JP4279828B2 - 多段触媒系、ならびにアルカンをアルケンおよびそれらの対応する酸素化生成物へ転化させる方法 - Google Patents

多段触媒系、ならびにアルカンをアルケンおよびそれらの対応する酸素化生成物へ転化させる方法 Download PDF

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JP4279828B2
JP4279828B2 JP2005332699A JP2005332699A JP4279828B2 JP 4279828 B2 JP4279828 B2 JP 4279828B2 JP 2005332699 A JP2005332699 A JP 2005332699A JP 2005332699 A JP2005332699 A JP 2005332699A JP 4279828 B2 JP4279828 B2 JP 4279828B2
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catalyst
reactor
unsaturated carboxylic
catalysts
alkane
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JP2006142295A5 (https=
JP2006142295A (ja
Inventor
アブラハム・ベンダリー
アン・メイ・ガフニー
マーク・アンソニー・シルバノ
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Rohm and Haas Co
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Rohm and Haas Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02P20/10—Process efficiency
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2005332699A 2004-11-18 2005-11-17 多段触媒系、ならびにアルカンをアルケンおよびそれらの対応する酸素化生成物へ転化させる方法 Expired - Fee Related JP4279828B2 (ja)

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US62920504P 2004-11-18 2004-11-18

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JP2008283785A Division JP2009067808A (ja) 2004-11-18 2008-11-04 多段触媒系、ならびにアルカンをアルケンおよびそれらの対応する酸素化生成物へ転化させる方法

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JP2006142295A JP2006142295A (ja) 2006-06-08
JP2006142295A5 JP2006142295A5 (https=) 2006-07-20
JP4279828B2 true JP4279828B2 (ja) 2009-06-17

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JP2005332699A Expired - Fee Related JP4279828B2 (ja) 2004-11-18 2005-11-17 多段触媒系、ならびにアルカンをアルケンおよびそれらの対応する酸素化生成物へ転化させる方法
JP2008283785A Pending JP2009067808A (ja) 2004-11-18 2008-11-04 多段触媒系、ならびにアルカンをアルケンおよびそれらの対応する酸素化生成物へ転化させる方法

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EP (1) EP1658895A1 (https=)
JP (2) JP4279828B2 (https=)
KR (1) KR100809939B1 (https=)
CN (1) CN1781596A (https=)
BR (1) BRPI0504993A (https=)
TW (1) TWI314876B (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7935654B2 (en) 2006-09-28 2011-05-03 Lg Chem, Ltd. Oxide catalyst and phosphoric oxide catalyst for hydrocarbon steam cracking, method for preparing the same and method for preparing olefin by using the same
KR100948228B1 (ko) * 2006-09-28 2010-03-18 주식회사 엘지화학 탄화수소 수증기 열분해용 인산화물 촉매, 이의 제조방법및 이를 이용한 경질 올레핀의 제조방법
US9404045B2 (en) * 2011-02-17 2016-08-02 AMG Chemistry and Catalysis Consulting, LLC Alloyed zeolite catalyst component, method for making and catalytic application thereof
US9630904B2 (en) 2013-12-24 2017-04-25 Mitsubishi Gas Chemical Company, Inc. Catalyst for use in production of methyl methacrylate, and method for producing methyl methacrylate
CN109661481B (zh) 2016-07-14 2021-11-30 恩特格里斯公司 使用MoOC14的CVD Mo沉积
CN108579801B (zh) * 2018-04-27 2021-03-23 中自环保科技股份有限公司 一种具有良好低温no氧化能力的氧化型催化系统及其制备方法
CN108404975B (zh) * 2018-04-27 2021-03-23 中自环保科技股份有限公司 一种具有良好低温起燃性能的氧化型催化系统及其制备工艺

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2144985A5 (https=) 1971-07-05 1973-02-16 Catalyse Soc Prod Francais
US4732881A (en) * 1986-09-25 1988-03-22 The Abestos Institute Catalysts for up-grading steam-cracking products
US4788371A (en) * 1987-12-30 1988-11-29 Uop Inc. Catalytic oxidative steam dehydrogenation process
GB9226453D0 (en) * 1992-12-18 1993-02-10 Johnson Matthey Plc Metal oxide catalyst
DE10047642A1 (de) * 2000-09-26 2002-04-11 Basf Ag Verfahren zur Dehydrierung von Kohlenwasserstoffen
ZA200209470B (en) * 2001-12-04 2003-06-03 Rohm & Haas Improved processes for the preparation of olefins, unsaturated carboxylic acids and unsaturated nitriles from alkanes.
EP1411043A1 (en) * 2002-10-18 2004-04-21 Rohm And Haas Company Preparation of unsaturated carboxylic acids and unsaturated carboxylic acid esters from alkanes and/or alkenes
JP2005144432A (ja) * 2003-11-18 2005-06-09 Rohm & Haas Co アルカンをアルケン、およびそれらの対応する酸素化生成物に転化するための触媒系

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JP2009067808A (ja) 2009-04-02
CN1781596A (zh) 2006-06-07
TWI314876B (en) 2009-09-21
EP1658895A1 (en) 2006-05-24
BRPI0504993A (pt) 2006-07-04
KR100809939B1 (ko) 2008-03-06
JP2006142295A (ja) 2006-06-08
KR20060055330A (ko) 2006-05-23
TW200624168A (en) 2006-07-16

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