JP4014546B2 - Solid bath composition - Google Patents
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- JP4014546B2 JP4014546B2 JP2003280135A JP2003280135A JP4014546B2 JP 4014546 B2 JP4014546 B2 JP 4014546B2 JP 2003280135 A JP2003280135 A JP 2003280135A JP 2003280135 A JP2003280135 A JP 2003280135A JP 4014546 B2 JP4014546 B2 JP 4014546B2
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Description
本発明は、固形浴用剤組成物に関し、詳しくは、リンゴ酸と２〜１０％のフマル酸および炭酸塩を含有し、成形性が非常に良好であり、しっとりとした入浴感を有し、発泡時の浴湯表面状態が優れた固形浴用剤組成物に関する。 The present invention relates to a solid bath agent composition, and more specifically, contains malic acid and 2 to 10% fumaric acid and carbonate, has a very good moldability, has a moist bathing feeling, and foams. The present invention relates to a solid bath agent composition having an excellent bath water surface condition.
従来より、有機酸と炭酸塩を配合した固形浴用剤組成物（以下、「固形浴用剤」という）は、炭酸ガスによる温浴効果、発泡による入浴の楽しみを提案できるものとして知られており、各種の製品が作られている。この固形浴用剤に用いられる有機酸として、いくつかのものが知られている。このうち、フマル酸、コハク酸は、成形性は良好であるが、フマル酸の場合には浴湯に投入した際に不溶解物が発生しやすいという問題があり、コハク酸は使用者がむせる等の問題があった。 Conventionally, a composition for a solid bath containing an organic acid and a carbonate (hereinafter referred to as a “solid bath agent”) has been known to be able to propose a warm bath effect by carbon dioxide gas, and enjoyment of bathing by foaming. Products are made. Several organic acids are known for use in the solid bath agent. Among these, fumaric acid and succinic acid have good moldability, but in the case of fumaric acid, there is a problem that insoluble matter is likely to be generated when it is added to bath water, and succinic acid can be removed by the user. There was a problem such as.
一方、リンゴ酸は、しっとりとした入浴感が得られるというメリットもあるが、成形性が良好ではなく、打錠障害が発生しやすいという問題点があった。特に、ブリケット状の固形浴用剤組成物を製造する際にリンゴ酸を用いた場合には、ブリケットマシーンのロールに製剤が付着しやすいという問題点があった。 On the other hand, malic acid has a merit that a moist bathing feeling can be obtained, but there is a problem that moldability is not good and tableting troubles are likely to occur. In particular, when malic acid is used when producing a briquette solid bath agent composition, there is a problem that the preparation tends to adhere to the roll of the briquette machine.
このような錠剤やブリケットの製造障害を抑制するため、ポリエチレングリコール６０００、タルク、ステアリン酸マグネシウム等の滑沢剤を用いることで成形性を改善することが行われているが、このような滑沢剤を用いた固形浴用剤は、これを浴湯に投入した際に、浴湯表面に浮き泡や、不溶解物の浮きが生じ、使用者が不快に感じる等の問題点があった。 In order to suppress the manufacturing trouble of such tablets and briquettes, the moldability is improved by using a lubricant such as polyethylene glycol 6000, talc, and magnesium stearate. When the solid bath agent using the agent is added to the bath water, there are problems such as floating bubbles and insoluble matter floating on the surface of the bath water and the user feeling uncomfortable.
従って本発明の課題は、成形性に優れ、しっとりとした使用感を有し、浴湯表面状態も良好である固形浴用剤を提供することにある。 Accordingly, an object of the present invention is to provide a solid bath agent having excellent moldability, a moist feeling of use, and a good bath surface condition.
本発明者らは、上記課題を解決すべく鋭意検討した結果、固形浴用剤に配合する有機酸として、リンゴ酸とフマル酸とを一定の割合で組み合わせて配合することにより、成形性が非常に優れ、使用者にしっとりした入浴感を与え、発泡時の浴湯表面状態にも優れた固形浴用剤が得られることを見出し、本発明を完成した。 As a result of diligent investigations to solve the above problems, the present inventors have obtained a very high moldability by combining malic acid and fumaric acid in a certain ratio as an organic acid to be blended in the solid bath preparation. The present invention was completed by finding that a solid bath agent that gives an excellent and moist bathing feeling to the user and is excellent in the surface condition of the bath water during foaming can be obtained.
