁基板１０４ｃから放熱側の最外側となる下側絶縁基板１０４ｈに向けて一方向に熱が流れる。中段絶縁基板１０４ｍは、１段目熱電変換部１０５の吸熱側絶縁基板であり、且つ、２段目熱電変換部１０６の放熱側絶縁基板でもある。
【０００４】
このような従来の２段型熱電モジュール１００に通電すると、例えば、１段目熱電変換部１０５に配置された第１段ｎ型熱電素子１０１ｎ及び第１段ｐ型熱電素子１０１ｐに電流が流れる。これらのｎ型及びｐ型の熱電素子１０１ｎ，１０１ｐは、ペルチェ効果によって、吸熱側となる中段絶縁基板１０４ｍ側で吸熱すると共に、放熱側となる下側絶縁基板１０４ｈで放熱する。この電流は、更に、中段絶縁基板１０４ｍに設けられた貫通孔１０７内周壁に形成された導電性被膜１０８を介して第１段ｎ型熱電素子１０１ｎから第２段ｎ型熱電素子１０２ｎに流れる。そうすると、２段目熱電変換部１０６に配置された第２段ｐ型熱電素子１０２ｐ及び第２段ｎ型熱電素子１０２ｎにも順次交互に電流が流れ、２段目熱電変換部１０６においても、１段目熱電変換部１０５と同様に、ペルチェ効果によって、吸熱側となる上側絶縁基板１０４ｃ側で吸熱すると共に、放熱側となる中段絶縁基板１０４ｍ側で放熱する。この従来の多段熱電モジュール１００においては、貫通孔１０７内周壁に形成された導電性被膜１０８を介して各段の熱電素子同士を電気的に接続することによって、リード線等で各段の熱電素子同士を接続する場合と比較して、よりコンパクトで信頼性が高い多段熱電モジュールを構成している（例えば、特許文献１参照。）。
【０００５】
【特許文献１】
特開平１０−１９００７１号公報（第１頁、第４図）
【０００６】
【発明が解決しようとする課題】
しかしながら、このような従来の多段熱電モジュール１００において、より高密度に熱電素子を設置するために、例えば、図６に示すように、１段目熱電変換部１０５に配置された第１段ｎ型熱電素子１０１ｎの直上に第２段ｎ型熱電素子１０２ｎを配置し、これらの第１段ｎ型熱電素子１０１ｎと第２段ｎ型熱電素子１０２ｎとの間に位置する中段絶縁基板１０４ｍに貫通孔１０７を設けて、この貫通孔１０７内周壁に形成された導電性被膜１０８を、第１段ｎ型熱電素子１０１ｎとはんだ１１０ｄを介して接合された上部電極１０３ｄ及び第２段ｎ型熱電素子１０２ｎとはんだ１１０ｂを介して接合された下部電極１０３ｂと一体化させることによって、１段目熱電変換部１０５に配置された第１段ｎ型熱電素子１０１ｎと２段目熱電変換部１０６に配置された第２段ｎ型熱電素子１０２ｎとを電気的に接続するような場合、この貫通孔１０７の内部には気泡（ボイド）１１１が残ってしまう。このような気泡１１１が残留した多段熱電モジュール１００においては、この多段熱電モジュール１００を稼働することにより熱冷サイクルが発生するような場合、気泡１１１内部の圧力が温度変化に応じて変動し、この気泡１１１周辺に応力が発生する。このため、貫通孔１０７の上下に配置された第１段ｎ型熱電素子１０１ｎ及び第２段ｎ型熱電素子１０２ｎと夫々の上部電極１０３ｄ及び下部電極１０３ｂに接合するためのはんだ１１０ｄ及び１１０ｂとの接合部にクラックが入り易い等、耐久性が劣化する原因となり、この多段熱電モジュールの性能劣化の要因ともなる。
【０００７】
本発明はかかる問題点に鑑みてなされたものであって、各段の熱電変換部における熱電素子を高い耐久性を備えた方法により電気的に接続することによって、高い信頼性を有する多段熱電モジュールを提供することを目的とする。
【０００８】
【課題を解決するための手段】
本発明に係る多段熱電モジュールは、上下に対向して配置された３個以上の基板と、前記各基板の各対向面に形成された夫々複数個の上部電極及び下部電極と、前記各基板間に配置された複数個のｐ型熱電素子及びｎ型熱電素子とを有し、前記基板間に配置された熱電素子群毎に前記ｐ型熱電素子及びｎ型熱電素子が交互に直列及び／又は並列に接続されるように前記上部電極及び下部電極に夫々１対又は複数対のｐ型熱電素子及びｎ型熱電素子が接触して熱電変換部が構成され、更に前記熱電素子群が直列に接続されて前記熱電変換部が多段に構成され、一方の最外側の基板から他方の最外側の基板に向けて一方向に熱が流れる多段の熱電モジュールにおいて、
第１特定基板の下部電極とそれより２段以上上方の第２特定基板の上部電極とを接続すると共に、前記第１特定基板と前記第２特定基板の間の基板から離れた接続用熱電素子が前記第１特定基板の熱電素子群の最端列に配置され、この接続用熱電素子自身が、前記第１特定基板の下部電極に接続された熱電変換部の熱電素子と前記第２特定基板の上部電極に接続された熱電変換部の熱電素子とを兼ねていることを特徴とする。
【０００９】
前記接続用熱電素子は、前記第１特定基板と前記第２特定基板との間の基板に形成されたスルーホール間に配置されると共に、前記第１特定基板の下部電極と前記第２特定基板の上部電極とを接続することができる。
【００１０】
前記接続用熱電素子は、前記第１特定基板と前記第２特定基板との間の基板に形成された切欠間に配置されると共に、前記第１特定基板の下部電極と前記第２特定基板の上部電極とを接続しても良い。
【００１１】
また、前記第１特定基板と第２特定基板との間の基板は前記第１特定基板及び前記第２特定基板よりも平面視での外形寸法が小さく、前記接続用熱電素子は前記第１特定基板及び前記第２特定基板が前記第１特定基板と前記第２特定基板との間の基板より平面視において突出した部分に設けられると共に、前記突出した部分の対向面に形成された前記第１特定基板の下部電極と前記第２特定基板の上部電極とを接続しても良い。
【００１２】
【発明の実施の形態】
以下、本発明に係る多段熱電モジュールの実施形態について、添付の図面を参照して具体的に説明する。図１は、本発明の第１の実施形態に係る多段熱電モジュールにおける接続用熱電素子を示す断面図である。本実施形態においては、放熱側基板４ｈ上に形成された下部電極７ｂ上にはんだ６ｂを介して接合された接続用熱電素子１が、中段基板４ｍに設けられたスルーホール５の間に配置され、吸熱側基板４ｃ上に形成された上部電極７ａ上にはんだ６ａを介して接合されている。接続用熱電素子１は、放熱側基板４ｈ上の下部電極７ｂ及び吸熱側基板４ｃ上の上部電極７ａに夫々はんだ７ｂ及び７ａを介して接続されて、１段目熱電変換部１５と２段目熱電変換部１６とを電気的に接続している。
