JP4223796B2 - Anaerobic treatment apparatus and treatment method - Google Patents
Anaerobic treatment apparatus and treatment method Download PDFInfo
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- JP4223796B2 JP4223796B2 JP2002365452A JP2002365452A JP4223796B2 JP 4223796 B2 JP4223796 B2 JP 4223796B2 JP 2002365452 A JP2002365452 A JP 2002365452A JP 2002365452 A JP2002365452 A JP 2002365452A JP 4223796 B2 JP4223796 B2 JP 4223796B2
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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Description
【0001】
【発明の属する技術分野】
本発明は、各種の工場、下水、し尿、畜産業施設等から排出される有機性の廃水又は有機性の廃棄物等を対象として、これ等の廃棄物等を無害化する嫌気性汚泥床処理装置に関し、更に詳しくは、従来の処理装置よりコンパクトで、気・液・固(液)分離部(以下、「GSS」とも記す)を多段に有する嫌気性汚泥床処理装置に関する。
【0002】
【従来の技術】
有機性廃水及び/又は有機性廃棄物の処理方法の一つである嫌気性処理には様々な装置形状
(構成)があり、この処理方法の中で、気体・液体及び固体を分離させる必要がある嫌気性処理装置(以下、「装置」と略記することがある)の例としては、上向流嫌気性汚泥床(以下、「UASB」とも記す)、膨張汚泥床(以下、「EGSB」とも記す)が挙げられる。これらは、リアクター内にメタン菌などの嫌気性菌をグラニュール状に造粒化することにより、リアクター内のメタン菌濃度を高濃度に維持できるという特徴を持ち、対象原水が高濃度な場合でも効率よく処理出来ることが知られている(特許文献1)。
【0003】
これらの装置のリアクター内には、気体、液体及び固体を分離する気液固分離装置が必須であり、この形状や構成は様々である。この気液固分離装置をリアクター内へ多段に構成した場合は、その設置水深の影響から各分離ガスを水封させながら捕集する必要があるため、別途に水封槽を要する。この水封槽は、水圧を確保するために各気液固分離装置からリアクター水面までの高さ以上を要し、また、水封槽内の捕集ガス密度を一定以下にする必要もあるためリアクター本体の1/4〜1/2程度の大きな容量が必要である。
【0004】
また、廃水の性状によっては嫌気性処理の前に酸発酵処理が必要であり、この場合、リアクターの前段へ別途に滞留時問を1〜4時間程度とした酸発酵槽を設置している。そして、前記処理法を具体化した装置では、重クロム酸カリウムを酸化剤として用いて測定したCODCr(以下、単に「COD」とも記す)の容積負荷が10〜15kg/m3/dの廃水、廃棄物であっても、高率よく運転できることが知られている。
【0005】
【特許文献1】
特開2002−79291号公報
【0006】
【発明が解決しようとする課題】
しかしながら、多段化した上向流嫌気性汚泥床法(UASB)の装置にあっては、なお、以下に記載するような、問題点がある。
(a)対象とする原水性状によっては嫌気性処理の前に酸発酵槽が別途に必要となる。
(b)嫌気性処理で発生するガスをリアクター内へ多段に設置した気液固分離装置で分離する場合、設置水深の影響から分離ガスを水封捕集する槽が別途に必要となる。
本発明は、これらの問題点を解消し、酸発酵槽が別途に必要とすることなく、嫌気性処理と酸発酵処理を行い得るようにするとともに、リアクター内に設ける気液固分離装置で分離されたガスを、区画した部分へ容易に導入させるようにして、装置をコンパクト化することを課題とするものである。
【0007】
【課題を解決するための手段】
本発明は、下記の手段により前記の課題を解決した。
(1)有機性廃水及び/又は有機性廃棄物を嫌気性廃水処理により処理する嫌気性処理装置において、該嫌気性処理装置内を隔壁により内胴と外胴に区画し、内胴と外胴との間の該隔壁に該内胴中央部から底部の間に少なくとも1つ以上の開口を有し、かつ該有機性廃水及び/又は有機性廃棄物の流入部を前記内胴の上部、処理液流出部を該外胴の上部に有し、かつ装置内で発生するガスを外胴及び内胴の気相部に捕集させ、該捕集部にガス排出口を有し、かつ前記隔壁及び / 又は外胴の槽壁に複数取り付けられた下方にのびる邪魔板と前記隔壁及び / 又は外胴の槽壁によって形成された領域であり、該領域の上方が発生ガスの集積部である多段の気体、液体及び固体を分離する気液固分離装置を前記外胴に有し、かつ該気液固分離装置と内胴を結んでおり内胴内に開口して、各該気液固分離装置で分離された気体を前記内胴へ水封させながら導入する水封管を設けたことを特徴とする嫌気性処理装置。
