JP4099120B2 - Hair cosmetics - Google Patents

Description

  The present invention is excellent in stretch, slipperiness and soft feel when applied to wet hair, and gives a smooth feel without squeak when rinsing, and further, a smooth feel without being sticky to the hair after drying. It is related with the hair cosmetics which can provide a feeling and a moderate unity feeling.

  In recent years, along with the trend of hair coloring, damages such as hair loss due to coloring and permanent web treatment, difficulty in cohesion, and the like are increasing. For this reason, it is calculated | required that hair cosmetics can provide favorable slipperiness and a softness | flexibility with respect to damaged hair from the time of wet to the time of drying. On the other hand, stickiness is avoided because of touch and visual problems, and many hair cosmetics contain silicones in order to give smoothness to the hair after drying. However, when silicones are blended, there is a problem that squeaky sensation occurs during rinsing, and when the blending amount is increased or when highly polymerized silicones are used, they are uniformly attached to the hair. There was a problem that it was not possible to cause stickiness and deterioration of gloss.

As a hair treatment agent, a technique in which a low polymerization silicone or a volatile silicone is used in combination with a high polymerization dimethyl silicone gum is known (for example, see Patent Documents 1 and 2). However, in these hair treatment agents, due to the use of silicone gum with a high degree of polymerization, the elongation at the time of application, the finger's fingering from the time of application to the time of rinsing, the flexibility is inferior, the squeaky feeling at the time of rinsing and drying There were problems such as a sticky feeling after medium to dry.
Japanese Unexamined Patent Publication No. 1-139522 Japanese Unexamined Patent Publication No. 1-113311

  The present invention is excellent in stretch, slipperiness and soft feel when applied to wet hair, and gives a smooth feel without squeak when rinsing, and further, a smooth feel without being sticky to the hair after drying. It aims at providing the hair cosmetics which can provide a feeling and a moderate unity feeling.

  The present inventor employs dimethylpolysiloxane having a lower degree of polymerization than the silicone gum used in the above-mentioned prior art and having a number average polymerization degree in the range of 1000 to 3800, to which low-polymerized dimethylpolysiloxane and cyclic silicone are added. It discovered that the said subject was solved by combining.

  That is, the present invention includes the following components (A) to (C):

〔式中、ａは1000〜3800の数平均重合度を示す。〕 (A) Dimethylpolysiloxane represented by the following general formula (1)

[In formula, a shows the number average degree of polymerization of 1000-3800. ]

〔式中、ｂは10〜800の数平均重合度を示す。〕 (B) Dimethylpolysiloxane represented by the following general formula (2)

[Wherein b represents a number average degree of polymerization of 10 to 800. ]

〔式中、ｃは３〜７の数平均重合度を示す。〕
を含有し、組成物中の成分(A)、成分(B)、成分(C)の含有量をそれぞれ(A)重量％、(B)重量％、(C)重量％としたとき、〔(B)＋(C)〕／(A)≧１である水性毛髪化粧料を提供するものである。 (C) Cyclic dimethylpolysiloxane represented by the following general formula (3)

[In formula, c shows the number average degree of polymerization of 3-7. ]
When the contents of component (A), component (B), and component (C) in the composition are (A) wt%, (B) wt%, and (C) wt%, respectively, B) + (C)] / (A) ≧ 1 is provided.

  The hair cosmetic composition of the present invention is excellent in elongation, slipperiness and softness when applied to wet hair, and gives a smooth feel without squeaking when rinsing, and further, the hair after drying is not sticky and smooth. Can give a soft feeling, moist feeling, and a moderate feeling of unity.

  As the component (A) dimethylpolysiloxane, those having a number average polymerization degree of 1000 to 3800 are used, and those having a number average polymerization degree of 1500 to 3500, particularly 1700 to 3300 are preferred.

  The dimethylpolysiloxane of component (A) may be used in combination of two or more, and the content thereof is good for fingering when applied to wet hair and when rinsing, and the mass of hair after drying From the viewpoint of goodness, it is preferably 0.05 to 6% by weight, more preferably 0.1 to 5% by weight, and particularly preferably 0.1 to 4% by weight in the hair cosmetic composition of the present invention.

  As the component (B) dimethylpolysiloxane, those having a number average polymerization degree of 10 to 800 are used, and those having a number average polymerization degree of 50 to 700, particularly 100 to 650 are preferred.