【００１３】
このような構成とすることによって、本実施形態に係る多段熱電モジュールにおいては、１段目熱電変換部１５の下部電極７ｂより２段目熱電変換部１６の上部電極７ａに届く高さの接続用熱電素子１が、中段基板４ｍに設けられたスルーホール５を貫通して１段目熱電変換部１５の下部電極７ｂと２段目熱電変換部１６の上部電極７ａとにはんだ６ｂ及び６ａを介して接合される。このため、多段熱電モジュールを稼働させるために通電する場合、この接続用熱電素子１自身が、１段目熱電変換部１５と２段目熱電変換部１６とを電気的に接続する。よって、従来のように、１段目熱電変換部の熱電素子と２段目熱電変換部の熱電素子とを電気的に接続するために、スルーホール内周壁に導電性被膜を形成する必要が無い。従って、従来の多段熱電モジュールにおいて、スルーホール内部に残存して多段熱電モジュールの耐久性を劣化させる原因となっていた気泡が形成されることがない。また、本実施形態においては、１段目熱電変換部１５の熱電素子と２段目熱電変換部１６の熱電素子とを電気的に接続するのではなく、接続用熱電素子１自身が、１段目熱電変換部１５の熱電素子と２段目熱電変換部１６の熱電素子とを兼ねている。即ち、接合箇所が少ないので、信頼性が高い構成となっている。よって、本実施形態に係る多段熱電モジュールは、耐久性及び信頼性を向上させることができる。
【００１４】
次に、本発明の第２の実施形態について、図２を参照して説明する。図２（ａ）は第２の実施形態に係る多段熱電モジュールを示す平面図であり、図２（ｂ）は図２（ａ）におけるＡ−Ａ線による断面図であり、図２（ｃ）は図２（ａ）におけるＢ−Ｂ線による断面図である。本実施形態においては、１辺が８．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる放熱側基板４ｈ上に形成された銅電極（図示せず）上に、底面形状が１辺が０．７５ｍｍの正方形状で高さが０．９０ｍｍの立方柱状であるｎ型及びｐ型の第１段熱電素子２が交互に隣り合わせに並べられてはんだ（図示せず）を介して接合されると共に、底面形状が１辺が０．７５ｍｍの正方形状で高さが２．２０ｍｍの立方柱状である１対のｎ型及びｐ型の接続用熱電素子１が、第１段熱電素子２の最端列に配置され、全部で３１対の熱電素子対が１段目に設置されている。そして、これらの熱電素子対が直列に接続されるように下面に銅電極（図示せず）のパターンが形成されると共に、接続用熱電素子１を間に配置することができる大きさの矩形の切欠２５が１辺に設けられた１辺が８．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる中段基板４ｍが、熱電素子対とはんだ（図示せず）を介して、この下面の銅電極で接合されている。このようにして、１段目熱電変換部１５が構成されている。一方、中段基板４ｍの上面にも銅電極（図示せず）が形成されており、この銅電極上に、底面形状が１辺が０．７５ｍｍの正方形状で高さが０．９０ｍｍの立方柱状であるｎ型及びｐ型の第２段熱電素子３が交互に隣り合わせに並べられてはんだ（図示せず）を介して接合されている。また、これらの第２段熱電素子３と、中段基板４ｍに設けられた切欠２５を貫通して第２段熱電素子３と隣り合わせに並んだ接続用熱電素子１とが、直列に接続されるように下面に銅電極（図示せず）のパターンが形成され１辺が４．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる吸熱側基板４ｃが、第２段熱電素子３及び接続用熱電素子１とはんだ（図示せず）を介して、この下面の銅電極で接合されることによって、全部で８対の熱電素子対が２段目に設置されている。このようにして、２段目熱電変換部１６が構成されている。
【００１５】
次に、本発明の第３の実施形態について、図３を参照して説明する。図３（ａ）は第３の実施形態に係る多段熱電モジュールを示す平面図であり、図３（ｂ）は図３（ａ）におけるＣ−Ｃによる断面図であり、図３（ｃ）は図３（ａ）におけるＤ−Ｄによる断面図である。本実施形態においては、１辺が８．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる放熱側基板４ｈ上に形成された銅電極（図示せず）上に、底面形状が１辺が０．７５ｍｍの正方形状で高さが０．９０ｍｍの立方柱状であるｎ型及びｐ型の第１段熱電素子２が交互に隣り合わせに並べられてはんだ（図示せず）を介して接合されると共に、底面形状が１辺が０．７５ｍｍの正方形状で高さが２．２０ｍｍの立方柱状である１対のｎ型及びｐ型の接続用熱電素子１が、中段基板４ｍから離れて第１段熱電素子２の最端列に配置されると共に、吸熱側基板４ｃ及び放熱側基板４ｈが突出したモジュール外端部に配置されることによって、全部で２９対の熱電素子対が１段目に設置されている。そして、これらの熱電素子対が直列に接続されるように下面に銅電極（図示せず）のパターンが形成された長辺が８．０ｍｍ、短辺が７．０ｍｍの長方形状で厚さが０．３ｍｍのアルミナからなる中段基板４ｍが、熱電素子対とはんだ（図示せず）を介して、この下面の銅電極で接合されている。このようにして、１段目熱電変換部１５が構成されている。一方、中段基板４ｍの上面にも銅電極（図示せず）が形成されており、この銅電極上に、底面形状が１辺が０．７５ｍｍの正方形状で高さが０．９０ｍｍの立方柱状であるｎ型及びｐ型の第２段熱電素子３が交互に隣り合わせに並べられてはんだ（図示せず）を介して接合されている。また、これらの第２段熱電素子３と、中段基板４ｍから離れて吸熱側基板４ｃ及び放熱側基板４ｈが突出したモジュール外端部に配置されて第２段熱電素子３と隣り合わせに並んだ接続用熱電素子１とが、直列に接続されるように下面に銅電極（図示せず）のパターンが形成され１辺が４．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる吸熱側基板４ｃが、第２段熱電素子３及び接続用熱電素子１とはんだ（図示せず）を介して、この下面の銅電極で接合されることによって、全部で７対の熱電素子対が２段目に設置されている。このようにして、２段目熱電変換部１６が構成されている。
