JP3894217B2 - Liquid crystal display - Google Patents

Description

  The present invention relates to a liquid crystal display device, and more particularly to a technique for improving visibility by improving a display mode caused by reflected light.

  Conventionally, as a liquid crystal display device, there are various types of devices such as a TN (twisted nematic) type liquid crystal display element, a STN (super twisted nematic) type liquid crystal display element, and a ferroelectric liquid crystal display element. Among these, the one that switches the display using the change of the polarization state of light based on the electric field effect of the liquid crystal by using the polarizing plate, and the phase change and alignment state of the liquid crystal without using the polarizing plate. In some cases, the light transmission state and the light scattering state can be switched by a change in the light intensity and other changes.

  Since the latter liquid crystal display device does not use a polarizing plate, there is an advantage that light utilization efficiency is high and a bright display can be obtained. The display characteristics in this case are substantially determined by the transparency in the light transmission state and the scattering intensity or reflectance in the light scattering state.

  As an example of a liquid crystal display device that does not use a conventionally used polarizing plate, there is a polymer dispersion type liquid crystal display device shown in FIG. In this apparatus, an electrode 3 made of ITO (Indium Tin Oxide) or the like is formed on the inner surface of the substrate 1, and a metal electrode 4 also serving as a reflective layer made of Al, Cr or the like is formed on the inner surface of the substrate 2. Is formed. An alignment film 5 made of polyimide, polyvinyl alcohol or the like is formed on the surfaces of the substrate 1 and the transparent electrode 3, and a similar alignment film 6 is formed on the surfaces of the substrate 2 and the metal electrode 4. These alignment films 5 and 6 are rubbed in the a direction indicated by arrows in the figure.

  The substrate 1 and the substrate 2 are held in a state of facing each other with a predetermined interval (for example, 5 to 10 μm) by a sealant, a spacer, or the like, and a liquid crystal polymer composite layer 7 is sealed between both the substrates. In this liquid crystal polymer composite layer 7, particles of polymer 7B are dispersed in liquid crystal 7A. Both liquid crystal 7A and polymer 7B are aligned in the rubbing direction applied to alignment films 5 and 6. Yes.

  In the state where no voltage is applied between the transparent electrode 3 and the metal electrode 4, the liquid crystal 7A and the polymer 7B having the same orientation direction have substantially the same refractive index as shown in FIG. Therefore, the liquid crystal polymer composite layer 7 is in a light transmitting state, and incident light is reflected as it is by the metal electrode 4 which is a reflective layer. On the other hand, when a predetermined voltage is applied between the transparent electrode 3 and the metal electrode 4, the liquid crystal 7A having dielectric anisotropy is oriented in the electric field direction b as shown in FIG. A difference in refractive index occurs between the liquid crystal 7A and the polymer 7B exhibiting a directivity, the liquid crystal polymer composite layer 7 enters a light scattering state, and incident light is scattered.

  Various structures and manufacturing methods of the polymer dispersion type liquid crystal display device as described above are described in detail in US Pat. No. 3600060, Japanese Patent Laid-Open No. 5-119302, and the like.

  On the other hand, some liquid crystal display devices have color filters formed to enable color display. As a liquid crystal display device capable of such color display, for example, there is one having a cross-sectional structure shown in FIG. This liquid crystal display device is of a reflective type, and a transparent electrode 13 is deposited on the inner surface of a transparent substrate 11 which is one substrate, and an alignment film 14 is applied thereon and subjected to a rubbing process in a predetermined direction. A metal electrode 15 made of a metal such as Cr or Al is formed on the inner surface of the transparent substrate 12 as the other substrate, and a colored layer (red portion) arranged on the surface of the metal electrode 15 by a predetermined arrangement method. A color filter 16 having 16a, (blue portion) 16b, and (green portion) 16c is formed. An alignment film 17 similar to that described above is deposited on the surface of the color filter 16.

  The transparent substrate 11 and the transparent substrate 12 are bonded together through a sealing material (not shown) in the same manner as described above, and the liquid crystal layer 18 is formed by sealing liquid crystal in a region surrounded by the sealing material.

  In the reflection type liquid crystal display body formed in this way, light incident from the transparent substrate 11 side is sequentially transmitted through the liquid crystal layer 18 and the color filter 16 and reflected by the metal electrode 15. Since the liquid crystal layer 18 is configured to be emitted from the transparent substrate 11 through the layer 18, the liquid crystal layer 18 is controlled in orientation by applying a predetermined voltage between the transparent electrode 13 and the metal electrode 15. A desired color display can be performed by changing the 18 optical characteristics.

  In addition, in the reflective liquid crystal display device, in addition to forming a reflective layer made of metal on the inner side of the transparent substrate as described above, a reflective layer is formed on the outer side of the transparent substrate, or the substrate itself is made reflective. In some cases, it is made of the above materials.