【0008】
(2)前記嫌気性処理装置において、有機性廃水及び/又は有機性廃棄物を内胴へ導入し、内胴部分を有機性廃棄物の可溶化及び酸発酵を含む、嫌気性処理の前処理装置とすることを特徴とする請求項1に記載の嫌気性処理装置。
【0010】
【発明の実施の形態】
本発明の実施の形態を、図面を参照して説明するが、本発明の範囲はこれに限定されない。
図1〜図3は、嫌気性処理を実施するのに好ましい本発明の嫌気性処理装置の一形態の概要を例示した図である。
原水2は、原水管10から流入し、リアクター1内を区画した内胴15の内側へ投入する。この内胴15は、流入した原水をリアクター底部21へ導入する目的と、嫌気性処理の酸発酵を行う処理を兼ね備えている。底部21へ導入され、酸発酵が行われた廃水は、リアクター1の内胴15と外胴16を区画する隔壁18に内胴15の中央部より下に少なくとも1つ以上設置する開口20から外胴16に入り、上向き流でリアクターの内胴15と外胴16を通過し、リアクター1上部の処理水管11より処理水3を排出する。
【0011】
嫌気性処理は、この内胴15と外胴16に充填したグラニュール状の嫌気性菌により行われ、その結果、有機性廃棄物が分解されガスが発生する。発生ガスは内胴15と外胴16とを区画する隔壁18へ多段に設置する各気液固分離装置13で分離される。各気液固分離装置13で分離された分離ガス4は、各気液固分離装置13と内胴15を結ぶ水封管14を通過することで内胴15へ導入し、気泡17として上昇し、リアクター1頂部付近のガス流出管12から系外に排出する。なお、各気液固分離装置13は、かならずしも前記隔壁18に設ける必要はなく、外胴16内に設けておいて、各気液固分離装置13で分離された分離ガス4を送る水封管14を内胴15内に配置するようにすればよい。
【0012】
また、多段に設置される各気液固分離装置13の邪魔板は、グラニュールの沈積を防止するため、固定する壁との角度が45°以下、好ましくは35°以下とするのがよい。又、嫌気性処理を行う場合、内胴15と外胴16の間の液流速は、0.1〜10m/h、好ましくは、1〜3m/hとなるように調節すればよい。
【0013】
図1、図2及び図3の装置は、各気液固分離装置13の設置構成に違いがあり、図1は内胴15へ、図2は内胴15及び外胴16へ、図3は外胴16へ気液固分離装置13をそれぞれ設置したことを示すが、その段数および内胴15及び外胴16への設置構成は目的に応じて、適宜変更してもよく限定されるものではない。リアクター1内における気液固分離装置13の固定箇所については種々の構造を採用し得るものであり、図1では内胴15から外胴16への隔壁18に固定しており、図2では隔壁18及び槽壁19に固定しており、また、図3では槽壁19に固定しているものである。その他、図4に示すように、隔壁18及び槽壁19だけではなく隔壁18と槽壁19の中間位置に配置してもよい。なお、装置における内胴15と外胴16の配置関係は、二重円筒でも、またその他のどのような構造でもよい。
【0014】
本発明の対象となる嫌気性処理は、30℃〜35℃を至適温度とした中温メタン発酵処理、50℃〜55℃を至適温度とした高温メタン発酵処理など、全ての温度範囲の嫌気性処理を対象としている。嫌気性菌からなるグラニュール汚泥を投入し、有機性廃棄物などを含んだ原水をリアクターヘ導入する。更に、原水を処理水の循環液や系外から別に供給する希釈水等により、必要に応じて適宜希釈を行ってもよい。
【0015】
【実施例】
以下に、実施例を挙げて本発明を更に具体的に説明するが、本発明の範囲はこの実施例により限定されるものではない。
【0016】
実施例1
図1に示した内胴と外胴の間に内胴の隔壁から気液固分離装置13(以下、「GSS」ともいう)を3個設け、装置側壁と邪魔板との角度(θ)を35°とした嫌気性処理装置(リアクター)を使用した。
リアクターの断面積は4.52m2(2.4mφ)であり、その内胴部の断面積は0.78m2 であり、高さは12.8m(容量53.38m3)である。またGSS投影面積は3.30m2(内胴と外胴の間の断面積の67.3%)で実験した。原水は、リアクターの原水管10より流入し、リアクター上部のガス流出管12より分離ガスを排出する。
【0017】
本発明においては、上記したように装置内を内胴と外胴に区画することにより、リアクターが酸発酵+嫌気性処理+水封捕集の三つの機能を有している。そして、分離されたガスは系外に排出され、精製貯留設備へ送られる。
リアクター内の水温は、35℃になるように温度制御した。原水には、有機性廃水(COD7000mg/リットル)を用いた。通水速度を1.5〜3.0m/hに調整し、処理水COD濃度を見ながら、COD負荷量を40Kg/m3 /dまで徐々に上げた。実験経過後、約120日目までは略々同じ負荷量で処理できた。
【0018】
比較例1