【００１６】
本発明の第２及び第３の実施形態においては、１段目熱電変換部１５の下部電極より２段目熱電変換部１６の上部電極に届く高さの接続用熱電素子１が、中段基板４ｍ端部に設けられた矩形の切欠２５の間か又は中段基板４ｍから離れて吸熱側基板４ｃ及び放熱側基板４ｈが突出したモジュール外端部に配置されることによって、１段目熱電変換部１５の下部電極７ｂと２段目熱電変換部１６の上部電極７ａとにはんだ６ｂ及び６ａを介して接合される。このため、多段熱電モジュールを稼働させるために通電する場合、１段目熱電変換部１５に配置された一部の熱電素子２を経由して流れた電流が、この１対の接続用熱電素子１のうちの１個を介して１段目熱電変換部１５から２段目熱電変換部１６へ流れ（上向き矢印にて図示）、２段目熱電変換部１５に配置された熱電素子３を経由した後、もう１個の接続用熱電素子１を介して１段目熱電変換部１５へ戻り（下向き矢印にて図示）、残りの熱電素子２に流れる。このようにして接続用熱電素子１は、１段目熱電変換部１５と２段目熱電変換部１６とを電気的に接続することができる。よって、従来のように、１段目熱電変換部と２段目熱電変換部とを電気的に接続するための導電性被膜等を形成する必要が無い。従って、１段目熱電変換部と２段目熱電変換部とを電気的に接続するためのスルーホール内部等に残存して多段熱電モジュールの耐久性を劣化させる原因となっていた気泡が形成されることもない。また、本発明においては、１段目熱電変換部１５の熱電素子と２段目熱電変換部１６の熱電素子とを電気的に接続するのではなく、接続用熱電素子１自身が、１段目熱電変換部１５の熱電素子２と２段目熱電変換部１６の熱電素子３とを兼ねていて接合箇所が少ないので、熱冷サイクルに対しての耐久性が高い構成となっている。よって、本発明に係る多段熱電モジュールは、耐久性を向上させることができる。なお、図２に示す第２実施形態の中段基板４ｍのように、切欠型の場合には、チップとの寸法マージンをとることができるという利点があり、図３に示す第３実施形態の吸熱側基板４ｃ及び放熱側基板４ｈのように、突出型の場合には、基板加工が少なくてすむという利点がある。
【００１７】
本実施形態においては、多段熱電モジュールとして、２段の熱電変換部で構成される熱電モジュールの例を示したが、本発明は段数を限定せずに複数の段数を有する多段熱電モジュールに適用することができる。
【００１８】
【実施例】
次に、本発明の実施例について、添付の図面を参照して具体的に説明する。本実施例においては、図２に示した第２の実施形態と同一構造の多段熱電モジュールを２２個製造した。また、図４（ａ）は比較例として製造した従来技術による多段熱電モジュールを示す平面図であり、図４（ｂ）は図４（ａ）におけるＥ−Ｅによる断面図であり、図４（ｃ）は図４（ａ）におけるＦ−Ｆによる断面図である。この比較例の多段熱電モジュールにおいては、第２の実施形態と同様に、１辺が８．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる放熱側基板４ｈ上に形成された銅電極（図示せず）上に、底面形状が１辺が０．７５ｍｍの正方形状で高さが０．９０ｍｍの立方柱状であるｎ型及びｐ型の第１段熱電素子２が交互に隣り合わせに並べられてはんだ（図示せず）を介して接合され、全部で３１対の熱電素子対が１段目に設置されている。そして、これらの熱電素子対が直列に接続されるように下面に銅電極（図示せず）のパターンが形成され１辺が８．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる中段基板４ｍが、熱電素子対とはんだ（図示せず）を介して、この下面の銅電極で接合されている。このようにして、１段目熱電変換部１５が構成されている。一方、中段基板４ｍの上面にも銅電極（図示せず）が形成されており、この銅電極上に、底面形状が１辺が０．７５ｍｍの正方形状で高さが０．９０ｍｍの立方柱状であるｎ型及びｐ型の第２段熱電素子３が交互に隣り合わせに並べられてはんだ（図示せず）を介して接合されている。そして、これらの熱電素子対が直列に接続されるように下面に銅電極（図示せず）のパターンが形成され１辺が４．０ｍｍの正方形状で厚さが０．３ｍｍのアルミナからなる吸熱側基板４ｃが、第２段熱電素子３とはんだ（図示せず）を介して、この下面の銅電極で接合されることによって、全部で８対の熱電素子対が２段目に設置されて、２段目熱電変換部１６が構成されている。また、中段基板４ｍの一部には２個のスルーホール１１２が設けられている。そして、スルーホール１１２の内周壁には導電性被膜（図示せず）が形成されており、このスルーホール１１２の上下に配置された第１段熱電素子２及び第２段熱電素子３に接合された銅電極（図示せず）と接続されて、１段目熱電変換部１５と２段目熱電変換部１６とを電気的に接続している。このように構成された従来技術による多段熱電モジュールを、２２個製造して比較例とした。
【００１９】
上述のような夫々２２個の実施例及び比較例の多段熱電モジュールのサンプルに対し、これらの実施例及び比較例の全てのサンプルのＡＣ抵抗を測定してから、−４０℃で１５分間及び＋８５℃で１５分間の熱冷サイクルを１０００サイクル実施した。その後、ＡＣ抵抗を再測定し、１０００サイクルの熱冷サイクルの前後において、ＡＣ抵抗変化率が５％を超えたサンプルを不良品と判定した。本実施例及び比較例によるサンプルでの判定結果を下記表１に示す。
【００２０】
【表１】