  As described above, various liquid crystal display devices that perform display in various forms using liquid crystals have been developed and put into practical use. In this case, the reflective liquid crystal display device does not require a light source such as a backlight and can reduce power consumption, and thus is suitable for use in portable devices and the like. On the other hand, in the case of the reflection type, there is a problem that the display is generally dark and it is difficult to sufficiently increase the display contrast.

  For this reason, in the reflective liquid crystal display device, it is the most important technical problem to improve the brightness and contrast of display, and various developments have been made to solve this technical problem. Has been done. A display element of a type that performs display by light scattering described above is one of the results of the development, and a display element that exhibits a bright display and good contrast can be manufactured.

  However, when the brightness and contrast of the display are improved in the reflective liquid crystal display device, there is a problem that the light reflected by the metal electrode impairs the visibility of the display. This is because the reflective layer formed by metal electrodes etc. to improve the brightness and contrast of the display is formed so as to exhibit high reflectance almost like a mirror, so the transparency of the liquid crystal layer in the light transmission state If the height is high, the surrounding scenery may be reflected on the display screen, or the direct light emitted from the illumination may enter the eyes of the user and be dazzled.

  The visibility of such a reflective liquid crystal display device is slightly improved by attaching a non-glare plate or other filters, but these filters may reduce the brightness of the display or reduce the contrast. However, the basic characteristics of the display quality such as the reflection of the background cannot be changed, and it has been difficult to significantly improve the visibility.

  In addition, in the case of the display element using the above-described light scattering, the improvement of ensuring the brightness of the display and improving the contrast by improving the transmittance in the light transmitting state has been made. There is a problem that the more the image is displayed, the more the background reflection and the dazzle by direct light become more prominent.

  Therefore, the present invention solves the above-described problems, and an object thereof is to provide a novel technique for preventing a decrease in visibility due to light reflection of a reflective layer in a reflective liquid crystal display element.

  Means taken by the present invention to solve the above-mentioned problem is that a liquid crystal layer is sandwiched between a pair of substrates having electrodes on opposite inner surfaces, and the one substrate is provided with a reflective layer, The polymer is dispersed in the liquid crystal molecules, and a plurality of pixel regions are formed by the opposing electrodes, and the reflective layer has a plurality of reflective sections having different reflectances for each pixel region. It is formed.

  According to this means, since a plurality of reflection sections having different reflectivities are formed for each pixel area, light incident from one substrate is modulated in each pixel area by the difference in reflectivity of the reflection sections. Therefore, even if the liquid crystal layer becomes transparent, the background is not reflected and direct light does not enter the eyes as it is, which affects the display formed by the pixel area. In addition, the visibility of the liquid crystal display device can be improved.

  Here, the optical characteristic between the light transmission state and the light scattering state is controlled by the application state of the voltage applied to the liquid crystal layer. The plurality of reflection sections are preferably formed as back-side electrodes for applying a potential to the liquid crystal layer. In this case, since the reflection section is composed of the back surface side electrode, it is not necessary to separately provide a reflection layer, and it can be simultaneously formed in the electrode forming step.

  Moreover, it is preferable that the plurality of reflection sections are formed of different types of materials or under different conditions. Reflecting sections having different reflectivities can be easily formed by changing the type or composition of metal or other reflective material or the formation conditions.

  Furthermore, it is preferable that the plurality of reflection sections have a laminated structure in which another reflection film is partially overlapped on the surface of one reflection film. In this case, the reflectance can be changed by partially changing the thickness of the reflective film, or the reflectance can be changed partially by the material exposed on the surface. Can be easily changed. In particular, when the reflective layer is formed as a metal electrode, mutual conduction between the reflective sections can be easily and surely made, so that it is possible to easily form a reflective section having a complicated shape without impairing the function as an electrode. It can also be formed and it is possible to provide a large number of reflective sections.

  Next, as another means according to the present invention, a liquid crystal is sandwiched between a pair of substrates having electrodes on opposite inner surfaces, the one substrate is provided with a reflective layer, and the other layer is opposed to the reflective layer. A color filter composed of a plurality of color elements formed on the substrate side is arranged, a plurality of pixel regions are formed by the opposed electrodes, and the liquid crystal layer is controlled by the application state of a voltage applied to the liquid crystal layer Thus, the color filter is formed corresponding to the pixel region, and the color filter is selectively formed in a predetermined plane pattern in the pixel region.