比較例として、酸発酵槽、邪魔板の角度と断面積が本発明と同じGSS部を有するリアクター(嫌気性処理槽)及び水封槽の処理フローからなる従来法の嫌気性処理装置を使用した。この装置では、実施例1と同じ原水は酸発酵槽に導入され、次にリアクターで嫌気性処理が行われる。発生した分離ガスは水封槽に移送され、最後に精製、貯留設備へ送られる。
【0019】
酸発酵槽、リアクター及び水封槽の装置面積の組み合わせを各種変更して、本発明の実施例1と同じ処理結果が得られる条件の装置面積を検討して、酸発酵槽=1.96m2 (1.4m幅×1.4m長さ)、リアクター=3.8m2 (2.2mφ)及び水封槽=0.785m2 (1.0mφ)の組み合わせのものを用いた。これは検討によると最小装置面積のものである。その場合、合計装置面積は6.545m2 となった。
【0020】
以上の実施例1と比較例1の結果から、本発明の嫌気性処理装置(リアクター)は従来の装置の約三分の二の設置面積で少なくとも同等の処理結果が得られた。また、嫌気性処理装置内を内胴と外胴に区画し内胴中央部から底部の間に少なくとも1つ以上の開口を有する構造とすることにより同一リアクター内で「前処理」、「嫌気性処理」及び「発生ガスの水封・捕集」が可能となり、リアクターのコンパクト化が達成された。
【0021】
しかも、従来法では酸発酵槽内を混合する攪拌機、リアクターへ移送するポンプ及び制御器が必要であったが、本発明法では内胴の内側で分離したガスと内胴へ導入した廃水がクロスフローとなるため攪拌機が不要であり、また、内胴を酸発酵槽として利用するため移送ポンプ、制御器、移送配管も不要となり、装置のコストを大幅に圧縮できることが判明した。
【0022】
【発明の効果】
従来の嫌気性処理装置では、酸発酵槽内を混合する攪拌機、リアクターへ移送するポンプ及び制御器が必要であったが、本発明では内胴の内側で分離したガスと内胴へ導入した廃水がクロスフローとなるため攪拌機が不要となり、又、内胴を酸発酵槽として利用するため移送ポンプ、制御器、移送配管も不要となったため、リアクターの大幅なコンパクト化が可能となった。
又、高いCOD負荷においても、安定した処理を行うことができる嫌気性処理装置を提供することができ、有機物負荷が高くても常時安定した有機物の処理結果が得られた。
【図面の簡単な説明】
【図1】内胴部の隔壁に気液固分離装置13を設けた本発明の一実施態様を示す嫌気性処理装置の概略説明図である。
【図2】内胴部の隔壁及び外胴部の双方に気液固分離装置13を設けた本発明の一実施態様を示す嫌気性処理装置の概略説明図である。
【図3】外胴に気液固分離装置13を設けた本発明の一実施態様を示す嫌気性処理装置の概略説明図である。
【図4】内胴部の隔壁、外胴部の槽壁及び隔壁と槽壁との中間位置に気液固分離装置13を設けた本発明の一実施態様を示す嫌気性処理装置の概略説明図である。
【符号の説明】
1 リアクター
2 原水(有機性廃水)
3 処理水
4 分離ガス
10 原水管
11 処理水管
12 ガス流出管
13 気液固分離装置
14 水封管
15 内胴
16 外胴
17 気泡
18 隔壁
19 槽壁
20 開口
21 底部[0001]
BACKGROUND OF THE INVENTION
The present invention is intended for organic wastewater or organic waste discharged from various factories, sewage, human waste, livestock industry facilities, etc., and anaerobic sludge bed treatment that renders these wastes harmless. More particularly, the present invention relates to an anaerobic sludge bed processing apparatus that is more compact than conventional processing apparatuses and has multiple stages of gas / liquid / solid (liquid) separation units (hereinafter also referred to as “GSS”).
[0002]
[Prior art]