すなわち本発明は、有機酸と炭酸塩を含有する固形浴用剤組成物であって、有機酸としてリンゴ酸とフマル酸との混合物を用い、かつフマル酸の含有量が組成物全体の２〜１０質量％であることを特徴とする固形浴用剤組成物である。 That is, the present invention is a solid bath agent composition containing an organic acid and a carbonate, wherein a mixture of malic acid and fumaric acid is used as the organic acid, and the content of fumaric acid is 2 to 10 of the entire composition. It is a solid bath agent composition characterized by being a mass%.
本発明の固形浴用剤は、成形性に優れ、しっとりとした使用感を有し、浴湯表面状態も良好である。 The solid bath agent of the present invention is excellent in moldability, has a moist use feeling, and has a good bath water surface state.
本明細書中において、ブリケットとは、ピロー状、レンズ状、アーモンド状、プリズム状、棒状、フィンガー状などの形状を意味する。これらのブリケットは、粉体組成物をブリケッティングマシンにて成形加工して得られる。 In this specification, the briquette means a shape such as a pillow shape, a lens shape, an almond shape, a prism shape, a rod shape, or a finger shape. These briquettes are obtained by molding a powder composition with a briquetting machine.
本発明の固形浴用剤では、浴中において炭酸塩を発泡させるための有機酸として、リンゴ酸とフマル酸の混合物が用いられる。 In the solid bath agent of the present invention, a mixture of malic acid and fumaric acid is used as the organic acid for foaming carbonate in the bath.
このうちリンゴ酸は、篩い分析法による平均粒子径が１００μｍ〜１ｍｍ程度あれば良いが、成形性を考えると、３００〜５００μｍが特に好ましい。このリンゴ酸の配合量は、好ましくは２０〜４０質量％（以下、単に「％」で表す）であり、より好ましくは２５〜４０％である。配合量が、この範囲を下回ると、しっとり感を与えることができない場合があり、逆にこの範囲を超えて配合すると、安定性の面で問題が生じる場合がある。 Of these, malic acid has only to have an average particle size of about 100 μm to 1 mm according to a sieve analysis method, but considering moldability, 300 to 500 μm is particularly preferable. The blending amount of malic acid is preferably 20 to 40% by mass (hereinafter simply expressed as “%”), and more preferably 25 to 40%. If the blending amount is less than this range, it may not be possible to give a moist feeling. Conversely, if the blending amount exceeds this range, problems may occur in terms of stability.
一方、本発明の固形浴用剤でのフマル酸の配合量は、２〜１０％である。この範囲を超えて配合すると、浴湯に投入した際に発泡の勢いでフマル酸の浮きが発生する場合があり、浴湯表面が非常に汚く不快になる。特に、ブリケットの場合には発泡の勢いが大きいため顕著である。また、この範囲を下回って配合すると、製造時に成形装置への製剤の付着が発生する場合があり、成形性の向上が見られない。また、フマル酸を７〜１０％配合した場合には、特に成形性に優れた結果を得る。 On the other hand, the blending amount of fumaric acid in the solid bath preparation of the present invention is 2 to 10%. If the blending exceeds this range, fumaric acid may float due to foaming moment when thrown into bath water, and the bath surface becomes very dirty and uncomfortable. In particular, in the case of briquettes, the momentum of foaming is large, which is remarkable. Moreover, when it mix | blends less than this range, adhesion of a formulation to a shaping | molding apparatus may generate | occur | produce at the time of manufacture, and a moldability improvement is not seen. Further, when 7 to 10% of fumaric acid is blended, a result that is particularly excellent in moldability is obtained.
リンゴ酸とフマル酸は、上記した量範囲で配合すれば良いが、好ましくは、これらの配合比が、２０：１ないし２：１、より好ましくは、５：１ないし３：１となるように配合すればよい。 Malic acid and fumaric acid may be blended in the above-mentioned amount ranges, but preferably the blending ratio is 20: 1 to 2: 1, more preferably 5: 1 to 3: 1. What is necessary is just to mix | blend.