  According to this means, since the color filter is selectively formed in a predetermined planar pattern in the pixel region, the light incident from one substrate passes through the color filter in each pixel region. Each color filter is modulated in tone by the portion where the color filter is formed and the portion where the color filter is not formed, so even if the liquid crystal layer becomes transparent, the background is reflected or the direct light remains as it is. Therefore, the visibility of the liquid crystal display device can be improved without affecting the display formed by the pixel region and without sacrificing the brightness of the display. In addition, since there is a portion where the color filter is not formed, the electric field of the electrode can be directly applied to the liquid crystal without going through the color filter, so that the drive voltage is reduced and the drive voltage margin is increased. Is also possible.

  Here, the liquid crystal layer has a structure in which a polymer is dispersed in liquid crystal molecules, and the light transmission state and the light scattering state are controlled by applying a voltage. Further, the color filter is composed of red, blue, and green color elements, or yellow, magenta, and cyan color elements. It is preferable that the ratio of the formation area of the color filter in the pixel region is different for at least two of the color elements. According to this means, by changing the ratio of the formation area of the color filter for each color element, it is possible to mutually adjust the color tone according to the ratio of the formation area, and without changing the color tone of the color element itself. Since the color tone characteristics can be adjusted, high-quality color display can be realized.

  The planar pattern of the color filter is preferably formed in a single island shape in the pixel region. In this case, the color filter is formed in a single island shape, so it can be handled with only minor changes such as changing the size of the mask pattern. can do.

  Furthermore, it is preferable that the planar pattern of the color filter is composed of a plurality of divided pattern portions distributed in the pixel region. According to this means, since the color filter having a plurality of divided pattern portions is formed in the pixel region, incident light or reflected light can be sufficiently modulated, and display quality can be improved reliably. it can.

  Next, as another means according to the present invention, a liquid crystal is sandwiched between a pair of substrates having electrodes on opposite inner surfaces, the one substrate is provided with a reflective layer, and the reflective layer is A color filter composed of a plurality of color elements formed on the other substrate side is arranged, a plurality of pixel regions are constituted by the opposed electrodes, and a liquid crystal layer is formed by applying a voltage applied to the liquid crystal layer. The color filter is formed to correspond to the pixel region, and the color filter has a light and dark pattern having a predetermined dark region and a light region in the pixel region. And

  According to this means, since the color filter has a shading pattern in the pixel region, incident light or reflected light is modulated by the shading pattern, so that the background is reflected even when the liquid crystal layer becomes transparent. The display of the liquid crystal display device is not affected without affecting the display formed by the pixel area, and without impairing the display brightness. Can be improved.

  In the liquid crystal display device of the present invention, a liquid crystal is sandwiched between a pair of opposed substrates, a reflective layer provided on one of the pair of substrates, and one or the other of the pair of substrates. A plurality of colored regions having different colors from each other, and a colored layer is formed in each of the colored regions, and the colored layer has a dark portion pattern and a light color portion having different color tones. In the pixel region, one of the light color portion pattern and the dark color portion pattern is formed so as to surround the other pattern.

Further, the plurality of colored layers include red, blue, and green colors.

  Here, the liquid crystal layer has a configuration in which a polymer is dispersed in liquid crystal molecules, and the light transmission state and the light scattering state are controlled by applying a voltage. The color filter includes red, blue, and green color elements, or yellow, magenta, and cyan color elements.

  Further, the shade pattern may be formed by partially changing the thickness of the color filter or by providing a dark color portion and a light color portion having different color tones in the color filter.

  Furthermore, it is preferable that the density pattern of the color filter in the pixel region is different for at least two of the color elements. According to this means, the average thickness of the color filter can be changed by changing the density difference between the dark and light color portions in the light and dark pattern, the ratio of the pattern area, etc., so the color tone of the color elements can be adjusted mutually. Therefore, high-quality color display can be realized.

  Each of the above-mentioned means is, for example, a liquid crystal polymer composite layer in which the liquid crystal layer is a liquid crystal polymer composite layer formed by compatibilizing a liquid crystal and a polymer and phase separating the liquid crystal and the polymer. It can be applied to a liquid crystal display device.

  Next, an embodiment of a liquid crystal display device according to the present invention will be described with reference to the accompanying drawings.

(First Reference Example)
FIG. 1 shows the structure of a liquid crystal cell of a liquid crystal display device of a first reference example according to the present invention. Similar to the display device of FIG. 10 described above, the transparent substrates 1 and 2, the transparent electrode 3, and the metal electrode 4 are provided. A liquid crystal polymer composite layer 7 composed of a liquid crystal 7A and a polymer 7B which are aligned to each other is encapsulated.