【００２１】
上記表１から明らかなように、従来技術による比較例の多段熱電モジュールでは、熱冷サイクル後に２個の不良品が発生した。一方、本実施例の多段熱電モジュールは、温度差が１２５℃の過酷な１０００サイクルの熱冷サイクルによってもＡＣ抵抗変化率が５％を超える不良品が発生することがなく、優れた耐久性を備えていることが証明された。
【００２２】
【発明の効果】
以上詳述したように、本発明に係る多段熱電モジュールにおいては、第１特定基板の熱電変換部の熱電素子とそれより２段以上上方の第２特定基板の熱電変換部の熱電素子とを兼ねる接続用熱電素子が、各段の熱電変換部を分ける中段基板に設けられたスルーホール又は切欠を貫通するか若しくは下段の熱電変換部の放熱側基板及び上段の熱電変換部の吸熱側基板が突出したモジュール外端部に中段基板から離れて配置されると共に、下段の熱電変換部の下部電極と上段の熱電変換部の上部電極とにはんだ等を介して接合される。このため、多段熱電モジュールを稼働させるために通電する場合、この接続用熱電素子自身が、複数段の熱電変換部を電気的に接続することができる。よって、従来のように、複数段の熱電変換部を電気的に接続するために、スルーホール内周壁に導電性被膜を形成する必要が無い。従って、従来の多段熱電モジュールにおいて、スルーホール内部に残存して多段熱電モジュールの耐久性を劣化させる原因となっていた気泡は形成されない。また、本発明による複数段の熱電変換部を電気的に接続する方法は、接合箇所が少なく耐久性が高い構成となっている。従って、本発明に係る多段熱電モジュールは、耐久性を向上させることができる。
【図面の簡単な説明】
【図１】第１の実施形態に係る多段熱電モジュールを示す部分的断面図である。
【図２】図２（ａ）は第２の実施形態の平面図であり、図２（ｂ）は図２（ａ）におけるＡ−Ａによる断面図であり、図２（ｃ）は図２（ａ）におけるＢ−Ｂによる断面図である。
【図３】図３（ａ）は第３の実施形態の平面図であり、図３（ｂ）は図３（ａ）におけるＣ−Ｃによる断面図であり、図３（ｃ）は図３（ａ）におけるＤ−Ｄによる断面図である。
【図４】図４（ａ）は比較例としての従来技術による多段熱電モジュールの平面図であり、図４（ｂ）は図４（ａ）におけるＥ−Ｅによる断面図であり、図４（ｃ）は図４（ａ）におけるＦ−Ｆによる断面図である。
【図５】従来の多段熱電モジュールを示す断面図である。
【図６】従来の多段熱電モジュールにおける問題点を説明するための断面図である。
【符号の説明】
１；接続用熱電素子
２；第１段熱電素子
３；第２段熱電素子
４ｃ；吸熱側基板
４ｍ；中段基板
４ｈ；放熱側基板
５，１１２；スルーホール
６ａ，６ｂ，１１０ａ，１１０ｂ，１１０ｄ，１１０ｅ；はんだ
７ａ；上部電極
７ｂ；下部電極
１５，１０５；１段目熱電変換部
１６，１０６；２段目熱電変換部
２５；切欠
１００；従来技術による２段型熱電モジュール
１０１ｎ；第１段ｎ型熱電素子
１０１ｐ；第１段ｐ型熱電素子
１０２ｎ；第２段ｎ型熱電素子
１０２ｐ；第１段ｐ型熱電素子
１０３ａ；第２段上部電極
１０３ｂ；第２段下部電極
１０３ｄ；第１段上部電極
１０３ｅ；第１段下部電極
１０４ｃ；上側絶縁基板
１０４ｍ；中段絶縁基板
１０４ｈ；下側絶縁基板
１０７；貫通孔
１０８；導電性被膜
１１１；気泡（ボイド）[0001]
BACKGROUND OF THE INVENTION
The present invention relates to a multistage thermoelectric module configured by stacking thermoelectric modules in which thermoelectric element pairs having a Peltier effect are arranged between insulating substrates in multiple stages so that the heat flow is in one direction.
[0002]
[Prior art]
BiTe-based semiconductors are used as thermoelectric materials with good thermoelectric performance as thermoelectric materials that convert thermal energy into electrical energy or, conversely, supply thermal energy to move thermal energy and exert a cooling effect. ing. In particular, an electronic cooling element using the Peltier effect, which is one of the thermoelectric effects of this semiconductor, and a thermoelectric element using the Seebeck effect are simple in structure, easy to reduce in size and weight, and are silent and vibration-free. Since no maintenance is required, there is a possibility that it can be used in a wide range such as application to a temperature controller inside a semiconductor device such as a small refrigerator for special applications and a semiconductor laser.
[0003]
Some thermoelectric modules used for thermoelectric power generation using the electronic cooling using the Peltier effect and the Seebeck effect are assembled into a multi-stage module structure. For example, in the two-stage thermoelectric module 100 as shown in FIG. 5, the first-stage n-type thermoelectric elements 101n and the first-stage p-type thermoelectric elements 101p are alternately arranged adjacent to each other, and the upper electrode 103d and the lower electrode 103e. Are connected in series, and are sandwiched between the middle insulating substrate 104m and the lower insulating substrate 104h to form the first-stage thermoelectric converter 105. Similarly, the second-stage n-type thermoelectric element 102n and the second-stage p-type thermoelectric element 102p are alternately arranged adjacent to each other, connected in series via the upper electrode 103a and the lower electrode 103b, and the upper-stage insulating substrate 104c and the middle-stage insulating element. A second-stage thermoelectric conversion unit 106 is formed between the substrates 104m. A through hole 107 is formed in a part of the middle insulating substrate 104m, and a conductive coating 108 is applied to the inner peripheral wall of the through hole 107. The conductive film 108 is bonded to the upper electrode 103 d bonded to the first-stage n-type thermoelectric element 101 n in the first-stage thermoelectric conversion unit 105 and to the second-stage p-type thermoelectric element 102 p in the second-stage thermoelectric conversion unit 106. The first-stage n-type thermoelectric element 101n of the first-stage thermoelectric conversion unit 105 and the second-stage p-type thermoelectric element 102p of the second-stage thermoelectric conversion unit 106 are electrically connected in series to the lower electrode 103b. Connected. In the conventional two-stage thermoelectric module 100 configured as described above, each thermoelectric element absorbs Peltier heat at the heat absorption side of each stage and the heat dissipation side of each stage by energizing these thermoelectric elements. Peltier heat is dissipated, and, for example, heat flows in one direction from the upper insulating substrate 104c which is the outermost side on the heat absorption side toward the lower insulating substrate 104h which is the outermost side on the heat dissipation side. The middle-stage insulating substrate 104m is a heat-absorption-side insulating substrate of the first-stage thermoelectric conversion unit 105, and is also a heat-dissipation-side insulating substrate of the second-stage thermoelectric conversion unit 106.
[0004]
When such a conventional two-stage thermoelectric module 100 is energized, for example, a current flows through the first-stage n-type thermoelectric element 101n and the first-stage p-type thermoelectric element 101p arranged in the first-stage thermoelectric conversion unit 105. These n-type and p-type thermoelectric elements 101n and 101p absorb heat by the Peltier effect on the intermediate insulating substrate 104m side which is the heat absorption side and radiate heat by the lower insulating substrate 104h which is the heat dissipation side. This current further flows from the first-stage n-type thermoelectric element 101n to the second-stage n-type thermoelectric element 102n via the conductive film 108 formed on the inner peripheral wall of the through hole 107 provided in the middle-stage insulating substrate 104m. As a result, a current sequentially flows through the second-stage p-type thermoelectric element 102p and the second-stage n-type thermoelectric element 102n arranged in the second-stage thermoelectric conversion section 106, and the second-stage thermoelectric conversion section 106 also has 1 Similar to the stage thermoelectric conversion portion 105, the Peltier effect absorbs heat on the upper insulating substrate 104c side serving as the heat absorbing side and radiates heat on the middle insulating substrate 104m side serving as the heat radiating side. In this conventional multistage thermoelectric module 100, the thermoelectric elements at each stage are electrically connected to each other through lead wires or the like through the conductive film 108 formed on the inner peripheral wall of the through hole 107. Compared with the case where they are connected to each other, a multistage thermoelectric module that is more compact and highly reliable is configured (see, for example, Patent Document 1).
[0005]
[Patent Document 1]
JP-A-10-190071 (first page, FIG. 4)
[0006]
[Problems to be solved by the invention]
However, in such a conventional multi-stage thermoelectric module 100, in order to install thermoelectric elements at a higher density, for example, as shown in FIG. 6, the first-stage n-type disposed in the first-stage thermoelectric conversion unit 105 is used. A second-stage n-type thermoelectric element 102n is disposed immediately above the thermoelectric element 101n, and a through-hole is formed in the middle-stage insulating substrate 104m located between the first-stage n-type thermoelectric element 101n and the second-stage n-type thermoelectric element 102n. The upper electrode 103d and the second stage n-type thermoelectric element 102n joined to the first stage n-type thermoelectric element 101n via the solder 110d are provided with the conductive film 108 formed on the inner peripheral wall of the through-hole 107. 1st n-type thermoelectric element 101n arranged in the first-stage thermoelectric converter 105 and second-stage thermoelectric conversion If a second-stage n-type thermoelectric elements 102n arranged in part 106 so as to electrically connect, it leaves a bubble (void) 111 inside the through hole 107. In such a multistage thermoelectric module 100 in which bubbles 111 remain, when a thermal cooling cycle is generated by operating the multistage thermoelectric module 100, the pressure inside the bubbles 111 fluctuates according to the temperature change. Stress is generated around the bubble 111. Therefore, the first-stage n-type thermoelectric element 101n and the second-stage n-type thermoelectric element 102n arranged above and below the through-hole 107 and the

