JP4239398B2 - Oil and fat infusion for meat, production method and use - Google Patents

Oil and fat infusion for meat, production method and use Download PDF

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JP4239398B2
JP4239398B2 JP2000342689A JP2000342689A JP4239398B2 JP 4239398 B2 JP4239398 B2 JP 4239398B2 JP 2000342689 A JP2000342689 A JP 2000342689A JP 2000342689 A JP2000342689 A JP 2000342689A JP 4239398 B2 JP4239398 B2 JP 4239398B2
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meat
fat
oil
weight
dispersion
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JP2002142671A (en
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雄三 木曾
基晴 新井
晋也 大野
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NOF Corp
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NOF Corp
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Description

【0001】
【発明の属する技術分野】
本発明は、肉全体に含有する油脂が少なく、スジが多くて硬い低品質な加工畜類肉及びそれを用いた畜類肉食材、及び食肉加工品の食感において改良するための食肉加工品用注入液、その製造方法および前記の注入液を注入してなる加工食肉に関する。
【0002】
【従来の技術】
近年、食事において食肉を味覚的によりおいしくかつ視覚的により高級に見せるため、食肉に本来含有する油脂をさらに追加して注入したり、タンパク質分解酵素を加えて食感を軟らかくしたりして品質を改善することが行われている。
食肉を改善する技術としては、例えば次のものが挙げられる。
(1)特開昭47− 28170号;組織を持ったタンパク質食品の風味及び保水性を改良する方法、
(2)特開昭52−110858号;特別注入肉のタンパク質増強のための改良法、
(3)特開昭55−048370号;合成肉製品の製造方法、
(4)特開昭55−144869号;エマルションの注入による食肉魚肉加工法、
(5)特開昭56−102767号;蛋白質を強化した赤身肉、
(6)特開昭58− 89161号;水中油適型乳化液を食肉に注入する方法、
(7)特開昭58−186863号;霜降り肉の製造法、
(8)特開昭60− 41467号;油脂を加熱溶解して食肉に注入する方法。前記の前記の(1)の技術では、組織状タンパク質によって肉に含まれる保水性は、向上するが、脂肪分が少なくジュウシー感等が不足する問題があった。
前記の(2)、(5)の技術では、タンパク質含量の強化には、効果的であるが、脂肪分が少なくジュウシー感の付与の効果はない問題があった。
前記の(3)の技術では、予め前処理した肉自体を使用しなくてはならなく、その赤身と脂肪乳状液との結合させて得られる製品は、油脂を添加できるものの見た目上、自然のサシ状の油脂とは、かけ離れたものであった。
前記の(4)、(6)、(7)および(8)の技術では、使用する油脂の融点以上の温度で食肉に注入するため、作業工程中に肉の温度が上昇し、食肉内の細菌数の増加や肉の変色の問題等の問題があった。またさらに、前記の(7)の技術では、食肉中でO/Wエマルションを破壊して、脂肪分領域をある程度の大きさで形成するために、見た目脂肪分の多い感じを与える等問題があった。
したがって、従来の技術では解決できていない、低温で作業性がよく、さらに低温での作業時にピックルインジェクターの針の目詰まりが生じないような注入液の改善が求められていた。
【0003】
【発明が解決しようとする課題】
前記のように見た目脂肪分が多くなく、且つ老廃肉や、脂肪分の少ない肉に脂肪を付与して、肉の食感を改善することが望まれていた。
本発明の第1の目的は、前記の問題点を解消し、簡便であり、またインジェクターの針の目詰まり等を生じない作業性のよい食肉用油脂注入液を提供することにある。
また本発明の第2の目的は、前記の問題点を解消し、さらに食感を軟らかくし、見た目もきれいな霜降り状とすることが可能な食肉用油脂注入液を提供することにある。
またさらに本発明の第3の目的は、前記の食肉用油脂注入液の製造方法を提供することにある。
またさらに本発明の第4の目的は、前記の食肉用油脂注入液を注入してなる加工食肉を提供することにある。
【0004】
【課題を解決するための手段】
本発明者らは、前記の問題点に鑑み鋭意検討した結果、特定の油脂へ必要に応じて乳化剤等を特定の組成で配合し、固形油脂の微粒子の分散液とすることにし、また、さらに肉組織の軟化目的として分散液にタンパク質分解酵素を配合することによって前記の問題も改善する知見を得て、本発明を完成するに至った。
