JP2004083584A - Solid bath medicine composition - Google Patents
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Abstract
Description
本発明は、固形浴用剤組成物に関し、詳しくは、リンゴ酸と２〜１０％のフマル酸および炭酸塩を含有し、成形性が非常に良好であり、しっとりとした入浴感を有し、発泡時の浴湯表面状態が優れた固形浴用剤組成物に関する。 The present invention relates to a solid bath preparation composition, and more specifically, it contains malic acid and 2 to 10% of fumaric acid and carbonate, has very good moldability, has a moist bathing sensation, and has foaming properties. The present invention relates to a solid bath composition having an excellent surface condition of bath water at the time.
従来より、有機酸と炭酸塩を配合した固形浴用剤組成物（以下、「固形浴用剤」という）は、炭酸ガスによる温浴効果、発泡による入浴の楽しみを提案できるものとして知られており、各種の製品が作られている。この固形浴用剤に用いられる有機酸として、いくつかのものが知られている。このうち、フマル酸、コハク酸は、成形性は良好であるが、フマル酸の場合には浴湯に投入した際に不溶解物が発生しやすいという問題があり、コハク酸は使用者がむせる等の問題があった。 2. Description of the Related Art Conventionally, a solid bath composition containing an organic acid and a carbonate (hereinafter referred to as “solid bath agent”) has been known as a composition capable of proposing a warm bath effect by carbon dioxide gas and a pleasure of bathing by foaming. Products are made. Several organic acids are known for use in this solid bath preparation. Among these, fumaric acid and succinic acid have good moldability, but in the case of fumaric acid, there is a problem that insolubles are easily generated when put into a bath water, and succinic acid is used by users. And so on.
一方、リンゴ酸は、しっとりとした入浴感が得られるというメリットもあるが、成形性が良好ではなく、打錠障害が発生しやすいという問題点があった。特に、ブリケット状の固形浴用剤組成物を製造する際にリンゴ酸を用いた場合には、ブリケットマシーンのロールに製剤が付着しやすいという問題点があった。 On the other hand, although malic acid has the merit that a moist bathing sensation can be obtained, it has a problem in that the moldability is not good and tableting failure is likely to occur. In particular, when malic acid is used when producing a briquette-like solid bath agent composition, there is a problem that the preparation easily adheres to the roll of the briquette machine.
このような錠剤やブリケットの製造障害を抑制するため、ポリエチレングリコール６０００、タルク、ステアリン酸マグネシウム等の滑沢剤を用いることで成形性を改善することが行われているが、このような滑沢剤を用いた固形浴用剤は、これを浴湯に投入した際に、浴湯表面に浮き泡や、不溶解物の浮きが生じ、使用者が不快に感じる等の問題点があった。 In order to suppress such troubles in the production of tablets and briquettes, the moldability has been improved by using a lubricant such as polyethylene glycol 6000, talc, magnesium stearate, etc. When the solid bath preparation using the preparation is put into the bath water, there are problems such as floating bubbles and insoluble matter floating on the surface of the bath water, and the user feels uncomfortable.
従って本発明の課題は、成形性に優れ、しっとりとした使用感を有し、浴湯表面状態も良好である固形浴用剤を提供することにある。 Accordingly, an object of the present invention is to provide a solid bath agent which has excellent moldability, has a moist feeling, and has a good bath surface condition.
本発明者らは、上記課題を解決すべく鋭意検討した結果、固形浴用剤に配合する有機酸として、リンゴ酸とフマル酸とを一定の割合で組み合わせて配合することにより、成形性が非常に優れ、使用者にしっとりした入浴感を与え、発泡時の浴湯表面状態にも優れた固形浴用剤が得られることを見出し、本発明を完成した。 The present inventors have conducted intensive studies to solve the above-described problems, and as a result, by combining malic acid and fumaric acid in a certain ratio as an organic acid to be added to the solid bath agent, the moldability is extremely high. The present inventors have found that a solid bath agent which is excellent and gives a user a moist bathing sensation and also has an excellent bath water surface condition at the time of foaming can be obtained.