  As in the conventional example, the liquid crystal polymer composite layer 7 becomes transparent and becomes transparent when the refractive indexes of the liquid crystal molecules 7A and the polymer 7B are substantially equal to the incident light and the reflected light. The orientation state of the liquid crystal molecules 7A having the dielectric anisotropy changes depending on the change of the electric field applied state, and this causes a difference in the effective refractive index between the liquid crystal molecules 7A having the refractive index anisotropy and the polymer 7B. When it occurs, it becomes a light scattering state and becomes cloudy. For example, the liquid crystal polymer composite layer 7 can be clouded when no electric field is applied and transparent when an electric field is applied, or can be transparent when no electric field is applied and can be clouded when an electric field is applied. The light transmission state and the light scattering state of the liquid crystal polymer composite layer 7 are appropriately realized by adjusting the mutual relationship between the refractive indexes of the liquid crystal molecules and the polymer particles.

  The metal electrode 4 is formed by depositing Cr entirely on a predetermined pixel region by vapor deposition or sputtering. The surface reflectance of the metal electrode 4 is adjusted to a range of about 50 to 70% depending on the film thickness of the Cr layer, film forming conditions, and the like. On the half region on the surface of the metal electrode 4, a dissimilar metal layer 8 is formed by depositing Al in a predetermined film thickness by vapor deposition or sputtering.

  In the liquid crystal display device formed as described above, the first reflection section A in which incident light is reflected by the metal electrode 4 in the predetermined pixel region D defined by the transparent electrode 3 and the metal electrode 4. The second reflection section B in which incident light is reflected by the dissimilar metal layer 8 is formed.

  In the structure of the reflective layer corresponding to each pixel region D of the liquid crystal display device formed in this way, as shown in FIGS. 2A to 2C, the first reflective section A and the second reflective section B Are arranged vertically or horizontally. As shown in FIGS. 2A, 2B, and 2C, various arrangement methods of the first reflection section A and the second reflection section B can be considered in relation to other adjacent pixel regions D. It is determined in such a way that it is as biased as possible over the pixel area. Each of the three arrangement methods shown in FIG. 2 shows a case where each pixel region D is divided into two vertically or horizontally. For example, a pixel region divided into two vertically and a pixel region divided into two horizontally are divided. They may be arranged alternately or dispersed appropriately.

  FIG. 3 conceptually shows the structure of a liquid crystal display device having pixel regions D of different modes. In FIG. 3A, the first reflection section A is arranged at the center of each pixel region D, and the second reflection section B is arranged around the first reflection section A. Also, what is shown in FIG. 3B is one in which each pixel region D is divided into four, and two each of the first reflection section E and the second reflection section F are provided. FIG. 3C shows a case where a first reflection section E and a second reflection section F, which are the same as those in FIG. 3B, are provided in each pixel region D, but the partition arrangement in each adjacent pixel region D is mutually different. Are different cases.

  As described above, by forming a plurality of reflection sections in the reflection layer in each pixel area D, each pixel area is divided into a plurality of sections having different reflectivities, thereby reducing the specularity of the reflection layer. Therefore, even when the liquid crystal polymer composite layer 7 is in a light transmitting state, the background is not projected and direct light is less likely to enter the eyes, and the visibility is greatly improved. In order to improve visibility, it is effective to set the arrangement period finely when arranging in a pattern, such as arranging multiple types of reflection sections in a mosaic pattern, and in some cases randomly arranging May be.

  Further, when the first reflection section and the second reflection section are formed using Cr and Al as described above, the reflectance of the second reflection section is set to about 50 to 70%. 90 to 100%, and the above effect can be enhanced by sufficiently taking the difference in reflectance between the first reflection section and the second reflection section. On the other hand, since the reflectance of the entire pixel region can be maintained as high as about 70 to 85% as an average of both, the brightness of display is hardly sacrificed.

  In the above reference example, the structure of the polymer-dispersed liquid crystal display device (FIG. 1) has been described as an example. However, the same thing can be obtained by utilizing other light scattering and coloring properties. Liquid crystal display method for displaying by a state transition between a scattering state or a colored state, for example, a phase transition type display method using a phase transition between a cholesteric phase and a nematic phase, a method using a dynamic scattering mode of liquid crystal, The present invention is equally effective when applied to liquid crystal display elements and devices that perform display by various methods that do not use a polarizing plate, such as a display method by orientation dispersion, or other forms, for example, The liquid crystal display device using STN liquid crystal and the liquid crystal display device using TN liquid crystal can also be applied to improve display quality. Further, the same effects can be obtained even when the configuration as in the present application is applied to a liquid crystal display device in which pixel electrodes are controlled by active elements, or a simple matrix type liquid crystal display device.

  In the above reference example, a plurality of reflective sections having different reflectivities are formed by partially forming another metal layer on the surface of the metal electrode 4, so that conduction between the respective reflective sections is facilitated. In addition, the conductive state is stabilized, but different metal layers are formed adjacent to each other without overlapping in this way, and both are directly conductively connected at the periphery or a wiring layer is formed. It can also be formed by conducting a conductive connection. It is obvious that the reflective layer itself does not have to serve as an electrode, and may be provided separately from the electrode, for example, along with a transparent electrode.