本発明の固形浴用剤には、更に炭酸塩が配合される。用いられる炭酸塩は、特に限定されないが、好ましいものとして、炭酸ナトリウム、炭酸水素ナトリウム、セスキ炭酸ナトリウム、炭酸カリウム、炭酸水素カリウム、炭酸マグネシウム、炭酸アンモニウム等が挙げられる。その中でも炭酸ナトリウム、炭酸水素ナトリウムが特に好ましい。 The solid bath preparation of the present invention further contains a carbonate. The carbonate used is not particularly limited, but preferred examples include sodium carbonate, sodium bicarbonate, sesquisodium carbonate, potassium carbonate, potassium bicarbonate, magnesium carbonate, ammonium carbonate and the like. Of these, sodium carbonate and sodium hydrogen carbonate are particularly preferable.
この炭酸塩の配合量は、固形浴用剤に対し、好ましくは２０〜６０％であり、より好ましくは３０〜５０％である。この範囲を外れると、十分な発泡を得ることができない。 The blending amount of the carbonate is preferably 20 to 60%, more preferably 30 to 50% with respect to the solid bath agent. Outside this range, sufficient foaming cannot be obtained.
本発明の固形浴用剤組成物には、上記各成分の他に、必要に応じ任意成分として、植物成分、無水ケイ酸等の安定化剤、香料、着色剤、芒硝等の無機塩類、油性成分、白濁剤、アスパラギン酸ナトリウム等のアミノ酸、保湿剤、溶解剤等を適宜添加することができる。 In addition to the above components, the solid bath agent composition of the present invention includes, as necessary, optional components such as plant components, stabilizers such as silicic anhydride, fragrances, coloring agents, inorganic salts such as mirabilite, and oil components. An amino acid such as a cloudiness agent and sodium aspartate, a moisturizing agent, a solubilizing agent, and the like can be appropriately added.
本発明の固形浴用剤の形状としては、特に限定されるものではないが、錠剤、ブリケット等が挙げられる。なかでもブリケットが、成形する際の圧力が比較的低いため、成形性の向上の面から好ましい。 Although it does not specifically limit as a shape of the agent for solid baths of this invention, A tablet, a briquette, etc. are mentioned. Of these, briquettes are preferred from the viewpoint of improving moldability because the pressure during molding is relatively low.
以下、ブリケットの形状を例に取り、本発明の固形浴用剤の製造法について説明する。 Hereinafter, the manufacturing method of the agent for solid baths of the present invention will be described by taking the shape of briquettes as an example.
まず、リンゴ酸とフマル酸を混合した有機酸、炭酸塩および目的に応じた任意成分を十分に混合し、混合物を得る。次いで、この混合物を、ブリケッティングマシンを通し、ピロー状、レンズ状、アーモンド状、プリズム状、棒状、フィンガー状などの所望の形状で、０．０１ｃｍ３から２０ｃｍ３程度の容積のブリケットを製造する。 First, an organic acid obtained by mixing malic acid and fumaric acid, a carbonate, and optional components according to the purpose are sufficiently mixed to obtain a mixture. The mixture is then passed through a briquetting machine, pillow-shaped, lenticular, almond-shaped, prismatic, rod, in a desired shape such as a finger-like, producing briquettes of 20 cm 3 of about volume from 0.01 cm 3 To do.
なお、ブリケッティングマシンとは、同速で互いに反対方向に回転する２本のロール間で原料粉体を圧縮し成型する乾式圧縮造粒機の一つであり、このロールの表面には、ブリケットの母型であるポケットが刻まれている。そのポケットの形状や大きさを変更することによって、種々の形状や大きさのブリケットを得ることが可能となる。通常、ブリケット製造においては、ロール間のクリアランスの大きさやロール同士の押さえ圧、フィードスクリューの押圧力などを調整することによりシート状一次成形体が得られる。ブリケットは、更にこの複数のブリケット粒子が連結部を介してシート状に成形されたシート状一次成形体を解砕することにより、得ることができるのである。 The briquetting machine is one of dry compression granulators that compress and mold the raw material powder between two rolls that rotate in the opposite directions at the same speed. The pocket, which is the base of the briquette, is engraved. By changing the shape and size of the pocket, briquettes of various shapes and sizes can be obtained. Usually, in briquette production, a sheet-like primary molded body is obtained by adjusting the clearance between rolls, the pressing pressure between rolls, the pressing force of a feed screw, and the like. The briquette can be obtained by further crushing a sheet-like primary molded body in which the plurality of briquette particles are formed into a sheet shape via the connecting portion.