Anaerobic treatment, which is one of the treatment methods for organic wastewater and / or organic waste, has various apparatus shapes (configurations). In this treatment method, it is necessary to separate gas, liquid and solid. Examples of a certain anaerobic treatment apparatus (hereinafter sometimes abbreviated as “apparatus”) include an upflow anaerobic sludge bed (hereinafter also referred to as “UASB”) and an expanded sludge bed (hereinafter referred to as “EGSB”). Note). These have the feature that the concentration of methane bacteria in the reactor can be maintained at a high level by granulating anaerobic bacteria such as methane bacteria in the reactor, even when the target raw water is at a high concentration. It is known that it can process efficiently (patent document 1).
[0003]
In the reactors of these devices, a gas-liquid solid separation device that separates gas, liquid, and solid is indispensable, and its shape and configuration are various. When this gas-liquid solid separation apparatus is configured in multiple stages in the reactor, it is necessary to collect each separation gas while sealing with water due to the influence of the installation water depth, so a separate water-sealed tank is required. This water-sealed tank requires more than the height from each gas-liquid solid separation device to the reactor water surface to secure the water pressure, and it is also necessary to keep the density of collected gas in the water-sealed tank below a certain level. A large capacity of about 1/4 to 1/2 of the reactor body is required.
[0004]
Further, depending on the properties of the wastewater, acid fermentation treatment is required before the anaerobic treatment, and in this case, an acid fermentation tank having a residence time of about 1 to 4 hours is separately installed in the previous stage of the reactor. In the apparatus embodying the treatment method, waste water having a volumetric load of COD Cr (hereinafter also simply referred to as “COD”) measured using potassium dichromate as an oxidizing agent is 10 to 15 kg / m 3 / d. It is known that even waste can be operated with high efficiency.
[0005]
[Patent Document 1]
JP-A-2002-79291 [0006]
[Problems to be solved by the invention]
However, the upward flow anaerobic sludge bed (UASB) apparatus having multiple stages still has problems as described below.
(A) An acid fermenter is separately required before anaerobic treatment depending on the target raw water state.