solders

110d and 110b for joining to the upper electrode 103d and the lower electrode 103b, respectively. It becomes a cause of deterioration of durability, such as a crack is likely to occur in the joint portion, and a factor of performance deterioration of the multistage thermoelectric module.
[0007]
The present invention has been made in view of such problems, and is a multi-stage thermoelectric module having high reliability by electrically connecting thermoelectric elements in thermoelectric conversion sections of each stage by a method having high durability. The purpose is to provide.
[0008]
[Means for Solving the Problems]
A multi-stage thermoelectric module according to the present invention includes three or more substrates arranged vertically opposite to each other, a plurality of upper electrodes and lower electrodes formed on each facing surface of each substrate, and between the substrates. A plurality of p-type thermoelectric elements and n-type thermoelectric elements, and the p-type thermoelectric elements and the n-type thermoelectric elements are alternately arranged in series and / or for each thermoelectric element group arranged between the substrates. One or more pairs of p-type and n-type thermoelectric elements are in contact with the upper electrode and the lower electrode so as to be connected in parallel to form a thermoelectric conversion unit , and the thermoelectric element groups are connected in series. In the multi-stage thermoelectric module in which the thermoelectric converter is configured in multiple stages, and heat flows in one direction from one outermost substrate to the other outermost substrate,
With connecting the upper electrode of the lower electrode and it than two or more stages above the second specific substrate of the first Japanese Sadamoto plate, for connection away from the substrate between the said first specific substrate second specific substrate A thermoelectric element is arranged in the outermost row of the thermoelectric element group of the first specific substrate, and the thermoelectric element for connection itself is connected to the thermoelectric element of the thermoelectric conversion unit connected to the lower electrode of the first specific substrate and the second It also serves as a thermoelectric element of a thermoelectric conversion unit connected to the upper electrode of the specific substrate .
[0009]
The connecting thermoelectric elements, said while being disposed between the formed through hole on the substrate between the first Japanese Sadamoto plate and the second specific substrate, wherein the lower electrode of the first Japanese Sadamoto plate second The upper electrode of the specific substrate can be connected.
[0010]
The connecting thermoelectric elements, said while being disposed between formed notches in the substrate between the first Japanese Sadamoto plate and the second specific substrate, said second identification and the lower electrode of the first Japanese Sadamoto plate You may connect with the upper electrode of a board | substrate.
[0011]
Further, the substrate between the first Japanese Sadamoto plate and the second specific substrate has a small external dimensions in plan view than the first Japanese Sadamoto plate and the second specific substrate, wherein the connecting thermoelectric element and the second 1 with Japanese Sadamoto plate and the second specific substrate is provided in the protruding portion in the plan view from the substrate between the second specific substrate and the first specific substrate, it is formed in pairs facing surfaces of the projecting portion and it may be connected to the upper electrode of the second specific substrate and the lower electrode of the first Japanese Sadamoto plate.
[0012]
DETAILED DESCRIPTION OF THE INVENTION
Hereinafter, embodiments of a multistage thermoelectric module according to the present invention will be specifically described with reference to the accompanying drawings. FIG. 1 is a cross-sectional view showing a connecting thermoelectric element in a multistage thermoelectric module according to a first embodiment of the present invention. In the present embodiment, the connecting thermoelectric element 1 joined via the solder 6b on the lower electrode 7b formed on the heat radiation side substrate 4h is disposed between the through holes 5 provided in the middle stage substrate 4m. The upper electrode 7a formed on the heat absorption side substrate 4c is joined via the solder 6a. The connecting thermoelectric element 1 is connected to the lower electrode 7b on the heat radiation side substrate 4h and the upper electrode 7a on the heat absorption side substrate 4c via