【0005】
即ち、本発明は、次の〔1〕〜〔〕である。
〔1〕炭素数12〜18の飽和脂肪酸のトリグリセリド、牛脂、豚脂、馬脂、および羊脂の畜類脂肪群より選択される1種または2種以上である油脂を平均粒径2μm以下の固形油脂分散液として水溶液中に5〜60重量%含有することを特徴とする食肉用油脂注入液であって、前記の油脂の融点以上の温度に加温させて液状とし、乳化剤を用いて乳化液とした後、3〜10℃にまで冷却して製造される食肉用油脂注入液。
〔2〕タンパク質分解酵素0.001〜1.0重量%および乳化剤0.1〜5.0重量%を含有する前記〔1〕の食肉用油脂注入液。
〔3〕タンパク質分解酵素がパパイヤ由来あるいはキウイフルーツ由来のタンパク質分解酵素である前記〔2〕の食肉用油脂注入液。
【0006】
【発明の実施の形態】
本発明の食肉用油脂注入液は、融点25℃以上の油脂を平均粒径2μm以下の固形油脂分散液として液中に5.0〜60.0重量%含有してなる食肉用油脂注入液である。
なおさらに本発明の食肉用油脂注入液は、A;融点25℃以上の油脂5.0〜60.0重量%、B;タンパク質分解酵素0.001〜1.0%および、C;乳化剤0.1〜3.0重量%を主成分として含有してなる食肉用油脂注入液である。
【0007】
本発明に用いる常温で固体状である油脂としては、例えば、炭素数12〜18の飽和脂肪酸のトリグリセリド、牛脂、豚脂、馬脂あるいは、パーム油などのような固形状植物油脂、ナタネ油、大豆油、コーン油、魚油等の液状油を水素添加した油脂、分別やインター反応により融点が25℃以上になった油脂を挙げることができる。
【0008】
本発明に用いるタンパク質分解酵素として、パパイヤおよびキウイフルーツから抽出されるタンパク質分解酵素が挙げられる。
【0009】
本発明に用いる乳化剤としては、例えば、通常食品に使用できる精製された乳化剤が好ましく挙げられる。
具体的には、乳化剤としては食品に使用できる下記ものが好ましく挙げられる。
(1)グリセリン脂肪酸エステル、
(2)ソルビタン脂肪酸エステル、
(3)ショ糖脂肪酸エステル、
(4)プロピレングリコール脂肪酸エステル等の乳化剤、
(5)レシチンまた、脂肪酸塩やタンパク質、
が挙げられる。
【0010】
前記の(1)グリセリン脂肪酸エステルの具体的な例としては、モノグリセリンステアレート、デカグリセリンジオレエート等が挙げられる。
(2)ソルビタン脂肪酸エステルの具体的な例としては、ソルビタンモノステアレート、ソルビタンモノラウレート等が挙げられる。
(3)ショ糖脂肪酸エステルの具体的な例としては、ショ糖モノステアリン酸エステル等が挙げられる。
(4)プロピレングリコール脂肪酸エステルの具体的な例としては、プロピレンモノスレアレート、プロピレンモノオレート等が挙げられる。
(5)レシチンの具体的な例としては、大豆レシチン、卵黄レシチン等が挙げられる。
脂肪酸塩や乳タンパク質の具体的な例としては、ステアリン酸ナトリウム、カゼインナトリウム等が挙げられる。
【0011】
A成分の油脂の融点が25℃より低い場合、インジェクション後油脂がひろがってしまい、きれいな霜降り状にならない。常温で固体状である油脂が5.0重量%未満であると、分散している固形油脂の量が少ないため、それによって得られる効果も極めて少なく、60.0重量%より多くなると、分散液そのものの安定性が望めない。
B成分のタンパク質分解酵素の量については、使用する原料の肉質にも左右されるが0.001重量%未満の場合では、軟化効果が低く、1.0重量%より多く配合すると添加効果に見合うだけの著しい効果が期待できない等の理由から好ましくない。
C成分の乳化剤は、製造方法にもよるが0.1重量%未満の場合は、油脂の高温での乳化分散効果が少なくなり、3.0重量%より多く配合すると乳化剤特有の風味によって食肉の旨味を損ねる、あるいは添加量に見合うだけの著しい効果が期待できない等の理由からも好ましくない。
【0012】
本発明の食肉用の対象としては、牛肉、豚肉、羊肉、馬肉、鹿肉等が挙げられる。
【0013】
本発明の食肉用注入液の製造方法は、前記記載の配合成分を、配合して次の2通りの方法で製造することができる。
第1の方法は、融点25℃以上の油脂を、前記の油脂の融点以上の温度に加温して液状とし、必要に応じて乳化剤を用いて、水中油滴型分散液若しくは乳化液とした後、冷却して分散液中の粒子が、平均粒径2μm以下の固形油脂分散液となるようにした食肉用油脂注入液の製造方法である。
冷却方法・装置は特に限定するものでないが、3〜10℃に急冷することが好ましい。
【0014】
第2の方法は、常温で固体状である油脂を、前記の油脂とドライアイスとを、さらに必要に応じて界面活性剤を用いて、固化後圧縮粉砕し、概ね平均粒径2μm以下の固形油脂粒子とし、これを水中に分散させて分散液とし、フイルターを通して粒径の大きなものを除去してなる、平均粒径2μm以下の固形油脂を含有する食肉用油脂注入液の製造方法である。
【0015】
これらの油脂の分散液は、好ましくは、最大粒径2μm以下の固形油脂分散液とすることがより好ましい。安定性等の点から、さらに好ましくは、最大粒径1μm以下の固形油脂分散液である。
前記の乳化機としては、ホモゲナイザー、ホモミキサー、超音波乳化機等が挙げられる。