すなわち本発明は、有機酸と炭酸塩を含有する固形浴用剤組成物であって、有機酸としてリンゴ酸とフマル酸との混合物を用い、かつフマル酸の含有量が組成物全体の２〜１０質量％であることを特徴とする固形浴用剤組成物である。 That is, the present invention relates to a solid bath preparation composition containing an organic acid and a carbonate, wherein a mixture of malic acid and fumaric acid is used as the organic acid, and the content of fumaric acid is 2 to 10 of the whole composition. % By mass.
本発明の固形浴用剤は、成形性に優れ、しっとりとした使用感を有し、浴湯表面状態も良好である。 固 形 The solid bath preparation of the present invention is excellent in moldability, has a moist feeling, and has a good bath surface condition.
本明細書中において、ブリケットとは、ピロー状、レンズ状、アーモンド状、プリズム状、棒状、フィンガー状などの形状を意味する。これらのブリケットは、粉体組成物をブリケッティングマシンにて成形加工して得られる。 ブ リ In this specification, a briquette means a pillow shape, a lens shape, an almond shape, a prism shape, a rod shape, a finger shape, or the like. These briquettes are obtained by molding a powder composition with a briquetting machine.
本発明の固形浴用剤では、浴中において炭酸塩を発泡させるための有機酸として、リンゴ酸とフマル酸の混合物が用いられる。 固 形 In the solid bath preparation of the present invention, a mixture of malic acid and fumaric acid is used as an organic acid for foaming a carbonate in the bath.
このうちリンゴ酸は、篩い分析法による平均粒子径が１００μｍ〜１ｍｍ程度あれば良いが、成形性を考えると、３００〜５００μｍが特に好ましい。このリンゴ酸の配合量は、好ましくは２０〜４０質量％（以下、単に「％」で表す）であり、より好ましくは２５〜４０％である。配合量が、この範囲を下回ると、しっとり感を与えることができない場合があり、逆にこの範囲を超えて配合すると、安定性の面で問題が生じる場合がある。 う ち Of these, malic acid may have an average particle size of about 100 μm to 1 mm as determined by a sieve analysis method, but from the viewpoint of moldability, 300 to 500 μm is particularly preferred. The blending amount of this malic acid is preferably 20 to 40% by mass (hereinafter, simply referred to as “%”), and more preferably 25 to 40%. If the amount is less than this range, it may not be possible to give a moist feeling. If the amount exceeds this range, a problem may occur in terms of stability.
一方、本発明の固形浴用剤でのフマル酸の配合量は、２〜１０％である。この範囲を超えて配合すると、浴湯に投入した際に発泡の勢いでフマル酸の浮きが発生する場合があり、浴湯表面が非常に汚く不快になる。特に、ブリケットの場合には発泡の勢いが大きいため顕著である。また、この範囲を下回って配合すると、製造時に成形装置への製剤の付着が発生する場合があり、成形性の向上が見られない。また、フマル酸を７〜１０％配合した場合には、特に成形性に優れた結果を得る。 On the other hand, the blending amount of fumaric acid in the solid bath preparation of the present invention is 2 to 10%. If the amount is more than this range, the fumaric acid may float due to the bubbling force when put into the bath water, and the bath water surface becomes very dirty and unpleasant. In particular, in the case of briquettes, this is remarkable because the momentum of foaming is large. If the amount is less than the above range, the preparation may adhere to the molding apparatus during the production, and the moldability is not improved. Further, when fumaric acid is blended in an amount of 7 to 10%, a result having particularly excellent moldability is obtained.
リンゴ酸とフマル酸は、上記した量範囲で配合すれば良いが、好ましくは、これらの配合比が、２０：１ないし２：１、より好ましくは、５：１ないし３：１となるように配合すればよい。 Malic acid and fumaric acid may be blended in the above-mentioned amount range. Preferably, the blending ratio is 20: 1 to 2: 1, more preferably 5: 1 to 3: 1. What is necessary is just to mix.