solders

7b and 7a, respectively, and the first stage thermoelectric conversion unit 15 and the second stage The thermoelectric converter 16 is electrically connected.
[0013]
By adopting such a configuration, in the multistage thermoelectric module according to the present embodiment, the height of the connection reaches from the lower electrode 7b of the first stage thermoelectric converter 15 to the upper electrode 7a of the second stage thermoelectric converter 16. The thermoelectric element 1 passes through the through-hole 5 provided in the middle stage substrate 4m, and passes through the lower electrode 7b of the first stage thermoelectric conversion part 15 and the upper electrode 7a of the second stage thermoelectric conversion part 16 via

solders

6b and 6a. Are joined. For this reason, when energizing to operate the multi-stage thermoelectric module, the connecting thermoelectric element 1 itself electrically connects the first-stage thermoelectric converter 15 and the second-stage thermoelectric converter 16. Therefore, unlike the prior art, in order to electrically connect the thermoelectric element of the first stage thermoelectric conversion part and the thermoelectric element of the second stage thermoelectric conversion part, there is no need to form a conductive film on the inner peripheral wall of the through hole. . Therefore, in the conventional multistage thermoelectric module, bubbles that remain inside the through hole and cause deterioration of the durability of the multistage thermoelectric module are not formed. In the present embodiment, the thermoelectric element of the first-stage thermoelectric conversion unit 15 and the thermoelectric element of the second-stage thermoelectric conversion unit 16 are not electrically connected, but the connecting thermoelectric element 1 itself is one-stage. The thermoelectric element of the eye thermoelectric conversion unit 15 also serves as the thermoelectric element of the second stage thermoelectric conversion unit 16. That is, since there are few joints, it has a highly reliable configuration. Therefore, the multistage thermoelectric module according to this embodiment can improve durability and reliability.
[0014]
Next, a second embodiment of the present invention will be described with reference to FIG. 2A is a plan view showing a multistage thermoelectric module according to the second embodiment, and FIG. 2B is a cross-sectional view taken along line AA in FIG. 2A, and FIG. These are sectional drawings by the BB line in Drawing 2 (a). In the present embodiment, the shape of the bottom surface is one side on a copper electrode (not shown) formed on the heat radiation side substrate 4h made of alumina having a square shape with a side of 8.0 mm and a thickness of 0.3 mm. N-type and p-type first stage thermoelectric elements 2 each having a square shape of 0.75 mm and a cubic column shape having a height of 0.90 mm are alternately arranged next to each other and joined via solder (not shown). In addition, a pair of n-type and p-type connection thermoelectric elements 1 having a bottom face shape of a square shape with a side of 0.75 mm and a height of 2.20 mm are connected to the first stage thermoelectric element 2. Arranged in the endmost row, a total of 31 thermoelectric element pairs are installed in the first stage. Then, a pattern of copper electrodes (not shown) is formed on the lower surface so that these thermoelectric element pairs are connected in series, and a rectangular shape having a size capable of arranging the connecting thermoelectric element 1 therebetween. A middle substrate 4m made of alumina having a square shape with a side of 8.0 mm and a thickness of 0.3 mm with a notch 25 provided on one side is connected to the bottom surface via a thermoelectric element pair and solder (not shown). Are joined by copper electrodes. In this way, the first-stage thermoelectric conversion unit 15 is configured. On the other hand, a copper electrode (not shown) is also formed on the upper surface of the middle stage substrate 4m, and on this copper electrode, the bottom shape is a square shape with a side of 0.75 mm and a cubic column shape with a height of 0.90 mm. N-type and p-type second-stage thermoelectric elements 3 are alternately arranged next to each other and joined via solder (not shown). Further, these second-stage thermoelectric elements 3 and the connecting thermoelectric elements 1 that pass through the notches 25 provided in the middle-stage substrate 4m and are arranged adjacent to the second-stage thermoelectric elements 3 are connected in series. A heat absorption side substrate 4c made of alumina with a pattern of copper electrodes (not shown) formed on the lower surface and a square shape with a side of 4.0 mm and a thickness of 0.3 mm is connected to the second stage thermoelectric element 3 and the connection. The thermoelectric element 1 and solder (not shown) are joined by the copper electrodes on the lower surface, so that a total of eight thermoelectric element pairs are installed in the second stage. In this way, the second-stage thermoelectric conversion unit 16 is configured.
[0015]
Next, a third embodiment of the present invention will be described with reference to FIG. FIG. 3A is a plan view showing a multistage thermoelectric module according to the third embodiment, FIG. 3B is a cross-sectional view taken along the line CC in FIG. 3A, and FIG. It is sectional drawing by DD in Fig.3 (a). In the present embodiment, the shape of the bottom surface is one side on a copper electrode (not shown) formed on the heat radiation side substrate 4h made of alumina having a square shape with a side of 8.0 mm and a thickness of 0.3 mm. N-type and p-type first stage thermoelectric elements 2 each having a square shape of 0.75 mm and a cubic column shape having a height of 0.90 mm are alternately arranged next to each other and joined via solder (not shown). In addition, a pair of n-type and p-type connecting thermoelectric elements 1 whose bottom shape is a square shape having a side of 0.75 mm and a height of 2.20 mm is separated from the middle substrate 4m. Arranged at the outermost end row of the first stage thermoelectric element 2 and at the outer end of the module from which the heat absorption side substrate 4c and the heat radiation side substrate 4h protrude, there are a total of 29 thermoelectric element pairs in the first stage. Is installed. Then, a copper electrode (not shown) pattern formed on the lower surface so that these thermoelectric element pairs are connected in series is a rectangular shape having a long side of 8.0 mm and a short side of 7.0 mm. A middle stage substrate 4m made of 0.3 mm alumina is bonded to the lower surface copper electrode via a thermoelectric element pair and solder (not shown). In this way, the first-stage thermoelectric conversion unit 15 is configured. On the other hand, a copper electrode (not shown) is also formed on the upper surface of the middle stage substrate 4m, and on this copper electrode, the bottom shape is a square shape with a side of 0.75 mm and a cubic column shape with a height of 0.90 mm. N-type and p-type second-stage thermoelectric elements 3 are alternately arranged next to each other and joined via solder (not shown). Further, these second-stage thermoelectric elements 3 are connected to the second-stage thermoelectric elements 3 so as to be arranged adjacent to the second-stage thermoelectric elements 3 at the outer end of the module where the heat absorption side substrate 4c and the heat dissipation side substrate 4h are separated from the middle substrate 4m. A heat absorption side made of alumina having a square shape with a side of 4.0 mm and a thickness of 0.3 mm with a copper electrode pattern (not shown) formed on the lower surface so that the thermoelectric element 1 is connected in series The substrate 4c is joined to the second stage thermoelectric element 3 and the connecting thermoelectric element 1 via the solder (not shown) with the copper electrode on the lower surface, so that a total of seven thermoelectric element pairs are in two stages. It is installed in the eye. In this way, the second-stage thermoelectric conversion unit 16 is configured.
[0016]
In the second and third embodiments of the present invention, the connecting thermoelectric element 1 having a height that reaches the upper electrode of the second-stage thermoelectric conversion unit 16 from the lower electrode of the first-stage thermoelectric conversion unit 15 is the middle substrate 4m. The first-stage thermoelectric conversion unit 15 is arranged between the rectangular cutouts 25 provided at the end portions or at the module outer end portion where the heat-absorbing side substrate 4c and the heat-dissipation side substrate 4h protrude away from the middle-stage substrate 4m. The lower electrode 7b of the second stage and the upper electrode 7a of the second stage thermoelectric converter 16 are joined via