以下、実施例に基づき本発明を更に具体的に説明するが、本発明はこれら実施例により何ら制約されるものではない。 EXAMPLES Hereinafter, although this invention is demonstrated more concretely based on an Example, this invention is not restrict | limited at all by these Examples.
実 施 例 １ 〜 ４、 比 較 例 １〜５
下記の表１、表２に示す配合処方（％）５ｋｇを万能攪拌混合機にて均一になるまで混合した後、ブリケットマシーンを用い、３〜６ｍｍのブリケットとして固形浴用剤を得る。
Examples 1 to 4 and Comparative Examples 1 to 5
After mixing 5 kg of the formulation (%) shown in the following Tables 1 and 2 with a universal stirring mixer until uniform, a solid bath preparation is obtained as a 3-6 mm briquette using a briquette machine.
これらの固形浴用剤について、以下に示す評価試験法により、ブリケットの成形性、使用した浴湯の感触および浴湯表面状態を評価した。得られた結果も下表１、表２に併記する。 For these solid bath agents, briquette moldability, feel of the bath water used, and bath water surface condition were evaluated by the following evaluation test methods. The obtained results are also shown in Tables 1 and 2 below.
（ ブリケットの成形性評価 ）
目視により、製造時のブリケットマシーンのロールへの製剤の付着の程度を下記３段階で評価した。
評 価
評 価 内 容
◎ ： 付着なし
○ ： ほとんど付着なし
× ： 付着あり
(Evaluation of formability of briquette)
The degree of adhesion of the preparation to the roll of the briquette machine at the time of production was evaluated by the following three stages.
Evaluation
Evaluation content ◎: No adhesion ○: Almost no adhesion ×: Adhesion
フマル酸を配合していない比較例１〜４はロールへの付着が多くみられたが、フマル酸を配合した実施例１〜４、比較例５は良好な成形性を示した。実施例１、４、比較例５は特に良好な成形性を示した。 Although Comparative Example 1-4 which did not mix | blend fumaric acid had many adhesion to a roll, Examples 1-4 and Comparative Example 5 which mix | blended fumaric acid showed favorable moldability. Examples 1 and 4 and Comparative Example 5 showed particularly good moldability.
（ 浴湯の感触 ）
各固形浴用剤約３０ｇを２００Ｌの浴湯に投入し、下記基準で使用感触の評価を行った。
評 価
評 価 内 容
○ ： しっとり感あり
× ： しっとり感なし
(Feel of bathing)
About 30 g of each solid bath agent was put into 200 L of bath water, and the feeling of use was evaluated according to the following criteria.
Evaluation
Evaluation content ○: Moist feeling ×: Moist feeling
比較例５はしっとり感が得られなかったが、実施例１〜４、比較例１〜４は良好な浴湯の感触を示した。 In Comparative Example 5, a moist feeling was not obtained, but Examples 1 to 4 and Comparative Examples 1 to 4 showed a good feeling of bath water.
（ 浴湯表面状態 ）
各固形浴用剤約３０ｇを２００Ｌの浴湯に投入し、目視により、浴湯表面状態を下記３段階で評価した。
評 価
評 価 内 容
◎ ： 浮遊物なし
○ ： 浮遊物が目立たない
× ： 浮遊物が多く不快
(Bath surface condition)
About 30 g of each solid bath agent was put into 200 L of bath water, and the bath water surface condition was visually evaluated in the following three stages.
Evaluation
Evaluation contents ◎: No floating substance ○: Floating substance is not noticeable ×: Many floating substances are uncomfortable
フマル酸を１５％配合した比較例５は、浮遊物が多く見られ、浴湯表面状態が不良であったが、実施例１〜４、比較例１〜４は、良好な浴湯表面状態を示した。実施例２、３は特に良好であった。 In Comparative Example 5 containing 15% fumaric acid, many floating substances were found and the bath water surface condition was poor, but Examples 1-4 and Comparative Examples 1-4 had a good bath water surface condition. Indicated. Examples 2 and 3 were particularly good.
実施例１〜４は、成形性、浴湯の感触、浴湯表面状態ともに良好なものであった。 In Examples 1 to 4, the moldability, the feeling of bath water, and the surface condition of the bath water were good.