前記のフイルターとしては、粒子径が2〜5μmでカットできるポリカーボネート膜等が挙げられる。
前記の方法で処理して得られた分散液は、通常水溶液であり、3〜10℃ぐらいの低温で保存して置くことが好ましい。
【0016】
本発明の食肉用油脂注入液は、前記の配合組成比率に範囲で、本発明の効果を損なわない範囲において、その他の成分を配合してもよい。他の成分としては例えば、ビタミンA、ビタミンB、ビタミンC、ビタミンD、ビタミンE等のビミン類;カルシウム、カリウム、マグネシウム等のミネラル類;ハーブ類、香辛料、糖分、アミノ酸分等を添加混合することもできる。
【0017】
食肉の場合は、特にグレードの低い肉を材料とし、インジェクション等を用いて、温度3〜10℃で、本発明の食肉用油脂注入液を直接肉へ、針から注入することが望ましい。
【0018】
本発明の固形分散液は、食肉との親和性の高い水相が連続相となっており、また、乳化剤の作用により、食肉中に均一に浸透する。これにより食肉油脂は食肉中に分散し、食肉にジュウシー感を付加する。
【0019】
また、注入された油脂粒子は細かく分散れた霜降り状になり、視覚的にも肉の品質を改善できる。
【0020】
【発明の効果】
本発明の食肉用油脂注入液によれば、融点25℃以上の油脂を食肉の品質を低下させずに注入させることが可能であり、異味を残すことなく低品質の食肉にジュウシー感を付与することができる。これにより、一般に脂身が少なく、スジが多くて硬い低品質の食肉をジュウシーでソフトな食肉加工品にすることができる。また、本発明の製造方法によれば、細かな油脂固形分を水系の液に分散して食肉用油脂注入液とするもので、容易に肉中にインジェクションできる注入液を製造することができる。また、前記の食肉用油脂注入液を注入したに加工食肉は、見た目比較的均一に分散されて、脂肪分が多くなく見え、さらに低質な肉質を軟らかくして高級品に見えるようにするので商品価値が大きい。
【0021】
【実施例】
以下、実施例に基づき本発明を更に詳細に説明する。
次に採用した評価方法を示す。
1.乳化液、分散液の粒径の測定;
PARTICLE SIZE DISTRIBUTION ANATLYER(HORIBA製 CAPA700)で分散液の粒子を測定した。
2.分散液の安定性試験方法;
調製した分散液を50mlをサンプルビンに取り、5℃の恒温槽で1カ月静置してから目視で次の評価基準で評価した。
○:上部の油脂の浮きが認められない。
×:上部の油脂の浮きが認められるまたは分離する。
3. インジェクション作業のし易さ
○:目詰まりせずにインジェクションできる。
×:油脂粒子が目詰まりを起こし、連続的に作業ができない。
4.食肉化工品の評価(1)
冷凍した食肉加工品は、その後解凍して、1.5cmの厚さにスライスした後、約180℃の鉄板で焼き、官能試験により評価した。評価基準は次のとおりである。
評価は、10名(19才〜40才男7名、女3名)のパネルにより、比較基準品;前記と同様にして焼いた未処理品(オーストラリア産牛モモ肉)に比べて、食感の軟らかさ感およびジューシー感について評価した。
2点:比較品に比べて格段に良くなった。
1点:良くなった。
0点:変わらない。
−1点:比較品より悪くなった。
5.食肉加工品の評価(2)(視覚的評価)
○:きれいな霜降りが見られる。
△:霜降りが見られるが、自然な外観ではない。
×:霜降りが見られない。
【0022】
比較例1
1.<水中油滴型分散液の調製>
水34.7重量部にグリセリン脂肪酸エステル(理研ビタミン(株)商品名エマルジーMS)0.5重量部、およびカゼインナトリウム(中央商工(株)商品名インスタンラックS)1.5重量部を溶解させた後、約60℃まで加温し、次いで、かき混ぜながら、同温度の牛脂(融点約42℃の精製品)64.3重量部を徐々に加えて20分間の粗乳化を行って水中油滴型乳化液を調製した。その後、約5℃/10分間の冷却速度で5℃まで冷却し、その後5℃で1時間保持して、水中油滴型分散液を調製した。その結果、調製後の乳化液の平均粒径は10.5μmであった。
2.<キウイフルーツ抽出物の調製>
市販のキウイフルーツ(国産のHayward種)を用い、その果肉を約1cm角に切断後、同重量の蒸留水を加えて、日本精機社製ホモジナイザーで10000rpmで15分間粉砕した。粉砕した液状物を遠心分離器を用いて、5000rpmで10分間分離し、上澄み液をキウイフルーツ抽出のタンパク質分解酵素液として5℃に冷却し保存して置いて用いた。
3.<注入液の調製>
前記の水中油滴型乳化液96重量部(液温5℃)に前記のキウイフルーツ抽出液(液温5℃)を4重量部を加えた。
4.<注入処理>
オーストラリア産牛モモ肉(脂肪分含量約3重量%)に公知のピックルインジェクター(フォマコ社製)を用いて、前記の実施例1で調製した注入液を肉100重量部に対して11重量部を3〜10℃で注入し、食肉加工品を得た。
その後−40℃の冷凍庫に1週間放置して凍結した。
5.<加工食肉の評価>
前記の加工肉を1.5cmの厚さに切断し、4〜5℃の冷蔵庫で1日放置して解凍した後、前記の方法により調理して評価した。なお、比較は未処理の肉を用いて行った。結果を表1に示す。
【0023】
比較例2:
比較例1と同様にして、表1に示した組成で油脂分散液を調製した。この分散液の評価、およびそれを用いて比較例1と同様に肉中に注入し、加工食肉の評価を表1に示す。
【0024】
実施例1