solders

6b and 6a. For this reason, when energizing in order to operate a multistage thermoelectric module, the current that has flowed through a part of the thermoelectric elements 2 arranged in the first-stage thermoelectric conversion section 15 is converted into this pair of connection thermoelectric elements 1. The first-stage thermoelectric conversion unit 15 flows to the second-stage thermoelectric conversion unit 16 through one of them (shown by an upward arrow), and passes through the thermoelectric element 3 arranged in the second-stage thermoelectric conversion unit 15. Thereafter, the flow returns to the first-stage thermoelectric conversion unit 15 via another connecting thermoelectric element 1 (shown by a downward arrow) and flows to the remaining thermoelectric elements 2. In this way, the connecting thermoelectric element 1 can electrically connect the first-stage thermoelectric converter 15 and the second-stage thermoelectric converter 16. Therefore, unlike the conventional case, there is no need to form a conductive film or the like for electrically connecting the first-stage thermoelectric conversion section and the second-stage thermoelectric conversion section. Accordingly, bubbles are formed that remain in the through hole for electrically connecting the first-stage thermoelectric conversion section and the second-stage thermoelectric conversion section and cause deterioration of the durability of the multistage thermoelectric module. It never happens. In the present invention, the thermoelectric element of the first stage thermoelectric conversion section 15 and the thermoelectric element of the second stage thermoelectric conversion section 16 are not electrically connected, but the connecting thermoelectric element 1 itself is the first stage. Since the thermoelectric element 2 of the thermoelectric conversion part 15 and the thermoelectric element 3 of the second stage thermoelectric conversion part 16 are combined and there are few junctions, it has the structure with high durability with respect to a heat-cooling cycle. Therefore, the multistage thermoelectric module according to the present invention can improve durability. In the case of a notch type like the middle substrate 4m of the second embodiment shown in FIG. 2, there is an advantage that a dimensional margin with the chip can be taken, and the heat absorption of the third embodiment shown in FIG. In the case of the protruding type, such as the side substrate 4c and the heat radiation side substrate 4h, there is an advantage that substrate processing is reduced.
[0017]
In the present embodiment, an example of a thermoelectric module including a two-stage thermoelectric conversion unit is shown as a multistage thermoelectric module. However, the present invention is applied to a multistage thermoelectric module having a plurality of stages without limiting the number of stages. be able to.
[0018]
【Example】
Next, embodiments of the present invention will be specifically described with reference to the accompanying drawings. In this example, 22 multistage thermoelectric modules having the same structure as that of the second embodiment shown in FIG. 2 were manufactured. FIG. 4A is a plan view showing a conventional multi-stage thermoelectric module manufactured as a comparative example, and FIG. 4B is a cross-sectional view taken along line EE in FIG. (c) is sectional drawing by FF in Fig.4 (a). In the multi-stage thermoelectric module of this comparative example, as in the second embodiment, a copper electrode formed on a heat radiation side substrate 4h made of alumina having a square shape with sides of 8.0 mm and a thickness of 0.3 mm. The n-type and p-type first-stage thermoelectric elements 2 having a square bottom shape with a side of 0.75 mm and a cubic column shape with a height of 0.90 mm are alternately arranged next to each other (not shown). In total, 31 thermoelectric element pairs are installed in the first stage through solder (not shown). Then, a pattern of copper electrodes (not shown) is formed on the lower surface so that these thermoelectric element pairs are connected in series, and a middle stage made of alumina having a square shape of 8.0 mm on one side and a thickness of 0.3 mm. The substrate 4m is bonded to the lower surface copper electrode via a thermoelectric element pair and solder (not shown). In this way, the first-stage thermoelectric conversion unit 15 is configured. On the other hand, a copper electrode (not shown) is also formed on the upper surface of the middle stage substrate 4m, and on this copper electrode, the bottom shape is a square shape with a side of 0.75 mm and a cubic column shape with a height of 0.90 mm. N-type and p-type second-stage thermoelectric elements 3 are alternately arranged next to each other and joined via solder (not shown). Then, a pattern of copper electrodes (not shown) is formed on the lower surface so that these thermoelectric element pairs are connected in series, and the heat absorption is made of alumina having a square shape of 4.0 mm on one side and a thickness of 0.3 mm. The side substrate 4c is joined to the second stage thermoelectric element 3 and the copper electrode on the lower surface via solder (not shown), so that a total of eight thermoelectric element pairs are installed in the second stage. A second-stage thermoelectric conversion unit 16 is configured. In addition, two through holes 112 are provided in a part of the middle substrate 4m. A conductive film (not shown) is formed on the inner peripheral wall of the through hole 112 and is joined to the first stage thermoelectric element 2 and the second stage thermoelectric element 3 disposed above and below the through hole 112. The first-stage thermoelectric conversion unit 15 and the second-stage thermoelectric conversion unit 16 are electrically connected to each other with a copper electrode (not shown). Twenty-two conventional multi-stage thermoelectric modules configured as described above were manufactured as comparative examples.
[0019]
For each of the 22 example and comparative multi-stage thermoelectric module samples as described above, the AC resistance of all the examples and comparative examples was measured, and then at −40 ° C. for 15 minutes and +85 1000 cycles of thermal cooling at 15 ° C. for 15 minutes were performed. Thereafter, the AC resistance was measured again, and a sample having an AC resistance change rate of more than 5% before and after 1000 thermal cooling cycles was determined as a defective product. Table 1 below shows the determination results of the samples according to this example and the comparative example.
[0020]
[Table 1]