Two or more kinds of the dimethylpolysiloxane of the component ( B ) may be used in combination, and the content of the dimethylpolysiloxane in the hair cosmetic composition of the present invention is from the viewpoint of no squeaking during rinsing and imparting softness. The content is preferably 0.1 to 10% by weight, more preferably 0.5 to 8% by weight, and particularly preferably 0.7 to 6% by weight.

  As the cyclic dimethylpolysiloxane of component (C), those having a number average polymerization degree of 3 to 7 are used, and preferred are octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane. .

  Two or more kinds of the cyclic dimethylpolysiloxane of component (C) may be used in combination, and the content of the cyclic dimethylpolysiloxane of the present invention is from the viewpoint of imparting smoothness during rinsing and non-stickiness of hair after drying. It is preferably 0.1 to 10% by weight in the hair cosmetic, more preferably 0.5 to 8% by weight, and particularly preferably 0.7 to 6% by weight.

  The relationship between the weights of component (A), component (B) and component (C) is as follows: from the viewpoint of suppression of squeaky sensation from the time of application to rinsing and the absence of stickiness of the hair after drying [(B) + ( C)] / (A) ≧ 1, but preferably 4 ≧ [(B) + (C)] / (A) ≧ 1.1.

〔式中、Ａは水素原子、又は総炭素数12〜24の直鎖若しくは分岐鎖の飽和若しくは不飽和の、アミド基、N-炭化水素カルバモイル基、アシルオキシ基若しくは炭化水素オキシ基を示し、Ｂは炭素数１〜22の２価の直鎖又は分岐鎖の飽和又は不飽和の炭化水素基を示し、Ｒ¹、Ｒ²及びＲ³は少なくとも１個が総炭素数１〜24の直鎖又は分岐鎖のアルキル基又はアルケニル基を示し、残りは炭素数１〜３のアルキル基を示し、Ｘ^-は無機又は有機アニオンを示す。〕

〔式中、Ａ及びＢは前記と同じ意味を示し、Ｒ⁴及びＲ⁵は独立して炭素数１〜４のアルキル基を示す。〕 The hair cosmetic composition of the present invention has a quaternary ammonium salt represented by the following general formula (4) or a general formula (5) as a component (D) from the viewpoint of providing a supple finish and gloss. It is preferable to contain the tertiary amine type compound or its salt represented.

[In the formula, A represents a hydrogen atom or a linear or branched saturated or unsaturated amide group, N-hydrocarbon carbamoyl group, acyloxy group or hydrocarbon oxy group having a total carbon number of 12 to 24; Represents a divalent straight chain or branched chain saturated or unsaturated hydrocarbon group having 1 to 22 carbon atoms, and at least one of R ¹ , R ² and R ³ is a straight chain having 1 to 24 carbon atoms in total or A branched alkyl group or an alkenyl group is shown, the remainder is an alkyl group having 1 to 3 carbon atoms, and X ⁻ is an inorganic or organic anion. ]

[Wherein, A and B have the same meaning as described above, and R ⁴ and R ⁵ independently represent an alkyl group having 1 to 4 carbon atoms. ]

  The quaternary ammonium salt (4) includes mono long chain alkyl (C12-28) quaternary ammonium salt, di long chain alkyl (C12-28) quaternary ammonium salt, branched chain alkyl (C12-12). 28) Quaternary ammonium salt, alkylamide (C12-28) alkylene (C1-5) quaternary ammonium salt, N-hydrocarbon (C12-28) carbamoylalkylene (C1-5) Examples include quaternary ammonium salts, acyl (C12-28) oxyalkylene (C1-5) quaternary ammonium salts, and hydrocarbon (C12-28) oxyalkylene quaternary ammonium salts.