本発明の固形浴用剤には、更に炭酸塩が配合される。用いられる炭酸塩は、特に限定されないが、好ましいものとして、炭酸ナトリウム、炭酸水素ナトリウム、セスキ炭酸ナトリウム、炭酸カリウム、炭酸水素カリウム、炭酸マグネシウム、炭酸アンモニウム等が挙げられる。その中でも炭酸ナトリウム、炭酸水素ナトリウムが特に好ましい。 炭 酸 The solid bath agent of the present invention further contains a carbonate. The carbonate used is not particularly limited, but preferred are sodium carbonate, sodium hydrogen carbonate, sodium sesquicarbonate, potassium carbonate, potassium hydrogen carbonate, magnesium carbonate, ammonium carbonate and the like. Among them, sodium carbonate and sodium hydrogen carbonate are particularly preferred.
この炭酸塩の配合量は、固形浴用剤に対し、好ましくは２０〜６０％であり、より好ましくは３０〜５０％である。この範囲を外れると、十分な発泡を得ることができない。 配合 The amount of the carbonate is preferably 20 to 60%, more preferably 30 to 50%, based on the solid bath preparation. Outside this range, sufficient foaming cannot be obtained.
本発明の固形浴用剤組成物には、上記各成分の他に、必要に応じ任意成分として、植物成分、無水ケイ酸等の安定化剤、香料、着色剤、芒硝等の無機塩類、油性成分、白濁剤、アスパラギン酸ナトリウム等のアミノ酸、保湿剤、溶解剤等を適宜添加することができる。 In the solid bath composition of the present invention, in addition to the above-mentioned components, as an optional component, a plant component, a stabilizer such as silicic acid anhydride, a fragrance, a coloring agent, inorganic salts such as sodium sulfate, an oil component , A clouding agent, an amino acid such as sodium aspartate, a humectant, a solubilizer, and the like can be appropriately added.
本発明の固形浴用剤の形状としては、特に限定されるものではないが、錠剤、ブリケット等が挙げられる。なかでもブリケットが、成形する際の圧力が比較的低いため、成形性の向上の面から好ましい。 形状 The shape of the solid bath preparation of the present invention is not particularly limited, and examples thereof include tablets and briquettes. Above all, briquettes are preferable from the aspect of improvement in moldability because the pressure during molding is relatively low.
以下、ブリケットの形状を例に取り、本発明の固形浴用剤の製造法について説明する。 Hereinafter, the method for producing the solid bath agent of the present invention will be described taking the briquette shape as an example.
まず、リンゴ酸とフマル酸を混合した有機酸、炭酸塩および目的に応じた任意成分を十分に混合し、混合物を得る。次いで、この混合物を、ブリケッティングマシンを通し、ピロー状、レンズ状、アーモンド状、プリズム状、棒状、フィンガー状などの所望の形状で、０．０１ｃｍ３から２０ｃｍ３程度の容積のブリケットを製造する。 First, an organic acid obtained by mixing malic acid and fumaric acid, a carbonate, and an optional component according to the purpose are sufficiently mixed to obtain a mixture. Next, the mixture is passed through a briquetting machine to produce briquettes having a desired shape such as a pillow shape, a lens shape, an almond shape, a prism shape, a rod shape, a finger shape, and a volume of about 0.01 cm 3 to 20 cm 3. I do.