実 施 例 ５
錠 剤 ：
下記の配合処方５ｋｇを万能攪拌混合機にて均一になるまで混合した。次いで、この混合物を単発の打錠機を用いて打錠し、直径５０ｍｍ、厚み１５ｍｍの浴用錠剤を成形した。
リンゴ酸 ３４％
フマル酸 ３
炭酸水素ナトリウム ２８
炭酸ナトリウム １５
硫酸ナトリウム １６
塩化カリウム ３
香料 １
色素 微 量
Example 5
Tablets:
5 kg of the following formulation was mixed with a universal stirring mixer until uniform. The mixture was then tableted using a single tableting machine to form a bath tablet having a diameter of 50 mm and a thickness of 15 mm.
Malic acid 34%
Fumaric acid 3
Sodium bicarbonate 28
Sodium carbonate 15
Sodium sulfate 16
Potassium chloride 3
Fragrance 1
Dye amount
実 施 例 ６
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３４％
フマル酸 ８
炭酸水素ナトリウム ３１
炭酸ナトリウム １５
硫酸マグネシウム ２
硫酸ナトリウム ７.５
Ｌ―グルタミン酸ナトリウム １
ポリエチレングリコール６０００ ０.５
香料 １
色素 微 量
Example 6
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 34%
Fumaric acid 8
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 7.5
Sodium L-glutamate 1
Polyethylene glycol 6000 0.5
Fragrance 1
Dye amount
実 施 例 ７
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３４％
フマル酸 ５
炭酸水素ナトリウム ３０
炭酸ナトリウム １５
硫酸ナトリウム １２
還元麦芽糖水飴 ３
香料 １
色素 微 量
Example 7
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 34%
Fumaric acid 5
Sodium bicarbonate 30
Sodium carbonate 15
Sodium sulfate 12
Reduced maltose starch syrup 3
Fragrance 1
Dye amount
実 施 例 ８
錠 剤 ：
下記配合組成を使用し、実施例５と同様な方法で浴用錠剤を得た。
リンゴ酸 ２５％
フマル酸 ８
コハク酸 ８
炭酸水素ナトリウム ３１
炭酸ナトリウム １５
硫酸マグネシウム ２
硫酸ナトリウム ８.２
Ｌ―グルタミン酸ナトリウム １
ポリエチレングリコール６０００ ０.５
無水ケイ酸 ０.３
香料 １
色素 微 量
Example 8
Tablets:
A bath tablet was obtained in the same manner as in Example 5 using the following composition.
Malic acid 25%
Fumaric acid 8
Succinic acid 8
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 8.2
Sodium L-glutamate 1
Polyethylene glycol 6000 0.5
Silicic anhydride 0.3
Fragrance 1
Dye amount
実 施 例 ９
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ２５％
フマル酸 ５
炭酸水素ナトリウム ２０
炭酸ナトリウム １５
硫酸ナトリウム ３１
塩化カリウム ３
香料 １
色素 微 量
Example 9
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 25%
Fumaric acid 5
Sodium bicarbonate 20
Sodium carbonate 15
Sodium sulfate 31
Potassium chloride 3
Fragrance 1
Dye amount
実 施 例 １０
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ２９％
フマル酸 ８
コハク酸 ３
炭酸水素ナトリウム ３４
炭酸ナトリウム １５
塩化ナトリウム ５
Ｌ―グルタミン酸ナトリウム ２
ポリエチレングリコール６０００ ０.５
酸化チタンの水溶性高分子被覆物 * ２.５
大豆油 ０.３
香料 ０.７
色素 微 量
Example 10
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 29%
Fumaric acid 8
Succinic acid 3
Sodium bicarbonate 34
Sodium carbonate 15
Sodium chloride 5
Sodium L-glutamate 2
Polyethylene glycol 6000 0.5
Titanium oxide water-soluble polymer coating * 2.5
Soybean oil 0.3
Fragrance 0.7
Dye amount
* 特開昭６３−５７５１６号の記載に従って調製 * Prepared as described in JP-A-63-57516
実 施 例 １１
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３０％
フマル酸 ８
炭酸水素ナトリウム ３０
炭酸ナトリウム ２０
カオリン ３
ベントナイト ３
酸化チタンの水溶性高分子被覆物 ** ５
ポリエチレングリコール６０００ ０.５
香料 ０.５
Example 11
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 30%
Fumaric acid 8
Sodium bicarbonate 30
Sodium carbonate 20
Kaolin 3
Bentonite 3
Titanium oxide water-soluble polymer coating ** 5
Polyethylene glycol 6000 0.5
Fragrance 0.5
** 特開昭６３−５７５１６号の記載に従って調製 ** Prepared as described in JP-A-63-57516
実 施 例 １２
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３０％