  Mono long chain alkyl (C12-28) quaternary ammonium salts include stearyl trimethylammonium chloride, myristyltrimethylammonium chloride, cetyltrimethylammonium chloride, aralkyltrimethylammonium chloride, behenyltrimethylammonium chloride, lauryltrimethylammonium chloride, N -Stearyl-N, N, N-tri (polyoxyethylene) ammonium chloride (total 3 mol addition). Di long-chain alkyl (C12-28) quaternary ammonium salts include distearyldimethylammonium chloride, dioleyldimethylammonium chloride, dipalmitylmethylhydroxyethylammonium methosulfate, diisostearyldimethylammonium methosulfate, di [ Examples include (2-dodecanoylamino) ethyl] dimethylammonium chloride, di [(2-stearoylamino) propyl] dimethylammonium etosulphate, and the like. Examples of branched alkyl (C12-C28) quaternary ammonium salts include 2-decyltetradecyltrimethylammonium chloride, 2-dodecylhexadecyltrimethylammonium chloride, di-2-hexyldecyldimethylammonium chloride, di-2-octyl And dodecyldimethylammonium chloride. Examples of the alkylamide (carbon number 12 to 28) alkylene (carbon number 1 to 5) quaternary ammonium salt include stearamide propyl quaternary ammonium salt. Examples of N-hydrocarbon (C12-28) carbamoylalkylene (C1-5) quaternary ammonium salts include N-stearylcarbamoylpropyl quaternary ammonium salts. Examples of acyl (C12-28) oxyalkylene (C1-5) quaternary ammonium salts include stearoxypropyl quaternary ammonium salts. Examples of the hydrocarbon (12 to 28 carbon atoms) oxyalkylene (1 to 5 carbon atoms) quaternary ammonium salt include octadecyloxypropyltrimethylammonium chloride.

In the tertiary amine type compound (5), when A is other than a hydrogen atom, A is preferably an amide group or a hydrocarbon oxy group having a total carbon number of 14 to 22, particularly a total carbon number of 18 to 22, Those in which the hydrocarbon part is saturated, in particular those having a straight chain, are preferred. In this case, B is particularly preferably a trimethylene group. When A is a hydrogen atom, B is preferably a group having 18 to 22 carbon atoms, and is preferably a saturated group, particularly a linear group. Examples of R ⁴ and R ⁵ include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, and a tert-butyl group. Among them, a methyl group and an ethyl group are preferable, and a methyl group is particularly preferable. Preferable specific examples of the tertiary amine type compound (5) include N, N-dimethyloctadecyloxypropylamine, stearamidepropyldimethylamine and the like.

  The salt of the tertiary amine compound (5) is formed by a neutralization reaction between the tertiary amine compound and an acidic amino acid, organic acid or inorganic acid. Examples of acidic amino acids include glutamic acid and aspartic acid. Examples of the organic acid include carboxylic acids such as monocarboxylic acid, dicarboxylic acid, hydroxycarboxylic acid, and polycarboxylic acid, alkyl sulfuric acid, and alkyl phosphoric acid. Among these, carboxylic acid, particularly dicarboxylic acid and hydroxycarboxylic acid are preferable. Examples of the dicarboxylic acid include malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid. Examples of the hydroxycarboxylic acid include glycolic acid, lactic acid, hydroxyacrylic acid, oxybutyric acid, and glyceric acid. , Malic acid, tartaric acid, citric acid and the like. Examples of the inorganic acid include phosphoric acid, sulfuric acid, nitric acid, hydrochloric acid and the like. Of these, organic acids are preferable, and α-hydroxycarboxylic acids, particularly lactic acid and malic acid are particularly preferable.

  The quaternary ammonium salt and tertiary amine type compound of component (D) can be used either alone or in combination, or in combination of two or more of them, and the content is supple. From the viewpoint of glossiness, it is preferably 0.05 to 10% by weight, more preferably 0.1 to 8% by weight, and particularly preferably 0.1 to 7% by weight in the hair cosmetic composition of the present invention. In addition, the contents of component (A), component (B), component (C), and component (D) in the hair cosmetic composition of the present invention are respectively (A) wt%, (B) wt%, and (C) wt %, (D)% by weight, [(A) + (B) + (C)] / (D) = 2-6.

  The hair cosmetic composition of the present invention may further contain a higher alcohol as component (E) from the viewpoint of imparting good finger-feel and smoothness to wet hair. As the higher alcohol, those having 12 to 28 carbon atoms are preferred, those having 16 to 24 carbon atoms, especially those having 22 carbon atoms are preferred, and linear or branched saturated or unsaturated ones can be used. A linear alkyl alcohol is particularly preferable.

  Preferred specific examples of component (E) include cetyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, 2-octyldodecanol, 2-hexyldecyl alcohol, isostearyl alcohol, carnervir alcohol (tetracosanol) and the like. In particular, behenyl alcohol is preferred.