なお、ブリケッティングマシンとは、同速で互いに反対方向に回転する２本のロール間で原料粉体を圧縮し成型する乾式圧縮造粒機の一つであり、このロールの表面には、ブリケットの母型であるポケットが刻まれている。そのポケットの形状や大きさを変更することによって、種々の形状や大きさのブリケットを得ることが可能となる。通常、ブリケット製造においては、ロール間のクリアランスの大きさやロール同士の押さえ圧、フィードスクリューの押圧力などを調整することによりシート状一次成形体が得られる。ブリケットは、更にこの複数のブリケット粒子が連結部を介してシート状に成形されたシート状一次成形体を解砕することにより、得ることができるのである。 The briquetting machine is a dry compression granulator that compresses and molds a raw material powder between two rolls rotating in opposite directions at the same speed. The pocket, the matrix of the briquette, is engraved. By changing the shape and size of the pocket, briquettes of various shapes and sizes can be obtained. Normally, in the production of briquettes, a sheet-like primary compact is obtained by adjusting the size of the clearance between the rolls, the pressing pressure between the rolls, the pressing force of the feed screw, and the like. Briquettes can be obtained by further pulverizing a sheet-like primary molded product in which the plurality of briquette particles are molded into a sheet via a connecting portion.
以下、実施例に基づき本発明を更に具体的に説明するが、本発明はこれら実施例により何ら制約されるものではない。 Hereinafter, the present invention will be described more specifically with reference to Examples, but the present invention is not limited by these Examples.
実 施 例 １ 〜 ４、 比 較 例 １〜５
下記の表１、表２に示す配合処方（％）５ｋｇを万能攪拌混合機にて均一になるまで混合した後、ブリケットマシーンを用い、３〜６ｍｍのブリケットとして固形浴用剤を得る。
Examples 1 to 4, Comparative Examples 1 to 5
After mixing 5 kg of the formulation (%) shown in Tables 1 and 2 below using a universal stirring mixer until uniform, a solid bath agent is obtained as a 3 to 6 mm briquette using a briquette machine.
これらの固形浴用剤について、以下に示す評価試験法により、ブリケットの成形性、使用した浴湯の感触および浴湯表面状態を評価した。得られた結果も下表１、表２に併記する。 、 These solid bath agents were evaluated for briquette moldability, feel of the bath water used, and surface condition of the bath water by the following evaluation test methods. The obtained results are also shown in Tables 1 and 2 below.
（ ブリケットの成形性評価 ）
目視により、製造時のブリケットマシーンのロールへの製剤の付着の程度を下記３段階で評価した。
評 価
評 価 内 容
◎ ： 付着なし
○ ： ほとんど付着なし
× ： 付着あり
(Evaluation of briquette formability)
The degree of adhesion of the preparation to the roll of the briquette machine at the time of production was visually evaluated according to the following three grades.
Evaluation
Evaluation contents ◎: No adhesion ○: Almost no adhesion ×: Adhesion
フマル酸を配合していない比較例１〜４はロールへの付着が多くみられたが、フマル酸を配合した実施例１〜４、比較例５は良好な成形性を示した。実施例１、４、比較例５は特に良好な成形性を示した。 比較 In Comparative Examples 1 to 4 in which fumaric acid was not blended, adhesion to the roll was large, but Examples 1 to 4 and Comparative Example 5 in which fumaric acid was blended showed good moldability. Examples 1 and 4 and Comparative Example 5 showed particularly good moldability.
（ 浴湯の感触 ）
各固形浴用剤約３０ｇを２００Ｌの浴湯に投入し、下記基準で使用感触の評価を行った。
評 価
評 価 内 容
○ ： しっとり感あり
× ： しっとり感なし
(Feel of a bath)
About 30 g of each solid bath agent was put into 200 L of bath water, and the feeling of use was evaluated based on the following criteria.
Evaluation
Evaluation content ○: Moist feeling ×: No moist feeling
比較例５はしっとり感が得られなかったが、実施例１〜４、比較例１〜４は良好な浴湯の感触を示した。 Comparative Example 5 did not give a moist feeling, but Examples 1 to 4 and Comparative Examples 1 to 4 showed a good feeling of bath water.
（ 浴湯表面状態 ）
各固形浴用剤約３０ｇを２００Ｌの浴湯に投入し、目視により、浴湯表面状態を下記３段階で評価した。
評 価
評 価 内 容
◎ ： 浮遊物なし
○ ： 浮遊物が目立たない
× ： 浮遊物が多く不快
(Bath water surface condition)
About 30 g of each solid bath preparation was put into 200 L of bath water, and the surface state of the bath water was visually evaluated according to the following three grades.