水58.0重量部にグリセリン脂肪酸エステル(理研ビタミン(株)商品名エマルジーMS)0.5重量部、およびカゼインナトリウム(中央商工(株)商品名インスタンラックS)1.5重量部を溶解させた後、約60℃まで加温し、次いで、かき混ぜながら、同温度の牛脂(融点約42℃の精製品)45.0重量部を徐々に加えて20分間の粗乳化後、三和機械(株)製圧力式ホモゲナイザーを用いて150kg/cmで均質化し、その後、約5℃/10分間の冷却速度で5℃まで冷却し、水中油滴型分散液を調製した。調製後の分散液の平均粒径は2μmであり、この分散液の評価、およびそれを用いて比較例1と同様に肉中に注入し、加工食肉の評価を表1に示す。
【0025】
実施例2:
実施例1の使用した乳化剤のみをレシチン(日清製油(株)商品名ニッシンレシチンDX)に変更し、実施例1と同様に油脂分散液を調製した。この分散液の評価、およびそれを用いて比較例1と同様に肉中に注入し、加工食肉の評価を表1に示す。
【0026】
実施例3:
実施例1の使用した乳化剤をショ糖エステル(三菱化学フーズ(株)商品名リョートーシュガーエステル)に変更し、また乳化機として特殊機化工業(株)製(TK AUTO.HOMO MIXER)を用いて10000rpmで均質化した以外は、実施例1と同様にして油脂分散液を調製した。この分散液の評価、およびそれを用いて比較例1と同様に肉中に注入し、加工食肉の評価を表1に示す。
【0027】
実施例4:
ドライアイス10mmのスライス板3枚にサンドイッチして牛脂、タンパク質分解酵素及び乳化剤を挟み込み、プレスして固体を粉砕した。これを冷却しながらジェットミル(セイシン企業 STJ-475S)でさらに粉砕し、その後粉砕物を10℃の水中へ投入後、超音波乳化機(BURANSON社製SONIFIER250、目盛6)を用いて粗油脂分散液を調製した。この分散液を平均細孔粒子径2μmのポリカーボネート膜(ニュクリーポアメンブレン、ニュクリポアー社製)に20kg/cm2で通過させた。この分散液の評価を、およびそれを用いて比較例1と同様に肉中に注入し、加工食肉の評価を表1に示す。
【0028】
実施例5:
市販のパパイン[和光純薬工業(株)製]0.01重量部を実施例2の水中油滴型乳化液100重量部に加えて注入液とした。この注入液を対肉10重量%の割合で実施例1と同じオーストラリア産牛モモ肉に注入し、実施例1と同様にして加熱、評価3を行った。結果を表1に示す。
【0029】
【表1】

Figure 0004239398
【0030】
注;なお表に用いた略号はつぎのとおりである。
<油脂>
牛脂;日本油脂(株)社製精製牛脂(融点約42℃の精製品)
サラダ油;日清製油(株)社製精製サラダ脂(融点約−7℃の精製品)
<乳化剤>
モノグリ;グリセリン脂肪酸エステル(理研ビタミン(株)商品名エマルジーMS)、
カゼインNa;カゼインナトリウム(中央商工(株)商品名インスタンラックS)
レシチン;(日清製油(株)商品名ニッシンレシチンDX)、
ショ糖脂肪酸エステル;ショ糖エステル(三菱化学フーズ(株)商品名リョートーシュガーエステル)、
PGエステル;プロピレングリコール脂肪酸エステル(理研ビタミン(株)社製、商品名リケマールPS−100)、
ポリグリ;ポリグリセリン(坂本薬品工業(株)社製、商品名SYグリスターML750)、
<酵素>;前記のキウイフルーツよりの抽出液。
【0031】
以上の結果から、本発明の実施例1〜5は、比較例に比べて食感に優れ視覚的にも高品質な食肉を製造できることがわかる。[0001]
BACKGROUND OF THE INVENTION
The present invention is a low quality processed livestock meat having a small amount of oil and fat contained in the whole meat and having a lot of streaks, a livestock meat food material using the same, and an injection for processed meat products for improving the texture of processed meat products The present invention relates to a liquid, a manufacturing method thereof, and processed meat formed by injecting the above-mentioned injection liquid.
[0002]
[Prior art]
In recent years, in order to make the meat taste better and visually higher in the diet, the quality of the meat can be improved by adding more fats and oils originally contained in the meat or adding a proteolytic enzyme to soften the texture. Improvements are being made.
Examples of techniques for improving meat include the following.