  Further, the number and shape of the reflection sections provided in the pixel region are arbitrary, but it is desirable to form more reflection sections with a complicated shape and arrangement in order to improve visibility.

  Further, as the material of the reflective layer for forming the reflective section, in addition to the above-mentioned Cr and Al, other metals such as Ag, Ni, Ta, and other alloys are properly used to provide a difference in reflectance. Alternatively, it may be formed of a resin material or other material other than metal.

  In addition, as a method of making the reflectance different from each other in the plurality of reflective sections, there is a method of changing the thickness of the reflective layer in addition to a method of changing the material of the reflective layer. For example, the reflectance can be increased by making one reflection section thicker than the other reflection section. In this case, as described above, the first layer is formed on the entire surface, and only one reflection section is again formed. It is also possible to form a reflective layer having reflective sections having different thicknesses by a method of forming the second layer or a method in which the order of formation is reversed.

  Furthermore, the substantial reflectance can be changed mutually by changing the surface state (surface roughness, etc.) of the reflecting surface in the reflecting section. For example, by making one reflective section an optical mirror surface, the substantial reflectivity is increased, and the surface of the other reflective section is roughened, or unevenness is formed on the surface of the reflective layer to increase scattered light. Thus, the substantial reflectance can be lowered.

(Second reference example)
Next, a second reference example according to the present invention will be described. This reference example is a liquid crystal display body in which a liquid crystal layer 38 is sealed between a substrate 31 and a substrate 32 made of transparent glass, as shown in FIG.

  On the inner surface of the substrate 31, for example, a plurality of striped transparent electrodes 33 made of ITO (indium tin oxide) or the like are formed in parallel. An alignment film 34 made of polyimide resin or the like is applied and formed on the surfaces of the electrode 33 and the transparent substrate 31. The alignment film 34 is rubbed in a predetermined direction.

  On the other hand, a metal electrode 35 also serving as a reflective layer is formed on the inner surface of the transparent substrate 32 by depositing a metal such as Cr or Al by a sputtering method or the like. The metal electrode 35 is formed, for example, in a shape divided for each pixel region, and each is connected to a wiring layer (not shown).

  The metal electrode 35 may be connected to the wiring layer via an active element such as an MIM (metal-insulator-metal) element or TFT (thin film transistor). When the metal electrode 35 is connected to the wiring layer through the MIM element, for example, the wiring layer has a stacked structure of Ta, the MIM element has a stacked structure of Ta (metal), tantalum oxide (insulator), and Cr (metal). The metal electrode 35 is formed of Cr.

  A color filter 36 is formed on the surface of the metal electrode 35. The color filter 36 is formed as follows, for example. First, a photosensitive pigment-dispersed resin is applied by spin coating, roll coating, flexographic printing, or the like to form a film with a thickness of about 3000 to 15000 mm. Next, pre-baking is performed under conditions of a temperature of 50 to 150 ° C. and a time of 5 to 60 minutes, and a plurality of color elements, for example, the three primary color red, blue, and green coloring regions 36a, 36b, and 36c are made to correspond to the pixel regions. Are sequentially formed. The colored layer is exposed using a mask having a desired shape, developed, and patterned into a desired shape. Thereafter, post-baking is performed under conditions of a temperature of 75 to 200 ° C. and a time of 10 to 20 minutes to completely cure each colored layer. A protective film (not shown) is formed on the surface of the color filter.

  Each color filter (colored region) 36a, 36b, 36c made up of a plurality of color elements is made up of red, blue, and green color elements, and is formed in a predetermined plane pattern formed by the above-described manufacturing method. That is, in each pixel region, the colored pattern portions 36a-1, 36b-1, and 36c-1 remaining by the patterning and the lacking portions 36a-2, 36b-2, and 36c-2 where no colored pattern exists are included. Existing.

  FIG. 6 is a plan view showing a planar pattern of the color filter 36 in this reference example. As shown in this figure, a colored layer is usually formed on the entire surface of the colored region corresponding to each pixel region, but in this reference example, a colored layer formed in the region corresponding to each pixel region. Is patterned in a state in which a plurality of rectangular colored pattern portions 36a-1, 36b-1, and 36c-1 are dispersedly arranged, and lack portions 36a-2 and 36b-2 around which the colored portions are not formed are patterned. , 36c-2.

  In this reference example, since the colored layers 36a, 36b, 36c are selectively formed in the above-described plane pattern in each pixel region, the incident light incident from the transparent substrate 31 is directly reflected by the metal electrode 35 and once again. When the light is emitted from the substrate 31, incident light and reflected light are modulated such that a color pattern is formed or refracted by a colored pattern portion formed in each pixel region. Thereby, on the display surface of the liquid crystal display body, the effect of reducing the reflection of the background and the direct reflection of the illumination light can be obtained.