Evaluation
Evaluation contents ◎: No suspended matter ○: Inconspicuous suspended matter ×: Many suspended matter is unpleasant
フマル酸を１５％配合した比較例５は、浮遊物が多く見られ、浴湯表面状態が不良であったが、実施例１〜４、比較例１〜４は、良好な浴湯表面状態を示した。実施例２、３は特に良好であった。 In Comparative Example 5 in which fumaric acid was blended at 15%, a large amount of suspended matter was observed, and the surface condition of the bath was poor. However, Examples 1 to 4 and Comparative Examples 1 to 4 showed good surface conditions of the bath. Indicated. Examples 2 and 3 were particularly good.
実施例１〜４は、成形性、浴湯の感触、浴湯表面状態ともに良好なものであった。 In Examples 1 to 4, the moldability, the feel of the bath water, and the surface condition of the bath water were all good.
実 施 例 ５
錠 剤 ：
下記の配合処方５ｋｇを万能攪拌混合機にて均一になるまで混合した。次いで、この混合物を単発の打錠機を用いて打錠し、直径５０ｍｍ、厚み１５ｍｍの浴用錠剤を成形した。
リンゴ酸 ３４％
フマル酸 ３
炭酸水素ナトリウム ２８
炭酸ナトリウム １５
硫酸ナトリウム １６
塩化カリウム ３
香料 １
色素 微 量
Example 5
Tablets:
5 kg of the following formulation was mixed with a universal stirring mixer until uniform. Next, the mixture was tableted using a single-shot tableting machine to form a bath tablet having a diameter of 50 mm and a thickness of 15 mm.
34% malic acid
Fumaric acid 3
Sodium bicarbonate 28
Sodium carbonate 15
Sodium sulfate 16
Potassium chloride 3
Fragrance 1
Dye amount
実 施 例 ６
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３４％
フマル酸 ８
炭酸水素ナトリウム ３１
炭酸ナトリウム １５
硫酸マグネシウム ２
硫酸ナトリウム ７.５
Ｌ―グルタミン酸ナトリウム １
ポリエチレングリコール６０００ ０.５
香料 １
色素 微 量
Example 6
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
34% malic acid
Fumaric acid 8
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 7.5
Sodium L-glutamate 1
Polyethylene glycol 6000 0.5
Fragrance 1
Dye amount
実 施 例 ７
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３４％
フマル酸 ５
炭酸水素ナトリウム ３０
炭酸ナトリウム １５
硫酸ナトリウム １２
還元麦芽糖水飴 ３
香料 １
色素 微 量
Example 7
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
34% malic acid
Fumaric acid 5
Sodium bicarbonate 30
Sodium carbonate 15
Sodium sulfate 12
Reduced maltose syrup 3
Fragrance 1
Dye amount
実 施 例 ８
錠 剤 ：
下記配合組成を使用し、実施例５と同様な方法で浴用錠剤を得た。
リンゴ酸 ２５％
フマル酸 ８
コハク酸 ８
炭酸水素ナトリウム ３１
炭酸ナトリウム １５
硫酸マグネシウム ２
硫酸ナトリウム ８.２
Ｌ―グルタミン酸ナトリウム １
ポリエチレングリコール６０００ ０.５
無水ケイ酸 ０.３
香料 １
色素 微 量
Example 8
Tablets:
Using the following composition, bath tablets were obtained in the same manner as in Example 5.