(1) Japanese Patent Application Laid-Open No. 47-28170; a method for improving the flavor and water retention of protein foods having a structure;
(2) JP 52-110858; improved method for protein enhancement of specially injected meat,
(3) JP 55-048370; a method for producing a synthetic meat product,
(4) Japanese Patent Laid-Open No. 55-144869; a method for processing meat and fish by injecting emulsion,
(5) Japanese Patent Laid-Open No. 56-102767; red meat with enhanced protein,
(6) JP 58-89161; a method of injecting an oil-in-water type emulsion into meat.
(7) JP-A-58-186863; method for producing marbled meat,
(8) JP-A-60-41467; a method in which fats and oils are dissolved by heating and poured into meat. In the technique (1), the water retention contained in the meat is improved by the textured protein, but there is a problem that the fat content is small and the juicy feeling is insufficient.
The techniques (2) and (5) described above are effective in enhancing the protein content, but have a problem that there is little fat and no effect of imparting a juicy feeling.
In the technique (3), the pre-treated meat itself must be used, and the product obtained by combining the red meat with the fat milky liquid can be added with fats and oils. The sag-like oil and fat was far away.
In the techniques (4), (6), (7) and (8) described above, since the meat is injected into the meat at a temperature equal to or higher than the melting point of the fats and oils used, the temperature of the meat rises during the work process, There were problems such as an increase in the number of bacteria and discoloration of meat. Furthermore, the technique (7) described above has a problem such as giving a feeling of a large amount of apparent fat in order to destroy the O / W emulsion in the meat and form the fat region with a certain size. It was.
Therefore, there has been a demand for an improved injection solution that is not solved by the prior art and has good workability at low temperatures and does not cause clogging of the needle of the pickle injector when working at low temperatures.
[0003]
[Problems to be solved by the invention]
As described above, it has been desired to improve the texture of meat by imparting fat to waste meat and meat having little fat content.
The first object of the present invention is to provide a fat and oil infusion solution for meat that eliminates the above-mentioned problems, is simple, and does not cause clogging of the needle of an injector and the like and has good workability.
A second object of the present invention is to provide a fat and oil infusion solution for meat that can solve the above-mentioned problems, further soften the texture, and have a beautiful marbling appearance.
Furthermore, the third object of the present invention is to provide a method for producing the above-mentioned meat fat injection solution for meat.
Furthermore, the fourth object of the present invention is to provide a processed meat obtained by injecting the above-described fat and oil injection liquid for meat.
[0004]
[Means for Solving the Problems]
As a result of intensive studies in view of the above-mentioned problems, the present inventors have formulated an emulsifier and the like with a specific composition as necessary into a specific fat and oil to obtain a dispersion of fine particles of solid fat and oil, and further As a result of blending a proteolytic enzyme into the dispersion for the purpose of softening the meat tissue, the inventors have obtained knowledge that the above problem can be improved, and have completed the present invention.
[0005]
That is, this invention is following [1]-[ 3 ].
[1] Solid fat having an average particle size of 2 μm or less, which is one or more selected from triglycerides of saturated fatty acids having 12 to 18 carbon atoms, beef tallow, pork tallow, horse tallow, and animal fat group of sheep fat An oil / fat infusion solution for meat characterized by containing 5 to 60% by weight as an oil / fat dispersion in an aqueous solution, which is heated to a temperature equal to or higher than the melting point of the oil / fat and emulsified using an emulsifier. After that, the fat-and-oil injection liquid for meat manufactured by cooling to 3-10 degreeC.
[2] The fat and oil injection solution for meat according to [1] above, containing 0.001 to 1.0% by weight of a proteolytic enzyme and 0.1 to 5.0% by weight of an emulsifier.
[3] The fat and oil injection solution for meat according to the above [2], wherein the proteolytic enzyme is a papaya-derived or kiwifruit-derived proteolytic enzyme.
[0006]
DETAILED DESCRIPTION OF THE INVENTION
The fat injection liquid for meat of the present invention is a fat injection liquid for meat comprising 5.0 to 60.0% by weight of a fat having a melting point of 25 ° C. or higher as a solid fat dispersion having an average particle diameter of 2 μm or less. is there.
Still further, the fat and oil infusion solution for meat of the present invention includes: A: 5.0 to 60.0% by weight of fats and oils having a melting point of 25 ° C. or higher; B; 0.001 to 1.0% of proteolytic enzyme; It is a fat and oil pouring liquid for meat comprising 1 to 3.0% by weight as a main component.
[0007]
Examples of oils and fats that are solid at room temperature used in the present invention include solid vegetable oils and fats such as triglycerides of saturated fatty acids having 12 to 18 carbon atoms, beef tallow, pork tallow, horse tallow or palm oil, rapeseed oil, Examples include oils and fats obtained by hydrogenating liquid oils such as soybean oil, corn oil and fish oil, and oils and fats having a melting point of 25 ° C. or higher by fractionation or an inter-reaction.
[0008]
Proteolytic enzymes used in the present invention include proteolytic enzymes extracted from papaya and kiwifruit.
[0009]
As the emulsifier used in the present invention, for example, a purified emulsifier that can be usually used in foods is preferably exemplified.