  In this reference example, the color elements of the color filter are composed of three color elements of red, blue, and green. However, the color filter is composed of three color elements of yellow, magenta, and cyan. Also good. When a color filter composed of yellow, magenta, and cyan is used, the color filter has high transmission characteristics, and when used as a reflective liquid crystal display device, a bright display can be obtained.

Further, a clear color can be displayed by using a white filter as a color filter composed of these three color elements.
In this reference example, the MIM element is used, but the same effect can be obtained even if the above-described structure is applied to the pixel electrode using the TFT element. Further, a simple matrix type liquid crystal display device has the same effect.

(Third reference example)
FIG. 7 is a plan view showing a planar pattern of the color filter in the third reference example of the present invention. This reference example is a liquid crystal display body having a structure similar to the longitudinal cross-sectional structure shown in FIG. Is attached.

  In this reference example, colored pattern portions 36a-3, 36b-3, and 36c-3 formed in a single island shape are formed inside the three colored regions 36a, 36b, and 36c constituting the color filter 36. Yes. In addition, there are missing portions 36a-4, 36b-4, and 36c-4 similar to those in the second reference example around these colored pattern portions.

  In this reference example, since each colored pattern portion is formed in a single island shape, the mask pattern in the patterning process does not need to be so fine and can be easily formed with high accuracy. Further, the mask pattern can be easily changed by simply reducing the pattern size of each colored region while keeping the pattern shape as it is.

  In the second reference example and the third reference example, the size and shape of the colored pattern in each colored region can be appropriately changed. In this case, the ratio of the occupied area (formation area) to the entire colored region of the colored pattern portion can be appropriately adjusted depending on the color tone of the desired colored pattern. Further, as shown in FIG. 7, in order to optimize the color tone obtained on the display screen for each color tone type of the colored region, that is, in the above case, for each color tone of red, blue, and green. Each area ratio can be set. Accordingly, the ratio of the occupied area differs for each color tone. In this way, it is not necessary to adjust the color tone of the material constituting each colored layer according to the material and the pigment concentration, or to adjust the film thickness according to the film thickness. Management and quality control become easier.

  Furthermore, since the colored pattern is selectively formed in the colored region instead of the entire surface, there is always a missing portion without a colored layer as described above, and the presence of this missing portion causes the presence of the missing portion below the color filter. Since an electric field can be directly applied to the liquid crystal layer 38 from a certain metal electrode 35 without passing through a colored layer that is a dielectric, the drive voltage can be reduced and the drive voltage margin can be increased. It becomes possible.

  This reference example can also be applied to a liquid crystal display device using a switching element (TFT, MIM) or a simple matrix type liquid crystal display device.

(4th reference example)
Next, a fourth reference example according to the present invention will be described. As shown in FIG. 5, in this reference example, a colored layer is entirely formed in each colored region 36a ', 36b', 36c '. , 36b-1 ′, 36c-1 ′ and thin portions 36a-2 ′, 36b-2 ′, 36c-2 ′ are formed. FIG. 8 shows the planar shape of the color filter of this reference example.

  Such a colored layer is formed by, for example, partially etching the colored layer formed on the entire surface to form an uneven shape on the surface, or on the first layer formed on the entire surface. The two layers are partially formed, the second layer is entirely formed on the selectively formed first layer, and the thick part and the thin part are separately formed. It can be formed by various methods.

  In this reference example, a thickness pattern is partially changed in the colored layer to form a light and dark pattern in each colored region, whereby the transmitted light can be modulated in tone, so that the second and second described above are used. As with the three reference examples, background reflection and dazzling due to illumination can be reduced, and display quality can be improved.

  In this case, it is possible to easily adjust and change the color tone of the color filter without changing the color tone of the material constituting the colored layer by adjusting the uneven shape of the colored layer itself or the shape of the thick and thin portions. Can do. Here, adjusting the shape of the colored layer means, for example, the depth of the unevenness (the difference in height between the bottom surface of the concave portion and the top surface of the convex portion), the difference in thickness between the thick portion and the thin portion, and / or the concave portion or It is to adjust the ratio of the formation area of the thin part and the convex part or the thick part. These can be controlled more easily than the method of changing the average thickness of the colored layer itself, and the accuracy can be secured.

  In addition, in order to optimize the mutual color tone relationship among the three colored layers, it is necessary to adjust the average thickness of the colored layers. In this case, too, the average thickness of each colored layer is simply used. If the average thickness changes as a result by changing the uneven shape or the shape of the thick and thin portions instead of changing the shape, it is possible to easily adjust the color relationship between each other. .