Malic acid 25%
Fumaric acid 8
Succinic acid 8
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 8.2
Sodium L-glutamate 1
Polyethylene glycol 6000 0.5
Silicic anhydride 0.3
Fragrance 1
Dye amount
実 施 例 ９
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ２５％
フマル酸 ５
炭酸水素ナトリウム ２０
炭酸ナトリウム １５
硫酸ナトリウム ３１
塩化カリウム ３
香料 １
色素 微 量
Example 9
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 25%
Fumaric acid 5
Sodium bicarbonate 20
Sodium carbonate 15
Sodium sulfate 31
Potassium chloride 3
Fragrance 1
Dye amount
実 施 例 １０
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ２９％
フマル酸 ８
コハク酸 ３
炭酸水素ナトリウム ３４
炭酸ナトリウム １５
塩化ナトリウム ５
Ｌ―グルタミン酸ナトリウム ２
ポリエチレングリコール６０００ ０.５
酸化チタンの水溶性高分子被覆物 * ２.５
大豆油 ０.３
香料 ０.７
色素 微 量
Example 10
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 29%
Fumaric acid 8
Succinic acid 3
Sodium bicarbonate 34
Sodium carbonate 15
Sodium chloride 5
Sodium L-glutamate 2
Polyethylene glycol 6000 0.5
Water-soluble polymer coating of titanium oxide * 2.5
Soybean oil 0.3
Spice 0.7
Dye amount
* 特開昭６３−５７５１６号の記載に従って調製 * Prepared as described in JP-A-63-57516
実 施 例 １１
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３０％
フマル酸 ８
炭酸水素ナトリウム ３０
炭酸ナトリウム ２０
カオリン ３
ベントナイト ３
酸化チタンの水溶性高分子被覆物 ** ５
ポリエチレングリコール６０００ ０.５
香料 ０.５
Example 11
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 30%
Fumaric acid 8
Sodium bicarbonate 30
Sodium carbonate 20
Kaolin 3
Bentonite 3
Water-soluble polymer coating of titanium oxide ** 5
Polyethylene glycol 6000 0.5
Fragrance 0.5
** 特開昭６３−５７５１６号の記載に従って調製 ** Prepared as described in JP-A-63-57516
実 施 例 １２
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３０％
フマル酸 ３
炭酸水素ナトリウム ２０
炭酸ナトリウム １５
硫酸ナトリウム ２６
還元麦芽糖水飴 ５
香料 １
色素 微 量
Example 12
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 30%
Fumaric acid 3
Sodium bicarbonate 20
Sodium carbonate 15
Sodium sulfate 26
Reduced maltose syrup 5
Fragrance 1
Dye amount
実 施 例 １３
ブリケット：
下記配合組成を使用し、実施例１と同様な方法で浴用ブリケットを得た。
リンゴ酸 ３９％
フマル酸 ３
炭酸水素ナトリウム ３１
炭酸ナトリウム １５
硫酸マグネシウム ２
硫酸ナトリウム ７.５
Ｌ―グルタミン酸ナトリウム １
ポリエチレングリコール６０００ ０.５
香料 １
色素 微 量
Example 13
Briquette:
Using the following composition, a briquette for bath was obtained in the same manner as in Example 1.
Malic acid 39%
Fumaric acid 3
Sodium bicarbonate 31
Sodium carbonate 15
Magnesium sulfate 2
Sodium sulfate 7.5
Sodium L-glutamate 1
Polyethylene glycol 6000 0.5
Fragrance 1
Dye amount
実施例５〜１３で得られた固形浴用剤（錠剤およびブリケット）は、成形性、浴湯の感触、浴湯表面状態ともに良好なものであった。 固 形 The solid bath preparations (tablets and briquettes) obtained in Examples 5 to 13 had good moldability, feel of bath water, and surface condition of bath water.
本発明の固形浴用剤は、製造において成形性に優れたものであり、これを使用した場合は、肌にしっとりとした使用感を与え、浴湯表面状態も良好なものである。従って、固形浴用剤として広く使用することが可能なものである。
The solid bath agent of the present invention is excellent in moldability in production, and when used, gives a moist feeling on the skin and has a good surface condition of the bath water. Therefore, it can be widely used as a solid bath agent.