Specifically, preferable examples of the emulsifier include the following that can be used in foods.
(1) glycerin fatty acid ester,
(2) sorbitan fatty acid ester,
(3) sucrose fatty acid ester,
(4) an emulsifier such as propylene glycol fatty acid ester,
(5) Lecithin, fatty acid salts and proteins,
Is mentioned.
[0010]
Specific examples of the (1) glycerol fatty acid ester include monoglycerol stearate and decaglycerol dioleate.
(2) Specific examples of sorbitan fatty acid esters include sorbitan monostearate and sorbitan monolaurate.
(3) Specific examples of sucrose fatty acid esters include sucrose monostearate.
(4) Specific examples of the propylene glycol fatty acid ester include propylene monosaleate and propylene monooleate.
(5) Specific examples of lecithin include soybean lecithin and egg yolk lecithin.
Specific examples of fatty acid salts and milk proteins include sodium stearate and sodium caseinate.
[0011]
When the melting point of the component A oil and fat is lower than 25 ° C., the oil and fat spreads after the injection and does not become a beautiful marbling. If the fat that is solid at room temperature is less than 5.0% by weight, the amount of solid fat that is dispersed is small, so the effect obtained thereby is extremely small, and if it is more than 60.0% by weight, the dispersion The stability of itself cannot be expected.
The amount of the proteolytic enzyme of component B depends on the meat quality of the raw material used, but if it is less than 0.001% by weight, the softening effect is low, and if it is added more than 1.0% by weight, the addition effect is commensurate with the addition effect. It is not preferable because the remarkable effect cannot be expected.
Although the emulsifier of component C depends on the production method, if it is less than 0.1% by weight, the effect of emulsifying and dispersing oils and fats at a high temperature is reduced. This is also undesirable for reasons such as the loss of umami or the inability to expect a significant effect corresponding to the amount added.
[0012]
Examples of the object for meat of the present invention include beef, pork, lamb, horse meat, venison and the like.
[0013]
The method for producing an infusion solution for meat of the present invention can be produced by blending the above-described blending components by the following two methods.
In the first method, an oil having a melting point of 25 ° C. or higher is heated to a temperature equal to or higher than the melting point of the oil and fat to form a liquid, and if necessary, an oil-in-water dispersion or emulsion is obtained using an emulsifier. Then, it is cooled and the manufacturing method of the fats and oils injection | pouring liquid for meats which made the particle | grains in a dispersion liquid become a solid fat dispersion with an average particle diameter of 2 micrometers or less.
Although the cooling method and apparatus are not particularly limited, it is preferable to rapidly cool to 3 to 10 ° C.
[0014]
In the second method, fats and oils that are solid at room temperature are solidified with compression and pulverization after solidifying the above fats and dry ice with a surfactant as required, and a solid having an average particle diameter of 2 μm or less. This is a method for producing a fat and oil pouring liquid for meat containing solid fats and oils having an average particle size of 2 μm or less, which is obtained by making fats and oils particles, dispersing them in water to obtain a dispersion, and removing those having a large particle size through a filter.
[0015]
These oil dispersions are preferably solid oil dispersions having a maximum particle size of 2 μm or less. From the viewpoint of stability and the like, a solid oil dispersion having a maximum particle size of 1 μm or less is more preferable.
Examples of the emulsifier include a homogenizer, a homomixer, and an ultrasonic emulsifier.
Examples of the filter include a polycarbonate film that can be cut with a particle diameter of 2 to 5 μm.
The dispersion obtained by the treatment by the above method is usually an aqueous solution and is preferably stored at a low temperature of about 3 to 10 ° C.
[0016]
The fat and oil pouring liquid for meat of the present invention may be blended with other components within the above-mentioned blending composition ratio and within a range not impairing the effects of the present invention. Other ingredients include, for example, vitamin A, vitamin B, vitamin C, vitamin D, vitamin E and other bimins; calcium, potassium, magnesium and other minerals; herbs, spices, sugar, amino acids, etc. You can also.
[0017]
In the case of meat, it is desirable to inject the meat fat-injection solution of the present invention directly into the meat from the needle at a temperature of 3 to 10 ° C. using injection or the like, particularly with low grade meat.
[0018]
In the solid dispersion of the present invention, an aqueous phase having high affinity with meat is a continuous phase, and penetrates uniformly into meat by the action of an emulsifier. Thereby, meat fats and oils are disperse | distributed in meat, and a juicy feeling is added to meat.
[0019]
In addition, the injected fat and oil particles are in a finely dispersed marbling shape, which can visually improve the quality of the meat.
[0020]
【The invention's effect】
According to the fat and oil infusion solution for meat of the present invention, it is possible to inject fats and oils having a melting point of 25 ° C. or higher without deteriorating the quality of the meat, and imparting a juicy feeling to the low quality meat without leaving an unpleasant taste. be able to. As a result, it is possible to produce a processed meat product that is generally low in fat, hard and low in quality, and is processed into a juicy and soft processed meat. Further, according to the production method of the present invention, fine fat solids are dispersed in an aqueous liquid to obtain a fat infusion for meat, and an infusion that can be easily injected into meat can be produced. In addition, processed meat that has been injected with the above-mentioned fat and oil infusion solution for meat is distributed relatively uniformly in appearance, so that it does not contain a lot of fat, and softens the low-quality meat so that it looks like a high-class product. Great value.