(Embodiment)
Next, an embodiment according to the present invention will be described with reference to FIG. In this embodiment, the same parts as those in the fourth reference example are denoted by the same reference numerals, and the description thereof is omitted. The color filter 46 is formed on the surface of the transparent electrode 33, and in each of the colored regions 46a, 46b, 46c of the color filter 46, a colored layer having the same uneven shape as that of the fourth reference example is formed on the surface. Has been.

  As shown in this embodiment, the color filter may be formed at any position as long as it is located on the surface side of the reflective layer. In the present embodiment, the color filter 46 can be mixed with a conductive material to form a colored layer on the surface of the electrode 33, and a colored layer (colored electrode) integrated with the transparent electrode 33 can be configured. In this way, the manufacturing process and structure can be simplified.

  Note that the light modulation by the colored layer may result in a light / dark pattern being formed inside the portion corresponding to each pixel area of the color filter. You may comprise by forming a color part separately.

  In addition, a color filter capable of obtaining an optimum display quality can be configured by appropriately combining the formation of the shade pattern of the colored layer and the selective formation of the colored pattern portion as in the second reference example.

  The pattern shape of the shade pattern formed by the structure described in the fourth reference example and the embodiment and the method of partially changing the color tone is arbitrary, for example, the partition shape of the reflection layer shown in the first reference example It may be formed in a planar pattern, and the colored pattern portion of the second reference example or the third reference example may be adopted as one pattern shape (that is, either the dark color portion or the light color portion).

  In each of the above embodiments, particularly when the liquid crystal layer is formed as a polymer dispersion type liquid crystal display device in which the polymer and the liquid crystal are separated from each other in a phase separated state, the brightness of the screen display is increased. It is possible to remarkably reduce the reflection of the background while ensuring the image quality. This is because, in this type of liquid crystal display, it is not necessary to use a polarizing plate. Therefore, when the present invention is not applied, when the liquid crystal layer is in a light transmitting state, the reflected light of the reflective layer is visually recognized as it is, especially in the background. This is because the reflection of light and the reflection of illumination light appear clearly.

  As a polymer-dispersed liquid crystal display device, in particular, liquid crystal molecules and polymer monomers that are compatible in a liquid crystal cell are aligned in a predetermined horizontal direction, and polymer monomers are polymerized and cured, for example, light It is preferable that liquid crystal molecules and polymer particles are dispersed in each other by polymerization and curing. In this case, for example, when no electric field is applied, the alignment directions of the liquid crystal molecules and the polymer particles are aligned and the liquid crystal polymer composite layer is in a transparent state, and when the electric field is applied, only the liquid crystal molecules are directed in the electric field direction. Become.

  In addition to the above-described polymer dispersion type liquid crystal display device, as a liquid crystal display device that does not require the use of a polarizing plate, a state between a light transmission state and a light scattering state or a colored state utilizing light scattering and colorability Various liquid crystal display methods for displaying by transition, such as phase transition type using phase transition between cholesteric phase and nematic phase, using dynamic scattering mode of liquid crystal, orientation dispersion, etc. In these cases, a remarkable effect can be obtained by similarly applying the present invention.

  In addition, a liquid crystal display device using active elements (MIM, TFT) and a simple matrix liquid crystal display device have the same effect.

(The invention's effect)
As described above, since a plurality of reflection sections having different reflectivities are formed for each pixel area, light incident from one substrate is modulated in each pixel area by the difference in reflectivity of the reflection sections. Is done.
In addition, even if the liquid crystal layer becomes transparent, the background is not reflected, or direct light does not enter the eye as it is, without affecting the display formed by the pixel region, The visibility of the liquid crystal display device can be improved.

  Further, the light transmission state and the light scattering state can be controlled, and display can be performed in various states.

  Further, since the reflective section is composed of the back surface side electrode, it is not necessary to provide a reflective layer separately, and it can be simultaneously formed in the electrode forming step.

  In addition, it is possible to easily form reflective sections having different reflectivities by changing the type, composition, or formation condition of the metal or other reflective material.

  In addition, the reflectance can be changed by changing the thickness of the reflective film, or the reflectance can be changed depending on the material exposed on the surface. be able to. In particular, when the reflective layer is formed as a metal electrode, mutual conduction between the reflective sections can be easily and surely made, so that it is possible to easily form a reflective section having a complicated shape without impairing the function as an electrode. It can also be formed and it is possible to provide a large number of reflective sections.

  In addition, since the color filter is selectively formed in a predetermined plane pattern in the pixel region, light incident from one substrate passes through the color filter, and the color filter in each pixel region. Since it is modulated in color by the part that is formed and the part that is not formed, even if the liquid crystal layer becomes transparent, the background is reflected or the direct light enters the eye as it is Therefore, the visibility of the liquid crystal display device can be improved without affecting the display formed by the pixel region and without sacrificing the brightness of the display. In addition, since there is a portion where the color filter is not formed, the electric field of the electrode can be directly applied to the liquid crystal without going through the color filter, so that the drive voltage is reduced and the drive voltage margin is increased. Is also possible.