フマル酸 ３
炭酸水素ナトリウム ２０
炭酸ナトリウム １５
硫酸ナトリウム ２６
還元麦芽糖水飴 ５
香料 １
色素 微 量
Example 12
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 30%
Fumaric acid 3
Sodium bicarbonate 20
Sodium carbonate 15
Sodium sulfate 26
Reduced maltose starch syrup 5
Fragrance 1
Dye amount
実 施 例 １３
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３９％
フマル酸 ３
炭酸水素ナトリウム ３１
炭酸ナトリウム １５
硫酸マグネシウム ２
硫酸ナトリウム ７.５
Ｌ―グルタミン酸ナトリウム １
ポリエチレングリコール６０００ ０.５
香料 １
色素 微 量
Example 13
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 39%
Fumaric acid 3
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 7.5
Sodium L-glutamate 1
Polyethylene glycol 6000 0.5
Fragrance 1
Dye amount
実施例５〜１３で得られた固形浴用剤（錠剤およびブリケット）は、成形性、浴湯の感触、浴湯表面状態ともに良好なものであった。 The solid bath preparations (tablets and briquettes) obtained in Examples 5 to 13 were good in moldability, bath water feel, and bath water surface condition.
本発明の固形浴用剤は、製造において成形性に優れたものであり、これを使用した場合は、肌にしっとりとした使用感を与え、浴湯表面状態も良好なものである。従って、固形浴用剤として広く使用することが可能なものである。
The solid bath agent of the present invention is excellent in moldability in production, and when it is used, it gives a moist feeling to the skin and the bath surface condition is also good. Therefore, it can be widely used as a solid bath agent.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003280135A JP4014546B2 (en) | 2002-08-08 | 2003-07-25 | Solid bath composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002231421 | 2002-08-08 | ||
| JP2003280135A JP4014546B2 (en) | 2002-08-08 | 2003-07-25 | Solid bath composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004083584A JP2004083584A (en) | 2004-03-18 |
| JP4014546B2 true JP4014546B2 (en) | 2007-11-28 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003280135A Expired - Lifetime JP4014546B2 (en) | 2002-08-08 | 2003-07-25 | Solid bath composition |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3934526B2 (en) * | 2002-10-15 | 2007-06-20 | 花王株式会社 | Powder or granular bath preparation |
| JP4826884B2 (en) * | 2005-08-19 | 2011-11-30 | 株式会社バスクリン | Briquette machine for producing solid bath agent and method for producing solid bath agent |
| JP5259060B2 (en) * | 2006-07-19 | 2013-08-07 | 株式会社ヘルスカンパニー | Bath agent composition |
| JP5072570B2 (en) * | 2007-12-18 | 2012-11-14 | 花王株式会社 | Granular foam bath agent |
| JP5877778B2 (en) * | 2012-05-28 | 2016-03-08 | 株式会社ホットアルバム炭酸泉タブレット | Tablet manufacturing method and tablet |
| JP5982664B2 (en) * | 2012-06-08 | 2016-08-31 | 株式会社バスクリン | Effervescent briquette formulation |
| JP5588490B2 (en) * | 2012-10-10 | 2014-09-10 | 株式会社ホットアルバム炭酸泉タブレット | Tablet manufacturing method and tablet |
| JP6075553B2 (en) * | 2013-06-25 | 2017-02-08 | 白元アース株式会社 | Foaming bath composition |
| JP2014221818A (en) * | 2014-07-25 | 2014-11-27 | 株式会社ホットアルバム炭酸泉タブレット | Method for producing of tablet, and tablet |
| TWI724994B (en) * | 2014-12-22 | 2021-04-21 | 日商花王股份有限公司 | Solid foaming bath agent for foot bath |
-
2003
- 2003-07-25 JP JP2003280135A patent/JP4014546B2/en not_active Expired - Lifetime
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| JP2004083584A (en) | 2004-03-18 |
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