[0021]
【Example】
Hereinafter, the present invention will be described in more detail based on examples.
Next, the adopted evaluation method is shown.
1. Measurement of particle size of emulsions and dispersions;
The particles of the dispersion were measured with PARTICLE SIZE DISTRIBUTION ANATLYER (CAPA700 from HORIBA).
2. Dispersion stability test method;
50 ml of the prepared dispersion was taken in a sample bottle and allowed to stand in a thermostatic bath at 5 ° C. for one month, and then visually evaluated according to the following evaluation criteria.
○: No floating of upper oil or fat is observed.
X: Floating oil or fat at the top is observed or separated.
3. Ease of injection work ○: Injection can be performed without clogging.
X: The fat and oil particles are clogged and cannot be continuously operated.
4). Evaluation of meat products (1)
The frozen processed meat product was then thawed and sliced to a thickness of 1.5 cm, then baked on an iron plate at about 180 ° C. and evaluated by a sensory test. The evaluation criteria are as follows.
Evaluation is based on a panel of 10 people (19-year-old to 40-year-old male, 3 females), comparative reference product; texture compared to untreated product (Australian beef leg meat) baked in the same manner as above The softness and succulent feeling of each were evaluated.
2 points: Significantly better than the comparative product.
1 point: Improved.
0 points: not changed.
-1 point: It was worse than the comparative product.
5. Evaluation of processed meat products (2) (visual evaluation)
○: A beautiful marbling is observed.
Δ: Marbling is observed, but the appearance is not natural.
X: No marbling is observed.
[0022]
Comparative Example 1
1. <Preparation of oil-in-water dispersion>
In 34.7 parts by weight of water, 0.5 part by weight of glycerin fatty acid ester (Riken Vitamin Co., Ltd. trade name Emergy MS) and 1.5 parts by weight of casein sodium (Chuo Shoko Co., Ltd. trade name Instant Rack S) are dissolved. After that, warm to about 60 ° C., then, while stirring, add 64.3 parts by weight of beef tallow (refined product having a melting point of about 42 ° C.) at the same temperature, and perform rough emulsification for 20 minutes to give oil-in-water droplets. A mold emulsion was prepared. Then, it cooled to 5 degreeC with the cooling rate of about 5 degreeC / 10 minutes, and hold | maintained at 5 degreeC for 1 hour after that, and the oil-in-water type dispersion liquid was prepared. As a result, the average particle size of the prepared emulsion was 10.5 μm.
2. <Preparation of kiwifruit extract>
Using commercially available kiwifruit (domestic Hayward seed), the pulp was cut into about 1 cm square, distilled water of the same weight was added, and the mixture was pulverized with a homogenizer manufactured by Nippon Seiki Co., Ltd. at 10,000 rpm for 15 minutes. The crushed liquid was separated using a centrifugal separator at 5000 rpm for 10 minutes, and the supernatant was cooled and stored at 5 ° C. as a proteolytic enzyme solution for kiwifruit extraction.
3. <Preparation of injection solution>
4 parts by weight of the kiwifruit extract (liquid temperature 5 ° C.) was added to 96 parts by weight of the oil-in-water emulsion (liquid temperature 5 ° C.).
4). <Injection process>
Using a known pickle injector (manufactured by Fomaco) for Australian beef leg meat (fat content of about 3% by weight), 11 parts by weight of the infusion prepared in Example 1 above is 100 parts by weight of meat. It inject | poured at 3-10 degreeC, and the processed meat product was obtained.
Then, it was left to stand in a freezer at −40 ° C. for one week and frozen.
5. <Evaluation of processed meat>
The processed meat was cut to a thickness of 1.5 cm, thawed for 1 day in a refrigerator at 4 to 5 ° C., and then cooked and evaluated by the method described above. The comparison was performed using untreated meat. The results are shown in Table 1.
[0023]
Comparative Example 2:
In the same manner as in Comparative Example 1, an oil dispersion was prepared with the composition shown in Table 1. Table 1 shows the evaluation of this dispersion and its use in the same manner as in Comparative Example 1, injecting it into meat.
[0024]
Example 1
In 58.0 parts by weight of water, 0.5 part by weight of glycerin fatty acid ester (Riken Vitamin Co., Ltd. trade name Emergy MS) and 1.5 parts by weight of casein sodium (Chuo Shoko Co., Ltd. trade name Instant Rack S) are dissolved. After that, the mixture was heated to about 60 ° C., and then 45.0 parts by weight of beef tallow (refined product having a melting point of about 42 ° C.) at the same temperature was gradually added while stirring, and after roughly emulsifying for 20 minutes, Homogenization was performed at 150 kg / cm 2 using a pressure homogenizer manufactured by Kogyo Co., Ltd., followed by cooling to 5 ° C. at a cooling rate of about 5 ° C./10 minutes to prepare an oil-in-water dispersion. The average particle size of the prepared dispersion is 2 μm, and the evaluation of this dispersion and the use of this dispersion in the meat in the same manner as in Comparative Example 1 show the evaluation of processed meat in Table 1.