Claims (3)
3. The solid bath composition according to claim 1, which is a briquette.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2003280135A JP4014546B2 (en) | 2002-08-08 | 2003-07-25 | Solid bath composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002231421 | 2002-08-08 | ||
| JP2003280135A JP4014546B2 (en) | 2002-08-08 | 2003-07-25 | Solid bath composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004083584A true JP2004083584A (en) | 2004-03-18 |
| JP4014546B2 JP4014546B2 (en) | 2007-11-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003280135A Expired - Lifetime JP4014546B2 (en) | 2002-08-08 | 2003-07-25 | Solid bath composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4014546B2 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004131455A (en) * | 2002-10-15 | 2004-04-30 | Kao Corp | Powdery or granular bathing agent |
| JP2007051117A (en) * | 2005-08-19 | 2007-03-01 | Tsumura & Co | Briquette machine for manufacture of solid bath salt and process for manufacture of solid bath salt |
| JP2008024612A (en) * | 2006-07-19 | 2008-02-07 | Health Chemical:Kk | Bath preparation composition |
| JP2009149532A (en) * | 2007-12-18 | 2009-07-09 | Kao Corp | Granular effervescent bath agent |
| WO2013180048A1 (en) * | 2012-05-28 | 2013-12-05 | 株式会社ホットアルバム炭酸泉タブレット | Method for producing tablet, and tablet |
| JP2013245218A (en) * | 2012-10-10 | 2013-12-09 | Hot Album Tansansen Tablet Inc | Method of producing tablet and tablet |
| JP2013253056A (en) * | 2012-06-08 | 2013-12-19 | Bathclin Corp | Foaming briquette formulation |
| JP2014221818A (en) * | 2014-07-25 | 2014-11-27 | 株式会社ホットアルバム炭酸泉タブレット | Method for producing of tablet, and tablet |
| JP2015007006A (en) * | 2013-06-25 | 2015-01-15 | 株式会社白元 | Composition for foamable bathing agent |
| WO2016103777A1 (en) * | 2014-12-22 | 2016-06-30 | 花王株式会社 | Solid foaming bath additive |
-
2003
- 2003-07-25 JP JP2003280135A patent/JP4014546B2/en not_active Expired - Lifetime
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004131455A (en) * | 2002-10-15 | 2004-04-30 | Kao Corp | Powdery or granular bathing agent |
| JP2007051117A (en) * | 2005-08-19 | 2007-03-01 | Tsumura & Co | Briquette machine for manufacture of solid bath salt and process for manufacture of solid bath salt |
| JP2008024612A (en) * | 2006-07-19 | 2008-02-07 | Health Chemical:Kk | Bath preparation composition |
| JP2009149532A (en) * | 2007-12-18 | 2009-07-09 | Kao Corp | Granular effervescent bath agent |
| WO2013180048A1 (en) * | 2012-05-28 | 2013-12-05 | 株式会社ホットアルバム炭酸泉タブレット | Method for producing tablet, and tablet |
| JP2014005266A (en) * | 2012-05-28 | 2014-01-16 | Hot Album Tansansen Tablet Inc | Method for producing agent and agent |
| JP2013253056A (en) * | 2012-06-08 | 2013-12-19 | Bathclin Corp | Foaming briquette formulation |
| JP2013245218A (en) * | 2012-10-10 | 2013-12-09 | Hot Album Tansansen Tablet Inc | Method of producing tablet and tablet |
| JP2015007006A (en) * | 2013-06-25 | 2015-01-15 | 株式会社白元 | Composition for foamable bathing agent |
| JP2014221818A (en) * | 2014-07-25 | 2014-11-27 | 株式会社ホットアルバム炭酸泉タブレット | Method for producing of tablet, and tablet |
| WO2016103777A1 (en) * | 2014-12-22 | 2016-06-30 | 花王株式会社 | Solid foaming bath additive |
| JPWO2016103777A1 (en) * | 2014-12-22 | 2017-09-28 | 花王株式会社 | Solid foaming bath agent |
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| Publication number | Publication date |
|---|---|
| JP4014546B2 (en) | 2007-11-28 |
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