  In addition, the liquid crystal layer has a structure in which a polymer is dispersed in liquid crystal molecules, and the light transmission state and the light scattering state are controlled by applying a voltage. Therefore, the liquid crystal layer reflects between the light transmission state and the light scattering state. The rate can be controlled arbitrarily.

  Further, since the color filter is composed of red, blue, and green color elements, a full color display can be obtained.

  Further, since the color filter is composed of color elements of yellow, magenta, and cyan, the transmittance is high, and a bright display can be obtained as a reflective display device.

  In addition, by changing the ratio of the color filter formation area for each color element, the color tone can be mutually adjusted according to the ratio of the formation area, and the color tone characteristics of the color filter can be adjusted without changing the color tone of the color element itself. Therefore, high-quality color display can be realized.

  In addition, by forming the color filter in a single island shape, it can be handled with only minor changes such as changing the size of the mask pattern, so that it can be manufactured with almost no change in the conventional manufacturing process. it can.

  In addition, since a color filter including a plurality of divided pattern portions is formed in the pixel region, incident light or reflected light can be sufficiently modulated, and display quality can be improved reliably.

  In addition, since the color filter has a light and shade pattern in the pixel region, incident light or reflected light is modulated by this light and shade pattern, so that even if the liquid crystal layer becomes transparent, the background is reflected or is directly irradiated. Since the light does not enter the eye as it is, the visibility of the liquid crystal display device is improved without affecting the display formed by the pixel region and without impairing the brightness of the display. be able to.

  In addition, the liquid crystal layer has a structure in which a polymer is dispersed in liquid crystal molecules, and the light transmission state and the light scattering state are controlled by applying a voltage. Therefore, the liquid crystal layer reflects between the light transmission state and the light scattering state. The rate can be controlled arbitrarily.

  Further, since the color filter is composed of red, blue, and green color elements, a full color display can be obtained.

  Further, since the color filter is composed of color elements of yellow, magenta, and cyan, the transmittance is high, and a bright display can be obtained as a reflective display device.

  In addition, since the average thickness of the color filter can be changed by changing the density difference between the dark color portion and the light color portion in the light and shade pattern, the ratio of the pattern area, and the like, the color tone of the color elements can be mutually adjusted. Therefore, high-quality color display can be realized.

It is sectional drawing which shows the structure of the 1st reference example of the liquid crystal display device which concerns on this invention. It is a schematic explanatory drawing (a)-(c) which shows the example of arrangement structure of various pixel fields in the 1st reference example. It is a schematic explanatory drawing (a)-(c) which shows the example of arrangement structure of various pixel fields in the 1st reference example. It is a longitudinal cross-sectional view which shows the structure of the 2nd reference example of the liquid crystal display device which concerns on this invention. It is a longitudinal cross-sectional view which shows the structure of the 4th reference example of the liquid crystal display device which concerns on this invention. It is a top view which shows the planar structure of the color filter of the 2nd reference example of the liquid crystal display device which concerns on this invention. It is a top view which shows the planar structure of the color filter of the 3rd reference example of the liquid crystal display device which concerns on this invention. It is a top view which shows the planar structure of the color filter of the 4th reference example of the liquid crystal display device which concerns on this invention. It is a longitudinal cross-sectional view which shows the structure of embodiment of the liquid crystal display device based on this invention. It is a longitudinal cross-sectional view which shows the structure of the conventional polymer dispersion type reflection type liquid crystal display device. It is a longitudinal cross-sectional view which shows the structure of the reflection type liquid crystal display device provided with the conventional color filter.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1, 2 Transparent substrate 3 Transparent electrode 4 Metal electrode 5, 6 Orientation film | membrane 7 Liquid crystal polymer composite layer 7A Liquid crystal 7B Polymer A, E 1st reflection division B, F 2nd reflection division D Pixel area 36, 36 ', 46 Color filters 36a, 36b, 36c Colored regions 36a-1, 36b-1, 36c-1 Colored pattern portions 36a-1 ′, 36b-1 ′, 36c-1 ′ Thick portions 36a-2 ′, 36b-2 ′, 36c-2 'Thin part

Claims (2)

A liquid crystal is sandwiched between a pair of opposing substrates,
A reflective layer provided on one of the pair of substrates;
A plurality of colored regions provided on one or the other of the pair of substrates and having different colors from each other;
A colored layer is formed in each colored region,
The colored layer comprises a dark portion pattern and a light portion pattern having different color tones,
A liquid crystal display device, wherein one pattern of the light color portion pattern and the dark color portion pattern is formed to surround the other pattern in a pixel region.   2. The liquid crystal display device according to claim 1, wherein the plurality of colored layers include red, blue, and green colors.

Images