(B) When the gas generated in the anaerobic treatment is separated by a gas-liquid solid separation device installed in multiple stages in the reactor, a separate tank for collecting and separating the separated gas is required due to the influence of the installation water depth.
The present invention eliminates these problems, enables an anaerobic treatment and an acid fermentation treatment to be performed without requiring an acid fermentation tank separately, and separates them with a gas-liquid solid separation device provided in the reactor. It is an object of the present invention to make the apparatus compact by easily introducing the generated gas into the partitioned part.
[0007]
[Means for Solving the Problems]
The present invention has solved the above problems by the following means.
(1) In an anaerobic treatment apparatus for treating organic wastewater and / or organic waste by anaerobic wastewater treatment, the anaerobic treatment apparatus is divided into an inner trunk and an outer trunk by a partition, and the inner trunk and the outer trunk The partition between the inner cylinder has at least one opening between the center and the bottom of the inner cylinder, and the inflow part of the organic waste water and / or organic waste is treated at the upper part of the inner cylinder. has a liquid outlet portion in the upper portion of the outer cylinder, and to collect the gas generated in the apparatus in the gas phase portion of the outer cylinder and inner cylinder, have a gas outlet in the collecting portion, and the partition wall And / or a region formed by a plurality of baffle plates extending downwardly attached to the tank wall of the outer shell and the partition wall and / or the tank wall of the outer shell, and the upper part of the region is a multistage where the generated gas is accumulated A gas-liquid solid separation device for separating the gas, liquid and solid in the outer cylinder, and the gas-liquid solid separation device and the inner cylinder Open into cages within the barrel Nde binding, anaerobic treatment apparatus, characterized in that the gas separated in the gas-liquid-solid separation device provided with a water seal tube for introducing while water seal into said cylinder.
[0008]
(2) In the anaerobic treatment apparatus, organic waste water and / or organic waste is introduced into the inner body, and the inner body is pretreated for anaerobic treatment including solubilization of organic waste and acid fermentation. anaerobic treatment apparatus according to
[0010]
DETAILED DESCRIPTION OF THE INVENTION
Embodiments of the present invention will be described with reference to the drawings, but the scope of the present invention is not limited thereto.
1 to 3 are diagrams illustrating an outline of an embodiment of an anaerobic treatment apparatus of the present invention that is preferable for carrying out an anaerobic treatment.
The
[0011]
The anaerobic treatment is performed by the granular anaerobic bacteria filled in the
[0012]
In addition, the baffle plates of the gas-liquid
[0013]
1, 2, and 3 are different in the installation configuration of each gas-liquid
[0014]
The anaerobic treatment that is the subject of the present invention is an anaerobic treatment in all temperature ranges, such as a medium temperature methane fermentation treatment with an optimum temperature of 30 ° C. to 35 ° C., and a high temperature methane fermentation treatment with an optimum temperature of 50 ° C. to 55 ° C. It is intended for sex processing. Granule sludge composed of anaerobic bacteria is introduced, and raw water containing organic waste is introduced into the reactor. Furthermore, the raw water may be appropriately diluted as necessary with a circulating solution of treated water, dilution water supplied separately from outside the system, or the like.
[0015]
【Example】
Hereinafter, the present invention will be described more specifically with reference to examples. However, the scope of the present invention is not limited to the examples.
[0016]
Example 1
Three gas-liquid solid separation devices 13 (hereinafter also referred to as “GSS”) are provided from the inner cylinder partition between the inner cylinder and the outer cylinder shown in FIG. 1, and the angle (θ) between the apparatus side wall and the baffle plate is set. An anaerobic treatment apparatus (reactor) at 35 ° was used.
The cross-sectional area of the reactor is 4.52 m 2 (2.4 mφ), the cross-sectional area of its inner trunk is 0.78 m 2 , and the height is 12.8 m (capacity 53.38 m 3 ). The GSS projection area was 3.30 m 2 (67.3% of the cross-sectional area between the inner cylinder and the outer cylinder). The raw water flows in from the
[0017]
In the present invention, the reactor has three functions of acid fermentation + anaerobic treatment + water seal collection by partitioning the inside of the apparatus into an inner cylinder and an outer cylinder as described above. The separated gas is discharged out of the system and sent to the refined storage facility.