  The higher alcohol of component (E) may be used in combination of two or more thereof, and the content thereof is that of the present invention from the viewpoint of imparting smoothness and slipperiness during application and rinsing to wet hair. 0.5 to 11% by weight in the hair cosmetic is preferable, further 0.8 to 11% by weight, particularly 0.9 to 11% by weight is preferable. The weight ratio of the quaternary ammonium salt or tertiary amine type compound of component (D) to the higher alcohol of component (E) is preferably 1: 1 to 1: 5, particularly 1: 2 to 1: 4.

  In the hair cosmetic of the present invention, various surfactants other than the component (D) used in normal hair cosmetics can be further used. As the surfactant, a nonionic surfactant or an amphoteric surfactant is preferable.

  Nonionic surfactants include polyoxyalkylene alkyl ether, polyoxyalkylene fatty acid ester, polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene sorbit fatty acid ester, polyoxyalkylene glycerin fatty acid ester, monoglyceride, sorbitan Examples include fatty acid ester series.

  Examples of amphoteric surfactants include acetic acid betaines, amidoacetic acid betaines, sulfobetaines, amidosulfobetaines, imidazolium betaines, amino acids, amidoamines, phosphobetaines, alkylamine oxides, amidoamine oxides, and the like. .

  Two or more surfactants other than these components (D) may be used in combination, and the content thereof is 0.01 to 10% by weight in the hair cosmetic composition of the present invention from the viewpoint of improving the emulsion stability. More preferably, it is 0.1 to 5% by weight, particularly 0.5 to 2% by weight.

  Further, in the hair cosmetic composition of the present invention, in addition to the above components, a thickening agent such as hydroxyethyl cellulose, carboxyvinyl polymer and the like can be used in an amount of 0.01 to 5% by weight from the viewpoint of system stability and ease of extension of the agent. Furthermore, it is preferable to contain 0.1 to 0.5 weight%.

  Furthermore, in addition to the above components, the hair cosmetic of the present invention can contain other components and additives commonly used in hair cosmetics depending on the purpose. Examples of such components include oil agents such as hydrocarbon oils and ester oils; humectants such as 1,3-butylene glycol, propylene glycol, glycerin and protein hydrolysates; highly polymerized PEG, cationized cellulose, and cationization Conditioning agents such as guar gum; solubilizers such as polyoxyethylene alkyl ethers and polyoxyethylene hydrogenated castor oil; preservatives such as parabens; bactericides such as salicylic acid, triclosan and piroctone olamine; sodium hydroxide, potassium hydroxide PH adjusters such as edetate, sequestering agents such as hydroxyethane diphosphonic acid; UV absorbers such as paramethoxycinnamic acid-2-ethylhexyl, oxybenzone, paradimethylaminobenzoic acid-2-ethylhexyl; dibutyl Antioxidants such as hydroxytoluene and tocopherol acetate Others, mention may be made of animal and plant-derived extract, dyes and the like.

  The hair cosmetic composition of the present invention can be produced by mixing components (A) to (C), other optional components, and water according to a conventional method. For example, hair rinse, hair conditioner, hair treatment, hair pack , Hair cream, conditioning mousse, hair mousse, hair spray, shampoo, leave-on treatment, etc. In particular, it is suitable as a dosage form to be used after washing away, such as a hair rinse, a hair conditioner, and a hair treatment.

Examples 1-8 and Comparative Examples 1-5
Hair conditioners shown in Table 1 were prepared and evaluated.
(Evaluation methods)
A hair bundle (20g, 30cm) made from the hair of a woman that has been subjected to hair bleach treatment once was thoroughly washed with a plain shampoo (prepared with sodium polyoxyethylene (2.5) lauryl ether sulfate and diethanolamide), and then lightly I drained the water. After 2 g of hair conditioner was applied, it was rinsed with 6 L / min of 40 ° C. flowing water for 30 seconds, towel-dried, and sufficiently dried with warm air from a dryer for 2 to 3 minutes.
Sensory evaluation was performed by 20 panelists according to the following criteria, and ranking was performed based on the average of the evaluation points.