[0021]
As is clear from Table 1 above, in the multi-stage thermoelectric module of the comparative example according to the prior art, two defective products occurred after the thermal cooling cycle. On the other hand, the multi-stage thermoelectric module of this example does not generate a defective product with an AC resistance change rate exceeding 5% even with a severe 1000 cycles of thermal cooling with a temperature difference of 125 ° C., and has excellent durability. Proven to have.
[0022]
【The invention's effect】
As described above in detail, in the multistage thermoelectric module according to the present invention, the thermoelectric element of the thermoelectric conversion part of the first specific substrate serves as the thermoelectric element of the thermoelectric conversion part of the second specific substrate two or more stages above it. The connecting thermoelectric element passes through a through hole or notch provided in the middle stage substrate that divides the thermoelectric conversion part of each stage, or the heat dissipation side board of the lower thermoelectric conversion part and the heat absorption side board of the upper thermoelectric conversion part protrude. while being located away from the middle substrate modules outer end, is engaged against through solder or the like to the upper electrode of the lower electrode and the upper thermoelectric conversion portion of the lower thermoelectric conversion unit. For this reason, when it supplies with electricity in order to operate a multistage thermoelectric module, this thermoelectric element for connection itself can electrically connect the multistage thermoelectric conversion part. Therefore, unlike the prior art, it is not necessary to form a conductive coating on the inner peripheral wall of the through hole in order to electrically connect a plurality of thermoelectric conversion portions. Therefore, in the conventional multistage thermoelectric module, bubbles that remain in the through hole and cause deterioration of the durability of the multistage thermoelectric module are not formed. Moreover, the method of electrically connecting the multi-stage thermoelectric converters according to the present invention has a configuration with few joints and high durability. Therefore, the multistage thermoelectric module according to the present invention can improve durability.
[Brief description of the drawings]
FIG. 1 is a partial cross-sectional view showing a multistage thermoelectric module according to a first embodiment.
2A is a plan view of the second embodiment, FIG. 2B is a cross-sectional view taken along line AA in FIG. 2A, and FIG. 2C is FIG. It is sectional drawing by BB in (a).
3A is a plan view of the third embodiment, FIG. 3B is a cross-sectional view taken along the line C-C in FIG. 3A, and FIG. 3C is FIG. It is sectional drawing by DD in (a).
4 (a) is a plan view of a conventional multi-stage thermoelectric module as a comparative example, FIG. 4 (b) is a cross-sectional view taken along line EE in FIG. 4 (a), and FIG. (c) is sectional drawing by FF in Fig.4 (a).
FIG. 5 is a cross-sectional view showing a conventional multistage thermoelectric module.
FIG. 6 is a cross-sectional view for explaining a problem in a conventional multistage thermoelectric module.
[Explanation of symbols]
1; connection thermoelectric element 2; first-stage thermoelectric element 3; second-stage thermoelectric element 4c; heat-absorption side substrate 4m; middle-stage substrate 4h; heat-

dissipation side substrate

5, 112; through

holes

6a, 6b, 110a, 110b, 110d, 110e; Solder 7a; Upper electrode 7b;

Lower electrodes

15, 105; First stage

thermoelectric converter

16, 106; Second stage thermoelectric converter 25; Notch 100; Two-stage thermoelectric module 101n according to the prior art; First stage n Type thermoelectric element 101p; first stage p type thermoelectric element 102n; second stage n type thermoelectric element 102p; first stage p type thermoelectric element 103a; second stage upper electrode 103b; second stage lower electrode 103d; Electrode 103e; first stage lower electrode 104c; upper insulating substrate 104m; middle insulating substrate 104h; lower insulating substrate 107; through-hole 108; conductive coating 111;

Claims

Three or more substrates disposed vertically opposite to each other, a plurality of upper electrodes and lower electrodes formed on each opposed surface of each substrate, and a plurality of p-type disposed between the substrates. The upper part has a thermoelectric element and an n-type thermoelectric element, and the p-type thermoelectric element and the n-type thermoelectric element are alternately connected in series and / or in parallel for each thermoelectric element group disposed between the substrates. One or more pairs of p-type and n-type thermoelectric elements are in contact with the electrode and the lower electrode to form a thermoelectric conversion unit, and the thermoelectric element group is connected in series so that the thermoelectric conversion unit is multistaged. In a multi-stage thermoelectric module that is configured and heat flows in one direction from one outermost substrate to the other outermost substrate,
With connecting the upper electrode of the lower electrode and it than two or more stages above the second specific substrate of the first Japanese Sadamoto plate, for connection away from the substrate between the said first specific substrate second specific substrate A thermoelectric element is arranged in the outermost row of the thermoelectric element group of the first specific substrate, and the thermoelectric element for connection itself is connected to the thermoelectric element of the thermoelectric conversion unit connected to the lower electrode of the first specific substrate and the second A multi-stage thermoelectric module characterized by also serving as a thermoelectric element of a thermoelectric conversion unit connected to an upper electrode of a specific substrate .

The connecting thermoelectric elements, said while being disposed between the formed through hole on the substrate between the first Japanese Sadamoto plate and the second specific substrate, wherein the lower electrode of the first Japanese Sadamoto plate second The multistage thermoelectric module according to claim 1, wherein an upper electrode of a specific substrate is connected.

The connecting thermoelectric elements, said while being disposed between formed notches in the substrate between the first Japanese Sadamoto plate and the second specific substrate, said second identification and the lower electrode of the first Japanese Sadamoto plate The multistage thermoelectric module according to claim 1, wherein the multistage thermoelectric module is connected to an upper electrode of the substrate.

Substrate between the first Japanese Sadamoto plate and the second specific substrate has a small external dimensions in plan view than the first Japanese Sadamoto plate and the second specific substrate, wherein the connecting thermoelectric element and the first Japanese with Sadamoto plate and the second specific substrate is provided in the protruding portion in the plan view from the substrate between the second specific substrate and the first specific substrate, are formed in pairs facing surfaces of the projecting portion wherein multistage thermoelectric module according to claim 1, characterized in that for connecting the upper electrode of the second specific substrate and the lower electrode of the first Japanese Sadamoto plate.