[0025]
Example 2:
Only the emulsifier used in Example 1 was changed to lecithin (Nisshin Oil Co., Ltd. trade name Nissin Lecithin DX), and an oil dispersion was prepared in the same manner as in Example 1. Table 1 shows the evaluation of this dispersion and its use in the same manner as in Comparative Example 1, injecting it into meat.
[0026]
Example 3:
The emulsifier used in Example 1 was changed to sucrose ester (trade name Ryoto Sugar Ester, Mitsubishi Chemical Foods Co., Ltd.). A fat dispersion was prepared in the same manner as in Example 1 except that the mixture was homogenized at 10,000 rpm. Table 1 shows the evaluation of this dispersion and its use in the same manner as in Comparative Example 1, injecting it into meat.
[0027]
Example 4:
Sandwiched on 3 slices of dry ice 10 mm, beef tallow, proteolytic enzyme and emulsifier were sandwiched and pressed to grind the solid. This is cooled and further pulverized with a jet mill (Seishin company STJ-475S), and then the pulverized product is poured into water at 10 ° C., followed by dispersion of crude oil and fat using an ultrasonic emulsifier (SONIFIER 250, scale 6 manufactured by BURANSON). A liquid was prepared. This dispersion was passed through a polycarbonate membrane having an average pore particle diameter of 2 μm (Nucree Pore Membrane, manufactured by Nuclepore) at 20 kg / cm 2 . Evaluation of this dispersion liquid and its use were injected into meat as in Comparative Example 1, and the evaluation of processed meat is shown in Table 1.
[0028]
Example 5:
0.01 parts by weight of commercially available papain [manufactured by Wako Pure Chemical Industries, Ltd.] was added to 100 parts by weight of the oil-in-water emulsion of Example 2 to prepare an injection solution. This injected solution was injected into the same Australian beef leg meat as in Example 1 at a ratio of 10% by weight to the meat, and heated and evaluated in the same manner as in Example 1. The results are shown in Table 1.
[0029]
[Table 1]
Figure 0004239398
[0030]
Note: The abbreviations used in the table are as follows.
<Oil and fat>
Beef tallow; Refined beef tallow (manufactured by Nippon Oil & Fats Co., Ltd.)
Salad oil; refined salad fat (manufactured by Nisshin Oil Co., Ltd.)
<Emulsifier>
Monoglyceride; Glycerin fatty acid ester (trade name Emergy MS, Riken Vitamin Co., Ltd.)
Casein Na; sodium caseinate (trade name: Instant Rack S, Chuo Shoko Co., Ltd.)
Lecithin; (Nisshin Oil Co., Ltd. trade name Nissin lecithin DX),
Sucrose fatty acid ester; sucrose ester (Mitsubishi Chemical Foods Co., Ltd. trade name Ryoto Sugar Ester),
PG ester; propylene glycol fatty acid ester (manufactured by Riken Vitamin Co., Ltd., trade name Riquemar PS-100),
Polyglycerin; polyglycerin (manufactured by Sakamoto Pharmaceutical Co., Ltd., trade name: SY Glister ML750),
<Enzyme>: Extract from the above kiwi fruit.
[0031]
From the above results, it can be seen that Examples 1 to 5 of the present invention are superior in texture to the comparative examples and can produce visually high-quality meat.

Claims (3)

炭素数12〜18の飽和脂肪酸のトリグリセリド、牛脂、豚脂、馬脂、および羊脂の畜類脂肪群より選択される1種または2種以上である油脂を平均粒径2μm以下の固形油脂分散液として水溶液中に5〜60重量%含有することを特徴とする食肉用油脂注入液であって、前記の油脂の融点以上の温度に加温させて液状とし、乳化剤を用いて乳化液とした後、3〜10℃にまで冷却して製造される食肉用油脂注入液。Solid fat dispersion having an average particle size of 2 μm or less of one or more fats and oils selected from triglycerides of saturated fatty acids having 12 to 18 carbon atoms, beef tallow, pork tallow, horse tallow, and sheep fat animal fat group As a fat and oil infusion liquid for meat characterized in that it is contained in an aqueous solution as 5 to 60% by weight, after being heated to a temperature equal to or higher than the melting point of the fat and oil and made into an emulsion using an emulsifier A fat injection solution for meat produced by cooling to 3 to 10 ° C. タンパク質分解酵素0.001〜1.0重量%および乳化剤0.1〜5.0重量%を含有する請求項1記載の食肉用油脂注入液。The fat and oil injection solution for meat according to claim 1, comprising 0.001 to 1.0% by weight of a proteolytic enzyme and 0.1 to 5.0% by weight of an emulsifier. タンパク質分解酵素がパパイヤ由来あるいはキウイフルーツ由来のタンパク質分解酵素である請求項2記載の食肉用油脂注入液。The fat and oil injection solution for meat according to claim 2, wherein the proteolytic enzyme is a proteolytic enzyme derived from papaya or kiwifruit.
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