(Evaluation criteria)
・ Elongation when applied to wet hair 4: Very good elongation 3: Good elongation 2: Slightly good 1: Not very good 0: Not good

・ When applied to wet hair ・ When rinsing ・ After finger drying (sliding)
4: Very good fingering 3: Good fingering 2: Slightly good fingering 1: Not very good fingering 0: Bad fingering

・ Squeeze at the time of rinsing 4: Slightly scratching 3: Slightly scratching 2: Slightly scratching 1: Slightly squeaking 0: Slightly squeaking

・ Softness of hair during rinsing 4: Very soft 3: Soft 2: Slightly soft 1: Not very soft 0: Not soft

・ During drying (when half dry) ・ Stickness of hair after drying 4: Not sticky 3: Not sticky 2: Not sticky 1: Slightly sticky 0: Sticky

-Hair unit after drying 4: Very good unity 3: Good unity 2: Good unity 1: Slight unity 0: Bad unity

(Criteria)
◎: Average evaluation score of 3 or more and 4 or less ○: Average evaluation score of 2 or more and less than 3 △: Average evaluation score of 1 or more and less than 2 ×: Average evaluation score of 0 or more and less than 1

Example 9 Hair Conditioner
(weight%)
Cetyltrimethylammonium chloride 1.0
Stearyl alcohol 4.5
Methyl polysiloxane a = 2700 2.0
Methyl polysiloxane b = 500 2.5
Dodecamethylcyclohexasiloxane 4.0
Benzyloxyethanol 0.3
Lactic acid 0.5
Hydroxyethyl cellulose 0.1
Purified water remaining

Example 10 Hair Conditioner
(weight%)
Behenyltrimethylammonium chloride 1.2
Behenyl alcohol 4.0
Methyl polysiloxane a = 3200 1.5
Methyl polysiloxane b = 200 1.5
Decamethylcyclopentasiloxane 1.5
Octamethylcyclotetrasiloxane 1.5
Benzyloxyethanol 0.2
Malic acid 0.2
Hydroxyethyl cellulose 0.2
Fragrance 0.5
Purified water remaining

Example 11 Hair Conditioner
(weight%)
Stearyltrimethylammonium chloride 1.0
Behenyl alcohol 3.5
Methyl polysiloxane a = 2200 1.0
Methyl polysiloxane b = 300 2.0
Octamethylcyclotetrasiloxane 1.5
Benzyloxyethanol 0.1
Lactic acid 0.5
Hydroxyethyl cellulose 0.1
Fragrance 0.3
Purified water remaining

Example 12 Hair Conditioner
(weight%)
N, N-dimethyl-3-octadecyloxypropylamine 2.0
Stearyl alcohol 6.0
Methyl polysiloxane a = 3000 1.0
Methyl polysiloxane a = 2000 1.0
Methyl polysiloxane b = 400 2.0
Decamethylcyclopentasiloxane 2.0
Benzyloxyethanol 0.3
Lactic acid 0.3
Malic acid 0.2
Hydroxyethyl cellulose 0.1
Fragrance 0.3
Purified water remaining

Claims (3)

Next ingredients (A) to ( E )
(A) Dimethylpolysiloxane represented by the following general formula (1)

[In formula, a shows the number average degree of polymerization of 1000-3800. ]
(B) Dimethylpolysiloxane represented by the following general formula (2)

[Wherein b represents a number average degree of polymerization of 100 to 800. ]
(C) Cyclic dimethylpolysiloxane represented by the following general formula (3)

[In formula, c shows the number average degree of polymerization of 3-7. ]
(D) The following general formula (5)

[In the formula, A represents a hydrogen atom or a linear or branched saturated or unsaturated amide group, N-hydrocarbon carbamoyl group, acyloxy group or hydrocarbon oxy group having a total carbon number of 12 to 24; Represents a divalent linear or branched saturated or unsaturated hydrocarbon group having 1 to 22 carbon atoms, and R ⁴ and R ⁵ independently represent an alkyl group having 1 to 4 carbon atoms. ]
A tertiary amine compound represented by the formula:
(E) a higher alcohol, and the contents of component (A), component (B), and component (C) in the composition are (A) wt%, (B) wt%, (C ) When used as a weight%, 4 ≧ [(B) + (C)] / (A) ≧ 1 An aqueous hair cosmetic that is used after washing . When the contents of component (A), component (B), component (C), and component (D) are (A) wt%, (B) wt%, (C) wt%, and (D) wt%, respectively [(A) + (B) + (C)] / (D) = 2-6 . The aqueous hair cosmetic composition according to claim 1 or 2 , wherein the weight ratio of component (D) to component (E) is 1: 1 to 1: 5 .