The water temperature in the reactor was controlled to 35 ° C. Organic waste water (COD 7000 mg / liter) was used as raw water. The water flow rate was adjusted to 1.5 to 3.0 m / h, and the COD load was gradually increased to 40 kg / m 3 / d while observing the treated water COD concentration. After the experiment, it was possible to process with substantially the same load until about 120 days.
[0018]
Comparative Example 1
As a comparative example, an acid fermentation tank, a reactor (anaerobic treatment tank) having the same GSS part as that of the present invention in the angle and cross-sectional area of the baffle plate, and a conventional anaerobic treatment apparatus comprising a processing flow of a water-sealed tank were used. . In this apparatus, the same raw water as in Example 1 is introduced into the acid fermenter, and then anaerobic treatment is performed in the reactor. The generated separation gas is transferred to a water-sealed tank and finally sent to a purification and storage facility.
[0019]
Various combinations of the device areas of the acid fermenter, reactor, and water-sealed tank were changed, and the device area under the condition that the same treatment result as that of Example 1 of the present invention was obtained was examined. Acid fermenter = 1.96 m 2 (1.4 m wide × 1.4 m in length), it was used in combination of the reactor = 3.8m 2 (2.2mφ) and Mizufuso = 0.785m 2 (1.0mφ). This is the smallest device area according to the study. In that case, the total device area was 6.545 m 2 .
[0020]
From the results of Example 1 and Comparative Example 1 described above, the anaerobic treatment apparatus (reactor) of the present invention obtained at least the same treatment result with about two-thirds the installation area of the conventional apparatus. In addition, the anaerobic treatment device is divided into an inner cylinder and an outer cylinder, and a structure having at least one opening between the center and the bottom of the inner cylinder is used to perform “pretreatment” and “anaerobic” in the same reactor. Treatment and water sealing and collection of generated gas became possible, and the reactor was made compact.
[0021]
Moreover, in the conventional method, a stirrer for mixing the inside of the acid fermenter, a pump for transferring to the reactor, and a controller are required, but in the method of the present invention, the gas separated inside the inner cylinder and the waste water introduced into the inner cylinder are crossed. Since it becomes a flow, a stirrer is unnecessary, and since the inner drum is used as an acid fermentation tank, a transfer pump, a controller and a transfer pipe are also unnecessary, and it has been found that the cost of the apparatus can be greatly reduced.
[0022]
【The invention's effect】
In the conventional anaerobic treatment apparatus, a stirrer for mixing the inside of the acid fermentation tank, a pump for transferring to the reactor, and a controller were required. In the present invention, the gas separated inside the inner cylinder and the waste water introduced into the inner cylinder Since the cross flow, the agitator becomes unnecessary, and since the inner cylinder is used as an acid fermentation tank, the transfer pump, controller, and transfer piping are also unnecessary, so that the reactor can be greatly downsized.
In addition, an anaerobic treatment apparatus capable of performing stable treatment even at a high COD load can be provided, and a stable treatment result of organic matter can be obtained even when the load on organic matter is high.
[Brief description of the drawings]
FIG. 1 is a schematic explanatory view of an anaerobic treatment apparatus showing an embodiment of the present invention in which a gas-liquid
FIG. 2 is a schematic explanatory view of an anaerobic treatment apparatus showing an embodiment of the present invention in which a gas-liquid
FIG. 3 is a schematic explanatory view of an anaerobic treatment apparatus showing an embodiment of the present invention in which a gas-liquid
FIG. 4 is a schematic illustration of an anaerobic treatment apparatus showing an embodiment of the present invention in which a gas-liquid
[Explanation of symbols]
1
3 treated water 4
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CN102276077A (en) * | 2011-07-14 | 2011-12-14 | 浙江工商大学 | Aerobic activated sludge mud-water separation device |
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